HI

Series SSRR3/3 SET-2

iiiiiiih«iiiiiiih
Q.P. Code 56/3/2
■qO^TTSff 'bls <JvK-^fWcbl
Roll No.
Candidates must write the Q.P. Code
on the title page of the answer-book.

NOTE
(I) cfPW qq rf TO-Tq 3 ® Please check that this question paper
27 | I contains 27 printed pages.

(II) qfq qv TO-Vd 3 (ID Please check that this question paper
33TO^ I contains 33 questions.

(III) TO-Td 3 sfF (HI) Q.P. Code givenl on the right hand
❖ yRH-qq q?ls qd qftsinsff qrR-jfRtqq side of the question paper should be
qt wi 1 written on the title page of the
M answer-book by the candidate.
•x* (IV) ■5T5H TrR IrRsHI (IV) Please write down the serial
O^rl, cFTf sbHIcb number of the question in the
answer-book before attempting it.
(V) 15 ITO (V) 15 minute time has been allotted to
rpp I I (cfcHyi read this question paper. The
3 10.15 tor 1 question paper will be distributed
at 10.15 a.m. From 10.15 a.m. to
10.15 10.30 cHd
10.30 a.m., the students will
sfk 3jq1v % qkn
read the question paper only and
cf ^vR-qf^d'hl Tl f^^i) |
will not write any answer on the
answer-book during this period.

'('HUM RsIH (x1<glAl<T>)

CHEMISTRY (Theory)

I^TfftcT 77^: 3 37/^W : 70

Time allowed : 3 hours Maximum Marks: 70

56/3/2-15 1 P.T.O.
H
URTFR :
i^ff Rft uf^ir 3RRR :
(i) 'RT R 33 RRT f / Wft 1RR aifocfM f /
(it) RRRTR H fRmiRR f -3R, 7T, R UR ^ /
(Hi) ■(Si^-S R> - xw •HisR! 1 3 16 cfRy RFfRRRRiR Rrk & 16H f / y<~RR> l/W 1 31R> RR
t/
(iv) JRR fRsRT 17 R21 (RF 31f(T ^-RrTfiR & MW I 2 Zttt
Rflf /
(v) 7RVRR - R13R722 $28 (RF 1FFR t / 37r^ RTF 3 RFFl RF # /
(vi) j?-- WsVT29 RSF30 ^H-FRRlfRT RTF f / 37r^ RTF 4 3FF? RR f /
(vii) J7?F FRsFT 31 $33 5RFR RTF #' / RTF 5 3RF? FR # /
(viii) RTF-RR RRR FRi icRR RRT 9^
9^7 ■RiH fRFT RRT /
(ix) ^IH TR> RU^lTtSR] /
(x) RR c/W'/ 'l/Z-iri f I

•yu^ cf;

RlsRT 1 3 16 (79^ s/g'/Qqbe'^ RRR1 & 1 3T^ R> SRR / 16x1=16

1. fWf 3Wci4l-3W TjtfjjHF 3 PlHfdfisId 1dJl^ 3 3 ^H-HT Wft <d H1 c| <n c| d I

dchdl t ?

(A) nh3 2-
(B) SC 4

(C) no2 (D) c2 or

2. Cljd NiC12.4NH31 Hid 'ft AgN03 fcid^H (ndlU, di*} 44 AgCl <1 WT

PiWd I H^>d Ni fgJkch Hiil^cbdl KPft :

(A) 4 (B) 2

(C) 3 (D) 6

56/3/2-13 2 vV W\?s/s^AA7\/VA^V\,^-/vVvvWv

Jj
General Instructions :
Read the following instructions carefully and follow them :
(i) This question paper contains 33 questions. All questions are compulsory.
(ii) This question paper is divided into five sections - Section A, B, C, D and E.
(Hi) Section A - questions number 1 to 16 are multiple choice type questions. Each
question carries 1 mark.
(iv) Section B - questions number 17 to 21 are very short answer type questions.
Each question carries 2 marks.
(v) Section C - questions number 22 to 28 are short answer type questions. Each
question carries 3 marks.
(vi) Section D - questions number 29 and 30 are case-based questions. Each
question carries 4 marks.
(vii) Section E - questions number 31 to 33 are long answer type questions. Each
question carries 5 marks.
(viii) There is no overall choice given in the question paper. However, an internal
choice has been provided in few questions in all the sections except Section A.
(ix) Kindly note that there is a separate question paper for Visually Impaired
candidates.
(x) Use of calculators is not allowed.

SECTION A

Questions no. 1 to 16 are Multiple Choice type Questions, carrying 1 mark

each. 16x1=16

Which of the following ligands can show linkage isomerism in a

coordination compound ?
(A) NH3 (B) so*-
(C) NO2 (D) C2o2-

2. On adding AgNOs solution to 1 mole of complex NiC12.4NH3, two moles

of AgCl are formed. The secondary valency of Ni in the complex will be :

(A) 4 (B) 2

(C) 3 (D) 6

56/3/2-13 3 P.T.O.
E
3. eTv? srwft 3 ftwg ^RT f :
(A)
(B) <HcQ chuH ^IrTl |t
(C) rrh ar^anit f
(D) RWT RRH 3TTRN (RI^) |

4. PlHftffisld ajR-jfshqi m [cfciK ^ifRlJ. :

/CHg
Br2, y^Ri
-> ?
W ^§4 t :
/CHg ,CH3
(A) (B) -Br
\Br

CH2Br CHg
(C) (D)
Br

5. ft H Id Rd d 4lRl<=hl I pKa HH 3tc(dH I? ?

(A) p-dlS^Wdld
(B) m-dl^^dld

(C) P-sAm id
(D) 2,4,6-^l^<I^HTd

6. C6H5 - O - CHg HI BT2T vt t:

(A) C6H5 - I + CHg - OH

(B) CgHs-OH + CHg-I

(C) C6H5 - OH + CHg - OH

(D) C6H5-I + CH3-I

56/3/2-13 4
 Transition elements form alloys easily because they have :
(A) same electronic configuration
(B) same enthalpies of atomisation
(C) same oxidation states
(D) nearly the same atomic size

4. Consider the following reaction :

CHg
Br2, UV light
?

The major product obtained is :

CH3 CHg

(A) Br
(B)
^•Br

CH2Br CHg
(C) (D)
Br

5. Which one of the following compounds has the highest pKa value ?
(A) p-Nitrophenol
(B) m-Nitrophenol
(C) p-Cresol
(D) 2,4,6-Trinitrophenol

6. CgHg - O - CHg when treated with HI gives :

(A) CgHs-I + CHg-OH

(B) C6H5-OH + CH3-I

(C) C6H5 - OH + CH3 - OH
(D) CgHg-I + CHg-I
56/3/2-13 5 P.T.O.
H
7. pHfdfed qlRlcbl 3 $ tfr’Klfad 4dl<l^g BTS[
3rTr^ sHiar t ?

(A) (CH3)3N

(B) (CH3)2NH
(C) ch3ch2nh2

(D) c6h5nh2

8.
(A) c2h5nh2

(B) (C2H5)2NH
(C) (C2H5)3N
(D) nh-ch3

9. awr ‘ufa 3F^ar’ t?

(A) B (B) C
(C) K (D) A

10. fedd ‘X’ aa 1% fdol'MH ^Ul (atdT joqtiH = 342 g mol 1) % 6% fad44
tiHMAitild t I fddd ‘X’aa t :

(A) 34-2 g mol 1

(B) 57 g moli-l

(C) 114 g mol-1

(D) 3-42 g mol -1

56/3/2-13 6 ■A AtWVWAAa/WSa^
 Bl
7. Which of the following compounds on treatment with benzene sulphonyl
choride forms product insoluble in alkali ?

(A) (CH3)3N

(B) (CH3)2NH

(C) ch3ch2nh2

(D) C6H5NH2

8. Which of the following amines gives carbylamine reaction ?

(A) c2h5nh2

(B) (C2H5)2NH

(C) (C2H5)3N
(D) NH - CH3

9. ‘Night-Blindness’ is caused by the deficiency of Vitamin :

(A) B (B) C

(C) K (D) A

10. A 1% solution of solute ‘X’ is isotonic with a 6% solution of sucrose (molar

mass = 342 g mol-1). The molar mass of solute ‘X’ is :

(A) 34-2 g mol 1

(B) 57 g mol 1

(C) 114 g mol 1

(D) 3-42 g moli-l

56/3/2-13 7 P.T.O.

I
®aJ£

11. arfafshqi R arftcbiRh ri 3r4-3TFg RRH I^rft

t I stWru t :

(A)

(B) W
(C)

1
(D)
2
I
12. t?
(A)
(B)
I
I
(C)
I
(D)

U^TT 13 $16 & fenr, it fa? TH? f — /^7# 3Tf^F2F7 (A) (f8fT
chi^ui (K) ^77T 3fT^T 7^ ctoLs)

(A), (B), (C) 3fa(D)

(A) (A) 3^1 RHIW (R) f 3Tk (R), srtasR (A)

oi||<oi|i RRcTT t |

(B) (A) 3Tk (R) t, wg Rnrn (R), 3lfW-H (A)

oMIOAII t |

(C) (A) wg ^RUT (R) TRRT t I

(D) 3rfiRF2H (A) W t, wg RWT (R) t I

56/3/2-13 ) 8 ■A vWx/AaA/W/V'AtvVv^vV\A/vWv
 11. When the initial concentration of a reactant is doubled in the reaction,
the half life period remains same. The order of reaction is :

(A) First

(B) Second

(C) Zero

1
(D)
2

12. Which of the following is a secondary cell ?

(A) Dry cell

(B) Lead storage cell

(C) Mercury cell

(D) Daniell cell

For Questions number 13 to 16, two statements are given — one labelled
as Assertion (A) and the other labelled as Reason (R). Select the correct
answer to these questions from the codes (A), (B), (C) and (D) as given
I below.

(A) Both Assertion (A) and Reason (R) are true and Reason (R) is the
correct explanation of the Assertion (A).

(B) Both Assertion (A) and Reason (R) are true, but Reason (R) is not
the correct explanation of the Assertion (A).

(C) Assertion (A) is true, but Reason (R) is false.

(D) Assertion (A) is false, but Reason (R) is true.

56/3/2-13 P.T.O.
I

I
»
n
13. 3jfa^2H (A) : 3RWT iWTKT % Afa^H stk Afap^V ^T fI
(R): STdi^i [g<Wd if fd^d-fdrdMK ST-Ml-MfshdK,
feWK-fwiTW 3T--d)"MfK'Ml3if sth ifl^ fd^d-fcIcrl'M
ST-Kl^fshd Isti K KWT Wt’ KW f>
14.
^RW(R): RN 3 % KIST R'Kcft RKK I
I
15. 3Tf^SH (A) : fK ^T ,rHl if WKWT KT WWIK
KW (R) : -Sl^isTRT % 3TJ K^tKT 3WKT g|{| KKg f I
16. (A) : Qjd^d T^Utf-SblM-Krl KfafshK KTrft t I
^T^T(R) : J^T-KOd-H KfafKK 3 tPltffa, 3KK A1C13 KHT KKH
«Hldl t I

17. PtHprlRsld % KI2J Jrjchi-H ST^lfsh'MI f^rfeli; : 2x1=2

(^) H2N - OH
(^) Br2 SKT

18. fdHfdRsld <1MIdfdSlf^lfsh'Misti °Ft ^jyi ■ndtrld <=APt|l!i : 2x7=2

KH
(^) KMnO4 ------- >

(^) 2MnO; + SC^- + 16H+ ->

19. (^>) SKFRR ftwK KT RftRlfw cAfdM, I Idd R^<r’ti tl fKK WK

iwfw t ? 2
STSIen

(^) vsJkk ark ^d)H -friw ^rt WK W ^lidl WT t ? KWT

cOfdM, I K? fWKR tt fwi WK ftrKWTrK fWd WI t ? 2

56/3/2-13 10 x>AAA<VVx/vVsA'\x^V^/V/\/V'v\'VA\AAAz

I
1
' a®

13. Assertion (A) : A^^H and AmixV are zero for non-ideal solutions.
Reason (R): Solute-solvent interactions are not same as pure
solute-solute and pure solvent-solvent interactions in
non-ideal solutions.

14. Assertion (A) : Rate of reaction increases with increase in temperature.

Reason (R) : Number of effective collisions increase with increase in

temperature.

15. Assertion (A): The boiling point of ethanol is higher than that of
dimethyl ether.
Reason (R) : Dimethyl ether molecules are associated through
hydrogen bonding.

16. Assertion (A) : Aniline undergoes Friedel-Crafts reaction.

Reason (R): Aniline forms salt with AICI3, the Lewis acid in
Friedel-Crafts reaction.

SECTION B

17. Write the reactions of glucose with : 2x1=2

(a) H2N - OH

(b) Br2 water

18. Complete and balance the following chemical equations : 2x1=2

heat
(a) KMnO4 ---------- >
9—
(b) 2MnO; + 5C2O4 + 16H+ >

19. (a) Define molal depression constant. How is it related to enthalpy of

fusion ? 2
OR

(b) What type of deviation is shown by ethanol and acetone mixture ?

Give reason. What type of azeotropic mixture is formed by that
deviation ? 2

56/3/2-13 11 P.T.O.

♦
Eg
20. fd^dftffcsld if $ 4)Rl'+> Sj^l 3rfi|fsh^| if
3jfWi?n wrr sfk W ?
ch3
CH3 - CH - CH3 3TW CH3-C-Br
Br ch3

'Fdh^-Tlfd Wjyf 4dl<l$-S ^f ^<ddi if r-bd <+41

^TTt? 1+1=2

21. (^) Wt 31W^TT 3, stfiwCF ‘X’ wn <ftj ^pTT eft ift

^rfilfsbdI ^T 'Hdl^’W HHT 1ft ^FTdl t I 31^1^'Ml ^t 'Fife 'W t ?

(*j) W^rfcT fgsnfcB 37fW>^n J|fd4>d: ym <t

3^I5<UI I 1+1=2

T^rgiT

22. fa+dfolfisld 31firf^T3ft 3 A, B sfk C IK^FTR : 2x1 — =3

2
KCN LiAlHj HN02
(^) CH3CH2C1 + A-------- B
0°C
c
NO2

(^)
Fe/HCl NaN02 + HC1
+ A -------- ±--------- > B
c 6H55 OH
273 K

23. 3TH fdHfdf<9ld ^Ml-d<u| 5I^R H+RR ? (^ ?#7) 3x1=3

(R>) ^^sfl^ch 3RRT if
(^) ff^Rl ji)did

(^T) Qi-flt/niddld if 3Re1

(^) ^tRt^ftd it l-^fdel^^Hf^

56/3/2-13 12 J\A/\x/W>zxA/\WvsA^V\,Vy^^

4
'IS
20. (a) Which halogen compound in the following pair will react faster in
S^l reaction and why ?

CH3
CH3 - CH - CH3 or CH3 - C - Br

Br CH3

(b) Why is the dipole moment of chlorobenzene lower than that of

cyclohexyl chloride ? 1+1=2

21. (a) In a reaction, if the concentration of reactant ‘X’ is tripled, the rate
of reaction becomes twenty-seven times. What is the order of the
reaction ?

(b) State a condition under which a bimolecular reaction is kinetically

a first-order reaction. Give an example of such a reaction. 1+1=2

SECTION C

22. Give the structures of A, B and C in the following reactions : 2x1 - =3

2

KCN LiAlH4 hno2

(a) ch3ch2ci A---------- B
o°c
NO2

Fe/HCl NaNOn + HC1 CfiH.OH

(b) •> A--------- - ———+ B > C
273 K

23. How will you bring about the following conversions ? (any three) 3x1=3

(a) Benzoic acid to Benzaldehyde

(b) Ethanal to Propanone

(c) Acetophenone to Benzoic acid

(d) Bromobenzene to 1-Phenylethanol

56/3/2-13 13 P.T.O.

I 1
 24. (^>) PiHifelfed 3lfe[$bq|3ji 3 ^fenfeid ■
(i) RfefeRTT
(ii) I rd Slfefshd I

(^) '£hi’<d stl4]dH 2,4,6-<l59Tlo^dTd ^44 if 5R{tF 3Tf^<+>4-*

fefeiT I 2+1=3

25. TJ2W ^bTfe 3TfW^T 25% n 40 Z <dJld I '^Pl cFT

kr qRcbfdd i ta4 wr 3 rWsptt 80% ? 3
[f^I W t : log 2 = 0-30, log 3 = 0-48, log 4 = 0-60, log 5 = 0-69]

26. («fi) 2-9llHl®^H RR-3TWH $ (±)-®^R-2-3TTR 3 RRR <^1

RfWU^ft TjfdWRT (SN1 RSRfT Sn2) | ? ■RRR ({iRllJ, |

(^) W | d-d I Ch-/H 3TIt irfkR dvlkis-s i2R if -Hl fed H

rtsj srfwi Rfrt rktt t ? 2+1=3

27. 0-2 M KC1 fdddH ■did<=hdl 2-48 x 10-2 S cm 1 't I ^'HcQ ■dld'bdl
■feffcR 8ldl (a) M[15bRid cARlU, I 3
f^IT W | : I

1
X°K+ = 73-5 S cm2 mol 1

z° = 76-5 S cm2 mol 1

cr

28. 200 g RR 4 Rbdl 3141'Rdilrl feetd 5 g R 4 dd>< faddd «Hldl W I

300 K TR 4M 31-84 mm Hg t I WH WR goiWH dlfebfeld

cAfcm i 3
(300 K 41 RR R4 RPR Rd = 32 mm Hg)

56/3/2-13 14

4 4
n
24. (a) Write the reactions involved in the following :
(i) Reimer-Tiemann reaction
(h) Kolbe’s reaction

(b) Name the reagent used in the bromination of phenol to form

2,4,6-Tribromophenol. 2+1=3

25. A first-order reaction is 25% complete in 40 minutes. Calculate the value

of rate constant. In what time will the reaction be 80% complete ? 3

[Given : log 2 = 0-30, log 3 = 0-48, log 4 = 0-60, log 5 = 0-69]

26. (a) What type of nucleophilic substitution (S^l or 8^2) occurs in the

hydrolysis of 2-Bromobutane to form (±)-Butan-2-ol ? Give reason.

(b) What happens when chlorobenzene and methyl chloride are

treated with sodium metal in dry ether ? 2+1=3

27. The conductivity of 0-2 M solution of KC1 is 2-48 x 10“2 S cm 1. Calculate

its molar conductivity and degree of dissociation (a). 3

Given :

X° + = 73-5 S cm2 mol 1

K+
= 76-5 S cm2 mol 1
cr

28. A solution is prepared by dissolving 5 g of a non-volatile solute in 200 g of

water. It has a vapour pressure of 31-84 mm Hg at 300 K. Calculate the

molar mass of the solute. 3

(Vapour pressure of pure water at 300 K = 32 mm Hg)

56/3/2-13 15 P.T.O.

* J
 bWs

MW xw I 3^t MW) & Jrf< <f)fyy, /

29. sTIcDh £f w, sr^ i yltfln d^un 41^ 'Rrs a-^4)41

^Hril sigdcb t arrw 4 ^tu f I c^i i\4IhI

34lc|^ch Rfrrt BT^d Mi^dlri f I Rc|d< 34iqPjch 4, BT^d WT^qff yi^7fd

<vdR |> MdiR 34J-di ^1 liRl HT§I t i

34 [fucieh 34 |<4>frl % BTTUR qT JjIcDdl 4 cpIT^d R^l d Id I t : ^Rl<

Rfd'bl'bK 4l<fld I MlcOdl 4<dHI Bdicj-ifd qq BTMAM dR f4d Kill 1K R>q|

dT 44ddI t : Rldfad, lg4|q<+>, d4|q<+> xrq d^b 44<dHI^ I Mdl* dR 4RR 4>t
gdHT 4 dfed ^rTT | | pH BTSIdT RTR 4 dfW^ 3 dT

^cflqd-) ^RddlR dd KT dRft f BTfr 4 BIRR iJ4>l4 RRH 4 dSfR I iTlcfid

qq f4^>41d><’Jl ddrf f |

Pinftf Rslrl SHRt % 3vR ({ir^ :

(^) ^Wqch ^4)hI 3d<-d ct'MI qI?I |> ? 1

(^) ^41h) 34J-cdl % f?c(d< 3diqpcb Wj <=M| fI ? 1

(^ (i) 7^qR RWl ddl 4llldd|cbl< rWr qq Rd-Rd Bqi^i I

(ii) ylcDdl R^dddt dt fdd RdR di dd dts «sldl ? 2x1=2

sjaicn

(’T) (i) 44<xMI<-H=h Wwdl 1? 31W i!i4><i srf^R’W'Ji ^1

^11411 ?

(ii) sfh -^Rd^rt^r^ 3 W ’W<,'cl’1lrHch 2x1=2

56/3/2-13 16

k 4
I
 SECTION D

The following questions are case-based questions. Read the case carefully and
answer the questions that follow.

29. Proteins are the most abundant biomolecules of the living system.
Proteins are the polymers of about twenty different a-amino acids which
are linked by peptide bonds. Ten amino acids are called essential amino
acids. In zwitter ionic form, amino acids show amphoteric behaviour as
they react both with acids and bases.

On the basis of their molecular shape, proteins are classified into two
types : Fibrous and Globular proteins. Structure and shape of proteins can
be studied at four different levels i.e., primary, secondary, tertiary and
f quaternary, each level being more complex than the previous one. The
secondary or tertiary structure of proteins get disturbed on change of pH
or temperature and they are not able to perform their functions. This is
called denaturation of proteins.

Answer the following questions :

(a) What are essential amino acids ? 1

(b) What is meant by zwitter ionic form of amino acids ? 1

(c) (i) Give one example each for Fibrous protein and Globular
protein.

(ii) What type of linkages hold monomers of proteins together ? 2x1=2

OR
(c) (i) What is the structural feature which characterises a reducing
sugar ?

(ii) What is the structural difference between nucleoside and

nucleotide ? 2x1=2

56/3/2-13 17 P.T.O.

»
I I
30. WW ?fPt 3 (n - l)d wWt ^5
fdf^l^d ^yr KR ^Tcft I 3RI: MpcldT 3d'iWWul 3W-r4T3ff 3dfdf<Th <d9bH'Jl

qpjU Sd^J-dcQd Tjq 3^T 3rtl<c6 yyi f rWT VftH WH ^TTH Sl^fri ^Tli

3n?ft t I <ist>H’J| mgy ^Kd Ht 3Ttn^3Tf, 3Wfr3R, dl^Pd ^olPdl

srfdfsfdT ddTft f | KMnO4 3fk K2Cr2O7 WFRI 341^1 f I

3didf<4> <ishHU| TTr^t (TSn ypedT'M-S 34I<P <if-'X'IKb

pspn MhJ) f I <^hNSl 4 4f-^ST^ $<p£pl 34^1 mPuSF1! TTHR

(imperfect shielding effect) chl<ul WTTJ 9hHWTHJ ^MIM

^4 sbft<=h KTH KHn t d>l<ul SJFh^H ^Idl t I

fdJ-dGdfed M^dl % 3vl< :

(■^i) <-ist>'HKjl MTrjy dSTT 4lPlch 34^ 3r^l<4> Pfd ^RTl c 1

(Tsf) C'fcsI’INSl WTPI 34HIM (size) 3^1 4tT 44T cbl<ul t? 1

(1T) 3d|j>'dd 1crft^lfad dilfdU, I ’HsbHul Xp

WTP] |3ti fei 5)W ^FTT t ? 2

ajsicn

(d) TJTWI 3, Cr2+ 3JS!dT Fe2+ 3 £ d^T-dl 3WR 3dMdm t 3fk ddf ? 2

56/3/2-13 18 aaazWVWvw>aaa^a/wa/\Aa/'A/v

4
t i
I

30. The involvement of (n - l)d electrons in the behaviour of transition

elements impart certain distinct characteristics to these elements. Thus,
in addition to variable oxidation states, they exhibit paramagnetic
behaviour, catalytic properties and tendency for the formation of coloured
ions. The transition metals react with a number of non-metals like
oxygen, nitrogen and halogens. KMnO4 and K^CrgOy are common
examples.

The two series of inner transition elements, lanthanoids and actinoids,

constitute the f-block of the periodic table. In the lanthanoids, there is
regular decrease in atomic size with increase in atomic number due to the
imperfect shielding effect of 4f-orbital electrons which causes contraction.

Answer the following questions :

(a) Why do transition metals and their- compounds act as good

catalysts ? 1

(b) What is the cause of contraction in the atomic size of lanthanoids ? 1

(c) Define lanthanoid contraction. How does it affect the atomic radii of
the third transition series and the second transition series ? 2

OR

(c) In aqueous media, which is a stronger reducing agent —

Cr2+ or Fe2+ and why ? 2

56/5/2-13 19 P.T.O.

I
I J
31. Pinftf Rsld 3rR fdfeu, : 5x1=5

(
I
(^) [Co(H2O)(CN)(en)2]2+^T IUPACHTR I
I

(73) ■c|^’+>r1'A'4 'gt fXR 5FFR i^PFg

^|[i|c{|i| <lHHdddl RRt B'RR RFft ?

l
(TT) Rnldfed WHi 3H^t fsh^d WH 3^d (Ao)
oMdf^SRT :

[Co(NH3)g]3+, [CoF6]I3-, [Co(CN)6]3~

(^) 3TR^ Rl^ld SH^R RI [Ni(CO)4] ^w:°T

■cjMIeAq oqd^K RTi fefeR |

[Ni wn^j sbni^ = 28]

[CoF6]3- 3Tk [00(6204)3]3 ■HJd d^d-KT ’WJd :

0?)
(i) srfe wft t ?
(ii) <5^ SM$bul ?

(^) 3W[<ft fdJl^ 3Tk ldJlA 3 W 3RR t ?

(?5) 3db<iLbdcPl’i1 d° RR ^d^Tfdch t2ig e„ Rgt R ftffcsiy,

o

(i) Ao > P, 3fk (ii) Ao < P

56/3/2-13 20 xAz^^A'\^A^V,V\^aAVkvWvV'i/\'\A/

1
/ I
 SECTION E

31. Attempt any five of the following : 5x1=5

(a) Write the IUPAC name of the complex :

[Co(H2O)(CN)(en)2]2+

(b) Why is geometrical isomerism not possible in tetrahedral complexes

having two different types of unidentate ligands coordinated with
the central metal ion ?

(c) Arrange the following complex ions in increasing order of their

crystal field splitting energy (Ao) :
[Co(NH3)6]3+, [CoFg]3-, [Co(CN)6] 3-

(d) Write the hybridization and magnetic character of the complex

[Ni(CO)4l on the basis of valence bond theory.

[Atomic No. : Ni = 28]

0_ O_
(e) Out of [CoFg] and [Co(C2O4)3] » which one complex is :
I
I (i) more stable ?
(ii) the high spin complex ?

(f) What is the difference between an ambidentate ligand and

bidentate ligand ?

(g) Write the electronic configuration of d5 in terms of t2g and eg in an

octahedral field when :

(i) Ao > P, and (ii) A0<P

56/3/2-13 21 P.T.O.

I
i
 1

E^®

32. (^) (i) 25°C pHldf^d Tl?[ k.^T. W (emf) vft^Td eftfa^ :

Zn(s) | Zn2+(0-001M) | | Cd2+(0-1 M) | Cd (s)

fw W t : E0 .2+ = - 0-76 V, E°
E 9 = 0-40 V [log 10 = 1]
Zn2+/Zn (Cd24,/Cd

(ii) fa^cT-amMck ^T fefrr fwr I NaCl

eft pH f^T WIT Wlfer ft1)) IWT f^T-aiM^cH fw WTT

t? 3+2=5

i
1
i

STSIeH
I

(^) (i) ftHldPdd 3k aifWkT fkJ. ArG° ahi log Kc MPicbldd ^ftftk :
4- 9-L z s
Fe (s) + Ag (aq) Fe (aq) + Ag (s)
fen W t : E° = o-44 V, E° +
Ag+; Ag
= + 0-80 V
Fe2+/Fe
1 F = 96500 C mol-1

(ii)

(iii) 1 h)^1 H2O % O2 adTet-Jl^ui f^pr [cheft ^><1^ 3TR^I^i ?

3+l+l=5

56/3/2-13 22

I
1
1^®

32. (a) (i) Calculate emf of the following cell at 25°C :

Zn(s) | Zn2+(0-001M) | | Cd2+ (0-1 M) | Cd(s)

Given : E° = - 0-76 V, E° = - 0-40 V [log 10 = 1]

Zn 2+/Zn Cd 2+/Cd

(ii) State Faraday’s second law of electrolysis. How will the pH of

aqueous NaCl solution be affected when it is electrolysed ? 3+2=5

OR

(b) (i) Calculate the ArG° and log for the following cell reaction :

Fe (s) + Ag^ (aq) Fe2+(aq) + Ag (s)

Given: E° 9 =-0-44V, E .
= — 0-44 V, E° = + 0-80 V,
Fe2+ZFe
2+/Fe Ag7Ag
1 F = 96500 C mol-1

(ii) Write any two advantages of the fuel cells over primary and
secondary batteries ?

(iii) How many Faradays are required for the oxidation of 1 mole
ofH2OtoO2? 3+l+l=5

56/3/2-13 23 P.T.O.
 I

33. (^) (i) pHRlfyd 3^f9hdl3Tf 4rMl< IdfelO, :

CH2CH3 a) KMnO4 , KOH

(1) ?
b)H+
NaOH
(2) CHO + CII33 - C - C.II3 — - ------------ > 9
II
o
COOH
Br9 / FeBro
(3) —£-------- £> 9

(ii) pHfdfed qlFl* ^Irft 3 W iHldPid-) Rft^PT

^tWl. :

COCHo COCH2CH3
•>
3TR
(1)

(2) ^T-3-3]H 3+2=5

3J2Ien

(H) (i) pHfdf^d % fdU,

(1) chcltf — NH2 ■fnp? fcRxH

-W^ldd KtrU t I

(2) ^4ldld ^HT 3 HCN Trfa

Sjftfshd l^fld KtcTT | I

56/3/2-13 24 WWA'ATsA/VAVVvVWAAVAA/v
33. (a) (i) Write the major product(s) in the following reactions :
ch2ch3 a) KMnO4 , KOH
(1) --------------- 3------------ > 9
b) H+

(2) dil NaOH> 9.

OHO + CH3 ~ c - ch3 ----------------

O
COOH
Br2±
— / FeBro 9
(3)

(ii) Give simple chemical tests to distinguish between the

following pairs of compounds :

COCHg COC.H2CH3
and
(1)

(2) Pentanal and Pentan-3-one 3+2=5

OR

(b) (i) Give reasons for the following :

(1) In semicarbazide, only one - NH2 group is involved in

the formation of semicarbazone.

(2) Acetaldehyde is more reactive than acetone towards

addition of HCN.

56/3/2-13 25 P.T.O.
n
(ii) (1) PlHfelfeld STJ^fhT WT24 % 7JZH sCT oq^SRT

CHgCOOH, O2N - CH2 - COOH, HCOOH

(2) fdHRlfiad SrRdfsb'MI IdU, 31facb4'+> HH ■

r

CH3 - CH = CH - CH2 - CN ■»

CH3 - QH = CH - CH2 - CHO

(iii) STfW^IT 3 Sjf^rfsPIT I 2+2+1=5

56/3/2-13 26
1

(ii) (1) Arrange the following in decreasing order of their acidic

strength :
CHgCOOH, O2N - CH2 - COOH, HCOOH

(2) Name the reagent in the following reaction :

?
CH3 - CH = CH - CH2 - CN -—>

CH3 - CH = CH - CH2 - CHO

(iii) Write the reaction involved in Hell-Volhard-Zelinsky reaction.

2+2+1=5

56/3/2-13 27
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