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Atomic Structure
Indicate True or False as the case may be
1. Gases are good conductors of electricity at high pressure.
2. Cathode rays can ionize gases.
3. Positive rays were discovered in 1896.
4. Neutron was discovered by Chadwick.
5. J.J Thomson measured e/m value of electrons.
6. Mass of electron is 1.9 X 10-28 grams.
7. Two electrons in the same orbital should have same spin.
8. In the absence of magnetic field all-orbitals are degenerate.
9. The value of azimuthal quantum number always starts from zero.
10. The uncertainty principle is applicable only for microscopic particles.
11. Louis de Broglie equation relates the wavelength and momentum of electron.
12. X-rays are emitted from the target in one direction.
13. Bohr’s theory can not explain the origin of the spectrum of H-atom.
14. Balmer spectral lines appear in visible region.
15. Rainbow is an example of line spectrum.
16. The unit of frequency is per meter.
Encircle the most suitable answer from the given ones in each question
17. _________ produces a greenish fluorescence on striking the walls of the glass tube.
a. Canal rays. b. α-particles. c. Electric & Magnetic d. Cathode rays
18. A scientist concluded from his experiments that cathode rays consist of streams of _______ particles.
a. Cathode rays b. positively charged c. neutral d. negatively charged.
19. Positive rays are also known as ___________.
a. Magnetic b. Anode rays c. Neutrons d. Canal rays
20. Positive rays are deflected by ________________fields.
a. Electric B. Magnetic c. Magnetic quantum d. Both ‘a’ and ‘ b’.
21. The _______ value for positive rays is always smaller than that of electron.
a. m/e b. e/m c. electro negativity d. Magnetic quantum
22. The mass of neutron is always equal to mass of _______.
a. β-particle. b. electron c. Proton d. X-rays
23. A fast neutron ejects _____ from the nucleus of nitrogen.
a. proton b. γ-Particle c. quark d. α-particle.
24. A fast moving neutron should have energy equal to ____ .
a. 1.1ev b. 2.1Mev c. 1.3Mev d. 1.2Mev
25. The e/m value for an electron is equal to ________.
a. 0.7588X1011 coulombs Kg-1 b. 1.7588X1110 coulombs Kg-1
12 -1
c. 1.7588X10 coulombs Kg d. 1.7588X1011 coulombs Kg-1
26. Ruther-ford in his experiment used the photographic film as a detector which was coated with__
a. NaNO3 b. ZnS c. sodium d. AgNO3
27. Max Plank proposed the quantum theory in 1900 to explain the _____ and _______ of radiations.
a. Electric & Magnetic effects b. Emission & Absorption
c. Continuous & line spectrum d. Principal & Spin quantum numbers.
28. For d sub-shell there are five values of _______ number.
a. Principal quantum b. Magnetic quantum c. Spin quantum d. Azimuthal quantum
29. The e/m value for the positive rays is maximum for.
a. Nitrogen b. Helium c. Oxygen d. Hydrogen
30. Neutron was discovered by Chadwick in.
a. 1935 b. 1934 c. 1930 d. 1932
31. The velocity of photon is
a. Equal to its wave number b. Equal to velocity of light.
c. Independent of its wavelength d. less than velocity of light.
32. Quantum number values for 3p orbitals are.
a. n=3,l=3 b. n=3,l=1 c. n=1,l=3 d. n=3,l=0,1

Chemistry, Unit # 5, Atomic Structure, F. Sc Part-I

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33. The radius of first orbit of hydrogen atomic

a. 0.429A0 b. 0.529A0 c. 0.329A0 d. 0.229A0

34. Proton and electron

a. P-orbital b. X-rays c. 1886 d. Nucleus
35. Lord Rutherford
a. Electron b. Nucleus c. α-particles d. X-rays.
36. Spin quantum number
a. P-orbital b. X-rays c. proton d. Electron
37. Dumb-Bell
a. s- orbital b. d-orbital c. P-orbital d. f - orbital
38. Moseley;
a. X-rays b. Nucleus c. Electron d. H-Spectrum
39. Positive rays
a. mvr b. E.Goldstein c. J-Perrin d. William Crooks
40. Infra-red region
a. Lyman series b. Pfund series c. Balmer series d. Quantum theory
41. Angular momentum
a. h b. hν c. mvr d. E. Goldstein
mv
42. Bohr’s Theory
a. Line spectrum b. v = 1 c. mvr d. E = hcv
λ
43. Max Plank
a. VSEPR theory b. Quantum theory c. electron gas theory d. uncertainty principle
44. Wavelengths of visible spectrum are:
a. 100-200nm b. 400 nm to 750nm c. five component lines d. .04A0-8A0
45. Spectral lines of shorter wavelength are known as
a. K-series b. M-series c. L-series d. P-series
46. Line spectrum of sodium
a. Yellow colored b. continuous spectrum c. IR region d. different colored lines
47. Electric discharged
a. 400 nm to 750nm b. Electron c. Infra-red’s microwave d. Yellow
48. The limiting Line in Blamer Series lies in _________region.
a. 400 nm to 750nm b. UV c. IR d. visible
49. Exact position of electron and velocity cannot be determined spontaneously …….
a. Compton’s effect b. Heisenberg c. Hund’s rule d. Aufbau principle
50. Compton’s effect
a. Uncertainty b. Heisenberg c. Geometry of molecules d. Spherical shape
51. S-Orbitals
a. complicated shape b. Heisenberg c. Dumb-bell shape d. Spherical shape
52. Three values of magnetic quantum number of P-subshell are
a. 0,1,2 b. 1,2,3 c. 0,+1,-1, d. All a, b, c
53. Two electrons in the same orbit have
a. Spherical shape b. Opposite spins c. same spin d. different n.
54. Discovery of proton.
a. E.Goldstein b. J.Perrin c. J.Thomson d. Chadwick
55. Prediction of neutral particles in atom was given by.
a. E.Goldstein b. Chadwick c. J.Thomson d. Rutherford
56. Slow neutrons have energy less than.
a. 500 ev. b. 2ev c. 1ev d. 1.2 Mev
57. e/m value of Electron was determined by……..
a. William crooks b. Millikan c. J.J Thomson d. Rutherford
58. Relative charge on electron is
a. -1.6022x10-19 b. 1.6750x10-27 c. -1 d. +1
59. The value of planks constant ‘h’ is
a. 6.626x10-34 Js b. 6.626x10-34 Ns c. 13.22A0 d. 900nm

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60. ∈0 is vacuum permittivity and its value is ………….

a. 8.84x10-12C2J-1m-1 b. 8.84x10+12 C2J-1m-1 c. 1.6750x10-27 C2J-1m-1
61. The best example of continuous spectrum is
a. H2 spectrum b. Na spectrum c. rainbow d. Balmer series
62. Paschen , Brackett and Pfund series of lines are produced as a result of electronic transitions from
higher orbits to
a. 1st, 2nd, 3rd b. 2nd, 3rd, 4th c. 3rd, 4th, 5th d. none of these
63. A simple relationship between the frequency of a particular line of X-rays and the atomic number Z is
a. v = a ( Z − b) b. v = (aZ − b ) c. v = a ( Z + b)
64. Splitting of spectral lines in a magnetic field is called
a. Stark Effect b. Zeeman Effect c. Hund’s rule d. Uncertainty principle
65. Longer wavelength spectral lines are known as
a. K-series b. L series c. M series d. N series
66. All matter particles in motion have a dual character.
a. Max plank b. Aufbau c. Louis de Broglie d. Compton
67. E= mc2
a. Newton’s equation b. Plank’s equation c. Einstein’s equation d. Davisson’s equation
68. The volume of space in which there is 95% chance of finding an electron is called ______.
a. nodal plane b. nodal surface c. atomic orbital d. sub shell
69. Self rotation of electrons in 1925.
a. Schrodinger b. Dirac c. Goudsmit & Ulenbech d. Bohr
70. It is impossible for two electrons residing in the same orbital of a poly-electron atom to have the same
values of four quantum numbers.
a. Aufbau principle b. Hund’s rule c. Pauli’s Exclusion principle
71. Degenerate sub-shells
a. same energy b. same spin c. different energy
72. The maximum number of electrons that can be accommodated in an orbital are
a. 4 b. 2 c. 2n2 d. 6
73. Splitting of spectral lines into closely spaced lines in electric field is known as :
a. Zeeman effect b. Compton’s effect c. Stark effect d. Germer effect
74. In 1927 two American scientists , ____________ & ____________ did an experiment to verify the
wave nature of moving electrons.
a. Schrodinger , Heisenberg b. Schrodinger, Dirac
c. Davisson , Germer d. Heisenberg , Dirac
75. The wavelength of photon is __________ proportional to the momentum of photon.
a. directly b. inversely c. not d. none
76. The _________ of an element determines the physical and chemical chemical characteristic properties.
a. atomic mass b. atomic number c. covalent radii d. ionic radii
77. The electrons should be filled in energy subshells in order of increasing energy values.
a. Hund’s Rule b. Pauli’s Exclusion principle c. Aufbau principle
78. Plank put forward his quantum theory in
a. 1905 b. 1904 c. 1900 d. 1911
79. Frequency
a. distance between the two adjacent crests b. number of waves per unit length
c. number of waves passing through a point per unit time d. reciprocal of wavelength
80. Neutrino has __________charge.
a. positive b. negative c. neutral d. none of the above

Chemistry, Unit # 5, Atomic Structure, F. Sc Part-I