SDSIN / EN / 12

Version: 2.0
Revision date: 13.09.2013
Initiator: 0001
150000096086

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name: Eastman Effusion(TM) Plasticizer

Product No.: 33792-00, P3379202, P3379203, P3379208, P3379205, P3379204, P3379200, P3379206

Additional identification
Chemical name: terephthalic acid, dibutyl ester
CAS-No.: 1962-75-0

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Plasticizer
Uses advised against: None known.

1.3 Details of the supplier of the safety data sheet

Manufacturer / Supplier
Eastman Chemical Company
200 South Wilcox Drive
Kingsport, TN 37660-5280 US
+14232292000

Visit our website at www.EASTMAN.com or email [email protected]

1.4 Emergency telephone number:

For emergency health, safety and environmental information, call 91-22-5599-9757 in India or call 00-1-
423-229-4511 in the United States.

For emergency transportation information, telephone 1 423 229 2000 (USA) and identify the call as a
transportation emergency.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

The product has not been classified as hazardous according to the legislation in force.

Hazard summary
Physical hazards: Not classified as hazardous.

Health hazards
Inhalation: None known.

Eye contact: None known.

Skin contact: None known.

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Ingestion: None known.

Other Health Effects: No data available.

Environmental hazards: None known.

2.2 Label elements Not applicable

2.3 Other hazards: None known.

SECTION 3: Composition/information on ingredients

3.1 / 3.2 Substances / Mixtures

General information:

Chemical name Concentration Additional identification Notes

terephthalic acid, dibutyl ester 100% CAS-No.: 1962-75-0
EC No.: 217-803-9

* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
#This substance has workplace exposure limit(s).
PBT: persistent, bioaccumulative and toxic substance.
vPvB: very persistent and very bioaccumulative substance.

SECTION 4: First aid measures

4.1 Description of first aid measures

Inhalation: Treat symptomatically. Move to fresh air. Get medical attention if symptoms
persist.

Eye contact: Any material that contacts the eye should be washed out immediately with
water. If easy to do, remove contact lenses. Get medical attention if
symptoms persist.

Skin contact: Wash with soap and water. Get medical attention if symptoms occur.

Ingestion: Seek medical advice. Material is not expected to be absorbed from the
gastrointestinal tract so that induction of vomiting should not be necessary.

4.2 Most important symptoms No known chronic or acute health risks.

and effects, both acute and
delayed:

4.3 Indication of any immediate medical attention and special treatment needed
Hazards: None known.

Treatment: Treat symptomatically.

SECTION 5: Firefighting measures

General fire hazards: None known.
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Version: 2.0
Revision date: 13.09.2013
Initiator: 0001
150000096086

5.1 Extinguishing media

Suitable extinguishing Water spray. Dry chemical. Carbon Dioxide. Foam.
media:

Unsuitable extinguishing None known.

media:

5.2 Special hazards arising None known.

from the substance or
mixture:

5.3 Advice for firefighters

Special fire fighting None known.
procedures:

Special protective Self-contained breathing apparatus and full protective clothing must be
equipment for fire-fighters: worn in case of fire.

SECTION 6: Accidental release measures

6.1 Personal precautions, Wear appropriate personal protective equipment.
protective equipment and
emergency procedures:

6.2 Environmental precautions: Not regarded as dangerous for the environment.

6.3 Methods and material for Absorb spill with vermiculite or other inert material, then place in a container
containment and cleaning for chemical waste.
up:

Notification Procedures: In the event of a spill or accidental release, notify relevant authorities in
accordance with all applicable regulations.

SECTION 7: Handling and storage:

7.1 Precautions for safe No special precautions are necessary beyond normal good hygiene
handling: practices. See Section 8 of the MSDS for additional personal protection
advice when handling this product.

7.2 Conditions for safe storage, Keep container closed.

including any
incompatibilities:

7.3 Specific end use(s): Plasticizer

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Version: 2.0
Revision date: 13.09.2013
Initiator: 0001
150000096086

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limits

Country specific exposure limits have not been established or are not applicable
unless listed below.

8.2 Exposure controls

Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used.
controls: Ventilation rates should be matched to conditions. Supplementary local
exhaust ventilation, closed systems, or respiratory and eye protection may
be needed in special circumstances; such as poorly ventilated spaces,
heating, evaporation of liquids from large surfaces, spraying of mists,
mechanical generation of dusts, drying of solids, etc.

Individual protection measures, such as personal protective equipment

General information: Eye bath. Washing facilities.

Eye/face protection: It is a good industrial hygiene practice to minimize eye contact.

Skin protection
Hand protection: It is a good industrial hygiene practice to minimize skin contact.

Other: No data available.

Respiratory Protection: If engineering controls do not maintain airborne concentrations below

recommended exposure limits (where applicable) or to an acceptable level
(in countries where exposure limits have not been established), an
approved respirator must be worn. Respirator type: Air-purifying respirator
with an appropriate, government approved (where applicable), air-purifying
filter, cartridge or canister. Contact health and safety professional or
manufacturer for specific information.

Hygiene measures: Observe good industrial hygiene practices.

Environmental Controls: No data available.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance
Physical State: Liquid
Form: Liquid
Color: colorless
Odor: Mild
Odor Threshold:
pH: No data available.
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Freezing Point: 14.7 °C

Boiling Point: 341 °C
Flash Point: 196 °C (Setaflash Closed Cup)
Evaporation Rate: No data available.
Flammability (solid, gas): Not applicable
Flammability Limit - Upper (%)–: No data available.
Flammability Limit - Lower (%)–: No data available.
Vapor pressure: < 0.038 Pa (25 °C)
Vapor density (air=1): No data available.
Specific Gravity: 1.0452
Solubility(ies)
Solubility in Water: < 0.00001 g/l (25 °C)
Solubility (other): No data available.
Partition coefficient (n-octanol/water): log Pow: 4.61 - 5.66
Autoignition Temperature: 419 °C (ASTM E659)
Decomposition Temperature: Thermal stability not tested. Low stability hazard
expected at normal operating temperatures.
Dynamic Viscosity: 16.0 mPa.s (25 °C)
Kinematic viscosity: 15.3 mm2/s (25 °C)
Explosive properties: Not classified
Oxidizing properties: Not classified

SECTION 10: Stability and reactivity

10.1 Reactivity: None known. Materials containing similar structural groups are normally
stable.

10.2 Chemical stability: Not fully evaluated.

10.3 Possibility of hazardous None known.

reactions:

10.4 Conditions to avoid: None at ambient temperatures.

10.5 Incompatible materials: Strong oxidizing agents.

10.6 Hazardous decomposition Carbon Dioxide. Carbon Monoxide.

products:

SECTION 11: Toxicological information

Information on likely routes of exposure
Inhalation: None known.

Ingestion: None known.

Skin contact: None known.

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Eye contact: None known.

11.1 Information on toxicological effects

Acute Toxicity
Oral
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl Oral LD-50: (Rat): > 2,000 mg/kg
ester

Dermal
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl Dermal LD-50: (Rat): > 2,000 mg/kg
ester

Inhalation
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl No data available.
ester

Repeated dose toxicity

Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl NOAEL (Rat, in feed, 90 d): 0.125 % Read-across from a similar material
ester NOAEL (Rat, by gavage, 90 d): 125 mg/kg Read-across from a similar material

Skin corrosion/irritation:
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl (Rabbit, 4 h): none
ester

Serious eye damage/eye

irritation:
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl (Rabbit): slight
ester

Respiratory or skin
sensitization:
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl Skin Sensitization:, (Human) - non-sensitizing
ester

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Germ cell mutagenicity

In vitro
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl Mutagenicity - Bacterial, : negative +/- activation
ester Chromosomal aberration, : negative +/- activation
Mutagenicity - Mammalian, : negative +/- activation

In vivo
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl No data available.
ester

Carcinogenicity
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl No data available.
ester

Reproductive toxicity
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl No data available.
ester

Specific target organ toxicity - single exposure

Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl No data available.
ester

Specific target organ toxicity - repeated exposure

Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl No data available.
ester

Aspiration hazard
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl No data available.
ester

Other adverse effects: No data available.

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Version: 2.0
Revision date: 13.09.2013
Initiator: 0001
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SECTION 12: Ecological information

12.1 Toxicity
Acute toxicity
Fish
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl NOEC: (Fish, 96 h): >= 0.17 mg/l (limit of solubility in fresh water)
ester

Aquatic invertebrates
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl NOEC: (daphnid, 48 h): >= 0.16 mg/l (limit of solubility in fresh water)
ester

Chronic Toxicity
Fish
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl NOEC: (Fish, 28 d): >= 0.024 mg/l (limit of solubility in fresh water)
ester

Aquatic invertebrates
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl NOEC: (daphnid, 21 d): >= 0.050 mg/l (limit of solubility in fresh water)
ester

Toxicity to Aquatic Plants

Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl NOEC: 0.013 mg/l (limit of solubility in fresh water)
ester

12.2 Persistence and degradability

Biodegradation
Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl 76 % (28 d, Ready Biodegradability: CO2 Evolution Test) Readily biodegradable
ester

Biological Oxygen Demand:

Product No data available.
Specified substance(s)
terephthalic acid, dibutyl No data available.
ester
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Chemical Oxygen Demand:

Product No data available.
Specified substance(s)
terephthalic acid, dibutyl No data available.
ester

BOD/COD ratio
Product No data available.
Specified substance(s)
terephthalic acid, dibutyl No data available.
ester

12.3 Bioaccumulative potential

Product: No data available.
Specified substance(s)
terephthalic acid, dibutyl No data available.
ester

12.4 Mobility in soil: No data available.

Known or predicted distribution to environmental compartments

terephthalic acid, dibutyl ester 3.05 - 4.5 (QSAR model)

12.5 Results of PBT and vPvB No data available.

assessment:

terephthalic acid, dibutyl ester Not fulfilling PBT

(persistent/bioaccumulative/toxic) criteria

12.6 Other adverse effects: No data available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

General information: No data available.

Disposal methods: Dispose of waste and residues in accordance with local authority
requirements. Incinerate.

SECTION 14: Transport information

Important Note: Shipping descriptions may vary based on mode of transport, quantities, package size,
and/or origin and destination. Consult your company's Hazardous Materials/Dangerous Goods expert for
information specific to your situation.

IMDG - International Maritime Dangerous Goods Code

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Class not regulated

IATA
Class not regulated

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:

TSCA (US Toxic Substances Control Act): All components of this product are listed on the TSCA inventory.
Any impurities present in this product are exempt from listing.

DSL (Canadian Domestic Substances List) and CEPA (Canadian Environmental Protection Act): All
components of this product are listed on the DSL. Any impurities present in this product are exempt from
listing.

AICS / NICNAS (Australian Inventory of Chemical Substances and National Industrial Chemicals
Notification and Assessment Scheme): One or more components of this product have been notified as a
new substance to Australia. Importation into Australia may be restricted.In Australia, its use is restricted to
research and development purposes only.

MITI (Japanese Handbook of Existing and New Chemical Substances): This product is listed in the
Handbook or has been approved in Japan by new substance notification.

ECL (Korean Toxic Substances Control Act): One or more components of this product are not listed on the
Korean inventory. In Korea, its use is restricted to research and development purposes only.

Philippines Inventory (PICCS) : One or more components of this product are not listed on the Philippine
inventory. In the Philippines, commercial industrial use is restricted to lawful food, drug, or cosmetic
applications. Other uses are restricted to research and development purposes only.

Inventory of Existing Chemical Substances in China: All components of this product are listed on the
Inventory of Existing Chemical Substances in China (IECSC).

SECTION 16: Other information

Revision Information: Not relevant.

Key literature references and No data available.

sources for data:
Training information: No data available.

Regulation (EC) No. 1272/2008

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 SDSIN / EN / 12
Version: 2.0
Revision date: 13.09.2013
Initiator: 0001
150000096086

Issue date: 13.09.2013

SDS No.:
Disclaimer: This information is provided without warranty. The information is believed to
be correct. This information should be used to make an independent
determination of the methods to safeguard workers and the environment.

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