PYQ Sourabh Raina SOLUTIONS Very short amswt type questions CI Meals) ol wey aaprate species are more (orn rtablle in. tole water Han im WOAm waters. (2018? Ars Solubihety of om g% decreases Wh ina/ase bn water. Hence aqynake species One ~~ Lompaature of : congnrtable Sn Cobol Wraber, [soPbbityoc le [_sget_remputly He main, oy oe 6 Cabity over mnlloriby 08 Bae unt % ventontcotion® Ans, Molallit, does not Ramge with Ramage in fempecabune pale mcbasiby clecreaser With rise tn Lemperatiore a2 State 1h n MoGoritys ~— 9 Mofabity = ones Noe souin Cm) 3 ites eens a vn Dobe inky63 ee 33 What Lappens when acctone actded to pure Ars When accéore s added to ehamo€ , some Of U-bond between He ehamok mmpbecules break clown aesutliong wm am inuease WV Ua. PRES BUAC of mixer: the mixture show posthive clexiation fom Racnre's 2a ethan” C2922) B4 pefene the following Lum Mobok elevator constome ckb> coor? : a Dib: eLevakionin bovking pore gd | =m 2 aokolity, se te defied OF eLevatwon im boiling pout phon He mol ality, of Be so2ntion is warty Unt > KEG 8Cave season fn the following : Measurement of osmotic pus sinc fn Be dekemination of ro lor mare suck os proto anh polymers” Cgols? Ars As ned fo otrer olligatve 20; cue ct wl Dihion aoom temp us Losge even £m Vey bh Mauomolecules De a - are wot generals S method us profeneot es ts amogrcbacle e- oe Whak oe uoton Ars Twd soGutans ok & ger Lemperaine = No Osmosis between tHese Linn golutionsSourabh Raina Bt Gwercasow the follows , point of INK i wlition, CLevakor of 60 , a double than on De sugar 10 Ww Ga. mar eyes Ars [Bet Kb oA a qokuduon bel Kee wbuton £ £22 qengot ae DTb of IMR golutwon Us Roubke je. kom Some Leapih on emuxeng 4 az eotopes” c20l4) : co oe Ans They are he pirat Ine ZVe" ae . a He same compos ae re boils ck constant em apentropes What We Aone Vapour pa64 ° ote, : fA Tdenthy whick Beaptoe vith Rave a Kiger vapour puessine of qe ci4 He bobin point of Bua Leapick A amol B one 1Uee amd [80 Aispecterely (2022) Am The Osqutd with a Lowe, boibing pout hos a hiigka vapour pene’ Hence Gamice A Kos Rigen vapome pene He vapour pressing of a 6° Ment ofpeced ia cusotvedn 2 caol¥) 6 How when anon volatile wolute Ars Ip Ben non vobotihe podubets added t fhe coQvent Vapour, perane of 40luhon becomes Lowe tham ao age of pure wohrenk at same te mpernbine Vapomt PGID define tte followtng Let Abnowmok moor mor ort) Ars The moZar mors bil & ether Lowe & Kiger Hhom expected a nowmak value = Awouaknn Dinouzabion | ale Wot Lopper when we place Be Dood 2h2 rakent gp oton a7euhor) Gave eO*ON c2ols> An ugg fo osmosis water sno Deen les cuk. AS a geen l& phoock chk gel amch mag BusseShore amsuser type Lanestions C2morks? BI Stake Heny's Law. Why ar bs olcuert with Reblisuron in Hoe Lank usec by “scuba avers”. ps pad pn of ce yon oppo ws proportconal to mole frattion gc aes kue Hema’ : > e a aswell % the ie ue ae tend tration Of Nvbager in tke hoo eg feck ob Righ Con a z oot thaw 4, :Sourabh Raina GIM Cakeulate the molarity of 4.8 t CW/W) A0Gution of : : i 1,504.14 Hhe density of solictvon us 1.029 me CN awe" Ars Mam fH, Sou 485 i Duke Ars Maw Loxity = 0 ae of r0bestion= 100% Mokae4 ote eobetzon 2 mo hes of, Hy Oy = ans Moon mans = ol at = 4e I “Toe oo Density = More Fe aa Vodume = [00 1.02M loo OS aeGIS Waite Pao dif. erence bet é. p nan ésteot ae iis eer) tdeak 10lition anol Ars Tdeak solution Non-Edkeal solution. L Obey Racnlt's Low 1. Donnt obey Raonlt's ak atl Lomperature and low at ah Eomperatine Concombakion amd. concentration P, =AG P, #PiX 2. DNemxt 2 DNemmz0 DH mix =0 DH mixtoBIG ee He freezing pom: of & solution wboumions, 604 of fucose Cmolar mars = [Gog mae”) in 2503 of waiter Cke f waters Leek bgmot") (Bole) Ars 2 Ans — mars of glucose = 6° 2 of, ti 3 My 3 Mors wort, =25 0% 1.86 162 xt Wh Spee. ke = 186 beg me a KE Atbe ausk Die= ke ™ t fl faceringt 100s Hue ae Diez key Wz xloe0 ux Wy a>2FoO5LKGIt Give season gyeimia fs Raho, bon pont non om gore me (gor? Ars OD — DTb=iltbom eg ante haumse Ee! ponte EGov okwor. of bong x Nog P pleeSourabh Raina ag What is meant by postive dewiofion fom Raoulh's Law? Gre am example What is the sign fo Dis H 4 posiéve deviatirn. ° (ols)? - Ans A.B inferartions axe weaker, Ham AA amok | ~ a Y remsure muUens[es : how. p fo this Vapour P a Poe suaute te positive dleniation 40m Rooulk's Law e4 Ethanol? + Awtone AW = *NEol4 Fon §%o bution of Wen CMoLormars 260g/ mot) Coheubok 0 th : . eee pussuae of go0/e Mass of Usa ¢p20.08el Lamm Fn 5a% 7 os toond of sot te [x= ek) : g_.0.0821839° ne aoe 60% 108 i : Too° me = 1 0.082183? ° Co = ap. 5| atmeee ee eee ee azertope. What type $ apeobops formed by poodve deviation fom Raonte's Caw? c2os> Gye am exam! ce topes uw famed b > Define azersope What £ype% azeo eregabae dovtodion fom Raoult’s Caw? ave an exam . Ave Méneanumn bouling apestope e4 Etonol* Woe C4gfoby Nome on Maxtmum bo ling azeswope 4 Nut oma Wate CO8% by moss)vied ao Goto ty ith 04 %o rodime cklintde : ne if Wwe : hin ee et ibm laa Blood cobl. In ‘q C2016) 1.2% Nak gobution a. © 047. Nach solutdn Ave Gy 12% Nott Solubron. ( Rypestonic phood eth, vats wll 5 Oo one of fre cell am would sBink: tonic Wh segpet to wih ane, a @ OH Zo Nal goeteon ts Rypo plook 2, waker wil few Odo ch amd woul swerk-Foss whesi Vas'# Hogs gare? What type of vane | nae gm forming the yoluhor tee soluble onolecule undergo C2014) ie pusoctation (D Assocation arti | Ars Jt bs defied os the sakn oF experzmental value of He cothigative propreg ho the caboubabedt value of iollizgabve pps, : ie seve cobigaboe Pepa. Caleubaked witignive pope’ oO picowaton ral © Asowakar telShort amswer type I questions 3mauis> 42 Some eth xlone glyok HOCH, CH,OK ad your Cor cooling system along wih Skg of water. 4 the fering poe of water - fyvol solution is -1S°C- Nhat a mb of the soAubion” Cieb = 0.2 te eg ma VF = 1,86 ke leg he bouting po Aw ATp 2 ISC 15% = 1.86% Wax (00° Wy, =? 62 x500° M,, CHocUychon) =6? Wy Isagae® tal = 5G ial, 2 25°°4 AtTps kb™ siee™ be em __, keen Wa xl00 4 pare | My Wl Be M,XH = 0.SAXZG500x 1085 = 4.9K soe Th= 3734419 2399 iaSourabh Raina BB rn 300k, 309 of geuwose sesont in a tre of Ue Holukion bos an osmobnpussure Of 4.98 bar. HY the Osmmokue pressine 0f a glucose soGtion isl S2bor at te same Lemp erative what wouldl be uts concentaabiow’”. (2014) Ans Kpe RT ie use, RT A, 2c RS re 300k yags am XRT Mav = 30xRT Teor 2c, RT 4.48 1522 oD 4.48 21 RT tsa 6 xq RV =F | ~ | S2 = \g2 a. uAexé 248P 7 = 0.08l mekas Colenfote the bovbin point iden fm a Aohudaon prepared. +4 adehing log of, Cathy 402009 of water Cie frwates = 0 52lekg mat malonate - ol) Ant Cah, — Conte 2 Get? Le? Alpe tke ™ > eps Wa x1000 =e aR ooo eaxosariexs = o-F08k ALO26 - 3.99 of bonpoe aoid cusolved mm 44 4 of benzene shows a depression, dn freezing pore of 162k. Calculate the vant Hoy fatter ome predué the noture of 40 Cube (orsouiabed & duwociabed) - Gwen Mo kar marsog benroe 7 keg 249 Keg mat aud |2 24 /met> we pyle Die =i ge We xlove _. teas Mx Banton" Gre Ex49% 3.4 x10? oe = pe “4 ra pelo amowakinO24 7 oe Of F-CH,-Cooh CMolo mors * FS anne"! oy aed, of water. tHe ction fs F-Cy, ed. tobe Ic. Calculate dogec BS te “CH, “COOH. C kp of water = La iekguce ‘Or LF Ars Waly 21 4S3 Mz 248g mot"! Wh 250° 3 i e . 4.Sk2 Ate = uke ™ 1.86x! f pelote te UKE oe oF c-cH,cook = g-cH, coe tHT vy Wh oa 1+ Cr- 0% og» olegree S nou ahi | = ix LO 6K IAE x Woe No 48 500 jor el C2-D% porecke Laas te dosousto = lots! = 0.045 = #5%‘026 30g of Urea (Mebogmol') is dusoled m S404 of waren . Coloulote the Vapour pressure of water 4u Hs solution of VApons pussure of pwe water af 249k 23.8 mong: (a0lF? fot t= 30 ° Ky > 6463 Pa = Pa% Xa Mure > 32 20-S 2 23.8% woh mwsoten twee mr wobne B6.47 223.8% 1 a as 2 23.8% 0.19 : [Link] Ha aSB2n When 25 ai Me fs % sulphur was dinsoluek tn 100g zing pomt is Lo Cds fommitacs Ck wered. by 0.3634 Ars 5 Chee of C5, = 3.83k bg ma | Alb Il, = 2.564 Wy 21003 (aolé) ato moran My =? My 2 3.93K 2.56x100° btes kee 0. 583xI00 Tee ker Wee x 100 M, 2 256gnae™! Mi _W ae pipbeceLon mers Box 0.383= 3.3% ASE x 1000 ieee My loo x = 28626 32 Fotmuln> $8| | 83° AY Yo sokutionC W/W) of sucnose CM= 342g maak / kh. Cokeubale 7 Pe fos freezing point of 241.15 é © freezing pomt of 5 70 gf wse (Mz [Go gnoe"! nw : a 2 ( Facezing pont of pre woken? 275! Aws Mars of Suirose = "9 cael Mays of INabe 2 [00-4 aon of bao ci S chy) = 489 bacon Nake Cn) = oi Digs kex™ a = W, 100? : is 5 l02? QEBIS- AFIS ken Meee pres Kem be xt : Wx (eke 21S. SSR x 102? Kes 46 Atle e4S4le eo 45 - i nb 2 REBAS Ire = 15.58 Kkgmet 1 Freezing park? a tre! a 2268: 61kot Avs The v [Link] PREBSURC of pure LigpihX and pure Bayi Y 2S°c axe [20mm of H and (60mm of, Hg RR ectively e mixed to fm an Pdeok solution. earn e vapour pressure of the awlition? (2028) No of mokes of XK omhV=% aes Mole fraction x= 2 = % ef Pq pure Sapte CF? pee = 120mmH Moke pachon gy = 4 V.P d, pure Bacto = 'gommHo heal solubion Raoult's Law Frotal pressure = Pu thy) , 2 puxrXxt Pytty s L jor b+ Wort 2 6x8? 2 Wom HeOBUO Why is th ar y ts the wabue of Van't H 5 acid tn benzene clore ra ong fautor $e ethanoic | @ ptamine the osmotic premure a solution prepared by oisrolving 2.32 xg a Ks SOx in 22 of solution 0 ave, Sasuming KaSoy ts completa wuinootated?. ous) | Ans aMoals {oo O In benzene two mobecubes of He ethamote ach ansocate de form dimer @CH,CooK = (CH,C0OH2, puto ode potest tion Theorekicol umber of wate particles032 OWGy te the value of Van't Hoff 42 ; acid in gene choxe ioc a oe ate 6% ethamoie exsure of O solution neponedt @ pettamine the osmotic ps puisvolving 2.32 x10 g a |e SOn in QL of BOEUzON ab 28, | axbuming KrSm % completely digociated?. (Qozs) Avs i sols | AN @ We gg2rxiorg = T= aSe 2 asrrt3 a | yrs ae = ark MpZar mars 25? | ep S0y ak + soe” ee | ie3 ag | ne ZCRt\ stat aa 2 3x 232418008 AK29 ~ 4g xto atm IF Xe | |A solution is prepared. by alisobiing log of monvotosibe — ) 7092 iw Aoog of water. Tt kas a vopour Aes UAC Of 31.84 mmHg af 308k- Calculate the molar mors of the wile v ak 308 ke = 32mmHa) C pour premsure of pure 1 er ok le cae} A Was lOG F232 mmHg ny = 189 Imol aManks | W,= 2003 Pye Bh Bumm He Mz =? | G Fi ntms| (ailake 00rLon) 1, 277M 7 —Pi NL Bie oA 39-3184 = Jey IB al BQ Mz 205 Pi-Pr = WoxMi OlG ote M, = 18x32 Ze | M, 20 0-16x20 } = Bogie! |"0 W By @ is the boidin 4 point of IMNate solution mute ram that of, IM gfusose yo Cubion @ Denon volatile solute XC Molar mars Sogmoe”) phen olimolved in 78g of benzene reduced UB v opoUr 4 40%. Coleukate the toa ox dsokved mthe sobution 2524) etal, olissotote 4 le which & not powtbfe in a! Pier | Aw © Nak 2, Lone amd wo | give 2 fons pec mofec | gluco | 2 amt Hoff sale ha 2 faa amd cb && | for glucose Bip =o kEx™ bribing points Dil be mate fri Nace than | Tnareose En Ghuseprse BMA,@o Why is the boiking point: of IMNatl so€ution mune | tham that of IM gfucore solution | ® Amon olotibe yolute XC Molar mam = sogmo£”) phen olimolved nm 784 of, benzene seduced Us \ opoUr prose to 40%. Collcukate the mor o% X dinokrec nthe sofution (5245 3 | - Maas | Aw © Wp =? Mz= 50g mee! aa extol Wie 799 proton manag bergene C= 66 e 78g (me! VP 4, benzene CBL)= rae “ 3240! GF! ° V.P 4 so@ution CPO" oa py rOAPr = We xg 5 Py 5o Fe EP = tee Wentt| oP. Pi ™ Me Wi er eee Wy, = 9%