000223 ROSE FLAVOUR

The Product Makers (Australia) Pty Ltd Chemwatch Hazard Alert Code: 3
Version No: 1.1 Issue Date: 17/09/2019
Safety Data Sheet according to WHS and ADG requirements Print Date: 17/09/2019
[Link]

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier
Product name: 000223 ROSE FLAVOUR
Proper shipping name: EXTRACTS, FLAVOURING, LIQUID
Other means of identification: Not Available

Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Use according to manufacturer's directions.

Details of the supplier of the safety data sheet Emergency telephone number
Registered company name The Product Makers (Australia) Pty Ltd Association / Organisation The Product Makers (Australia) Pty Ltd
Address 50 - 60 Popes Road Keysborough 3173 Australia Emergency telephone numbers 61 3 9771 0300
Telephone 61 3 9771 0300 Other emergency telephone numbers Not Available
Fax 61 3 9771 0301
Website [Link]
Email Not Available

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
ChemWatch Hazard Ratings
Flammability 3
Toxicity 1 0 = Minimum
1 = Low
Body Contact 2 2 = Moderate
Reactivity 0 3 = High
Chronic 3 4 = Extreme

Poisons Schedule Not Applicable

[1] Eye Irritation Category 2A, Flammable Liquid Category 2, Chronic Aquatic Hazard Category 3
Classification
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HCIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI

Label elements
Hazard pictogram(s)

SIGNAL WORD : DANGER

Hazard statement(s)
H319: Causes serious eye irritation.
H225: Highly flammable liquid and vapour.
H412: Harmful to aquatic life with long lasting effects.

Precautionary statement(s) Prevention

P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.

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000223 ROSE FLAVOUR

P241: Use explosion-proof electrical/ventilating/lighting/intrinsically safe equipment.

P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statement(s) Response

P370+P378: In case of fire: Use alcohol resistant foam or normal protein foam for extinction.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

Precautionary statement(s) Storage

P403+P235: Store in a well-ventilated place. Keep cool.

Precautionary statement(s) Disposal

P501: Dispose of contents/container in accordance with local regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances
See section below for composition of Mixtures

Mixtures
CAS No %[weight] Name
64-17-5 60-90 ethanol
106-21-8 <1 geraniol tetrahydride
141-25-3 <1 alpha-citronellol

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye Contact

If this product comes in contact with the eyes:

- Wash out immediately with fresh running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
- Seek medical attention without delay; if pain persists or recurs seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin contact occurs:

- Immediately remove all contaminated clothing, including footwear.
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.

Inhalation

- If fumes, aerosols or combustion products are inhaled remove from contaminated area.
- Other measures are usually unnecessary.

Ingestion

- Immediately give a glass of water.

- First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Indication of any immediate medical attention and special treatment needed

For acute or short term repeated exposures to ethanol:
- Acute ingestion in non-tolerant patients usually responds to supportive care with special attention to prevention of aspiration, replacement of fluid and correction of nutritional deficiencies
(magnesium, thiamine pyridoxine, Vitamins C and K).
- Give 50% dextrose (50-100 ml) IV to obtunded patients following blood draw for glucose determination.
- Comatose patients should be treated with initial attention to airway, breathing, circulation and drugs of immediate importance (glucose, thiamine).
- Decontamination is probably unnecessary more than 1 hour after a single observed ingestion. Cathartics and charcoal may be given but are probably not effective in single ingestions.
- Fructose administration is contra-indicated due to side effects.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media
- Alcohol stable foam.

Special hazards arising from the substrate or mixture

Fire Incompatibility

- Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Fire Fighting

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000223 ROSE FLAVOUR

- Alert Fire Brigade and tell them location and nature of hazard.

Fire/Explosion Hazard

- Liquid and vapour are highly flammable.

Combustion products include:
carbon dioxide (CO2)
other pyrolysis products typical of burning organic material.

HAZCHEM
3YE

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions
See section 12

Methods and material for containment and cleaning up

Minor Spills

- Remove all ignition sources.

Major Spills

- Clear area of personnel and move upwind.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling

- Containers, even those that have been emptied, may contain explosive vapours.
- Avoid all personal contact, including inhalation.
- DO NOT allow clothing wet with material to stay in contact with skin

Other information

- Store in original containers in approved flame-proof area.

- Shelf Life : 12 months
- Storage Conditions: Store tightly closed under cool, dry conditions in an approved storage [Link] exposure to light.

Conditions for safe storage, including any incompatibilities

Suitable container

- Packing as supplied by manufacturer.

- For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type.

Storage incompatibility

- Avoid oxidising agents, acids, acid chlorides, acid anhydrides, chloroformates.

- Avoid strong bases.
*

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

Occupational Exposure Limits (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

Australia Exposure Standards ethanol Ethyl alcohol 1000 ppm / 1880 mg/m3 Not Available Not Available Not Available

Exposure controls
Appropriate engineering controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.

Personal protection

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000223 ROSE FLAVOUR

Eye and face protection

- Safety glasses with side shields.

Skin protection
See Hand protection below

Hands/feet protection

- Wear chemical protective gloves, e.g. PVC.

NOTE:
- The material may produce skin sensitisation in predisposed individuals.
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer.

Body protection
See Other protection below

Other protection

- Overalls.
- Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as they may produce static electricity.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance
:
Clear, colourless to pale yellow liquid

Physical state Liquid Relative density (Water = 1) 0.85

Odour Characteristic Partition coefficient n-octanol / water Not Available

Odour threshold Characteristic of Rose Auto-ignition temperature (°C) Not Available

pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point (°C) Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling range (°C) Not Available Molecular weight (g/mol) Not Available

Flash point (°C) <23 Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability HIGHLY FLAMMABLE. Oxidising properties Not Available
Refractive Index 1.364 Surface Tension (dyn/cm or mN/m) Not Available
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water Not Available pH as a solution (1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity:
See section 7
Chemical stability:
- Unstable in the presence of incompatible materials.
Possibility of hazardous reactions:
See section 7
Conditions to avoid:
See section 7
Incompatible materials:
See section 7
Hazardous decomposition products:
See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhaled

The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives using animal models).
Inhalation of vapours may cause drowsiness and dizziness.
Animal testing shows that the most common signs of inhalation overdose is inco-ordination and drowsiness.
Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervous depression with headache and dizziness, slowing of reflexes, fatigue and
inco-ordination.
Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the health of the individual.

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000223 ROSE FLAVOUR

Ingestion

Ingestion of ethanol (ethyl alcohol, 'alcohol') may produce nausea, vomiting, bleeding from the digestive tract, abdominal pain, and diarrhoea.
The material has NOT been classified by EC Directives or other classification systems as 'harmful by ingestion'.
Accidental ingestion of the material may be damaging to the health of the individual.

Skin Contact

Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damage following entry through wounds, lesions or abrasions.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.
There is some evidence to suggest that the material may cause moderate inflammation of the skin either following direct contact or after a delay of some time.

Eye

Direct contact of the eye with ethanol (alcohol) may cause an immediate stinging and burning sensation, with reflex closure of the lid, and a temporary, tearing injury to the cornea together with
redness of the conjunctiva.
There is evidence that material may produce eye irritation in some persons and produce eye damage 24 hours or more after instillation.

Chronic

Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population.
Based on experiments and other information, there is ample evidence to presume that exposure to this material can cause genetic defects that can be inherited.
Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
This material can cause serious damage if one is exposed to it for long periods.
Ample evidence exists that this material directly causes reduced fertility
Prolonged exposure to ethanol may cause damage to the liver and cause scarring.

TOXICITY IRRITATION
000223 ROSE FLAVOUR
Not Available Not Available

TOXICITY IRRITATION
[2] Eye (rabbit): 500 mg SEVERE
Inhalation (rat) LC50: 124.7 mg/l/4H
[2] Eye (rabbit):100mg/24hr-moderate
Oral (rat) LD50: =1501 mg/kg
ethanol [1]
Eye: adverse effect observed (irritating)
Skin (rabbit):20 mg/24hr-moderate
Skin (rabbit):400 mg (open)-mild
[1]
Skin: no adverse effect observed (not irritating)

TOXICITY IRRITATION
[2] Skin (rabbit): 500 mg/24h
geraniol tetrahydride Dermal (rabbit) LD50: 2400 mg/kg
[2]
Oral (rat) LD50: >5000 mg/kg

TOXICITY IRRITATION
[2] Not Available
alpha-citronellol Dermal (rabbit) LD50: 3600 mg/kg
[2]
Oral (rat) LD50: >5000 mg/kg

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS -
Register of Toxic Effect of chemical Substances

000223 ROSE FLAVOUR

Fragrance allergens act as haptens, low molecular weight chemicals that cause an immune response only when attached to a carrier protein.

ETHANOL
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.

GERANIOL TETRAHYDRIDE
Asthma-like symptoms may continue for months or even years after exposure to the material ends.
The Branched Chain Saturated Alcohol (BCSA) group of fragrance ingredients was evaluated for safety.

ALPHA-CITRONELLOL
Fragrance allergens act as haptens, which are small molecules that cause an immune reaction only when attached to a carrier protein.
Current opinion holds that there are no safety concerns regarding the branched chain unsaturated non-cyclic alcohols, as fragrance ingredients, at current declared levels of use and exposure;
however, use of these materials at higher maximum levels of skin or whole-body exposure requires re-evaluation.

000223 ROSE FLAVOUR & ALPHA-CITRONELLOL

The following information refers to contact allergens as a group and may not be specific to this product.
Adverse reactions to fragrances in perfumes and fragranced cosmetic products include allergic contact dermatitis, irritant contact dermatitis, sensitivity to light, immediate contact reactions, and
pigmented contact dermatitis.

GERANIOL TETRAHYDRIDE & ALPHA-CITRONELLOL

Alkyl alcohols of chain length C6-13 are absorbed from skin, when inhaled or swallowed but show evidence of little harm.
With few exceptions* (see below), there are no safety concerns regarding certain cyclic and non-cyclic terpene alcohols **, as fragrance ingredients, under present declared levels of use and
exposure, because
- They have low acute toxicity
- No significant toxicity was observed in repeat dose toxicity tests
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000223 ROSE FLAVOUR

- They were not found to cause mutations or genetic toxicity

- Substances in this group are processed similarly in the body
- There is no indication of persistent breakdown products causing severe toxicity
- They practically do not irritate the skin
- They have a generally low potential for sensitization
- The margin of safety is more than 100 times the maximum daily exposure.
Citronellol, geraniol, nerol, and geranyl acetate are currently generally regarded as safe by the US FDA for their intended use as flavouring substances.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin sensitisation STOT - Repeated Exposure
Mutagenicity Aspiration Hazard

Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

000223 ROSE FLAVOUR
Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

LC50 96 Fish 11-mg/L 2
ethanol EC50 48 Crustacea 2mg/L 4
EC50 96 Algae or other aquatic plants 17.921mg/L 4
NOEC 2016 Fish 0.000375mg/L 4

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

LC50 96 Fish 1.707mg/L 3
EC50 48 Crustacea 3.6mg/L 2
geraniol tetrahydride
EC50 96 Algae or other aquatic plants 2.780mg/L 3
EC10 72 Algae or other aquatic plants 9.5mg/L 2
NOEC 96 Fish 10mg/L 2

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

alpha-citronellol
Not Available Not Available Not Available Not Available Not Available

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity
Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) -
Bioconcentration Data 8. Vendor Data
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark.
For Ethanol:
log Kow: -0.31 to -0.32;
Koc 1: Estimated BCF= 3;
Half-life (hr) air: 144;
Half-life (hr) H2O surface water: 144;
Henry's atm m3 /mol: 6.29E-06;
BOD 5 if unstated: 0.93-1.67,63%
COD: 1.99-2.11,97%;
ThOD : 2.1.
DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
ethanol LOW (Half-life = 2.17 days) LOW (Half-life = 5.08 days)
geraniol tetrahydride LOW LOW

Bioaccumulative potential
Ingredient Bioaccumulation
ethanol LOW (LogKOW = -0.31)
geraniol tetrahydride LOW (LogKOW = 3.6406)

Mobility in soil
Ingredient Mobility

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000223 ROSE FLAVOUR

ethanol HIGH (KOC = 1)

geraniol tetrahydride LOW (KOC = 70.79)

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Product / Packaging disposal

- Containers may still present a chemical hazard/ danger when empty.

Legislation addressing waste disposal requirements may differ by country, state and/ or territory.
- DO NOT allow wash water from cleaning or process equipment to enter drains.
- Recycle wherever possible.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant
NO

HAZCHEM
3YE

Land transport (ADG) Air transport (ICAO-IATA / DGR) Sea transport (IMDG-Code / GGVSee)

UN number: Environmental hazard: Environmental hazard: Environmental hazard:

1197 Not Applicable Not Applicable Not Applicable
UN proper shipping name: Special provisions: ERG Code: EMS Number:
EXTRACTS, FLAVOURING, LIQUID Not Applicable 3L F-E , S-D
Transport hazard class(es): Limited quantity: Special provisions: Special provisions:
3 5L A3 Not Applicable
Subrisk: Cargo Only Packing Instructions: Limited Quantities:
Not Applicable 364 5L
Packing group: Cargo Only Maximum Qty / Pack:
II 60 L
Passenger and Cargo Packing Instructions:
353
Passenger and Cargo Maximum Qty / Pack:
5L
Passenger and Cargo Limited Quantity Packing Instructions:
Y341
Passenger and Cargo Limited Maximum Qty / Pack:
1L

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

ethanol is found on the following regulatory lists

- Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List - IMO IBC Code Chapter 18: List of products to which the Code does not apply
- Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes - IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
- Australia Exposure Standards - IMO Provisional Categorization of Liquid Substances - List 2: Pollutant only mixtures containing at
- Australia Hazardous Chemical Information System (HCIS) - Hazardous Chemicals least 99% by weight of components already assessed by IMO
- Australia Inventory of Chemical Substances (AICS) - IMO Provisional Categorization of Liquid Substances - List 3: (Trade-named) mixtures containing
- Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix B at least 99% by weight of components already assessed by IMO, presenting safety hazards
(Part 3) - International Air Transport Association (IATA) Dangerous Goods Regulations
- GESAMP/EHS Composite List - GESAMP Hazard Profiles - International Maritime Dangerous Goods Requirements (IMDG Code)
- IMO IBC Code Chapter 17: Summary of minimum requirements - United Nations Recommendations on the Transport of Dangerous Goods Model Regulations

geraniol tetrahydride is found on the following regulatory lists

- Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List - IMO MARPOL (Annex II) - List of Noxious Liquid Substances Carried in Bulk
- Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes - IMO Provisional Categorization of Liquid Substances - List 2: Pollutant only mixtures containing at
- Australia Inventory of Chemical Substances (AICS) least 99% by weight of components already assessed by IMO
- GESAMP/EHS Composite List - GESAMP Hazard Profiles - International Air Transport Association (IATA) Dangerous Goods Regulations
- IMO IBC Code Chapter 17: Summary of minimum requirements - International Maritime Dangerous Goods Requirements (IMDG Code)
- United Nations Recommendations on the Transport of Dangerous Goods Model Regulations

alpha-citronellol is found on the following regulatory lists

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000223 ROSE FLAVOUR

- Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List - IMO IBC Code Chapter 17: Summary of minimum requirements
- Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes - International Air Transport Association (IATA) Dangerous Goods Regulations
- Australia Inventory of Chemical Substances (AICS) - International Maritime Dangerous Goods Requirements (IMDG Code)
- GESAMP/EHS Composite List - GESAMP Hazard Profiles - United Nations Recommendations on the Transport of Dangerous Goods Model Regulations

National Inventory Status

National Inventory Status
Australia - AICS Yes
Canada - DSL Yes
Canada - NDSL No (ethanol; alpha-citronellol; geraniol tetrahydride)
China - IECSC Yes
Europe - EINEC / ELINCS / NLP Yes
Japan - ENCS Yes
Korea - KECI Yes
New Zealand - NZIoC Yes
Philippines - PICCS Yes
USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ No (alpha-citronellol)
Vietnam - NCI Yes
Russia - ARIPS No (alpha-citronellol)
Yes = All CAS declared ingredients are on the inventory
Legend:
No = One or more of the CAS listed ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 OTHER INFORMATION

Revision Date: 17/09/2019
Initial Date: 17/09/2019

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using
available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment.

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