Safety Data Sheet Westlake
W Chemical
Section 1: Identification of the Substance/Mixture and of the Company/Undertaking
4.1 Product identifier
Product Name + PVC Suspension Resin
‘Synonyms + All products with the Product Numbers 1050 thru 2110M and 5226 thru 5565;
Chioroethylene homopolymer; Chloroethylene polymer, Polyvinyl Chloride resin; Pond
Resin; PVC resin; Sifter Overfiow
CAS Number + 9002-86-2
4.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified use(s) = Industrial raw material for plastics processing
4.3 Details of the supplier of the safety data sheet
Manufacturer + Westlake Vinyls Company, LP
Westlake Vinyls, Inc.
Axial, LLC.
2801 Post Oak Blvd
Suite 600
Houston, TX 77058
‘www. westlake.com
[email protected]
Telephone (General) . +1 713-960-9111
‘Supplier + Axiall Canada, Inc.
34, rue de L'industrie
Beauhamois J6N 1W5
Canada
Telephone (General) + 450-429-4641
Telephone (General) + 450-429-3326 - FAX
1.4 Emergency telephone number
CHEMTREC (24 Hrs) + 1-800-424-9300
jazards Identification
Section
EU/EEC
‘According to: Regulation (EC) No 1272/2008 (CLPYREACH 1907/2006 [amended by 2015/830]
2.1 Classification of the substance or mixture
cur + No dala avaible
2.2 Label Elements
cr fost. Pose
K c= a
2.3 Other Hazards CSR, WESTLAKE CHEMICAL,
cu «No dala avatabe
Renan 5/2024 sen HESUN GHS Revision 3
‘According to: UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS): Third
Revised Edition
2.4 Classification of the substance or mixture
UN GHS + Not classifies
2.2 Label elements
UN GHS
Hazard statements - No label element(s) required
Precautionary statements
2.3 Other hazards
UN GHS «According to the Globally Harmonized System for Classification and Labeling (GHS)
this product is nat considered hazardous
United States (US)
According to: OSHA 29 CFR 1910.1200 HCS:
2.4 Classification of the substance or mixture
OSHA Hes 2012 + Not classified
2.2 Label elements
OSHA Hes 2012
Hazard statements + No labet elements) required
2.3 Other hazards
OSHA Hes 2012 «This product is not considered hazardous under the U.S. OSHA 29 CFR 1910.1200
Hazare Communication Standard.
Canada
According to: WHMIS 2015
2.4 Classification of the substance or mixture
WHMIs 2015 + Not classified
2.2 Label elements
WHMIS 2015
Hazard statements - No label element(s) required
Precautionary statements
2.3 Other hazards
WHMIS 2015 + In Canada, the product mentioned above is not considered hazardous under the
Workplace Hazardous Materials Information System (WHMIS).
‘Section 3 - Composition/Information on Ingredients
3.1 Substances‘Composition
% — |Losoncso
[Glassifications According to
[chemical Name [Regulation/Directive
—T ‘EU CLP: Not classified
Pay > UN GH Reson 3 Not cased
Chionde (CAS:9002-06-2 goa% [NOR OSHA HCS 2012: Not classified
vrs 2018: Not so
CRETEOT
Ee Number 200851-
Vencntide | snp | hgmnoranar.ns0-200 | eyeum, Commun expen nis
EU tndex:802-023-00
Zr
3.2 Mixtures
«| Material does not meet the criteria of a mixture in accordance with Regulation (EC) No
1272/2008.
‘Section 4 - First Aid Measures
4.1 Description of first aid measures
Inhalation «Administer oxygen if breathing is difficult, Do not use mouth-to-mouth method if victim
‘Muled the susetance, give artiftal respiration with the aid of a pocket mask
sduipped wih a one-way valve of other proper respiratory medical device. Give artificial
TertBion i vet is net bresthing. Get medical attention immediatly.
‘Skin 1s For minor skin contact, avoid spreading material on unaffected skin. in case of contact
‘nih sulostance, immediately fish skin wih running water for atleast 20 minutes.
Rarove angie contamnetd cating, Hirtaion develops and pers, st
medical atlontion.
Eye = Incase of contact with substance, immediately flush eyes with running water for at
least 20 minutes. if eye irritation persists: Get medical advice/attention.
Ingestion «If swallowed, rinse mouth with water (only if the person is conscious). Do NOT induce
Yomiing, Do not use mouth-to-mouth method if victim ingested the substance. Obtain
medical attention immediately if ingested.
4.2 Most important symptoms and effects, both acute and delayed
+ Refer to Section 11 - Toxicological Information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to Physician |» Immediate medical attention after exposure to this material not expectod fo be
necessary. No special treatment indicated related to exposure to this material
‘Section 5 - Firefighting Measures
5.1 Extinguishing media
Suitable Extinguishing Media - Carton dioxide or water.
In case of fire Use media as appropriate for surrounding fire,
Unsuitable Extinguishing «None known.
Media
5.2 Special hazards ari
Unusual Fire and Explosion + Dense smoke emitted wh
ing from the substance or mixture
bumed without sufficient oxygen. PVC will not continue to
Hazards ‘bum after ignition without an external fre source.
Hazardous Combustion + No daia available
enteo ey FAP OHS aeons rove wagProducts
5.3 Advice for firefighters
+ Dust Explosivty (Kst) Rating: St 0 Non-explosive dust
+ Wear postive pressure sof-coniained breathing apparatus (SCBA)
Structural firefighters" protective cothing wil only provide limited protection.
Do not allow fre fighting runof" water to enter streams, rivers or lakes. The water wil
‘collect Hydrochloric Acid from the by-products of combustion.
Dike fre Control water for later disposal
‘Section 6 - Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal Precautions ' Ventilate enclosed areas. Stay upwind. Do not walk through spilled material. Wear
appropriate personal protective equipment, avoid direct contact
Emergency Procedures + Contain spill and monitor for excessive dust accumulation. Avoid unnecessary
personnel and equipment traffic in the spill area.
6.2 Environmental precautions
+ Prevent entry into waterways and sewers.
6.3 Methods and material for containment and cleaning up
ContainmentClean-up + Avoid generating dust.
Measures pil rca can be washed wih water, Plage unusable mata into 2 closed, properly
ledcontainer compatible with the product.
6.4 Reference to other sections
+ Reler o Saston 8 - Exposure Contls/Personal Protocon ‘and Section 13 - Disposal
consider
‘Section 7 - Handling and Storage
7.1 Precautions for safe handling
Handling + Avoid breathing dust. Avold contact with eyes. Wash thoroughly after handling. PVC
resin processing may result in the release of low levels of vinyl chloride. Use only in
well-ventilated areas.
7.2 Conditions for safe storage, including any incompatibilities
Storage + Keep container closed. Store in a cool, dry, wellventilated place. Reseal containers
immediately after use. To maintain product quality, do not store in heat or direct
sunlight, Keep oniy in the original container at a temperature not exceeding 40C.
Incompatible Materials or + Strong acids, strong bases, and oxidizing agents.
Ignition Sources
7.3 Specific end use(s)
+ Refer to Section 1.2 - Relevant identified uses,
Section 8 - Exposure Controls/Personal Protection
8.1 Control parameters:
Exposure Limie/Suidetines
onan] acm | caraeaBetsh | canaca ontario | canadeaueise | OSHA
substances
regulation);
Troan TWA
(designated
‘ppmin TWA appliesto | ppm TWAEV: 26
lvnwciende [WAS Jt 79m ' Pom TWA workplaces to which |mgina TWagv |" PPM TWA
7501-4) tre dosignates
substances
regulation does not
ety)
ie [5 ppm STEL (g00 29
Jsrcts |notestantsned | [otestabiched _|Notestabished —[Notestbtshed | OPRata 1017)
T iO mgind TWAEV
incusing dust, nor
enucenes 15 mgin TWA (ttl
Habart dust, S main THA
respirable traction)
+ gia TWA. gin TWA ]tmaima TWA [Asbestos and «1%
Poiyviny Chloride TWAS |recpirable traction) |(rsirab) (espirable) [crytatine sic, total | tos not
ious) terse classiied
as Pertcultes not "NOS
othorwise clessied
PNoC)
8.2 Exposure controls
Engineering :
MeasuresiControls
Personal Protective Equipment
Respiratory .
EyelFace :
‘Skin/Body .
General Industrial Hygiene +
Considerations
Environmental Exposure +
Controls
‘ay to abbreviations
9.1 Information on Basic Physical and Chemical Properties
Good general ventilation should be used, Ventilation rates should be matched fo
Conditons. If applicable, use process enclosures, local exhaust ventilation, of other
Engineering controls to maintain airborne levels below recommended exposure limits.
tfrexposure limits have rot been established, maintain airbome levels to an acceptable
level Use only appropriately classified electrical equipment.
Respirator selection must be based on known ot anticipated exposure levels, the
hazards of the product and the safe woking mis of the alerted respyator Fofow
the OSHA respirator regulations found in 25 CFR 1910.134, Use a NIOSHIMSHA
approved respirator if exposure limits are exceeded or symptoms are experienced.
Use good hygiene pracies when handling this material. Safety glasses wil side
Shields should be worn at a minimum. in dusty environments, goggles or glasses
designed for dust protection are recommended.
Personal protecve equipment fo th body shoul selected based on the task
being performed and the risks Involved and should be approved by a specialist before
handling this product. HANDS: Chemical-resistant, impervious gloves complying with
dr approved Standard should be worn at all imes when handling chemical products i
eiriskassessment indicates this is necessary. Considering the parameters specified
by the glove manufacturer, check during use that the gloves are stil retaining their
protective properties.
Controls should be engineered to prevent release to the environment, including
progedure in provant ep, atrosphers lease and release to walerways. Follow
eat practice for sile management and disposal of waste.
Controls should be engineered to prevent release to the environment, including
procedures to prevent spills, atmospheric release and release to waterways.
‘American Conference of Governmental Industial Hygin@
‘Nationa Institute of Occupational Safety and Heath
‘Occupational Safety snd Health Administration
Time Weighted Averages are basad on Bria, 40hweek exposures
: ee ‘one wets[Material Description
[Physical Form [seid —- [White powder with no odor.
[Coor we odor ocoriess
[Odor Testo [No cata avaible
jeneral Properties
Boxing Pant recta aealooe ncn Pamtreng Font [No dia avalabio
[remporatces of 300% (150°C) or
Decompostion Temperature [grote over an extended pen of pH Notreavant
ime may eause heal
degradation of PC resin
Specie GravyiRelave Doeiy [= 1.38 Walert Water Subany Negigbie<07 %
Viscosity hes fovea soesive Properties Not exstaave.
riding Prarie: Ne data avaiable
[Volatility
[Vapor Pressure [Tamra tor) [vanerBansiy a dat evelable
Evaporation Rate Ne deta avaiable
lammability
Fash Pant [Ratretvant aL fotrlevant
on Retreat [auigrion No cata avaiable
[Rermabiy (od. gos) (Noda avalablo
nvironmental
[Octano/aer Pariion concent [No daa avaiable I
9.2 Other Information
+ No additional physical and chemical parameters noted.
[Section 10: Stability and Reactivity
10.1 Reactivity
+ No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
+ Stable under normal temperatures and pressures.
10.3 Possibility of hazardous reactions
+ Under normal conditions of storage and use, hazardous polymerization will not occur.
10.4 Conditions to avoid
+ None known,
10.5 Incompatible materials
+ Polyvinyl chloride materials should not come into contact with acetal or acetal
Copolymers in elevated temperature processing equipment. The two materials are not
‘compatible and will react ina violent decomposition when mixed under conditions of
heat or pressure. Strong oxidizing agents.
10.6 Hazardous decomposition products
+ Temperatures of 300F (1596) of oreter ove an extended por of im may cause
thermal degradation of PVC resin. The formation of hydrogen chloride, HCI, may be
generated during this thermal degradation. HCI vapors may cause irritation of the
eyes, mucous membrane and respiratory tractSection 11 - Toxicological Information
[serious eye damagefirritation
wits 2015 -No data avaiable
IEUIGLP «No data avaliable
JUN GHS 3 No cata avalae
JOSHA HCS 2012. No daia avaiable
WHMIS 2015 No data avaiable
FEUIGLP- No data evalable
JUN GHS 3 No data avaible
JOSHA HCS 2012- No data aveiabio
WHMIS 2015 -No date avaiable
41.1 Information on toxicological effects
Componente 7
Ian [Fumorigen Carcinogen: IngeienOrat-RotTD.0-710 gg 30 Weals-Contouous TunorgoncEquvors!
2002" umorigenic agent by RTECS criteria; Lungs, Thor, or Respirain Tumors; Sn and
lAppendeges:Other Tumors
[GHS Properties [Etassitication
TEUICLP - No dala avaiable
UN GHS 3- No data avaiable
[Acute toxicity JOSHA HES 2012. No data avaiable
Iskin sensitization
Respiratory sensitization
EVICLP- No data avaiable
UN GHS 3 No data avalabie
JOSHA HCS 2012 No data available
| WHMIS 2015.-No data available
FEUICLP - No data avaliable
JUN GHS 3- No data available
JOSHA HCS 2012-No data avaible
|Wints 2015 No data avaiable
|Aspiration Hazard
[EUICLP- No dota avaiable
UN GHS 3 No deta avatabie
JOSHA HCS 2012. No data avaible
| WHMIS 2016. No data avalatle
Icarcinogonicity
IEUICLP «No data avaiable
JUN GHS 3 No data avaliable
JOSHA HCS 2012 No data avaiable
WHI 2015 - No data avalabie
|cerm cell Mutagenicity
FEUICLP «No data avaiable
UN GHS 3. No deta avaiabie
JOSHA HCS 2012+ No cata avaliable
watts 2015» No data avalable
[Toxicity for Reproduction
IEUICLP + No data avatable
JUN GHS 3+ No data avaioble
JOSHA HCS 2012- No data avaliable
WHHRIS 2015. No data avelablo
© muraton —— Aors20 5
[cP Ne da ate
Page of 8
es Reon $UN GHS 3.No data avalabio
jerorse (OSHA HCS 2012 No data avaiable
WHMIS 2015. No data available
ELIGLP «No ata
INGH 3+
lstorne 3 nee
Potential Health Effects
Inhalation
Acute (Immediate) .
Chronic (Delayed) :
te) :
Chronic (Delayed) .
Eye
‘Acute (Immediate) :
Chronic (Delayed) :
Ingestion
Acute (Immediate) :
Chronic (Delayed) .
[OSHA HCS 2012 «No data availabe
WHIIS 2015+ No data avalable
Exposure to dust may cause irritation. Processes such as cutting, grinding, crushing,
(oF Impact may result In generation of excessive amounts of airbome dusts in the
Workplace. Nuisance dust may affect the lungs but reactions are typically reversible,
Prolonged and repeated inhalation of respirable dust (partidles less than 10 microns in
‘Size) may cause damage to lungs. Exposure to PVC respirable dust hes been
reported fo cause lung changes in animals and humans, including decreased
respiratory capacity and inflammation. Axiall's PVC Suspension Resin is.
manufactured by suspension polymerization and the particle size Is generally large
enough in diameter that itis not considered respirable.
Exposure to dust may cause mechanical iritation.
No data available
Exposure to dust may cause mechanical iritation, Excessive concentrations of
rnulgance dust in the workplace may reduce visibility and may cause unpleasant
deposits in eyes.
No data available
No data avaitable
No data available
[Section 12 - Ecological Information
12.1 Toxicity
Based onthe high maleoulor weight ofthis polymere rate anspor of is,
compoundacross biological membranes is unlikely. Accordingly, the probability of
Environmental toxicity or bioaccumulation in organisms is remote. Due caution should
be exercised to prevent the accidental release of this material to the environment.
12.2 Persistence and degradability
+ Not subject to biodegradation.
12.3 Bioaccumulative potential
+ Matorial data tacking,
12.4 Mobility in Soil
+ Material data lacking
12.5 Results of PBT and vPvB assessment
+ PBT and vPVB assessment has not been carried out.
12.6 Other adverse effects
+ Material data lacking.‘Section 13 - Disposal Considerations
13.1 Waste treatment methods
Product waste + Dispose of content and/or container in accordance with local, regional, national, andlor
international regulations.
«Dispose of content and/or container in accordance with local, regional, national, andlor
Packaging waste
international regulations.
‘Section 14 - Transport Information
141 UN 742 UN proper | 14.3 Transport hazard | 14.4 Packing | 14.5 Environmental
number shipping name ‘lass(es) ‘group hazards
loor NDA Not Regulated NDA NDA NDA
lros NDA Toi Regulated NDA NDA NDA
lions | _ NDA ‘Nat Regulated NDA NDA NDA
liaTaicao] NDA Not Regulated NDA NDA NDA
146 Special precautions for + None specified.
user
14.7 Transport in bulk: + Data lacking.
according to Annex Il of
Marpol and the IBC Code
Section 15 - Regulatory Information
45.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
SARA Hazard Classifications + None
Taventor
‘Component Canada NOSL. EDELNICS TSCA
[Poiywnyl Chonda _|9002-06-2 No Yes Yes.
WVinyictonae [7601-4 No Ne Yoo.
Canada
Labor = ——
‘Canada - WHMIS - Classifications of Substances
* Vieyi Chloe 7e01-4 ——A,B1,02A,028,F
‘Uncontoted product
+= Polyvinyl Chloride 9002-862 according io WHNIS
Classiticaon erteris
Canada - WHMIS - Ingredi
* Vinyl Chloride
1 + Point Chotide
Tors 0.4%
9002-862 Not Listed
Environment ~~
Ganada - CEPA - Prierty Substances List
1+ Ving! Chloride 7601-4 ——Notlisted
+ Palyiny! Chioride 002-862 NotListed
eat gto
cup ww 3,030
Pe 9United States
Labor
‘U8, - OSHA - Process Safety Management - Highly Hazardous Chemicals
1+ Vinyl Chloride
1 + Polpinyl Chloride
1
U.S,-OSHA - Specifically Regulated Chemicals
'
| + Vinyl Chioride
t
+ Pojyviny Chlodse
Environment ————.-
UU'S.-CAA (Clean Air Act) - 1990 Hazardous Air Pollutant
Ming hiorce
{+ Potyiny! Chloride
"U.S. -CERCLA/SARA - Hazardous Substances and thelr Reportable Quantities
= Vil Close
| Poti crore
|
US. -CERCLA'SARA Radionuclides and Their Reportable Quantities
+ Veyt Chose
| + Paling chore
|.8.- CERCLAISARA - Section 202 Extremely Hazardous Substances EPCRA RAs
* Vinyl Chiore
| + Poiyeiny Criorde
U.S, -CERCLAISARA - Section 302 Extremely Hazardous Substances TPOs
+ Vinyl Chlorde
+ Polysiny Chloride
\
|u.s. -CERCLA'SARA - Section 313 -Emission Reporting
+ Viny Criorde
+ Poin Chiorde
\U.S, -CERCLA'SARA - Section 313 = PBT Chemical Listing
Vinyl Chloride
j + Polyiny! Chore
U.S, - TSCA (Toxle Substance
| = ving chloride
| « Poiyany: Chloride
United States - California
Environment ——-——~
USS. California - Proposition 65 - Carcinogens Lis
+ Ving Chore
+ PolyinglChioride
Control Act) - Section 12(4) - Expert Notification
75014
9002-86-2
75.014
9002-882
7501-4
9002-86-2
T8014
9002-862
7501-4
9002-86-2
7501-4
9002-86-2
7501-4
9002-86-2
75014
9002-862
Ts014
9002-86-2
rs018
9002.88-2
75.014
9002-882
Not Listed
Not Listes
0.5 ppm Action Level (See 22
CFR 1910.1017); 1 ppm TWA
{See 29 CFR 1910.1017);5
om STEL (See 28 CFR
4810.1097, 15 min)
Not Listed
NotListed
1 fy fnal RO; 0.454 kg fal RO
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not ised
0.1% de minimis
concentration |
Not Listed !
Not Listed
Not Listed
Not Listed
Not Listed
carcinogen, nial date 227187
NotListed
3)California - Proposition 65 - Developmental Toxicity
+ Vinyl Chloride
| + Polyiny Crionde
7501-4 Not Listed
9002-96:2 Not Listed
U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL)
+ Vinyl Chloride
+ Polyvinyl Corde
7601-4 Not Listed
9002.96:2 NolListed
U.S. - California - Proposition 65 - No Significant Risk Levels (NSRL)
+ Vinyl Chloride
+ Poiyiny Corde
7501-4 3 ualday NSRL
900286-2 Not Listed
U.S. - California - Proposition 85 - Reproductive Toxteity - Female
7501-4 NotListed
+ Vinyl Chore
+ Polyvinyl Chote 9002862 Not Listed
U.S. - California - Proposition 85 - Reproductive Toxicity - Male
+ Vinyl Chloride 750-4 NotlListed
+ Polyvny! Chloride 9002862 NotListed
15.2 Chemical Safety Assessment
+ No Chemical Safety Assessment has been carried out.
15.3 Other Information
ZSWARNING: This product can expose you to Vinyl Chloride, which is known
fe the State of California to cause cancer. For more information go to
wow P65Warnings.ca.gov.
Section 16 - Other Information
National Fire Protection Association (U.S.A.)
Flammability
Health Instabllity’Reactivity
‘Special hazards
Revision Date + 20/Augusu2021
Preparation Date + 20/ApR12015
DisclaimeriStatement of + The technical data given herein is correct to the best of our knowledge, information
{and belo’ at the date ofits publication. The information given is designed only as 2
{Guidance for safe handling, use, processing, storage, transportation, disposal and
Srisase, and is no! lo be considered a warranty or quality specification. No guarantee
[s being given as to the end use performance, The product is sold on the basis that
buyers test the product for their specitic purposes. This information related to the
raterial designated and may not be valid for such material used in combination with
‘any other materials or in any process.
Liability
Koy to abbreviations
NOA=No Data Available
oven hie Reson