SAFETY DATA SHEET Nissan Chemical Industries

according to Regulation (EC) No. 1907/2006 Ltd.

NISSAN T.C.C.A. GRANULAR
Revision Date . .201 Version 1.1 GB / EN

1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name : NISSAN T.C.C.A. GRANULAR

Chemical Name : symclosene

CAS-No. : 87-90-1
Index-No. : 613-031-00-5
EC-No. : 201-782-8
Registration number : no data available

1. Details of the supplier of the safety data sheet

Company : Nissan Chemical Industries Ltd.

Chemicals Division
Kowa Hitotsubashi Building, 7-1, Kanda-Nishiki-cho 3-chome,
Chiyoda-ku
Tokyo,
Japan
Telephone : +81-3-3296-8025

E-mail address : [email protected]

1. Emergency telephone number

+81-3-3296-8025 (9:00-17:00, JST)

2. Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)
Oxidizing solids, Category 2 H272: May intensify fire; oxidiser.
Acute toxicity, Category 4 H302: Harmful if swallowed.
Eye irritation, Category 2 H319: Causes serious eye irritation.
Specific target organ toxicity - single ex- H335: May cause respiratory irritation.
posure, Category 3
Acute aquatic toxicity, Category 1 H400: Very toxic to aquatic life.
Chronic aquatic toxicity, Category 1 H410: Very toxic to aquatic life with long lasting
effects.
Classification (67/548/EEC, 1999/45/EC)
Dangerous for the environment R50/53: Very toxic to aquatic organisms, may
cause long-term adverse effects in the aquatic
environment.

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SAFETY DATA SHEET Nissan Chemical Industries
according to Regulation (EC) No. 1907/2006 Ltd.
NISSAN T.C.C.A. GRANULAR
Revision Date Version 1.1 GB / EN

Oxidising R 8: Contact with combustible material may cause

fire.

R31: Contact with acids liberates toxic gas.

Irritant R36/37: Irritating to eyes and respiratory system.

Harmful R22: Harmful if swallowed.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms :

Signal word : Danger

Hazard statements : H272 May intensify fire; oxidiser.

H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting
effects.

Supplemental Hazard : EUH031 Contact with acids liberates toxic gas.

Statements
Precautionary statements : Prevention:
P210 Keep away from heat.
P221 Take any precaution to avoid mixing with
combustibles.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/
eye protection/ face protection.
Response:
P304 + P340 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable
for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with wa-
ter for several minutes. Remove contact
lenses, if present and easy to do. Continue
rinsing.

Labelling according to EC Directives: 67/548/EEC

Hazard symbols :

Oxidising Harmful Dangerous

for the envi-
ronment

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SAFETY DATA SHEET Nissan Chemical Industries
according to Regulation (EC) No. 1907/2006 Ltd.
NISSAN T.C.C.A. GRANULAR
Revision Date Version 1.1 GB / EN

R-phrase(s) : R8 Contact with combustible material may

cause fire.
R22 Harmful if swallowed.
R31 Contact with acids liberates toxic gas.
R36/37 Irritating to eyes and respiratory system.
R50/53 Very toxic to aquatic organisms, may
cause long-term adverse effects in the aq-
uatic environment.

S-phrase(s) : S8 Keep container dry.

S26 In case of contact with eyes, rinse imme-
diately with plenty of water and seek medi-
cal advice.
S41 In case of fire and/or explosion do not
breathe fumes.
S60 This material and its container must be
disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to
special instructions/ Safety data sheets.

2.3 Other hazards

no data available

3. Composition/information on ingredients
3.1 Substances
The product is a chemical substance within the meaning of the REACH Regulation (1907/2006/EC).
The following table contains the main constituent at the top.
Further dangerous ingredients are mentioned when it is necessary in accordance with Appendix II
No. 3.1 of the REACH Regulation.

Chemical Name CAS-No. EC-No. Index-No.

Registration number
symclosene 87-90-1 201-782-8 613-031-00-5

4. First aid measures

4.1 Description of first aid measures

General advice : In the case of accident or if you feel unwell, seek medical ad-
vice immediately (show the label where possible). First aider
needs to protect himself. Move out of dangerous area. Never
give anything by mouth to an unconscious person. Take off
contaminated clothing and shoes immediately.

If inhaled : If breathed in, move person into fresh air. If symptoms persist,
call a physician. Keep patient warm and at rest. If not breath-
ing, give artificial respiration. If breathing is difficult, give oxy-
gen.

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SAFETY DATA SHEET Nissan Chemical Industries
according to Regulation (EC) No. 1907/2006 Ltd.
NISSAN T.C.C.A. GRANULAR
Revision Date Version 1.1 GB / EN

In case of skin contact : Wash off with plenty of water. Do NOT use solvents or thin-
ners. If skin irritation persists, call a physician.

In case of eye contact : Protect unharmed eye. If easy to do, remove contact lens, if
worn. In the case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.

If swallowed : If swallowed, seek medical advice immediately and show this

container or label. If swallowed, DO NOT induce vomiting. If a
person vomits when lying on his back, place him in the recov-
ery position.

4.2 Most important symptoms and effects, both acute and delayed
no data available

4.3 Indication of any immediate medical attention and special treatment needed
no data available

5. Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media : Water

Unsuitable extinguishing : Dry chemical

media

5.2 Special hazards arising from the substance or mixture

Specific hazards during fire : Hazardous decomposition products may be formed under fire
fighting conditions (see section 10). Exposure to decomposition prod-
ucts may be a hazard to health.

5.3 Advice for firefighters

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters Use personal protective equipment.

Further information : Standard procedure for chemical fires. The product itself does
not burn. Use extinguishing measures that are appropriate to
local circumstances and the surrounding environment. Keep
people away from and upwind of spill/leak. In the event of fire
and/or explosion do not breathe fumes. Collect contaminated
fire extinguishing water separately. This must not be dis-
charged into drains. Fire residues and contaminated fire ex-
tinguishing water must be disposed of in accordance with local
regulations.

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SAFETY DATA SHEET Nissan Chemical Industries
according to Regulation (EC) No. 1907/2006 Ltd.
NISSAN T.C.C.A. GRANULAR
Revision Date Version 1.1 GB / EN

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Refer to protective measures listed in sections 7 and 8. Use personal protective equipment. Avoid
dust formation. Avoid breathing dust. Avoid contact with skin and eyes. Ensure adequate ventilation,
especially in confined areas. Immediately evacuate personnel to safe areas.

6.2 Environmental precautions

Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes
or drains inform respective authorities. Avoid release to the environment. Refer to special instructions/
Safety data sheets.

6.3 Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Use mechanical handling equipment. Do not flush
with water. Clean contaminated surface thoroughly.

6.4 Reference to other sections

see chapter: 7, 8, 11, 12 and 13

7. Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : For personal protection see section 8. Avoid creating dust. Do
not breathe dust. Avoid contact with skin and eyes. Use ap-
propriate container to avoid environmental contamination.
Protect from contamination.

Advice on protection against : Normal measures for preventive fire protection. Keep away
fire and explosion from heat and sources of ignition. Do not smoke.

Dust explosion class : no data available

7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage : Store in a place accessible by authorized persons only. Store
areas and containers in original container. Keep containers tightly closed in a dry,
cool and well-ventilated place. Protect from moisture. Keep
away from heat. Keep away from direct sunlight.

Advice on common storage : Never allow product to get in contact with water during sto-
rage. Keep away from food, drink and animal feedingstuffs. Do
not store near combustible materials. Incompatible with bases.
Keep away from reducing agents. Incompatibility/reactions to
different substances.

Other data : No decomposition if stored and applied as directed.

7.3 Specific end uses

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SAFETY DATA SHEET Nissan Chemical Industries
according to Regulation (EC) No. 1907/2006 Ltd.
NISSAN T.C.C.A. GRANULAR
Revision Date Version 1.1 GB / EN

no data available

8. Exposure controls/personal protection

8.1 Control parameters

Contains no substances with occupational exposure limit values.

Other information on limit values: see chapter 16

8.2 Exposure controls

Engineering measures
Provide sufficient air exchange and/or exhaust in work rooms.

Personal protective equipment

Respiratory protection : Respirator with combination filter for vapour/particulate (EN
141).
Respirator with filter type ABEK

Hand protection

Remarks : Choose gloves to protect hands against chemicals depending

on the concentration and quantity of the hazardous substance
and specific to place of work. For special applications, we
recommend clarifying the resistance to chemicals of the
aforementioned protective gloves with the glove manufacturer.

Eye protection : Wear eye/face protection.

Skin and body protection : Choose body protection according to the amount and concen-
tration of the dangerous substance at the work place.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.
General industrial hygiene practice.
Do not breathe dust.
Avoid contact with skin, eyes and clothing.
When using do not eat, drink or smoke.
Wash hands before breaks and at the end of workday.
Follow the skin protection plan.
Wash contaminated clothing before re-use.

Environmental exposure controls

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SAFETY DATA SHEET Nissan Chemical Industries
according to Regulation (EC) No. 1907/2006 Ltd.
NISSAN T.C.C.A. GRANULAR
Revision Date Version 1.1 GB / EN

General advice : Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Avoid release to the environment. Refer to special instruc-
tions/ Safety data sheets.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : Crystalline solid
Colour : white
Odour : Chlorine
Odour Threshold : no data available
Flash point : does not flash
Ignition temperature : no data available
Lower explosion limit : no data available
Upper explosion limit : no data available
Explosive properties : Not explosive

Flammability (solid, gas) : no data available

Oxidizing properties : Oxidising

Autoignition temperature : not auto-flammable

Burning number : no data available
Molecular Weight : no data available
pH : 2,7 - 3,3 at 25 °C
Concentration: 1,00 g/l

Melting point/range : ca. 225 °C

Boiling point/boiling range : not applicable

Vapour pressure : no data available
Density : no data available
Bulk density : no data available
Water solubility : 10 g/l at 25 °C

Partition coefficient: n- : no data available

octanol/water
Solubility in other solvents : no data available
Viscosity, dynamic : no data available
Viscosity, kinematic : no data available
Flow time : no data available
Impact Sensitivity : no data available
Relative vapour density : no data available
Surface tension : no data available
Evaporation rate : no data available
Minimum ignition energy : no data available
Acid number : no data available
Refraction index : no data available
Miscibility in water : no data available
Solvent separation test : no data available

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SAFETY DATA SHEET Nissan Chemical Industries
according to Regulation (EC) No. 1907/2006 Ltd.
NISSAN T.C.C.A. GRANULAR
Revision Date Version 1.1 GB / EN

9.2 Other information

None known.

10. Stability and reactivity

10.1 Reactivity
no data available

10.2 Chemical stability

The product is chemically stable.

10.3 Possibility of hazardous reactions

Stability: No decomposition if stored and applied as directed.
Contact with combustible material may cause fire. Contact with acids liberates toxic gas.

10.4 Conditions to avoid

Heat, flames and sparks. Exposure to moisture.

10.5 Incompatible materials

Materials to avoid : Water, Organic Substances, Amines, Ammonium salts, organ-
ic nitro compounds, Hypochlorites, Oxidizing agents, Acids
and bases, Reducing agents

10.6 Hazardous decomposition products

Hazardous decomposition : In case of fire hazardous decomposition products may be
products produced such as:

Chlorine, Hydrogen chloride gas, nitrogen oxides (NOx), Bo-

ron compounds, Carbon monoxide, carbon dioxide and un-
burned hydrocarbons (smoke).

Other hazardous decomposition products may be formed.

Thermal decomposition : > 225 °C

11. Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Acute oral toxicity:

symclosene : LD50 (rat): 490 mg/kg

Acute inhalation toxicity:

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SAFETY DATA SHEET Nissan Chemical Industries
according to Regulation (EC) No. 1907/2006 Ltd.
NISSAN T.C.C.A. GRANULAR
Revision Date Version 1.1 GB / EN

symclosene : LC50 (rat): > 50 mg/l

Exposure time: 1 h

Acute dermal toxicity:

symclosene : LD50 (rabbit): > 2.000 mg/kg

Acute toxicity (other routes of administration):

no data available

Skin corrosion/irritation
symclosene : Species: rabbit
Skin irritation

Serious eye damage/eye irritation

symclosene : Species: rabbit
Risk of serious damage to eyes.

Respiratory or skin sensitization

Sensitisation:

no data available

Germ cell mutagenicity

Genotoxicity in vitro:

no data available

Carcinogenicity
no data available

Reproductive toxicity
no data available

Teratogenicity
no data available

STOT - single exposure

no data available

STOT - repeated exposure

no data available

Aspiration hazard
Aspiration toxicity

no data available

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SAFETY DATA SHEET Nissan Chemical Industries
according to Regulation (EC) No. 1907/2006 Ltd.
NISSAN T.C.C.A. GRANULAR
Revision Date Version 1.1 GB / EN

Neurological effects
no data available

Toxicology Assessment
Toxicology, Metabolism, Distribution

no data available

Acute effects

no data available

12. Ecological information

12.1 Toxicity
Toxicity to fish

symclosene : LC50 (Lepomis macrochirus (Bluegill sunfish)): 0,3 mg/l

Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates.

symclosene : EC50 (Daphnia magna (Water flea)): 0,21 mg/l

Exposure time: 48 h

12.2 Persistence and degradability

no data available

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Results of PBT and vPvB assessment

no data available

12.6 Other adverse effects

Additional ecological informa- : The product should not be allowed to enter drains, water
tion courses or the soil.

13. Disposal considerations

13.1 Waste treatment methods

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SAFETY DATA SHEET Nissan Chemical Industries
according to Regulation (EC) No. 1907/2006 Ltd.
NISSAN T.C.C.A. GRANULAR
Revision Date Version 1.1 GB / EN

Advice on disposal and : Disposal:

packaging In accordance with local and national regulations. This materi-
al and its container must be disposed of as hazardous waste.
Do not dispose of together with household waste.
Waste codes should be assigned by the user based on the
application for which the product was used.

14. Transport information

ADR
UN number : 2468
Description of the goods : TRICHLOROISOCYANURIC ACID, DRY
Class : 5.1
Packing group : II
Classification Code : O2
Hazard identification No : 50
Labels : 5.1
Limited quantity : LQ11
Tunnel restriction code : (E)
Environmentally hazardous : yes

RID
UN number : 2468
Description of the goods : TRICHLOROISOCYANURIC ACID, DRY
Class : 5.1
Packing group : II
Classification Code : O2
Hazard identification No : 50
Labels : 5.1
Limited quantity : LQ11
Environmentally hazardous : yes

IATA
UN number : 2468
Description of the goods : Trichloroisocyanuric acid, dry
Class : 5.1
Packing group : II
Labels : 5.1
Packing instruction (cargo : 562
aircraft)
Environmentally hazardous : no
Packing instruction (passen- : 558
ger aircraft)
Packing instruction (LQ) : Y544

IMDG
UN number : 2468
Description of the goods : TRICHLOROISOCYANURIC ACID, DRY

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SAFETY DATA SHEET Nissan Chemical Industries
according to Regulation (EC) No. 1907/2006 Ltd.
NISSAN T.C.C.A. GRANULAR
Revision Date Version 1.1 GB / EN

Class : 5.1
Packing group : II
Labels : 5.1
EmSNumber 1 : F-A
EmS Number 2 : S-Q

Marine pollutant : yes

Special precautions for user

see chapter: 6, 7 and 8

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Directive 96/82/EC : Update: 2003 Quantity 1 Quantity 2
Oxidising 50 t 200 t

Update: 2003
Dangerous for the envi- 100 t 200 t
ronment

Further information : Reserved for industrial and professional use.

15.2 Chemical Safety Assessment

no data available

16. Other information

Full text of R-phrases referred to under sections 2 and 3
R8 Contact with combustible material may cause fire.
R22 Harmful if swallowed.
R31 Contact with acids liberates toxic gas.
R36/37 Irritating to eyes and respiratory system.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.

Full text of H-Statements referred to under sections 2 and 3.

H272 May intensify fire; oxidiser.
H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

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SAFETY DATA SHEET Nissan Chemical Industries
according to Regulation (EC) No. 1907/2006 Ltd.
NISSAN T.C.C.A. GRANULAR
Revision Date Version 1.1 GB / EN

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not to
be considered a warranty or quality specification. The information relates only to the specific ma-
terial designated and may not be valid for such material used in combination with any other mate-
rials or in any process, unless specified in the text.

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