Seat No.
: _______________
AJ-106
April -2018
B.Sc., Sem.-II
CC-2 : Paper-103 : Chemistry
(General Chemistry)
Time : 3 Hours] [Max. Marks : 70
.
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1. (A) ? sp3 . 7
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H2O SF4 , - .
(B)
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. 7
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2. (A) , . 7
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(B) H2 H2+ . 7
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, Be .
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3. (A) 2, 3– . 7
, R-S .
(B) n- . 7
.
AJ-106 1 P.T.O.
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4. (A) . 7
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(B) , N/Z . 7
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5. 14
(1) sp .
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(2) NH3 .
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(3) .
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(4) [Co(NH3)6]Cl3 IUPAC .
(5) .
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(7) “ ” ?
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(8) .
(9) ?
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(10) ?
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(12) ?
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(13) 0.0005 M H2SO4 pH .
(14) () .
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______________
AJ-106 2
Instagram : @GRealsir
Seat No. : _______________
AJ-106
April -2018
B.Sc., Sem.-II
CC-2 : Paper-103 : Chemistry
(General Chemistry)
Time : 3 Hours] [Max. Marks : 70
Instruction : Figures on right hand side indicate marks.
(A) What is hybridization ? Explain sp3 hybridization with suitable example.
o
1. 7
OR
nf
Explain hybridization, shape and bond angle of H2O and SF4 molecule.
(B) Explain factors affecting on stability of Complex Compounds. 7
OR
2.
r.i
Explain Werner's Principle for Complex Compounds.
i
(A) Explain Normalized, Orthogonal and Orthonormal Wave functions. 7
ls
OR
Explain Eigen function, Eigen value and Eigen value equation by giving example.
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(B) Derive Hamiltonian operator for H2 molecule and H2+ molecular ion. 7
OR
Define Operator. Construct Hamiltonian operator for Be atom.
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3. (A) Explain Optical isomerism in 2, 3 – di bromo pentane. 7
OR
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Discuss R-S Nomenclatures of Lactic acid, Tartaric acid and Glyceraldehyde.
(B) Discuss conformational analysis of n- butane. 7
w
OR
Draw conformers' of ethane and discuss its stability.
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4. (A) Explain Ostwald’s dilution law and give its limitations. 7
OR
Write a short note on buffer solutions.
(B) Indicates factors affecting stability of nucleus, of which explain effect of N/Z
ratio. 7
OR
Explain Soddy's group displacement law by giving suitable example.
AJ-106 3 P.T.O.
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5. Give answer of the following questions in short : 14
(1) Indicate shape and bond angle of the molecule having sp hybridization.
(2) Write number of bonding and non bonding electron pair present in NH3 molecule.
(3) Give an example of hexa dentate Ligand.
(4) Write IUPAC name and shape of complex [Co(NH3)6]Cl3.
(5) Indicate Schrodinger equation as Eigen value equation.
(6) Which term indicates probability of finding particle in wave mechanics ?
(7) What is “Turn Over Rule” ?
(8) Indicate quantum mechanical operator of total energy of particle.
(9) Which nomenclature method is popular for geometrical isomers ?
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(10) What is Chirality ?
(11) What are Conformers ?
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(12) What is buffer capacity ?
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(13) Find out pH of 0.0005 M H2SO4 solution.
(14) Write equation of radioactive disintegration constant ().
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______________
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AJ-106 4
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