SAFETY DATA SHEET

Section 1. Identification
Product name Optigear Synthetic A 320
SDS # 450763
Historic SDS #: 61832
Code 450763-US03

Relevant identified uses of the substance or mixture and uses advised against
Product use Gear lubricant
For specific application advice see appropriate Technical Data Sheet or consult our
company representative.

Manufacturer Castrol Industrial North America, Inc.

150 W. Warrenville Road
Naperville, IL 60563
Supplier Castrol Industrial North America, Inc.
150 W. Warrenville Road
Naperville, IL 60563
Product Information: +1-877-641-1600
EMERGENCY SPILL 1 (800) 424-9300 CHEMTREC (USA)
INFORMATION:

Section 2. Hazards identification

OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the SKIN SENSITIZATION - Category 1
substance or mixture

GHS label elements

Hazard pictograms

Signal word Warning

Hazard statements May cause an allergic skin reaction.
Precautionary statements
Prevention Wear protective gloves. Avoid breathing vapor. Contaminated work clothing must not
be allowed out of the workplace.
Response IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before
reuse. If skin irritation or rash occurs: Get medical attention.
Storage Not applicable.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise Defatting to the skin.
classified

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Section 3. Composition/information on ingredients
Synthetic lubricant and additives.
Substance/mixture Mixture
Ingredient name CAS number %
Base oil - highly refined Varies ≥1 - <3
Zinc dialkyl dithiophosphate 68457-79-4 ≥1 - <3
Base oil - highly refined Varies ≥1 - <3
Reaction product of ethoxylated fatty amine and ammonium compound Proprietary ≥1 - <3
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in
this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Eyelids should be held away from the eyeball to ensure thorough rinsing. Check for and
remove any contact lenses. Get medical attention.
Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognized skin cleanser. In the event of any complaints or symptoms,
avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before
reuse. Get medical attention.
Inhalation If inhaled, remove to fresh air. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours. Get medical attention if symptoms occur.
Ingestion Do not induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Get medical attention if adverse health effects
persist or are severe.
Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.

Most important symptoms/effects, acute and delayed

See Section 11 for more detailed information on health effects and symptoms.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Treatment should in general be symptomatic and directed to relieving any effects.
Specific treatments No specific treatment.

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing In case of fire, use foam, dry chemical or carbon dioxide extinguisher or spray.
media
Unsuitable extinguishing Do not use water jet.
media

Specific hazards arising In a fire or if heated, a pressure increase will occur and the container may burst.
from the chemical

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Section 5. Fire-fighting measures
Hazardous combustion Combustion products may include the following:
products carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
phosphorus oxides
metal oxide/oxides

Special protective actions Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Special protective Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA)
equipment for fire-fighters and full turnout gear.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Put on appropriate personal protective equipment. Floors
may be slippery; use care to avoid falling. Contact emergency personnel.
For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapor, mist or
fume is extremely hazardous without the correct respiratory protective equipment and a
safe system of work. Wear self-contained breathing apparatus. Wear a suitable
chemical protective suit. Chemical resistant boots. See also the information in "For non-
emergency personnel".

Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill Stop leak if without risk. Move containers from spill area. Absorb with an inert material
and place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Large spill Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas.
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to local
regulations. Contaminated absorbent material may pose the same hazard as the spilled
product. Dispose of via a licensed waste disposal contractor.

Section 7. Handling and storage

Precautions for safe handling
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or
on skin or clothing. Avoid breathing vapor or mist. Do not ingest. Empty containers
retain product residue and can be hazardous. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not in
use. Do not reuse container. Persons with a history of skin sensitization problems
should not be employed in any process in which this product is used.
Advice on general Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Wash thoroughly after handling. Remove contaminated
clothing and protective equipment before entering eating areas. See also Section 8 for
additional information on hygiene measures.

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Section 7. Handling and storage
Conditions for safe storage, Store in accordance with local regulations. Store in original container protected from
including any direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
incompatibilities (see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Store and use only in equipment/containers designed for use with this
product. Containers that have been opened must be carefully resealed and kept upright
to prevent leakage. Do not store in unlabeled containers. Use appropriate containment
to avoid environmental contamination.

Sulfur compounds in this material may decompose when heated to release hydrogen
sulfide gas which may accumulate to potentially lethal concentrations in enclosed air
spaces. Vapor concentrations of hydrogen sulfide above 50 ppm, or prolonged
exposure at lower concentrations, may saturate human odor perceptions so that the
smell of gas may not be apparent. Exposure to concentrations of hydrogen sulfide vapor
above 500 ppm may cause rapid death. Do not rely on the sense of smell to detect
hydrogen sulfide.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Base oil - highly refined ACGIH TLV (United States).
TWA: 5 mg/m³ 8 hours. Issued/Revised:
11/2009 Form: Inhalable fraction
OSHA PEL (United States).
TWA: 5 mg/m³ 8 hours. Issued/Revised:
6/1993

Zinc dialkyl dithiophosphate None.

Base oil - highly refined ACGIH TLV (United States).

TWA: 5 mg/m³ 8 hours. Issued/Revised:
11/2009 Form: Inhalable fraction
OSHA PEL (United States).
TWA: 5 mg/m³ 8 hours. Issued/Revised:
6/1993

Reaction product of ethoxylated fatty amine and ammonium compound None.

While specific OELs for certain components may be shown in this section, other components may be present in any mist,
vapor or dust produced. Therefore, the specific OELs may not be applicable to the product as a whole and are provided
for guidance only.

Appropriate engineering All activities involving chemicals should be assessed for their risks to health, to ensure
controls exposures are adequately controlled. Personal protective equipment should only be
considered after other forms of control measures (e.g. engineering controls) have been
suitably evaluated. Personal protective equipment should conform to appropriate
standards, be suitable for use, be kept in good condition and properly maintained.
Your supplier of personal protective equipment should be consulted for advice on
selection and appropriate standards. For further information contact your national
organisation for standards.
Provide exhaust ventilation or other engineering controls to keep the relevant airborne
concentrations below their respective occupational exposure limits.
The final choice of protective equipment will depend upon a risk assessment. It is
important to ensure that all items of personal protective equipment are compatible.
Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure they
controls comply with the requirements of environmental protection legislation. In some cases,
fume scrubbers, filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.

Individual protection measures

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Section 8. Exposure controls/personal protection
Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.
Eye/face protection Safety glasses with side shields.
Skin protection
Hand protection Wear protective gloves if prolonged or repeated contact is likely. Wear chemical
resistant gloves. Recommended: Nitrile gloves. The correct choice of protective gloves
depends upon the chemicals being handled, the conditions of work and use, and the
condition of the gloves (even the best chemically resistant glove will break down after
repeated chemical exposures). Most gloves provide only a short time of protection
before they must be discarded and replaced. Because specific work environments and
material handling practices vary, safety procedures should be developed for each
intended application. Gloves should therefore be chosen in consultation with the supplier/
manufacturer and with a full assessment of the working conditions.
Consult your supervisor or Standard Operating Procedure (S.O.P) for special handling
instructions.
Body protection Use of protective clothing is good industrial practice.
Cotton or polyester/cotton overalls will only provide protection against light superficial
contamination that will not soak through to the skin. Overalls should be laundered on a
regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or
if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical
suits and boots will be required.
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
Other skin protection Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
The correct choice of respiratory protection depends upon the chemicals being handled,
the conditions of work and use, and the condition of the respiratory equipment. Safety
procedures should be developed for each intended application. Respiratory protection
equipment should therefore be chosen in consultation with the supplier/manufacturer
and with a full assessment of the working conditions.

Section 9. Physical and chemical properties

Appearance
Physical state Liquid.
Color Brown. [Dark]
Odor Not available.
Odor threshold Not available.
pH Not available.
Melting point Not available.
Boiling point Not available.
Flash point Open cup: 205°C (401°F) [Cleveland.]
Evaporation rate Not available.
Flammability (solid, gas) Not applicable. Based on - Physical state
Lower and upper explosive Not available.
(flammable) limits
Vapor pressure Not available.
Vapor density Not available.
Density <1000 kg/m³ (<1 g/cm³) at 15.6°C
Solubility insoluble in water.

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Section 9. Physical and chemical properties
Partition coefficient: n- Not available.
octanol/water
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Kinematic: 320 mm2/s (320 cSt) at 40°C

Section 10. Stability and reactivity

Reactivity No specific test data available for this product. Refer to Conditions to avoid and
Incompatible materials for additional information.

Chemical stability The product is stable.

Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur.
reactions Under normal conditions of storage and use, hazardous polymerization will not occur.

Conditions to avoid No specific data.

Incompatible materials Reactive or incompatible with the following materials: oxidizing materials.

Hazardous decomposition Hydrogen Sulfide (H2S)

products

Section 11. Toxicological information

Information on toxicological effects
Aspiration hazard
Name Result
Base oil - highly refined ASPIRATION HAZARD - Category 1

Information on the likely Routes of entry anticipated: Dermal, Inhalation.

routes of exposure
Potential acute health effects
Eye contact No known significant effects or critical hazards.
Skin contact May cause an allergic skin reaction.
Inhalation Exposure to decomposition products may cause a health hazard. Serious effects may
be delayed following exposure.
Ingestion No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact No specific data.
Skin contact Adverse symptoms may include the following:
irritation
redness
dryness
cracking
Inhalation May be harmful by inhalation if exposure to vapor, mists or fumes resulting from thermal
decomposition products occurs.
Ingestion No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate Not available.
effects

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Section 11. Toxicological information
Potential delayed effects Not available.
Long term exposure
Potential immediate Not available.
effects
Potential delayed effects Not available.
Potential chronic health effects
General No known significant effects or critical hazards.
Carcinogenicity No known significant effects or critical hazards.
Mutagenicity No known significant effects or critical hazards.
Teratogenicity No known significant effects or critical hazards.
Developmental effects No known significant effects or critical hazards.
Fertility effects No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity
No testing has been performed by the manufacturer.

Persistence and degradability

Not expected to be rapidly degradable.

Bioaccumulative potential
Not available.

Mobility in soil
Soil/water partition Not available.
coefficient (KOC)
Mobility Non-volatile. Liquid. insoluble in water.

Other adverse effects No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods The generation of waste should be avoided or minimized wherever possible. Significant
quantities of waste product residues should not be disposed of via the foul sewer but
processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Disposal of this product, solutions
and any by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.

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Section 14. Transport information
DOT Classification TDG Classification IMDG IATA
UN number Not regulated. Not regulated. Not regulated. Not regulated.

UN proper - - -
shipping name
Transport - - - -
hazard class(es)

Packing group - - - -
Environmental No. No. No. No.
hazards
Additional Special provisions - - -
information Petroleum oil, not
regulated in
containers less than
3500 gallons.

Special precautions for user Not available.

Transport in bulk according Not available.

to Annex II of MARPOL
73/78 and the IBC Code

Section 15. Regulatory information

U.S. Federal regulations
United States inventory All components are listed or exempted.
(TSCA 8b)
SARA 302/304
Composition/information on ingredients
No products were found.

SARA 311/312
Classification Immediate (acute) health hazard
SARA 313

Product name CAS number Concentration

Form R - Reporting Zinc dialkyl dithiophosphate 68457-79-4 1.3918
requirements
Supplier notification Zinc dialkyl dithiophosphate 68457-79-4 1.3918
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts None of the components are listed.
New Jersey The following components are listed: ZINC compounds
Pennsylvania The following components are listed: ZINC COMPOUNDS

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Section 15. Regulatory information
California Prop. 65 WARNING: This product contains a chemical known to the State of California to cause
cancer.
Ethyl acrylate; arsenic

WARNING: This product contains a chemical known to the State of California to cause
birth defects or other reproductive harm.
Toluene

WARNING: This product contains a chemical known to the State of California to cause
cancer and birth defects or other reproductive harm.
Cadmium (Non-pyrophoric); lead
Other regulations
Australia inventory (AICS) All components are listed or exempted.
Canada inventory At least one component is not listed.
China inventory (IECSC) All components are listed or exempted.
Japan inventory (ENCS) At least one component is not listed.
Korea inventory (KECI) All components are listed or exempted.
Philippines inventory At least one component is not listed.
(PICCS)
Taiwan inventory (CSNN) All components are listed or exempted.
REACH Status For the REACH status of this product please consult your company contact, as
identified in Section 1.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health 2

Flammability 1
Physical hazards 0

Personal protection X

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
National Fire Protection Association (U.S.A.)

1 Flammability
Health 2 0 Instability/Reactivity
Special

History
Date of issue/Date of 06/23/2015.
revision
Date of previous issue 10/07/2014.
Key to abbreviations ACGIH = American Conference of Industrial Hygienists
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
CAS Number = Chemical Abstracts Service Registry Number
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)

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Section 16. Other information
OEL = Occupational Exposure Limit
SDS = Safety Data Sheet
STEL = Short term exposure limit
TWA = Time weighted average
UN = United Nations
UN Number = United Nations Number, a four digit number assigned by the United
Nations Committee of Experts on the Transport of Dangerous Goods.
Indicates information that has changed from previously issued version.
Notice to reader
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental
information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is
made as to the accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not use the
product other than for the stated application or applications without seeking advice from BP Group.

It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The
BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the
material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material.
Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that
any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell
employees and others who may be affected of any hazards described in this sheet and of any precautions that should be
taken. You can contact the BP Group to ensure that this document is the most current available. Alteration of this
document is strictly prohibited.

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