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Cooraimation Compounds: (61) comply Combninas |!
C6 are those adddton molecular (ompounds
which retain — their ideality in Solid Slate as
well aS in dissolved’ *6taters9n there Cornpound,
the Central metal’ atom’ orion. it linked by
| font oy molecule: with coordinat bonds
¢-4. Potawium Ferrocyanide ku [Fe CON),J-
kylFecende] = aka 4 [eedend) a7 arhes
a) abpre (00 10"
Ligand ke
Kyl Fe chy] e Coordination number
We /
fin? i Sphere Cerlity)
Counter ion Coordi ne
Woulle opal
therdltave the addition molecular
Solid tate but
Central met
Cornpeund
which are Stable in :
ditociate — tnt constituent rons 19, ps
eg. Mohve Salt, [asoy cre), 604d
solution fo
Het digcociated i. oe and $04 ‘ort
Related to Coordin nation Compounds
Related *
“Terme
i Cooy vdination entity
4. Comper ion or
M4 ctrically charged Gpecie in
7 Ape
or ion iS
iS an ele
which Central metal atom
Survounde d by urna og 8008 Ov neutral
mole cules. an A
@ scanned with OKEN Scanner 7 ') Cationic Complex enti enti ly ion
Qt ts oak Complex too which carries os postive
Charge ,¢-9. fet (Nya)?
it) Anionic Comple x cot
ith Carviet negative
4 is the Complex for uh
Charge
_
Gr (Fe Con),)'
Q. Ceatral Atom oy Yo Pon
The ss oy fan iat ree a fined dimer of
Pei oy group § are bound ic j called Cenfral
or ten OF I alto veterved ag Lewie acid.
lom or t
(nich (HO), Ni |
transition element oF een
A “Central metal alom .2+
r Sh
re generally
glement-
iB Moroz
Ligand is clectron donating Species Lions or radlel
bound te the Central atom in “the Coordi natin
ently
thesetingay , be charged or meatal Ligands i
are of the joi lowing type: ‘ y
i) Unidentate: MO io Kgand , which has one.
a. |
bn, kh pe ligan d bound fo a
metal ton through a Ging le donor sie + ee
@ scanned with OKEN Scanner ‘ Ego HO NT cele
ii) Aide ntate Gt 1 the ligand , which have two
clonor siles'n
C007 cHy — NHL
|
clhowe "2
C60 - cH, “NH, 0°
diornni ne
Coralate fon) “Cethylene diammine)
(ox) Cen)
iti) Po lydentate :- Dts the legand , which have
Several donor siles- tania ibs 190
ee (Epra) 1S heradenale ligand:
arn ne tre Acitate
Ethylene Dra! thon
C-N
"i Ne
: CH, C00”
Hy C-N— 2
™ cH, | C007
F af tehylere iarnune teeGe acetale son]
lin eAnbi \mbi dentate ligands Thete are the monodent
ate Vigand which can a through two
di tterent Sites -
Ear Noy , oN” ee
») Che helati rq ligand
Faure ¢ cligakion around the mela!
" chelales Sue ligands use, fwd
metal ton
» PE or * polydlen tale te igand:
alsin which |
|
|
f
Known as
6
°' more clonor atoms ‘te bind) single
Bhs anit
Md are krown as chelating | legen
@ scanned with OKEN Scanner More the number 0 Fo thelate rings More is
the @tabilt y ot Comple % :
The Stabile cation of Coordination Compoun de
due to chelation vs lenown as, chelate ettea
meacid ligands are those ligands which can
form o-bond and n-bond = by
appreciable amount of 1 dlectron clensity
trom -rnetal . oom to empty Lv hoy! orbitals
4- Coordi natlion Number
Qt is defined a the number of coordina?
Be bonds — formed by Central) metal alom,
rth the ligands:
and (etcy) pt har ¢6 ordination “number 6
pf
accepting an
mn care Of ‘mond dentate ligande,
lrgands.
Coordination number snum ber of
Cn poly dentate. ligand,
Coordination number = number of ligands ,
density :
5. Coordination, sphere
ordi nan pher
The central ion and the I'gand, affachéal
4
i} are enclosed in
Compounds with Suitable example
ns Poctulates:-
) every complex compound: Contain Central
ae
alom Cor) jon: ;
Guay pad, cokers iW. A oe andi tude pameee
a) The ynetal atorn Cor) fon show: two type of
metal
valencies they, are
i) Primary valency .
ii) peconda ry Valency
Primary Nalency:-
DAH ss equal do Central metal Oxidation
number
Bit we completely
Hen by Goby omtant 0)
ions sable
3) Dt 1s sat
y Ot ts Non directional
OTM re denoted by dotted
Suordary valet"
lines. 283+);
D4 ¥¢ equal to Certral meta! Coordination
5
DT ig not fonisable
9D
Ot ic satisfied by negative ions amd neutral
PY cleeates
B+ is directional
0.
9455 deneled by Continuour lines C B.S
@ scanned with OKEN Scanner
a eo!
Bo grthanide \ Goatracton Consequentes
i) The crystal “Shrudture dnd’ other propertliad
lonthanides Gre very cimilar , There fore, tf ite
dittreutt to Separate then from a mirtire. 4
ii) The effect of lanthanide Contraction okie
observed in the 5d transition feries- é
iit) The alomic radii of Se and Ud transition
elements are very Close ty each other when
pared ty those of ad and 4d transition
menb -
ad and 6d transition element are more ©
Similar in properties
| Exam Les for Werner's theory
9 Leo-cnad, bets:
gol) Cocha. CNH,
nl Ny's ity
Gol: NGS. ~ru
2 i
“\
nH a nwt
a valency 26NN3 j
U valency = ack
with Agno, 6 pmole) ‘
Bag’ 4 ack — ange! a
3 moles ot 6
I aacl
@ scanned with OKEN Scanner af watery: 5NH3
Valenty = 3027
bth f gat tcke
with Agno,
aAg* act —sgngcd>
amples oF
ageh:
a molesot
Ag N05:
u) cocks. ants |
fol
ney
Cle ne
om valency = 3NHs
1 valeneys OCF
beth eat 23 Ck7
24 doer not seach
with 49 NOs.
SLT
3) Cocks UNHa:,
nes
sol. BK
ot “ He
J: ‘ “10d
An, | Hs
ce
a? valency’ UNts
° valency sack Gu
Poth {hes 2%.
lyithzag nos! |
Agt+ CUS Aghios
vmole of
Agel wh
@ scanned with OKEN Scanner EAN:
vo
GAN = Cal-mo- ox-ne) +
2b)
o-kulFe’ con.)
£0) ULeya ttee) ee CON) =O
Cat) + x t6C-0) 20
u+x-6 +0
ab 2) +24)
Yair = 36 = kd
ka lFectnde)
se BLK)4ICFe) te (EN) =d
aCar)t webCT) 20
a+x-62D
Ges
EAN = (26-3) + ale): 354CK0
3) (NICE Na)
Lan aulenyee2
sol.
metre?
gectrt LD
EAN = (ge )e(2e4) = 4 £09
£390) Ce)
ak coordi nati on umber. . Es
@ [co cna) Jets
Gol 1 Ceo) 46 Untty)43 Code
HA OF 3L1) 2D
EAN = (24-3) +200)
=36 =kkr)
@ Ni (coy,
soli ini) +4 lo) 20>
we 44 Co) 204
EAN 2 (2g -0) +20)
L326 A16 go
ae cee
© [cucw¥d)ior {
sou
Sol ved) gatas sal
ZH lo) H@L-2)>0
KAD - Fo
sae EE 1]
Fan: C24 -2) +24)
Tl™t+B
*3S4.cky)
;
@ scanned with OKEN Scanner 4) Cer C2076) Chas
oli
Y40 abl) 20
Ean: QU-
3)+2(6)
sadtle
may 23a OK)
Names
cer) +6(H,0) +3CCL) =O
Ligand
Name
flussido
chlorido
Bromido
name.
thiocyanalo
2 Sothioc anato
Cyano
ae
a Pein A
ita Hy drido NOs Nitrate,
ne- 2
No,
—ONO7
Nitridd
Nitrite - N
a
Thiosulphato
ps
Ace talo
NO” | Nitrite—o Ot , Bo 5 j
4
ANH, coo
ee |
Hy dv xo er fp
mo Ue
@ scanned with OKEN Scanner Names of Cation’¢ and neutra) Wein ds,
| ‘Catronic Vigan d Name.
Not Nikrogonium
No,t Nitronium
NH,NH,t Hydrarinium
: Itoi) pia Emi
Neutral ligand * Name
Ammine
4
Co
Car bony) 4
CsHsN Pyridine | |
| [Han Cty tH NH ethane-1,2- charaming
i | NH, CH, Methyla mine.
) Kulfecen))
p Potassium Hexa Cyiano Ferveite CZ)
a) Kg (fe Conds)
a) Polastum — Hexo Cyiano Ferrale civ)
3) €to UNHs)g) Cts i
A) Hera —Ammine Cobalt Citi) chloride. :
+3
u) Cr CH,0),]
A) Hexo agua Titakiam cin) inn
@ scanned with OKEN Scanner 5) (PE CNHs), CL CHAINH J CL
A) diammine Chloridb: methyl amine Aahrsursey ehled
tosod ave
y (20 CoWu). : cea teenth
| a) tetra hydvoxo Bincale (B) ton. me Rte ae
3-2) =0
(Oy) Bch +xt
1 k3) cr (104) 3) ' eo
A) Potassium trioxclate chroma Ci). Kz43
g) (nicl)? \ BANC e >
a) tetra chlovido Nickelate CE) ron. eee
4) Fe’ ft Cones 05) 4 Ceaasz alec ies
ax-6 26
A) Tron) Hexa Cy and Fervate Wr) a
a4e
wear
wd{ eves, Cen), Jee
a) dichloro biel ethane 1,2'-diammine ) cobalt (i) chlovide.
48
Explain Wee rent types of 'Someriim exhibited
by Cor giaaiior Compoun dev gi ving guitab le,
1.0m ples -
Ane Structural isomerism
Two dr more Gubstances having ‘Sdéhe
+ different Structural , avvangement
ormula but
a ° i
© called Structural isomers j
|
) toniaation fsomerigm:
Com poun di ishich give
sonizalion® Wome re.
citderen? fons wt
Solutron are called
Stuns giants othe exchonge of ‘tons in
{Nd putside of the
> Cras HATE SOF
Coordination Sphere.
[CoS dyCNHo)s} BY
@ scanned with OKEN Scanner a Hydrate Peomeriem (9 0
P tomers, which differ in the no ol waler
molecules attached to metal atom Ifonas
ligands are Called hydrate Somers.
Lor cnod) ly [Orch ore] et, HO ‘
Violet (blue) 4a
a) Lin in kage Dsomerigms: .
[— by the Gorpouinds Conte
Am bidentate ti igand whith Can attach. bh, ;
the metal through more line Gap doa
alom. i
[co.eno) Mads tty [C0 Cond) CNHI) cto
u) Co-ordination Ocomerirr
|| This ‘ype of Deomeritm Oteurt When bat
“positive and negative tanto of ,a ¢alt are
"Complex tone and) two. ‘Somers differ tn
~~ the Aravibutton' ot leg ance jo two Complexe
Eq’ [Co (NHS) fer conde]), anid Y
Lov ONHs)¢) (cocende) rors nai 4
Stereo iSomerigm!
Dt cari set becaute of the dif terence
he Arrange ment ot ligand in Space
is around the metalton
@ scanned with OKEN Scanner 71) geomet ee SE ths rank dkomerism
[Nher two tdentreal groups “occupy
adjacent positions, the isomer it called
when arranged opposile Jo one
Choa, oF
another thiad..'somer i¢ Called trans. Pt
Pr, not shown by Complenes ne
Goin ay 3 ty 5S Common a) Square!
planar and octahedral Compe xer«
Square planar complex: MA,x, » PIABK,,
PIA XY,
Octahedval Complexes: # MAY, » MIA 3%.
Geometrical Psomer'sm 9 Complexe aaith
ee
——
Copdination number q.
tei
i) Tetrahedral Comple net do not Show geome’
jc fgomer som
) Dayuare’ planay Complexes of ee lall (mets)
ne and bare unidenla fale) Show geome bvical
“the two X Iegande may be
ty each other ina Gs
to each other. in @ trans
isomerism -
ovranged adjacent
‘Somer, oF oppessts
Bsc mer:
mer ob
: Ha nis, we
BE 4.
4 Ny
ob Ch Avons
@ scanned with OKEN Scanner ti) Aepuare’ Planar Complex ot the type (Magy
(Where AiB,x,L are Uniden tate ligands) hewn
three ‘Somers ,two Cis and one trang.
fg: Let ening) cbr) Cer Cry].
Geometrical sgorneriim in _Complener ith
Coordination number 6.
Octohedral Complexes of formula [Mau) tn
whith the two x legands nay be oriented
crs and trans to each other,
+
eg: [co CNH) Cid
L
x
L L bi
Od
iL I un ite
»
Trans
formula (Mx. A], when
Octahedral Complexet of
; di and A are didental
Xo are unidentate ligan
; md ar SSomerc. 4
oe dorm Civ a J ant mere :
Leotk, (én),). q
:
Bh ee Complexes of formula (Mase),
dhree donor atom of . the Same Inqanel
if
jacent position ¢ al the Co¥nere ofan
occupy ad
ttahedral face, 1 18 frown ax facial Gat)
Komer, When the positions are around the
tridian of the Octahedron, it is known as
@ scanned with OKEN Scanner Tmneridional SEV, Hiomey :
£4: {co (NH), (NO, ), J
ue nie Noo Ov vay
|Z
1/0. NOL
Wo Oy
dae
ii) Optical ‘Sorner {gras
Ahe Coraplenes, port: which
when mirvoe
onone,¢
“These. ave have
QA ovites
be Supe rirnp osed
ave Ca Wed
ove called dexto
chiral Ghruclare
irna.g es cannot
anothers These mirror
the ‘4wo forres
imna.get
enantiomers
[acevo () forms
wilh formula [ml inn),)?
nh
(d) and
letrohedral Cornplexet
jLormers
form) eahibit oplicoal
Show optical and olahedral
eet (ois
Leviton oe
¥
Valence Bond Theory (ver). Foe
The. theory was propoed by 1 Fauling on y
5
this hrory when 4
19261. Arcording iD
metol ‘onlatom
formed the
crowd arp ly orbilals to the Gur rounding
= “a
@ scanned with OKEN Scanner
oinpleyr is
p Bart Coordination num ber Shouse the nurs
Ri Such empty orbitals, ie number of rnp
orbital: is qual fe the Coordi natin
These empty ovbilals hybridised bet
ation in bonding and the nature of q
ridisation depend: cn othe valure oF racial
don the rvlue of Gpproaching Tigaind. —
nurrber.
€ pe vie Ge
Taner orbital Comple xet or outer orbital
Corp lexer i
When outer d-orbital are. uted in bonding
the Complexes are Called outer” orbital f
t zak
Compleret Le Gre formed dug ° Geo!
be | gard or high Spin ligand: Gn
, ; oh 1
+ have Octahedral
hy brid cation iy spid-- They iy :
|
Shape
then d-ovbitale ot (n-) Shell are uted,
these &7e%
known Gt inner fae Corepleny
dormed dué to Strong Feld liga nd:
ligand: and bbc on rs
a
: a are alto Sttahedral in Shape.”
op
@ scanned with OKEN Scanner Formula Macanil
of Electronic configuration ne
complex °
IM(CN) 1) GREECE +2 |d’sp?— | Octahedral Paramagnetic|
(nner)
[MnCi,)- THANE +2 sp? ‘Tetrahedral Paramagnetic|
[Cuct, > RI & +20 Isp? Tetrahedral Paramagnetic|
[PdBr,]?- MT] EE +2 dsp? Square Diamagnetic
planar
[CrNH,), P+) GT alle} +3 @sp3 | Octahedral Paramagnetic|
(nner)
(c0.1*| GEER EIE ae +3 d@sp}— | Octahedral Paramagnetic|
26) 8!
(Inner)
(Fe(CN),J* | FURIE +2 asp? | Octahedral Diamagnetic
6 2
(nner)
(Fe(H,0),* | aT ICEEICEI] +2 sp*d?_— | Octahedral Paramagnetic|
(Outer)
[Fe(CN) | ETT [sa] +3 @sp? | Octahedral Paramagnetic
(inner)
[Fe(Co),] GREE 0 dsp? | Trigonal Diamagnetic
bipyramidal
(inner)
SS
@ scanned with OKEN Scanner
