P- Brock (@s-13 , Gx-1u)
Fa> In PAl> ba 2b
coup -3
(Bacon Femity)
& (Ben) Cs) adap! |
AL (Aluminium) (13) 32% sp!
ba (Galiwm) G!) UA%y p! oer nénp!
In (Ivalium) 4) __S*sp! f
TL CThelium) (8) 6A% ep! |
Physicap . .
setaast) me [Ame JRE ER Tony
B | Selia- New m ae
ay}ssie | at |Y Soe [Fane |/ fk
fe [soi otsy] aneray [HEC HSER 7 Nac |
Ln] Sole - Mutap | dnc. [oe x Af
Ty] Solid - Mutap dnc. 1
<>
&>T0> Ga>M> InStability op Stability op MP. | AP
+1 0-S. +30-S.
8B Max
xy
TY
Boum eysts im the foum of
Bia Votes in Ceystarl Lattice
(CN of each B= 5)
Bi, + dco sohedeen Shape
1Q Ventices
B12
ao Trig onad faces (eos ahedren)
30 Edaes
t Cafing => 60 Veneers
naa a (fullerene tee)
Our so Amal Aize ef Boren => 3h
Covgltut bends b/w bev atems and Close
Packs eter Stouctue DV High mestirg pont:Ga exists sb oisute olatemic (ba)
Mole wes int Selid phase =D So west
THAT Hg point
MP bo Very Hasge Ait.
Ga Bey wry JS buy MP duet BD.
No TE Oa _ewsts im b4ud Stale 1m a
wide eo) Temperate So it 1S vSeof
im Making tomoteces fore MmeAduMin Pugs
tempat wud -
a Qigua) < braCSetia) + Volune.
9 Boron doed aot exists im forona of 8%
ToS in Compounds - why ?
Ans: 3+
Oat de Bien
Very Pith:
[> data meng 4 free
S-unable to tompenste
L__, Hiden omen g. freért
S unable to lompennteCrema) Chemie seaenons —
© Reaction worth _dulegms :
E+ Ky —A > Ex,! Dor Relide)
eeape TH
qytt ast
All ake Covalent
BU ane AeworS aurols
© e&w BU, @) SBrae) S536)
WAU ArKcts north Vis 6
AXs + Ni, ——> %5B— Nite [Adduct]
© & Xs Av mot foams olimer-
(mone Stewie sepulsion in Bo Xs)
@pl-apr a@pl-sb3r @bT-ypr _&bT-spr
BFFs > AUs > B Bt BIs
Dec. Aprreng th af Te back bord
dnc. e7 clecpi enc 4 ef 8
dnc. Aeaie audit strug th:
dmc. Axe => dnc. LDF
duc: MP and BP:
AU ane Planar , equal bend angle = lao”H Lyar BxXs
Case x = UY, Br, I.
8 X35 +3Hyp ——— > BH), + 3Hx
Mechanism
H, ©
z XY 2
x Hg 6 *&™
> Sg S0Y **__y» “Bob
B x
ta 7 s- “yy 7
x “() x x Hx
Vatu &p
Caged xX=Ff
Bf3s Under Jord pastel hy deat psis deo to
hgh Sivength A B-F bonds:
BFFs + Bho —— > on), + SHP
BF, + HF —> Ht (aF4J_) 3
ef
4uBF, + 3hyo —> Bow,+ 3 HORT
p4tho bowc Tetwa
aud Flouro
oe (Bowe Ava) Boric acd.h-a
[ imé aie ee
APs = demic
Alxs Cx= 4,80, 2)
4 ‘
Belid State ji Vabevk. phase AS, u4U3 Sef,
_Betid Stele pee > “AP pase PRM S ln
Covalewt, Polymeric Coveteut diameic. i Ionic
Ne Y wy RN ON ((Atezo)]™ + axa)
Ua mw i MM a ; Bolutt
“ry Ny yo ON AY. on of,
L Alka, t& acidic.
CoN ofeach Ales |!
a Alka | eter” = (Atens con] Sr
: (arene) i
AW, fumes im ™morst an (Alleigo), JU, *$ > Alowss
As MOISE We Lay 4 He
Cw Witefemes 2) Alaosttze
9 lem pane hewis Adolic Stomgtys of BUs auddlds:
\e
oO & eh
BOs + NHx ——> C8 — Mts Bad ema
ALU, + NHa ——> Cay —
LA Shieugth = BOs > AlsThe _tendeucy up behave aS KA: dtougses
down te qToup in _- 18 torhalraes:
@ Reattion —_wai't Drs abs
E + 02. —— > f,93
@xc-) (oyrdesy
AN bewmes pesrive dus to protective toadng
op MoOn vex mete Surface
Pouodened We, Ay, 0, (expltSive ven)
Bars AnOs Gms Fm Thos
fradie Ambit Bane
+3 A +d
TH, 0 —€— Thot+o,
Flow
(Storeng base guivelut b Kor)
* +3 (~ ry +3
symone, © > Thos TH < uw)
p cpeaiine ie
Amo phous Bown 2 Mote sea chive—@ Reach. vworth Neo!
A +N, aT (on),
, ; Cdneeg amic §mbhite)
Ny CB pkon nitride )
[| | |
Ne NGA Ne Geaphte Ake Sauctime
lol Foo,
3 a Io 4 ol_lemaluctre _»p.
se ‘Y FN tepmerry
,: “A wes
ADo+n 3 — PIN
+312
(A! N + Hyo ——> AIO H), + nang
OD _Reachov wort C_
B+C ‘ ByC (Beton Cerbide)
Cova] vuts Poly meni
i 00 Sxtoum
Bullet pron) xtetmely Par of
VU. High Mp
Hou .
a Alo Gf eer
StummA +c A, Aly Ca (4407 30%)
(Au (s+ Hyo—> WAlow, + 3 chy)
Methanrale.
© Reachev po ty Auds
B suas only vote oxidizing auds
hou :
OR Zing Aad Nen- OW Rg Atuds
Cone: Ha SOy | Orl My SOy
Hxos , HOU, hx (x= fa an DL
HMnDy, HU0y | oty AudSeP! HsP0u, Hy Pos,
Ho PO»
B+ Conc. Heh ——> NP Patton
B+ Ale Ho — > NP Patho
B+ ofl He®y, —— No Rather,
Notes 8 Can't dlisphy Ht fom _awas.
= +> ay
B+ HNO, (lnc) ——> SOW, + +p
0 4b. +3 ry
B+ 23% (ume) —— BOK), + Sr + mo
NoTe:
lent. Acid \
& om Any LS CFanachondccus 3Al betemed pars've inn predener off Lone.
oyidizing ads C due ep protective Cating,
wer metel Stapau)
A+ yr L + Alas+ wf
A+ H5S2y Cj) —> ALSou), + hy
© Reaction worth al Kady’
Bt NaH G@) — Ne rather
BO+ Nach @ Pitty Naz Bost t
Ali+ NaoHcgy ——> Na Md, + Ha t
aa
Nal Alon,
Al + Nia once, —> Nag Alds4 of
Choe)
Extoachon oan
® Fon minvuls ;
Borax > Na, ByO,+ Jo yO
Colemanite § Go B84 %+- Sho
fale
Hy duateol R-0 €om
Nio. of tel Fanlur SPYR =) —Vechwge] manureSe “ap Bue en: -
fee
aut — 7 Ve —< By ~@Nyd
H Dd &
gro 7 a
™
CS < gs
oH
a4 Colemmitr + Go Bso, - Sto
Ive] charge = y > Teroarntur-(sp*) B=
[Link] Sp* typ 6 = b-¥=2
Naz By9, 3 Na,D t+ a Br
AaNg BO, > Ald t 805
Ca, Bg 0,1 AGO + 3 8.05
Nag COx 3 Nad + Oo
YU Na BO, 8 ANd D t AB OnNd, 0 tA B,O,ty,o
Ms By Op
Extoatr on af Boru form Borax anineral
Shh | Bota —"* Bowe audNag By Og + Hep + Sh,o —>»y Bow, t+ ANG
(tort.
Steba: Bowe Aad NPs Bro,
A BeKW), a Bg 0,t aryot
Step : ay Og Teokuter 8
By 0,4 Al “+67 Ahds
x Pa Ox 4 Mg A. 84 Mo
Bg 0,4 xn A» B+ And
dt is v Ol Ah cult $0 plane pure
Opt ll’ ne oun 3
() Ve High MPL
(i) High CopwAive dg. B-
As mee SEO» Cupstdling
“one 2 cong” (ty
Cyto ath on a. Botum {teu (Cole rante
Colemomte ———> 8ovax ——> 8
Sith:
Gy B49, + A Na, W314) — rd ay +4 N4BO, +
N42 6yo7ANeBO, + Alb, By g Ueystall’setabs
(44) (Fast Gop)
AOD. 3 Bs 03 ANA, 0-200
Nga 0 Fe By Ont NGO trey
alatds WhrBy 0s ana Bor
Staba G CO, (&) 4+» Go + a,t
U Wa Bray + ©, — > MA Bae AY toy
eae ae
4a:
Mh, Bu, On __Coptallzatber,
Bete tuep)
UNABO, = AYO + 2 Bo
On
47003, Aa, By 0p
dame othe, metiools 44 Bown extorcton
Bt z,f
. 4
© BIs Wy filam)
Wi) Ba Hy —__ 4A ¥, B+ totGit) BUg+ Ha —S—> B&B +HUTD
Qome enp.- lem pomas
B Aluminium
B stax Alds
Bowie gud Potash alum
Di botane
Sodium perbotate
Jen seepamic Beuzue
8 etax( Tin yea)
“ag Gu en]: ¢ ho
Por sp
oN $F
ana aa \ oO aby Ghyd
INK Pf gm
sp } o + Back bend
Bx 3 vor &
| %
aH
Total A&B % spr iNien — plane
Total AB > Bp > Fo OME UME
Teton my ae quire unt (anarn 4 Context pons)S How wang 0 atrns Dave I bog
Chana ctr in 4 anele cule of Borax ?
Ams: 6
=
Peto pute
OO wtute Crystalline Seta, waty Seluble
Ay. Solr of Borax 13 alkaline
(Salt ©) wA ava SR)
titi) Aq Beln. of botax gurs 43 buffer
Sow:
-
By Dp -+a¥g0 <= ty By & Hon™
Hp Gyo, + Sto —— > “Blew,
By 0447 + F#lyp — 4 RCH). + 20 ~
pha = Vas HC BOM) AB eW,+ 4 BOW,
uW-4 Salt of woA
pia pha + bg
Ruf er
= pit= pha = 4-25() Rea ubion wrth Auds
NMy By 0, + HY +h,o ——» 8 OCW,tNay
con:
Ke By 05 + "aS8,+ Hyd —> 8 OW, + Na,
cnc:
O) Reach wrt Mitel *
Nag By0, + ANMOH ——""'NaBo, + Mee
CS ockium anetebotalt)
Mia + 2B, Os => YAla BDL
Nig, 0/+ H2d
(i) Reach wath _amoltn ity? :
Nar By 0p + Ny GY —S—> BN) + Nally
(M0 |t mn) (Molt) B29
426
Nag O'/* 28293, BNI tH
uc _/ + Nie J + 8, 22
a
* Bota Bead Test(fox detectrem af A- bhce capren)
Steps *
Na, By, + bye (8) —S—> Nae Bu Oy B Hod
M4, By &2 —4 + ang Bo, + Br os
Bow ¢
arty du de
Temibarbat gel ke
(Glassy Beara)
Step?
= Block oyrde + Barer fread —4—rlolowey
beak
° J He
OLbloek opr de + Bz Os, ——> Metal met botate
( 20,~)
&y CoSOy + borax —4— > Bhe_jead.
Ce8Oy —A > Go + So
Bowar —S > Bro3+ ruBo,
Br0,4 Gos Gf Bow ,
( Bhe)4-3
Boe Need /otdheoboric a4
[Hs80s % 8 eH]
BK
| Ha 0
Cenc: Genc- B
& owdizingactd BOW, owwckiziny acid ay compound
:
Rrboame
enter
Boi + to ———> Bow),+ tet ) force
feoben bes
Ci _Steructwe |
hagored » H- bended a
Po yarn wc in Sold State
H ~ bend wrthin lagen
No_H=bend blu Sayers a
Slippery touch ae
me mole cute forms 6 H- bonds:Gi _flaaic Natwe
Veg weak, Mmobaric Stews 8S Fag
St aloes not undergo Self tonr2atron
dt 13 abootre acca
He 803 + Hoo = (sem) + Ht,
+ weak eleddohte
JES nertee arkbeniys 20d Moke Bronsted aug
gq
ci d Moe Bair Audie Sr reat, :
Crs _-1,Q- diets Sen =) 2 otto s Vinal AAS a frey
-¢-0
CH-OH , CM, -on , ’
I
CH, - 04 U4 —on Sur, blucod», Froutesy..
Cthglone glycol) cH, -oH (Gra hy y 9) C6 His 2) 646 Hin 5)
Glguueel (4 ly ceune)
Blow, + Heo == Blow + Ht —O
adanon A Crs -\)2 - ols , auore Shrayt,
+ bowie gud 13 imeumsed-
\
- t= di 1 D5 Qin Be =e- - nef
}— >|
~ Wh oc 07 eee
| 8
~C-oh_n 2)“ Yon po- >- li
mM€9q. ii) dvivey envi) im foeuvaral oliver 7
CdAe = Uroteien's P eimuple ) —> (#49) merase.
Boom /uhy tts Cann be obtained by
| °
CiS-J\2- Higls ~ C- Sy, Saige "
= C —SH Cooy,
1
Uy) He adios Her
a
UBOg + Hyd
BOW, see Bea fe
eutho bowie aad Myxta bowe aud
4
UHB0, pe Ry % + He?
(Teta bowie aed)
Hy By 2 > FL aQyos + 1,0
wn Borie anty amide)
H Bog
ot
BOW;
Ww) _Tert ouc awd
Blow. + 3 R-eh —“-» BER + Bio
C Altes) Cte alt bouate)Ces Uy, Sts)
Bury
Gruen edged fume
© (Devoe @e Hs)
(i) By + HT > Batty + *T
ey
madi
QB Fs + 6NaH ——> Bott, + 6 NaF nausnee
. on
BU, + LiLAl Hy) "E> Bot, +d + Alls
Lithium
Aluminium
ny duiole (LAH)
GU _dab method oh
te
Q Nia BHy + Ty —[o——> Boy tarut+ 4
Sodtuen Goveny °
douohy dude or aang Ag eur”
(Resta ung ag ety
QNUBMy = ANA 42 BNE eH Zit oI
Abts Ree
Bgye
(2 Uovelers, towe gas
WW kus acd
Gid__Stou ctw
tach B: Bb? hyduidlizeg
Hew C—*—D i, Nie. of 2e-ae bonis=y
8 Nb. af Beat bonis=2
B
——
Tmax atemszn aplaue= 4
(Nin = planer)
(wy Cotdhes fire in an om teating
oH, + 02 ee 8,0, + tpD, Ane
& Bz onal
Vi) Reacmen _vorth ews bases $
Cage + Syrmrnorrie) Cleavage of Bre
ees a(4 Ba “B)
Cage Ungy rennet or tad Cleavage ef Batt
/" eee
[2% (0) Cen)
oe
UV’ aminy(Cg), ion
( 2° amine)
wy ® Reautren vw’ NIH3$
PyH, + Nis wt Cony Gry), J en
(2 4 —=—
4
Ry Hy + Nits Hah te Banh + Het
Ce st) Com eu gamrc beuzme)
A
u
Py Hz + nig’ Ha tentg (BN), + if
(2 + (4m ong Ane 4 Bapshite
Sodiuen Pec borate L8odivn Prrcpo boleate,
Nag C Bs» Ou, (ow, J * 6H D
Pep atashren %
Nila) By 07 + ANIZOH ——> UAbBO, + 20
NIA B05 + MgO ——> N14, By (Ox) (OH),
oe
Wha, Bo On (ow,Pov brates *
anar 4 one” Ne"
04 Noe OY
H
BIS ysed as brighter Cuhite ney) i
Astheseg eat powoler 8
Inorganic Bonzong/ Boruxely/Borexine
(23 INE Hg)
p
w From oi be ame: A
3Bo Hp + 6 NH, —~—>4 Bs Ua + ota
lity From BY 3%
3 BU; + 3VHU ——> Barla Hou, HY
Ct chlexo Doraxine)
3BU3 By
n—__ —
4d- 4ut
<QA Bs N2Hs4s +6 VAR, —»8 Age yt
bNUAU F
3S Bo te
a BsNZhsUs + bduty 6RHg
sure? 8 BRM, 5-8 Ba My
Poropeetteds of imo arc. _bemzme’
O _Stourtuw — ()sosteuctunad 1 benzos)
4
No b=
Ape Set
i
He om HA
Resorontinns, Stn To.
cach B ama n> Sp Ay boralrzeed)-
D1 AMAA Speues
have 61 eleroms
Awusman'c leMpounds
OD Soe iteronic. yore bezme (Ua tote)
© Nev Poke (pmet=9) but Rave polar bonds
&) H
Resmromet Aybord,
Ba Ne Hy + yo —2> 3 ROH) +343 + 3H,
(Steam -(X= Sragle Valen
Nig yx
Ba
WD Ba Na Hy Xe
Ww
)
fi) x
l
Le
No
[
&
6
|
oot
ve
4
x,
HOS
©
® Y
FoursDit em ou
dnecgau'c benzene i& mee “are than
bouzene as Mp effective AUB prom te 83
thee in bemzme due gD _ p-|o duerltp blu
eeactig Samu Au E4|S-
Addit
Beoxzme a ><
5 Addition
. deroteg ane Benzene Ga
S+—g=
Bo NaH, + 3 HG —— Banat bg
Ch = X,0R --)
val 7
o7 Ny
WN Ne
nel ly
HPN onAf C3
GAlumimiven ton’ chloride )
Ala,
|
Betid State aim Vabevk. phase i A4,u0U8 Selo,
Covalewt, Pot jmekic | Covalent direc. i Sonic.
RATA aw AN Jt ‘(Alleeoy]™ + hay
ume ge Ny ANG Me Behan ef
a Y i A i Alda, 13 acidic.
CN ofeach D6 | | :
i od Als | tea = [AtonxconT ye
(amenerner) i
™ heating Ayoltated Als, it Suffer 3 Py duolyss:
AlU3 - 6Hyo . Meow, + Hut+ mod
[4i, Lily Ont ot
dy Wee gutya- Als
B
Af tg fumed im amor'st_ aA
Ald, + H,0 ——» Alow,+ Hut
C whtyRea chien yor" elkafi
AlUs + NaoH ———> MoH. + Alay
(olwte)
Soluble g_txe-_|
Nia (At. 0H),) Nach
@)
' dn wrth
_ Wy CRMuoH) *
AU, + WH, OH —— > ALOMW., 4 UMY
Cuolute)
t¥C-Al
Most oP d — bhek Cem pouunald drsselve am
CAC oP, ep. DH dd feta WMple x tstrpond.
NeTE:
Arn Uy + NIHYoH ———> Aue, +My
bdkety
u e
et XC:
[xm Wry, J »
Secluble
Al4 of An, (ory,
oot” JPrrebasaen xp daa tyd: Ales *
(2 AL + Hedy) —A—> Ata, + tpt
( tad.)
i) M+ Ug Wy 4+ Alcs
(andy)
ii) Aho, t C+ 4 4+ > Mas t of
UH HOs (Cbs) 2. (ani,
PotaS-. Alum C gow)
(Ky 804 + Ab Boy), Av go)
+) +3
Geuusl fouls ap alums * My So, - My (Say) “24 he
+) Bt -
Acted * al (ae), J ra [lM Cae]: 40,4
(each metelio "3S Bursounded by bye]
* + a Ae Baral! Sxe
M* = aut kt PB st WK
od 3
M = ast Fe 7 >t noeDeve i i
KpS0u (yy + Bb (Bu), Cen RX» Solution
Soled nya! aps
Potrsn Lu ae
(Double Salt)
Pre beutrete °
©
Ka Sey + rio hy duelysis (Saito 54458)
Aly (Sou), * Gtrm duc
i) Henson fer s
Posh Alum (8) —4 +> Swollen Alum + rot
(gra tramch)
ka Soy + Ap(S%), +24 ind
Aa
x z
Blkab_ meta) Sutbhats ce Hrednally Blno5 + Sesh
Stable Ute Catbeonates.(ii) Feats for Yotas ‘
Potash alia —FaMEEBE » Violet olor
(amps pecsence of Kt)
Bade Baddy ami ndeap dm selubl
(uote) oy Arua .
‘Solunwy NaOH MOH) 5) — > Sokeble
fr Vata Albury white PH
Vt MOH) .L rma Wobble
White
VU tAsh
Ci) USeo) de Stop bleeoting by Loagulaton:
id used fe wile pumifcatien (mate ppt- af anud
dist)
Wi) Vset aS moklnut im tertile imdusrey
Colour bind ex t fabric)Soup — ly
Caxton = famuily)
C (6) 4: ani apa
Si UW + 3a% Bpa
Ge (3a) 2 ua® ypa ee > ne mp
Sm (S0) + sar spa J
PL (82) 2 Bo pA
Guu) phe) ond _atrnic Pobwuhes:
Phpitep |Natw | Sixe| =-E) deg len Allotaes 4 Pe
state pretion
© | Sold |NomnetP| | nay. ase] us [ae
Sr | Sold — |NommeteP!] YS 1 | doc. —
- “VG
Ge | Sold |Metallord mig]
Sy | Selrd metep ane: ine sr dee
Pp | Sold | Metep x
st eat dec.
> SiS Ge >Pb>Sm e=6
bend
Strougih-ef? rewe ference | dng: ut A Stabil ty] Stabil ty
size Size ¢ feo
0:s:
cl — —_
Be} dee.
Se me dee.
. : mc.
5 [one dnt J
>
amon — throm
torhedp end’ % bxr-13
‘
downs, all Known lvmeuts ”
Alotwobe.s af Sy
TRIG
a -Sm I36C
—— -S
(wowte T> B6C e a
Sud) C d Pouselr’)
« &- Sm and B-Sm have At ferret
Shou dad Abtows crn im crystal LMhcs .
Covurnpen oP X-Sm into fb-Su vs
treme ad bin oliSease oe tin plageBeualin 9 rf. Sy > caging Sound D Tn og.
" SuQhy. Sho > Butter af Tin
(use: Mn olout)
Gem vurtad Pa urens
OQ Rear gn vote haleg ons
an —_
i zc) Lee K2 EXu( Tétoa Aahide)
_( # PoTy) |
NC dow not Hear obseetty Uditte haleg ens.”
Chy me made _inofiretty
2g CHy + Uy + cay + Hy
m ;
Y Luis mt bow ’
PptY: Siren OxV’'Serr, £ 3 Strong Jadluter,
‘BU Tetonfalides, ate tov 4 ,Comp aus en of Stability
ory
O chy > dy > CBs, > CTy (5 »
@ Ge Xo A Sn ty XK Pbk
( Stabrinty ef er
o- S$. _ tye: dows
We Brug)
@& Cy S Siky > 5 eky > Saky> Poy,
(Stabiirty fry
0. S. et - eloasag
He Ors)
a=
iS Moun sut Si rs mot- why?
men
Steuc. ul Sven im (arr of
Ss > ™t
a
8r Fe
\File
Seagen_*
Chu + Ho ———> Alo TA evr
C opeA not Pawe laut O4bital
Valrug hel
wb oC!
st
Cc
“tTK Sr
SiUy + UrgD ——= > Sion), + WAY
CSiltcre acid)
A SOy_ + BHyO
6k + gd scot + AY
(Suet Pesctag Phos9 ime
sam) (Bye PS)
Chlodafexem ete
E
tee 0
ze 1 Ed3 (dowdy)
44 “a
£0, > £0
= Aude
~ covalent.
ovde | rtatume ovde | Natune
co Neutoa) COn Audie
Sid Sn tudic
Geo tudic Fed. | vtuuicSO | Amphotewic. SO. | sonphotemc
VoD | cmmphotemic. P| Awmphotemc
($0 exists enly ateveny Dig trap
Mixed ovr led : Pb, Ds => (Poo- Por), Bye (Reo. ah)
dtm pho ted C fm po Teta C
Ss Sta i + C30), C50) ----
ee
Citlien SubSde dhinne ar
8 Compare, Resturing. powers 4 Co ,SmD, Poo -
Pos: top > Sp > hep
Cime: Stabilitys +2 > 8: dowa Hu 3 voup)-
8 Compare ONtO1"Rinng prweng of C2 ,5mQ, Poo, -
fs: +4 +. ay
Co,
74 | C (odtot) + Hero —4»% Cd+ H2
&4 ot) ts
oS
sgn gas/
( water 58
) Bosch's Voor:
@ Reariem wrth awas :
Aud Chae
E + Cone. aud an Evy @=-mem)
cy c+ lene -Hntbs a Hy + (On + nto, 4
Po + Ge. Hy —t» Phas t Hof
Po + Game nia, 49> Fa itog) + HyD+ Noa
@ Rea chon vt alKabr :
Sn + Naty ——> N4&SmD, + 7
fb + Klaoh ——> jimh 22+ Mt
Si + Ntaon fir, Aig, Sd, + tTCosas
‘ ' '
i f < Ken Steechyo
danic Gxbude-s C4 fut Crduides _Stetehvemae
omvettyann toed Oe Ly
EY Ben ¢ * Byl . Fes c
Auta leales » Bae “Wo
Nana Casio rwnalurnn
Pore pyen'oleS
=I Mn Ca,
_ NM Storoni omer Grtudes.
+ Polymeric Sdlrits * romeot by metalsyf Ad f block.
+ Extremely hod C-twabbed im intushitep
+ Weve Weg amelting Vos ef Lathe
pont: Taprcalty Nerthey Covalent
‘ jt eer pf Ho i Moe tonic
Q] Sten) it Hamdness > Respeerve mutap
*3D- Nletwetol Stoudia i Heahee M7: pt’ thom metals
Le Vee AS abtTAyivein
| Culing tso).SAllo tropes oC
'
Chota ne Drm or pha us
Oxdwud aueamsornent | to On denad adtsventmug
She wes (S obsswu
Gy Gra plete Ui) Chwrcoap
ui Hiamend WW karmb black
GD Fullerenes Gi ke pousder.
y entlin benas
pa Zz a
Black — ary Colowud
Cath C+ Oh Pyborclised
12 C-C Bendoruger <2
Au c-ct bend dungths aly usp
» Auemar ce
dmay cts Ae eta’
+ Slipboud Selid Lagat Streit
Vind waalls fortes blo adprcud Layers: Thole rmo Ayn avni Cally mst Stabe allotropy ac
Density & tances Dees thom that of
Or pared:
fore Valuers.
° used as Lubricant
. Chen ortly rete Sea Bre trom AcQamond
oe booty
Covap'te Strong Owner, yore Loo
7
dike KMnO 4, Hy Cay Op
Hood . Coo
Cooy
pe" (Melee
che awd
° ‘wy
oz ~, 4
ox, <<
r
\ po enon °
Di dunevd : ot
/\
+ 3D uneluerd Solrd:.
*
>
tah Ci SP
C-L Bm eoer=/
AU (© bend hugths ac¢eSame
Cmtdins Aanglin bods
Do not lmoluet “Cleetorat
Density moe thon _gwaphete
Haudest allerree of (ah bon -
V& Digh M-Y-
UStk AS Ab VAsive in Cutting bools
Sue Otomend 1S Cefovrtess
ampwe Atamend + (lowed.
Nim - byic
Htaphte ——> Oimuond (uom- spt)
llerem¥s
L__y Ant visu, Auch oxclaus
Owabhite —eleunic ac, Svot ——> (mtams
pa Cir abrtosp hex) Vappoutaseq
C Ong
SM Att Anowes
fullermes
Coot Buckminster Fulluene
CFootball rte Shape)BO &
* Cath ¢ Bp Aybaiased
"No amg ling beng
+ Puust Allotepe of, Carbon
»_Arcornoibic Camp umd -
Two types og C- C bend Doagths:
Peutagerad aS well AS Rexaonat
Hane
Tings:
WHys Graphite < Diauend < Futtenenes
C4ue) (tun)
(xu)
Cm (Fue
Pe mtagonel wings = (2
a
a Hexng onal Tings = ao
c-C Ain tages ate than, i'm Cyo?
How wandany
40 Cath Carlyn 04, te3
Ain bg
eoNeed dinkages > L273. =40
ammo oxide ( Co
(rn.
Pow en
Ww Cut A+ of
lib Cory + Cis) —4-» coh
Gi) By de Ay due oth on of frome aud Lobalic avid:
0
, nt 3,
nt 5%, Co + (On
AWw Faw Potassium Ferro cyanide *
Ky [fe ery] ts > fy 504 + Fe Set nent
Ky [Fe rng) + HeS°y —A> fy Soy + Pe Dy 460+
C Come, iy), SOy
+ Ns
Lene Ha S0y (tty) 59 |
+» (0dndusteial dS a
ww C + Ho 4 SY tomy Hap
By Stem) Duende
hot) Nate gas/ Syngas
du Co +otny, 4 5 Come Nop
ky SY
hob) ah. Peodutoe qs
Poebentres ‘
i Cofowlas , Odouk ler’ as , Neuteep.
Ww Toric
Oy + Haemoglobin ——> O44 “haemoa le bin
CD + Haemoglobin — Cx boty “haemoglobin
ON ett
CoO —— lawe % dehy
louah
* Niegvous nes
* WaK ege Sight
. Frovelly death.
0.GU _AewiS base *
eo &
7C =O;
CO aus ab dkewis base sing EP fc.
Ay
Bo Hy + (0 ———> a Ms8 + Co)
5) Reduaing Tabune
Co 8 a good Aadu urs quer (24,60
Fegd, + CO —S» fe + Cot (metallurgy af &)
W Dele chin
+ CO puan8 wrth blue flumup-
+8
1 Yd, + hor to — Pay + By, +H
(ue) (Black)
Wi) Abs epi *
CO is absorbed by Amumoniatel Culf
Cud + ANHa+ co —> Leu (rgg eg]
( Cofourters)Vil) Quanbtabve eSh mation of co%
wry) cexey (48)
SCO + tad Hh, Ty + 5 Co,t
QA (o-AY ( Sterely
(CBieck= Bly
Za + aN, S25 ——* Mh Suayy ANGE
(Steray
(Binet = Bay Cotowserss
@ Galeri npide (C02)
tos VKC-O2
a Cok og fomp - = o,f +e. --
ee 3
C+ op mm @®
cD + 20, —4++> w,
Hy + O20 ++ ©, tho
GD Metal Crctorate/biaeborate Hts tayfe.....
ey:
CaCos+ HU ———> Gly t Co + Wo
Nah Wat HNO, ——> Madlog+ CO) + WO
(i) Teumal dtteomperation of (actionste / biterbaratet
Caco, —4 > Qot w,ANaHW, —*—> Ala, lo, + Oot Ino
Mats —A—+ Abo agen.
(M = Na, k, Pb, Cs)
Peroben NE xf Or
W) Coto, palouetens, Acielrc
Gy dt Liens Dame punter amilkg (When ig
Creer comnileymerd aliS appears)
rap) Solr COg + Iuevom 48 ay re:
Gy CO, 1 used 4s fike e¥ bingrgher
W) :Silt Quo itis lpmpowngs
Silty + used a3 Sear tonauctye3
Silom is extoacted by-
CO Realy ttm of Sand o% Fuserz (Si0.)
SiOr+ aC —4*» SG + 2eof
CReof =
tet)
Gi) Reduttrenn of Sid:
Sd, + 2%, —4> Si + a Fula
Say + amy te Si + 2 HU.
Com po mad of Get
Siliten Ovrpwde Gr0s)o
4:
}
| | |
— Ss; —-o —s; —o — Si—o~
) | |
0 ° o
| } bo
—s' —o — S—o — SF —
| ( /
(ad ~ network Boli)
* Each Sr rs Butuoumded by 4 '0’
' Each O rs dutowmded by 43?faa, Si
&
* Thue is ApT - 3d T back bonding bw 0b Sj
depbun
(S03),
— Aim eephou Kerselqued
Nye talline’= Tridyonte, Quasdx,
: pre ballte
Quantz ——> Piezo dectac Substance
C Poodluce elector ert 4 m™ Applying porBuxe)
< ved high theunrel Sta bill
vey igh smelting porn
Kuo
fen
N45 SiO + Hso
Sids N\ HE Sify + Hao
Sidy + Une —> Srfut Iso
Sr hydbuolyses paedrally Guat the &F3
SrFy + Ytyo ——> Srlom, + anf
CSify + Que ——" (8 Fe] Jaa
BSiFy + Ynyo ——» Sr@h), +2 Wy(SiA)HF «Ss hy only aud lWohich Sachs with
glass CSr02)
(E>: Smaiat Auten, other dun: Stuccepul sm)
HF iS Mot Stor :
mn gles Vetbe/s,
C3t cs Stoted in plas te)
@ Silitenes
« Sileenes ate
949 Aino Sil Comic (Si-o)
Polymers Paving 3f—o -S; Ainkag es:
. They a Sy nthere pety mend
+ They ane plaparicl by Aydialyss of
-alegl chlo Silanes.
followed ay ly MH Sabp,
CHy % Methome
Sity & Silane
Sidy 3 Tetoachlonoi lane
RS; U3 8 Akg? ter chlo silane
Ro 3i Cp 2 Diafkyt of Ch low Silane.
£3 SiC 5 Tot afkat chlowo SilanePore bavatton alk ChloMo 3; lames:
WD Qdsp 43) SE Crs sidy
(Majo)
tin Fem Graig mand) Rengeurs
S- s+
R- Mg — (R= —Hs- Cots ---)
Sidy BMX 5 RS :04.4 AMR Ry Sidy RMX Ks Sid
t Maxcp t Maxg t Maxg
Subsotunm Reavrony
Tapes awd pueb axahen oh Silanes
C) Chaim Sileynes / kimear Silicones ?
Ry Sidg—2 2 > Chaim Sihicomes / dimear Silicones
Ra 31g + Hyg0 — > Ro Sylow, + aHyp& R &
| 1 )
---— Sr —o —Si —0 — Sr —o----
| | ]
B RK R
Chain Silreme (Mab
GS _Cyetea Steen
Ro Sr u —n? 4 Kc Sileymes
nd Gwar ~ )imk Stk
RVUs thd, boar - Dimbteo Sil terns
-R3Us + Shed — > R Sow, + 3nymw Sr —o — Ss — 60 — S-—O----
-— 0 — Sr—o----
)
p
wm SoS
I
gz
Rad
Fun
Mah a5
iS USed foe Cham tem
RaSvO
im poly smeSan'on process of SS Itunes -
Ory
i
38Popparties wk Silicones
CO Veeg Thigh Mee mad Stability C'Stromg Sic , Sto beds)
tii) €xthe anely Tigh M9. qud B:&
aid Chemically rebel
Qw_Hyduo phobic__C wabek 208 ¢Stant)
(du tp bems Swoewded by mon peter alhy?
Gtups)
W)_Oo met Conduct electorerty.
(Wi) Non toxic
Wil Bro - Cempatible
UN) Vis warty =f Q4qued Se tenes 23 mot aff e ches by
Temperate:
G_High deel coe Stoength (Stable ry alectore Freld)
@) Five Poroogt
Uses =p Silivenes!
Ouse aS water Axpetlaut #7 pamts-
Cid USeot fete ma kivy Coo big moulds.
lili) USeal for clectereal mS ulaten:
@) Useol for cwSmetic S
©) US| for fixing punctwe in fs:
WY Liqued Siltones ane used aS Iubsitauts ever
™ Very Cold corr'trend.@__ Silicate s :
Sr-p bendy 4 Metap |» dn Siliates
Quem Cahrenlay
Bihicates ety present in Commi, Som Sones,
Glas, Vatwous mimety/3 -...
y=
Sinnplesir — Silrcate anim + Sr,
[ Basic Siltexte unre:
Tybe3 op Siltcates *
W ettho 3iicates Gid fyeo siliated
Giid Simgte Charm Sil'eates Civ) Cyelee SiltatesWW Deuble cham Sikutes Wi) Shut Sik ules
Wid 3d - Silitetes
(iy Oat Siltcgres [Sy & Mere canis]
bf ZA Si Oy > Kiko
Hooks dike Aram ond
USed im making Tewellees
Less dumable but cheaber than
Olvarmmend -
© Pymo silicates /O'silicates *
(Si, 0957 + meted Canora)
U= 6-
2 Srby let Sing L Had
esi
Oo(sio,)"
chain
Each aetratedud umit- 1S Shaving itis
two p'd por'th — Mat jacent—uwts-
a) Cyclic Silicate
|
t
Gros), + _Meta/ atensmas Bes Aly 3% Dig Bergt) ominexap
G) Double chain Silregtes “CA am piibetes)
(Asbestos) — (sty 0,5),
v
TRS Sonallest_ epeating vite
3 = 6=
(32 One) > (Se Ox, ),2 (sy Q, ),
Half detahulu) oni'ks 244 shan thes
2% wrth Suvwumdings, white sert Ral
dutvath lta) Unr'ks Aue Shatiorg Boo’ wrth
Dus [Link] S
ON au ang, ead Letwatedead vra't
83 Shawing aS Sv’ vot Sumo unalngs.WD Sheet Silcahes
unit
(S101 Om), (80g) > (Sa 5°),
Cath tetwahedus Unit 9 Shmuing /H1B,
3D? wth Ss iho wactinns Units:
{iy = Sitiates, C Atymino Silcares)
(Srog), => feo Si" ome suplaced by O°?
Examples to Learember_!
( Keolites Coy Pocmurt)-_
Ly mimesNido Aly Si, Og + XO
(Sioa), > asi” Bt +
2h, > r Merblaced by AW and Ay
No Te’ KRSM-§ CGeotte) iS used as Catalyst
pcm Alecks into Gasefine:
(i FeDds bor, (a mmimerst)
KA S308 at x
Se), B13 Saplaced by Wand Kt
Gi) (stra manne Uabis dazulls
Ly Blue _byment
nag Ay Sip Oy Se
at ge
(Nae Al Sy Oxy) Se .
|, CSro,) bait JEpuaed by bAL +
im) @ A t(Siog 2"
hain
tNSum omaha
Type Fetemula [Link] DY hated bya
po etree re |
Duethosilicate Si oy" Zeng
Pytesilicate Sig 09° 4
Single chain (sos 2, a
Siltute
eye —_ | GOI 3
|_Siliate _|or= 3,6 (most armnen) |
le Chair *y One 4,3
Double claim (s 4 On Ly lay’ 236
[sia |“ OO" fy seg)
Sheet (Si2.057),, 3
Siliates
a. $02)
3p - Silicates Soret rebaced —
bay AIS* onetation S
Some omts wding Siliales
© All Sihates< ae mom panar
@__dn_all Siltates i 0-5-0) Si = +
0:S- ° -a
ou® Mm Situ anton =4x- 2
Coee= mo. 9p Si » @? m0. of o )
S4 Sr. Oz
aRY — 7#xQ =-6
Ono op ‘0’ worth ene_bond_%& —ve charged 0's |4x-2 |
Ady. roto
dp Pande val min Ben Aly Si,dig
ig:
m (a) + Qs) + 6 Yt 1B Eas
an + 6 tau -36 =o
Ma?ame dmbortaur Compowwls =P Sar pud
Compounds ¢ Sm
OD Stamnous chtouide (Sm Uy):
Frrep ahatton
‘Sn + HU ——> Say + igh (sus
Smu** Compounds ake adusgys stud alarg
worn the peeces op Sn_ metal
Smt? Ste» Syltt
Sn + Sn“! ——> 2&rit
Comp we boktiguatien
Porop ek tie &
Ww Reducing Natu:
Sut _lompowd sae good Audlutiyy agrute
a> Sut 3 ombte 3Tble “tram Sn
+e 5 $e +y
Sy Cy + Us, ——> feauy + Sndy
"Sady + Wu, — > ly + Siu,
& ze tT
ty
| Sn, + Hy Gy ——> Ha tle + SoltyL“4y. us + Sn, —> yf + Shey
(Grey Bice
+2 +> 0 74
Qn Oy + Au ds — Au + Sndly
(Cotlordad
gaa
pe el D +y
Su Un + Ago — Ayt Sndy
(Brak
5 2 ate “sot?
— CBlaey
di) _kewis awd
Snd, au3 as duoS 4ut du gd
(2 Vatut OALutad om Coutoal atom
U1? dncomplete 0 tub
Sud, + Ch ——+ Snu,”
a aB
(Ny) Heat duated 5
Sm 4,7 AH20 Undeesors Ay dualyars m
Aeohing’ “d
Snly+ FHp0 (6) —49-> Su Owes HUt HoeA, Snow,
3nd
CY) Regu yo'th al kel
Sully + A NgoH ——> Sulon. | + anucy
(Whrte )
te
Nia, [Solo Wy) Xo
(Setubk) “aol
Gite Waa. (Se 04]
CSetapley
Z Stannic chiewde (Sm dy) *
Pow banat
o Sn + Ug Cent) ——> Su ty
Gy Sm Gy —Aeeahiony — Smcty
Gi) Sm Ae Sntly
Paro
= aq
Gd _hewis Aud. Sn Gy + AU ——> Sut,
SnGut @HU ——> Hol 8ney,
Sm Weta Muy ——> Why), L Sn bs]tip Reaction wrth atkel’
Sn Uy + 4Y Nao h ——» Sulow, 4 + YAAYy
Wobrty
Sm (on kh
na, [Sn ( 1, ] NOP
(Setubk) ‘
& Oxides ef Sy
Sn 0% tye Sm03: whrte
@m plot wi) @m plot wu)
: (Mutastamc au,
See poration oma 9
D ty =e?
Sn + Oa 8 Sg OO
Cexc-)
air-
+a 7
Sa C, Oy 4A, Sy0 + Wt Wr
(Stann ous
0 Kalate)
Yooper sird
Ha SDy
“2
Sm Soy
(abs ence bia aia)(absente of a4)
ae
Nagou Nita Sn 02 9 A1g,{Sn(0K,]
(absence of ain)
+4
HoSOy
—HaS0u sm (Sou),
+4 HY a
Sud, fo OMY
ae
+4 4
Ngov Na, Sud. ot Ny, [Sno]
Piseb mation +
UW Pb 29), —A_» fot no, t +ogh
=
w tides Bb eae Roe tat
ey Phony —4> Por 4 dst
%by D3, —*—> apo + 15,4
(Pho: Pho)Pra Oy —*> 3f07 Lot
(2 Pbo- Yb02)
YorobundieS
a «fellows ¢ ohowrud (knowns Massrcot)
Pho
RB coo use Cknowy 43 Ai thang)
C2 Amnphotene owde , Water imdetuble
w) Leumit Aauds:
Ao + Hu ——» PbUQ + Io
Ro + Ha S0y ————> PhSOyt Hao
Yo + HNO, ———> PbhWlos), + tro
Git) Regetmr worth alike:
PbO + NaOWw ——— > An hdgt ho
Nol Pb OW.)
a heaol Oi oyrde (PbO) =
ons
Pbx0, * Red Lead ( Mineral)Posy + Y HAto, ——> Pho, 4 +2 Ph (Mog) +30
Cont) (Bac)
en - P4or weactron.
+o +Y ~ ae
p
[Link] — aro: PbO, [oo basic b Os
i La ynoa 2 Pb(Nos), + &ino
[C71 20) ee
Poroputies »
G) dnSeluble in water, ampho teuc oxide
© Snselble m Has ag
did Strom onidise, CO > Orta ze)
(¥s09_——» Po + (oJ)
*Y “t +2 °
PbO. + UK ——> Phu, +t ayo
aM +Y ss
Yb O, + 309 ——> Fb30,
fl au * "@y) Heating / boi ling wort [gne-_ovy Awds%
( PhO, ——> Phot og
|_av¢ _, Salt
#0505 + Cone. rvdsmy —A—» od + Sat
Awd
9b 0g + HNOS —+— Po (Nog) +0n+hO
Clent) 2
9 Og + —HaSey —S—> Py So, 4 Drab Myo
Clent.)
®) Reach wrth alkali
(Soluble)
PL Op+ Kao ———> Nal Ph(on), ]
a
Nia PbO + Meo
Reams ep aminrd ovo of Yo
Po,0, + Hy —4-» 7?
APD + HY — >» 4 Pbhuy + dugod
Ph Og tHu ——> PU, + +danroPb,Oy + HU —4A—> Pilla + Us + ine
The &mdq