U0047
Date of issue :2018/11/08
Revision date :2019/03/05
Version :2.0
SAFETY DATA SHEET
1. Chemical product and company identification
Trade name : U0047
Company/undertaking identification : ISHIHARA CHEMICAL CO., LTD.
Address : 5-26 Nishiyanagiwara-cho, Hyogo-ku, Kobe-shi, Hyogo
652-0806, Japan
Tel. : +81-78-682-2307
Fax : +81-78-682-2320
Department name : 7th Sales Department, technical development group
Recommended uses and restrictions : Reagent for analyzer
2. Hazards identification
GHS classification
This product does not correspond to GHS classification criteria.
Hazard pictograms : None
Signal word : None
Hazard statements : None
Precautionary statements : None
3. Composition/information on ingredients
Product form : Mixture
Chemical name Concentration Formula CAS No.
D-Sorbitol 40~50% C6H14O6 50-70-4
Magnesium nitrate <0.1% Mg(NO3)2 10377-60-3
Organic compound <0.1% Trade secret Trade secret
Propylene glycol <0.1% HOCH2CH(OH)CH3 57-55-6
4. First aid measures
First-aid measures general：
Consult a doctor/medical service if you feel unwell.
If exposed or concerned, get medical advice and attention.
First-aid measures after inhalation：
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Artificial respiration and/or oxygen if necessary.
Seek immediate medical advice.
First-aid measures after skin contact：
Wash off immediately with soap and plenty of water removing at the same time all contaminated clothes.
Get medical advice if skin irritation persists.
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First-aid measures after eye contact：
Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do.
Continue rinsing.
Seek immediate medical advice.
First-aid measures after ingestion：
Rinse mouth.
Do not induce vomiting.
Never give anything by mouth to an unconscious person.
Seek immediate medical advice.
Personal protection in first aid and measures：
Wear proper protective equipment.
Most important symptoms/effects
Symptoms/injuries : No information available.
after inhalation
Symptoms/injuries : May cause skin irritation / dermatitis.
after skin contact
Symptoms/injuries : May cause eye irritation.
after eye contact
Symptoms/injuries : No information available.
after ingestion
Chronic symptoms : No information available.
Other medical advice or treatment : Treat symptomatically.
5. Fire fighting measures
Suitable extinguishing media : Water spray,Dry powder,Foam,Carbon dioxide
Unsuitable extinguishing media : Do not use a solid water stream as it may scatter and spread fire.
Fire hazard : Irritating toxic fumes or gases may be caused in the event of a fire.
Reactivity in case of fire : No information available.
Firefighting instructions : The product is not easily ignited.
Exercise caution when fighting any chemical fire.
If there is a fire close by, use suitable extinguishing agents.
Move the container out from the fire area with safety guaranteed.
Stop leak if safe to do so.
If it is difficult to move the container, continue water spray from
protected position until container stays cool.
In case of fire: Evacuate area. Fight fire remotely due to the risk of
explosion.
Prevent fire fighting water from entering the environment.
Personal protection : Do not enter fire area without proper protective equipment, including
(Emergency response) respiratory protection.
Protection during firefighting : Self-contained breathing apparatus.
Wear fire/flame resistant/retardant clothing.
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6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
General measures：
Evacuate personnel to a safe area.
Mark out the contaminated area with signs and prevent access to unauthorized personnel.
Ensure good ventilation of the work station.
Do not attempt to take action without suitable protective equipment.
Do not touch the leakage and walk on the leakage.
Carry out the work in the windward, and take care not to inhale the fumes etc..
Always take a shower after work.
Environmental precautions
Avoid discharge to the environment.
Notify authorities if liquid enters sewers or public waters.
Methods and equipment for containment and cleaning up
For containment：
Large quantities: Contain large spillage with sand or earth.
Collect leaking and spilled liquid in sealable containers as far as possible.
Wash away remainder with plenty of water.
Recover the cleaning water for later disposal.
Remove to an authorized waste treatment plant.
Prevention measures for secondary accidents：
Refer to the detailed list of incompatible materials in section 10 Stability/Reactivity.
Clean in contaminated areas after the treatment.
7. Handling and storage
Handling
Technical measures：
Both local exhaust and general room ventilation are usually required.
Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any
potential exposure.
Precautions for safe handling：
Do not handle until all safety precautions have been read and understood.
Carry out operations in the open/under local exhaust/ventilation or with respiratory protection.
Open container carefully to avoid spurting.
Wear suitable protective clothing, gloves and eye or face protection.
In case of breathable dust and/or fumes, use a self-contained breathing apparatus.
Do not eat, drink or smoke in areas where product is used.
Do not allow product to spread into the environment.
Prevents handling of incompatible substances or mixtures：
Refer to the detailed list of incompatible materials in section 10 Stability/Reactivity.
Hygiene measures：
Always wash hands after handling the product.
Contaminated work clothing must not be allowed out of the workplace.
Wash contaminated clothing before reuse.
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Storage precautionary statements
Technical measures：
Use appropriate ventilation.
Storage conditions：
Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight.
Store away from oxidation agents.
Containers which are opened should be properly resealed and kept upright to prevent leakage.
Store locked up.
Minimize storage period.
Material used in packaging/containers：
Store always product in container of same material as original container.
Incompatible materials：
Oxidation agents
8. Exposure controls / Personal protection equipment
Japan administration level : Unlisted
Exposure limits (JSOH)(2017) : Unlisted
Exposure limits (ACGIH)(2018) : Unlisted
Appropriate engineering controls : Ensure good ventilation of the work station.
Emergency eye wash fountains and safety showers should be
available in the immediate vicinity of any potential exposure.
Respiratory protection : Suitable respiratory equipment.
Supplied air respirator if working in a confined area.
Hand protection : Protective gloves.
Eye protection : Eye protection.
Skin and body protection : Wear suitable protective clothing or rubber apron.
Environmental exposure controls : Avoid release to the environment.
9. Physical and chemical properties
Appearance
Physical state : Liquid
Appearance : Clear Liquid
Color : Colorless
Odor : Slightly characteristic odor
Odor threshold : No data available
pH : 6.0 - 8.0
Melting point/Freezing point : ≤ 0 °C
Boiling point : ≥ 100 °C
Flash point : Non flammable
Relative evaporation rate : No data available
(butylacetate=1)
Flammability (solid, gas) : Not applicable
Explosive limits (g/m³) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Specific gravity density : 1.17 (20°C)
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Solubility : Dissolve in water
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity : No data available
10. Stability and reactivity
Reactivity : The product is non-reactive under normal conditions of use, storage
and transport.
Chemical stability : Stable at ambient temperature and under normal conditions of use.
Possibility of hazardous reactions : React violently in contact with oxidation agents.
Conditions to avoid : Heating,On contact with incompatible materials,All heat sources,
including direct sunlight
Incompatible materials : Oxidizing agent
Hazardous decomposition products : Carbon monoxide
11. Toxicological information
Acute toxicity (oral) : No data available
Acute toxicity (dermal) : No data available
Acute toxicity (gas) : Not applicable
Acute toxicity (vapour) : No data available
Acute toxicity (dust) : Not applicable
Acute toxicity (mist) : No data available
Skin corrosion/irritation : No data available
Serious eye damage/eye irritation : No data available
Skin sensitization : No data available
Respiratory sensitization : No data available
Germ cell mutagenicity : No data available
Carcinogenicity : No data available
Reproductive toxicity : No data available
Specific target organ toxicity : No data available
(Single exposure)
Specific target organ toxicity : No data available
(Repeated exposure)
Aspiration hazard : No data available
12. Ecological information
Hazardous to aquatic environment : No data available
- Acute hazard
Hazardous to aquatic environment : No data available
- Chronic hazard
Ecotoxicity : No data available
Persistence and degradability : No data available
Bioaccumulative potential : No data available
Ecology - soil : No data available
Hazardous to the ozone layer : This substance is not listed in Annexes to the Montreal Protocol.
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13. Disposal considerations
Ecology - waste materials：
Cleaning residues containing this material may be classified hazardous waste.
Remove to an authorized waste treatment plant.
External treatment and disposal of waste should comply with applicable local and/or national regulations.
Contaminated container and packaging：
Do not dispose of the packaging without first carrying out the necessary cleaning.
Empty containers should be taken for recycling, recovery or waste in accordance with local regulation.
14. Transport information
Not regulated for transport
International regulations
Marine pollutant : Not applicable
Special transport precautions : For the transportation, load the cargo without direct sunlight,
damage to the container, corrosion, and leakage.
Prevent from the collapse of cargo without any fail.
Do not heap up heavy goods.
15. Regulatory information
Follow in accordance with all local, state, and federal regulation.
16. Other information
Data sources：
SDS JIS(Z 7253:2012)
JCW Chemical Products Handbook, The Chemical Daily Co, Ltd. (2017)
CHEMINDEX, The Chemical Daily Co, Ltd. (2018)
Regulations for the carriage and storage of dangerous goods in ship
IATA Dangerous goods Regulations, The Japan Air Cargo Institute for Safety (2018)
National institute of Technology and Evaluation, HP
Japan industrial safety and health association, Japan advanced information center of safety and health, HP
ezCRIC, Japan Chemical Database Co. Ltd.
LOLI(List of Lists) ChemADVISOR Inc.
SDS from a manufacturer of raw materials
Disclaimer
The contents in this document do not always guarantee the accuracy and safety of the information although
the contents have been described under the currently available documents and information.
All the chemicals should be treated as the substances which have "unknown hazard and toxicity". It may be
much different in the danger and hazard depending on the circumstances, handling, storage condition, and
storage duration.
Carry out the usage, storage, and disposal of the product with the guidance of experienced mentors.
Decide safety handling under the responsibility of users using this information.
The SDS of our company may be revised without prior notice when new knowledge, results, etc. are
obtained.
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