SMEA1403
SMEA1403
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THERMAL POWER PLANT - PLANT LAYOUT
COMPONENTS
Coal delivery equipment is one of the major components of plant cost. The various steps involved
in coal handling are as follows:
(viii) Weighing and measuring (ix) Feeding the coal into furnace.
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COAL DELIVERY
The coal from supply points is delivered by ships or boats to power stations situated near to sea or
river whereas coal is supplied by rail or trucks to the power stations which are situated away from
sea or river. The transportation of coal by trucks is used if the railway facilities are not available.
UNLOADING
The type of equipment to be used for unloading the coal received at the power station depends on
how coal is received atthe power station. If coal is delivered by trucks, there is no need of unloading
device as the trucks may dump the coal to the outdoor storage. In case the coal is brought by railway
wagons, ships or boats, the unloading may be done by car shakes, rotary car dumpers, cranes, grab
buckets and coal accelerators.
COAL DELIVERY
The coal from supply points is delivered by ships or boats to power stations situated near to sea or
river whereas coal is supplied by rail or trucks to the power stations which are situated away from
sea or river. The transportation of coal by trucks is used if the railway facilities are not available.
PREPARATION
When the coal delivered is in the form of big lumps and it is not of proper size, the preparation
(sizing) of coalcan be achieved by crushers, breakers, sizers, driers and magnetic separators.
TRANSFER
After preparation coal is transferred to the dead storage by means of the following systems:
• Belt conveyors
• Screw conveyors
• Bucket elevators
• Grab bucket elevators
• Skip hoists
• Flight conveyor
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BELT CONVEYOR
It consists of an endless belt. Moving over a pair of end drums (rollers). At some distance a
supporting roller is provided at the centre. The belt is made, up of rubber or canvas. Belt conveyor
is suitable for the transfer of coal over long distances. It is used in medium and large power plants.
The initial cost of the system is not high and power consumption is also low. The inclination at
which coal can be successfully elevated by belt conveyor is about 20. Average speed of belt
conveyors varies between 200-300 rpm. This conveyor is preferred than other types.
ADVANTAGES
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SCREW CONVEYOR
It consists of an endless helicoid screw fitted to a shaft. The screw while rotating in a trough transfers
the coal from feeding end to the discharge end. This system is suitable, where coal is to be transferred
over shorter distance and space limitations exist. The initial cost of the system is low. It suffers from
the drawbacks that the power consumption is high and there is considerable wear of screw. Rotation
of screw varies between 75-125 rpm.
BUCKET ELEVATOR
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It consists of buckets fixed to a chain. The chain moves over two wheels. The coal is carried by the
buckets from bottom and discharged at the top.
It lifts and transfers coal on a single rail or track from one point to the other. The coal lifted by grab
buckets is transferred to overhead bunker or storage. This system requires less power for operation
and requires minimum maintenance. Although the initial cost of this system is high but operating
cost is less.
SKIP HOIST
It consists of a vertical or inclined hoist way a bucket or a car guided by a frame and a cable for
hoisting the bucket.
The bucket is held in upright position. It is simple and compact method of elevating coal or ash.
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FLIGHT CONVEYOR
It consists of one or two strands of chain to which steel scraper or flights are attached which scrap
the coal through a trough having identical shape. This coal is discharged in the bottom of trough. It
is low in first cost but has large energy consumption. There is considerable wear. Skip hoist and
bucket elevators lift the coal vertically. Belts and flight conveyors move the coal horizontally or on
inclines.
STORAGE OF COAL
It is desirable that sufficient quantity of coal should be stored. Storage of coal gives protection
against the interruption of coal supplies. Also when the prices are low, the coal can be purchased
and stored for future use. The amount of coal to be stored depends on the availability of space for
storage, transportation facilities, the amount of coal that will whether away and nearness to coal
mines of the power station.
The coal is piled on the ground up to 10-12 m height. The pile top should be given a slope in the
direction in which the rain may be drained off.
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UNDER WATER STORAGE
The possibility of slow oxidation and spontaneous combustion can be completely eliminated by
storing the coal under water.
IN PLANT HANDLING
From the dead storage the coal is brought to covered storage (Live storage) (bins or bunkers). In
plant handling may include the equipment such as belt conveyors, screw conveyors, bucket elevators
etc. to transfer the coal. Weigh lorries hoppers and automatic scales are used to record the quantity
of coal delivered to the furnace.
CYLINDRICAL BUNKER
Weigh lorries, hoppers and automatic scales are used to weigh the quantity coal. The commonly
used methods to weigh the coal are as follows:
The Mechanical method works on a suitable lever system mounted on knife edges and bearings
connected to a resistance in the form of a spring of pendulum.
The pneumatic weighters use a pneumatic transmitter weight head and the corresponding air
pressure determined by the load applied.
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The electronic weighing machines make use of load cells that produce voltage signals proportional
to the load applied.
A large quantity of ash is, produced in steam power plants using coal. Handling of ash is a problem
because ash coming out of the furnace is too hot, it is dusty and irritating to handle and is
accompanied by some poisonous gases.
Figure 1.10 Ash Handling & Dust Collection System – General Layout
• Hydraulic system
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• Pneumatic system
• Mechanical system
In this system, ash from the furnace grate falls into a system of water possessing high velocity and is
carried to the sumps. It is generally used in large power plants.
• Low pressure hydraulic system used for continuous removal of ash, and
• High pressure system which is used for intermittent ash disposal.
In this method water at sufficient pressure is used to take away the ash to sump. Where water and
ash are separated.
WATER JETTING
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In this method a low pressure jet of water coming out of the quenching nozzle is used to cool the
ash. The ash falls into a trough and is then removed.
In this system ash from the boiler furnace outlet falls into a crusher where larger ash particles are
crushed to small sizes. The ash is then carried by a high velocity air or steam to the point of delivery.
Air leaving the ash separator is passed through filter to remove dust etc. so that the exhauster handles
clean air which will protect theblades of the exhauster.
In this system ash cooled by water seal falls on the belt conveyor and is carried out continuously to
the bunker. The ash is then removed to the dumping site from the ash bunker with the help of trucks.
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SMOKE AND DUST REMOVAL
In coal fed furnaces the products of combustion contain particles of solid matter floating in
suspension. This may be smoke or dust. The production of smoke indicates that combustion
conditions are faulty and amount of smoke produced can be reduced by improving the furnace
design. To avoid the atmospheric pollution, the flyash must be removed from the gaseous products
of combustion before they leaves the chimney. The removal of dust and cinders from the flue gas is
usually effected by commercial dust collectors which are installed between the boiler outlet and
chimney usually in the chimney side of air pre-heater.
GRAVITATIONAL SEPARATORS
Mechanical dust collectors are sub-divided into wet and dry types. In wet type collectors also known
as scrubbers, water sprays are used to wash dust from the air. As shown in Fig.1.15 (a) by increasing
the cross- sectional area of duct through which dust laden gases are passing, the velocity of gases
is reduced and causes heavier dust particles to fall down. Changing the direction of flow Fig. 1.15
(b) of flue gases causes the heavier particles of settle out. Sometime baffles are provided as shown
in Fig. 1.15 (c) to separate the heavier particles.
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ELECTROSTATIC PRECIPITATORS
It has two sets of electrodes, insulated from each other that maintain an electrostatic field between
them at high voltage. The flue gases are made to pass between these two sets of electrodes. The
electric field ionises the dust particle; that pass through it attracting them to the electrode of
opposite charge. The other electrode is maintained at a negative potential of 30,000 to 60,000 volts.
The dust particles are removed from the collecting electrode by rapping the electrode periodically.
The electrostatic precipitator is costly but has low maintenance cost.
SUPER HEATER
It is integral part of boiler and is placed in the path of hot flue gases from the furnace. The heat
recovered from the flue gases is used in superheating the steam before entering into the turbine
(i.e., prime mover).Its main purpose is to increase the temperature of saturated steam without raising
its pressure.
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• Condensation loss in the pipes is reduced.
• It removes entrained water particles from the steam conveyed to the steam turbines and
increases the temperature of saturated steam.
Whatever type of boiler is used, steam will leave the water at its surface and pass into the steam space.
Steam formed above the water surface in a shell boiler is always saturated and cannot become
superheated in the boiler shell, as it is constantly in contact with the watersurface. If superheated
steam is required, the saturated steam must pass through a super heater. This is simply a heat
exchanger where additional heat is added to the saturated steam. In water-tube boilers, the super
heater may be an additional pendant suspended in the furnace area where the hot gases will provide
the degree of superheat required. In other cases, it superheats the steam generated by the boiler
and increases the temperature steam above saturation temperature at constant pressure.
Superheaters are placed in the path of flue gases to recover some of their heat. In bigger installations,
the super heaters are placed in an independently fired furnace. Such super heaters are called
separately fired or portable super heaters.
WORKING
Steam stop valve is opened. The steam (wet or dry) from the evaporator drum is passed through
the super heater tubes. First the steam is passed through the radiant super heater and then to the
convective super heater. The steam is heated when it passes through these super heaters and
converted into superheated steam. This superheated steam is supplied to the turbine through a
valve.
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Applications
This type of super heaters are used in modern high pressure boilers.
AIR PREHEATERS
Air pre-heaters are provided in boilers to preheat the combustion air. There are two main types:
recuperative and regenerative air heaters. Tubular or recuperative air pre-heaters are provided in
boilers of medium and small range of steam generation. This type of air pre-heater becomes very
large in size if they have to be used in very high capacity boilers like 600 tons/hr of steam
production and above. In these cases regenerative air pre-heaters are used. The arrangement of all
these air pre-heaters differs with the design and, in large, the way they are combined for very high
capacity boilers. Regenerative air per-heaters are compact and can have a stationary or rotating
hood. A combination of tubular and regenerative type of air pre-heaters is used in very high
capacity boilers. The tubular being used for primary air heating and the regenerative used for the
secondary air heating. In case the boiler designers do not want to go for a combination of tubular
and regenerative air pre-heater, then they have a choice of tri-sector regenerative air heater.
Normally the ambient air is heated to about 300 to 350 degree centigrade. This results in a flue gas
temperature drop of around 230 to 250 degree centigrade. So for each degree pick up in air
temperature, roughly 0.8 degree drop in flue gas temperature is achieved.
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ECONOMIZER
The feed water from the high pressure heaters enters the economizer and picks up heat from the flue
gases after the low temperature super heater. Many types of economizer are designed for picking
up heat from the flue gas. These can be classified as an inline or staggered arrangement based on
the type of tube arrangement. The staggered arrangement is compact and occupies less volume for
the same amount of heat transfer when compared to the inline arrangement. Economizers are also
designed with plain tube and fined tubes. The fins can be longitudinal or spiral. All these types are
suitable for clean fuels like gas, oil, and low ash coals. For high ash coals, only the plain tube inline
arrangement is used. This is mainly to reduce ash erosion and thus reduce erosion failures.
These economizers pick up about 50 to 55 degrees centigrade in a large capacity boiler, which will
reduce the flue gas temperature by about 150 to 170 degree centigrade. The boiler designers always
keep the economizer water outlet temperature to about 25 to 35 degrees below the drum saturation
temperature. This is done to mainly avoid steaming in the economizer. A steaming economizer
generally is less reliable. As a rule of thumb, for every one degree pick up of economizer water
temperature, there will be a drop of about 3 to 3.5 degrees.
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REHEATER
The purpose of a reheating cycle is to remove the moisture carried by the steam at the final stages
of the expansion process. In this variation, two turbines work in series. The first accepts vapour
from the boiler at high pressure. After the vapour has passed through the first turbine, it re-enters
the boiler and is reheated before passing through a second, lower-pressure, and turbine. The reheat
temperatures are very close or equal to the inlet temperatures; whereas the optimums reheat
pressure needed is only one fourth of the original boiler pressure. Among other advantages, this
prevents the vapour from condensing during its expansion and thereby damaging the turbine
blades, and improves the efficiency of the cycle, because more of the heat flow into the cycle
occurs at higher temperature. Power plant furnaces may have a reheater section containing tubes
heated by hot flue gases outside the tubes. Exhaust steam from the high pressure turbine is passed
through these heated tubes to collect more energy before driving the intermediate and then low
pressure turbines. The reheater functions similar to the super heater in that it serves to elevate the
steam temperature. Primary steam is supplied to the high pressure turbine. After passing through
the high pressure turbine, the steam is returned to the steam generator for reheating (in a reheater)
after which it is sent to the low pressure turbine. A second reheat cycle may also be provided.
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BOILERS
Steam generator is a device or equipment which burns the fuel and facilitates the exchange of
heat produced to the water to generate required quantity and quality of steam. Thus, it is a heat
exchanger which has the place for burning of fuel and flow of hot flue gases produced and also
has space for storing of water and steam. As steam is produced & stored at high pressure than the
atmospheric pressure, steam generator is also a pressure vessel. To handle the hot flue gases and
to keep high pressure steam, certain other mountings and accessories are also required for its safe
and efficient operation. In this way steam generator is not simply a vessel to boil water but it is a
complete unit performing the complete task of producing & handling the high-pressure steam by
burning of the fuel and exhausting the flue gases efficiently and safely. Most of the boilers are
actually a type of shell & tube type heat exchangers.
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Evaporation end point of these plants
In subcritical units the drum acts as a fixed evaporation end point. The furnace water walls act as
the evaporator. Not so in the case of a supercritical unit. The evaporation end point can occur in
various levels of the furnace depending on the boiler load the percentage of Superheat in
supercritical units is higher than subcritical units. Because of this the furnace tubes act more as
super heaters than waterwalls. This necessitates the use of higher grade of materials like alloy
steels in the furnace.
Heat transfer area
Higher steam temperatures in supercritical units results in a lesser differential temperature for
heat transfer. Because of this heat transfer areas required are higher than subcritical units. Higher
Superheat steam temperatures entering the HP turbine also mean higher reheater inlet
temperatures which again results in a higher heat transfer areas.
Water Chemistry
In supercritical units the water entering the boiler has to be of extremely high levels of purity.
Supercritical boilers do not have a steam drum that separates the steam and the water. If the
entering water quality is not good, carry over of impurities can result in turbine blade deposits.
Materials
Super critical power plants use special high grade materials for the boiler tubes. The turbine
blades are also of improved design and materials. In fact, the very increase in higher pressure and
temperature designs are dependent on the development of newer and newer alloys and tube
materials.
(a) Alignment of axis of boiler: Boilers are classified as Horizontal, Vertical and Inclined type
boiler. Horizontal boiler occupies more floor area but is easily accessible for inspection and
maintenance. Vertical boiler occupies less floor area but difficult to access and clean. In a dairy
processing plant, we generally find horizontal type boiler.
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(b) Flow of water and hot flue gases through the boiler: Boilers are broadly classified as fire
tube and water tube boiler. This is the first major classification of boilers. Most of the boilers are
actually shell and tube type heat exchangers in which one fluid i.e. either water or hot gas flows
through the shell and other through the tubes. In a boiler, if fire flows through tubes and water
remains in the shell, it is called fire tube boiler. Conversely if water flows through tubes and fire
or hot flue gases pass through the shell it is called water tube boiler. In a dairy processing plant,
fire tube boilers are generally used due to low pressure requirement, comparatively safe, less
operational cost and easy to maintain type characteristics.
(c) Location of furnace or burner: Boilers are classified as: Externally fired and internally
fired. If fuel is burnt outside the boiler and after burning only, hot flue gases are forced to flow
through boiler, it is called externally fired. e.g. Babcock & Wilcox boiler, Sterling boiler etc. If the
furnace is located inside the boiler itself, it is called internally fired boiler e.g. Cochran boiler,
Lancashire boiler etc.
(d) Mode of water circulation: Boilers are classified as forced circulation and natural
circulation boilers. If the water flows through boiler by the force of pump, it is called forced
circulation boiler. If water flows due to natural current produced, it is called natural circulation
boiler.
(e) Pressure of steam produced: Boilers are classified as high pressure and low pressure
boilers. Above 80 bar pressure, boilers are called high pressure boilers and below this limit,
Boilers are called low pressure Boilers. In a dairy processing plant where steam is used only for
heating purpose and not to produce any mechanical work, low pressure boilers are used. High
pressure boilers are used in applications where steam is used as a working agent like in thermal
power plants etc. High pressure boilers are Benson, Babcock & Wilcox, and Lamont etc. Low
pressure boilers are Cochran, Cornish, Lancashire & Locomotive boilers.
Table 1.1 Comparison between fire tube and water tube boilers
1. Hot gases flow through tubes or flues Water flows through tubes passing
passing through water stored in the shell through the passage of the flue gases.
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2. Steam production rate is less i.e. up to 9 Steam production rate is high. It can be
tons / hour up to 450 tones/hour.
6. Feed water treatment is necessary but Feed water treatment is critical and
not so critically required because small highly essential as even a small deposit
deposit in the boiler shell does not in boiler tube may cause overheating and
deteriorate much the performance of bursting.
boiler.
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It can cope up with fluctuating load. It can also bear fluctuating load but only
9.
for a shorter period.
It takes time to produce steam and It produces steam fast and so increases
10.
increase the steam pressure at a slower the steam pressure at a faster rate.
rate.
Cochran Boiler
It is a best example of vertical fire tube boiler and has a very simple construction. It is internally
fired multi tubular and natural circulation boiler. Its working can be well understood with the
help of a diagram
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Babcock & Wilcox Boiler
It is a simple water-tube boiler and used where higher steam pressure and higher steam production
rate is required. It can be used for stationary and marine purposes. It consists of a horizontal shell
supported on the masonry structure. The shell is connected to two headers on both ends, which
are at different level and connected by a number of inclined tubes. When shell remains filled with
water, up to the desired level, the headers and tubes also remain filled with water. The tubes are
inclined at an angle of 15˚ and remain suspended/ supported inside the closed furnace/flue gases
space. The flue gases produced from burning of the fuel are directed over the tubes in between
the baffles forming the zig-zag flame passage. Steam is produced inside the inclined tubes and
lifts through the top header and collects in the steam space of the boiler shell. Water from the
bottom header comes in place of steam. Water level is checked by level indicator and maintained
by feed pump.
The boiler shell & tubes are hung by means of wrought iron girders supported on pillars. This
arrangement allows the drum and tubes to expand or contract freely.
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Boiler Terms
(i) Boiler Shell: It is a cylindrical shaped structure fabricated with steel plates rolled
& riveted or welded together.
(ii) Grate: It is a Cast Iron platform in the furnace of boiler on which fuel is burnt. Fuel
is coal or wood or any other solid fuel which rests on the perforated surface of grate made of C.I.
bars. Air can easily pass through perforated surface from the bottom and also after burning, ash
can fall down itself easily.
(iii) Furnace/Fire box: It is an enclosed space where fuel is burnt and hot flue gases
accumulate. From the furnace, flue gases are directed to flow through the boiler.
(iv) Water Space: Volume occupied by water in the boiler is termed as water space
which is maintained at a constant level with the help of water level indicator fitted on boiler shell.
(v) Steam Space: It is volume occupied by steam over the water surface in boiler. As
steam is light, it lifts up and remains in the steam space at the top end of the boiler.
(vi) Boiler Mountings: Various fittings on the boiler like pressure gauge, safety valves
etc. which are necessary for its safe and efficient operation are called Boiler Mountings.
(vii) Boiler Accessories: The integral parts of boiler which are required to enhance its
efficiency or for overall performance are called accessories e.g. super heater, economizer, feed
pump etc.
(viii) Foaming: The formation of bubbles on the surface of boiling water is called
foaming.
(ix) Scale: The deposits of water salts and foreign particles on the heating surface in the
form of a hard layer or film is called scale.
(x) Blowing off: The suspended impurities in the boiler water usually settle down and
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are thrown out through a cock due to pressure difference inside and outside the boiler. This process
is called blowing off and the cock used is called blow-off-cock.
(xi) Lagging: The insulation block mode or rope made of asbestos or magnesia wrapped
or fixed outside the boiler shell and steam pipe are called lagging.
(xii) Refractory: The fire bricks or clay having low thermal diffusivity are used in the
furnace walls and other passages of flue gases where flue gases should retain their heat i.e. where
heat loss of flue gases is to be prevented.
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the extreme heat in the flue gas path will also heat the super heater steam piping and the steam
within. While the temperature of the steam in the super heater rises, the pressure of the steam
does not: the turbine or moving pistons offer a continuously expanding space and the pressure
remains the same as that of the boiler.
Almost all steam super heater system designs remove droplets entrained in the steam to prevent
damage to the turbine blading and associated piping. In all modern power plants, high pressure
boilers (> 100 bar) are universally used as they offer the following advantages. In order to obtain
efficient operation and high capacity, forced circulation of water through boiler tubes is found
helpful.
1. The efficiency and the capacity of the plant can be increased as reduced quantity of steam is
required for the same power generation if high pressure steam is used.
2. The forced circulation of water through boiler tubes provides freedom in the arrangement of
furnace and water walls, in addition to the reduction in the heat exchange area.
4. The danger of overheating is reduced as all the parts are uniformly heated.
5. The differential expansion is reduced due to uniform temperature and this reduces the
possibility of gas and air leakages.
Lamont Boiler
A forced circulation boiler was first introduced in 1925 by La Mont. The arrangement of water
circulation and different components are shown in Figure. The feed water from hot well is
supplied to a storage and separating drum (boiler) through the economizer. Most of the sensible
heat is supplied to the feed water passing through the economizer. A pump circulates the water
at a rate 8 to 10 times the mass of steam evaporated. This water is circulated through the
evaporator tubes and the part of the vapour is separated in the separator drum. The large quantity
of water circulated (10 times that of evaporation) prevents the tubes from being overheated.
The centrifugal pump delivers the water to the headers at a pressure of 2.5 bar above the drum
pressure. The distribution headers distribute the water through the nozzle into the evaporator.
The steam separated in the boiler is further passed through the super-heater. Secure a uniform
flow of feed water through each of the parallel boiler circuits a choke is fitted entrance to each
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circuit. These boilers have been built to generate 45 to 50 tons of superheated steam at a pressure
of 120 bar and temperature of 500°C. Recently forced circulation has been introduced in large
capacity power.
Benson Boiler
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It is a water tube boiler capable of producing steam at super critical pressure (> 225 bar). At super
critical pressure, water flashes into steam without any latent heat requirement. Therefore steam
generation is faster. Above critical point, water transforms into steam without boiling and without
change in volume. i.e., same density. Super critical steam generation does not have bubble
formation and consequent pulsations. Materials of construction should be strong to withstand high
pressure and temperature. 130 – 135 tons of steam per hour is generated at > 225 bar and ~90%
thermal efficiency.
Velox Boiler
Principle
When the velocity of the gas is greater than the speed of sound, its heat transfer rate is also
increases. So more heat is transfer from gas to water as compare when the heat transfer at the
subsonic speed. This is the basic principle of it. This boiler can increase the heat transfer rate or
can say steam generation rate without increasing boiler size. This is why? Velox boiler is most
successful boiler in the gas turbine industries
Construction
Velox boiler is a water tube forced circulation boiler. It has a gas turbine driven air compressor,
which compresses the air. This compressed air enters into the vertical combustion chamber, as
result, high rate of heat release from the fuel, which increases the flue gases velocity up to the
sound velocity. This is a force circulation boiler, so pump is used to circulate water inside the
boiler. This boiler also consist water and fire tube to maintain the flow of gas and water inside the
boiler. This boiler also consists other necessary mounting and accessories like economizer, super
heater, blow off valve, safety valve etc.
Working
The Velox boiler works as a basic heat exchanger. The air is compressed by air compressor driven
by gas a turbine driven. This compressed air passes from the combustion chamber, where more
heat release by the fuel which increase the velocity of the flue gases up to sound velocity. From
the bottom of combustion chamber, this flue gases pass from the fire tubes. These fire tubes
surrounded by the evaporator water tubes.
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Figure 1.37 Velox Boiler
The water from the economizer passes from the evaporator tube force by a circulating pump.
This water passes 15 - 20 time from the evaporator tube at very high speed. Due to this high
speed circulation, heat is transfer from the gases to the water at very high rate. The mixture of
water and steam is formed which further passes from the water and steam separator.
Loffler boiler
The feed water from the feed tank is supplied to the economizer by feed pump. In the
economizer the feed water is made to flow through a number of tubes surrounding which the
hot gases leaving the furnace pass over. There is a heat exchange from the hot gases to the feed
water, which is preheated in the economizer.
Evaporated Drum
It is housed away from the furnace. It contains a mixture of steam and water. The feed water
from the economizer tubes enters the evaporator drum into which is also passed two-thirds of
the superheated steam generated by the boiler. The superheated steam gives its superheat to the
water in the drum and evaporates it to saturated steam.
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Mixing Nozzles
The nozzles distribute and mix the superheated steam throughout the water in the evaporator drum.
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the flue gases entirely by convective heat transfer. Both radiant and convection super heater
are arranged in series in the path of the flue gases.
Steam outlet
About one-third of the superheated steam from the convection super heater passes to the steam
turbine while the remaining two-thirds is passed on to evaporator drum to evaporate the feed
water to saturated steam.
Capacity
Capacity of the Loffler boiler is about 100 Tonnes/Hr. of superheated steam generated at a pressure
of 140 kgf/sq.cm and at a temperature of 500’C.
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CONDENSER
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➢ In single pass surface condensers, the cooling water flows in the condenser tubes only
once.
➢ In multi pass surface condensers, the cooling water flows in the condenser tubes number
of times.
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2. High level jet condenser
A high-level jet condenser is shown in figure. This is similar to a low-level condenser, except
that the condenser shell is placed at a height of 10.36 m [barometric height] above the hot well.
The column of water in the tail pipe forces the condensate into the hot well by gravity. Hence
condensate extraction pump is not required.
3. Ejector condenser
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m enters at the top of the condenser. It is passed through a series of convergent nozzles. There is
a pressure drop at the throat of the nozzle. The reduction is pressure draws exhaust steam into the
nozzle through a non-return valve. Steam is mixed with water and condensed. In the converging
cones, pressure energy is partly converted into kinetic energy. In diverging cones, the kinetic
energy is partly converted into pressure energy. The pressure obtained is higher than atmospheric
pressure and this forces the condensate to the hot well.
Demerits
1. Condensate is wasted.
2. The cooling water should be clean and free from harmful impurities.
3. In low level jet condensers, the engine may be flooded, if condensate extraction pump fails
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3. Evaporative condenser
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condensed steam is taken out from the condenser by a separate extraction pump and air is
removed by an air pump.
3. Evaporative condenser
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falls over these tubes in the form of spray. A steam of air flows over the tubes to increase
evaporation of cooling water which further increases the condensation of steam. These condensers
are more preferable where acute shortage of cooling water exists. The arrangement of the
condenser is shown in figure 1.45. Water is sprayed through the nozzles over the pipe carrying
exhaust steam and forms a thin film over it. The air is drawn over the surface of the coil with the
help of induced fan as shown in figure. The air passing over the coil carries the water from the
surface of condenser coil in the form of vapour. The latent heat required for the evaporation of
water vapour is taken from the water film formed on the condenser coil and drops the temperature
of the water film and this helps for heat transfer from the steam to the water. This mode of heat
transfer reduces the cooling water requirement of the condenser to 10% of the requirement of
surface condensers. The water particles carried with air due to high velocity of air are removed
with the help of eliminator as shown in the figure. The make-up water (water vapour and water
particles carried with air) is supplied from outside source. The quantity of water sprayed over the
condenser coil should be just sufficient to keep the condenser coil thoroughly wetted. The water
flow rate higher than this will only increase the power requirement of water pump without
materially increasing the condenser capacity. This type of condenser works better in dry weather
(low WBT) compared with wet weather as the water vapour carrying capacity of dry air is higher
than wet air at the same temperature. The arrangement of this type of condenser is simple and
cheap in first cost. It does not require large quantity of water therefore needs a small capacity
cooling water pump. The vacuum maintained in this condenser is not as high as in surface
condensers therefore the work done per kg of steam is less with this condenser compared
with surface condenser. These condensers are generally preferred for small power plants and where
there is acute shortage of cooling water.
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The various disadvantages of the surface condenser are as follows:
i) The capital cost is more.
ii) The maintenance cost and running cost of this condenser is high.
iii) It is bulky and required more space.
COOLING TOWERS
A cooling tower is a semi-enclosed device for evaporative cooling of water by contact with air.
It is a wooden, steel, concrete structure and corrugated surfaces or troughs or baffles or perforated
trays are provided inside the tower for uniform distribution and better atomization of water in the
tower. The hot water coming out from the condenser are fed to the tower on the top and allowed
to tickle in the form of thin sheets or drops. The air flows from the bottom of the atmosphere after
effective cooling. An evaporative cooling tower is a machine of relatively simple conception and
operation. The water to be cooled for a chiller, industrial process or refrigeration installation is
pumped and distributed through spray nozzles over a fill pack or heat exchange surface through
which passes an air current commonly generated buy a fan. A small fraction of this water
evaporates and the remainder is cooled thanks to the absorption of latent heat of evaporation by
the passing air, and fall under gravity into a basin from there it is pumped back to the heat load
source.
Cooling Water Systems
Site conditions determine the method to be used for supplying the cooling water to the
condensers, and may be one of three systems namely:
Therefore, for large power plants situated away from the source of natural water, enormous
quantities of pure water may not be available for once through condenser cooling and the same
supply of water may have to be used again the again. Moreover, enough quality of water may not
be available for cooling requirement from river. Therefore, there must be some arrangement to
recool the circulating water and for this Purpose cooling ponds or cooling towers are needed. This
type of cooling water system is known as closed circuit or circulating cooling water system, or
closed cooling system. Due to losses caused by the evaporation leakage etc., it is still necessary
to have water available to compensate for this loss. Assuming the heat loss to be 1 percent, then
the make-up water required per hour in a 300 MW station would be between 650,000 to 750,000
liters per hour. This make up water may be taken from a river, sewage outfall or in times of
emergency, from a town main supply, the latter being rather expensive.
The system is similar in many respects to the river circulating system, the main difference being
that the cooling water is alternatively warmed and cooled and circulated continuously. The final;
inlet temperature to the condensers depends to a large extent on atmospheric conditions, and the
41
temperatures of the cooling water tower is much above that of a river. In this case the hot water
coming out of a condenser is passed on to a cooling tower where it is cooled down. The water in
the cooling tower is made to trickle down drop by drop and is broken into small particles while
passing over the baffling devices. These water particles come in contact with stream of a moving
in the opposite direction. As a result of this, some portion of the water gets evaporated and is
carried away along with air. The air vaporizes a small percentage of water, thereby cooling the
remaining of water. The air gets heated and leaves the tower at the top. The cooled water falls
down into a tank at the bottom of the tower from where it can be again circulated to the condenser,
through water culver. The heat exchange between air and water through direct contact is from (i)
by the evaporative cooling of water or by (ii) the convective heating of air. Cooling by
evaporation is the greatest.
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(c) Metallic or steel duct type
(a) Atmospheric
(b) Natural draft
(1) Its large capacity, of the order of 5 x 106 liters per hour.
(2) Its improved draft and air circulation.
(3) Low maintenance charges. Its good stability under air pressure and
(4) A wide base lead to stability under wind pressure, double curvature resists buckling
and shearing stresses in the structure due to its own weight are suppressed. Multi deck towers are
also used in large steam power plants.
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Hyperbolic Cooling Towers
The hyperbolic natural draft towers are widely used in Europe. These types are not feasible in
locations wherein summer time dry bulb temperature is much higher like in U.S.A. The
arrangement of hyperbolic cooling tower is shown in fig.1.47 below.
The hyperbolic Ferro-concrete tower offers little or no impendence to air flow, and when arranged
in groups there is no trouble due to eddies or local depressions. The construction is good from a
structural point of view and also provides and regulates adequate air draught as the air streams
are directed towards the vertical axis of the tower. The tower consists of a smooth reinforced
concrete shell which depending on the capacity, may extend some 80m.The shape of the stack is
circular in plan and hyperbolic in profile. This construction offers greater resistance to wind
pressure, eliminates shearing stresses and internal bracing, thus avoiding the formation of eddies.
Further, the lightness of the steel saves foundation work, and ground loading of 10 tons per sq.m.
And under as possible. The tower pond, outlet stair-cases and gangways are constructed as one
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unit. The shell is supported on specially arranged reinforced concrete columns designed to offer
a minimum resistance to air flow through the chimney. These columns take the shear. The
operation of this tower is much like that of other natural draft spray cooling towers with hot-
water cascading over timber splash type filling through which cooling air is circulating. With the
hyperbolic cooling tower, the widening of the top of the chimney permits of condensation taking
place within the tower of a certain amount of the water evaporated at lower levels. The velocity
of the rising air within the chimney is diminished before exit thereby avoiding eddies around the
top.
1. Power cost and auxiliary equipment’s are eliminated as fans are not needed.
Resulting operating and maintenance costs are consequently reduced.
2. Chimney shape creates its own draft, assuring efficient operation even when there is
no wind.
3. Cooling capacity of this type of tower is quite comparable with that of multi cell
installation of induced draft type towers.
4. Local fogging and warm air circulation, which are there in mechanical draft
installations, are also avoided.
The capacity of this tower varies from 50 to 100 liters per minute per m2 of base area depending
upon the air velocity.
(1) Its initial cost is high
(2) Its performance varies with the seasonal changes in dry bulb temperature and relative
humidity of air.
(3) Nuisance is caused due to condensation of moisture from nearby cooling towers to
householders.
(4) During winter months trouble may be experienced from ice building up around the tower
45
and ice deposits on nearby roads may necessitate salting and ashing. It is sometimes necessary to
remove some of the stack timber to facilitate the passage of air and so reduce the precipitation
outside the top of tower.
In this type of tower, hot water from the condenser is pumped to the troughs and nozzles situated
near the bottom. Troughs spray the water falls in the form of droplets into a pond situated at the
bottom of the tower. The air enters into the cooling tower from air openings provided near the
base, rises upward and takes heat of the falling water.
46
Natural draught towers
Advantages:
Disadvantages:
1. High initial cost
2. Its performance varies with seasonal changes in DBT and RH of air.
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for the inlet of fresh air, and outlet at the top for except of air and vapors. There are hoods at the
base projecting from the main portion of the tower where the fans are placed for forcing the air,
into the tower.
1. It is more efficient
2. No problem of fan blade erosion
3. It is more safe
4. The vibration and noise are minimum
Disadvantages:
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In these towers, the fans are placed at the top of the tower and drawn the air in through louvers
extending all around the tower.
Advantages:
1. The coldest water comes in contact with the driest air and warmest water comes
in contact with the most humid air.
2. In this tower, the re-circulation is seldom a problem.
3. Initial cost is low because the reduced pump capacity and smaller length of water
pipes.
4. Less space required.
5. This tower is capable of cooling of cooling through a wide range.
Disadvantages:
1. The air velocities through the packing are unevenly distributed and it has very little
movement near the walls and center of the tower.
2. Higher H.P. motor is required to drive the fan comparatively. This is due to the fact
that the static pressure loss is higher as restricted area at base tends to choke off the flow of higher
velocity air.
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SCHOOL OF MECHANICAL ENGINEERING
DEPARTMENT OF MECHANICAL ENGINEERING
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DIESEL ENGINE POWER PLANT
A generating station in which diesel engine is used as the prime mover for the generation of
electrical energy is known as diesel power station. In a diesel power station, diesel engine is used
as the prime mover. The diesel burns inside the engine and the products of this combustion act as
the working fluid to produce mechanical energy. The diesel engine drives alternator which converts
mechanical energy into electrical energy. As the generation cost is considerable due to high price
of diesel, therefore, such power stations are only used to produce small power. Although steam
power stations and hydro-electric plants are invariably used to generate bulk power at cheaper costs,
yet diesel power stations are finding favour at places where demand of power is less, sufficient
quantity of coal and water is not available and the transportation facilities are inadequate. This plants
are also standby sets for continuity of supply to important points such as hospitals, radio stations,
cinema houses and telephone exchanges.
Advantages
(a) The design and layout of the plant are quite simple.
(b) It occupies less space as the number and size of the auxiliaries is small.
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(c) It can be located at any place.
(d) It can be started quickly and it can pickup load in a short time.
(e) There are no standby losses.
(f) It requires less quantity of water for cooling.
(g) The overall cost is much less than that of steam power station of same
capacity.
(h) The thermal efficiency of the plant is higher than that of a steam power
station.
(i) It requires less operating staff
Disadvantages
(a) The plant has high running charges as the fuel (diesel) used is costly.
(b) The plant doesn’t work satisfactorily under overload conditions for a longer
period.
(c) The plant can only generate small power.
(d) The cost of lubrication is generally high.
(e) The maintenances charges are generally high
It consists of storage tank, strainers, fuel transfer pump and all day fuel tank. The fuel oil is supplied
at the plant site by rail or road. The oil is stored in the storage tank. From the storage tank, oil is
pumped to smaller all day tank at daily or short intervals. From this tank, fuel oil is passed through
strainers to remove suspended impurities. The clean oil is injected into the engine by fuel injection
pump.
After being filtered, the air is routed by the intake system into the engine's intake manifold or air
box. The manifold or air box is the component that directs the fresh air to each of the engine’s intake
valves or ports. If the engine is turbocharged or supercharged, the fresh air will be compressed with
a blower and possibly cooled before entering the intake manifold or air box. The intake system also
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serves to reduce the air flow noise.
Exhaust System
This system leads the engine exhaust gas outside the building and discharges it into atmosphere. A
silencer is usually incorporated in the system to reduce the noise level. The exhaust system of a
diesel engine performs three functions. First, the exhaust system routes the spent combustion gasses
away from the engine, where they are diluted by the atmosphere. This keeps the area around the
engine habitable. Second, the exhaust system confines and routes the gases to the turbocharger, if
used. Third, the exhaust system allows mufflers to be used to reduce the engine noise.
Cooling System
The heat released by the burning of fuel in the engine cylinder is partially converted into work. The
remainder part of the heat passes through the cylinder wall, piston, rings etc. and may cause damage
to system. In order to keep the temperature of the engine parts within the safe operating limits,
cooling is provided. The cooling system consists of a water source, pump and cooling towers. The
pump circulates water through cylinder and head jacket. The water takes away heat form the engine
and it becomes hot. The hot water is cooled by cooling towers and re circulated for cooling.
Lubricating System
The system minimizes the wear of rubbing surfaces of the engine. It comprises of lubricating oil
tank, pump, filter and oil cooler. The lubrication oil is drawn from the lubricating oil tank by the
pump and is passed through filter to remove impurities. The clean lubrication oil is delivered to the
points which require lubrication. The oil coolers incorporated in the system keep the temperature of
the oil low.
This is an arrangement to rotate the engine initially, while starting, until firing starts and the unit
runs with its own power. Small sets are started manually by handles but for larger units, compressed
air is used for starting. In the latter case, air at high pressure is admitted to a few of the cylinders,
making them to act as reciprocating air motors to turn over the engine shaft. The fuel is admitted to
the remaining cylinders which makes the engine to start under its own power.
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Working of Diesel Engine Power Plants
• Diesel engines or compression ignition engines as they are called are generally classified as
two stroke engine and four stroke engines.
• In diesel engine, air admitted into the cylinder is compressed, the compression ratio being 12
to 20.
• It burns and the burning gases expand and do work on the position.
• Diesel power plant is in the range of 2 to 50 MW capacity. They are used as central station for
small or medium power supplies.
• They can be used as stand-by plants to hydro-electric power plants and steam power plants for
emergency services.
• They can be used as peak load plants in combinations with thermal or hydro-plants.
• They are quite suitable for mobile power generation and are widely used in transportation
systems such as automobiles, railways, air planes and ships.
• Now-a-days power cut has become a regular feature for industries. The only solution to tide
over this difficulty is to install diesel generating sets.
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GAS TURBINE POWER PLANT
• Air is compressed (squeezed) to high pressure by a fan-like device called the compressor.
• Then fuel and compressed air are mixed in a combustion chamber and ignited.
• Hot gases are given off, which spin the turbine wheels.
• Most of the turbine’s power runs the compressor. Part of it drives the generator/machinery.
• Gas turbines burn fuels such as oil, nature gas and pulverized (powdered) coal.
• Instead of using the heat to produce steam, as in steam turbines, gas turbines use the hot
gases directly to turn the turbine blades.
• Gas turbines have three main parts:
i) Air compressor
ii) Combustion chamber
ii) Turbine
➢ The air compressor and turbine are mounted at either end on a common horizontal axle
(shaft), with the combustion chamber between them.
➢ Gas turbines are not self-starting. A starting motor initially drives the compressor till the
first combustion of fuel takes place, later, part of the turbine’s power runs the compressor.
➢ The air compressor sucks in air and compresses it, thereby increasing its pressure.
Combustion chamber:
➢ In the combustion chamber, the compressed air combines with fuel and the resulting
mixture is burnt.
➢ The greater the pressure of air, the better the fuel air mixture burns.
➢ Modern gas turbines usually use liquid fuel, but they may also use gaseous fuel, natural
gas or gas produced artificially by gasification of a solid fuel.
Note:
✓ The combination of air compressor and combustion chamber is called as gas generator.
Turbine:
➢ The burning gases expand rapidly and rush into the turbine, where they cause the turbine
wheels to rotate.
➢ Hot gases move through a multistage gas turbine.
➢ Like in steam turbine, the gas turbine also has fixed (stationary) and moving (rotor) blades.
➢ The stationary blades guide the moving gases to the rotor blades and adjust its velocity.
➢ The shaft of the turbine is coupled to a generator or machinery to drive it.
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▪ The thermal efficiency of gas turbine made of metal components do not exceed 36%.
▪ Research is underway to use ceramic components at turbine inlet temperature of 13500C
or more, and reach thermal efficiencies over 40% in a 300 kW unit.
According to the closed cycle gas turbine, the compressed air from the surroundings is heated by
using the heat exchanger (air heater). At constant pressure from the external source the heat is
additionally given to the heat exchanger. High pressure working fluid increases over the turbine and
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then the power is developed. The exhaust working fluid must be cooled in a pre-cooler.
Same fluid is sent into the compressor before the process is done. In the turbine same working fluid is always
distributed. From an external source the fuel is required for adding heat so the fuel ranges from kerosene and
then to the heavy oil. Straightly the fertilizer and coal slurry enter the turbine without reducing the efficiency.
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HYDEL POWER PLANT
Water reservoir
Continuous availability of water is the basic necessity for a hydro-electric plant. Water collected
from catchment area during rainy season is stored in the reservoir. Water surfaces in the storage
reservoir us known as head race.
Dam
The function of a dam is to increase the height of water level behind it which ultimately increases
the reservoir capacity. The dam also helps to increase the working heat of the power plant.
Spillway
Water after a certain level in the reservoir overflows through spillway without allowing the
increase in water level in the reservoir during rainy season
Pressure tunnel
It carries water from the reservoir to surge tank.
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Penstock
Water from surge tank is taken to the turbine by means of penstocks, made up of reinforced
concrete pipes or steel.
Surge tank
There is sudden increase of pressure in the penstock due to sudden backflow of water, as load on
the turbine is reduced. The sudden rise of pressure in the penstock is known as water hammer. The
surge tank is introduced between the dam and the power house to keep in reducing the sudden rise
of pressure in the penstock. Otherwise, penstock will be damaged by the water hammer.
Water turbine
Water through the penstock enters into the turbine through and inlet valve. Prime movers which
are in common use are Pelton turbine, Francis turbine and Kaplan turbine. The potential energy of
water entering the turbine is converted into mechanical energy. The mechanical energy available
at the turbine shaft is used to run the electric generator. The water is then discharged through the
draft tube.
Draft tube
It is connected to the outlet of the turbine. It allows the turbine to be placed over tail race level.
Tail race
Tail race is a water way to lead the water discharged from the turbine to the river. The water held
in the tail race is called tail race water level.
Step-up transformer
Its function is to raise the voltage generated at the generator terminating before transmitting the
power to consumers.
Power house
The power house accommodates the turbine, generator, and transformer and control room.
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Figure 2.7 Layout of Pumped Storage Power Plant
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SCHOOL OF MECHANICAL ENGINEERING
DEPARTMENT OF MECHANICAL ENGINEERING
63
NUCLEAR POWER PLANTS
Basics
Atoms consist of nucleus and electrons. The nucleus is composed of protons and neutrons.
Protons are positively charged whereas neutrons are electrically neutral. Atoms with nuclei having
same number of protons but difference in their masses are called isotopes. They are identical in
terms of their chemical properties but differ with respect to nuclear properties.
Nuclear Fission
When unstable heavy nuclei are bombarded with high energy neutrons, it splits into several smaller
fragments. These fragments, or fission products, are about equal to half the original mass. This
process is called Nuclear Fission. Two or three neutrons are also emitted. The sum of the masses
of these fragments is less than the original mass. This missing mass (about 0.1 percent of the
original mass) has been converted into energy. Fission can occur when a nucleus of a heavy atom
captures a neutron, or it can happen spontaneously.
64
Figure 3.1 Nuclear Fission
Nuclear Fusion
Fusion is the opposite of fission, it is the joining together of two light nuclei to form a heavier one
(plus a small fragment). For example if two 2H nuclei (two deuterons) can be made to come
together they can form He and a neutron.
Fuel
Usually pellets of uranium oxide (UO2) arranged in tubes to form fuel rods. The rods are arranged
into fuel assemblies in the reactor core.
Moderator
This is material which slows down the neutrons released from fission so that they cause more
fission. It is usually water, but may be heavy water or graphite.
Coolant
A liquid or gas circulating through the core so as to transfer the heat from it. In light water
reactors the moderator functions also as coolant.
Steam Generator
Part of the cooling system where the heat from the reactor is used to make steam for the turbine.
Reflectors
Some of the neutrons produced during fission will be partly absorbed by the fuel elements,
moderator, coolant and other materials. The remaining neutrons will try to escape from the reactor
and will be lost. Such losses are minimized by surrounding (lining) the reactor core with a material
called a reflector which will reflect the neutrons back to the core. They improve the neutron
economy. Economy: Graphite, Beryllium.
Shielding
During Nuclear fission σ α γ particles and neutrons are also produced. They are harmful to human
life. Therefore it is necessary to shield the reactor with thick layers of lead, or concrete to protect
both the operating personnel as well as environment from radiation hazards.
Cladding
In order to prevent the contamination of the coolant by fission products, the fuel element is covered
with a protective coating. This is known as cladding. Control rods are used to control the reaction
to prevent it from becoming violent. They control the reaction by absorbing neutrons. These rods
are made of boron or cadmium. Whenever the reaction needs to be stopped, the rods are fully
inserted and placed against their seats and when the reaction is to be started the rods are pulled
out.
Coolant
The main purpose of the coolant in the reactor is to transfer the heat produced inside the reactor.
The same heat carried by the coolant is used in the heat exchanger for further utilization in the
power generation.
Some of the desirable properties of good coolant are listed below
1. It must not absorb the neutrons.
2. It must have high chemical and radiation stability
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3. It must be non-corrosive.
4. It must have high boiling point (if liquid) and low melting point (if solid)
5. It must be non-oxidizing and non-toxic.
(a) Fast Reactor: In these reactors, fission is effected by fast neutrons without any use of
moderators.
(b) Thermal Reactors: In these reactors, fission is effected by fast neutrons are
slowed down with the use of moderators. The slow neutrons are absorbed by the
fissionable fuel and chain reaction is maintained.
(a) Natural Fuel: In this reactor, natural Uranium is used as fuel and generally heavy
water or graphite is used as moderator.
(b) Enriched Uranium: In this reactor, the Uranium used contains 5 to 10% U235 and
ordinary water can be used as moderator.
(a) Electricity
(b) Propulsion
(i) Desalination
(i) Breeder Reactors: Fast breeder reactors are capable of producing more
fissile materials than they consume during the fission chain reaction (by
converting fertile U-238 to Pu-239) which allows an operational fast
reactor to generate more fissile material than it consumes. Thus, a breeder
reactor, once running, can be re-fueled with natural or even depleted
uranium.
(ii) Creating various radioactive isotopes, such as americium for use in smoke
detectors, and cobalt-60, molybdenum-99 and others, used for imaging
and medical treatment.
(e) Providing a source of neutron radiation (for example with the pulsed Godiva device)
and position radiation (e.g. neutron activation analysis and potassium-argon dating).
(f) Research Reactor: Typically reactors used for research and training, materials
testing, or the production of radioisotopes for medicine and industry. These are much
smaller than power reactors or those propelling ships, and many are on university
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campuses. There are about 280 such reactors operating, in 56 countries. Some
operate with high-enriched uranium fuel, and international efforts are underway to
substitute low-enriched fuel.
The BWR uses demineralized water (light water) as a coolant and neutron moderator. Heat is
produced by nuclear fission in the reactor core, and this causes the cooling water to boil, producing
steam. The steam is directly used to drive a turbine, after which is cooled in a condenser and
converted back to liquid water. This water is then returned to the reactor core, completing the loop.
The cooling water is maintained at about 75 atm (7.6 MPa) so that it boils in the core at about
285°C. In comparison, there is no significant boiling allowed in a PWR because of the high
pressure maintained in its primary loop - approximately 158 atm (16 MPa, 2300 psi).
The most widely used reactor type in the world is the Pressurized Water Reactor (PWR)
which uses enriched (about 3.2% U235) uranium dioxide as a fuel in zirconium alloy cans. The
fuel, which is arranged in arrays of fuel "pins" and interspersed with the movable control rods, is
held in a steel vessel through which water at high pressure (to suppress boiling) is pumped to act
as both a coolant and a moderator. The high-pressure water is then passed through a steam
generator, which raises steam in the usual way.
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Figure 3.5 Pressurized Water Reactor
➢ All of today's commercially successful reactor systems are "thermal" reactors, using slow
or thermal neutrons to maintain the fission chain reaction in the U 235 fuel. Even with the
enrichment levels used in the fuel for such reactors, however, by far the largest numbers of
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atoms present are U 238, which are not fissile.
➢ Consequently, when these atoms absorb an extra neutron, their nuclei do not split but are
converted into another element, Plutonium.
➢ Plutonium is fissile and some of it is consumed in situ, while some remains in the spent
fuel together with unused U 235. These fissile components can be separated from the
fission product wastes and recycled to reduce the consumption of uranium in thermal
reactors by up to 40%, although clearly thermal reactors still require a substantial net feed
of natural uranium.
➢ It is possible, however, to design a reactor which overall produces more fissile material in
the form of Plutonium than it consumes. This is the fast reactor in which the neutrons are
un-moderated, hence the term "fast".
➢ The physics of this type of reactor dictates a core with a high fissile concentration, typically
around 20%, and made of Plutonium. In order to make it breed, the active core is
surrounded by material (largely U238) left over from the thermal reactor enrichment
process. This material is referred to as fertile, because it converts to fissile material when
irradiated during operation of the reactor.
➢ The successful development of fast reactors has considerable appeal in principle. This is
because they have the potential to increase the energy available from a given quantity of
uranium by a factor of fifty or more, and can utilise the existing stocks of depleted uranium,
which would otherwise have no value.
Advantages of NPPs
1. Reduces demand for fossil fuels
2. Quantity of nuclear fuel is much less: thus reducing transport and resulting costs
3. Area of land required is less: compared to a conventional plant of similar capacity
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4. Production of fissile material
5. Location independent of geographical factors: except water requirement
Disadvantages of NPPs
1. Not available for variable loads (load factor-0.8): as the reactors cannot be
controlled to respond quickly
2. Economical reason should be substantial
3. Risk of leakage of radioactive material
4. Further investigation on life cycle assessment and reliability needs to be done
5. Perception problems
(a) Minimize the volume of waste requiring management via treatment processes.
(b) Reduce the potential hazard of the waste by conditioning it into a stable solid form that
immobilizes it and provides containment to ensure that the waste can be safely handled
during transportation, storage and final disposal. It is important to note that, while treatment
processes such as compaction and incineration reduce the volume of waste, the amount of
radioactivity remains the same. As such, the radioactivity of the waste will become more
concentrated as the volume is reduced.
Conditioning processes such as cementation and vitrification are used to convert waste into a stable
solid form that is insoluble and will prevent dispersion to the surrounding environment. A
systematic approach incorporates:
(a) Identifying a suitable matrix material – such as cement, bitumen, polymers or borosilicate
glass - that will ensure stability of the radioactive materials for the period necessary. The
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type of waste being conditioned determines the choice of matrix material and packaging.
(b) Immobilizing the waste through mixing with the matrix material.
(c) Packaging the immobilized waste in, for example, metallic drums, metallic or concrete
boxes or containers, copper canisters.
The choice of process used is dependent on the level of activity and the type (classification) of
waste. Each country's nuclear waste management policy and its national regulations also influence
the approach taken.
Incineration
Incineration of combustible wastes can be applied to both radioactive and other wastes. In
the case of radioactive waste, it has been used for the treatment of low-level waste from nuclear
power plants, fuel production facilities, research centers (such as biomedical research), medical
sector and waste treatment facilities.
Following the segregation of combustible waste from non-combustible constituents, the
waste is incinerated in a specially engineered kiln up to around 1000oC. Any gases produced
during incineration are treated and filtered prior to emission into the atmosphere and must conform
to international standards and national emissions regulations.
Following incineration, the resulting ash, which contains the radionuclide’s, may require
further conditioning prior to disposal such as cementation or bituminization. Compaction
technology may also be used to further reduce the volume, if this is cost-effective. Volume
reduction factors of up to around 100 are achieved, depending on the density of the waste.
Incineration technology is subject to public concern in many countries as local residents
worry about what is being emitted into the atmosphere.
However, modern incineration systems have well engineered high technology processes
designed to completely and efficiently burn the waste whilst producing minimum emissions.
The incineration of hazardous waste (e.g. waste oils, solvents) and non-hazardous waste
(municipal waste, biomass, tyres and sewage sludge) is also practiced in many countries.
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Figure 3.7 Incineration Unit
Compaction
Compaction is a mature, well-developed and reliable volume reduction technology that is used for
processing mainly solid man-made low-level waste (LLW). Some countries (Germany, UK and
USA) also use the technology for the volume reduction of man-made intermediate-
level/transuranic waste. Compactors can range from low-force compaction systems (~ 5 tons or
more) through to presses with a compaction force over 1000 tones, referred to as super compactors.
Volume reduction factors are typically between 3 and 10, depending on the waste material being
treated.
Low-force compaction is typically applied to the compression of bags of rubbish, in order to
facilitate packaging for transport either to a waste treatment facility, where further compaction
might be carried out, or to a storage/disposal facility. In the case of super compactors, in some
applications, waste is sorted into combustible and non-combustible materials. Combustible waste
is then incinerated whilst non-combustible waste is super compacted. In certain cases, incinerator
ashes are also super compacted in order to achieve the maximum volume reduction.
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Figure 3.8 Compaction Unit
Low-force compaction utilizes a hydraulic or pneumatic press to compress waste into a suitable container,
such as a 200-litre drum. In the case of a super compactor, a large hydraulic press crushes the drum itself or
other receptacle containing various forms of solid low- or intermediate-level waste. The drum or container is
held in a mold during the compaction stroke of the super compactor, which minimizes the drum or container
outer dimensions. The compressed drum is then stripped from the mold and the process is repeated. Two or
more crushed drums, also referred to as pellets, are then sealed inside an over pack container for interim
storage and/or final disposal.
A super compaction system may be mobile or stationary in concept, supplied as a basic system
manually controlled, with a minimum of auxiliary equipment, to an elaborated computer controlled
system which selects drums to be processed, measures weight and radiation levels, compresses the
drums, places the crushed drums in over pack containers, seals the over packs, records the drums
and over packs content via a computerized storage system. Every year worldwide tens of thousands
of drums are volume-reduced and stored, with waste generally being reduced in volume by up to
a factor of 5.
Cementation
Cementation through the use of specially formulated grouts provides the means to immobilize
radioactive material that is on solids and in various forms of sludge’s and precipitates/gels (flocks)
or activated materials. In general the solid wastes are placed into containers. The grout is then added
into this container and allowed to set. The container with the monolithic block of concrete/waste is
then suitable for storage and disposal. Similarly in the case of sludge’s and flocks, the waste is
placed in a container and the grouting mix, in powder form, is added. The two are mixed inside the
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container and left to set leaving a similar type of product as in the case of solids, which can be
disposed of in a similar way.
This process has been used for example in small oil drums and 500-litre containers for
intermediate-level wastes and has been extended to ISO shipping containers for low-level waste
materials. The technology is being used in the immobilization of many toxic and hazardous wastes
that arise outside the nuclear industry and has the potential to be used in many more cases.
Vitrification
The immobilization of high-level waste (HLW) requires the formation of an insoluble, solid waste
form that will remain stable for many thousands of years. In general borosilicate glass has been
chosen as the medium for dealing with HLW. The stability of ancient glass for thousands of years
highlights the suitability of borosilicate glass as a matrix material. This type of process, referred
to as vitrification, has also been extended for lower level wastes where the type of waste or the
economics have been appropriate. Most high-level wastes other than spent fuel itself arise in a
liquid form from the reprocessing of spent fuel. To allow incorporation into the glass matrix this
waste is initially calcined (dried) which turns it into a solid form. This product is then incorporated
into molten glass in a stainless container and allowed to cool, giving a solid matrix. The containers
are then welded closed and are ready for storage and final disposal. Several other alternative
ceramic processes have also been developed which also achieve the desired quality of product. In-
situ vitrification has also been investigated as a means of 'fixing' activity in contaminated ground
as well as creating a barrier to prevent further spread of contamination.
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Nuclear Power in India
220x4
Tamil Nadu
Gujarat
Karnataka 2011
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COMBINED CYCLE PLANT FOR POWER GENERATION
• Gas turbines have low efficiency in simple cycle operation, the output produced by the steam turbine
accounts for about half of the CCGT plant output.
• HRSG is basically a heat exchanger, or rather a series of heat exchangers.
• creates steam for the steam turbine by passing the hot exhaust gas flow from a gas turbine or
combustion engine through banks of heat exchanger tubes.
• HRSG can rely on natural circulation or utilize forced circulation using pumps.
• hot exhaust gases flow past the heat exchanger tubes in which hot water circulates, heat is absorbed
causing the creation of steam in the tubes.
• tubes are arranged in sections, or modules, each serving a different function in the production of dry
superheated steam.
• These modules are referred to as economizers, evaporators, superheaters/reheaters and preheaters.
• The economizer is a heat exchanger that preheats the water to approach the saturation temperature
(boiling point), which is supplied to a thick-walled steam drum.
• The drum is located adjacent to finned evaporator tubes that circulate heated water.
• As the hot exhaust gases flow past the evaporator tubes, heat is absorbed causing the creation of steam
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in the tubes. The steam-water mixture in the tubes enters the steam drum where steam is separated from
the hot water using moisture separators and cyclones.
• The separated water is recirculated to the evaporator tubes. Steam drums also serve storage and water
treatment functions.
• An alternative design to steam drums is a once-through HRSG, which replaces the steam drum with
thin-walled components that are better suited to handle changes in exhaust gas temperatures and steam
pressures during frequent starts and stops.
Binary cycle geothermal power generation plants differ from Dry Steam and Flash Steam systems in
that the water or steam from the geothermal reservoir never comes in contact with the
turbine/generator units. Low to moderately heated (below 400°F) geothermal fluid and a secondary
(hence, "binary") fluid with a much lower boiling point that water pass through a heat exchanger.
Heat from the geothermal fluid causes the secondary fluid to flash to vapor, which then drives the
turbines and subsequently, the generators.
Binary cycle power plants are closed-loop systems and virtually nothing (except water vapor) is
emitted to the atmosphere. Resources below 400°F are the most common geothermal resource,
suggesting binary-cycle power plants in the future will be binary-cycle plants.
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SCHOOL OF MECHANICAL ENGINEERING
DEPARTMENT OF MECHANICAL ENGINEERING
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ECONOMIC ASPECTS OF POWER PLANT
1. Load Factor
It is defined as the ratio of the average load to the peak load during a certain
prescribed period of time. The load factor of a power plant should be high so that the
total capacity of the plant is utilized for the maximum period that will result in lower cost
of the electricity being generated. It is always less than unity. High load factor is a
desirable quality. Higher load factor means greater average load, resulting in greater
number of power units generated for a given maximum demand. Thus, the fixed cost,
which is proportional to the maximum demand, can be distributed over a greater number
of units (kWh) supplied. This will lower the overall cost of the supply of electric energy.
2. Utility Factor
It is the ratio of the units of electricity generated per year to the capacity of the
plant installed in the station. It can also be defined as the ratio of maximum demand of a
plant to the rated capacity of the plant. Supposing the rated capacity of a plant is 200
mW. The maximum load on the plant is 100 mW atload factor of 80 per cent, then the
utility will be
= (100 × 0.8)/(200) = 40%
It is the ratio of the duration during which the plant is in actual service, to the total
duration of the period of time considered.
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4. Plant Capacity Factor
It is the ratio of the average loads on a machine or equipment to the rating of the
machine or equipment, for a certain period of time considered. Since the load and
diversity factors are not involved with ‘reserve capacity’ of the power plant, a factor is
needed which will measure the reserve, likewise the degree of utilization of the installed
equipment. For this, the factor “Plant factor, Capacity factor or Plant Capacity factor” is
defined as,
Plant Capacity Factor = (Actual kWh Produced)/(Maximum Possible Energy that might
have produced during the same period).
Thus the annual plant capacity factor will be,
The difference between load and capacity factors is an indication of reserve capacity.
5. Demand Factor
The actual maximum demand of a consumer is always less than his connected load
since all the appliances in his residence will not be in operation at the same time or to
their fullest extent. This ratio of' the maximum demand of a system to its connected load is
termed as demand factor. It is always less than unity.
6. Diversity Factor
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7. Load Curve
It is a curve showing the variation of power with time. It shows the value of a
specific load for each unit of the period covered. The unit of time considered may be
hour, days, weeks, months or years.
It is the curve for a plant showing the total time within a specified period, during
which the load equalled or exceeded the values shown.
9. Dump Power
This term is used in hydro plants and it shows the power in excess of the load
requirements and it is made available by surplus water.
It is the power, which should always be available even under emergency conditions.
It is that reserve generating capacity which is not in operation but can be made
available for service.
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14. Spinning Reserve
It is that reserve generating capacity which is connected to the bus and is ready to
take the load.
This is a modification of Plant Capacity factor in that only the actual number of
hours that the plant was in operation is used. Thus Annual Plant Use factor is,
= (Annual kWh produced) / [Plant capacity (kW) × number of hours of plant
operation]
The cost of a power plant depends upon, when a new power plant is to set up or an existing
plant is to be replaced or plant to be extended. The cost analysis includes taxes.
1. Fixed Cost
It includes Initial cost of the plant, Rate of interest, Depreciation cost, Taxes,
and Insurance.
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2. Operational Cost
Rates are the different methods of charging the consumers for the consumption of
electricity. It is desirable to charge the consumer according to his maximum demand
(kW) and the energy consumed (kWh). The tariff chosen should recover the fixed cost,
operating cost and profit etc. incurred in generating the electrical energy.
REQUIREMENTS OF A TARIFF
(4) It should take into account maximum demand charges and energy charges.
(5) It should provide less charges for power connections than for lighting.
(6) It should avoid the complication of separate wiring and metering connections.
TYPES OF TARIFFS
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(6) Three part tariff.
The various types of tariffs can be derived from the following general equation:
Y = DX + EZ + C
where
C = Constant amount to be charged from the consumer during each billing period.
(1) Flat Demand Rate. It is based on the number of lamps installed and a fixed number
of hours of use per month or per year. The rate is expressed as a certain price per
lamp or per unit of demand (kW) of the consumer. This energy rate eliminates the use
of metering equipment. It is expressed by the expression.
2) Straight Line Meter Rate. According to this energy rate the amount to be charged from the
consumer depends upon the energy consumed in kWh which is recorded by a means of a
kilowatt hour meter. It is expressed in the form
Y = EZ
This rate suffers from a drawback that a consumer using no energy will not pay any
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amount although he has incurred some expense to the power station due to its readiness to
serve him. Secondly since the rate per kWh is fixed, this tariff does not encourage the
consumer to use more power.
(3) Step Meter Rate. According to this tariff the charge for energy consumption goes down
as the energy consumption becomes more. This tariff is expressed as follows.
Y = EZ If 0 ≤ Z ≤ A
Y = E1Z1 If A ≤ Z1 ≤ B Y =
E2Z2 If B ≤ Z2 ≤ C
And so on. Where E, E1, E2 are the energy rate per kWh and A, B and C, are the limits of
energy consumption.
4) Block Rate Tariff. According to this tariff a certain price per units (kWh) is charged for all
or any part of block of each unit and for succeeding blocks of energy the corresponding unit
charges decrease.
It is expressed by the expression
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Fig. 4.3 Block Rate Tariff
5) Two Part Tariff (Hopkinson Demand Rate). In this tariff the total charges are based on the
maximum demand and energy consumed. It is expressed as
Y = D . X + EZ
A separate meter is required to record the maximum demand. This tariff is used for industrial
loads.
(6) Three-Part Tariff (Doherty Rate). According to this tariff the customer pays some fixed
amount in addition to the charges for maximum demand and energy consumed. The fixed
amount to be charged depends upon the occasional increase in fuel price, rise in wages of
labour etc. It is expressed by the expression
Y = DX + EZ + C
(1) Land
(2) Building
(3) Equipment
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The fixed element means which are not movable, and for any types of power plant, the
fixed elements play a major role. Since each cost is added to the final cost of our product
(electricity in case of Power plant). So when a power plant is established, the first selection
is fixed element.
Effect of plant on land is as cost of land.
The costs included in these charges depend upon the number of customers. The various
costs to be considered are as follows:
(1) Capital cost of secondary distribution system and depreciation cost, taxes and interest
on this capital cost.
(2) Cost of inspection and maintenance of distribution lines and the transformers.
(3) Cost of labour required for meter reading and office work.
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hydropower plant provided water is available in large quantities. The capital cost per unit
installed is higher if the quantity of water available is small. While installing a
hydropower plant cost of land, cost of water rights, and civil engineering works cost
should be properly considered as they involve large capital expenditure. The other factor,
which influences the choice of hydropower plant, is the cost of power transmission lines
and the loss of energy in transmission. The planning, design and construction of a hydro
plant is difficult and takes sufficient time.
The nuclear power plant should be installed in an area having limited conventional
power resources. Further a nuclear power plant should be located in a remote or
unpopulated are to avoid damage due to radioactive leakage during an accident and also
the disposal of radioactive waste should be easy and a large quantity of water should be
available at the site selected. Nuclear power becomes competitive with conventional coal
fired steam power plant above the unit size of 500 mW. The capital cost of a nuclear power
plant is more than a steam power plant of comparable size. Nuclear power plants require
less space as compared to any other plant of equivalent size. The cost of maintenance of
the plant is high.
The diesel power plant can be easily located at the load centre. The choice of the
diesel power plant depends upon thermodynamic considerations. The engine efficiency
improves with compression ratio but higher pressure necessitates heavier construction of
equipment with increased cost. Diesel power plants are quite suitable for smaller outputs.
The gas turbine power plant is also suitable for smaller outputs. The cost of a gas turbine
plant is relatively low. The cost of gas turbine increases as the sample plant is modified
by the inclusion of equipment like regenerator, reheater, and intercooler although there is
an improvement in efficiency of the plant by the above equipment. This plant is quite
useful for regions where gaseous fuel is available in large quantities.
In order to meet the variable load the prime movers and generators have to act
fairly quickly to take up or shed load without variation of the voltage or frequency of the
system. This requires that supply of fuel to the prime mover should be carried out by the
action of a governor. Diesel and hydropower plants are quick to respond to load variation
as the control supply is only for the prime mover. In a steam power plant control is
required for the boilers as well as turbine. Boiler control may be manual or automatic for
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feeding air, feed water fuel etc. Boiler control takes time to act and therefore, steam
powers plants cannot take up the variable load quickly. Further to cope with variable
load operation it is necessary for the power station to keep reserve plant ready to
maintain reliability and continuity of power supply at all times. To supply variable load
combined working of power stations is also economical. For example to supply a load the
base load may be supplied by a steam power plant and peak load may be supplied by a
hydropower plant or diesel power plant.
The size and number of generating units should be so chosen that each will operate
on about full load or the load at which it gives maximum efficiency. The reserve required
would only be one unit of the largest size. In a power station neither there should be only
one generating unit nor there a large number of small sets of different sizes. In steam
power plant generating sets of 80 to 500 MW are quite commonly used whereas the
maximum size of diesel power plant generating sets is about 4000 kW. Hydro-electric
generating sets up to a capacity of 200 MW are in use in U.S.A.
(iv) Carrying out proper maintenance of power plant equipment to avoid plant breakdowns.
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Power plant selection depends upon the fixed cost and operating cost. The fuel
costs are relatively low and fixed cost and operation and maintenance charges are quite
high in a case of a nuclear power plant. The fuel cost in quite high in a diesel power plant
and for hydro power plant the fixed charges are high of the order of 70 to 80% of the cost
of generation. Fuel is the heaviest items of operating cost in a steam power station. A
typical proportion of generating cost for a steam power station is as follows:
Fuel cost = 30 to 40%
The power generating units should be run at about full load or the load at which they can give
maximum efficiency. The way of deciding the size and number of generating units in the
power station is to choose the number of sets to fit the load curve as closely as possible. It is
necessary for a power station to maintain reliability and continuity of power supply at all
times. In an electric power plant, the capital cost of the generating equipment’s increases with
an increase in efficiency. The benefit of such increase in the capital investment will be
realized in lower fuel costs as the consumption of fuel decreases with an increase in cycle
efficiency. Fig. 4.4 shows the variation of fixed cost and operation cost with investment.
LOAD CURVES
The load demand on a power system is governed by the consumers and for a system
supplying industrial and domestic consumers, it varies within wide limits. This variation of
load can be considered as daily, weekly, monthly or yearly. Typical load curves for a large
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power system are shown in Fig. 4.5.
These curves are for a day and for a year and these show the load demanded by the
consumers at any particular time. Such load curves are termed as “Chronological load
Curves”. If the ordinates of the chronological load curves are arranged in the descending
order of magnitude with the highest ordinates on left, a new type of load curve known as
“load duration curve” is obtained. Fig. 3.6 shows such a curve. If any point is taken on this
curve then the abscissa of this point will show the number of hours per year during which the
load exceeds the value denoted by its ordinate. Another type of curve is known as “energy
load curve” or the “integrated duration curve”. This curve is plotted between the load in kW
or MW and the total energy generated in kWh. If any point is taken on this curve, abscissa
of this point show the total energy in kWh generated at or below the load given by the
ordinate of this point. Such a curve is shown in Fig. 5.5. In Fig. 6(b), the lower part of the
curve consisting of the loads which are to be supplied for almost the whole number of hours
in a year, represents the “Base Load”, while the upper part, comprising loads which are
required for relatively few hours per year, represents the “Peak Load”.
Fig. 4.5 Chronological Load Curves (a) Daily Load Curve (b) Yearly Load Curve.
From the standpoint of equipment needed and operating routine, the ideal load on a
power plant would be one of constant magnitude and steady duration. However, the shape of
the actual load curve (more frequently realized) departs far from this ideal, (Fig. 4.6). The
cost to produce one unit of electric power in the former case would be from 1/2 to 3/4 of that
for the latter case, when the load does not remain constant or steady but varies with time. This
is because of the lower first cost of the equipment due to simplified control and the
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elimination of various auxiliaries and regulating devices. Also, the ideal load curve will
result in the - improved operating conditions with the various plant machines (for example
turbine and generators etc.) operating at their best efficiency. The reason behind the shape of
the actual realized load curve is that the various users of electric power (industrial, domestic
etc.) impose highly variable demands upon the capacity of the plant.
Fig. 4.6. Load Duration Curve. Fig. 4.7. Energy Load Curve.
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Variable load results in fluctuating steam demand. Due to this it become, very
difficult to secure good combustion since efficient combustion requires the co-ordination
of so many various services. Efficient combustion is readily attained under steady
steaming conditions. In diesel and hydro power plants, the total governing response is
prompt since control is needed only for the prime mover. The variable load requirements
also modify the operating characteristics built into equipment.
Due to non-steady load on the plant, the equipment cannot operate at the designed
load points. Hence for the equipment, a flat-topped load efficiency curve is more
desirable than a peaked one. Regarding the plant units, if their number and sizes have
been selected to fit a known or a correctly predicted load curve, then, it may be possible
to operate them at or near the point of maximum efficiency. However, to follow the
variable load curve very closely, the total plant capacity has usually to be sub-divided
into several power units of different sizes. Sometimes, the total plant capacity would
more nearly coincide with the variable load curve, if more units of smaller unit size are
employed than a few units of bigger unit size.
Also, it will be possible to load the smaller units somewhere near their most
efficient operating points. However, it must be kept in mind that as the unit size
decreases, the initial cost per kW of capacity increases. Again, duplicate units may not fit
the load curve as closely as units of unequal capacities. However, if identical units are
installed, there is a saving in the first cost because of the duplication of sizes, dimensions
of pipes, foundations, wires insulations etc. and also because spare parts required are less.
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carrying load. This will increase the cost of electric generation per unit (kWh). In a steam
power plant, the variable load on electric generation ultimately gets reflected on the
variable steam demand on the steam generator and on various other equipment. The
operation characteristics of such equipment are not linear with load, so, their operation
becomes quite complicated. As the load on electrical supply systems grow, a number of
power plants are interconnected to meet the load. The load is divided among various
power plants to achieve the utmost economy in the whole system. When the system
consists of one base load plant and one or more peak load plants, the load in excess of
base load plant capacity is dispatched to the best peak system, all of which are nearly
equally efficient, the best load distribution needs thorough study and full knowledge of
the system.
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ENVIRONMENTAL HAZARDS OR ISSUES CAUSED BY POWER PLANTS
The thermal power plants burning conventional fuels (coal, oil, gas) contribute to
air pollution in a large measure. The influence of thermal power plants on the
surroundings is determined by their ejection of flue gases, heat and contaminated waste
waters. Though thermal power plants are not among the worst contaminants of water
basins in terms of scope and composition of their liquid wastes, their discharge into water
basins can cause great harm if proper means are not taken for water protection. power
plants are follows:
1) CO
2) CO2
3) SO2
5) Dust
6) Fly ash
With incomplete combustion of fuel in furnaces, carbon monoxide (CO), hydro carbons
CH4, C2H4 etc. are produced. The CO is injurious to human health as it combines with
hemoglobin in the red blood corpuscles and thus interfere with their normal function of
supplying oxygen to the blood tissues. The thermal power plants contribute substantially to
CO2 emissions. CO2 has very harmful effect on atmospheric climate which could turn
fertile land into deserts. Therefore the imply cations and control of CO2 need priority study.
Sulphur dioxide (SO2) is the main pollutant from steam power plant. The primary source of
SO2 in the atmosphere is the combustion of bituminous coal and residual oil fuel.
Vegetables are most sensitive to the content of SO2 gas is associated with deterioration of
the surfaces of leaves or needles due to destruction of their chlorophyll.
Nitrogen dioxide (NO2) and nitric oxide (NO) are often referred collectively as
nitrogen oxides. Nitrogen oxides are toxic and produce a sharp irritating effect. People living
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in NO2 contaminated areas suffer from reduced respiratory function and have a higher
incidence of respiratory diseases. Acid rains are another menace caused by the thermal power
plants. Three main constituents of flue gases which mainly effect acidity of rains are SO2 and
nitrogen oxides. In the atmosphere SO2 is fairly readily converted into sulphuric acid
(H2SO4) whereas the nitrogen oxides get converted into nitric acid (HNO3). During rainy
season the acid formed in the atmosphere falls on the ground in the form of rain called acid
rain. The effect of this rain is to increase the acidity of lake, well water and water of flowing
rivers.
In general SO2 contributes about 60% of the acidity whereas nitrogen oxides
contribute 35% carbon dioxide (CO2) also cause the rain to be acidic but to a very small
extent.
Maximum permissible limit of nitrogen oxide is 0.05 to 0.1 ppm. The further
detrimental effect of acid rains is the reduction of ground fertility and crops yield smoke, dust
and fly ash carried by flue gases also produce injurious effects on human health. The quantity
of ash. (Q) carried off by flue gases per kg of fuel burnt and taking into account unburnt
carbon is found by the following formula
where K = Fraction of solid particles carried off from furnace with flue gases.
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Fly ash. cinders, various gases and smoke discharged from the stack become
atmospheric contaminants. Gases diffuse in all directions. The path followed by the fuel
gases depends upon the thermal and dynamic properties of gases and wind flow past the
stack.
The various variables affecting the area over which flue gases constituents will
settle out are as follows:
(i) Stack height (ii) Stack exit gas velocity
Control of Pollutants
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the purity of atmosphere and water basins is of national significance. Thermal power
plants consume about more than 113 of all the fuel produced and thus can significantly
affect the local environment and the whole biosphere. Large condensation plants are
among the greatest sources of heavy ejections of contaminants into the atmosphere. The
effects of particulate matter in the atmosphere surrounding steam power plant are many
and varies. Adverse effects on health, climate and water basin are quite serious. Adverse
health effects are associated with SO2 concentrations. Acid fall out in the form of acid
rain is one of the more serious environmental hazards of increased concentrations of
sulphur and nitrogen oxides in the atmosphere.
As regards thermal power plants the state of environment around them depends on
the following:
(i) kind of fuel used,
(iv) devices used for ejection of flue gases into the atmosphere,
(v) the influence of thermal power on the surroundings is also determined by their ejection
of flue gases, heat and contaminated waste waters.
During high temperature combustion of gaseous or liquid fuel the pollution of the
atmosphere by solid particles, CO and SO2 can be kept minimum by suitable organization
of the following:
It is necessary to minimize the emission of SO2 into the atmosphere from thermal
power plants as its contribution to pollution is maximum.
Large amounts of air pollutants are produced with coal combustion than any other
fuel.
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Therefore research is continued on converting coal to cleaner and more convenient gaseous
and liquid fuel.
The permissible maximum concentrations of SO2 at ground level are 0.05 to 0.08 ppm for
24 hours, 0.12-0.2 ppm for 1 hour and 0.1 - 0.5 ppm for five minutes. The maximum
permissible limit of nitrogen oxide is 0.05 to 0.1 ppm.
Particulate matter which is composed of smoke, dust and other solids made of
wide variety of organics and metals contributes to undesirable climatic conditions,
especially when combined with smoke (smog). Of the human causes, dust and ash that
emanate from industrial processes, fossil power plants, and other combustion processes
are the largest contributor, of which power plants contribute about one-third. Sulfur
compounds are the largest contributors to particulate matter.
The effects of particulate matter in the atmosphere are many and varied. The major
effects of particulate matter are: decreasing visibility, increasing soiling, corrosion, and
health hazard that is a complex function of concentration and particle size. These effects
the lungs and obstructs the respiratory passages, and thus results in respiratory illness and
causes a large increase in the number of bronchitic patients.
Steam power plants generally use the following mechanical arrestors for the
removal of solid particles:
(a) Fabric filters (1) Electro-static precipitators
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(c) to control the dust within allowable limit. It can be done by increasing the
height of chimney so that the dispersion will be on the larger area thus reducing
concentration.
Electrostatic precipitators are used to remove the dust particles from the flue gases.
Details of electrostatic precipitator are given in the relevant Chapter. A combination of
mechanical and electrostatic precipitators can remove more than 99.5% of the particulate
matter from the effluent gases. Fly ash used to remove fly ash. A fly scrubber is explained
in the relevant Chapter. Cinder catcher and cyclone dust collector are also explained in
the Chapter. Furnaces burning coal in suspension (pulverised coal burners and spreader
stokers) throw dust in the form of fly ash and collectors should be installed in the
breeching to remove ash particles.
Smoky atmosphere is less healthful than smoke free atmosphere. Smoke has
deadly effect on the vegetation principally because of sulphur products it carries. Smoke
Corrodes metals and darkens paints. Fuels should be burnt completely to reduce quantity
of dust particles in the flue gases.
CONTROL OF SO2
Since conversion of a relatively small amount of SO2 to SO3 can lead to the formation
of enough sulfuric acid to cause serious corrosion in boilers. This has been the cause of
concern to combustion engineers. In the atmosphere, SO2 is fairly rapidly converted into
sulfuric acid and sulfates, it associates readily with particulate matter in the air, including rain
drops. It reduces the productivity of forests and agricultural products. Acidity of certain rivers
and lakes threatens to be hazardous to fish and animal life. Acid fall out in the form of acid
rain is one of the more serious environmental hazards of increased concentrations of sulfur
and nitrogen oxides in the atmosphere.
Solid fuels contain sulphur in the following three forms.
(iii) sulphate sulphur (in sulphur salts of calcium and alkali metals)
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SO2 is one of the principal toxic component which may pollute the atmosphere
substantially.
Following methods are used to reduce the quantity of sulphur dioxide (802)
produced during combustion of fuel.
a) Desulphurisation of fuels
b) Decreasing the sulphur content in fuel is called desulphurisation process. This process
can remove a substantial amount of sulphur from fuel.
Following three methods are used to remove sulphur from coal:
These processes leave the coal unchanged in form. In chemical treatment coal is
leached with an aqueous solution of ferric sulphate at a temperature in the range of 90—
130°C. In froth flotation process the coal is suspended in water through which air is
bubbled. The air bubbles tend to attach themselves to the coal particles rather than to the
mineral matter. The mineral waste falls to the bottom and is discharged.
In magnetic separation the finely crushed coal is passed through a strong magnetic
field which removes pyrite (FeS2) from coal. Coal itself is non-magnetic.
The sulphur from liquid petroleum fuels is generally removed by reaction with
hydrogen gas in the presence of a catalyst at a moderately high temperature and pressure.
Sulphur is converted into hydrogen sulphide which is then removed.
c) To use low sulphur fuels. To use low sulphur content fuels is the commercially
proved means to control SO2 emission into atmosphere.
d) Use of tall stakes. To prevent air pollution with SO2 tall chimneys are used to disperse
flue gases over larger area.
e) Cleaning of flue gases. Commonly the three methods used to remove SO, from the
flue gases are as follows:
1. Wet scrubbing 2. Solid absorbent
3. Catalytic oxidation.
It is observed that to remove SO2 from flue gases is more economical as compared to
removing sulphur from coal. Methods used to prevent air pollution with SO2 are different for
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gaseous, liquid and solid fuels. It is advisable to remove H2S from natural gas before
burning it.
The sulphur content of liquid fuels can be reduced by following ways subjecting the
fuel to a high temperature either with the use of oxidants (gasification) or without them
(pyrolysis).
The process of gasification is effected at a high temperature (900-1300°C) with a
limited admission of oxygen.
Pyrolysis of fuel is carried out at 700-1000°C without an oxidant. Pyrolysis is effected
by contacting atomised oil directly with a heat carrier which may be in either a
stationary or moving state. The combustible gas thus produced is purified from sulphur
compounds and other harmful impurities and used as pure power fuel. Pyrolysis of fuel oil,
crude petroleum and heavy petroleum residues can also be made by using liquid heat carriers
as fused salts, slags etc.
Wet Scrubber
Wet scrubber also called wet flue gas desulphurisation system uses lime stone in the
form of an aqueous slurry. This slurry when brought in contact with the flue gas absorbs 802
in it. Fig. 9 shows schematically the wet lime stone scrubbing process. In this scrubber 502 of
exhaust gases is absorbed and reacts chemically with water and lime stone to form products
that are transferred from scrubber to tank. In reaction tank chemical reactions take place
resulting in disposable precipitates. Make up slurry is added to the tank and scrubbing liquid
is sent back to the scrubbing. The thickener receives a mixture of 5 to 15% suspended solids
in water which are concentrated by sedimentation and removed to pond or land fill.
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Fig 4.8 Wet Scrubber
In the scrubber following reactions take place.
(ii) Costly disposal problem for the waste material which is a water logged sludge.
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Catalytic oxidation
It is used to produce sulphuric acid from dilute SO2 in the flue gas. The sulphuric add is
separated from flue gases.
In this process magnesium sulphate and sulphite salts are regenerated, producing a
concentrated stream of SO2 and magnesium oxide (Mg0) for reuse in the scrubbing loop.
Mg0 + SO2 = MgS03
The magnesium sulphite formed reacts further with SO2 and water to from
magnesium bi-sulphite.
MgS03 + SO2 + H2O = Mg (HS03)2
Mg0 is returned into the process whereas SO2 can be reprocessed into sulphuric
acid. The principal disadvantage of this process is that it involves numerous procedures
with solid substances. It causes abrasion wear of equipment and formation of much dust.
Further much heat is needed for the drying of crystals and removal of hydrate moisture.
Nitrogen dioxide (NO2) and nitric oxide (NO) are often referred to collectively as
nitrogen oxides. Plants using fossil fuels emit nitric oxide which gets oxidised into
nitrogen dioxide. Nitrogen oxides possess high biological activity. Nitrogen oxides are
poorly soluble in liquids and for that reason can penetrate deep into lungs and can cause
harmful diseases.
People living in NO2 contaminated areas may suffer from following:
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(i) reduced respiratory function
Lower concentration of NO2 though being apparently harmless for plants can inhibit
their growth. The combustion of fossil fuels in air is accompanied by the formation of nitric
oxide (NO) which is partly oxidised to nitrogen dioxide (NO2). The resulting mixture of
variable composition is represented by the symbol NOx where x has a value between 1 and 2.
Nitrogen oxides (NO and NO2) are present in flue gases produced by burning coal, oil and
gas, in exhaust gases from internal combustion engines and turbines. NOx is formed in high
temperature zones of combustion chamber from N2 and O2 of air. It is observed that usually
up to about 1000°C the formation of NO from air is negligible but above 1000°C the amount
increases with increasing temperature. The various methods commonly used to reduce to
reduce the emission of NOx from steam Power plants and gas turbine power plant are as
follows:
1. Reduction in temperature in combustion zone. By adjusting the combustion
conditions to minimise the formation of nitric oxide. The obvious requirements are
low combustion temperatures and use of low nitrogen fuels if possible. Although
higher temperature during combustion of fuels produce less amount of CO but
higher temperatures also lead to the formation of nitric oxide (NO). Therefore, the
combustion temperature should be so adjusted that minimum amount of NO and
CO are formed.
2. Reduction of residence time in combustion zone. This is the most promising method
because reducing the time of residence of combustion products in high temperature
zone not only reduces the formation of NO but also produces minimum amount of
CO2, SO2 and hydrocarbons.
3. Increase in the equivalence ratio in the combustion zone. By carrying out
combustion using equivalence ratio of 1.6 to 1.8 the amount of NOx produced can
be reduced.
Pollution of biosphere by gaseous contaminants can be avoided by the following:
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(ii) By cleaning fuel
The global concern for the environment protection and pollution control has made it
mandatory for most combustion plants to continuously monitor flue gases for pollutants like
CO, NO, S02, and also measure 02, temperature, smoke density or dust concentration.
Analyser used for CO, NO and SO2 and for the reference variable 02 may be microprocessor-
controlled which feature automatic status monitoring.
The waste waters discharged from steam power plant pollute the water basin if the waste
waters are not properly handled, The waste water discharge into the basins may be in the
following forms.
(i) Single
(ii) Periodic
(v) Occasional
The most favourable mode of waste water discharged is that at which the
maximum permissible (safe) concentration (WC) of impurities in the basin is not
exceeded.
Steam Power Plants are the sources of following types of waste waters:
Cooling waters of steam power plant carry an enormous amount of heat into water
basins, waste waters of water treatment plants contain various neutral salts acids and
alkalis which may affect water basin by changing pH value of water and by varying the
salt concentration in water. The waste waters of hydraulic ash disposal systems should be
discharged into water basin only when they contain no coarse particle substances.
Since waste waters usually contain a number of pollutants therefore waste waters
should be purified before being discharged into water basins. Use of contaminated waste
waters may harm agriculture, fishing industry etc.
Purification of waste waters is carried by number of methods. Some of the methods are
as follows:
(a) Methods for direct separation of impurities
(c) Methods of impurity separation with a change in the phase state of water or impurity.
All the waste water drains which individually though small finally add upto a
fairly large quantity. The drains from coal handling area are likely to contain high level
of suspended Particulate matter for which if required we may have to provide filters. The
drains from fuel oil area should be ensured free from oil and grease, for which oil traps
should be provided before they join other drains.
It is essential to take weekly samples from these channels for testing and any
abnormalities are immediately controlled from source which can be identified. Further
regular observations are necessary for any visible abnormalities to take immediate
corrective action. In order to assess the impact of the total plant effluents to the
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surrounding water bodies sampling of surface water from the water body as well as
ground water samples in the plant and ash pond surroundings are also necessary. This
helps in identifying any adverse impacts of plant water effluents.
Ash Pond
Fly ash is a major solid discharge from the thermal power station Inch is the source
of a major worry. The magnitude of the problem is a very huge considering the high ash
content of Indian coal. Generally the ash is converted to slurry form and pumped to a
large pond. Here the ash is allowed to settle and water should filter out. While the ash
settles in the pond it is important to design the system in such a way that a large water
sheet is maintained on the surface of the pond, without which the dry areas of pond will
create a dust nuisance to the atmosphere. For preventing the ash particles flying, it is
better to develop a thick green belt all around the ash dye well in advance. Further, the
ash should be used in bricks, cement, road construction etc.
ACID RAIN
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Acid rain, or acid deposition, is a broad term that includes any form of precipitation with acidic
components, such as sulfuric or nitric acid that fall to the ground from the atmosphere in wet or
dry forms. This can include rain, snow, fog, hail or even dust that is acidic.
• Acid rain results when sulfur dioxide (SO2) and nitrogen oxides (NOX) are emitted into the
atmosphere and transported by wind and air currents. The SO2 and NOX react with water,
oxygen and other chemicals to form sulfuric and nitric acids. These then mix with water
and other materials before falling to the ground.
• While a small portion of the SO2 and NOX that cause acid rain is from natural sources such
as volcanoes, most of it comes from the burning of fossil fuels. The major sources of SO2
and NOX in the atmosphere are:
• Burning of fossil fuels to generate electricity. Two thirds of SO2 and one fourth of NOX in
the atmosphere come from electric power generators.
• Winds can blow SO2 and NOX over long distances and across borders making acid rain a
problem for everyone and not just those who live close to these sources.
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ENVIRONMENTAL HAZARDS OF NUCLEAR POWER PLANTS
• Nuclear power has ZERO GHG emissions and ZERO air pollution during use.
• But, nuclear energy is responsible for some GHG emissions during manufacturing,
transport, installation, and decommissioning – about 0.06 pounds of carbon dioxide
equivalent gases per kWh of energy produced compared to 2 pounds per kWh for
burning coal.
Water Usage
• Nuclear power can use large amounts of water, but some of this water is returned to its
point of origin rather than evaporating, leaving about 400 gallons/MWh consumed in
the production of electricity.
Other Impacts
• Land Usage: Like natural gas and coal burning plants, nuclear power plants consume
very small amounts of land per electricity produced.
• While nuclear power plants release very small amounts of radiation into water and air
surrounding the plants, the most serious environmental (and public health) threat
imposed by nuclear energy is that of nuclear waste.
• In theory, nuclear waste can be stored safely in geological repositories (in the earth),
but the extreme ecosystem and human health consequences of a leak or release of such
waste makes it difficult to find a community willing to store it.
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SCHOOL OF MECHANICAL ENGINEERING
DEPARTMENT OF MECHANICAL ENGINEERING
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NON - CONVENTIONAL POWER GENERATION
Introduction
Power is the most important infrastructure input for the development and growth of
economy of the country. The energy consumption in the world has been growing at an
alarming rate. Fossil fuels, which today meet major part of the energy demand, are being
depleted quickly. The stock of coal may not last longer than a few decades. The world has
started running out of oil and it is estimated that 80% of the world's supply will be
consumed in our lifetimes. The prices of fossil fuels will shortly become higher than any
other source of energy option. Fossil fuels are not only depleting rapidly but the use of these
fuels also leads to atmospheric carbon emission resulting in global warming. The renewable
energy sources are expected to play an important role in solving the energy problems in
decentralized locations, rural and remote areas in the years to come. Renewable energy not
only augments energy generation but also helps in maintaining a pollution free environment.
The harnessing of renewable sources of energy in India constitutes a small but rapidly
growing industry. Since fossil fuel, which are main fuels for thermal power are getting
exhausted eventually in the next few decades; other systems based on non-conventional and
renewable sources are being encouraged. These are solar, wind, sea, geothermal and
biomass. As discussed earlier, energy sources are W primary sources and (ii) secondary
sources Primary sources are those which are available in nature in raw from, like coal,
petroleum-oil, natural gas, wind, water at high level, uranium ore, solar radiation,
geothermal fluid, ocean waves, ocean thermal fluid, ocean tides, biomass fuels etc. Thus
primary sources include conventional and non- conventional (alternate), renewables and
non-renewables. Secondary energy sources are usable energy and are supplied to the user
for consumption. Electrical energy, steam, hot water, LPG in cylinders or pipe-lines etc., are
the examples of secondary energy sources.
Renewable energy sources are those which are renewed by the nature again and again and
their supply is not affected by rate of consumption. Wind energy, solar energy, geothermal
energy, ocean wave, hydro energy etc., are the renewable energies. Alternative energy
sources are those which are non-traditional. They are alternatives to the conventional energy
sources. Today fossil fuel, nuclear and hydro-power sources are considered as conventional
sources of energy, while others are non-conventional. The non-conventional sources
including hydro power are the renewable sources of energy. Non-renewable energy
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resources are those which do not get replenished after their consumption e.g., coal once
burnt is consumed without replacement of the same. Therefore, the resources which are
formed very slowly in nature and which are likely to be exhausted in a few more decades or
centuries are called non-renewable. Renewable energy sources like solar, wind, sea waves
etc. cannot be stored in original natural form. It is converted continuously to electrical form,
transmitted, distributed and utilized without long term storage. The renewables are available
free of cost, hence, consumption of renewables should be maximized. This may help in
conserving non- renewables for some more decades/centuries. In this book till now we have
discussed conventional sources of energy, now;
The advantage of non-conventional energy sources are listed below:
i. Non-depletable
v. Low gestation
vi. Government provides lot of facilities and promotional measures, such as:
• Soft loans
• State support
1. Solar energy
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2. Wind energy
4. Geo-thermal
5. Ocean thermal
6. Ocean wave
7. Tidal
8. Waste
9. Fuel cells
SOLAR ENERGY
Solar energy is a clean, cheap and abundantly available renewable energy. The heat and
light radiated by the Sun are received by the earth which supports the environment through
the following well known natural effects:
1. Temperature balance on the earth.
4. Water cycle i.e., Evaporation > Clouds - > rains ---> water - > evaporation.
5. Heating of ocean water. This gives Ocean Thermal Energy Conversion (OTEC).
The Sun produces enormous amount of heat and light through sustained nuclear fusion
reactions. The solar energy received on earth in the form of radiation is used for heating and
producing electrical energy. Since the Sun is expected to radiate at an essentially constant
rate for a few billion years, it may be regarded as an inexhaustible source of useful energy.
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India is endowed with a very vast solar energy resource. Most of the parts of the country
have about 250-300 sunny days. There is an immense scope and potential for the use of solar
energy viz., solar thermal and solar photovoltaic in India. A large number of solar energy
applications for rural, remote areas and other applications have contributed in a significant
way to the process of commercialization of solar energy products in India.
2. Space heating.
3. Space cooling.
4. Solar distillation.
5. Solar pumping.
7. Solar furnace.
8. Solar cooking.
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Heat is also stored in containers of chemicals called eutectic or phase changing salts. These
salts, which store large quantities of heat in a relatively small volume, melt when they are
heated and release heat later as they cool and crystallize. When the building needs heat, the
air or water from its heating system passes through the storage is warmed, and is then free
through the conventional heaters to warm the space. For sunless days or cloudy days, an
auxiliary system as a backup, is always required. This is true for solar cooling systems.
Solar thermal collector system gathers heat from the solar radiation and gives it to the heat
transport fluid. The heat transport fluid receives the heat from the collector and delivers it to
the thermal storage tank, boiler steam generator, heat exchanger etc. Thermal storage sys-
tem stores heat for a few hours and the heat is released during cloudy hours and at night.
The solar thermal electric power plants are considered to be economically viable only in
locations having favorable sunlight throughout the year and the fossil fuels /hydro resources
etc., are not available in the vicinity.
The intermittent and variable manner in which it arrives at the earth's surface, and the large
area required to collect the energy at a useful rate. Experiments are under-way to use this
energy economically for power production, house heating, air conditioning, cooking etc.
SOLAR RADIATION
The solar radiation that penetrates the earth's atmosphere and reaches the surface differs in
bath amount and character from the radiation at the top of the atmosphere. In the first place,
part of the radiation is reflected back into the space, especially by clouds. The radiation
entering the atmosphere is partly absorbed by molecules in the air. Oxygen and ozone (O3),
formed from oxygen, absorb nearly all the ultraviolet radiation and water vapour and carbon
dioxide absorb some of the energy in the infrared range. In addition, part of the solar
radiation is scattered by droplets in clouds by atmospheric molecules, and by dust particles.
Solar radiation that has not been absorbed or scattered and reaches the ground directly from
the Sun is called "direct radiation" or "beam radiation" Diffuse radiation is that solar
radiation received from the Sun after its direction has been changed by reflection and
scattering by the atmosphere. Because of the solar radiation is scattered in all directions in
the atmosphere, diffuse radiation comes to the earth from all parts of the sky. The total solar
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radiation received at any point on the earth's surface is the sum of the direct and diffused
radiation. This is referred to in a general sense as the "insolation" at that point. Therefore,
the insolation is defined as the total solar radiation energy received on a horizontal surface
of unit area (e.g., 1 sq. m) on the ground in unit time (e.g., 1 day). Solar radiations can be
converted directly or indirectly in the form of energy such as heat and electricity. Solar
power would eliminate most of the serious environmental problems associated with fossil
fuel and nuclear power. Energy is released by the Sun as electromagnetic waves of which
99% have wavelengths between 0.2 to 0.4 µ, where µ is micrometer. Solar energy reaching
the top of earth's atmosphere consists of about 8% ultra violet radiation (short wave-length
less than 0.39 µ), 46% visible light (0.39 to 0.78 µ) and 46% infrared radiation (long wave-
length more than 0.78 µ).
Following two type of instruments are used for solar radiation measurement: (i)
Pyrheliometer. It collimates the radiation to determine the beam intensity as a function of
incident angle.
(ii) Pyronometer. It measures the total hemi-spherical solar radiation. The Pyronometer is
quite popular.
Solar Constant
It is the rate at which solar energy arrives at the top of atmosphere. This is the amount of
energy received in unit time on a unit area perpendicular to the sun's direction at the mean
distance of the earth from the Sun. The rate of arrival of solar radiations vary throughout the
year. According to National Aeronautics and Space Administration (NASA) the solar
constant is expressed in following three ways.
(i) 1.353 kilowatts per square meter or 1353 watts per square meter.
Sunlight has low pressure density (0.1 kW/m2 to 1 kW/m2), hence, very large surface area
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of the collectors is required for producing rated power of 1 MW. Efficiency of thermal
collectors is very important. This depends on collector layout tracking, atmospheric clarity
etc. Other important features of a solar collector system is concentration ratio and
temperature range. Main types of solar thermal collectors are:
— Flat plate collectors.
— Concentrating collectors
Flat Plate Collectors. A flat plate collector is shown in Fig. 5.1. Flat plate collectors are
made in rectangular panels from about 1.7 to 2.9 sq. m in area and are relatively simple to
construct and erect. Flat plates can collect and absorb both direct and scattered solar
radiation they are thus partially effective even on cloudy days where there is no direct
radiation.
The solar rays pass through transparent covers and fall on absorbing surface. The absorbing
surface which is usually made of copper, aluminium, or steel coated with a heat resistant
black (carbon) point intercepts and absorbs the solar radiation energy. Radiation energy is
converted into heat and water flowing through the tubes gets heated. It is not possible to
generate steam with plate collectors so this system cannot be used directly to run the prime
mover. So some other organic fluid such as Freon- 14, 150 butane etc., which evaporate at
low temperature and high pressure by absorbing heat from heated water. The vapours
formed can be used to run the prime mover (turbine or engine) to generate power. Insulation
is used to prevent loss of heat from the absorber and heat transporting fluid. The insulating
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materials commonly used are fiber glass or Styrofoam. Flat plate collectors are also called
non-concentrating type. These collectors are classified as low temperature collectors
because they can generate temperature less than 90 °C and have a collection efficiency of
about 30 to 50%.
1. Concentrating Collectors.
Focusing collectors collect solar energy with high intensity of solar radiations on the energy
absorbing surface. Such collectors generally use optical system in the form of reflectors or
refractors and can heat the fluids up to about 500 °C. An important difference between
collectors of non-focusing and focusing types is that the latter concentrate only direct
radiation coming from a specific direction.
Fig. 2 shows a parabolic trough collector. In this col-lector the solar radiations coming from
a particular direction are collected over the area of the reflecting surface and is concentrated
at the focus (F) of parabola. Mostly cylindrical parabolic concentrators are used in
which absorber is placed along focus axis. Fig. 3 shows a typical cylindrical parabolic
collector. It consists of parabolic cylinder reflector to concentrate sunlight on to a collecting
pipe. The reflector is steered during day time to keep sunlight focused on the collector. This
type of concentrator produces much higher temperature than flat plate collectors. The
dimensions of parabolic trough collector or parabolic cylindrical collector can vary over a
wide range, the length of a reflector unit may be above 3 to 5 m and width about 1.5 to 2.4
in. Ten or more such units may be connected end to end in a row, several rows being
connected in parallel. Parabolic trough reflectors may be made from polished aluminium,
silvered glass or a thin film of highly aluminised plastic on a firm base.
(b) Point Focusing Collector. Fig.4 shows a paraboloidal dish collector which bring solar
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radiation to a focus at a point. In this collector a dish 6.6 meter in diameter made from about
200 curved mirror segments forming a paraboloidal surface is used. The absorber located at
the focus is a cavity made of a zirconium-copper alloy with a black chrome selective
coating. The heat transport fluid flows into and out of absorber cavity through pipes bonded
to the interior. The dish can be turned left and right and up and down so that Sun rays can be
focused properly.
Fig. 5.2 Parabolic trough collector Fig. 5.3 Cylindrical parabolic collector
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(ii) Cost of collecting system per unit area is low.
(iii) The absorber arc of concentration is small and therefore, solar energy concentrated
can produce more heat and therefore, working fluid can attain temperature for the same solar
energy falling on the concentrator.
(iv) Since the temperature that can be attained with concentrating collector system is
higher, the amount of heat which can be stored per unit volume is larger and consequently
the heat storage costs are less for concentrator systems than for flat plate collectors.
(v) They have more efficiency.
Disadvantages
i. Diffused solar radiations cannot be focused and is lost.
iii. Costly orienting system for reflector to track the Sun is required.
Energy storage is essential with solar thermal energy systems and solar electrical power
plant because of the following:
(ii) Cloudy hours and night hours without solar insolation. (iii)Difference between solar
energy supply curve and the load curve.
In electrical power systems, following methods of energy storage are being used/considered:
b) Compressed air energy storage (CAES) is not economical for solar system.
The thermal energy collected during the sun shine is stored in the thermal storage system.
The stored thermal energy is released during night and during cloudy hours. Solar thermal
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system should therefore be supplemented with additional energy supply system. Such
systems are called 'Hybrid system' e.g., solar-Diesel Hybrid. In this, solar energy plants are
operated in conjunction with a diesel generating set. Such plants are economical for remote,
stand- alone plants rated up to 350 KW.
The solar thermal system may be operated in following three modes:
1) Energy Supply Mode (Collection Mode). During the energy supply mode thermal
energy collected by the solar collector is supplied to the central receiver or the thermal
reservoir. From there, it is supplied to the load.
2) Energy Storage Mode. During the energy storage mode, the thermal energy
collected by the solar collectors is given to the storage tank. The material in the storage tank
gets heated and stores the sensible heat. Excess energy collected by the system is stored.
3) Energy Release Mode. During the stored energy release mode, the stored thermal
energy from the storage tank is released to the load.
Thus during cloudy days or at night, energy previously stored during high insolation times
could be used to provide a continuous electrical output or thermal output. Thus the addition
of storage can increase the reliability of being able to deliver power at an arbitrary needed
time.
Thus storage of solar energy in a solar system may:
1. Permit solar energy to be captured when insolation is highest and then later used
when the need is greatest.
2. Make it possible to deliver electrical load power demand during times when
insulation is below, normal or non-existent. Storage also make possible to deliver short
peaks of power for exceeding the rated power capacity of the plant.
3. Be located near the load, thereby minimizing the need for costly transmission and
distribution facilities.
4. Improve the reliability.
5. Permit a better match between the solar energy input and the load demand output
than would be the case without storage.
Solar energy storage systems may be broad y classified as shown in Fig 5
The heat transfer fluid, also known as primary coolant, is pumped through the collector
piping. The thermal energy collected by the solar collectors is given to the heat transfer
fluid. The heat transfer fluid flows from the collectors to the central receiver or storage
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tanks. Then heat transfer fluid may be same as the working fluid of the thermodynamic
cycle or it may be different.
Fig. 5.5. Solar Energy Storage Systems Heat Transfer Fluid (Primary Coolant)
The following heat transfer fluids are common for practical solar thermal systems.
1. Water-steam
2. Liquid metals e.g., Sodium (Na). It has boiling point at 883° C and operating
temperature at 540° C.
3. Molten Salts e.g., Nitrate salt mixtures.
SOLAR PUMPING
The various parts of solar pumping system are as follows:
1. Solar collectors, such as (a) Flat plate collectors (b) Stationary concentrators.
2. Heat exchanger or Boiler
3. Heat engine such as (a)Brayton cycle as turbine (b)Stirling hot gas engine
(c) Rankine engine
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4. Condenser
Solar radiation can be converted into two principal forms of energy. One is the heat and the
other is electricity. Heat is obtained when solar radiation is absorbed by a black surface.
The heat may be used in various Ways, which may be broadly divided into two categories.
(i) Direct thermal applications like water heating, cooking etc., known as solar thermal
power generation.
(ii) (ii) Solar energy can be converted into electrical by solar thermal power generation
route or solar radiation can be directly converted into electrical power.
In direct conversion of solar energy into electricity, we may employ photovoltaic,
thermoelectric, thermionic and photo chemicals.
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SOLAR THERMAL POWER GENERATION
Solar thermal power generation uses power cycles which are broadly classified as:
(ii) Electricity.
Heat is obtained when solar radiation is absorbed by a black surface. The heat then may use
in two ways:
a) Direct thermal applications such as water heating, drying, cooking, distillation etc.
b) In direct conversion so solar energy into electricity using photo voltaic cells, thermo
electric thermionic and photo chemicals. Photo voltaic effect is quite popular.
The mechanical power production is called solar thermal power production system. So far
as conversion of solar energy into electrical energy is concerned it may be done either by
solar thermal power production route or solar radiations can be directly converted into
electrical power.
Low Temperature Systems. Fig 5.7 shows a low temperature thermal electric power
generation scheme using solar pond. Hot water from pond enters an evaporator where the
organic working fluid is vaporized. Then the vaporised organic fluid at high pressure enters
a turbine and thereby expanding the turbine wheel to produce power.
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The vapour now passes through a condenser where it is condensed to a liquid is pumped
back to the evaporator where cycle is repeated.
Another type of low temperature solar power plant is shown is Fig. 5.8. This system uses an
array of flat plate collectors to heat water to about 70°C and then in heat exchanger the heat
of water is used to boil butane. The butane at high pressure is made to pass through a
turbine. This scheme is quite commonly used for lift irrigation purposes.
Fig. 5.8 Low temperature solar power plant High Temperature Systems
For efficient conversion of heat energy into mechanical energy and then into electrical
energy, the working fluid should be supplied to the turbine at high temperature. To obtain
such temperatures (above 175° C) from solar energy requires the use of focusing
concentrating collectors. Since these collectors concentrate direct solar radiation, they would
be most effective in locations where there is ample sunshine.
Two basic arrangements are used for converting solar radiation into electrical energy:
(a) Tower Solar Power Plant. This type of power plant uses an array of plane mirrors or
heliostats which are individually controlled to reflect radiation from the Sun into a boiler
mounted on a tall (about 500 m high) tower. The steam is generated in the boiler. The steam
may attain a temperature up to 2000°K. The steam so produced is used to drive a turbine
coupled to a generator. Fig. 5.9 shows a tower concept type solar power plant.
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Fig. 5.9 Tower type solar power plant
Another type of solar power plant based on similar principle is shown in Fig 5.10. It uses an
array of heliostats guided mirrors to focus sunlight into a cavity type boiler near the ground
to produce high temperature high pressure steam which is used to drive a steam turbine. The
solar rays striking the mirrored faces of heliostats modules are reflected and concentrated in
the cavity of boiler.
The distributed collector system or solar farms may consist of a number of parabolic trough
type (line focusing) collectors or of parboiled dish type (point focusing) collectors. The
absorber pipes (or receiver) of the individual collectors are connected so that all the heated
fluid is carried to a single location where the electricity is generated. The basic difference
between the central receiver and distributed collector system is that in the former the solar
energy falling on a large area is transmitted to a central point as radiation, but in the latter,
the energy is carried as heat in fluid. In the distributed collector system, heat collected by a
fluid flowing through the pipes could be stored at a temperature over 500°C in a molten
eutectic salt and used as required to produce steam for electric power generation.
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PHOTOVOLTAIC (PV) CELLS OR SOLAR CELL
These cells directly convert solar energy to D.C. power. These cells are made of
semiconductors that generate electricity when they absorb light. Solar cells made of single
crystal silicon are commonly used as its theoretical efficiency of about 24%. But
commercially available cells have an efficiency of about 10 to 12%. Gallium arsenide is
another solar cell material. Cells of this material may achieve an efficiency of 20 to 25%.
Solar cells made of gallium arsenide can retain efficiency at much higher temperature than
cells made of silicon. The silicon cell consists of a single crystal of silicon into which a
doping material is diffused to form a semi-conductor. The best known application of
photovoltaic cells for electrical power generation has been spacecraft for which silicon solar
cell is the most highly developed type.
Various advantages of solar cell are as follows:
Solar cells have also been used to operate irrigation pumps, navigational signal, highway
emergency cell Systems, rail road crossing signals etc.
The most common configuration of a typical solar cell to form a p-n junction semiconductor
is shown in Fig. 5.11.
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Fig.5.11 typical solar cell
WIND MILLS
Wind energy is used to run wind will which in turn drives a generator to produce electricity.
A wind mill converts the kinetic energy of moving air into mechanical motion that can be
either used directly to run the machine or to turn the generator to produce electricity.
Various types of wind mills are as follows:
(i) Horizontal axis wind mills
(a) Multi blade type wind mill (b) Sail type wind mill
Vertical axis wind mills are of simple design as compared to the horizontal axis.
Horizontal axis wind mills may be single bladed, double bladed or multi bladed.
Wind energy conversion devices are commonly known as wind turbines because they
convert the energy of the wind stream into energy of rotation: the component which rotates
is called rotor. The terms turbine and rotor are however often regarded as being
synonymous. An electric generator is coupled to the turbine to produce electric power. The
combination of the wind turbine and generator is sometimes called as an Aero Generator.
The fraction of free flow wind power than can be extracted by a rotor is called the power
coefficient.
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K = Power coefficient
= P1 / P2
The maximum theoretical power coefficient is 0.593. The mass of air is calculated as
follow:
Q = Amount of air passing in unit time
=AxV
M = Mass of air traversing through area A swept by the rotating blades of wind mill type
generator.
M=ρ.A.V
The physical conditions in a wind turbine are such that only a fraction of available wind
power can be converted into useful work. The power available in the wind increases rapidly
with the speed and hence Wind Energy Conversion (WEC) machines should be located
preferably in areas where winds are strong and persistent. Wind turbine generators have
been built having capacity ranging from a kilowatt or so to a few thousand kilowatts. Wind
power has been successfully used for cooling of homes, space heating, for operating
irrigation; navigational signals and for offshore drilling operations.
Figure 12 shows the various parts of a wind-electric generating power plant. They are
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The wind mill head supports the rotor housing the rotor bearings. The moving air makes the
blades to rotate and the electricity is produced at the generator. Part A indicated
transmission; Speed increases. Drive shaft and bearing brake clutch and coupling.
Fig. 5.12. Parts of a wind mill Fig. 5.13. Horizontal axis type wind mill.
Fig. 5.13 shows schematic arrangement of a horizontal axis type wind mill and Fig. 5.14
shows vertical axis type wind mill
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Basic Components of a Wind Energy Conversion System (WECS)
Figure 5.15 shows the basic components of a wind energy conversion system. Figure 5.16
shows a horizontal axis multi blade type wind mill.
The blades are made of metallic sheets. They have high starting torque and are economical.
Aero turbines convert the wind energy to rotary mechanical energy. A mechanical interface
consisting of a step up gear and a coupling transmits the rotary mechanical energy to an
electrical generator. The output of generator is connected either to load or power grid. The
purpose of controller is to sense wind speed, wind direction, shafts speeds and torques,
output power and generator temperature. Figure 5.17 shows a horizontal axis wind mill
Dutch type. The blades are made of wood.
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Site Selection for Wind Mill Units
Following factors should be considered while locating Wind Energy Conversion Systems
(WECS).
(i) Wind energy conversion machines should be installed at sites where winds are strong
and persistent. The most suitable sites for wind turbines would be found where the annual
average wind speeds are known to be moderately high. It is desirable to have average wind
speed of about 3.5-4.5 m/sec which is the lower limit at which WECS generators start
turning. An ideal site will be one where a smooth steady wind flows all the time.
(ii) It is desirable to install WECS at higher altitudes because the winds tend to have higher
velocities at higher altitudes.
(iii) The ground conditions at the site should be such that the foundations for WECS are
secured. The land cost should be low.
(iv) Icing problem, salt spray or blowing dust should not be present at the site as they affect
aeroturbing blades.
(v) The site selected should be near to the users of generated electric energy.
(vi) The site selected should be near to the road or railway facilities.
The best site for wind energy systems are found off shore and the sea coast and at
mountains.
TIDAL POWER
Ocean tidal power refers to the hydro energy in ocean tides. The ocean tides occur due to
gravitational attractive forces from Sun and moon. The level of the ocean water rises
periodically during high tides and drops during low tides. The difference in head of water
during high tide and low tide is used for rotating hydro turbine-generator units installed
within barrages (dams). The time span between high tide and next low tide is 6 hours and 25
minutes and the water head of high tide is 2 to 5 m or even more. In about 24 hours there are
two high tides and two low tides. These are called as semiduirnal tides.
Ocean waves and tides contain large amount of energy. Such tides rise and fall and water
can be stored during rise period and it can be discharged during fall. Due to low head of
water available low head hydroelectric plants can work successfully Fig. 24 shows the
schematic layout of a power plant using tidal power. These plants can utilise a head of just a
few meters. During high tide the height of tide is above that of tidal basin and the turbine
unit operates and generates power. During low tide the height of tide is lower than that of
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the tidal basin. At this time water is allowed to flow out to drive the turbine unit. The turbine
unit does not operate if the tide sea level and basin level are equal.
In India the possible sites, identified for tidal power plants are as follows:
The tidal range in the Gulf of Cambay is about 10.8 meter. Whereas the maximum range of
Gulf of Kutch is 7.5 meter. The tidal range in Sunderban area is 4.3 meter. The rise and fall
of water level follows a sinusoidal curve as shown in Fig. 5.18 with point M indicating the
high tide point and point N indicating the low tide point. The difference between high and
low water levels is called the range of the tide.
Advantages
(i) The power generated does not depend on rain. Therefore there is certainty of power
supply as the tidal cycle is very definite.
(ii) The tidal power plants are free from pollution. (iii)Unhealthy wastes like ash, gases etc.,
are not produced. (iv)These plants require lesser space.
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(v) Such plants have a unique capacity to meet the peak power demand effectively when
they work in combination with hydro power plants and steam power plants.
Disadvantages
(i) The capital cost of a tidal power plant is considerably large as compared to steam power
plant and hydro power plant.
(ii) The supply of water is not continuous as it depends upon the timing of tides.
(iii) Tidal power plants are located away from load centers. This increases power
transportation cost.
Following are the important points for the selection of location of tidal power plant:
(i) The tidal range at the desired location should be adequate throughout the year. (ii)The
site selected for tidal power plant should be free from the wave attack of sea. (iii)There
should be no appreciable change in tidal pattern at the proposed site.
(iv)The site at which tidal power plant is to be located should not have excessive sediment
load.
The three main components of a tidal power plant are as follows:
(ii) Sluice ways from the basin to the sea and vice versa (iii) the power house.
The turbines, electric generators and other auxiliary equipment’s are the main equipment’s
of power house.
Classification
Tidal power plants are classified on the basis of number of basin used for the power
generation. They are further subdivided as one way or two way system as per the cycle of
operation for power generation.
Various types of tidal power plants are as follows:
(i) 'Single basin system (a)One way system (b)Two way system
(c)Two way with pump storage.
(ii) Double basin system (a) Simple double basin system (b) Double basin with pumping.
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Figure 5.19 shows a single basin one way tidal power plant. In this plant a basin is allowed
to get filled during the flood tide and during the ebb tide, the water flowing. Single basin
one way tidal power from the basin to the sea through the turbine and generates power. The
power is available for a short duration during ebb tides.
In single basin two way tidal power plant the power is generated both during flood tide as
well as ebb tide. The direction of flow through the turbines during the ebb and flood tides
alternates but machine acts as a turbine for either direction of flow. Figure 5.20 shows a
double one way tidal power plant. In this plant one basin in intermittently filled by flood
tide and other is intermittently drained by ebb tide.
The tidal power plant generates unregulation power from tides. Some of the methods which
help to generate regular power from tidal power plants are as follows:
(i) Combining two or more tidal schemes with different tidal phases.
(ii) Providing two basins (one high and one low) having inter-connection with each
other and with the sea.
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(iii) To inter-connect tidal power plant with (a) steam power plant (b) pumped storage
hydro power plant (c) hydro power plant.
Fuel cell
A fuel cell is an electrochemical cell, which can continuously and directly convert the
chemical energy of a fuel and an oxidant to electrical energy by a process involving
essentially electrode-electrolyte system. The basic principles of a fuel cell are those of the
electrochemical batteries. The big difference is that, in the case of batteries, the chemical
energy is stored in the substances located inside them. When this energy has been converted
to electrical energy, the battery must be thrown away or recharged appropriately. In a fuel
cell, the chemical energy is provided by a fuel and an oxidant stored outside the cell in
which the chemical reactions take place. As long as the cell is supplied with the fuel and
oxidant, electrical power can be obtained.
In direct fuel cell, hydrogen is fed directly as fuel at the cathode and it is further classified as
low (25°C-100°C), intermediate (100°C-500°C), high (500°C-1000°C) and very high
temperature (above 1000°C) fuel cells depending up on the temperature of operation. In the
case of indirect fuel cell, the active fuel is obtained from a source and oxidized, example
hydrogen obtained by hydrocarbon cracking. When fuel is reformed by using reformer
internally or externally it is known as reformer fuel cells and when this conversion is carried
out by bacteria, enzymes and algae it is known as biochemical fuel cell. In biochemical fuel
cells, Sulphur containing compounds are biodegraded to form H2S and O2 containing wastes
are biodegraded to form O2, which is then used in this fuel cells. In regenerative fuel cells,
fuel is used again and again through regeneration, which is done by an external agency.
Energy is consumed in the regeneration. Fuel is regenerated from the products by thermal,
electrical, photochemical or radiochemical methods. For practical reasons fuel cell systems
are simply distinguished by the type of electrolyte used and following names and
abbreviations are used: Proton Exchange Membrane Fuel Cells (PEMFC), Alkaline Fuel
Cells (AFC), Direct Methanol Fuel Cells (DMFC), Phosphoric Acid Fuel Cells (PAFC),
Molten Carbonate Fuel Cells (MCFC), and Solid Oxide Fuel Cell (SOFC). Subsequent
classifications are discussed with the system. The fuel cells offer advantages and efficiency
reliability and economy cleanliness unique operating characteristics planning flexibility and
future development potentials.
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Fig. 5.21 Classification of fuel cells
Efficiency
Fuel cells can convert unto 90% of energy contained in its fuel into useable electric power
and heat. Current PAFC designed offer 42% conversion efficiency. It is predicted that
MCFC may achieve electrical efficiencies > 60%. As the fuel cells contain fewer moving
parts they have higher reliability than ICE. They cannot experience a catastrophic
breakdown as can occur with ICE when the rotating parts fail. The quiet electrochemical
nature of fuel cell eliminates many of the noise associated with conventional energy
systems. No ash or large volume wastes are produced from fuel cell operations. They are
among the least hazardous methods of energy conversion due to their comparatively small
size, the absence of a combustion engine. The electrochemical reaction of a fuel cell
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produces water as by product, the quantity being comparatively lower than conventional
fossil fuel powered energy systems.
Hydrogen from the fuel gas stream is consumed at the anode, yielding electrons and
hydrogen ions, which enter the electrolyte. At the cathode, oxygen combines with electrons
from the cathode and hydrogen ions from the electrolyte to produce water. Water does not
dissolve in the electrolyte and instead it is carried out of the fuel cell by excess oxidant flow.
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ability to operate over a wide temperature range. It consists of two porous electrodes with
liquid KOH electrolyte between them. The hydrogen fuel is supplied to the anode electrode,
while oxygen from air is supplied to the cathode. The working temperature ranges from 293
to 363K. The electrical voltage between the anode and the cathode of a single fuel cell is
between 0.9 V and 0.5 V depending on the load and the electrochemical reactions taking
place at these electrodes. The hydrogen is usually compressed and the oxygen is obtained
from the air. It uses a circulating liquid alkaline electrolyte, potassium hydroxide (30-45%
KOH). This is an effective heat transfer and water management medium. The fuel cell can
produce power at ambient temperatures but is designed to deliver full power at about 343 K,
which, with electrical heating, it will normally reach within 10 min of a cold start.
The cell reactions are as follows:
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Direct Methanol Fuel Cells (DMFC)
DMFC is essentially the same as a PEMFC, but in DMFC, methanol is fed directly at the
anode which does not require external reforming of the fuel, which leads to highly efficient,
low cost and reduced size fuel cell. The operating voltages of systems using methanol
directly is 100-200 mV lower than indirect hydrocarbon systems. Methanol permeates from
the anode chamber across the membrane, adsorbs onto the cathode catalyst, and reacts with
air (O2) resulting in parasitic loss of methanol fuel and reduced cell voltage at higher
current densities. Methanol and water react electrochemically at the anode to produce
carbon dioxide, protons and electrons. The protons produced migrate through the polymer
electrolyte to the cathode where they react with oxygen to produce water. These reactions
are promoted by the incorporation of platinum- based electro catalyst materials in the
electrodes. Methanol oxidation, which is irreversible, is a six-electron process and the
product of oxidation CO is rejected by the electrolyte. The maximum theoretical voltage is
1.186 at 25°C. The potential developed is a mixed potential involving reaction of HCHO
and HCOOH species.
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Phosphoric Acid Fuel Cell (PAFC)
The Phosphoric Acid fuel cell (PAFC) is in a mature state in terms of technological
advancement. Acid fuel cells with phosphoric acid as electrolyte use relatively clean,
reformed fuels (Natural gas, LPG, light distillates). Phosphoric acid has the advantages of
good thermal, chemical and electrochemical stability, good capillary properties and low
vapour pressures though it is a poor ionic conductor. Among the common acids, it has the
lowest volatility and this property allows PAFCs to operate at 463K to 473K for several
thousand hours. Other inorganic acids such as HCl, HF, H2SO4 and HClO have lower
thermochemical stability and higher vapour pressures and therefore not suitable for
operations at high temperatures (>473K). H3PO4 is the only inorganic acid that is suggested
for its utility in fuel cell applications for these reasons.
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electrodes. The advantage of this type of fuel cells is their relatively simple construction,
mainly based on the use of carbon, PTFE and SiC which all can be processed by methods
which are well-known from the origin of the fuel cell technology and could be easily
adjusted to the demands of the fabrication of PAFC fuel cell components.
Molten carbonate fuel cells are approaching the early stages of commercialization, having
been under study and development for more than 40 years. The high operating temperatures
of MCFCs offer the prospect of being able to internally reform fuels such as natural gas.
Long start-up times are implied, expensive materials are needed, and a number of design
challenges are encountered due to leakage, corrosion, and loss through vaporization of the
electrolyte. One of the most promising aspects of molten carbonates is the possibility of
using, apart hydrogen, low cost fuels, as methanol, gaseous carbon. CO+H2 (syngas)
resulting from methane conversion by thermal cracking or reforming reaction. The oxidant
is constituted by a mixture of air and carbon dioxide in the proportions of 70% and 30%
respectively.
In operating MCFC, electrons are transferred from the anode through an external circuit to a
cathode, where they participate in reduction reactions. Negative charges are conducted by
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carbonate anions (CO) from the cathode through the molten electrolyte to an anode. At the
anode, electrons are produced by oxidation. MCFCs differ in many respects from PAFCs
because of their higher operating temperature and the nature of the electrolyte. The higher
operating temperature of MCFCs provides the opportunity for achieving higher overall
system efficiencies and greater flexibility in the use of available fuels. On the other hand,
the higher operating temperature places severe demands on the corrosion stability and life of
cell components, particularly in the aggressive environment of the molten carbonate
electrolyte. Another difference between PAFCs and MCFCs lies in the method used for
electrolyte management in the respective cells. In a PAFC, PTFE serves as a binder and
wet-proofing agent to maintain the integrity of the electrode structure and to establish a
stable electrolyte/gas interface in the porous electrode. The phosphoric acid is retained in a
matrix of PTFE and SiC between the anode and cathode. There are no materials available
for use in MCFCs that are comparable to PTFE. Therefore, a different approach is required
to establish a stable electrolyte/gas interface in MCFC porous electrodes. The MCFC relies
on a balance in capillary pressures to establish the electrolyte interfacial boundaries in the
porous electrodes.
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at 1200 K vs 54.6 Kcal/mol at 300 K for H). The heat of reaction is almost independent of
temperature; therefore the potential (ideal efficiency) is reduced by the high temperature
operation. Different SOFC designs have been developed to implement the fuel cell and
reformers into the stack and, ultimately, the complete system. Three main designs are
encountering rapid development in SOFC technology: tubular, planar and monolithic
configurations. Tubular SOFC designs are closer to commercialization and are being
produced by several companies around the world. Demonstrations of tubular SOFC
technology have produced as much as 220 kW. Since SOFC requires high operating
temperatures, their most common application is in large, stationary power plants. The high
temperatures open the opportunity for “cogeneration”-using waste heat to generate steam for
space hearing, industrial processing, or in a steam turbine to make more electricity.
Although they require inverters to change their direct current to alternating current, they can
be manufactured in relatively small modular units. The compact size and cleanliness of
SOFCs make them especially attractive for urban settings.
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