PENETRATING Spray

Safety Data Sheet

according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Issue date: 06/07/2020 Revision date: 03/02/2023 Supersedes version of: 23/05/2022 Version: 11.2

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Mixture
Trade name : PENETRATING Spray
UFI : 9P30-N0CJ-500N-U21Y
Vaporizer : Aerosol

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Industrial use,Professional use
Industrial/Professional use spec : For professional use only
Industrial
Use of the substance/mixture : Lubricants, Greases and Release Products

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

Manufacturer
ROCOL a division of ITW Ltd
Rocol House Wakefield Rd, Swillington
LS26 8BS Leeds – West Yorkshire
United Kingdom
T +44 (0)113 232 2600
[email protected] - www.rocol.com

1.4. Emergency telephone number

Emergency number : +44 (0)113 232 2600

Country Organisation/Company Address Emergency number Comment

United Kingdom National Poisons Information Service Dudley Road 0344 892 0111 Only for healthcare
(Birmingham Centre) B18 7QH professionals
City Hospital

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]
Aerosol, Category 1 H222;H229
Full text of H- and EUH-statements: see section 16

Adverse physicochemical, human health and environmental effects

No additional information available

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :

GHS02
Signal word (CLP) : Danger

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PENETRATING Spray
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Hazard statements (CLP) : H222 - Extremely flammable aerosol.

H229 - Pressurised container: May burst if heated.
Precautionary statements (CLP) : P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
P211 - Do not spray on an open flame or other ignition source.
P251 - Do not pierce or burn, even after use.
P271 - Use only outdoors or in a well-ventilated area.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing
protection.
EUH-statements : EUH066 - Repeated exposure may cause skin dryness or cracking.

2.3. Other hazards

Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting
properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable

3.2. Mixtures

Name Product identifier % Classification according to

Regulation (EC) No. 1272/2008
[CLP]
HYDROTREATED NAPHTHENIC DISTILLATE CAS-No.: 64742-53-6 50 – 70 Carc. Not classified
(NOTE L <3% DMSO EXTRACTABLE EC-No.: 265-156-6 Asp. Tox. 1, H304
COMPONENTS) REACH-no: 01-2119480375-
34

HYDROCARBONS, C11-C14, N-ALKANES, CAS-No.: 64742-47-8 30 – 50 Asp. Tox. 1, H304

ISOALKANES, CYCLICS, <2% AROMATICS EC-No.: 926-141-6
REACH-no: 01-2119456620-
43

CARBON DIOXIDE AEROSOL PROPELLANT CAS-No.: 124-38-9 2.4 – 5 Press. Gas (Comp.), H280
substance with national workplace exposure limit(s) EC-No.: 204-696-9
(GB); substance with a Community workplace REACH-no: Exempt
exposure limit

CALCIUM DINONYLNAPHTHALENESULPHONATE EC-No.: 939-717-7 1 – 2.4 Skin Irrit. 2, H315

REACH-no: 01-2119980985- Eye Irrit. 2, H319
16
Product subject to CLP Article 1.1.3.7. The disclosure rules of the components is modified in this case.
Full text of H- and EUH-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice.
First-aid measures after inhalation : Allow affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persists.

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PENETRATING Spray
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayed
No additional information available

4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

No additional information available

5.3. Advice for firefighters

Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.

6.2. Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
Collect spillage.

6.4. Reference to other sections

See Section 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent
formation of vapour.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Keep container closed when not in use.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight.

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PENETRATING Spray
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

7.3. Specific end use(s)

No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

8.1.1 National occupational exposure and biological limit values

CARBON DIOXIDE AEROSOL PROPELLANT (124-38-9)

EU - Indicative Occupational Exposure Limit (IOEL)

Local name Carbon dioxide

IOEL TWA 9000 mg/m³

Regulatory reference COMMISSION DIRECTIVE 2006/15/EC

United Kingdom - Occupational Exposure Limits

Local name Carbon dioxide

WEL TWA (OEL TWA) [1] 9150 mg/m³

WEL TWA (OEL TWA) [2] 5000 ppm

WEL STEL (OEL STEL) 27400 mg/m³

WEL STEL (OEL STEL) [ppm] 15000 ppm

Regulatory reference EH40/2005 (Fourth edition, 2020). HSE

8.1.2. Recommended monitoring procedures

No additional information available

8.1.3. Air contaminants formed

No additional information available

8.1.4. DNEL and PNEC

No additional information available

8.1.5. Control banding

No additional information available

8.2. Exposure controls

8.2.1. Appropriate engineering controls
No additional information available

8.2.2. Personal protection equipment

Personal protective equipment:

Avoid all unnecessary exposure.
Personal protective equipment symbol(s):

8.2.2.1. Eye and face protection

Eye protection:
Chemical goggles or safety glasses

8.2.2.2. Skin protection

Hand protection:
Wear protective gloves. Nitrile rubber gloves

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PENETRATING Spray
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

8.2.2.3. Respiratory protection

Respiratory protection:
In case of inadequate ventilation wear respiratory protection. Wear a respirator conforming to EN140 with Type A filter or better

8.2.2.4. Thermal hazards

No additional information available

8.2.3. Environmental exposure controls

Other information:
Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid
Colour : Grey.
Odour : aromatic.
Odour threshold : Not available
Melting point : Not available
Freezing point : Not available
Boiling point : > 140 °C
Flammability : Non flammable.
Explosive limits : Not available
Lower explosion limit : Not available
Upper explosion limit : Not available
Flash point : > 62 °C
Auto-ignition temperature : > 200
Decomposition temperature : Not available
pH : Not available
Viscosity, kinematic : Not available
Solubility : insoluble in water.
Partition coefficient n-octanol/water (Log Kow) : Not available
Vapour pressure : Not available
Vapour pressure at 50°C : Not available
Density : Not available
Relative density : ≈ 0.8
Relative vapour density at 20°C : Not available
Particle characteristics : Not applicable

9.2. Other information

9.2.1. Information with regard to physical hazard classes
% of flammable ingredients : 0.67508 %

9.2.2. Other safety characteristics

VOC content : 331 g/l

SECTION 10: Stability and reactivity

10.1. Reactivity
Extremely flammable aerosol.

10.2. Chemical stability

Not established.

10.3. Possibility of hazardous reactions

Not established.

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PENETRATING Spray
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

10.4. Conditions to avoid

Direct sunlight. Extremely high or low temperatures.

10.5. Incompatible materials

Strong acids. Strong bases.

10.6. Hazardous decomposition products

fume. Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

HYDROTREATED NAPHTHENIC DISTILLATE (NOTE L <3% DMSO EXTRACTABLE COMPONENTS) (64742-53-6)

LD50 oral rat > 5000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 401 (Acute Oral
Toxicity), Guideline: OECD Guideline 420 (Acute Oral Toxicity - Fixed Dose Method)

LD50 dermal > 2000 mg/kg

HYDROCARBONS, C11-C14, N-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS (64742-47-8)

LD50 oral rat > 5000 mg/kg bodyweight Animal: rat, Guideline: EPA OTS 798.1175 (Acute Oral
Toxicity), Guideline: OECD Guideline 420 (Acute Oral Toxicity - Fixed Dose Method)

LD50 oral > 5000 mg/kg

LD50 dermal rabbit > 2000 mg/kg bodyweight Animal: rabbit, Guideline: EPA OTS 798.1100 (Acute Dermal
Toxicity), Guideline: OECD Guideline 402 (Acute Dermal Toxicity)

LD50 dermal > 5000 mg/kg

LC50 Inhalation - Rat > 5.28 mg/l air Animal: rat, Guideline: OECD Guideline 403 (Acute Inhalation Toxicity),
95% CL: 0,42 -

CALCIUM DINONYLNAPHTHALENESULPHONATE
LD50 dermal rabbit > 20000 mg/kg bodyweight Animal: rabbit, Guideline: other:FHSLA, CFR. Title 21. para.
191.10 and Appraisal of the Safety of 'Chemicals in Foods, Drugs and Cosmetics,
Association of Food and Drug Officials of the U.S.
Skin corrosion/irritation : Not classified
Additional information : Repeated exposure may cause skin dryness or cracking.
Serious eye damage/irritation : Not classified
Additional information : Based on available data, the classification criteria are not met
Respiratory or skin sensitisation : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : Not classified
Additional information : Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Additional information : Based on available data, the classification criteria are not met
Reproductive toxicity : Not classified
Additional information : Based on available data, the classification criteria are not met

HYDROCARBONS, C11-C14, N-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS (64742-47-8)

NOAEL (animal/male, F0/P) ≥ 3000 mg/kg bodyweight Animal: rat, Animal sex: male
STOT-single exposure : Not classified
Additional information : Based on available data, the classification criteria are not met
STOT-repeated exposure : Not classified
Additional information : Based on available data, the classification criteria are not met

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PENETRATING Spray
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

HYDROTREATED NAPHTHENIC DISTILLATE (NOTE L <3% DMSO EXTRACTABLE COMPONENTS) (64742-53-6)

LOAEL (oral, rat, 90 days) 125 mg/kg bodyweight Animal: rat, Animal sex: male, Guideline: OECD Guideline 408
(Repeated Dose 90-Day Oral Toxicity in Rodents)

NOAEL (dermal, rat/rabbit, 90 days) ≈ 1000 mg/kg bodyweight Animal: rabbit, Guideline: OECD Guideline 410 (Repeated Dose
Dermal Toxicity: 21/28-Day Study)

HYDROCARBONS, C11-C14, N-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS (64742-47-8)

NOAEL (oral, rat, 90 days) 750 mg/kg bodyweight Animal: rat, Animal sex: female

NOAEC (inhalation, rat, vapour, 90 days) ≥ 0.024 mg/l air Animal: rat, Guideline: OECD Guideline 412 (Subacute Inhalation Toxicity:
28-Day Study)

CALCIUM DINONYLNAPHTHALENESULPHONATE
NOAEL (oral, rat, 90 days) 95 – 298 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 422 (Combined
Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening
Test)
Aspiration hazard : Not classified
Additional information : Based on available data, the classification criteria are not met

PENETRATING Spray
Vaporizer Aerosol

HYDROTREATED NAPHTHENIC DISTILLATE (NOTE L <3% DMSO EXTRACTABLE COMPONENTS) (64742-53-6)

Viscosity, kinematic 8.5 mm²/s

Hydrocarbon Yes

HYDROCARBONS, C11-C14, N-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS (64742-47-8)

Viscosity, kinematic ≤ 2 mm²/s

Hydrocarbon Yes

11.2. Information on other hazards

11.2.1. Endocrine disrupting properties
No additional information available

11.2.2. Other information

Potential adverse human health effects and : Based on available data, the classification criteria are not met
symptoms

SECTION 12: Ecological information

12.1. Toxicity
Hazardous to the aquatic environment, short–term : Not classified
(acute)
Hazardous to the aquatic environment, long–term : Not classified
(chronic)

HYDROTREATED NAPHTHENIC DISTILLATE (NOTE L <3% DMSO EXTRACTABLE COMPONENTS) (64742-53-6)

LC50 - Fish [1] > 100 mg/l

EC50 - Other aquatic organisms [1] > 100 mg/l

HYDROCARBONS, C11-C14, N-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS (64742-47-8)

LC50 - Fish [1] > 1000 mg/l

EC50 - Other aquatic organisms [1] > 250 mg/l

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PENETRATING Spray
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

12.2. Persistence and degradability

PENETRATING Spray
Persistence and degradability Not established.

12.3. Bioaccumulative potential

PENETRATING Spray
Bioaccumulative potential Not established.

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Endocrine disrupting properties

No additional information available

12.7. Other adverse effects

Additional information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

In accordance with ADR / IMDG / IATA / ADN / RID
ADR IMDG IATA ADN RID

14.1. UN number or ID number

UN 1950 UN 1950 UN 1950 UN 1950 UN 1950

14.2. UN proper shipping name

AEROSOLS AEROSOLS Aerosols, flammable AEROSOLS AEROSOLS

Transport document description

UN 1950 AEROSOLS, 2.1, UN 1950 AEROSOLS, 2.1 UN 1950 Aerosols, UN 1950 AEROSOLS, 2.1 UN 1950 AEROSOLS, 2.1
(D) flammable, 2.1

14.3. Transport hazard class(es)

2.1 2.1 2.1 2.1 2.1

14.4. Packing group

Not applicable Not applicable Not applicable Not applicable Not applicable

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PENETRATING Spray
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

ADR IMDG IATA ADN RID

14.5. Environmental hazards

Dangerous for the Dangerous for the Dangerous for the Dangerous for the Dangerous for the
environment: No environment: No environment: No environment: No environment: No
Marine pollutant: No

No supplementary information available

14.6. Special precautions for user

Overland transport
Classification code (ADR) : 5F
Special provisions (ADR) : 190, 327, 344, 625
Limited quantities (ADR) : 1l
Excepted quantities (ADR) : E0
Packing instructions (ADR) : P207, LP200
Special packing provisions (ADR) : PP87, RR6, L2
Mixed packing provisions (ADR) : MP9
Transport category (ADR) : 2
Special provisions for carriage - Packages (ADR) : V14
Special provisions for carriage - Loading, unloading : CV9, CV12
and handling (ADR)
Special provisions for carriage - Operation (ADR) : S2
Tunnel restriction code (ADR) : D

Transport by sea
Special provisions (IMDG) : 63, 190, 277, 327, 344, 381, 959
Packing instructions (IMDG) : P207, LP200
Special packing provisions (IMDG) : PP87, L2
EmS-No. (Fire) : F-D
EmS-No. (Spillage) : S-U
Stowage category (IMDG) : None
Stowage and handling (IMDG) : SW1, SW22
Segregation (IMDG) : SG69

Air transport
PCA Excepted quantities (IATA) : E0
PCA Limited quantities (IATA) : Y203
PCA limited quantity max net quantity (IATA) : 30kgG
PCA packing instructions (IATA) : 203
PCA max net quantity (IATA) : 75kg
CAO packing instructions (IATA) : 203
CAO max net quantity (IATA) : 150kg
Special provisions (IATA) : A145, A167, A802
ERG code (IATA) : 10L

Inland waterway transport

Classification code (ADN) : 5F
Special provisions (ADN) : 190, 327, 344, 625
Limited quantities (ADN) : 1L
Excepted quantities (ADN) : E0
Equipment required (ADN) : PP, EX, A
Ventilation (ADN) : VE01, VE04
Number of blue cones/lights (ADN) : 1

Rail transport
Classification code (RID) : 5F
Special provisions (RID) : 190, 327, 344, 625
Limited quantities (RID) : 1L
Excepted quantities (RID) : E0
Packing instructions (RID) : P207, LP200

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PENETRATING Spray
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Special packing provisions (RID) : PP87, RR6, L2

Mixed packing provisions (RID) : MP9
Transport category (RID) : 2
Special provisions for carriage – Packages (RID) : W14
Special provisions for carriage - Loading, unloading : CW9, CW12
and handling (RID)
Colis express (express parcels) (RID) : CE2
Hazard identification number (RID) : 23

14.7. Maritime transport in bulk according to IMO instruments

Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

REACH Annex XVII (Restriction List)

Contains no substance(s) listed on REACH Annex XVII (Restriction Conditions)

REACH Annex XIV (Authorisation List)

Contains no substance(s) listed on REACH Annex XIV (Authorisation List)

REACH Candidate List (SVHC)

Contains no substance(s) listed on the REACH Candidate List

PIC Regulation (Prior Informed Consent)

Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)

POP Regulation (Persistent Organic Pollutants)

Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)

Ozone Regulation (1005/2009)

Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)

VOC Directive (2004/42)

VOC content : 331 g/l

Explosives Precursors Regulation (2019/1148)

Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)

Drug Precursors Regulation (273/2004)

Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain
substances used in the illicit manufacture of narcotic drugs and psychotropic substances)

15.1.2. National regulations

No additional information available

15.2. Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information

Indication of changes
Section Changed item Change Comments

Supersedes version of Added

Revision date Modified

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PENETRATING Spray
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances
and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and
amending Regulation (EC) No 1907/2006.
Other information : None.

Full text of H- and EUH-statements:

Asp. Tox. 1 Aspiration hazard, Category 1

Carc. Not classified Carcinogenicity Not classified

EUH066 Repeated exposure may cause skin dryness or cracking.

Eye Irrit. 2 Serious eye damage/eye irritation, Category 2

H222 Extremely flammable aerosol.

H229 Pressurised container: May burst if heated.

H280 Contains gas under pressure; may explode if heated.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H319 Causes serious eye irritation.

Press. Gas (Comp.) Gases under pressure : Compressed gas

Skin Irrit. 2 Skin corrosion/irritation, Category 2

Safety Data Sheet (SDS), EU

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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