Laminex AbsoluteGrain Laminate SDS
Laminex AbsoluteGrain Laminate SDS
Product Identifier
Product name Laminex - Laminate Product
Chemical Name Not Applicable
Laminex Redback; Laminex Redback Laminate; Laminex Chemical Resistant Laminate; Laminex Squareform Laminate; Laminex
Synonyms
DiamondGloss; Laminex AbsoluteMatte; Lamines AbsoluteGrain; Laminex Formica Classic Collection; Alucci Apex
Chemical formula Not Applicable
Other means of
Not Available
identification
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Decorative surfacing of furniture, cabinets, bench tops, walls, ceilings, floors and doors
Emergency telephone
+61 1800 951 288
numbers
Other emergency
+61 2 9186 1132
telephone numbers
Once connected and if the message is not in your prefered language then please dial 01
Label elements
Hazard statement(s)
Page 1 continued...
Chemwatch: 58017 Page 2 of 12 Issue Date: 29/09/2020
Version No: 13.1 Print Date: 01/02/2022
Laminex - Laminate Product
Not Applicable
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
Not Available manufactured as a laminate
Not Available paper as
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HCIS; 3. Classification drawn from Regulation (EU) No 1272/2008 -
Annex VI; 4. Classification drawn from C&L; * EU IOELVs available
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Inhalation
Other measures are usually unnecessary.
Extinguishing media
Continued...
Chemwatch: 58017 Page 3 of 12 Issue Date: 29/09/2020
Version No: 13.1 Print Date: 01/02/2022
Laminex - Laminate Product
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
Water spray or fog - Large fires only.
Environmental precautions
See section 12
Continued...
Chemwatch: 58017 Page 4 of 12 Issue Date: 29/09/2020
Version No: 13.1 Print Date: 01/02/2022
Laminex - Laminate Product
Control parameters
INGREDIENT DATA
Emergency Limits
MATERIAL DATA
Odour Safety Factor(OSF) OSF=0.36 (melamine/ formaldehyde resin)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure Standard is being exceeded.
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Continued...
Chemwatch: 58017 Page 5 of 12 Issue Date: 29/09/2020
Version No: 13.1 Print Date: 01/02/2022
Laminex - Laminate Product
ClassOSF Description
Over 90% of exposed individuals are aware by smell that the Exposure Standard (TLV-TWA for example) is being reached, even when distracted by
A 550
working activities
B 26-550As "A" for 50-90% of persons being distracted
C 1-26 As "A" for less than 50% of persons being distracted
D 0.18-1 10-50% of persons aware of being tested perceive by smell that the Exposure Standard is being reached
E <0.18 As "D" for less than 10% of persons aware of being tested
Exposure controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation
that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if
designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.
General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator.
Correct fit is essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas. Air
contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of
fresh circulating air required to effectively remove the contaminant.
0.25-0.5 m/s
solvent, vapours, degreasing etc., evaporating from tank (in still air)
(50-100 f/min)
aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers,
0.5-1 m/s
welding, spray drift, plating acid fumes, pickling (released at low velocity into zone of active
(100-200 f/min.)
generation)
Appropriate engineering
direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas 1-2.5 m/s
controls
discharge (active generation into zone of rapid air motion) (200-500 f/min)
grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial 2.5-10 m/s
velocity into zone of very high rapid air motion). (500-2000 f/min.)
Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity
generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the
extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.) for extraction of solvents generated in a tank 2
meters distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction
apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are
installed or used.
Personal protection
Continued...
Chemwatch: 58017 Page 6 of 12 Issue Date: 29/09/2020
Version No: 13.1 Print Date: 01/02/2022
Laminex - Laminate Product
NOTE:
The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other
protective equipment, to avoid all possible skin contact.
Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.
Body protection See Other protection below
When cutting wear approved dust respirator to avoid inhalation of wood dust created during the cutting process.
Overalls.
P.V.C apron.
Barrier cream.
Skin cleansing cream.
Eye wash unit.
Avoid breathing dust when sawing or grinding.
WARNING: Wood dusts have been classified by the IARC as Group 1: CARCINOGENIC TO HUMANS.
Wood dusts produce dermatitis and an increased risk of upper respiratory disease. Epidemiological studies in furniture workers
show an increased risk of lung, tongue, pharynx and nasal cancer. An excess risk of leukaemia amongst millwrights probably is
associated with exposure to various components used in wood preservation.
IARC has not limited this finding to any specific type of industry (e.g. furniture manufacturing) or wood dust source (hardwood vs.
softwood). IARC s conclusions are based primarily on human carcinogenicity data from studies of various exposed worker
populations.
The softwood TLV-TWA reflects the apparent low risk for upper respiratory tract involvement amongst workers in the building
industry. A separate TLV-TWA, for hard woods, is based on impaired nasal mucociliary function reported to contribute to nasal
adenocarcinoma and related hyperplasia found in furniture workers.
Allergic reactions are more common from handling green timber, less common for dried hardwood.
Impairment of nasal mucociliary function may occur below 5 mg/m3 and may be important in the development of nasal
adenocarcinoma amongst furniture workers exposed to hardwoods.
Certain exotic hardwoods contain alkaloids which may produce headache, anorexia, nausea, bradycardia and dyspnoea.
ACGIH Exposure Standards for Wood dusts
Other protection
Species ACGIH TLV TWA (inhalable fraction) Notations TLV Basis
Western red cedar (WRC) 0.5 mg/m3 Sensitiser, A4*** May produce asthma
Oak and beech 1 mg/m3 A1* May affect pulmonary function
Birch, mahogany, teak, walnut 1 mg/m3 A2* May affect pulmonary function
All other species 1 mg/m3 A4*** May affect pulmonary function
Respiratory protection
Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)
Where the concentration of gas/particulates in the breathing zone, approaches or exceeds the "Exposure Standard" (or ES), respiratory protection is required.
Degree of protection varies with both face-piece and Class of filter; the nature of protection varies with Type of filter.
Required Minimum Protection Factor Half-Face Respirator Full-Face Respirator Powered Air Respirator
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur
dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic
compounds(below 65 degC)
Continued...
Chemwatch: 58017 Page 7 of 12 Issue Date: 29/09/2020
Version No: 13.1 Print Date: 01/02/2022
Laminex - Laminate Product
Partition coefficient
Odour Not Available Not Available
n-octanol / water
Auto-ignition temperature
Odour threshold Not Available >220
(°C)
Decomposition
pH (as supplied) Not Applicable Not Available
temperature
pH as a solution (Not
Solubility in water Immiscible Not Applicable
Available%)
Eye Although the material is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce
Continued...
Chemwatch: 58017 Page 8 of 12 Issue Date: 29/09/2020
Version No: 13.1 Print Date: 01/02/2022
Laminex - Laminate Product
TOXICITY IRRITATION
Dermal (rabbit) LD50: >2000 mg/kg[2] Not Available
cellulose
Inhalation(Rat) LC50; >5.8 mg/L4h[2]
TOXICITY IRRITATION
Dermal (rabbit) LD50: >5000 mg/kg[2] Eye(rabbit):40/110 mod - Draize
phenol/ formaldehyde
Oral (Rat) LD50; >2500 mg/kg[2] Eye: adverse effect observed (irritating)[1]
resin
Skin (rabbit): 3/8 - mod - Draize
TOXICITY IRRITATION
Dermal (rabbit) LD50: >2000 mg/kg[2] Not Available
cellulose
Inhalation(Rat) LC50; >5.8 mg/L4h[2]
TOXICITY IRRITATION
Dermal (rabbit) LD50: >5000 mg/kg[2] Eye(rabbit):40/110 mod - Draize
phenol/ formaldehyde
Oral (Rat) LD50; >2500 mg/kg[2] Eye: adverse effect observed (irritating)[1]
resin
Skin (rabbit): 3/8 - mod - Draize
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a
non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high
levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory disease,
in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented
exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial
CELLULOSE
hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have
also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an infrequent
disorder with rates related to the concentration of and duration of exposure to the irritating substance. Industrial bronchitis, on the
other hand, is a disorder that occurs as result of exposure due to high concentrations of irritating substance (often particulate in
nature) and is completely reversible after exposure ceases. The disorder is characterised by dyspnea, cough and mucus
production.
The following information refers to contact allergens as a group and may not be specific to this product.
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The
PHENOL/ pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic
FORMALDEHYDE RESIN & skin reactions, e.g. contact urticaria, involve antibody-mediated immune reactions. The significance of the contact allergen is not
MELAMINE/ UREA/ simply determined by its sensitisation potential: the distribution of the substance and the opportunities for contact with it are
FORMALDEHYDE RESIN equally important. A weakly sensitising substance which is widely distributed can be a more important allergen than one with
stronger sensitising potential with which few individuals come into contact. From a clinical point of view, substances are
noteworthy if they produce an allergic test reaction in more than 1% of the persons tested.
The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may
produce conjunctivitis.
PHENOL/
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
FORMALDEHYDE RESIN
This form of dermatitis is often characterised by skin redness (erythema) and swelling the epidermis. Histologically there may be
intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epidermis.
Continued...
Chemwatch: 58017 Page 9 of 12 Issue Date: 29/09/2020
Version No: 13.1 Print Date: 01/02/2022
Laminex - Laminate Product
Serious Eye
STOT - Single Exposure
Damage/Irritation
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification
Toxicity
Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -
Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
Bioaccumulative potential
Ingredient Bioaccumulation
Mobility in soil
Ingredient Mobility
cellulose LOW (KOC = 10)
Continued...
Chemwatch: 58017 Page 10 of 12 Issue Date: 29/09/2020
Version No: 13.1 Print Date: 01/02/2022
Laminex - Laminate Product
Labels Required
Marine Pollutant NO
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
melamine/ urea/
Not Available
formaldehyde resin
Safety, health and environmental regulations / legislation specific for the substance or mixture
Australian Inventory of Industrial Chemicals (AIIC) International WHO List of Proposed Occupational Exposure Limit (OEL)
Values for Manufactured Nanomaterials (MNMS)
Continued...
Chemwatch: 58017 Page 11 of 12 Issue Date: 29/09/2020
Version No: 13.1 Print Date: 01/02/2022
Laminex - Laminate Product
12.1 01/11/2019 One-off system update. NOTE: This may or may not change the GHS classification
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch
Classification committee using available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks
in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available
engineering controls must be considered.
Continued...
Chemwatch: 58017 Page 12 of 12 Issue Date: 29/09/2020
Version No: 13.1 Print Date: 01/02/2022
Laminex - Laminate Product
end of SDS