Form 4West
Precipitation reactions occur when cations and anions in aqueous solution combine
to form an insoluble ionic solid called a precipitate. Whether or not such a
reaction occurs can be determined by using the solubility rules for common ionic
solids. Because not all aqueous reactions form precipitates, one must consult the
solubility rules before determining the state of the products and writing a net ionic
equation.
Ionic Equations Practice
Example 6
Write the chemical equation that represents the dissociation of each ionic
compound in water.
1. KBr
2. Na2SO4
Solution
1. KBr(s) → K+(aq) + Br−(aq)
2. Not only do the two sodium ions go their own way, but the sulfate ion stays
together as the sulfate ion. The dissolving equation is
Na2SO4(s) → 2Na+(aq) + SO42−(aq)
Write the complete ionic equation for each chemical reaction.
Remember only the aqueous substances can be converted into ions.
1. MgSO4(aq) + Ba(NO3)2(aq) → Mg(NO3)2(aq) + BaSO4(s)
Mg2+ (aq) + SO4 2-(aq) +Ba2+ (aq) + 2 NO3- (aq) Mg2+ (aq) + 2NO3- (aq)
+ BaSO4 (s)
Ba2+( aq) +SO42- (aq) BaSO4 (s)
2. CaCl2(aq) + Pb(NO3)2(aq) → Ca(NO3)2(aq) + PbCl2(s)
Ca2+ (aq) + 2 Cl- (aq) + Pb2+ (aq) + 2 NO3- (aq) Ca2+ (aq) +
2 NO3- (aq) + PbCl2 (s)
Pb 2+ (aq) + 2 Cl – (aq) PbCl2 (s)
3. AgNO3(aq) + NaCl(aq) → AgCl(s) + NaNO3(aq)
Ag+ (aq) + NO 3- (aq) + Na + (aq) + Cl- (aq) AgCl
(s) + Na + (aq) + NO3- (aq)
Ag + (aq)+ Cl- (aq) AgCl (s)
1. Acid + Base = Salt + Water
2. Acid + Metal = Salt + Hydrogen Gas
Excess acid was used .
Mg (s) + 2 HCl (aq) = MgCl2 (aq) + H2
Wait for all bubbling of hydrogen to stop
Evaporating the magnesium chloride solution
Concentrate the solution, leave to crystallize.
Things to consider – Reactivity Series
This method cannot make copper, silver or gold salts.
3. Acid + Metal Carbonate = Salt + Carbon Dioxide + Water
H2SO4 (aq) + CuCO3 (s) = CuSO 4( aq) CO2 (g) + H2O (l)
Observations – bubbles of CO2
- Blue solution forming
Wait for the bubbling to stop
Evaporation process then begins
CuSO4. 5H20 contains water of crystallization
Gentle evaporation to concentrate the solution and then you
leave to dry on its own.