SAFETY DATA SHEET

Refrigerant R417A
Version 1.0
Revision Date: 28.09.2011

SAFETY DATA SHEET

REFRIGERANT R417A
This SDS is compiled according to the standards and regulatory requirements of Great Britain. It may not meet the regulatory
requirements in other countries.

SECTION 1: IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

1.1. Product Identifier

Product name: REFRIGERANT R417A

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use: Refrigerant.
Advised Against: No identified use advised against.

1.3. Details of the supplier of the safety data sheet

Company name: National Refrigerants Ltd.

4 Watling Close
Sketchley Meadows Business Park
Hinckley
LE10 3EZ

Telephone Number: +44(0)1455 630790

Fax Number: +44(0)1455 630791
Email: [email protected]
1.4. Emergency telephone number

Emergency Telephone: +44(0)1865 407333

Opening hours: 24 Hour.
Other comments: English only.

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture
Classification under Directive Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 199/45/EC.
67/548/EEC and 1999/45/EC:
2.2. Label elements

Directives 67/458/EEC or Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 199/45/EC.
1999/45/EC:
Label elements under Directive
67/458/EEC and 1999/45/EC:
Special labelling of certain Contains 1,1,1,2-Tetrafluoroethane, Pentafluoroethane/Contains fluorinated greenhouse gas
substances and mixtures: covered by the Kyoto Protocol.

2.3. Other hazards

Vapours are heavier than air and can cause suffocation by reducing oxygen available for
breathing.
Rapid evaporation can cause frostbite.
Misuse or intentional inhalation abuse may cause death without warning symptoms, due to
cardiac effects.
May cause cardiac arrhythmia.

SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS

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3.1. Substances
Hazardous Ingredients: Not applicable

3.2 Mixtures
1,1,1,2-TETRAFLUOROETHANE (HFC134a) [REGISTRATION NO. 01-2119459374-33]
EINECS CAS 67/548/EEC Classification CLP Classification Percent
212-337-0 811-97-2 - Pressurised Gas H280 50%
PENTAFLUOROETHANE (HFC125)
EINECS CAS 67/548/EEC Classification CLP Classification Percent
206-557-8 354-33-6 - Pressurised Gas H280 46.6%
BUTANE (<0.1% BUTADIENE)(HC600)
EINECS CAS 67/548/EEC Classification CLP Classification Percent
203-448-7 106-97-8 F+;R12 Flammable Gas H220 3.4%
Pressurised Gas H280
The above products are REACH compliant; Registration number(s) may not be provided because substance(s) are exempted, not yet
registered under REACH or registered under another regulatory process (biocide uses, plant protection products etc.).

For full text of R-phrases mentioned in this Section see Section 16.
For full text of H-Statements mentioned in this Section see Section 16.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

General Advice: If unconscious place in recovery position and seek medical advice. Never give anything by
mouth to an unconscious person. If breathing is irregular or stopped administer artificial
respiration.
First aider needs to protect himself.
If symptoms persist seek medical adavice.

Skin contact: Take off contaminated clothing and shoes immediately. Flush area with lukewarm water. Do
not use hot water. If frostbite has occurred call a physician.

Eye contact: Hold eyelids apart and flush with plenty of water for at least 15 minutes. Get medical attention.

Ingestion: Not considered a potential route of exposure.

Inhalation: Remove from exposure to fresh air and lie down. Keep patient warm and at rest. Artificial
respiration and/or oxygen may be necessary. Consult a physician.

4. 2. Most important symptoms and effects, both acute and delayed

Skin contact: Skin contact may give the following symptoms: Frostbite, Irritation, Discomfort, Itching, and
Redness of skin, Swelling of tissue.

Eye contact: Eye contact may give the following symptoms: Frostbite, Irritation, Tearing, Redness or
discomfort.

Ingestion: Ingestion is not considered as a route of exposure.

Inhalation: Misuse or intentional inhalation abuse may cause death without warning symptoms, due to
cardiac effects. Other symptoms potentially related to misuse or inhalation abuse are:
Anaesthetic effects, Light-headedness, dizziness, confusion, incoordination, drowsiness,
unconsciousness, irregular heartbeat, with a strange sensation in the chest, heart thumping,
apprehension, feeling of fainting or weakness, Narcosis.

Irritating to the respiratory system. Cough, sneezing, runny nose, sore throat or shortness of

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breath.
Delayed/immediate effects: Skin contact may not give immediate symptoms of frostbite.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate/special treatment: Do not give adrenaline or similar drugs.

SECTION 5: FIRE-FIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media: Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Use water spray to cool cylinders/tanks in a fire.

5.2. Special hazards arising from the substance or mixture

Special hazards arising from Pressure build-up. Fire or intense heat may cause violent rupture of cylinders.
the mixture: Hazardous thermal decomposition products may form. They are: Carbon oxides, Hydrogen
Fluoride, Fluorinated compounds. Exposure to decomposition products may be hazardous to
health.

5.3. Advice for fire-fighters

Advice for fire-fighters: In event of a fire wear self-contained breathing apparatus. Use personal protective equipment.
Wear neoprene gloves during cleaning up work after a fire.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Evacuate personnel to safe areas. Ventilate area, especially low or enclosed places where
heavy vapours might collect. Refer to protective measures listed in Sections 7 and 8.
6.2. Environmental precautions

Environmental precautions: Do not release into the environment. Treat according to local and national regulations.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Product evaporates.

6.4. Reference to other sections

Reference to other sections: For Handling and Storage see Section 7.

For Exposure Controls and Personal Protection see Section 8.
For Disposal Methods see Section 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Handling requirements: Avoid breathing vapours or mist. Avoid contact with the skin, eyes and clothing. Provide
sufficient air exchange and/or exhaust in work rooms. For personal protection see Section 8.
Vapours are heavier than air and may spread along the floor.

Cylinder Handling: Do not drag, slide or roll cylinders.

Never attempt to lift cylinder by its valve or cap.
Use a check valve or trap in the discharge line to prevent back flow into the cylinder.
See General Safety & Handling Data.

7.2. Conditions for safe storage, including any incompatibilities

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Storage conditions: Store in a cool, dry and well-ventilated area at temperatures not exceeding 52oC. Keep out of
direct sunlight. Keep cylinders tightly closed. Protect from contamination.
See General Safety & Handling Data.

Suitable packaging: Store in original cylinders only.

7.3. Specific end use(s)

Specific end use(s) No data available.

SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. Control parameters

Hazardous ingredients:
1,1,1,2-TETRAFLUOROETHANE (HFC134a) (CAS No. 811-97-2)
Workplace exposure limits
Form of Exposure Control Parameter Basis
3
TWA 4 240 mg/m EH40 WEL (2007)
1 000 ppm
BUTANE (HC600) (CAS No. 106-97-8)
Workplace exposure limits
Form of Exposure Control Parameter Basis
3
TWA 1 450 mg/m EH40 WEL (2007)
600 ppm
STEL 1 810 mg/m3 EH40 WEL (2007)
750 ppm

Derived No Effect Level (DNEL’s):

1,1,1,2-Tetrafluoroethane: Type of application (use): Worker

Exposure routes: Inhalation
Health Effects: Chronic effects, Systemic toxicity
3
Value: 13 939 mg/m

Type of application (Use): Consumers

Exposure routes: inhalation
Health Effect: Chronic effects, Systemic toxicity
3
Value: 2 476 mg/m

Pentafluoroethane: Type of application (use): Worker

Exposure routes: Inhalation
Health Effects: Chronic effects, Systemic toxicity
3
Value: 16 444 mg/m

Type of application (Use): Consumers

Exposure routes: inhalation
Health Effect: Chronic effects, Systemic toxicity
3
Value: 1 753 mg/m

Predicted No Effect concentration

1,1,1,2-Tetrafluoroethane: Value: 0.1 mg/l

Compartment: Fresh Water

Value: 0.01 mg/l

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Compartment: Marine Water

Value: 1 mg/l
Compartment: Water
Remarks: Intermittent use/release.

Value: 0.75 mg/kg dry weight (d.w.)

Compartment: Fresh water sediment.

Value: 73 mg/l
Compartment: Water
Remarks: Sewage treatment plants.

Pentafluoroethane: Value: 1mg/l

Compartment: Water
Remarks: Intermittent use/release

Value: 0.6 mg/kg

Compartment: Fresh water sediment

8.2. Exposure controls

Engineering measures: Ensure adequate ventilation, especially in confined areas. Local exhaust should be used when
large amounts are released.

Respiratory protection: For rescue and maintenance work in storage tanks use self-contained breathing apparatus.
Vapours are heavier than air and can cause suffocation by reducing the oxygen available for
breathing. Respiratory protection to comply with EN 137.

Hand protection: Material: leather gloves

The suitability for specific workplace should be discussed with the producers of the protective
gloves.

Eye protection: Wear safety glasses or coverall chemical splash goggles. Eye protection should comply with
EN 166 or ANSI Z87.1.
Wear a face shield where the possibility exists for face contact due to splashing, spraying or
airborne contact with this material.

Skin protection: Wear suitable protective equipment. Wear as appropriate: impervious clothing.

Protective Measures: Self-contained breathing apparatus (SCBA) is required if a large release occurs. The type of
protective equipment must be selected according to the concentration and amount of the
substance at the specific workplace.

Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

State: Liquefied gas

Colour: Colourless
Odour: Slight, ether-like.
pH: Neutral
Melting Point: Not available for this mixture
o
Boiling Point/range: -39.1 C
Flash Point: Does not flash
Flammability: Type: lower flammability limit. Method ASTM E681: None
Ignition Temperature: None
Upper explosive limit/upper Type: Upper flammability limit Method ASTM E681: None
flammability limit:
o
Vapour pressure: 9.835 Bar (9 835 hPa) at 25 C

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o
Liquid Density: 1.2 g/cm3 at 20 C
Vapour Density: 0.0044 g/cm3 at 25oC (1 Bar)
Vapour Density (Air = 1) 3.8 at 25oC

9.2 Other Information

No data available.

SECTION 10. STABILITY AND REACTIVITY

10.1. Reactivity

Reactivity: Decomposes on heating.

10.2. Chemical stability

Chemical stability: The product is chemically stable.

10.3. Possibility of hazardous reactions

Hazardous reactions: Stable under recommended storage conditions. Polymerization will not occur.

10.4. Conditions to avoid

Conditions to avoid: Avoid open flames and high temperatures. The product is not flammable in air under ambient
conditions of temperature and pressure. When pressurised with air or oxygen, the mixture may
become flammable. Certain mixtures of HFC’s with chlorine may become flammable or
reactive under certain conditions. Pressurized container: Do not pierce or burn even after use.
o
Keep at temperature not exceeding 52 C

10.5. Incompatible material

Materials to avoid: Alkali metals, Alkaline earth metals, Powdered metals, Powdered metal salts.

10.6. Hazardous decomposition products

Hazardous decomposition Hazardous thermal decomposition products may include: Hydrogen fluorides, Carbon oxides,
products Fluorocarbons, Carbonyl Fluoride.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Acute toxicity: Oral toxicity
Pentafluoroethane
Not applicable

Butane (<0.1 % butadiene)

Not applicable

Inhalation toxicity
1,1,1,2-Tetrafluoroethane
LC50/4 h rat: 567 000 ppm

Low Observed Adverse Effect Concentration (LOEC)/ dog: 75 000 ppm

No Observed Adverse Effect Concentration (NOEC)/ dog: 50 000 ppm

Pentafluoroethane
LC50/4 h rat: >800 000 ppm

Low Observed Adverse Effect Concentration (LOEC)/ dog: 100 000 ppm

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Butane (<0.1% butadiene)

LC50/4 h rat: 277 018 ppm
Irritating to respiratory system. Central nervous system depression narcosis.

Low Observed Adverse Effect Concentration (LOEC)/ dog: 150 000 ppm
Cardiac sensitization

Dermal toxicity
Pentafluoroethane
Not applicable

Butane (,0.1% butadiene)

Not applicable

Irritation: Skin irritation

1,1,1,2-Tetrafluoroethane
Rabbit
Classification: Not classified as an irritant.
Result: Slight irritation.
Not expected to cause skin irritation based on expert review of the properties of the substance.

Human
Classification: Not classified as an irritant.
Result: No irritation.

Pentafluoroethane
Not tested on animals
Classification: Not classified as an irritant.
Result: No skin irritation.
Not expected to cause skin irritation based on expert review of the properties of the substance.

Butane (<0.1% butadiene)

Not tested on animals
Classification: Not classified as an irritant.
Result: No skin irritation.
Not expected to cause skin irritation based on expert review of the properties of the substance.

Eye irritation
1,1,1,2-Tetrafluoroethane
Rabbit
Classification: Not classified as an irritant.
Result: Slight irritation.
Not expected to cause eye irritation based on expert review of the properties of the substance.

Human
Classification: Not classified as an irritant.
Result: No irritation.

Pentafluoroethane
Not tested on animals
Classification: Not classified as an irritant.
Result: No skin irritation.
Not expected to cause eye irritation based on expert review of the properties of the substance.

Butane (<0.1% butadiene)

Not tested on animals
Classification: Not classified as an irritant.
Result: No skin irritation.
Not expected to cause eye irritation based on expert review of the properties of the substance.

Sensitisation: 1,1,1,2-tetrafluoroethane
Guinea pig

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Classification: Not a skin sensitizer.

Result: Did not cause skin sensitization on laboratory animals,
Not expected to cause sensitization based on expert review of the properties of the substance.

Did not cause respiratory sensitization on laboratory animals. There are no reports of human
respiratory sensitization.

Pentafluoroethane
Not tested on animals.
Classification: Not a skin sensitizer
Result: Does not cause skin sensitization.
Not expected to cause sensitization bases on expert review of the properties of the substance.

There are no reports of human repertory sensitization.

Butane (<0.1% butadiene)

Not tested on animals.
Classification: Not a skin sensitizer
Result: Does not cause skin sensitization.
Not expected to cause sensitization bases on expert review of the properties of the substance.
Not tested on animals.
Classification: Not a skin sensitizer
Result: Does not cause skin sensitization.
Not expected to cause sensitization bases on expert review of the properties of the substance.

Repeated dose toxicity: 1,1,1,2-Tetrafluoroethane

Inhalation rat
No toxicologically significant effects were found.

Pentafluoroethane
Inhalation rat
No toxicologically significant effects were found.

Butane (<0.1% butadiene)

Inhalation multiple species
No toxicologically significant effects were found.

Carcinogenic assessment: 1,1,1,2-Tetrafluoroethane

Not classified as a human carcinogen.

Pentafluoroethane
Not classified as a human carcinogen.

Butane (<0.1% butadiene)

No data available.

Mutagenic assessment: 1,1,1,2-Tetrafluoroethane

Animal testing did not show any mutagenic effects. Tests on bacterial or mammalian cell
cultures did not show mutagenic effects.

Pentafluoroethane
Animal testing did not show any mutagenic effects. Tests on bacterial or mammalian cell
cultures did not show mutagenic effects.

Butane (<0.1% butadiene)

Animal testing did not show any mutagenic effects.

Toxicity to reproduction 1,1,1,2-Tetrafluoroethane

Assessment: No toxicity to reproduction.

Pentafluoroethane
No toxicity to reproduction.

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Butane (<0.1% butadiene)

No data available.

Assessment Teratogenicity Pentafluoroethane

Did not show tetratoginic effects in animal experiments.

Butane (<0.1% butadiene)

No data available.

SECTION 12. ECOLOGICAL INFORMATION

12.1. Toxicity

Toxicity to fish: 1,1,1,2-Tetrafluoroethane

LC50/96 h/Oncorhynchus mykiss (rainbow trout): 450 mg/l

Pentafluoroethane
LC50/96 h/Danio rerio (zebra fish): >200 mg/l
Information given is based on data obtained from similar substances.

LC50/96 h/Oncorhynchus mykiss (rainbow trout): 450 mg/l

Information given is based on data obtained from similar substances.

Butane (<0.1% butadiene)

LC50/96 h/Fish (unspecified species) >1 000 mg/l

Toxicity to Aquatic plants: 1,1,1,2-Tetrafluoroethane

EC50/72 h/Algae: >118 mg/l
Data given is based on data obtained from similar substances.

Pentafluoroethane
EC50/96 h/Algae: 142 mg/l
Data given is bases on data obtained from similar substances.

Acute Toxicity to aquatic 1,1,1,2-Tetrafluoroethane

invertebrates: EC50/48 h/Daphnia magna (Water flea): 980 mg/l

Pentafluoroethane
EC50/48 h/Daphnia magna (Water flea): >200 mg/l
Information given is based on data obtained from similar substances.

12.2. Persistence and degradability

Biodegradability: 1,1,1,2 Tetrafluoroethane

/28 d Biodegradation: 3%
Not readily biodegradable.

Butane (<0.1% butadiene)

/34 d Biodegradation: 100%
Readily biodegradable.

12.3. Bio accumulative potential

Bio-accumulative potential: 1,1,1,2-Tetrafluoroethane

Bioaccumulation is unlikely.

12.4. Mobility in soil

Mobility: No data available.

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12.5. Results of PBT and vPvB assessment

PBT identification: No data available

12.6. Other adverse effects

Other adverse effects: Ozone deletion potential (ODP) (R11 = 1)

1,1,1,2-Tetrafluoroethane: 0
Pentafluoroethane: 0
Butane (<0.1% butadiene): 0
R417A (Blend): 0

Global Warming Potential (GWP) (CO2 = 1)

1,1,1,2-Tetrafluoroethane: 1430
Pentafluoroethane: 3500
Butane (<0.1% butadiene): 20
R417A (Blend): 2300

SECTION 13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Disposal operations: Can be used after reclaiming. If reclaiming is not practicable, dispose of in compliance with
local regulations.

Disposal of packaging: Empty pressure cylinders should be returned to the supplier. If recycling is not practicable,
dispose of in compliance with local regulations.
N.B.
SECTION 14. TRANSPORT INFORMATION

14.1. ADR
UN Number: 1078
Proper Shipping Name: REFRIGERANT GAS N.O.S. (1,1,1,2-TETRAFLUOROETHANE, PENTAFLUOROETHANE)
Class: 2.2
Packing Group: N/A
Tunnel Code: (C/E)
Transport Group: 2.2

14.2. IMDG
UN Number: 1078
Proper Shipping Name: REFRIGERANT GAS N.O.S. (1,1,1,2-TETRAFLUOROETHANE, PENTAFLUOROETHANE)
Class: 2.2
Packing Group: N/A
EmS codes: F-C, S-V
Marine Pollutant: No

SECTION 15. REGULATORY INFORMATION

15.1. Safety, health and environment regulations/legislation specific for the substance or mixture
Take note of Directive 98/24/EC on the protection of health and safety of workers from the
risks related to chemical agents at work.

15.2. Chemical Safety Assessment

Chemical safety assessment: A chemical safety assessment has not been carried out by the supplier of this mixture.

16. OTHER INFORMATION

Other information: This safety sheet is prepared in accordance with Commission Regulation (EU) No. 453/2010.

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* Indicates text in SDS which has changed since the last revision.

R-Phrases Text of R-Phrases mentioned in Section 3

R12: Extremely flammable.

H-Statements Text of H-statements mentioned in Section 3

H220: Extremely flammable gas.
H280: Contains gas under pressure; may explode if heated.
Legal disclaimer: National Refrigerants Ltd. believes that the information and recommendations contained herein (including data
and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE,
WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE
INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not
be valid where such product is used in combination with any other methods of use of the product and of the information referred to
herein are beyond the control of National Refrigerants Ltd. National Refrigerants Ltd. expressly disclaims any and all liability as to
any results obtained or arising from any use of the product or reliance on such information.

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GENERAL SAFETY & HANDLING DATA

1. GENERAL Do not subject Cylinders to mechanical shocks which

may cause damage to their valves or safety devices.
Only trained persons should handle compressed gases.
Observe all regulations and local requirements regarding Never attempt to repair or modify Cylinder valves or
the storage of Cylinders. safety relief devices. Damaged valves should be reported
Do not remove or deface labels provided by the supplier immediately to the supplier.
for the identification of the Cylinder contents. Close the Cylinder valve whenever gas is not required
Ascertain the identity of the gas before using it. even if the Cylinder is still connected to the equipment.
Know and understand the properties and hazards
associated with each gas before using it. 2. STORAGE
When doubt exists as to the correct handling procedure
for a particular gas contact the supplier. Cylinders should be stored in a well-ventilated area.
Some gases will require a purpose built area.
HANDLING AND USE Store Cylinders in a location free from fire risk and away
from sources of heat and ignition. Designate as a no
Wear stout gloves. smoking area.
Never lift a Cylinder by the cap or guard unless the
supplier states it is designed for that purpose. Gas Cylinders should be segregated in the storage
Use trolley or other suitable device or technique for according to the various categories.
transporting heavy Cylinders, even for a short distance.
Where necessary wear suitable eye and face protection. The storage area should be kept clear and access
The choice between safety glasses, chemical goggles, or should be restricted to authorized persons only, the area
full face shield will depend on the pressure and nature of should be clearly marked as a storage area and
the gas being used, appropriate hazard warning signs displayed (Flammable,
Toxic etc.).
Where necessary for toxic gases see that self-contained The amount of flammable or toxic gases should be kept
positive pressure breathing apparatus or full face airline to a minimum.
respirator is available in the vicinity of the working area. Flammable gases should be stored away from other
Employ suitable pressure regulating device on all combustible materials.
Cylinders when gas is being emitted to systems with
lower pressure rating than that of the Cylinder. Cylinders held in storage should be periodically checked
Ascertain that all electrical systems in the area are for general condition and leakage.
suitable for service with each gas.
Cylinders in storage should be properly secured to
Never use direct flame or electrical heating devices to prevent toppling or rolling.
raise the pressure of a Cylinder, Cylinders should not be Vertical storage is recommended where the Cylinder is
o
subjected to temperatures above 45 C. designed for this.
Never re-compress a gas mixture without consulting the Cylinder valves should be tightly closed and, where
supplier. Never attempt to transfer gases from one appropriate, valves should be capped or plugged.
Cylinder to another. Protect Cylinders stored in the open against rusting and
Do not use Cylinders as rollers or supports, or for any extremes of weather.
other purpose other than to contain the gas as supplied. Cylinders should not be stored in conditions likely to
Never permit oil, grease or other readily combustible encourage corrosion.
substances to come into contact with valves of Cylinders Store full and empty Cylinders separately and arrange
containing oxygen or other oxidants. full Cylinders so that the oldest stock is used first.
Keep Cylinder valves clean and free from contaminants
particularly oil and water.

FOR FURTHER INFORMATION CONTACT YOUR NEAREST DISTRIBUTION CENTRE

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