Scribd
Upload
231 views2 pages

Chemistry Unit Test: Aniline Reactions

The document is a chemistry exam with multiple choice and long answer questions about organic compounds containing nitrogen like amines and nitrobenzene. It tests the understanding of reactions of these compounds including how nitrobenzene can be converted to aniline, reactions of aniline including its lack of reactivity in Friedel-Crafts reactions, and comparisons of amine properties.

Uploaded by

ghssayyampettaitnj
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
231 views2 pages

Chemistry Unit Test: Aniline Reactions

The document is a chemistry exam with multiple choice and long answer questions about organic compounds containing nitrogen like amines and nitrobenzene. It tests the understanding of reactions of these compounds including how nitrobenzene can be converted to aniline, reactions of aniline including its lack of reactivity in Friedel-Crafts reactions, and comparisons of amine properties.

Uploaded by

ghssayyampettaitnj
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 2

Unit test - XIII

Subject : CHEMISTRY Marks:30


Class : XII Time : 1 Hr
PART – A(5 X 1 = 5)
I)Choose the correct answer
1. Which of the following reagent can be convert nitro benzene to aniline?
a)Sn / Hcl b)Zn-Hg/NaOH c)Zn/NH4cl d)All of these
2.The product formed by aldehyde with a primary amine
a)Carboxylic acid b)Aromatic acid c)Schiff’s base d)Ketone
3.When aniline reacts with aceticanhydride the product formed is
a)o-aminoacetophenone b)m-aminiacetophenone c)p-aminoacetophenone d)acetanilide
4.The method by which aniline cannot be prepared is
a)degradation of benzamide with Br2/NaOH
b)potassium salt of phthalimide treated with chlorobenzene followed by hydrolysis with
aqueous NaOH solution
c)reduction of nitrobenzene with LiAlH4
d)reduction of nitrobenzene by Sn /Hcl
5.The order of basic strength of methyl substituted amine in aqueous solution is
a)N(CH3)3 > HN(CH3)2 > H2N(CH3) > NH3
b) H2N(CH3) > HN(CH3)2 > N(CH3)3> NH3
c) NH3 > H2N(CH3) > HN(CH3)2 > N(CH3)3
d) HN(CH3)2 > H2N(CH3) > N(CH3)3 > NH
PART – B(3 X 2 = 6)
II)Answer any 3 questions . Question number 8 is compulsory . Answer any two from the
remaining.
6.How will you convert nitrobenzene into i)1,3,5 – trinitro benzene ii)o and p–nitrophenol ?
7.Explain diazotisation reaction.
8.Aniline does not undergo Friedel – Craft’s reaction.Why?
9.Explain the Schotten – Baumann reaction of aniline.
PART – C(3 X 3 = 9)
III)Answer any 3 questions . Question number 12 is compulsory . Answer any two from
the remaining.
10.Explain the mustard oil reaction of i)Methyl amine ii)Aniline .
11.Which type of amine is prepared by Gabriel phthalimide synthesis?Write the reaction.
12. Explain the reuction of nitrobenzene in various medium.
13.Explain : i)Hoffmann’s bromide reaction ii)Hoffmann’s ammonolysis
PART – D(2 X 5 = 10)
IV)Answer any two questions.
14.i)Write any three differences between 10 , 20 and 30 aliphatic amines.
ii)Name the test used to identify primary amines . Write the reaction involved in the test.
15.Give an account for the following :
i)Pkb of aniline is more than that of methyl amine .
ii)Ethylamine is soluble in water whereas aniline is not .
iii)Amines are more basic than amides .
16.i)How will you convert aniline into p-nitro aniline?
ii)What are the difference between nitro form and aci form?

You might also like