Date Planned : __ / __ / __ Daily Tutorial Sheet-2 Expected Duration : 90 Min
Actual Date of Attempt : __ / __ / __ Level-1 Exact Duration :_________
16.
For the reaction, 2HI(g) ↽ ⇀ H2 g I2 g Q kJ , the equilibrium constant depends upon :
(A) Temperature only (B) Pressure
(C) Catalyst (D) Volume
17. 1.6 moles of PCl5 (g) is placed in 4 dm3 closed vessel. When the temperature is raised to 500 K, it
decomposes and at equilibrium 1.2 moles of PCl5 (g) remains. What is the Kc value for the decomposition
of PCl5 (g) to PCl3 (g) and Cl2 at 500 K
(A) 0.013 (B) 0.050 (C) 0.033 (D) 0.067
18. Ammonium carbamate decomposes as :
NH2COONH4 s ↽ ⇀ 2NH3 g CO2 g
For the reaction, K p 2.9 10 5 atm 3 . If we start with 1 mole of the compound, the total pressure at
equilibrium would be :
(A) 0.766 atm (B) 0.0582 atm (C) 0.0388 (D) 0.0194 atm
19. 4 moles each of SO2 and O2 gases are allowed to react to form SO3 in a closed vessel. At equilibrium 25%
of O2 is used up. The total number of moles of all the gases at equilibrium is :
(A) 6.5 (B) 7.0 (C) 8.0 (D) 2.0
20. In chemical equilibrium, the value of n (number of molecules), is negative, then the relationship
between Kp and Kc will be :
n
(A) K p Kc 0 (B) K p K c RT
n 1
(C)
K p K c RT (D) Kp
Kc
21. For the reaction CO (g) 0.5 O2 (g) ↽ ⇀ CO2 (g) K p / K c is equal to :
1
(A) RT (B) (C) 1 (D) RT2
RT
22. The equilibrium constant (Kc) of the reaction A 2 (g) B2 (g) ↽ ⇀ 2AB(g) is 50. If 1 mol of A2 and 2 mol
of B2 are mixed, the amount of AB at equilibrium would be :
(A) 0.934 mol (B) 0.467 mol (C) 1.866 mol (D) 1.401 mol
23. A B ↽ ⇀ C D. If initially the concentration of A and B are both equal but at equilibrium,
concentration of D will be twice of that of A, then what will be the equilibrium constant of reaction ?
(A) 4/9 (B) 9/4 (C) 1/9 (D) 4
24.
Which of the following is correct for the reaction? N2 g 3H2 g ↽ ⇀ 2NH3 g
(A) Kp = Kc (B) Kp < Kc
(C) Kp > Kc (D) Pressure is required to predict the correlation
VMC | Chemical Equilibrium 80 DTS-2 | Level-1
25. The equilibrium constant of a reaction is 300. If the volume of reaction flask is tripled, the equilibrium
constant is :
(A) 300 (B) 600 (C) 900 (D) 100
26.
Partial pressure of O2 in the reaction 2Ag 2O s ↽ ⇀ 4Ag s O2 g is :
(A) KP (B) Kp (C) 3 Kp (D) 2KP
27. The compounds A and B are mixed in equimolar proportion to form the products, A B ↽ ⇀ C D. At
equilibrium, one third of A and B are consumed. The equilibrium constant for the reaction is :
(A) 0.5 (B) 4.0 (C) 2.5 (D) 0.25
28. In which of the following reactions, the concentration of product is higher than the concentration of
reactant at equilibrium? (K = equilibrium constant)
(A) A ↽ ⇀ B; K 0.001 (B) M ↽ ⇀ N ; K 10
(C) X ↽ ⇀ Y ; K 0.005 (D) R ↽ ⇀ P ; K 0.01
29.
The equilibrium, P4 s 6Cl2 g ↽ ⇀ 4PCl3 g attained by mixing equal moles of P4 and Cl2 in a
evacuated vessel. Then at equilibrium.
(A) [Cl2] > [PCl3] (B) [Cl2] > [P4] (C) [P4] > [Cl2] (D) [PCl3] > [P4]
30.
Consider the following reaction equilibrium N2 g 3H2 g ↽ ⇀ 2NH3 g
Initially, 1 mole N2, 3 moles of H2 are taken in a 2L flask. At equilibrium state, if the number of moles of
N2 is 0.6, what is the total number of moles of all gases present in the flask ?
(A) 0.8 (B) 1.6 (C) 3.2 (D) 6.4
VMC | Chemical Equilibrium 81 DTS-2 | Level-1
