Subject Code: 043 CHEMISTRY Time Allowed : 3 Hours Maxtonums Marks: 70 General Instructions : Read the following instructions carefully. (a) There are 33 questions in this question paper with internal choice. (b) SECTION A consists of 16 multiple-choice questions carrying 1 mark each. () SECTION B consists of 5 short answer questions carrying 2 marks each, (d) SECTION C consists of 7 short answer questions carrying 3 marks each. (©) SECTION D consists of 2 case-based questions carrying 4 marks each. (f) SECTION E consists of 3 long answer questions carrying 5 marks each. @ All questions are compulsory. (h) Use of log tables and calculators is not allowed. SECTION A ‘The following questions are multiple-choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. 1. Anelectric charge of 5 Faradays is passed through three electrolytes AgNOs, CuSO, and FeCl; solution. The grams of each metal liberated at cathode will be (a) Ag=10.8g,Cu=12.7g,Fe=1llg (©) Ag=108 g, Cu= 63.5 g, Fe = 56 2. Twoisomeric compounds A and Bhave the formula C;HsCl,. With aq, KOH solution, A gives propionaldehyde and B gives acetone. Then A and B respectively are (a) CH3- CCl- CH; and CH;- CH;- CHCl, (b) CH3-CHCI-CH,Cl and CH3~CH,-CHCl, (©) CHy- CH,-CHCI, and CH3- CCl,~ CH; (@) CH3-CHCI-CH,Cl and CH- CCl; CH 3. Match the column I with column II and mark the appropriate choice, Column I Column It (A) [An element which can show +8 oxidation state _| (i) Ce (B) | Outer electronic configuration is 4f7 6s (ii) Pm (C) | Radioactive lanthanoid iti) Os (D) | Lanthanoid which shows +4 oxidation state (iv) Eu (@ (A) @, B) > (ii), (©) > (iii), (D) > (tv) (b) (A) (ii), (B) > Gait), (C) > (iv), (D) > () (© (A)> @, (B)> Gv), (C) > Gi), (D) > (iit) (a) (A) Gill), B) > Civ), (C) > Gi), (2) > Chemistry Scanned with CamScanner5 . Theactivation energies of two reaction tn three beakers labelled a (A), (22) andl (C), 100 tl oF water 100 rls uf A woluton of yluc and 100 mL of 0.5 M solution of ghicose In water ate nken reapectively anil kept at same temper”! [weer | Th HA wlacvns " vi | ilo | (b) Vapour pressure of beaker B Is highest, (© Vapour pressure of beaker C ls highest. (a) Vapour pressure of beaker His lower than that of Cand vapour pressure of heaker Cs lormer than that of Which of the following statement Is correct (a) Vapour pressure in all the three beakers Is mune, Which one of the following is the most acldle compound? oH OH Ou On ON AS NO, @) (b) (o) ey J (d) I NO, NO, Cy Which of the following pairs represents linkage Isomers? (a) [Cu(NH,),)(PtCly] and [Pt((NH)4][(CuCl,] (b) [Pd(PPh3)2(NCS),] and [Pd(PPh3)2(SCN)a) (©) [Co(NHg)s(NOs3)}SO, and [Co(NH3)3(S0,)]NO3 (a) [PtCl,(NHs),)Brz and [PtBr,(NH3),]Cl, Which of the following compounds will undergoes self aldol condensation in the presence of cold dilute alkali? () CH=C—CHO (b) (CHy);CCHO (c) CgHsCHO- (d) CHyCH,CHO A binary liquid solution is prepared by mixing n-heptane and ethanol. Which one of the following statements is correct regarding the behaviour of the solution? (a) The solution formed is an ideal solution, (b) The solution is non-ideal, showing +ve deviation from Raoult’s law. (c) The solution is non-ideal, showing ~ve deviation from Raoult’s law, (d) n-heptane shows +ve deviation while ethanol shows ~ve deviation from Raoult's law. A tripeptide (X) on partial hydrolysis gave two dipeptides Cys-Gly and Glu-Cys, he, CH,CH,COOH CH,SH CH,SH Nny—cHe¢ ceettg-8 ond Rey qe 4-C-O" ° 4 Identify the tripeptide, "CH Cy-cly (@) GluCysGly 0) Gly.Gucys fe). CysGly-Gu (a). GyssGluscly ns are H and (E> Ey), Ifthe temperature of the system {s Increased he reactions changes from ky to Kj In the first reaction and ky to Kl" of the following expression Is correct? from T, to T, the rate constant of t ) Kw ky @ Heke WR Clase 12 Scanned with CamScanner11. Which of the following alcohols reacts most readily with Lucas reagent? CH; (a) CH;CH,CH,OH — (b) CHy~Ci—cy () Story (d) Sis CHO on CH, CH 12, Hexaamminenickel({1) hexanitrocobaltate(II1) can be written as (@)_ [Ni(NH3)¢]2{Co(NO,)6]5 (b)_ [Ni(NH5)¢]3[Co(NO3)6]2 (©) [Ni(QNHy)g] [Co(NO,),) (d)_ [Ni(NH3)6(NOz),]Co 13. Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A) : Hoffmann degradation of benzamide gives aniline, Reason (R) : Hoffmann bromamide degradation reaction can be used for descending amine series. Select the most appropriate answer from the options given below: {a) Both A and R are true and R is the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (Q) Aistrue but Ris false, (@_Aisfalse but Ris true, 14. Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A) :In acidic medium, K,Cr0; exists as Cr03- (orange) while in basic medium, itis converted to CrO}" (yellow). Reason (R) : KzCr,0; is hygroscopic in nature and changes colour on reaction with water. Select the most appropriate answer from the options given’ below: (a) Both A and Rare true and Ris the correct explanation of A. (b) Both A and Rare true but R is not the correct explanation of A. (©) Aistrue but Ris false. mn (@) Aisfalse but Ris true. 15. Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A) : Hydrolysis of sucrose brings about a change in sign of rotation from dextro to laevo. Reason (R) ; Hydrolysis always changes the optical rotation of a compound. Select the most appropriate answer from the options given below: (a) Both A and Rare true and R is the correct explanation of A. (b) Both A and Rare true but Ris not the correct explanation of A. (©) Ais true but R is false. (d) Ais false but R is true. 16. Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A) : Boiling point of ethanol is higher than that of propane. Reason (R) : Molecular mass of ethanol is higher than that of propane, Select the most appropriate answer from the options given below: (@) Both A and R are true and R is the correct explanation of A. (b) Both Aand Rare true but R is not the correct explanation of A. (©) Ais true but Ris false, (d) A is false but Ris true, SECTION B ‘This section coritains 5 questions with internal choice in one question. The following questions are very short answer type and carry 2 marks each, 17.” Half-life period of first order reaction at'47 °C is 10 minutes and at 27 °C is 30 minutes. Calculate the activation energy of the reaction: * ‘ Chemistry Re Scanned with CamScanner18. 19. 20. 2. OR is kinetically first order reactio i ich a bimolecular reaction is kinetical a. (i) State a condition under which} C if the order of the reaction is zero then what will be the (ii) For the reaction, 2A + ° ne, between rate of reaction and rate constant? ining 50 cm? of ethylene glycol in 50 g water is found to be _ 7 cont ee ree he density of ethylene glycol (Ky for HO = 1.86 Kkg mort) ‘Assuming ideal behaviour, calculate t Draw the structures of optical isomers of ‘each of the following complex ions : [PtCl,(en),]**, [Cr(NH3)2Cly(en)]* ‘Write the following conversions : (i) Nitrobenzene —> Acetanilide (ii) Acetanilide —> p-Nitroaniline Explain why (i) Alkyl halides, though polar, are immiscible with water. (ii) Tertiary halides are least reactive towards Sy2 reactions. SECTION 'C This section contains 7 questions with internal choice in one question. The following questions are shy answer type and carry 3 marks each. 22. 23, 24, 25, 26. 27. (Based on solute-solvent interactions arrange the following in order of increasing solubility in n-ociue and explain : Cyclohexane, KCI, CHjOH, CH3CN (ii) Two elements A and B form compounds having molecular formula AB, and AB,. When dissolved 20 g ofbenzene (CeHg), 1g of AB, lowers the freezing point by 2.3 K whereas 1 g of AB, lowersitby 13k ‘The molal depression constant for benzene is 5.1 K kg mol", Calculate atomic masses of A and B. (i) Out of (CH,)sC — Br and (CHs);C — I, which one is more reactive towards Syy1 and why? (i) Write the product formed when p-nitrochlorobenzene is heated with aqueous NaOH at 443 K followed by acidification, (ii) Why dextroand laevo-rotatory isomers of butan-2-0l are difficult to separate by fractional distil! (2) Name the reagents and write the chemical equations forthe preparation ofthe following compos! by Williamson's synthesis (i) Ethoxybenzene (ii) 2-Methyl-2-methoxypropane (b)_ Why do phenols not give the protonation reaction readily? (@) Whats the effect of substituents on basicity of amines? ()_ Rearrange the following in an increasing order of thei CoHsNH2, CoHsN(CH3),, (CgHs),NH and CH3NH, (@) The cell in which the following reaction occurs, Wel + ag) > 2FeRy + Igy has B® 6 =0: o the equim constant ofthe celleaton, 98K: calculate the standard Gibbs = (0) Agifor NaCl, HCland NaAc are 126.4, 425.9 an Write down functional isomers of a will react faster with HCN and why? Expla ith molecular formula CsH,0. Which 4 the completion with the conversion basic strengths : 1d 91.0 S cm? mol! respectively. Calculate A°!0" se Scanned with CamScanner28, Answer the following questions (any 2) : (a) Whatis “spectrochemical series” ligand? (b) Why chelate complexes are more stable than complexes with unidentate ligands ? (© Forthe given complex [Fe(en),Cl,}Cl write the name ofthe complex and also give oxidation number of iron. What isthe difference between a weak field ligand and a strong field SECTION D ‘The following questions are case -based questions, Each question has an internal choice and carries 4 (1+1+2) marks each, Read the passage carefully and answer the questions that follow. 29. Ina reaction, the rates of disappearance of different reactants or rates of formation of different products may not be equal but rate of reaction at any instant of time has the same value expressed in terms of any reactant or product. Further, the rate of reaction may not depend upon the stoichiometric coefficients of the balanced chemical equation. The exact powers of molar concentrations of reactants on which rate depends are found experimentally and expressed in terms of ‘order of reaction’ Each reaction has a characteristic rate constant depends upon temperature. The units of the rate constant depend upon the order of reaction. Answer the following questions : (a) The rate constant of a reaction is found to be 3 x 10™° mol L? sec"!. What is the order of the reaction? OR Rate of a reaction can be expressed by following rate expression, Rate = k[A]? [B], ifconcentration of A is increased by 3 times and concentration of B is increased by 2 times, how many times rate of reaction increases? (b) Therate ofa certain reaction is given by, rate = k{H*]". The rate increases 100 times when the pH changes from 3 to 1. What is the order () of the reaction ? (©) Inachemical reaction A +2B—> products, when concentration of A alone is doubled, rate of the reaction increases 4 times and when concentration of B alone is doubled rate continues to be the same. What is the order of the reaction? 30. (A), (B) and (C) are three non-cyclic functional isomers of a carbonyl compound with molecular formula CHO. Isomers (A) and (C) give positive Tollens’ test whereas isomer (B) does not give Tollens' test but gives positive iodoform test. Isomers (A) and (B) on reduction with Zn(Hg)/conc. HCI give the same product (D). Answer the following questions : (a) Whatis the functional group present in compound (A)? (b) Out of (A), (B) and (C) isomers, which one is least reactive towards addition of HCN? (©). Identify the compounds (4), (B), (C) and (D). OR What will be the product when (B) reacts with ethylene glycol in presence of HCI gas? SECTION E “The following questions are long answer type and carry 5 marks each, All questions have an internal choice. 31. Attempt any five of the following : (a) What is the basic structural difference between glucose and fructose? (b) | Write the structure of the product obtained when glucose is oxidised with nitric acid. Chamictey i Scanned with CamScanner32, 33. (c) What is meant by inversion of sugar? , i e by giving example, Explain glycosidic linkage by gi : o which component of starch isa branched polymer of o-glucose and insoluble in water? (A) Define polypeptide, (g) What isthe difference between ot-form and -form of glucose? (a) (1) Complete the following reactions : (i) 2MnOj 4 3Mn** + 2H,0 —> (ii) SNOJ + 2MnOj + 6H ——> (1). Give two uses of KMnO,. (b) Cul, isnot known, Why ? (© Second ionisation enthalpy for Cr and Cu is unusually high, Explain. OR Assign a reason for each of the following : (@) _ Cr**is reducing and Mn** is oxidising in nature when both have d configuration. (ii) [TI(H,0),]** is purple coloured, i) Te transition metals (with the exception of Zn, Cd and Hg) arehard and have high melting and boiling points, (iv) “The ionisation enthalpies (frst and second) in the first series of the transition elements are found vary irregularly. (¥)Ce(IV) is a good analytical reagent. {) () What would happen ifthe protective tin coating over an iron bucket is broken in some plac? i) Why Ap, for acetic acid cannot be determined experimentally? (b) The standard electrode potential for Daniell cells 1.1 V. Calculate the standard Gibbs energy for the reaction ; Zig + Cufiyy > Zn) + Cay (©) The resistance of 0.01 M NaCl solution at 25°C is 200 ©. The cel constant of the conductivity cell used is unity. Calculate the molar conductivity of the solution, degree of dissociation of NH4OH solution? (b) The £ values corresponding to the followin, (@) Curicu=+052V (i) Cu*/Cu = +016 V Formulate the galvanic cell for their combination, What will be the st Calculate A,G° for the cell reaction, (F = 96500 C mot), (©) What are fuel cells? ig two reduction electrode Processes are : andard cell potential for it Scanned with CamScanner