Hydrogen Fuel in IC Engines Seminar
Hydrogen Fuel in IC Engines Seminar
BACHELOR OF ENGINEERING
IN
MECHANICAL ENGINEERING
BY
SUNEEL P SHIRAGAR
(1SI21ME447)
Dr. Jatadhar G. S
Assistant Professor
CERTIFICATE
This is to certify that the Technical Seminar entitled “Hydrogen fuel used in IC engine ” is
carried out by Suneel P Shiragar (1SI21ME447) bonafide students of Siddaganga Institute of
Technology, Tumakuru. Have submitted in partial fulfillment of the requirement for the award of
Bachelor of Engineering in Mechanical Engineering of Visvesvaraya Technological University,
Belagavi during the year 2023-24. It is certified that all corrections/suggestions indicated for
Internal Assessment have been incorporated in the report and same is deposited in the
departmental library. The Technical Seminar report has been approved as it satisfies the academic
requirements in respect of Technical seminar prescribed for the said degree.
Shri. Jatadhar G. S
Assistant Professor Dr. U S Mallikarjun
Guide HOD
Examiners:
1. .........
2. .........
ACKNOWLEDGEMENT
First and foremost, I would like to extend my sincere gratitude to our holiness Dr. Sree
Sree Shivakumara Swamigalu and Sree Siddalinga Swamigalu who are the fore
runner of the Siddaganga Society. Everything would have been impossible without his
omnipresent blessings bestowed on us.
This project would not have been realized without the consistent encouragement of
Dr.U S Mallikarjun, Head of Department of Mechanical Engineering. He was always
a pillar of support who was never exhausted to assist us at any time.
Regards
Suneel P Shiragar ( 1SI21ME447)
CONTENTS
5 Conclusion 16
6 Reference 17
Abstract
Hydrogen as a fuel in Internal Combustion engines is a solution for the near future to realize zero
CO2 emissions for traffic applications. The hydrogen fuelled IC engine is ready for that. The
storage and production of hydrogen, and to build the necessary infrastructure, are the real
shortcomings in the general use of hydrogen in IC engines. This overview indicates the evolution
in the development of hydrogen fuelled engines (different generation of engines). This evolution
is also made at Ghent University. Ghent University has been working for nearly 15 years on the
development and optimization of hydrogen engines. Several test rigs are in function (all with
electronic control management systems and sequential multi-point injection).
Keywords - IC engines; hydrogen; emissions; backfire
CHAPTER 1
INTRODUCTION
Hydrocarbon fuels have been taking the world by storm in power and propulsion generation for
over a century. An increase in the number of rules and regulations imposed onto exhaust emissions,
alongside with the possibility of the depletion of non-renewable fuels have been a driving force
that propels research in looking for alternative sources of fuels
[1]. Thus, a wide list of fuels which are known to leave a less impactful carbon footprint on the
environment have been suggested as a substitute for hydrocarbon fuels
[2]. Among these suggested fuels, hydrogen was found to be renewable and less polluting to the
environment, combined with its clean burning effect which emits no carbon dioxide into the
atmosphere upon combustion, hydrogen fuels have been a topic of interest since it also delivers
great performance
[3]. There are several crucial properties of hydrogen that immensely impact the technological
development of an internal combustion engine.
When contrasted against other fuels, hydrogen evidently displays a wide range of flammability
which ranges from 4 – 75% volume in air. Such a drastic range of flammability is a major concern
when handling hydrogen. However, this also implies that it is possible to obtain a lean fuel-air
mix which means that the mix consists of an amount of fuel that is less than the chemically ideal
amount. An engine that functions on a lean air-fuel mix makes it possible to achieve a greater fuel
economy because the fuel undergoes complete combustion. Besides that, the combustion
temperature of the fuel is reduced, causing a decrease in the emissions of pollutants [4].
Hydrogen is known to have a minute quenching distance of just 0.6mm. This quenching distance is
the actual distance originating from the internal cylinder wall in which the flame of combustion is
extinguished. This proves that it would be more of a hassle to extinguish a hydrogen flame as the
chances of backfiring are higher considering that the flame readily passes through an almost closed
intake valve . Hydrogen also ignites with a great flame speed. Thus, such a feat makes it possible
for hydrogen engines to function close to a thermodynamically ideal engine cycle during the
scenario in which a chemically ideal fuel mix is utilised. Flame speeds however, slow down
drastically when a lean fuel mix is used . Adiabatic flame temperature and flame velocity are 1
two important factors for engine control and operation, in certain thermal efficiency, emissions
and combustion stability.
Great Diffusivity
Hydrogen is found to have a very high level of diffusivity which is greater than gasoline. Thus,
this proves to be an advantage for two reasons. The first being that it encourages the formation of
an air-fuel mixture that is uniform. Besides that, when a hydrogen leak occurs, the hydrogen
disperses quickly. Therefore, risky conditions can be reduced .
Low Density
The most crucial effect of having a low density is that hydrogen requires a certain amount of
compression or conversion to liquid, if not, a very great volume will be required to store enough
hydrogen to power a vehicle. This low density of hydrogen also implies that the air-fuel mix has
low density of energy. Thus, a larger amount of hydrogen is needed to produce the same amount
of energy needed to run a vehicle when compared to other fuels .
Methane 540-630
Propane 450
Octane 415
Methanol 460
Hydrogen 585
3
HYDROGEN AS A FUTURE FUEL
Hydrogen is recognized for its special characteristics, making it one of the most resourceful
alternatives to fossil fuel in this current era. Hydrogen is easily sourced as it is one of the most
abundant elements present in the environment . This element is also used in several applications
in the industry, being a source of fuel to generate power for machines. Hydrogen has been
recommended to be a future fuel due to its many advantages, one of it being that it is a form of
renewable energy that can be quickly replenished and is also non-polluting to the environment
Production of Hydrogen
In order to obtain hydrogen, it must first be separated from other elements which are present
together with it in a mixture. Hydrogen can be obtained from various sources such as
hydrocarbons, natural gas, biomass and water. Below are the various ways to obtain hydrogen.
For a scenario in which oxygen is too little to completely oxidise the methane, the reaction is
said to be partially oxidised. Thus, this process gives off heat seeing that it is exothermic. This
partial oxidation reaction is also much quicker than standard steam reforming processes and
needs a much smaller vessel for reaction, however it produces less hydrogen for the same amount
of fuel used when compared to the standard steam methane reformation process.
Partial oxidation of methane equation of reaction:
1
4 + ⁄2 2 → + 2 2 (+ℎ ) 4
Electrolysis
This is a process of utilising electricity to divide water molecules into hydrogen and oxygen.
Such a reaction is done in an electrolyser that can come in various sizes depending on the
amount of hydrogen that needs to be produced. An electrolyser consists of a cathode and an
anode that is separated through the means of an electrolyte. Below are a few commonly used
electrolytes along with their electrolysers.
Polymer Electrolyte Membrane Electrolysers
The electrolyte of such an electrolyser is a solid type of plastic material. The anode of the
electrolyser reacts with water to generate hydrogen ions which are positively charged. At the
cathode, the hydrogen ions receive electrons to create hydrogen gas.
+ −
4 +4 →2 2
Alkaline Electrolysers
These electrolysers function through the transportation of hydroxide ions across the electrolyte.
Alkaline electrolysers usually consist of electrolytes that contain either potassium hydroxide or
sodium.
Solid Oxide Electrolysers
These electrolysers use an electrolyte that is made from ceramic material in solid form. This
makes it possible for the electrolyte to selectively conduct oxygen ions that have been negatively
charged at high temperatures. Solid oxide electrolysers produce hydrogen differently from
conventional electrolysers because water reacts at the cathode and combines with electrons to
generate hydrogen gases, alongside oxygen ions that are negatively charged. The negatively
charged oxygen then goes through the electrolyte, causing a reaction at the anode to create oxygen
gas and electrons.
Coal Gasification
Coal is a highly adaptable substance that has many uses. Coal gasification is a means to
producing liquid fuels, hydrogen, chemicals and power. When coal is exposed to oxygen and
steam at high pressures and temperatures, synthesis gas is produced. This mixture is mainly
composed of hydrogen and carbon monoxide.
Unbalanced equation of reaction for coal gasification:
0.8 + 2 + 2 → + 2 + 2 + ℎ
Impurities present in the gas are removed and carbon monoxide mixture is exposed to more steam
to initiate a water-gas shift process that produces even more hydrogen and carbon dioxide.
Hydrogen is then removed from the mixture through a separation system. 5
Biomass Gasification
This is a process in which organic carbon-based materials are converted at high temperatures of
above 700 C under controlled conditions into hydrogen, carbon dioxide and carbon monoxide .
Carbon monoxide is once again able to react with water through the water-gas shift process to
form more hydrogen.
Since biomass does not turn to gas easily when compared to coal and it produces a mixture of
other compounds, an extra process must be introduced to the mixture. This process yields a
mixture of carbon monoxide, carbon dioxide and hydrogen in the presence of a catalyst. Then just
like the gasification process in the coal gasification reaction, carbon monoxide is introduced to
steam, and hydrogen is separated from the mixture and later purified.
6
Attention was given to a qualitative control of the load (variation of the richness of the hydrogen-
air mixture), beneficial for the engine efficiency compared to a quantitative control using a throttle
valve. Also injection duration and ignition maps were optimized, crankcase ventilation and
supercharging were applied – Sierens (1999), Sierens and Verhelst (2000).
A single cylinder CFR engine (fixed speed of 600 rpm, variable compression ratio) has been
initially equipped with a gas carburetor (first generation), then with a sequential injector (second
generation) and is now working with a sequential injector (and MoTeC control unit), exhaust gas
recirculation (EGR) and three way catalyst (third generation). Detailed studies are carried out:
•P c b c b c l (λ-value), compression
ratio, ignition timing etc.
• Influence of the position of the injector and start of injection on the power output and efficiency.
Exhaust gas recirculation (EGR) is an effective means for NOx reduction and an especially
interesting option at stoichiometric operation as the high NOx reduction efficiency of a standard
three-way catalyst (TWC) can then be exploited. Furthermore, one could vary the engine power
output by changing the amount of recycled exhaust gas, instead of throttling, thus avoiding engine
efficiency penalties.
Two more engines are now fully operated. A one- cylinder research engine from the, at
that time, Audi-NSU, and further referred to as Audi engine (engine speed 1000 – 4500 rpm).The
schematic arrangement of the engine test bench is seen in fig.
The engine is equipped with a high pressure transducer and two injectors (for one
cylinder). The ignition- and injection timing are controlled by a MoTeC M4 Pro control unit.
Initial results are given by Verstraeten et al. (2004). The same measurements and studies as for
the CFR engine will be carried out: pressure measurements, backfire studies, exhaust gas
recirculation, catalyst studies, supercharging.
The latest engine is a Volvo V40 engine, adapted for bi-fuel operation: gasoline or
hydrogen (ignition- and injection timing also controlled by a MoTeC control unit.
7
CHAPTER 2
LITRETURE REVIEW
Dr. R. HARI PRAKASH.[1] has indicated the advantages of hydrogen as a fuel for spark
ignited internal combustion engines and has shown that the hydrogen engine is growing up. An
overview is given of the development by car manufacturers and also of the research at the
laboratory of Transport Technology, Ghent University. Finally an extended overview is given of
the design features in which a dedicated hydrogen engine differs from traditionally
fuelled engines.
M. Faizal [2] The sources of energy to be used in the future will have to be cleaner and more
efficient than current sources. Hydrogen fuel accomplishes these criteria with relative ease. Many
challenges need to be solved before wide- spread hydrogen use can be feasible, these include
restrictions with size, cost, reliability and safety. Among other alternative fuels, hydrogen proffers
the best solution to reduction or complete elimination of hazardous vehicle emissions and their
environmental [Link] of efficient production, storage and distribution of hydrogen is
currently underway. This shows that there is a great prospect for hydrogen fuel in automobile.
Balu jinendor Shinde[3] The existing port and direct injection hydrogen engines are offering
good brake thermal efficiency in comparison with gasoline engines. The hydrogen properties are
more suitable for gasoline application, but it requires certain changes to make full utilisation of
hydrogen potential. For DI operation further research should continue to use late injection strategy
to perform near to ideal combustion. The efficiency losses such as compression work, improper
combustion and heat transfer to the
8
CHAPTER 4
METHODOLOGY
9
Inlet Manifold and Inlet Port Injection Method
Contrary to the fuel carburetion method, the inlet port injection method delivers the
hydrogen fuel directly to the intake manifold directly through mechanically or
electronically operated injectors, rather than drawing it in from the carburettor. At
the beginning of each intake stroke, hydrogen fuel is injected into the manifold with
the utilization of electronic injectors; which have quick responses under high speed
conditions to accurately control the injection timing and duration. Additionally, the
air is also injected separately during the beginning of the intake stroke to dilute the
hot residual gases which in turn lowers the temperature in the combustion chamber .
Throughout the engine cycles, less air-fuel mixture is held in the inlet manifold as
compared to the fuel carburettor engine; hence, the occurrence of pre-ignition has a
lower damaging impact. Among the three fuel induction methods, the inlet supply
pressure for port injections is higher than fuel carburettor engines but lower than
direct injection systems . On the other hand, lean operations can be achieved through
the port injection method by keeping the volume of inducted air constant in every
cycle, whereas the power output is controlled through the amount of fuel injected into
the chamber. This can be done by regulating the injection pressure of hydrogen or
manipulating the duration of injection through the injector signal pulse . For further
illustration, a schematic diagram depicting the operation of the port injection method
is shown in Figure.
10
Direct Injection Systems
Instead of using carburettors or port injectors, direct injection systems inject
hydrogen directly into the combustion chamber using high pressure at the end of
every compression stroke. The hydrogen is then forced to diffuse quickly and mix
with the air inside almost instantaneously, which will be ignited using a spark plug.
In this case, the main concern of having a drop in the power output can be eliminated
through in-cylinder ignition. Therefore, the direct hydrogen injection system is the
most efficient fuel induction technique among the other methods involving hydrogen
fuel. It has a power output of 20% more than a gasoline engine and 42% more than
hydrogen engines with a carburettor. Compared to a hydrogen engine which operates
in a pre-mixed state, injecting hydrogen fuel directly into the combustion chamber of
a compression ignition engine would result in twice the power output .Additionally,
11
CHAPTER 5
Fig 5.1 Power output of the Valmet engine fuelled with natural gas or hydrogen
12
It is clear that the Valmet engine with the gas carburetor is of the first generation. These tests have
proved that it is not difficult to run an engine on hydrogen (under lean conditions). But it has
shown at the same time that special attention is necessary for the power output, the NOx emissions
and the backfire problem. The original Valmet diesel engine has a power output of 64 kW, which
can be reached also with natural gas (CH ) but not at all with hydrogen conditions to avoid
backfire), see Fig. – Sierens (1992, 1993). Figure 3 shows the NOx emissions again for natural gas
and hydrogen – Sierens (1992, 1993). At a certain air-fuel ratio the NOx emissions for hydrogen
are higher than for natural gas ( l ). O l v l x (λ ≥ 2), l v l
becomes acceptably low.
The backfire phenomenon is shown in Fig. – Sierens and Rosseel (1998). Successive pressure
cycles are shown, indicating the runaway pre-ignition till finally the pre- ignition occurs before the
inlet valve closure (IVC) (cycle 32) resulting in the explosion of the mixture in the inlet manifold
APPLICATION
Petroleum refining
Glass purification
Semiconductor manufacturing
Aerospace applications
Fertilizer production
Welding, annealing and heat-treating metals
Pharmaceuticals
As a coolant in power plant generators
For hydrogenation of unsaturated fatty acids in vegetable oil.
14
ADVANTAGE
It is a clean fuel.
It is convenient for heavy transport and trains
It is environmental friendly
The combustion hydrogen does not produce of CO, CO2, oxides of nitrogen.
Better alternative of fossil fuels
Better emission control and less green house gas emission
DISADVANTAGE
15
CONCLUSION
This work has indicated the advantages of hydrogen as a fuel for spark ignited internal
combustion engines and has shown that the hydrogen engine is growing up. An overview is
given of the development by car manufacturers and also of the research at the laboratory of
Transport Technology, Ghent University. Finally an extended overview is given of the design
features in which a dedicated hydrogen engine differs from traditionally fuelled engine.
The sources of energy to be used in the future will have to be cleaner and more efficient than
current sources. Hydrogen fuel accomplishes these criteria with relative ease. Many challenges
need to be solved before wide- spread hydrogen use can be feasible, these include restrictions with
size, cost, reliability and safety. Among other alternative fuels, hydrogen proffers the best
solution to reduction or complete elimination of hazardous vehicle emissions and their
environmental effects. Efforts of efficient production, storage and distribution of hydrogen is
currently underway. This shows that there is a great prospect for hydrogen fuel in automobiles.
16
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Technical Paper, 1997.
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