VISHNU DHARM SCHOOLS

Subject : Chemistry 11EM CHEMISTRY JEE NEET 2 Paper Set : 1

Standard : 11 AND 3 Date : 23-02-2024
Total Mark : 400 Time : 1H:0M

(7) If wavelength of photon is 2.2 × 10−11 m,

......... Chemistry - Section A (MCQ) .........
h = 6.6 × 10−34 J − sec, then momentum of
photon is
(1) The number of s-electrons present in an ion
with 55 protons in its unipositive state is (A) 3 × 10−23 kg ms−1
(A) 8 (B) 9 (B) 3.33 × 1022 kg ms−1
(C) 12 (D) 10 (C) 1.452 × 10−44 kg ms−1
(2) Maximum number of electrons that can be (D) 6.89 × 1043 kg ms−1
accommodated in shell with n = 4 are:
(A) 16 (B) 32 (8) If electron falls from n = 3 to n = 2, then
emitted energy is ........... eV
(C) 50 (D) 72
(A) 10.2 (B) 12.09
(3) Arrange the following orbitals in decreasing
order of energy ? (C) 1.9 (D) 0.65
(A) n = 3, 1 = 0, m = 0 (9) If change in energy
(B) n = 4, l = 0, m = 0 (∆E) = 3 × 10−8 J, h = 6.64 × 10−34 J−s and
(C) n = 3, l = 1, m = 0 c = 3 × 108 m/s, then wavelength of the light
(D) n = 3, l = 2, m = 1 is
o o
The correct option for the order is : (A) 6.36 × 103 A (B) 6.36 × 105 A
(A) B > D > C > A (B) D > B > C > A o o
(C) 6.64 × 10−8 A (D) 6.36 × 1018 A
(C) A > C > B > D (D) D > B > A > C
(4) Which one of the following is not the (10) The radius of first Bohr’s orbit for hydrogen
o
characteristic of Planck’s quantum theory of is 0.53 A . The radius of third Bohr’s orbit
o
radiation would be .............. A
(A) The energy is not absorbed or emitted in (A) 0.79 (B) 1.59
whole number or multiple of quantum
(C) 3.18 (D) 4.77
(B) Radiation is associated with energy (11) The energy of a radiation of wavelength
o
(C) Radiation energy is not emitted or 8000 A is E1 and energy of a radiation of
absorbed conti- nuously but in the form o
wavelength 16000 A is E2 . What is the
of small packets called quanta
relation between these two
(D) This magnitude of energy associated (A) E1 = 6E2 (B) E1 = 2E2
with a quantum is proportional to the (C) E1 = 4E2 (D) E1 = 1/2E2
frequency
(12) The emission spectrum of hydrogen is found
(5) The energy of second Bohr orbit of the to satisfy the expression for the energy
hydrogen atom is −328 kJ mol −1 , hence the change. ∆E (in(joules))such that
energy of fourth Bohr orbit would be
∆E = 2.18 × 10 n12 − n12 J where n1 = 1, 2, 3.
.............. kJ mol−1 1 2

(A) −41 (B) −1312 . . .. and n2 = 2, 3, 4....... The spectral lines

correspond to Paschen series to
(C) −164 (D) −82
(A) n1 = 1 and n2 = 2, 3, 4
(6) The frequency of an electromagnetic
radiation is 2 × 106 Hz. What is its (B) n1 = 3 and n2 = 4, 5, 6
wavelength in metres (Velocity of light (C) n1 = 1 and n2 = 3, 4, 5
= 3 × 108 ms−1 )
(A) 6.0 × 1014 (B) 1.5 × 104 (D) n1 = 2 and n2 = 3, 3, 5

(C) 1.5 × 102 (D) 0.66 × 10−2 (13) The frequency corresponding to transition

1
 n = 2 to n = 1 in hydrogen atom is (20) The de-Broglie wavelength associated with a
(A) 15.66 × 1010 Hz (B) 24.66 × 1014 Hz particle of mass 10−6 kg moving with a
velocity of 10 ms−1 , is
(C) 30.57 × 1014 Hz (D) 40.57 × 1024 Hz
(A) 6.63 × 10−22 m (B) 6.63 × 10−29 m
(14) According to Bohr’s principle, the relation
between principle quantum number (n) and (C) 6.63 × 10−31 m (D) 6.63 × 10−34 m
radius of orbit is (21) The uncertainty in momentum of an
(A) r ∝ n (B) r ∝ n2 electron is 1 × 10−5 kg − m/s. The uncertainty
(C) r ∝ n1 (D) r ∝ n12 in its position will be
(h = 6.62 × 10−34 kg − m2 /s)
(15) The energy of electron in hydrogen atom in
(A) 1.05 × 10−28 m (B) 1.05 × 10−26 m
its grounds state is −13.6 eV . The energy of
the level corresponding to the quantum (C) 5.27 × 10−30 m (D) 5.25 × 10−28 m
number equal to 5 is ............. eV (22) The uncertainty in the position of a moving
(A) −0.54 (B) −0.85 bullet of mass 10 gm is 10−5 m. Calculate the
(C) −0.64 (D) −0.40 uncertainty in its velocity
(16) The energy of one mole of photons of (A) 5.2 × 10−28 m/sec
radiation of wavelength 300nm is ...... (B) 3.0 × 10−28 m/sec
kJ mol−1 .
(Given : (C) 5.2 × 10−22 m/sec
h = 6.63 × 10−34 Js, NA = 6.02 × 1023 mol−1 , (D) 3 × 10−22 m/sec
c = 3 × 108 ms−1 )
(A) 235 (B) 325 (23) Be′ s 4th electron will have four quantum
numbers
(C) 399 (D) 435 nlms
(17) Given below are two statements : one is (A) 1 0 0 +1/2 (B) 1 1 +1 +1/2
labelled as Assertion A and the other is (C) 2 0 0 −1/2 (D) 2 1 0 +1/2
labelled as Reason R:
Assertion A: In the photoelectric effect, the (24) The electronic configuration of silver atom
electrons are ejected from the metal surface in ground state is
as soon as the beam of light of frequency (A) [Kr]3d10 4s1 (B) [Xe] 4f 14 5d10 6s1
greater than threshold frequency strikes the (C) [Kr] 4d10 5s1 (D) [Kr] 4d9 5s2
surface.
(25) Principal, azimuthal and magnetic quantum
Reason R : When the photon of any energy
numbers are respectively related to
strikes an electron in the atom, transfer of
(A) Size, shape and (B) Shape, size and
energy from the photon to the electron
orientation orientation
takes place.
In the light of the above statements, choose (C) Size, orientation
the most appropriate answer from the and shape (D) None of the above
options given below : (26) Correct set of four quantum numbers for
(A) Both A and R are correct but R is NOT valence electron of rubidium (Z = 37) is
the correct explanation of A (A) 5, 0, 0, + 21 (B) 5, 1, 0, + 21
(B) A is correct but R is not correct (C) 5, 1, 1, + 21 (D) 6, 0, 0, + 21
(C) Both A and R are correct and R is the (27) Which set of quantum numbers are not
correct explanation of A possible from the following
(D) A is not correct but R is correct (A) n = 3, l = 2, m = 0, s = − 12
(18) The de-Broglie wavelength of a particle with (B) n = 3, l = 2, m = −2, s = − 21
mass 1 gm and velocity 100 m/ sec is
(C) n = 3, l = 3, m = −3, s = − 21
(A) 6.63 × 10−33 m (B) 6.63 × 10−34 m
(D) n = 3, l = 0, m = 0, s = − 12
(C) 6.63 × 10−35 m (D) 6.65 × 10−35 m
(19) What will be de-Broglie wavelength of an (28) Correct configuration of F e+3 [26] is
electron moving with a velocity of (A) 1s2 , 2s2 2p6 , 3s2 3p6 3d5(B)
1.2 × 105 ms−1 (C)
1s2 , 2s2 sp6 , 3s2 3p6 3d3 , 4s
(A) 6.068 × 10−9 (B) 3.133 × 10−37 1s2 , 2s2 2p6 , 3s2 3p6 3d6(D)
, 4s2
(C) 6.626 × 10−9 (D) 6.018 × 10−7 1s2 , 2s2 2p6 , 3s2 3p6 3d5 , 4s
2
 ( )
(29) Which of the following sets of quantum E = −2.178 × 10 J −18
. Wavelength of
Z2
n2
numbers is correct for an electron in 4f
light required to excite an electron in an
orbital
hydrogen atom from level n = 1 to n = 2 will
(A) n = 4, l = 3, m = +1, s = + 12 be :
(B) n = 4, l = 4, m = −4, s = − 12 (h = 6.62 × 10−34 Js and c = 3.0 × 108 ms−1 )
(A) 1.214 × 10−7 m (B) 2.816 × 10−7 m
(C) n = 4, l = 3, m = +4, s = + 12
(C) 6.500 × 10−7 m (D) 8.500 × 10−7 m
(D) n = 3, l = 2, m = −2, s = + 12
o (39) What transition in the hydrogen spectrum
(30) The ratio of the energy of a photon of 2000 A have the same wavelength as Balmer
o
wavelength radiation to that of 4000 A transition, n = 4 to n = 2 of He+ spectrum ?
radiation is (A) 3 → 2 (B) 2 → 3
(A) 0.25 (B) 4
(C) 2 → 2 (D) 2 → 1
(C) 0.5 (D) 2
(31) The frequency of a wave of light is (40) The wave number of the first Lyman
12 × 1014 s−1 . The wave number associated transition in H atom spectrum is equal to
with this light is the wave number of second balmer
(A) 5 × 10−7 m (B) 4 × 10−8 cm−1 transition in the spectrum of
(A) Li2+ (B) Be3+
(C) 2 × 10−7 m−1 (D) 4 × 104 cm−1
(32) Calculate the energy in joule corresponding (C) He+ (D) B 4+
to light of wavelength 45 nm. (Planck’s
(41) In Bohr series of lines of hydrogen
constant, h = 6.63 × 10−34 J s, speed of light,
spectrum, the third line from the red end
c = 3 × 108 m s−1 )
corresponds to which one of the following
(A) 6.67 × 1015 (B) 6.67 × 1011
inter-orbit in an atom of hydrogen
(C) 4.42 × 10−15 (D) 4.42 × 10−18 (A) 4 → 1 (B) 2 → 5
(33) Be2+ is isoelectronic with which of the (C) 3 → 2 (D) 5 → 2
following ions?
(A) H + (B) Li+ (42) The work function for a metal is 4 eV. To
(C) N a +
(D) M g 2+ emit a photo electron of zero velocity from
the surface of the metal, the wavelength of
(34) The outer electronic configuration of o
Gd (At. N o. 64) is incident light should be : ................ A
(A) 4f 5 5d4 6s1 (B) 4f 7 5d1 6s2 (A) 2700 (B) 1700
(C) 4f 3 5d5 6s2 (D) 4f 4 5d5 6s1 (C) 5900 (D) 3100
(35) The energies E1 and E2 of two radiations are (43) Photoelectric effect is the phenomenon in
25 eV and 50 eV respectively. The relation which
between their wavelengths i.e., λ1 and λ2
(A) Photons come out of a metal when it is
will be
(A) λ1 = λ2 (B) λ1 = 2λ2 hit by a beam of electrons.

(C) λ1 = 4λ2 (D) λ1 = 12 λ2 (B) Photons come out of the nuclues of an

atom under the action of an electric field
(36) According to Bohr’s theory, the angular
momentum of an electron in 5th orbit is (C) Electrons come out of a metal with a
(A) 10 h/π (B) 2.5 h/π constant velocity which depends on the
frequency and intensity of incident light
(C) 25 h/π (D) 1.0 h/π
wave.
(37) The energy required to break one mole of
Cl − Cl bonds in Cl2 is 242 kJ mol−1 . The (D) Electrons come out of a metal with
longest wavelength of light capable of different velocities not greater than a
breaking a single Cl − Cl bond is ............ nm certain value which depends only on the
(C = 3 × 10 ms and NA = 6.02 × mol ).
8 −1 −1 frequency of the incident light wave and
not on its intensity.
(A) 594 (B) 640
(C) 700 (D) 494 (44) The set of quantum number for the 19th
(38) Energy of an electron is given by electrons in chromium is

3
 (A) n = 4, l = 0, s = +1/2 or −1/2 (A) I < Br < Cl < F (increasing electron
(B) n = 3, l = 2, m = 1, s = +1/2 or −1/2 gain enthalpy)

(C) n = 3, l = 2, m = −1, s = +1/2 or −1/2 (B) Li < N a < K < Rb (increasing metallic
radius)
(D) n = 4, l = 1, m = 0, s = +1/2 or −1/2
(C) B < C < N < O (increasing first
(45) Ionic sizes increase in the order :- ionisation enthalpy)
(A) Ca2+ < Cl− < S 2− <(B) Ar < Ca2+ < Cl− <
(D) Both (a) and (c)
Ar S 2−
(53) The species Ar, K + and Ca2+ contain the
(C) Cl− < Ca2+ < Ar <(D) S 2− < Cl− < Ca2+ <
same number of electrons. In which order
S 2− Ar
do their radii increase ?
(46) In which of the following transition photon (A) Ca2+ < K + < Ar (B) K + < Ar < Ca2+
of maximum energy is absorbed
(C) Ar < K + < Ca2+ (D) Ca2+ < Ar < K +
(A) 1 to 2 (B) 2 to 3
(54) Which of the following represents the
(C) 1 to ∞ (D) ∞ to 1 correct order of increasing first ionization
(47) A 150 W att bulb emits light of wavelength enthalpy for Ca, Ba, S, Se and Ar ?
o
6600 A and only 8% of the energy is emitted (A) Ca < S < Ba < (B) S < Se < Ca <
as light. How many light photons are Se < Ar Ba < Ar
emitted by the bulb per second? (C) Ba < Ca < Se < (D) Ca < Ba < S <
(A) 4 × 1019 (B) 3.24 × 1019 S < Ar Se < Ar
(C) 4.23 × 1020 (D) 3 × 1020 (55) The correct order of electron affinity is
(48) Two radiations having energies E1 and E2 as (A) O > F > Cl (B) F > O > Cl
15 eV and 45 eV respectively then the (C) F > Cl > O (D) Cl > F > O
relationship in between λ1 and λ2 will be (56) Consider the following ionization enthalpies
(A) λ1 = λ2 (B) λ1 = 3λ2 of two elements ′ A′ and ′ B ′ .
(C) λ1 = λ2 /3 (D) λ1 = 9λ2 Element Ionization enthalpy (kJ/mol)
1st 2nd 3rd
(49) The de-Broglie’s wavelength of electron
present in first Bohr orbit of ′ H ′ atom is A 899 1757 14847
o o
(A) 4 × 0.529 A (B) 2π × 0.529 A B 737 1450 7731
o o Which of the following statements is correct
(C) 0.529
A
2π
(D) 0.529 A ?
(50) Based on the equation
( ) (A) Both ′ A′ and ′ B ′ belong to group −1
∆E = −2.0 × 10−18 J n12 − n12 where ′ B ′ comes below ′ A′ .
2 1
the wavelength of the light that must be (B) Both ′ A′ and ′ B ′ belong to group −1
absorbed to excite hydrogen electron from where ′ A′ comes below ′ B ′ .
level n = 1 to level n = 2 will be: (C) Both ′ A′ and ′ B ′ belong to group −2
(h = 6.625 × 10−34 J s, C = 3 × 108 m s−1 ) where ′ B ′ comes below ′ A′ .
(A) 1.325 × 10−7 m (B) 1.325 × 10−10 m
(D) Both ′ A′ and ′ B ′ belong to group −2
(C) 2.650 × 10 −7
m (D) 5.300 × 10 −10
m where ′ A′ comes below ′ B ′
(51) The element Z = 114 has been discovered (57) In general, the properties that decrease and
recently. It will belong to which of the increase down a group in the periodic table
following family/group and electronic respectively are
configuration? (A) atomic radius and electronegativity
(A) Carbon family, [Rn] 5f 14 6d10 7s2 7p2
(B) electron gain enthalpy and
(B) Oxygen family, [Rn] 5f 14 6d10 7s2 7p4 electronegativity
(C) Nitrogen family, [Rn] 5f 14 6d10 7s2 7p6 (C) electronegativity and atomic radius
(D) Halogen family, [Rn] 5f 14 6d10 7s2 7p5 (D) electronegativity and electron gain
enthalpy
(52) In which of the following options the order
of arrangement does not agree with the (58) Aluminium is usually found in +3 oxidation
variation of property indicated against it ? state. In contrast, thallium exists in +1 and

4
 +3 oxidation states. This is due to below :
(A) inert pair effect (B) diagonal (A) Both (A) and (R) are true and (R) is the
relationship correct explanation of (A)
(D) lanthanoid (B) Both (A) and (R) are true but (R) is not
(C) lattice effect contraction the correct explanation of (A)
(59) The IU P AC symbols for the element with (C) (A) is false but (R) is true
atomic number 119 would be:
(A) U un (B) U ue (D) (A) is true but (R) is false
(C) U uh (D) U ub (67) The difference between electron gain
enthalpies will be maximum between:
(60) Identify the incorrect match :
(A) N e and F (B) N e and Cl
Name IU P AC Official Name
(a) Unnilunium (i) Mendelevium (C) Ar and Cl (D) Ar and F
(b) Unniltrium (ii) Lawrencium (68) If an atom has electronic configuration
(c) Unnilhexlum (iii) Seaborglum 1s2 2s2 2p6 3s2 3p6 3d3 4s2 , it will be placed in
(d) Unununnium (iv) Darmstadtium (A) Second group (B) Third group
(A) (d), (iv) (B) (a), (i)
(C) Fifth group (D) Sixth group
(C) (b), (ii) (D) (c), (iii)
(69) Which of the following does not represent
(61) Identify the element for which electronic the correct order of the property indicated
configuration in +3 oxidation state is (A) Sc3+ > Cr3+ > F e3+ > M n3+ ionic radii
[Ar]3 d5 :
(A) Ru (B) M n (B) Sc < T i < Cr < M n Density
(C) Co (D) Fe (C) M n2+ > N i2+ < Co2+ < F e2+ ionic radii
(62) The CORRECT order of first ionisation (D) F eO < CaO > M nO > CuO Basic nature
enthalpy is: (70) Which of the following ion is the smallest
(A) Mg < Al < S < P (B) Al < Mg < S < P ion
(C) Mg < Al < P < S (D) Mg < S < Al < P (A) O2+ (B) O2−

(63) Given below are the oxides: (C) O2 (D) O2−2

N a2 O, As2 O3 , N2 O, N O and Cl2 O7 (71) The correct order of radii is
Number of amphoteric oxides is ..... . (A) N < Be < B (B) F − < O2− < N 3−
(A) 0 (B) 1 (C) N a < Li < K (D) F e3+ < F e2+ < F e4+
(C) 2 (D) 3 (72) The incorrect statement among the
(64) The IU P AC nomenclature of an element following is
with electronic configuration [Rn]5f 14 6d1 7s2 (A) The first ionisation potential of Al is less
is. than the first ionisation potential of M g
(A) U nnilbium (B) U nnilunium
(B) The second ionisation potential of M g is
(C) U nnilquadium (D) U nniltrium greater than the second ionisation
(65) Which of the following represents the potential of N a
correct order of metallic character of the (C) The first ionisation potential of N a is less
given elements ? than the first ionisation potential of M g
(A) Si < Be < M g < K (B) Be < Si < M g < K
(D) The third ionisation potential of M g is
(C) K < M g < Be < Si (D) Be < Si < K < M g greater than the third ionisation
(66) Given below are two statements : one is potential of Al
labelled as Assertion (A) and the other is (73) A sudden large jump between the values of
labelled as Reason (R) second and third ionisation energies of an
Assertion (A) : The first ionization enthalpy element would be associated with the
of 3d series elements is more than that of electronic configuration
group 2 metals (A) 1s2 , 2s2 p6 , 3s1 (B) 1s2 , 2s2 p6 , 3s2 p1
Reason (R) : In 3d series of elements
successive filling of d-orbitals takes place. (C) 1s2 , 2s2 p6 , 3s2 p2 (D) 1s2 , 2s2 p6 , 3s2
In the light of the above statements, choose (74) Which of the following elements are
the correct answer from the options given analogous to the lanthanides

5
 (A) Actinides (B) Borides (81) In which of the following arrangements the
order is N OT according to the property
(C) Carbides (D) Hydrides
indicated against it
(75) Which one of the following arrangements
does not give the correct picture of the (A) Al3+ < M g 2+ < N a+ < F − : Increasing
trends indicated against it ? ionic size
(A) F2 > Cl2 > Br2 > I2 : Bond dissociation (B) B < C < N < O : Increasing first
energy ionization enthalpy
(B) F2 > Cl2 > Br2 > I2 : Electronegativity (C) I < Br < F < Cl : Increasing electron
gain enthalpy (with negative sign)
(C) F2 > Cl2 > Br2 > I2 : Electron gain
enthalpy (D) Li < N a < K < Rb : Increasing metallic
radius
(D) Both (a) and (c)
(82) Following statements regarding the periodic
(76) The element with atomic number 117 has
trends of chemical reactivity of the alkali
not been discovered yet. In which family
metals and the halogens are given. Which of
would you place this element if discovered?
these statements gives the correct picture?
(A) Alkali metals (B) Alkaline earth
metals (A) Chemical reactivity increases with
increase in atomic number down the
(C) Halogens (D) Noble gases group in both the alkali metals and
(77) Which one of the following ions has the halogens
highest value of ionic radius
(B) In alkali metals the reactivity increases
(A) O2− (B) B 3+
but in the halogens it decreases with
(C) Li+ (D) F − increase in atomic number down the
(78) The formation of the oxide ion O(g)2−
requires group
first an exothermic and then an (C) The reactivity decreases in the alkali
endothermic step as shown below This is metals but increases in the halogens
because with increase in atomic number down
−
O(g) + e− = O(g) ∆H o = −142 kJ mol−1 the group
−
O(g) + e− = O(g)
2−
∆H o = 844 kJ mol−1 (D) In both the alkali metals and the
(A) O ion will tend to resist the addition of
− halogens the chemical reactivity
another electron decreases with increase in atomic
number down the group
(B) Oxygen has high electron affinity
(C) Oxygen is more electronegative (83) Which of the following statement
concerning lanthanides elements is false
(D) O− ion has comparatively larger size
(A) Lanthanides are separated from one
than oxygen atom
another by ion exchange method
(79) Among Al2 O3 , SiO2 , P2 O3 and SO2 the correct
(B) Ionic radii of trivalent lanthanides
order of acid strength is
steadily increases with increase in the
(A) Al2 O3 < SiO2 < SO2 < P2 O3 atomic number
(B) SiO2 < SO2 < Al2 O3 < P2 O3 (C) All lanthanides are highly dense metals
(C) SO2 < P2 O3 < SiO2 < Al2 O3 (D) More characteristic oxidation state of
(D) Al2 O3 < SiO2 < P2 O3 < SO2 lanthanide elements is +3
(80) Beryllium and aluminium exhibit many (84) The correct order of the decreasing ionic
properties which are similar. But, the two radii among the following isoelectronic
elements differ in species is
(A) Forming covalent halides (A) Ca2+ > K + > S 2− >(B) Cl− > S 2− > Ca2+ >
(B) Forming polymeric hydrides Cl− K+

(C) Exhibiting maximum covalency in (C) S 2− > Cl− > K + > (D) K + > Ca2+ > Cl− >
compounds Ca2+ S 2−

(D) Exhibiting amphoteric nature in their (85) Which one of the elements has the
oxides maximum electron affinity

6
 (A) F (B) Cl (95) If the valency shell electronic structure for
an element is ns2 np5 , this element will
(C) Br (D) I
belong to the group of
(86) Which one of the following arrangements (A) Alkali metals (B) Inert metals
represents the correct order of electron gain
enthalpy (with negative sign) of the given (C) Noble gases (D) Halogens
atomic species. (96) The electronic configuration of an element
(A) Cl < F < S < O (B) O < S < F < Cl is 1s2 , 2s2 2p6 , 3s2 3p3 . What is the atomic
number of the element which is just below
(C) S < O < Cl < F (D) F < Cl < O < S the above element in the periodic table
(87) Among the elements Ca, M g, P and Cl, the (A) 33 (B) 34
order of increasing atomic radii is
(C) 31 (D) 49
(A) M g < Ca < Cl < P (B) Cl < P < M g < Ca
(97) Which of the following has the smallest size
(C) P < Cl < Ca < M g (D) Ca < M g < P < Cl (A) N a+ (B) M g +2
(88) Among the following which one has the
(C) Cl− (D) F −
highest cation to anion size ratio ?
(A) CsI (B) CsF (98) Which of the following is largest
(A) Cl− (B) S 2−
(C) LiF (D) N aF
(C) N a+ (D) F −
(89) Amongst the elements with following
electronic configurations, which one of (99) Ionic radii are
them may have the highest ionisation (A) Directly proportional to effective nuclear
energy ? charge
(A) N e [3s 3p ]
2 2
(B) Ar [3d 4s 4p ]
10 2 3
(B) Directly proportional to square of
(C) N e [3s 3p ]
2 1
(D) N e [3s 3p ]
2 3 effective nuclear charge
(90) Which one of the following orders is not in (C) Inversely proportional to effective
accordance with the property stated against nuclear charge
it ? (D) Inversely proportional to square of
(A) F2 > Cl2 > Br2 > I2 : Bond dissociation effective nuclear charge.
energy
(100) Which of the order for ionisation energy is
(B) F2 > Cl2 > Br2 > I2 : Oxidising power correct
(C) HI > HBr > HCl > HF : Acidic property (A) Be > B > C > N > (B) B < Be < C < O <
in water O N

(D) F2 > Cl2 > Br2 > I2 : Electronegativity (C) B < Be < C < N <(D) B < Be < N < C <
O O
(91) Which one is the correct order of the size of
the iodine species
(A) I > I + > I − (B) I > I − > I +
(C) I + > I − > I (D) I − > I > I +
(92) Which one of the following ionic species has
the greatest proton affinity to form stable
compound ?
(A) N H2− (B) F −
(C) I − (D) HS −
(93) The nitride ion in lithium nitride is
composed of
(A) 7P + 7e (B) 10P + 7e
(C) 7P + 10e (D) 10P + 10e
(94) A neutral atom will have the lowest
ionization potential when its electronic
configuration is
(A) 1s1 (B) 1s2 , 2s2 p6
(C) 1s2 , 2s2 p2 (D) 1s2 , 2s2 p6 , 3s1
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