MATERIAL SAFETY DATA SHEET

1. Product and Company Identification

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Product Name
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AIR WICK® Air Freshener (Aerosols All Scents)
CAS #
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Mixture
This MSDS is designed for workplace employees, emergency personnel and for other
conditions and situations where there is a greater potential for large-scale or prolonged
exposure, in accordance with requirements of the U.S. Government's Occupational
Safety and Health Administration (OSHA).
This MSDS is not applicable for consumer use of our products. For consumer use, all
precautionary and first aid language is provided on the product label in accordance with
the applicable government regulation.

Air freshener Product Use

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Distributed by Reckitt Benckiser

Morris Corporate Center IV
399 Interpace Parkway
P.O. Box 225
Parsippany, NJ 07054-0225
In Case of Emergency: 1-800-338-6167
Transportation Emergencies: 24 Hour Number:
North America: CHEMTREC: 1-800-424-9300
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Outside North America: 1-703-527-3887
LEGEND Health / 0
HMIS/NFPA
Flammability 1
1
Severe 4
Serious 3
Physical Hazard 0
0 0
Moderate 2
Slight 1 Personal Protection
Minimal 0 B
.

2. Hazards Identification
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Emergency overview CAUTION

EYE IRRITANT. Prolonged or frequent skin contact may cause an allergic reaction.
CONTENTS UNDER PRESSURE.
DO NOT spray towards face. Avoid contact with eyes and skin. CONTAINER MAY
EXPLODE IF HEATED. Do not puncture or incinerate container. DO NOT expose to heat
or store at temperatures above 120°F (49°C) as the container may burst.

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KEEP OUT OF REACH OF CHILDREN AND PETS.
Potential short term health effects
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Routes of exposure Eye, Skin contact, Inhalation.
Eyes None expected during normal conditions of use.
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May cause eye irritation upon direct contact with the eyes.
Skin None expected during normal conditions of use.
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Prolonged or frequent skin contact may cause an allergic reaction.
Inhalation None expected during normal conditions of use.
Intentional misuse by deliberately concentrating and inhaling the contents may be
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harmful or fatal.
Ingestion Health injuries are not known or expected under normal use.
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Target organs Eyes.

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Chronic effects
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The finished product is not expected to have chronic health effects.
Signs and symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
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vomiting.
OSHA Regulatory Status This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
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Standard, 29 CFR 1910.1200.
Potential environmental effects This product has not been tested.

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3. Composition / Information on Ingredients

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Ingredient(s) CAS # Percent

Propane 74-98-6 7 - 13
Butane 106-97-8 10 - 30
Ethane, 1,1-difluoro- 75-37-6 10 - 30
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4. First Aid Measures

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First aid procedures

Eye contact If in eyes, IMMEDIATELY rinse eyes with plenty of water. Remove any contact lenses
and continue rinsing eyes for at least 15 minutes. If irritation persists, get medical
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attention.
Skin contact If on skin, wash with soap and water. If Irritation develops, get medical attention.
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Inhalation Move to fresh air in case of accidental inhalation of vapors.

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Ingestion Rinse mouth with water and drink afterwards plenty of water. DO NOT INDUCE
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VOMITING.
Notes to physician Treat patient symptomatically.
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General advice Do not puncture or incinerate container. Keep away from sources of ignition. No
smoking. If you feel unwell, seek medical advice (show the label where possible). Ensure
that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Show this safety data sheet to the doctor in attendance. Avoid
contact with eyes and skin. Keep out of reach of children.

NOTE TO PARENTS: Intentional misuse by deliberately concentrating and inhaling

aerosol products may be harmful or fatal. Help stop inhalation abuse; for information visit
[Link].
.

5. Fire Fighting Measures

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Flammable properties Non-flammable aerosol by flame projection test.

NFPA AEROSOL LEVEL: Flammability Rating 1, per NFPA 30B

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Extinguishing media
Suitable extinguishing media
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Dry chemical. Foam.
Unsuitable extinguishing media Water. Water spray.
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Protection of firefighters
Specific hazards arising from Contents under pressure. Pressurized container may explode when exposed to heat or
the chemical flame. Cool containers with flooding quantities of water until well after fire is out.
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Protective equipment for Firefighters should wear full protective clothing including self contained breathing
firefighters apparatus.
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Hazardous combustion products May include and are not limited to: Oxides of carbon.
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Explosion data
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Sensitivity to mechanical impact Not available
Sensitivity to static discharge Not available
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6. Accidental Release Measures

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Personal precautions Do not touch or walk through spilled material. Do not touch damaged containers or
spilled material unless wearing appropriate protective clothing. Keep people away from
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and upwind of spill/leak. Keep unnecessary personnel away.
Environmental precautions Prevent further leakage or spillage if safe to do so.
Do not contaminate water.
Do not allow material to contaminate ground water system.
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Advise authorities if product has penetrated drains, sewers or water pipes.
Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements
or confined areas.

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Methods for cleaning up Before attempting clean up, refer to hazard data given above. Remove sources of
ignition. Although the chance of a significant spill or leak is unlikely in aerosol
containers, in the event of such an occurrence, absorb spilled material with a
non-flammable absorbent such as sand or vermiculite.
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7. Handling and Storage

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Handling Ensure adequate ventilation.

DO NOT spray towards face.
Pressurised container: protect from sunlight and do not expose to temperatures
exceeding 50°C (120°F). Do not pierce or burn after use. Keep away from all sources of
ignition. Fires involving aerosols with flammable contents are severe and can spread
quickly. Warehouses or stores containing aerosols should therefore be separated from
other areas by a fire resistant construction. Stores should be well ventilated. The natural
ventilation in a large open warehouse building will normally be suitable.
Do not spray on a naked flame or any other incandescent material.
Use good industrial hygiene practices in handling this material.
When using do not eat or drink.
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Wash hands before breaks and immediately after handling the product.
Storage DO NOT expose to heat or store at temperatures above 120°F (49°C) as the container
may burst.
Do not puncture or incinerate container.
CONTAINER MAY EXPLODE IF HEATED.
Keep away from heat, open flames or other sources of ignition.
Store in a cool place.
Keep out of reach of children.

NOTE TO PARENTS: Intentional misuse by deliberately concentrating and inhaling

aerosol products may be harmful or fatal. Help stop inhalation abuse; for information visit
[Link].
.

8. Exposure Controls / Personal Protection

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Exposure limits
Ingredient(s) Exposure Limits

Butane ACGIH-TLV
TWA: 1000 ppm
OSHA-PEL
Not established

Ethane, 1,1-difluoro- ACGIH-TLV

Not established
OSHA-PEL
Not established

Propane ACGIH-TLV
TWA: 1000 ppm
OSHA-PEL
TWA: 1000 ppm
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Engineering controls
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Provide adequate ventilation.
Personal protective equipment
Consult the product label for special protection or precautions that have been identified
for using this product under directed consumer use conditions. The following
recommendations are given for workplace employees, emergency personnel and for
other conditions and situations where there is a greater potential for large-scale or
prolonged exposure.

Eye / face protection Not required under normal use conditions. Emergency
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responders should wear full eye and face protection.
Hand protection No special requirements under normal use conditions.
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Emergency responders should wear impermeable gloves.
Skin and body protection No special requirements under normal use conditions.
Prolonged or frequent skin contact may produce an allergic reaction in some
individuals.

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Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator.
Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid
inhalation of vapours generated by this product during a spill or other clean-up
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operations.
General hygiene considerations Avoid contact with skin, eyes and clothing.
Washing with soap and water after use is recommended as good hygienic practice to
prevent possible eye irritation from hand contact.
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9. Physical and Chemical Properties

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Appearance
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Aerosol.
Color
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Clear
Form
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Misty spray
Odor
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Characteristic
Odor threshold
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Not available
Physical state
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Gas
pH
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Not available
Freezing point
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Not available
Boiling point
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Not available
Pour point
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Not available
Evaporation rate
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Not available
Flash point
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Not available
Auto-ignition temperature
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Not available
Flammability limits in air, lower, % Not available
by volume
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Flammability limits in air, upper, % Not available

by volume
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Vapor pressure Not available

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Vapor density
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Not available
Specific gravity
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Not available
Octanol/water coefficient Not available
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10. Stability and Reactivity

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Reactivity
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This product may react with oxidizing agents.
Possibility of hazardous reactions
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Hazardous polymerization does not occur.
Chemical stability
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Stable under recommended storage conditions.
Conditions to avoid Keep away from open flames, hot surfaces and sources of ignition.
Protect from sunlight and do not expose to temperatures exceeding 50°C (120°F).
Extremes of temperatures can occur in cars and near ovens and fireplaces.
Do not place in contact with hot surfaces or near naked flames.
Do not pierce or burn after use.
Do not spray on a naked flame, onto or near a fire, or any incandescent material such as
an electric fire.
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Aerosol containers are unstable at temperatures above 49°C (120.2°F).
Incompatible materials
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Caustics. Oxidizers. Acids.
Hazardous decomposition products May include and are not limited to: Oxides of carbon.
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11. Toxicological Information

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Component analysis - LC50

Ingredient(s) LC50

Butane Not available

Ethane, 1,1-difluoro- > 64000 ppm rat
Propane Not available

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Component analysis - Oral LD50

Ingredient(s) LD50

Butane Not available

Ethane, 1,1-difluoro- 1500 mg/kg rat
Propane
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Not available
Effects of acute exposure
Eye None expected during normal conditions of use.
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May cause eye irritation upon direct contact with the eyes.
Skin None expected during normal conditions of use.
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Prolonged or frequent skin contact may cause an allergic reaction.
Inhalation None expected during normal conditions of use.
Intentional misuse by deliberately concentrating and inhaling the contents may be
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harmful or fatal.
Ingestion Health injuries are not known or expected under normal use.
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Sensitization The finished product is not expected to have chronic health effects.
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Chronic effects The finished product is not expected to have chronic health effects.
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Carcinogenicity The finished product is not expected to have chronic health effects.
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Mutagenicity The finished product is not expected to have chronic health effects.
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Reproductive effects The finished product is not expected to have chronic health effects.
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Teratogenicity
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The finished product is not expected to have chronic health effects.
Name of Toxicologically Synergistic Not available
Products
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12. Ecological Information

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Ecotoxicity
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This product has not been tested.
Persistence / degradability
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Not available
Bioaccumulation / accumulation
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Not available
Mobility in environmental media
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Not available
Environmental effects
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Not available
Aquatic toxicity
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Not available
Partition coefficient
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Not available
Chemical fate information Not available
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13. Disposal Considerations

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Disposal instructions Dispose in accordance with all applicable regulations.

Container disposal: Empty containers may be included with domestic refuse for disposal
to a landfill. This container may also be recycled in communities where aerosol container
recycling is available. Before offering for recycling, empty the can or use the product
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according to the label instructions.
Waste from residues / unused Not available
products
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Contaminated packaging Not available

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14. Transport Information

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U.S. Department of Transportation (DOT)

UN 1950, Aerosols, Class 2.1, Limited Quantity

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Transportation of Dangerous Goods (TDG - Canada)

UN 1950, Aerosols, Class 2.1, Limited Quantity

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IMDG (Marine Transport)

UN 1950, Aerosols, Class 2.1, Limited Quantity

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IATA/ICAO (Air)

UN 1950, Aerosols, Flammable, Class 2.1

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15. Regulatory Information

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Occupational Safety and Health Administration (OSHA)

29 CFR 1910.1200 hazardous Yes
chemical
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US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
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Standard, 29 CFR 1910.1200.
CERCLA (Superfund) reportable quantity
None
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Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - Yes
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Reactivity Hazard - No
Section 302 extremely No
hazardous substance
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Section 311 hazardous chemical No

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Clean Air Act (CAA) Not available

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Clean Water Act (CWA)

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Not available
State regulations This product does not contain a chemical known to the State of California to cause
cancer, birth defects or other reproductive harm.
U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances
Butane 106-97-8 Present
U.S. - Massachusetts - Right To Know List
Butane 106-97-8 Present
Ethane, 1,1-difluoro- 75-37-6 Present
Propane 74-98-6 Present
U.S. - Minnesota - Hazardous Substance List
Butane 106-97-8 Present
Propane 74-98-6 Simple asphyxiant
U.S. - New Jersey - Right to Know Hazardous Substance List
Butane 106-97-8 sn 0273
Ethane, 1,1-difluoro- 75-37-6 sn 0715
Propane 74-98-6 sn 1594
U.S. - Pennsylvania - RTK (Right to Know) List
Butane 106-97-8 Present
Propane 74-98-6 Present
U.S. - Rhode Island - Hazardous Substance List
Butane 106-97-8 Toxic; Flammable
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Propane 74-98-6 Toxic; Flammable
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
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16. Other Information

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Disclaimer This product should only be used as directed on the label and for the purpose intended.
To the best of our knowledge, the information contained herein is accurate. However,
neither the above named supplier nor any of its subsidiaries assumes any liability
whatsoever for the accuracy or completeness of the information contained herein. Final
determination of suitability of any material is the sole responsibility of the user. All
materials may present unknown hazards and should be used with caution. Although
certain hazards are described herein, we cannot guarantee that these are the only
hazards that exist.

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Further information AIR WICK® 4-In-1 Air Freshener - Apple Cinnamon Medley, 8 oz - 0.188360v2.0
AIR WICK® 4-In-1 Air Freshener - Cool Linen & White Lilac, 8 oz - 0192143v2.0
AIR WICK® 4-In-1 Air Freshener - Fresh Waters, 8 oz - 0192143v2.0
AIR WICK® 4-In-1 Air Freshener - Lavender & Chamomile, 8 oz - 0121604v2.0
AIR WICK® 4-In-1 Air Freshener - Magnolia & Cherry Blossom, 8 oz - 0188398v2.0
AIR WICK® 4-In-1 Air Freshener - Papaya & Mango, 8 oz - 0188364v2.0
AIR WICK® 4-In-1 Air Freshener - Rain Garden, 8 oz - 0188387v2.0
AIR WICK® 4-In-1 Air Freshener - Sparkling Citrus, 8 oz - 0188375v2.0
AIR WICK® 4-In-1 Air Freshener - Vanilla Indulgence, 8 oz - 0188341v2.0
AIR WICK® Air Freshener - Serene Waters (National Parks - Glacier Bay), 8 oz -
0192143v2.0
AIR WICK® Air Freshener - Tropical Sunset (National Parks - Hawaii), 8 oz -
0.188364v2.0
AIR WICK® Air Freshener - Vanilla Sugar Cookies (Festive Moments), 8 oz -
0299270v2.0
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AIR WICK Air Freshener - Warm Apple Pie (Festive Moments), 8 oz - 0340663v1.0
Issue date
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26-Sep-2012
Effective date
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15-Sep-2012
Prepared by
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Reckitt Benckiser Regulatory Department 800-333-3899
Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first
page of the document.

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