Waste Water Treatment Technologies and

Practices in Indian Pulp and Paper Industries

Dr. B. P. Thapliyal
Director

Central Pulp & Paper Research Institute

Saharanpur -247001 (U.P.) INDIA
Email : [email protected]
www.cppri.org.in
 Indian Paper Industry – A Brief
Number of Mills 850 +
Structure (operational mills ~ 600 mills) Small Scale (< 50 tpd) ~ 250
Medium Scale (50-100 tpd) ~ 150
Large Scale (Above 100 -1200 tpd) ~ 200
Total Installed Capacity (MMT) 25.00
Operating Installed Capacity (MMT) 21.50
Production of paper, board & newsprint (MTPA) 17.33
Consumption of paper, board & newsprint (MTPA) 19.35
Per capita consumption (KG) 13.2
Export (MMT)
Paper & Paper Board 0.97
Newsprint -
Import (MMT)
Paper & Paper Board 1.48
Newsprint 1.50

Ref : CPPRI Survey

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Indian Paper Industry

Diverse Diverse Diverse

Raw materials Processes Products
Packaging Papers &
15+ species of Wood Mechanical Pulping Coated/Uncoated
Paperboards

Coated/Uncoated Printing
Non-Woods: Bagasse, Rice Chemical Pulping – Kraft & Writing Papers
Straw, Wheat Straw, Process generally for wood
Grasses/ Reeds pulping
Newsprint & Magazine
Papers
Chemical Pulping – Soda
Waste Papers: White,
Process generally for Agro
Brown and Mixed
pulping Tissues & Hygiene Papers

Recycled Fibre (RCF)

Market Pulps Process – with or without Specialty Papers
De-Inking

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Technological Issues
Environmental Impacts
Mostly Second Hand

Obsolescence  High effluent load

in technology
Not Designed for  High Colour in effluent
Processing Mixed Raw
material  High level of COD, BOD &
AOX
 Black liquor management
Non availability of (agro based)
sufficient raw material
 High resource
Limited scale
of operation consumption
High Capital  High cost of basic inputs
Investment due to
imported origin

Restricts Adoption of State of Art Technology

Becomes uncompetitive in global market

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Technological Issues
Low cost of water

Lack of optimum performance of pulp washers.

Carrying out of most operations at high dilution.

Lack of water audit / water balance / assessment of optimum water requirement

Major
reasons for Lack of optimization of washer requirement on decker, pulp washers & paper m/c
high water
consumption
Lack of fiber recovery units or low performance of existing fiber recovery units

Lack of adequate ETP facilities

Mental block in reuse / recycle of treated effluent / back water

Lack of awareness, trained manpower and monitoring facilities

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ETP in Indian Paper Industry

Effluent Treatment
Process Employed in
Indian Paper Industry

Aerobic Anaerobic Tertiary

For Treatment of Combined For Pretreatment of High Polishing the Quality of
Effluent Strength Agro residues Raw Treated Effluent and meet
Material Washings and Pre- Stringent Norms in Ganga
hydrolysis Liquor River Basin
• Chemical Treatment
• Physical treatment: Sand Filter,
Dual Media Filter , Activated
carbon Filter

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Major Regulatory Agencies in India
National Level: Central Pollution Control Board;
State level: State Pollution Control Boards
Parameter Discharge Standards
General Standards CPCB – Pulp & Paper Mills
Small Scale Large Scale
Volume, m3/t - Agro based :200 (150)* Writing & Printing: 200 (100)*
Waste Paper: 75 (50)* Rayon grade/ News print: 150
pH 5.5-9.0 5.5 –9.0 7.0 - 8.5
BOD5 at 200C mg/l 30 (Inland surface water) 30 (inland discharge) 30
350 (Public Sewer on land discharge) 100 (on land discharge)
100 (Land for irrigation )
100 (Marine / Coastal areas)
COD, mg/l 250 (inland surface water ) Not specified 250
-(Public Sewer on land discharge)
-( Land for irrigation )
250 (Marine / Coastal areas )
SS, mg/l 100 (inland surface water ) 100 50
600 (Public Sewer on land discharge)
200 (Land for irrigation )
TOCl, kg/t paper - Not specified 2.0
AOX - 2.0 1.0
SAR - 26 -

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General Effluent Treatment Practices in Indian Paper Industry
Activated Sludge Process:

Primary Treatment Secondary Treatment

Influent Primary Secondary Final discharge

Aeration Tank
Clarifier Clarifier

Sludge Return
Sludge
Dewatering
Sludge Wasting

Limitations of Biological Treatment Process :

 Biological system i.e. ASP is effective for removal of degradable compounds contributing
BOD .
 Around 85-90 % of the total COD in finally treated effluent is mainly due to bio refractory
compounds like degraded lignin , extractives etc.
 Not able to reduce the colour and TDS of the effluent

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Biological Nature of Oxygen Consuming Pollutants

COD

Easily Biodegradable Slowly Biodegradable Resistant

(Free sugar, carbohydrates , (fibers, fines , (degraded lignin related
sugars, acids etc.) polysaccharides etc) compounds,)

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Need for Tertiary Treatment Options

 To meet the water consumption and discharge norms

 Primary & Secondary Treatment Measures – effective for pollution reduction but
not effective to treat waste water for reuse into the process

 Need to adopt tertiary treatment options to treat waste water up to a level

making it suitable for reuse into the process

 Selection of tertiary treatment option depend upon the end application of

treated effluent

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Stringent Environmental Norms
• Specifically for Pulp & Paper Mills in River Ganga Basin
• New Environmental Norms on same lines likely to be introduced soon on National Level

Waste Water Discharge

Fresh Water Consumption
Mill Category m3 /t paper
m3 /t paper

A1 ( Wood Bld.) 50 40

A2 ( Wood unbld) 25 20
B1 ( Agro Bld) 50 40
B2 ( Agro Kraft )
25 20

C1( RCF Bld ) 15 10

C2 ( RCF Kraft) 10 6
D ( Splty Paper) 50 40

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Stringent Environmental Norms
• Specifically for Pulp & Paper Mills in River Ganga Basin
• New Environmental Norms on same lines likely to be introduced soon on National Level

Discharge norms for Integrated

Discharge norms for RCF based Mills
Parameters Pulp & Paper Mills Producing
Chemical Pulp
pH 6.5-8.5 6.5-8.5

TSS,mg/l < 30 < 30

TDS, mg/l < 1800 < 1600

COD, mg/l < 200 < 150

BOD , mg/l < 20 < 20

Colour , PCU < 250 < 150

AOX , mg/l <8 -
SAR < 10 <8

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Stringent Environmental Norms

Resource Conservation Regulatory Pressure

• Less availability of • Environmental
Need for Water
surface water Compliance
Conservation / Water
• Declining level of • Disposal Problem- Less
Circuit Closure
ground water availability of river water
for dilution
• Improved quality of
treated effluent

Cost Economics
• High Water Cess
• High raw water and waste
water treatment cost
• Energy Conservation

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 Tertiary Treatment (EOP)

Carbon Filter / Dual Media Filter /

Chemical Treatment etc
Carbon Filter / Dual Media Filter / + Ultrafiltration + Nano Filtartion +
Chemical Treatment etc for polishing
OR
Reverse Osmosis for recovery of
Effluent Quality / partial reuse / recyle process / industrial grade water
of waste water to meet the discharge
norms

Primary Treatment Secondary Treatment

Influent Primary Secondary Waste Water

Aeration Tank
Clarifier Clarifier

Sludge Return
Sludge
Dewatering
Sludge Wasting

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Fiber Recovery Units for Back water Reuse & Recycling &
Reducing Pollution Load to ETP

DAF Units Spray Filter Sedicell

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Filters as Tertiary Treatment Options for Reuse & Recycling of
Treated Effluent

Activated Carbon Filter Micron Filter Pressure Sand Filter

Dual Media Filter Multi Media Filter

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Real Time On line Monitoring of Treated Effluent Quality -
Mandatory for Indian Paper Industry

All the monitors are linked to Central Server of Regulatory Bodies

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 Anaerobic Bioreactor Configuration in Indian Paper Industry
Biogas Benefits of Bio-methanation:
• Reduce pollution load to
subsequent ETP
Effluent
• Co-generation of energy as biogas
Gas rich in methane
collection
dome • Recovery of Biogas reduces GHG
emission responsible for global
warming
• Benefits of Carbon Credits
Sludge
Influent

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Recent Trends in Indian Pulp & Paper Mills for Improved
Environmental Management

Installation of Borewell Flow meter/ Setting up of ETP Lab & Trained manpower
Electronic Flow meter

Installation of Paper Machine Showers of Installation of On line Monitoring system

Specified Diameter

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Recent Trends in Indian Pulp & Paper Mills for Improved
Environmental Management

Installation of Chemical recovery System by Agro Installation of Tertiary Treatment System

Based Mills

Installation of Diffused Aeration System Installation of Fiber Recovery System

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Way Forward

Membrane Systems - Treated Effluent Process Water Quality ZLD

Ultra filtration Reverse Osmosis

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Requirements of Indian Paper Industry

 Cost effective and techno-economic alternative treatment options

 Cost effective color and TDS removal technologies

 Solid waste disposal and management or conversion to value added products

 Demonstration of such technologies on pilot/mill scale

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 Thank You
ありがとうございました

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