Table C.|_ Heat Capacities of Gases in the Ideal-Gas State! Constantin equation CHIR = 44 07 HOT? + OF? 63s _Chemical species Ton CIR Pavafins Maune se aE chaos I 1500 6369 Bppeiee Ce 1500, 9.001 oe CuHyo = 15001928 jso-fhuane GiHip 150011901 n-Pentane GHy 1500 14.731 i ae ate ie le e Hie 20.361 n-Oetane 1300 23.174 1-Alkenes: Ethylene 1500 Props iene 1500 -Butene I EPertene 1300 I-Hexene 1500 T-Heptene 1500, Loetene 1500 Miscellaneous organics? Acetaldehyde C;H,0 1000 Acetylene CHa 1500 Benzene CoHe 1500 1,3-Butadiene CaHs 1300 (Cyclohexane CoH, 1500 Ethanol ‘CHO 1500 Ethylbenzene CyHyo 1500 Ethylenconide CHO 1000 Formaldehyde CHO 1500 Methanol CHO 1500 ‘Styrene, CHy 1500 Toiuene OH 1500 Miscellaneous Air 2000 ‘Ammonia ‘iB 1800 Bromine Br 30 Carbon monoxide co 2500 Carbon dioxide co; 2000 Carbon disulfide cane Chlorine i 00 Hydrogen Hy 3000 Hydrogen sulfide HS 2300 Hydrogen chloride HCL 2000 Hydrogen eyanide cn 2500 Nitrogen N: 2000 yrous oxide N,0 2000 Nitric oxide NO 2000 Nitrogen dioxide, Nod 2000 Dinitrogen tetroxide aoe Ferg ets 50, 2000 Sulfur dioxide » Sulfur trioxide S03 2000 Water H;,0 2000 ‘TSelected from H. M. Spencs .sBur Mines Bull. 584. 1960: 17978 1952 39.064 26.786 63.209 20,001 55,380 23.463 7.022 12.216 50.192 47.052 0.575 3.020 0056 0.557 1.045 0805 0.089 0.422 1490 0.623 1359) 0593 1214 0.629 1195 2257 0.506 0.801 1.056. 1450 fines Bull. 672, 1982. ¥ (kelvin) fom 298.15 W Fn A 18 WC WD 1.702 9.081 -2164 HSE 19225 =5.501 1213 28785 ~ RRA 1935 3491s —11.402 \e77 37.853 1.45 2464 45351-4111 3025 53.722 16.791 3.570 62127 -19.486 4108 70567-22208 1439-4392 22706 6.915 31630-9873 30.753 12447 48.189 -15.157 56.588 17.847 64960-20521 -129 0.792 2.787 0227 LOIS 2.028 0.121 cx, Ind. Eng, Chem. vol. 40, pp. 2152-2154, 194 KK Kelley, 1B, Pankratz, US. Bur636 ENDIN C. Heat Capacities and Uroperty Changes of Formation ee —— a ormnttON Table C.2_ Heat Capacities of Solids! Constants for the equation Cp /R = A+ BT + DTT (kelvins) from 298.15 KW Tas Chemical species 4 oD 6108 04a 1047 12572 2.647 -3.120 9oss7 5.435 Lang ~1Lon 1.530 ~0302 om ~0.867 ois 003s 0.973 -o874 6. 1.150 9.67 1.916 m2 0409 13.286 1.502 400 5778 2416 0193 458 10.741 16.105 ant 3.386 4.688 Nact 1073 oun 1.963 NiOH 366 7177 16.316 NaliCO3 400 10539 18.148 S (rhombic) 36833748 =1.728 SiO, (quart) 37 545 5.365 ‘Selected from K. K. Kelley, U.S. Bur. Mines Bull. 584, 1960; 1B, Pankratz, US. Bur Mines Bull 672, 1982. Table C.3 Heat Capacities of Liquids! thee Ce/R= A+ BT + CT? TF from 273.15 0373.15 K Chemical species CP /R 1B 108 Fe Ammonia 978 22.66 — 100,75 192.71 Aniline 23.070 15,819 29.03, ~15.80 Benzene 16.187 -0.747 61.96 ~37.78 1,3-Butadiene 4779 ATH 87.96 205.79 Carbon tetrachloride 15.751 24.155 48.28 111s Chlorobenzene 18.240 14.278 32.86 31.90 Chloroform 13.806 19.215 12.89 8301 Cyclohexane 18.737 9.048 M138 161.62 Ethanol 13444 33.866 172.60 MONT Ethylene oxide 10.590 21,039 86.41 172.28 Methanol 9.998 13.431 S128 1313 »-Propanol 16921 41.653 210.32 427.20 Sulfur trioxide 30.408 2.930 137.08 84.73 Toluene 18.611 15.133 619 16.35 Water 9009 8.712 125 0.18 TI {Biased on correlations presented by J, W, Miller, I. GR Schwa; and CL, Yows, Chem, £ing., vol 83(23), p. 129, 1976,