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Chemistry Program Guide

The document provides information about the Master of Science in Chemistry program offered by the Department of Post Graduate Studies and Research in Chemistry at the Karnataka State Open University, including messages from the Vice Chancellor, Dean (Academic), and Chairman of the Department of Studies and Research in Chemistry welcoming new students and outlining the vision, mission and goals of the chemistry program.

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0% found this document useful (0 votes)
212 views159 pages

Chemistry Program Guide

The document provides information about the Master of Science in Chemistry program offered by the Department of Post Graduate Studies and Research in Chemistry at the Karnataka State Open University, including messages from the Vice Chancellor, Dean (Academic), and Chairman of the Department of Studies and Research in Chemistry welcoming new students and outlining the vision, mission and goals of the chemistry program.

Uploaded by

H S
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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KARNATAKA STATE OPEN UNIVERSITY

PROGRAMME GUIDE
MASTER OF SCIENCE IN CHEMISTRY

DEPARTMENT OF POST GRADUATE


STUDIES AND RESEARCH IN CHEMISTRY

Mukthagangothri, Mysore – 570 006


1
VICE CHANCELLOR’S MESSAGE
Dear Learner,
The family of KSOU welcomes you to pursue the academic programmes you have chosen to
achieve not only academic excellence but also to fulfill the desire of your career. The
University, established by the Act of State Legislature has created wonderful academic
ambience. The programmes offered by the University have been recognized by University
Grants Commission. Therefore, the degrees are valid for employment opportunities across the
country. The 'core values' of the University are derived from its vision ‘Higher Education to
Everyone, Everywhere’. The ultimate touchstone of quality higher education is the motto of
the University. Today, higher education stands at the crossroads of keeping pace with the
emerging needs of the country.

The University has adopted a school concept in its functioning. The school of science headed
by a Director offers academic programmes in basic and applied sciences. It combines an inter
disciplinary and professional approach to pedagogy and research. The University believes
that rigors of the contemporary world require competent quality human resources to create
knowledge based society. The academic activities of B.Sc. programmes are initiated through
well-established department/s led by the Chairperson/s. Well-qualified teaching faculty with
equally dedicated non-academic team is an asset to the University, which is always,
committed for the welfare of the students.

The University functions in a 3-tier system of student support service, namely Headquarters,
Regional Centres and Learners Support Centres spread all over Karnataka. The learners can
undergo teaching-learning process in the notified Regional Centres/Learner Support Centres.
The University has adopted a mechanism to deliver Self Learning Material by print, limited
audio visual and Counseling/Personal Contact Programme. As a learner, you will have
greater opportunity to gain knowledge and skill through those mechanisms. The academic
counselors will play a strategic role and supports you from the enrollment of the programme
till you accomplish the goal. A proper blending of the knowledge and skill will be imparted
so that you will be transformed as a good citizen to contribute to the development of society
and the country.

The UGC in its Public Notice dated: 23.02.2018 stated that the Degree/Diploma/Certificate
Programme awarded through distance mode are at par with corresponding Degree/ Diploma/
Certificate Programme obtained through conventional universities. The degrees acquired
through distance education are recognized for the purpose of employment in State/Central
Government, MNCs, Private Sector etc. and also for pursuing higher education in other
educational institutes. Therefore, you have greater opportunity of pursuing Higher Education
without any kind of fear about your career.

I am sure you will enjoy good experience with services rendered by the university through its
Regional centres and Learner Support Centres, besides Headquarters. I wish you all the best
in your academic endeavors.

Prof. Vidyashankar S
2
MESSAGE FROM DEAN (ACADEMIC)
Dear learner,
As you know education imparts knowledge and skills which empowers all to build
civilized society. Higher education policy which was once a priority sector is no longer
maintaining the same, due to General Agreements and Trade in Services (GATS). The
education policy of the government provides a greater opportunity to accelerate Gross
Enrolment Ratio (GER).
Higher education is imparted both by conventional system and ODL system. The
former education has inbuilt rigidity where ODL enjoy flexibility. Presently the GER in
higher education around is 27%, thanks to the role played by ODL system. The ODL system
operates under access, flexibility and success.
The Karnataka State Open University, which came up in 1996 under the Act of state
legislation 1992 play a stupendous role in imparting quality education. As one of the premier
institution in ODL system of the country, the university strive hard to empower various dis-
advantaged sections of the society like, house wives, economically and culturally backward,
tribal, senior citizens, working groups, differently abled, professionals, technocrat, jail
inmates etc., The University cater to the needs of students ranging from the age of 18 years
to 80 years.
The programmes offered by KSOU are strictly in conformity with quality and
standards set by regulatory bodies UGC/AICTE etc., The Karnataka State Open University
was established on 1st June 1996 vide Government Notification No. EDI/ UOV/ 95 dated 12 th
February 1996- KSOU Act 1992, keeping in view the educational needs of our country, in
general, and the state in particular. The University has a long and rich experience in the field
of Distance Education as the erstwhile Institute of Correspondence Course and Continuing
Education. University Grants Commission (UGC) New-Delhi vide order No: F.No 14-5/2018
(DEB-I) Dated : 14th August 2018 for the period from 2018-19 to 2022-23. The KSOU
operates on dictum quality first and students foremost. Further the university is highly
committed to provide need based education to the door steps of the students.

The KSOU has students’ support services which work in 3 tiers - head office; regional
centres and study centres within the jurisdiction of state. The admissions, counseling and the
examinations are conducted in different places, hence, education at the door steps.
The dedicated staffs in various department and state of the art student support services
create a conducive environment for teaching learning. The university put in places all
possible efforts to keep the learners happy from the stage of enrolment till they get employed.
I am confident that, as a learner in the university, you will enjoy good experience in the
system.
I wish you all the best in your academic endeavors.
Truly yours,

Dean (Academic)
3
Department of studies and Research in Chemistry

Vision:
To enhance our status as an outstanding teaching and multidisciplinary research hub which is
recognized for its quality teaching, innovative research to promote and discovery of new
molecular entities that attracts the best students globally
Mission:
Our mission is to cultivate a world-class quality teaching environment for
undergraduate, postgraduate, and doctoral research programs to empower our students
to meet the challenges of academic and industrial arenas. We foster and encourage the
pursuit of interdisciplinary research in the thrust areas of chemical sciences.

 To promote scientific thinking among the learners through offering accessible,


affordable quality higher education.
 To empower learners to gain knowledge and skills in the field of Chemical Science.
 To train the learners on curriculum to imbibe with moral, ethical and civic values.
 To impart the specific skills to the learners so as to enable them to be a responsible
citizen in the society.
 To enhance the attitude of the learners in such a way that they realize individual
responsibility in the society.
 To enhance the professionalism to diagnose and offer solutions thereof.

4
1. Chairman’s message

I would like to take this opportunity to welcome you to the Karnataka State Open
University and the Department of Studies and Research in Chemistry. I am delighted that you
have chosen to enrol in our Chemistry program and work towards being awarded the Master
of Science degree in Chemistry.

The Department of Studies and Research in Chemistry was established in 2013. Over
the last years, and with the excellent and rigorous academic preparation provided by our
program, the department has produced many outstanding graduates who have gone on to
successful and exemplary careers in industry, academia and government.
Chemistry is the branch of basic science that applies the core scientific disciplines
(chemistry, physics, biology, mathematics, computer basics and applied engineering sciences)
to transform raw materials or chemicals into more useful or valuable forms, invariably in
processes that involve chemical change. In research and development, chemical science not
only create new, more effective ways to manufacture chemicals, but also work collaboratively
with chemists to pioneer the development of new hightech materials for specialized
applications. The development, commercialization, and optimization of the industrial-scale
processes for manufacturing chemicals and advanced materials are feats of chemical science.
Indeed, virtually every aspect of a modern industrial economy is critically dependent upon
chemical science for manufacturing the vast array of bulk and specialty chemicals and high-
tech materials needed to create a limitless array of value-added products.
The faculties of the Department are committed to continuous improvements of our
program. We encourage your questions and comments on the various aspects of our program
and are particularly interested in your comments regarding the program's educational
objectives, outcomes and curriculum.
Warm Regards,
Chairman
Department of Studies and Research in Chemistry
Karnataka State Open University
Mukthagangothri, Mysuru-570007

5
2. About the Department

The Department of Chemistry is one of newly established departments of Karnataka


State Open University, established in 2013 and since then we are running postgraduate
program. From this year, undergraduate and Ph.D. courses in different specializations,
Analytical, Inorganic, Organic and Physical chemistry are also introduced. The chemistry
department has a rich tradition of imparting high-quality teaching and research in cutting-
edge thrust areas of chemical science, providing intensive learning and research training to
students and research scholars. The students have access to a seminar library where a large
collection of international and national reputed textbooks are housed. Besides this, the
department has a state-of-art laboratory infrastructure for training and conducting quality
research. The department has smart classroom, modern Audio and Video studio for offering
teaching in online mode. The department of chemistry organized workshops, symposia, and
national and international conferences on thrust areas of chemical sciences. A large number
of postgraduate students have qualified NET and GATE examinations every year. During the
last 5 years, the department has published more than 10 research papers in Scopus indexed
journals during 2013-2021.

Faculty Details
Faculty Details
a. Department of Chemistry
Sl. Name of the Faculty Designation Qualification Specialization Expe- Mobile
No. rience Number
in
Years
1 Dr. M. Umashankara Assistant Professor M.Sc. Ph.D. Organic Chemistry 7 9482510061
& Chairperson

2 Dr. Arjun H.A Assistant Professor


(Contract Basis)

3 Dr. Kemparaje Gowda Assistant Professor


(Contract Basis)

4 Dr. Krishna M.H Assistant Professor


(Contract Basis)

5 Dr. Obaiah G.O Assistant Professor


(Contract Basis)

6
3. Program offered:

M. Sc. in Chemistry

B.Sc. in Chemistry

Ph.D. in Chemical Science

4. Course detail of M.Sc. Chemistry

a. Duration of the course: Two years (Four semesters)


b. Medium of Instruction: Medium of Instruction is English only.
c. Mode of Instruction: Print material, E-content, PCP/Counseling.
d. Attendance (Minimum required): 75% for counselling sessions of theory
courses. 85% for practical sessions.

5. Course detail of B.Sc. Chemistry

a. Duration of the course: Three years (six semesters)

b. Medium of Instruction: Medium of Instruction is English only

c. . Mode of Instruction: Print material, E-content, PCP/Counseling.

d. Attendance (Minimum required): 75% for counselling sessions of theory


courses. 85% for practical sessions.

* * * * *

7
CBCS Course Matrix
Counselling/ Maximum Marks Examinat
Course PCP hours*
Semester and Course Credits Term-End ion
Code IA Total
Examination duration
Semester - I
HC 1.1 Course 1 4 12 20 80 100 3
HC 1.2 Course 2 4 12 20 80 100 3
HC 1.3 Course 3 4 12 20 80 100 3
HC 1.4 Course 4 ((Practical) 4 120 - 50+50 100 3+3
SC 1.1 Course 5 3 10 20 80 100 3
EL-1 Inter Disciplinary course – I 2 06 10 40 50 11/2
Semester - I Total 21 172 90 460 550
Semester - II
HC 2.1 4 12 20 80 100 3
Course 6
HC 2.2 4 12 20 80 100 3
Course 7
HC 2.3 4 12 20 80 100 3
Course 8
HC 2.4 4 120 - 50+50 100 3+3
Course 9 (Practical)
SC 2.1 3 10 20 80 100 3
Course 10
EL-2 Inter Disciplinary course – II
2 06 10 40 50 11/2
Semester - II Total 21 172 90 460 550
Semester - III
HC 3.1 Course 11 4 12 20 80 100 3
HC 3.2 Course 12 4 12 20 80 100 3
HC 3.3 Course 13 (Practical) 4 120 - 50+50 100 3+3
SC 3.1 Course 14 3 10 20 80 100 3
SC 3.2 Course 15 3 10 20 80 100 3
SDC-1 Skill development course-1 2 6 10 40 50 11/2
Semester – III Total 20 170 90 460 550
Semester - IV
HC 4.1 Course 16 4 12 20 80 100 3
HC 4.2 Course 17 (Practical) 4 120 - 50+50 100 3
HC 4.3 Course 18 4 12 20 80 100 3
SC 4.4 Course 20 3 10 20 80 100 3
SC 4.1 Course 21 3 10 20 80 100 3
SC 4.2 Skill development course-2 2 6 10 40 50 11/2
SDC-2 Semester – IV Total 20 170 90 460 500
Semester I to IV Grand total 82 684 360 1840 2200

Note: HC-Hard Core, SC-Soft Core, EL-Interdisciplinary Elective.


 During 4th Semesters student can study two soft cores course 20 and course 21 or opt
desertation.
 Student might take the department concern to opt specialized soft courses with limited
mobility.
Course and examination details of M.Sc. Chemistry Program under Choice Based Credit
System (CBCS)

8
M.Sc. Chemistry Semester-I
Teaching scheme
Examination scheme

Theory/practical
(Hours)

Duration in Hrs
Min. Passing

Credits
Code

Max. Marks

Total Marks
Marks

practical
Theory

Total

Practical
External

Internal

Theory
Marks

Marks
Inorganic
HCT101 12 - 12 4 3 80 20 100 40 -
Chemistry-I

Organic
HCT102 12 - 12 4 3 80 20 100 40 -
Chemistry-I

Physical
HCP103 12 12 4 3 80 20 100 40 20
Chemistry-I

Analytical
P1 - 60 60 2 3 50 - 50 - 20
Practical - I

Inorganic
P2 - 60 60 2 3 50 - 50 - -
Practical - I

Analytical
SCT101 10 - 10 3 3 80 20 100 40 -
chemistry

Open elective
EL 6 - 6 2 1½ 40 10 50 20
Chemistry-I

Total 52 120 172 21 19½ 460 90 550 180 40

9
M.Sc. Chemistry Semester-II

Teaching
scheme Examination scheme

Theory/practical
(Hours)
Min.

Credits

Duration in Hrs
Code

Max. Marks Passing

Total Marks
practical
Theory
Marks

Total

Practical
External

Internal

Theory
Marks

Marks
Inorganic
HCT201 12 - 12 4 3 80 20 100 40 -
Chemistry-II

Organic
HCT202 12 - 12 4 3 80 20 100 40 -
Chemistry-II

Physical
HCP203 12 12 4 3 80 20 100 40 20
Chemistry-II

Organic
P3 - 60 60 2 3 50 - 50 - 20
Practical - I

Physical
P4 - 60 60 2 3 50 - 50 - -
Practical - I

Molecular
SCT201 10 - 10 3 3 80 20 100 40 -
Spectroscopy

Open
EL elective 6 - 6 2 1½ 40 10 50 20
Chemistry-II

Total 52 120 172 21 19½ 460 90 550 180 40

10
M.Sc. Chemistry Semester-III

Teaching
scheme Examination scheme
Theory/practical (Hours)

Min.

Credits
Code

Max. Marks Passing

Duration in Hrs

Total Marks
Marks

practical
Theory

Total

Practical
External

Internal

Theory
Marks

Marks
Application of
HCT301 12 - 12 4 3 80 20 100 40 -
spectroscopy-1

Bioinorganic and
HCT302 12 - 12 4 3 80 20 100 40 -
Biophysical Chemistry

P5 Analytical Practical - II - 60 60 2 3 50 - 50 - 20

P6 Inorganic Practical - II - 60 60 2 3 50 - 50 - 20

SDC-1 Skill development course-1 6 - 6 2 1½ 40 10 50 20

a) Inorganic Chemistry
special
SCT301 b) Organic chemistry
& special 20 - 20 6 6 160 40 200 80 -

SCT302 c) Physical Chemistry


special

d) Separation techniques

Total 50 120 170 20 19½ 460 90 550 180 40

11
M.Sc. Chemistry Semester-IV

Teaching
scheme Examination scheme
(Hours)
Theory/practical

Min.

Credits
Code

Max. Marks Passing

Duration in Hrs

Total Marks
Marks

practical
Theory

Total

Practical
External

Internal

Theory
Marks

Marks
Application of
HCT401 12 - 12 4 3 80 20 100 40 -
spectroscopy-2

HCT402 Bioorganic Chemistry 12 - 12 4 3 80 20 100 40 -

P7 Physical Practical - II - 60 60 2 3 50 - 50 - 20

P8 Organic Practical - II - 60 60 2 3 50 - 50 - 20

SDC-2 Skill development course-2 6 - 6 2 1½ 40 10 50 20

SCD Desecration 6 - 200 200 -

a) Advanced
inorganic Chemistry

SCT401 b) Advanced
physical Chemistry
& 20 - 20 6 6 160 40 200 80 -
c) Advanced organic
SCT402 chemistry

d) Material
Chemistry

Total 50 120 170 20 19½ 460 90 550 180 40

Note: HC-Hard Core, SC-Soft Core, EL-Interdisciplinary Elective.


 During 4th Semesters student can study two soft cores course 20 and course 21 or opt
desertation.
 Student might take the department concern to opt specialized soft courses with limited
mobility.
12
Interdisciplinary Electives
SL
Department Sub Code I Semester Sub Code II Semester
No

1 KANNADA ELK-01 DzsÀĤPÀ PÀ£ÀßqÀ ¸Á»vÀåzÀ ELK-02 ¥ÁæaãÀ PÀ£ÀßqÀ ¸Á»vÀåzÀ


EwºÁ¸À EwºÁ¸À

2 ENGLISH ELE-01 Indian Literature -I ELE-02 Indian Literature -II

3 HINDI ELH-01 Vyavaharik Hindi ELH-02 Hindi Cinema


Vyakaran

4 TELUGU ELT-01 Tilak ELT-02 Telugu Samskruthi –


Samaajam

5 HISTORY ELHS-01 Ancient World ELHS-02 Social Reform


Civilisations Movement in India

(Egypt,
Mesopotamia,
Greek, Roman, Inca,
Chinese)

6 ECONOMICS ELEC-01 Economic Policies of ELEC-02 Institutions for


India Since 1991 International
Development

7 POLITICAL SCIENCE ELP-01 Local Government in ELP-02 Indian Constitution


India.

8 PUBLIC ELPA-01 Indian Polity-1 ELPA-02 Indian Polity-2


ADMINISTRATION

9 SOCIOLOGY ELS-01 Invitation to ELS-02 Study of Indian


Sociology Society

10 JOURNALISM AND ELJ-01 Aspects of ELJ-02 Aspects of Journalism


MASS Journalism and Mass and Mass
COMMUNICATION Communication - I Communication - II

11 ANCIENT HISTORY ELA-01 World heritage sites ELA-02 Cultural History of


AND ARCHEOLOGY of India Hoysalas

12 EDUCATION ELED-01 Foundations of ELED-02 Higher Education


Education

13
13 COMMERCE ELC –01 Personal Financial ELC –02 Entrepreneurship
Planning Development

14 MANAGEMENT ELM –01 Disaster ELM –02 E-Commerce


Management

15 BIOCHEMISTRY ELMBC –01 Basics of ELMBC –02 Basic Bioorganic


Bioinorganic and chemistry for Biology
Biophysical graduates.
chemistry for Biology
graduates.

16 BIOTECHNOLOGY ELMBT –01 Biotechnology ELMBT –02 Fundamentals of


Principles and Biotechnology
applications

17 CHEMISTRY ELMC –01 Open Elective I ELMC –02 Open Elective II

18 CLINICAL NUTRITION ELMCND –01 Healthy lifestyles and ELMCND–02 Nutraceuticals and
AND DIETETICS nutrition health foods

19 COMPUTER SCIENCE ELMCS –01 Mobile App ELMCS –02 E-Commerce


Development

20 ENVIRONMENTAL ELMES –01 Basics of ELMES –02 Advances in


SCIENCE Environmental Environmental
Science Science

21 GEOGRAPHY ELMG –01 Introduction to ELMG –02 Geography of


Physical Geography Karnataka

22 MATHEMATICS ELMM –01 Fundamentals of ELMM –02 Combinatorics and


Mathematics Graph Theory

23 MICROBIOLOGY ELMMB –01 Microbial World and ELMMB –02 Microbes in


Microbial Diversity Sustainable
Agriculture and
Development

24 PHYSICS ELMP –01 Mechanics ELMP –02 Waves and Optics

25 PSYCHOLOGY ELMPSY –01 Introduction to ELMPSY –02 Psychology in


Psychology Everyday Life

14
26 INFORMATION ELMIT –01 Green Computing ELMIT –02 E-Commerce
TECHNOLOGY

27 BOTANY (NEW) ELMBOT –01 Plant-Microbe ELMBOT –02 Plant Diversity and
Interactions Human Welfare

28 ZOOLOGY (NEW) ELMZ –01 Parasites Vectors & ELMZ–02 Essential of


communicable Reproductive Health
diseases

29 FOOD AND NUTRITION ELMFNS –01 Food Psychology ELMFNS –02 Nutritional
SCIENCES Management in
Disaster Conditions

Note:
A. I and II Semester Open elective (Interdisciplinary Electives) syllabus are
attached in Annexure – I and Annexure - II respectively.

B. The Students may contact respective department chairperson in case of any


queries regarding open elective course. The contact details available in the
university website.

M.Sc. Chemistry - First Semester

Course Credits
Course Course Title
Code
Course 1 HCT-101 Inorganic Chemistry-I 4
Course 2 HCT-102 Organic Chemistry-I 4
Course 3 HCT-103 Physical chemistry-I 4
Course 4(Practical) P1 Practical 1:Analytical Chemistry-I 4
P2 Practical 2: Inorganic Chemistry-I
Course 5 SCT-101 Analytical chemistry 3
Interdisciplinary Elective-1 IE -1 Open elective Chemistry-I 2
Total 21

15
M.Sc. Chemistry - Second Semester

Course Credits
Course Course Title
Code
Course 6 HCT-201 Inorganic Chemistry-II 4
Course 7 HCT-202 Organic Chemistry-II 4
Course 8 HCT-203 Physical Chemistry-II 4
Course 9(Practical) P3 Practical 3: Organic Chemistry-I 4
P4 Practical: Physical Chemistry-I
Course 10 SCT-201 Molecular spectroscopy 3
Interdisciplinary Elective-2 IE-2 Open elective Chemistry-II 2
Total 21

Interdisciplinary Electives to be offered by Department of Chemistry


 Open elective Chemistry-I
 Open elective Chemistry-II
M.Sc. Chemistry - Third Semester

Course Credits
Course Course Title
Code
Course 11 HCT-301 Application of spectroscopy-1 4
Course 12 HC-302 Bio-Inorganic and Bio-Physical chemistry 4
Course 13 (Practical) P5 Practical 5: Analytical Chemistry-II 4
P6 Practical 6: Inorganic Chemistry-II
Skill development course-1 SDC-1 2

Course 15 SCT-301 Inorganic chemistry Special 6


& & Organic chemistry Special
Course 15 SCT-301 Physical chemistry Special
Separation techniques

16
Total 20

M.Sc. Chemistry - Fourth Semester

Course Credits
Course Course Title
Code
Course 16 HCT-401 Application of spectroscopy-2 4
Course 17 HCT-402 Bio organic chemistry 4
Course 18(Practical) P7 Practical 7: Organic Chemistry-II 4
P8 Practical 8: Physical Chemistry-II
Skill development course-1 SDC-1 2

Course 19* HCD Dissertation 6


Course 20# SCT-401 Advanced Inorganic Chemistry 6
& & Advanced Physical Chemistry
#
Course 21 SCT-402 Advanced Organic chemistry
Material chemistry
Total 20

Note: HC-Hard Core, SC-Soft Core, EL-Interdisciplinary Elective.


 During 4th Semesters student can study two soft cores course 20 and course 21 or opt
desertation.
 Student might take the department concern to opt specialized soft courses with limited
mobility.
DETAILED SYLLABUS
FIRST SEMESTER
Course 1: Inorganic Chemistry -1
Block -1.1.1 Title: Covalent Compounds
Unit-1 Formation and properties of covalent compounds, oxidation numbers theory,
Octet rule theory, multicenter bonding, Bent rules.
Unit-2 Valence bond theory (VBT) and its limitations; Hybridization theory and
energetic of hybridizations.
Unit-3 VSEPR model and dπ-pπ bonds, shape of molecules-ClF3, ICl4-, TeF5- , I3-,
TeCl62-, XeF6, SbCl63-, IF7, ReF7
Unit-4 Concepts of resonance, criteria for resonating structures, electro negativity

17
and polar covalent bond.

Block -1.1.2 Title: Ionic compounds


Unit-5 Formation and properties of ionic compounds, dissolution of ionic compounds
in polar solvents and its energetic, lattice energy, Born-Lande’s equation,
Born-Haber cycle and its applications.
Unit-6 Ionic radii, size effect, factors affecting the radii of ions, efficiency of packing
and crystal lattices, radius-ratio rule and its significance, calculation of some
limiting radius ratio values.
Unit-7 Geometry of AB type crystals: NaCl, CsCl & NiAs, reasons for preference
for a particular structure in above AB type of compounds.
Unit-8 Geometry of AB2 type crystals: Fluorite, antifluorites, Rutile structures. Li2O,
Na2O, CdCl2, CdI2 structures. Zintl-isoelectronic relationship in solids

Block -1.1.3 Title: Modern theories of chemical bonding


Unit-9 Molecular orbital theory, Linear combination of atomic orbitals, Formation of
σ,  and δ molecular orbitals, Molecular orbital energy diagram.
Unit-10 Calculation of bond order, prediction of magnetic properties and stability of
hetero nuclear di-atomic molecules (ex: CO, NO) and linear tri-atomic
molecules (ex: CO2, NO2).
Unit-11 Covalent character in ionic compounds, polarization, dipole moment, Fajan’s
rules, effect of polarization on crystals, effect of polarization on thermal
stability of carbonates and melting points of anhydrous halides.
Unit-12 Metallic bond, Introduction and properties of metallic state, metallic bond,
VB theory of metallic bond, band theory of metallic bond, types of metals
(conductors, semiconductors, and insulators).

Block-1.1.4 Title: Metallic compounds and Metal pi-Complexes


Unit-13 Metal-Metal bonds: Occurrence of metal-metal bond, Classification of metal
clusters, Binuclear, trinuclear, tetranuclear, pentanuclear and hexanuclear
with reference to halide, oxide, alkoxide and acetate clusters, Isopoly,

18
Heteropoly acids and their anions.
Unit-14 Metal carbonyls: structure and bonding, EAN rule, Metal carbonyl clusters
with reference to classification, synthesis,
Unit-15 Vibrational spectra of metal carbonyls for bonding and structure elucidation,
important reaction of metal carbonyls, Synthesis reactions and applications of
Sandwich compounds.
Unit-16 Metal nitrosyls: Nitrosylating agents for synthesis of metal nitrosyls,
vibrational spectra and X-ray diffraction studies of transition metal nitrosyls
for bonding and structure elucidation, important reactions of transition metal
nitrosyls, structure and bonding
Reference Books
1. Inorganic Chemistry, 4th Ed, J. E. Huheey, E.A. Keiter and R. S. Keiter. Addission-Wesley
(1993).
2. Inorganic Chemistry, 2nd Ed, D. F. Shriver, P. W. Atkins and C. H. Langford. Oxford
University Press (1994)
3. Basic Inorganic Chemistry, 3rd Ed, F. A. Cotton, G. Wilkinson and P. L. Gaus, John-Wiley
and sons (1995)
4. Concepts and Models in Inorganic Chemistry 3rd Ed, B. Douglas. D. H. Daniel and J. J.
Alexander, John-Wiley and Sons (1983).
5. Concise Inorganic Chemistry-J. D. Lee, 5th Ed, New Age International (1996).
6. Inorganic chemistry-K. F. Purcell and J .C. Kotz W.B. Saunders San Francisco.

Course 2: Physical Chemistry -1

Block-1.2.1 Title: Fundamentals of thermodynamics


Unit-1 Introduction to three laws of thermodynamics, Entropy and equilibrium,
interpretation of Gibb’s function.
Unit-2 Variation of free energy with T and P, Maxwell’s relations, thermodynamics
equations of states, limitations of Vant Hoffs equation, Nerst heat theorems
and its applications.
Unit-3 Determination of absolute entropies. Application of thermodynamics:
Entropy and free energy of mixing, partial molar quantities, partial molar
volume and free energy (chemicals potential), their significance and

19
determinations (slope and intercept methods).
Unit-4 Gibbs – Duhem and Duhem- Margules equations, Calculations of standard
entropies from Cp data, Problems, Exceptions to third law.

Block-1.2.2 Title: Fundamentals of chemical kinetics


Unit-5 Definition of the terms: molecularity, stoichiometry, order and rate of the
reaction and their relationship, Factors influencing the rate of chemical
reactions, Types of chemical reactions with respect to rate (zero order, first
order and second order), Derivation of rate equation for zero order, first order
and second order reactions, Half-life period.
Unit-6 Derivation of rate equation for third order reaction, Experimental
determination of order of reaction with respect to reactant, Determination of
total order of a reaction, Problems.
Unit-7 Complex and Parallel reaction, Derivation of rate equation for complex and
parallel reactions, Problems.
Unit-8 Consecutive and Reversible reactions, Derivation of rate equation for
consecutive and reversible reactions, Problems.

Block-1.2.3 Title: Introduction to Quantum chemistry


Unit-9 Concept of operator, quantum mechanical operators (Cartesian, Spherical,
polar co-ordinate systems), Properties of quantum mechanical operators,
Postulates of Quantum mechanics.
Unit-10 Wave function, significance of wave function, Time dependent and
independent Schrodinger equation, Progressive and Stationary wave, their
wave equation, well behaved functions, Eigen values and Eigen functions.
Unit-11 Wave equation for a Particle in a one and three dimension box, problem,
Wave equation of harmonic oscillator & the rigid rotator, Born-Oppenheimer
approximation, solution of the Hydrogen-like atom and problems.
Unit-12 Radial and angular wave functions, Angular momentum and electronic

20
structure of atom, General theory of angular momentum, Eigen functions and
Eigen values of angular momentum operators, Spin angular momentum.

Block-1.2.4 Title: Theory of Gases


Unit-13 PVT relations for an ideal gas, non-ideal behavior of gases, Equation of state,
Compressibility factor, Virial equation.
Unit-14 van der Waals equation, excluded volume and molecular diameter, Maxwell-
Boltzmann law for distribution of molecular velocities, problems.
Unit-15 Derivation of expressions for average, root mean square and most probable
velocities, Experimental verification of distribution law, Problems.
Unit-16 Molecular collision in gases, collision diameter and collision number in a gas,
Kinetic theory of viscosity and diffusion, Problems.

Reference Books
1. Physical Chemistry, P. W. Atkins, ELBS, 1998
2. Physical Chemistry, G. M. Barrow, International student edition, 2003.
3. Physical Chemistry, G. W. Castellan, AddisionWeslay.
4. Physical Chemistry, W. J. moore, Orient Longman, 1998.
5. Thermodynamics for Chemist, S. Glasstone, D. Van Nostrand, 1965.
6. Essentials of Nuclear Chemistry, H. J. Arnikar, New Age Publication Ltd., 1995.
7. Nuclear and Radiochemistry, Friedlander, Kennedy and Miller, John-Wiley, 1981.
8. Introduction to Nuclear Physics and Chemistry, B. G. Harwey, Prentice Hall, 1963.
9. Sourcebook of Atomic Energy, S. Glasstone, van Nostrand, 1967.
10. Chemical Kinetics, K. J. Laidler, McGraw Hill, 1985.

Course 3: Organic Chemistry -1

Block-1.3.1 Title: Stereochemistry of organic molecule

Unit-1 Conformation, conformational analysis of saturated and unsaturated acyclic


molecule (Ethane Butane,1,4- butadiol, cis and trans compounds), stability of
cis and trans compounds.
Unit-2 Conformations of cyclic systems up to six membered– conformational
analyses of mono-and di-substituted cyclohexane, conformation and stability
of decalins and perhydro phenentherenes.

21
Unit-3 Configuration, Stereoisomerism, Chirality, Center of chirality, axis of
chirality, plane of chirality and helicity, Enantiomers and diastereomers,
racemic mixture, methods of resolution of racemic mixtures.
Unit-4 Stereochemistry of - allenes, spirans, biphenyls, cyclophanes and helicenes.
Block-1.3.2 Title: Reactive intermediates

Unit-5 Electrophiles and nucleophiles, carbocations, formation, stability and


geometry of carbocation, chemical reactions of carbocations, classical and
non-classical carbocations.
Unit-6 Carbanions, formation, stability and geometry of carbanions , chemical
reactions of carbanions, Free radicals, formation, stability and geometry of
free radicals, diradicals, singlet and triplet diradicals, their reactions and
detection methods
Unit-7 Carbenes and Nitrenes, formation, stability and geometry of carbenes and
nitrenes, chemical reactions of carbenes and nitrenes, singlet and triplet
carbenes, their reactions and detection methods
Unit-8 Formation, stability and geometry of Nitrile oxide, chemical reactions of
nitrile oxide, Synthetic equivalents, Unpolung reactions

Block-1.3.3 Title: Aromatic compounds


Unit-9 Alternant and non-alternant hydrocarbons, Concept of aromaticity, Aromaticity
in benzenoids, Huckels rule, anti-aromatic and non-aromatic compounds
Unit-10 Calculation of energies of different conjugated π-systems in cyclic and acyclic
systems, Calculation of charge densities, PMO theory and reactivity index.
Unit-11 Non benzenoid aromatic compounds, aromaticity in non- benzenoids
compounds, annulenes, hetroannulenes, fullerence-C60, ferrocene.
Unit-13 Azulene, fulvene, tropylium salts, three and five membered systems-Crown
ether complexes, cyclodextrins, cryptands, catenanes and Tropone, tropolone.

Block-1.3.4 Title: Organic substitution reactions


Unit-13 Types of organic reactions (Addition, substitution, elimination and
rearrangement), neucleophiles, electrophiles, nucleophilicity v/s basicity,

22
factors affecting the relative strength of neucleophiles and electrophiles.
Unit-14 Nucleophilic substitution reactions, kinetics, mechanism and stereochemical
factors of SN1, SN2, SNi, reactions. Neighboring group participation, Weldon
inversion, sterochemical outcomes of SN1, SN2 and SNi reactions.
Unit-15 Factors affecting the rate of SN1 and SN2, reactions, substrate effect, solvent
effect, ionic effect, isotopic effect, solvent isotopic effect, substituent effect,
steric effect.
Unit-16 Electrophilic substitution reactions, Kinetics, mechanism and stereochemical
factor of SE1 & SE2 reactions.
Reference books:
1. Organic Chemistry - P.Y. Bruice, Pearson Education Pvt. Ltd., New Delhi (2002).
2. Organic Chemistry - S. H. Pine, McGraw-Hill, London (1987).
3. Organic Chemistry - R.T. Morrison and R.T. Boyd, Prentice Hall, New Delhi(1994).
4. Organic Chemistry - T.W. G. Solomons, 4th Edition, John Wiley and Sons, (1988).
5. Organic Chemistry - F.A. Carey and S.J Sundberg 4th Edition, McGraw Hill (2000).
6. Advanced Organic Chemistry, Reactions, Mechanism and Structure - J. March, 3rd
Edition, Wiley Eastern Ltd. (2004).
7. Stereochemistry – Conformation and Mechanism - P. S. Kalsi, Wiley – Eastern Ltd,
New Delhi (1992).
8. Stereochemistry of Carbon Compounds, Ernest L Eliel, T M H edition,1994
9. Stereochemistry of Organic Compounds, D. Nasipuri,Newage International, 1991
10. Guidebook to Mechanism in Organic Chemistry - P. Sykes. Orient Longman, London,
2nd edition, ( 2002).
11. Organic Chemistry, Jonathan Clayden, Nick Geeves, Stuart Warren, 2nd Edition,
2012
Course 5: Chemical Spectroscopy
Block-1.5.1 Title: Microwave spectroscopy
Unit-1 Introduction to electromagnetic radiation, Properties of electromagnetic
radiation, Relation between Wavelength, Frequency, Wavenumber and
Energy, and their units, Regions of the electromagnetic spectrum, energies
corresponding to various kinds of radiation. Interaction of electromagnetic
radiation with matter (absorption, emission, transmission, reflection,
dispersion, polarisation and scattering)
Unit-2 Energy levels in atom and molecule, total energy of a molecule, transition
moment integral, selection rules. Classification of polyatomic molecules.
Unit-3 Rotation spectra of diatomic molecules, rigid and nonrigid rotators, Rotational
quantum number and selection rules, Effect of isotopic substitution on rotation
23
spectra, problems.
Unit-4 Relative intensities of spectral lines, Applications to determination of bond
length and moment of inertia of diatomic molecule, problems

Block-1.5.2 Title: Vibration spectroscopy


Unit-5 Vibration of diatomic molecules, vibrational energy curves of simple
harmonic oscillator. Effect of anharmonic oscillator, Vibration-rotation
spectra of carbon monoxide, Problems.
Unit-6 Fundamental and overtone frequencies. Vibration of polyatomic molecules-
degree of freedom of vibrations. Parallel and perpendicular vibrations (CO2
and H2O), Problems
Unit-7 Intensity of absorption band and types of absorptions. Important spectral
regions – hydrogen stretching region, double and triple bands region,
fingerprint region, Problems.
Unit-8 Applications for XY2 - linear, XY3 – planar. Factors affecting the group
frequency – electrical effect, hydrogen bonding, sterric and ring strain.

Block-1.5.3 Title: Raman and Electronic spectroscopy


Unit-9 Raman spectroscopy – Introduction, Raman and Rayleigh scattering, Stokes
and antistokes lines, polarization of Raman lines, depolarization factor,
polarizability ellipsoid.
Unit-10 Theories of Raman spectra – classical and quantum theory, Rotation-Raman
and vib-Raman spectra, Comparison of Raman and IR spectra, rule of mutual
exclusion princilple, Advantages of Raman spectra.

Unit-11 Electronic spectroscopy- Introduction – Beer’s law. Theory of molecular


absorption, Frank-Condon principle, Fluorescence and phosphorescence,
intersystem crossing, Vibration-rotation, fine structure of absorption bands: σ
→ σ*, π → π*, n → σ*, n → π*.

Unit-12 Solvent effect on the spectral lines. Empirical rules for predicting the wave
length of maximum, - olefins, conjugated dienes, ketones and substituted
benzene

24
Block-1.5.4 Title: Optical and Electrochemical spectroscopy
Unit-13 Atomic absorption spectroscopy: Principle. Atomic energy levels. Grotrian
diagrams, Population of energy levels, Instrumentation. Sources: Hollow
cathode lamp and electrodeless discharge lamp, factors affecting spectral
width. Atomizers: Flame atomizers, graphite rod and graphite furnace.
Unit-14 Cold vapour and hydride generation techniques. Factors affecting atomization
efficiency, flame profile, Monochromators and detectors, Beam modulation.
Detection limit and sensitivity, Interferences and their removal, Comparison
of AAS and flame emission spectrometry, Applications of AAS.

Unit-15 Stripping Voltammetry: Principle and technique in anodic and cathodic


stripping voltammetry, applications to metal ion analysis, limitations.
Adsorptive stripping voltammetry: Principle, technique, applications to metal
ions and organic analysis. Advantages over anodic stripping voltammetry.
Catalytic effects in voltammetry. Working electrodes: Mercury electrodes,
carbon electrodes, film electrodes.

Unit-16 Cyclic voltammetry: Principle and technique, Randles-Sevcik equation,


Interpretation of voltammogram- reversible, irreversible and quasi-reversible
systems, Applications of cyclic voltammetry in study of reaction mechanism
and adsorption processes.

Second Semester
Course 6: Inorganic chemistry-II
Block-2.6.1 Title: Modern theory of Acid-Base and non-aqueous solvents
Unit-1 Arrhenius concept, Lux-Flood and Usanovich concepts, Bronsted-Lowry,
theory, Lewis concepts, General theory of solvent system.
Unit-2 Measures of acid-base strength, Acid-base interactions, Hard and soft acids
and bases, Classification, HSAB principle and its applications, Irving-
William series.

25
Unit-3 General properties of ionizing solvents (dielectric constant, donor and
acceptor property), Solutions of metals in Liquid ammonia, hydrated
electron, Super acids.
Unit-4 Liquid Ammonia, Liquid sulphur dioxide, liquid dinitrogen tetra oxide,
liquid hydrogen fluoride, and liquid bromine trifluoride as solvents.

Block-2.6.2 Title: Co-ordination compounds


Unit-5 Introduction, definition of terms, classification of ligand, chelation effect,
Preparative methods of coordination compounds- simple addition reactions,
substitution reactions, oxidation-reduction reactions, thermal dissociation
reactions, reactions of coordinated ligands
Unit-6 Valence bond theory (VBT) of coordination compounds, Formation of
Tetrahedral, octahedral and square planar complexes on the basis of VBT.
Unit-7 Outer orbital and inner orbital octahedral complexes, limitations of VBT,
Geometries of metal complexes of higher coordination numbers
Unit-8 Isomerism in coordination compounds, geometrical isomerism, optical
isomerism, study of isomerism in coordination compounds using CD, ORD,
Cotton effect and magnetic circular dichroism,

Block-2.6.3 Title: Crystal Field Theory (CFT)


Unit-9 Crystal Field Theory, Salient features of CFT, Splitting of d-orbital in
tetragonal, octahedral, square planar and trigonal bipyramid complexes
Unit-10 CFSE, measurement of 10Dq, Factors affecting 10Dq, Spectrochemical
series, Nephelauxetic effect, d-d transitions and color of coordination
compounds, limitations of CFT, Problems.
Unit-11 High spin and low spin complexes; magnetic moments of high spin and low
spin complexes, John-Teller effect and John-Teller distortion in metal
complexes and metal chelates, spectroisomerism.
Unit-12 Application of crystal field theory and prediction of magnetic and spectral
properties of the co-ordination compounds, Spectra of aqua complexes of
trivalent V, Cr divalent Mn, Co Ni and Co 3d-metal ions, Calculation of
10Dq , B and β parameters, charge-transfer spectra.

26
Block-2.6.4 Title: Organometallic chemistry
Unit-13 Introduction, Nomenclature and general characteristics, hapticity,
classification of organometallic compounds based on hapticity and polarity
of M-C bond, stability and decomposition pathways, 16 and 18 electron
rules, electron counting, covalent and ionic models.
Unit-14 Synthesis, structure and applications of organometallic compounds of main
group elements, (Li, Mg, Ca, B and Al), and d-group elements (Cu, Zn, and
Co), Group trends.
Unit-15 Compounds with Metal-carbon multiple bonds, Alkylidenes, alkylidynes,
synthesis, structure bonding, reactions and their role in organic synthesis.
Unit-16 Transition metal π-complexes: transition metal π- complexes with
unsaturated organic molecules, alkenes, alkynes, allyl, diene,
cyclopentadienyl, arene, cyclooctatrienyl, cyclooctatetraene complexes and
their decomplexaion reactions.

Course 7: Physical Chemistry-II [HCT-P02]


Block-2.7.1 Title: Theories of Chemical kinetics
Unit-1 Collision theory and its application to reactions in solution, limitations,
problems.
Unit-2 Activated complex theory and its application to reactions in solution, Energy
of activation, activation parameters-determinations and their significance,
problems.
Unit-3 Lindemann theory of uni-molecular and bi-molecular reactions, Problems.
Unit-4 Factors affecting the order of reaction – primary and secondary salt effects.
Effects of dielectric constant, pressure and volume on the rate of reaction,
Problems.

Block-2.7.2 Title: Quantum mechanics


Unit-5 Radial and angular wave functions, Angular momentum and electronic
structure of atom, General theory of angular momentum. Eigen functions
and Eigen values of angular momentum operators, Ladder operators, Spin

27
angular momentum, anti- symmetry and Pauli's principle,
Unit-6 Wave functions of poly-electron atoms, Slater determinant, Approximation
methods- Necessity of approximation methods
Unit-7 Perturbation methods- first order correction, application to He-atom (first
order correction only) calculation of first ionization potential and binding
energy.
Unit-8 Variation theorem- Statement and proof, application variation methods to
particle in one dimensional box, linear oscillator, coupling of angular
momentums.

Block-2.7.3 Title: Statistical thermodynamics


Unit-9 Introduction, Concepts of distribution, thermodynamic probability and most
probable distribution, Ensemble, postulates of ensemble overlapping,
coninical, grand coninical and micro coninical ensembles.
Unit-10 Maxwell-Boltzmann distribution law, Maxwell’s distribution of molecular
velocities, Maxwell-Boltzmann statistics and applications, Bose-Einstein
and Fermi-Dirac statistics.
Unit-11 Partition functions – definitions and separations, evaluation of translational,
rotational, vibrational and electronic partition functions for monoatomic,
diatomic and polyatomic gases molecules.
Unit-12 Calculation of thermodynamic functions and equilibrium constant in terms
of partition functions, entropy of monoatomic gas – Sacker-Tetrode
equation, comparison of 3rd law and statistical entropies, Heat capacity
behavior of solids.

Block 2.7.4 Title: Surface and colloidal chemistry


Unit-13 Definition of absorption and adsorption, adsorption of gases on solid, factors
influencing adsorption (temperature, pressure and pH) Langmuir adsorption
for uni molecular and bi molecular reactions.
Unit-14 Adsorption forces, thermodynamics of physical adsorption, heat of
adsorption and its determination, measurement of adsorption by different
methods, chemisorptions and its mechanism.
Unit-15 Multilayer adsorption – critical comparison of various multilayer models-
28
BET, Potential and Polanyi models (no derivation). Measurement of surface
area of solids by different methods, Harkins and Jura equation.
Unit-16 Porous solids – Defination, pore size distribution, methods to determine pore
size, hysteresis of adsorption, theories of hysteresis, Adsorption behaviors of
porous materials.

Course 8: Organic chemistry-II


Block-2.8.1 Title: Elimination and free radical reactions and their mechanisms
Unit-1 Elimination reactions, kinetics, mechanism and stereochemical outcome, and
factor affecting the rate of E1, and E2, reactions.
Unit-2 E1cb reactions, mechanisms of cis and trans eliminations, Hofmann and
Saytzeff and Chugaev eliminations reaction.
Unit-3 Competition between elimination and substitution reactions, solvent effect,
ionic effect, isotopic effect, solvent isotopic effect, substituent effect, steric
effect on elimination and substitution
Unit-4 Types of free radical reactions, free radical substitution mechanism,
neighboring group assistance. Reactivity of aliphatic substrates at a bridgehead.
Reactivity in attacking radicals.

Block-2.8.2 Title: Aromatic substitution reactions and their mechanisms


Unit-5 Aromatic Electrophilic Substitution: Mechanism and Orientation in
Electrophilic Aromatic Substitution, An Addition-Elimination Mechanism,
Ortho, Meta and Para Orientation, Relative Rates of Substitution, the Rate
Orientation Relation, Orientation in Multiply Substituted aromatics
Unit-6 Arynes: Formation, structure, stability, and reactivity, examples of reactions
involving aryne and nitrile oxide intermediates.
Unit-7 Nucleophilic Aromatic Substitutions, The elimination-addition
mechanismbenzyne. The aryl cation mechanism- diazonium salts, Nucleophilic
Substitution via Thallium derivatives
Unit-8 Free radical reactions mechanism at an aromatic substrate, arylation of
aromatic compounds by diazonium salt, Sandmeyers reaction. Free radical

29
rearrangement, Hunsdiecker reaction.

Block-2.8.3 Title: Reagents in organic reactions


Unit-9 Use of Soadamide (NaNH2), Trimethylsilyl iodide (Peterson’s synthesis),
Titaniumchloride, titaniuiopropoxide, Phase transfer catalysts: Quaternary
ammonium and phosphonium salts, Crown ethers, Misceller Catalysis, in
organic synthesis
Unit-10 Use of Born trifluoride (BF3), N-Halosuccinimides (NBS and NCS),
Diazomethane, Sodiumcyanobrorohydride (NaCNBH3),
Trifluoromethanesulfonic anhydride (CF3SO2)2O, Diisobutylaluminium
hydride (DIBAL), N-Methoxy-N-methylamides (Weinreb amides)
Unit-11 Use of Lead tetra acetate (Pb(OAc)4, Periodic acid H5IO6 or HIO4.2H2O,
Se2O, MCPBA, Bu3SnH, Me3SiCl, Me3SiH, OsO4. DDQ, O3 in organic
synthesis
Unit-12 Use of Organo-zinc and organomercury and organotin reagents,
lithiumdialkylcuprate (Gilman’s reagent) and their addition to acylhalides and
unsaturated carbonyl compounds, Wilkinson’s and Ziegler-Natta Catalyst in
organic synthesis.

Block-2.8.4 Title: Types of organic reactions


Unit-13 Oxidation reactions olifins: Dehydrogenation with S, Se, Fremy’s salt,
chloranil, Woodward and Prevost dihydroxylation, Oxidation of alcohols:
pyridinium chlorochromate (PCC), pyridinium dichromate (PDC), Collin and
Jones reagent, Combination of DMSO with DCC, (COCl)2, NCS and
(CH3CO)2O, Oxidation with MnO2,
Unit-14 Oxidation of aldehydes and ketones, Oppenauer oxidation. Conversion of
ketones to α, β-unsaturated ketones and α-hydroxy ketones, Baeyer-Villiger
oxidation, Dess-Martin periiodinane, IBX.
Unit-15 Reduction reactions, (i) Reduction of aldehydes and ketones with complex
metal hydride [LiAlH4 and NaBH4], (ii) Reduction of conjugated systems:
reduction by dissolving metals (Birch reduction), (iv) Miscellaneous
reduction reactions
Unit-16 Catalytic heterogeneous and homogeneous hydrogenation (Wilkinson’s

30
catalyst), Hydrogenation of alkenes, alkynes and arenes, Selectivity of
reduction, Mechanism and stereochemistry of reduction, Raney Ni-catalyst,
Adam catalyst, Lindlar catalyst
Reference books:
1. Organic reaction mechanisms (II edition), 1995 - V. K. Ahluwalia & R. K.Parasar
2. Organic reaction Mechanism, Singh and Mukherjee, Mc millan 3rd ed, 2000.
3. Reaction mechanism and reagents in organic chemistry, 2nded ,1991-Gurdeep R.
Chatwal
4. Organic chemistry (VI edition),2001 - Morrison Boyd.
5. Organic chemistry – I.L. Finar, Vol.1, 3rd edition,1975
6. Organic chemistry - (VII edition), 2008 - Mc Marry)
7. Advanced organic chemistry (IV edition), 2001 – J March
8. Reaction mechanisms and problems in organic chemistry 2nd edition 2001 – P.
Chattopadhyay
9. Reactive intermediates in organic chemistry 1st Edition, 2001 - J. P. Trivedi
10. Principles of reaction mechanism in organic chemistry – Parmar & Chawla, Ed. II,
1978.
11. Organic Photochemistry2nd Edition ,1984 - J. Coxon & B. Halton
12. Advanced organic chemistry Part B – F.A. Carey & R. J. Sundberg Ed II, 1990 .
13. Organic Chemistry - P.Y. Bruice, Pearson Education Pvt. Ltd., New Delhi (2002), Ed
III

31
Course 10: Organic spectroscopy
Block-2.10.1 Title: Ultraviolent (UV) and Infrared( IR) spectroscopy for organic
molecule characterization
Unit-1 Ultraviolent (UV) spectroscopy: Introduction, Absorption Laws, Molar
absorptivity, Instrumentation, sample handling, theory of UV-Visible
spectroscopy.
Unit-2 Electronic transitions, Formation of absorption bands, types of absorption
bands, transition probability, allowed and forbidden transitions, conjugate
systems and transition energies.
Unit-3 Chromophore, Auxochrome, absorption and intensity shift, solvent effect,
Woodward and Fisher rules for calculating max in conjugated dienes and
trienes.
Unit-4 Calculating max inunsaturated carbonyl compounds, unsaturated
carboxylic acids and esters, benzene and its derivative, applications of UV-
Visible spectroscopy, Problems.

Block-2.10.2 Title: Nuclear magnetic resonance (1HNMR) spectroscopy for organic


molecule characterization
1
Unit-5 H NMR spectroscopy: Introduction, nuclear spin, energy absorption &
relaxation. Basic ideas about instrument, sample handing, chemical shift
magnetic anisotropy, Shielding deshielding,
Unit-6 Measurement chemical shift, NMR scale, factors affecting it, magnetic
anisotropy, Equivalent and non equivalent protons, number of PMR signals,
Unit-7 spin-spin splitting, coupling constant (J), nomenclature of spin system, First
order & non first order splitting for two, three & four interacting nuclei,
Magnetic equivalence, spin-spin coupling of proton with other nuclei,
32
Unit-8 Protons on heteroatoms, proton exchange reactions, simplification of
complex NMR spectra (lanthanide shift) Nuclear Overhauser effect (NOE),
analysis (interpretation) of NMR spectra.

Block-2.10.3 Title: (13CNMR) and Mass spectroscopy for organic molecule


characterization
13
Unit-9 C NMR spectroscopy, introduction and theory, C-C and C-H spin-spin
coupling, effect of deuterium substitution on CMR signals, Proton decoupled
13
C NMR, chemical shift equivalence.
Unit-10 , 13C chemical shift, factor affecting 13C chemical shift, use of shift reagents,
some solved examples
Unit-11 Mass spectroscopy, Introduction, Instrumentation, Ionization methods,
Molecular and fragment ions, mass spectrum and base peak, nitrogen rule,
metastable ions, multicharged ions,
Unit-12 Recognition of molecular ion peak and detection of isotopes, factors
governing general fragmentation process, fragmentation modes of various
classes of organic compounds, solved problems.

Block-2.10.4 Title: Infrared(IR) Spectroscopy for organic molecule characterization


Unit-13 Infrared(IR) Spectroscopy, Introduction, Instrumentation, sampling handling,
theory of infrared spectroscopy, number of fundamental vibrations,
calculation of virational frequencies,
Unit-14 Characteristic absorptions in common classes of organic compounds,
Fingerprints region, factors affecting the vibrational frequencies,
Unit-15 Applications of infrared spectroscopy to solve the structure of organic
molecule.
Unit-16 Photoelectron Spectroscopy Basic principles of photoelectric effect
ionization. Process, PES and XPS photo-electron spectra of O2, N2 and NO
(simple molecule). Adiabatic and vertical ionization energy, Koopman’s
theorem.

33
Third Semester
Course 11: Materials Chemistry
Block 3.11.1 Title: Hi-tech materials:
Unit-1 Solar cells (Photovoltaic cell), types of Solar cells. perovskites Solar cells,
super conducting materials, supercondcutivity in cuprates, isotropic and
anyzotropic materials, Thin films, Langmuir–Blodgett films, Preparation
techniques, sputtering, chemical process, sol gel, Photolithography,
Applications of LB films. Rectifiers, transistors, capacitors.
Unit-2 Solid State Reactions: General principle, types of reactions: Additive,
decomposition and phase transition reactions, tarnish reactions, kinetics of
solid state reactions, factors affecting the solid state reactions, photographic
process.
Unit-3 Nanoparticles and Nanostructural materials: Introduction, methods of
preparation, physical properties, and chemical properties, sol-gel chemistry of
metal alkoxide, application of Nanoparticles, Charecterization of
Nanoparticles by SEM and TEM. Nanoporous Materials:
Introduction, Zeolites and molecular sieves, determination of surface acidity,
porous lamellar solids,composition-structure, preparation and applications.
Unit-4 Smart Materials: Definition of smart materials (SM), Design of intelligent
materials, actively smart and passively smart materials and their
characteristics. e.g. - smart ceramics, oxides, smart polymers and gels, shape
memory alloys, electorheological fluids, ferrofluides, smart windows, smart
sensors, smart electroceramics, Magnetostrictive materials, biomineralisation
and biosensing.

34
Block-3.11.2 Title: Homogeneous and Heterogeneous catalysis
Unit-5 Introduction, basic principle, industrial requirements, thermodynamic and
kinetic aspects, classification of catalytic system.
Unit-6 Principle, experimental techniques, acid-base catalysis, catalysis involving
transition metal salts and metal complexes- hydrogenation, asymmetric
hydrogenation, transfer hydrogenation, hydrosilation and hydrocyanation.
Unit-7 Fisher- tropsch process, Acrylonic synthesis using mixed metal oxides,
alcohol, dehydration on γ-elimination reaction of olefin on zinc oxide.
Unit-8 Anchored catalysis- merits, polymer and metal oxides as supports, Zeolites as
shape selective catalysts, Clays as catalyst, pillavd clays- advantages,
decomposition of isopropanol using oxide catalyst, catalytic converter.

Block-3.11.3 Polymer Chemistry


Unit-9 Basic concepts of polymer science, classification of polymers as biological -
nonbiological, linear branched network, condensation, addition homo- and
heterochain, thermoplastic- thermosetting, molecular forces and chemical
bonding in polymers degree of polymerization, polydispersity of polymers,
Natural and synthetic polymers.

Unit-10 Solubility of polymers, Thermodynamics of polymer solutions - Entropy


and heat of mixing of polymer solutions - ideal behaviour and deviations.
Experimental results, flory – Krigbaum theory - Thermochemistry of chain
polymerization. Morphology and rheology of polymers - configuration of
polymer chains crystal structure, crystallization processes, viscous flow,
rubber elasticity, viscoelasticity.
Unit-11 Types of polymerization: Ionic, coordination and ring opening
polymerization, Copolymerization - Kinetics of copolymerization, the
copolymer equation, monomer reactivity ratios, instantaneous composition
of polymer. Polymer structure and physical properties - The crystalline
melting point Tm- the glass transition temperature (Tg ) - properties
involving small and large deformations- polymer requirements and polymer
utilization.
Unit-12 Average molecular weight concepts- Number, weight and viscosity average
molecular weight, Determination of molecular weights – viscosity method,
osmotic pressure method and light scattering method. . Conducting polymers
- Basics, synthesis, conduction mechanism, applications.

35
Block-3.11.4 Title: Chemistry of p block elements

Unit-13 Inorganic chain catenation, hetero catenation, silicate minerals, intercalation


chemistry, and one dimensional conduction.

Unit-14 Inorganic rings: Borazines, Phosphazenes, phosphazene polymer, Homo


cyclic and heterocyclic inorganic ring system.

Unit-15 Cage structure, phosphorus cage molecules, Boron cage molecule, Boranes
Carboranes, and metellocarboranes.

Unit-16 Interhalogen compounds, polyhalides, chemistry of halogen oxides and


oxyfluorides, oxyacids of heavier halogens, pseudohalides.

Course 12: Bio-inorganic and Bio-physical


chemistry
Block 3.12.1 Title: Chemistry of essential elements
Unit-1 Essential and trace elements in biological process, elements in biological
cell, bio molecules associated with metal ions and their roles, Molecular
mechanism of ion transport across cell membranes, ionophores, crown
ethers, Na+/K+ pump.
Unit-2 Metal ion deficiency, toxicity, detoxification Chelation therapy, Importance
of Ca2+ in muscle contractions and in blood clotting process, Metal ligand
interactions with DNA, Transition metal complexes as chemical nucleases,
Nuclease activity of Cu-(o-phen)2+metal complexes used in anticancer and
antiarithritic drugs.
Unit-3 Metallo proteins, metello enzymes, Transport and storage of Oxygen, Heme
protein, Hemoglobin and myoglobin, dioxygen bonding, model complexes.
Non-heme iron

36
Unit-4 Metal ion storing and transfer-ferritin, transferr in and siderophores,
Photosynthesis, structure of chlorophyll, PS1 and PS II in cleavage of water.

Block-3.12.2 Title: Metelo enzymes


Unit-5 Structure and functions of metalloproteins in electron transfer process.
Cytochromes, ferridoxins and rubredoxins. Cytochrome-C and Cytochrome-
C oxidase.
Unit-6 Zinc enzymes- carboxy peptidase, copper enzymes Xanthine oxidase. Iron
enzymes, Cytochrome P-450, Vit B12 co enzymes & model compounds,
Actions of Cobalamines, Adenosylcobalamine as a coenzyme,
Ribonucleotide reductase, Methylcobalamine as cofactor, Mo-cofactors,
Antagonism between Cu & Mo Hydroxylase
Unit-7 Nitrogen fixation: Nitrogenase –bacterial nitrogenise synthesis and synthetic
studies. Photosynthesis: structure of chlorophyll, PS1 and PS II in cleavage
of water.
Unit-8 Biochemistry of chromium and Vanadium, Vanadium proteins including
bromoperoxidases, Glucose Tolerance Factor, Vanadium Nitrogenase,
Vanadium as possible insulin modifiers, Characterization of insulin mimetic
effect, Sites of action of vanadium, toxicological considerations, and
improved tissue uptake.

Block 3.12.3 Title: Bioenergetics and Thermodynamics


Unit-9 The cell and its constituents, molecular basis of life, Colloids, Classification
of colloids, properties of colloidal solutions, coagulation of colloidal
solutions. Size of biopolymers, Methods of determining particle shape and
molecular weight, Interactions with water.
Unit-10 Molecular interpretation of Energy and Enthalpy, Non-covalent reactions,
hydrophobic interactions, Biochemical Applications of Thermodynamics,
Thermodynamics of Metabolism, Double Stranded Formation in Nucleic
Acids, Ionic Effect on Protein–Nucleic Acid Interactions
Unit-11 Basic Concepts of Enzyme kinetics, catalytic antibodies and RNA enzymes
Ribozymes, Michaelis Menten Kinetics, Competition and Inhibition, Monod-

37
Whyman Changeux Mechanism, Substrate as inhibitors, effect of Cr3+, Fe2+,
Zn2+ zeolite, UV-light on enzyme catalyzed reactions.
Unit-12 Polymerization of DNA and nature of blood flow through different vessel,
Detection of intrastrand disulphide bonds in proteins, Gel electrophoresis,
DNA Sequencing, DNA Finger Printing, Conformations of Nucleic Acids,
Protein Charges.

Block 3.12.4 Title: Biophysical process


Unit-13 Lipid Molecules and Bilayer Phase Transitions in Lipids, Bilayers and
Membranes, Biological Membranes, Membrane Equilibrium, Transport
through cell membrane, Active and Passive Transport, Osmosis and
Diffusion, Energy Generation. Nerve Cells, Neutron: Structure and Functions,
Nerve Impulse and its conduction,
Unit-14 Biological significance of Donnon membrane phenomena, micells and its
involvement during digestion and absorption of dietery lipids. Difference of
solvents across bio membranes and its application of solvents across bio
membranes and its application in the mechanism of respiratory exchange,
Bio-electrochemistry: Threshold membrane phenomena, Nernst Plank
equation, Hodges Huxley equations, core conductor models,
electrocardiography.
Unit-15 Electrical double lever, theories of double layer, electro-capillary phenomena,
electro-capillary curve, Electro-osmosis, electrophoreses, Streaming and
Sedimentation potentials, Zeta potentials and its determination by
electrophoresis, influence of ions on Zeta potential.
Unit-16 Salting in and salting out of proteins, osmotic behaviour of cells and asmo-
regulation and its application in coordination of excretory system of
organism, Significance of viscosity in biological systems, Effect of
temperature and pH on the viscosity of bio molecules (albumin solution),
Mechanism of muscles contraction, Biological significance of surface tension,
Effect of temperature, solute concentration (Aminoacids) on surface tension,
Interfacial tension in living cells (Danell and Davson model),

1. Uses of Inorganic Chemistry in Medicine Ed. Nicholas. P. Farrel


38
2. Metal Complexes as drugs and Chemotherapeutic agents. N. Farrell, Comprehensive
Coordination Chemistry II, Volume 9, pp 809–840.
3. The biological Chemistry of the Elements: The Inorganic Chemistry of Life–J. J. R.
Fraustoda Silva and R. J. P. Williams. Clarendron Press, Oxford, 1991.
4. Bioinorganic Chemistry: Inorganic elements in the Chemistry of life. An Introduction
and Guide—Wolfgang Kaim, Brigille Schwedrski John Wiley and sons, 1994.
5. Principles of Bioinorganic Chemistry –S. J. Lippard and J. M. Berg, University
Science Books, 1994.
6. Bioinorganic Chemistry: A ShortCourse-RosetteM.Malone3 Wiley Interscience,
2002.
7. Biological Inorganic Chemistry-An Introduction, Robert Crichton, Elsevier Science,
2007.
8. The biological Chemistry of the Elements: The Inorganic Chemistry of Life–J. J. R.
Fraustoda Silva and R. J. P. Williams. Clarendron Press, Oxford, 1991.
9. Bioinorganic Chemistry: Inorganic elements in the Chemistry of life., An Introduction
and Guide—Wolfgang Kaim, Brigille Schwedrski John Wiley and sons, 1994.
10. Principles of Bioinorganic Chemistry –S.J. Lippard and J.M.Berg, University Science
Books, 1994.
11. The Biological Chemistry of the Elements: The Inorganic Chemistry of Life– Silva, J.
J. R. Fraustoda and R. J. P. Williams; 2nd Ed. Oxford University Press, 2012.

Course 14: Analytical Chemistry


Block-3.14.1 Title: Introduction and statistical analysis
Unit-1 Introduction to analytical chemistry: Types of analysis-qualitative and
quantitative, Classification of analytical methods- classical and instrumental,
basis of their classification with examples.
Unit-2 Statistical analysis and validation: Errors in chemical analysis. Classification
of errors: systematic and random, additive and proportional, absolute and
relative, Accuracy and precision, Mean, median, average deviation and
standard deviation.
Unit-3 Significant figures and rules to determine significant figures, Calculations
involving significant figures, Confidence limit, correlation coefficient and
regression analysis.
Unit-4 Comparison of methods: F-test and T-test, Rejection of data based on Q-test,
Least squares method for deriving calibration graph, Numerical problems.

Block-3.14.2 Title: Classical methods of analysis


Unit-5 Volumetric analysis: General principle. Criteria for reactions used in
titrations, Primary standards and secondary standards, Theory of indicators,

39
Types of titrations with examples- Acid-base, precipitation, redox and
complexometric.
Unit-6 Titration curves for monoprotic and polyprotic acids and bases, Indicators
used in various types of titrations, Masking and demasking agents.
Unit-7 Gravimetric analysis: General principles and conditions of precipitation,
Concepts of solubility, solubility product and precipitation equilibria, Steps
involved in gravimetric analysis. Purity of precipitate: Co-precipitation and
post-precipitation.
Unit-8 Fractional precipitation, Precipitation from homogeneous solution, Particle
size, crystal growth, colloidal state, aging and peptization phenomena,
Ignition of precipitates.

Block-3.14.3 Title: Electrochemical methods of analysis


Unit-9 Conductometry: Concepts of electrical resistance, conductance, resistivity
and conductivity, Specific, molar and equivalent conductance and effect of
dilution on them, Measurement of Conductance.
Unit-10 Kohlrausch’s law, Applications of conductometry in determination of
dissociation constant, solubility product, Conductometric titrations, High
frequency titrations, Numerical problems.
Unit-11 Potentiometry: Circuit diagram of simple potentiometer, Indicator
electrodes: hydrogen electrode, quinhydrone electrode, antimony electrode
and glass electrode. Reference electrodes: Calomel electrode and Ag/AgCl
electrode.
Unit-12 Theory of potentiometric titrations, Nernst equation, standard electrode
potential, Determination of cell potential, n, Kf and Ksp. pH titrations,
Buffers and buffer capacity, pH of buffer mixtures based on Henderson-
Hasselbalch equation.

Block-3.14.4 Title: Electrochemical methods of analysis


Unit-13 Chromatography: Definition and Classification, Techniques used in Paper,
Thin Layer and Column chromatography, Applications in qualitative and

40
quantitative analysis.
Unit-14 Gas Chromatography: Principle including concept of theoretical plates and
van-Deemter equation. Instrumental set up- carrier gas, sampling system,
column and detector, Types of columns, their advantages and limitations.
Detectors in GC analysis. Temperature programmed GC. Factors affecting
retention, peak resolution and peak broadening.
Unit-15 Liquid chromatography: Principle, Instrumentation, Advantages and
applications of HPLC. Types of columns and detectors. Principle and
applications of size exclusion, gel permeation, ion retardation, normal phase
and reverse phase chromatography
Unit-16 Ion exchange: Principle and technique, Types of ion exchangers, Ion
exchange equilibria, Ion exchange capacity, Effect of complexing ions,
Zeolites as ion-exchangers, Applications.

Course 15: Inorganic chemistry special [30IS]


Block-3.15.1 Title: Ligand field theory [Molecular orbital theory (MOT)]
Unit-1 Introduction, evidence for metal-ligand covalence, MOT to octahedral,
tetrahedral and square planar complexes without and with pi-bonding,
limitations of MOT.
Unit-2 Electron transfer reactions. Types of electron transfer reactions, conditions
of electron transfer, and mechanism of one-electron transfer reactions.
Unit-3 Outer sphere and inner sphere mechanisms, two electron transfer reactions
complimentary and non-complimentary reactions.
Unit-4 Tunneling effect, cross-reaction, Marcus-Hush theory, bridged activated
mechanism.

Block-3.15.2 Title: Reaction mechanisms of coordination compounds


Unit-5 Reactivity of metal complexes, Inert and Labile complexes, Kinetics of
Octahedral substitution (SN1& SN2), Acid hydrolysis, factors affecting acid
hydrolysis, Stereochemistry of intermidiates in SN1& SN2 reaction.
Unit-6 Base hydrolysis, Conjugate base mechanism, Direct and indirect evidences
in favour of conjugate mechanism, Annation reaction, reaction without

41
metal-ligand bond breaking.
Unit-7 Substitution reaction in square planer complexes: the trans effect, cis effect,
steric effect, solvent effect, effect of leaving group, effect of charge, effect
of nucleophile, effect of temperature.
Unit-8 Trans effect theories, uses of trans-effect, Mechanism of substitution
reactions in Pt(II) complexes, application of trans effect in synthesis of new
complexes, Mechanism of redox reactions, inner sphere and outer sphere
mechanisms.

Block-3.15.3 Title: Magnetic and spectral Properties of coordination compounds


Unit-9 Magnetic susceptibility, types of magnetic behavior, diamagnetic
corrections, orbital contributions, spin-orbit coupling, determination of
magnetic susceptibility, ferro and anti ferro magnetic complex, spin cross.
Unit-10 Spectroscopic ground states, determining the Energy terms, Spin-orbit (L-S)
coupling scheme, terms symbols for dn ions
Unit-11 Racal parameters, Orgel correlation and Tanabe-Sugano diagrams, Laporte
‘orbital’ selection rule, spin selection rule, Hund’s rule, Hole Formulation,
Orgel diagrams for octahedral metal complexes.
Unit-12 Charge transfer spectra of transition metal complexes, Racah parameters,
calculations of 10Dq, B, β parameters, Tanabe-Sugano Diagrams of
octahedral complexes with d2 & d8 configuration.

Block-3.15.4 Chemistry of coordination compounds


Unit-13 Metal – Ligand Equilibria in Solution: Stability of coordination compounds,
Stepwise and overall stability constant, Trends in stepwise formation
constants;
Unit-14 Factors affecting stability of metal complexes with reference to nature of
metal ion, ligand, chelate effect and thermodyanamic origin, Determination
of formation constant by: spectrophotometric method (Job’s and Mole ratio
method) and Potentiometric method (Irving-Rossotti Method).
Unit-15 Liquid Crystals: Mesomorphic behaviour, thermotropic liquid crystals,
positional order, bond orientational order, nematics & smectic mesophases;

42
smectic-Nematic transition clearing temperature-homeotrpic, planer &
schlieren textures twisted nematics, chiral nematics, molecular arrngement
insmectic A & smectic C phases.
Unit-16 Optical properties of liquid crystals. Dielectric susceptibility & dielectric
constants. Lyotropic phases & their description of ordering in liquid crystals.

Course 15: Physical chemistry special [30PS]


Block-3.15.1 Title: Electrochemistry
Unit-1 Arrhenius theory of strong and weak electrolytes and its limitations, Debye-
Huckel theory of strong electrolytes, Debye-Huckel-Ousager equation.
Unit-2 Activity co-efficient, Debye-Huckel limiting equation for activity co-
efficient, Debye-Huckel equation for appreciable concentrations, Problems.
Unit-3 Electrical double layer, Brief survey of Helmoltz-Perrin, Gouy-Chapman
and Stern electrical double layer (derivation), Liquid Junction potentials and
its determination.
Unit-4 Transport numbers, Determination of transport number by Hittorf method
and emf method, True and apparent transport numbers, abnormal transport
numbers, effect of temperature and concentration on transport number.

Block 3.15.2 Title: Electrochemistry of solutions

Unit-5 Metal/Electrolyte interface: Reversible and irreversible electrodes, Reversible


and irreversible cells, Reversible Irreversible electrode process, Polarization,
overvoltage- Ohmic overvoltage, concentration overvoltage and activation
overvoltage, Experimental determination of overvoltage.

Unit-6 Equation for concentration over potential, diffusion-current, stationary-


current, potential-current, thickness of diffusion layer, diffusion controlled
current, dropping mercury electrode, half-wave potential.

Unit-7 Polorography and its application in quantitative and qualitative analysis,


Butter-Volmer equation under near equilibrium and non-equilibrium

43
conditions,, Tafel equation- Tafel plot, Hydrogen and Oxygen overvoltage,
Factor affecting overvoltage.

Unit-8 Fuel cells and batteries – primary and secondary power cells, fuel cells, Li
ion battery, evaluation of performance of electrochemical systems, energy
density, shelf life, and Faradic efficiency.

Corrosion and corrosion prevention- Thermodynamics and kinetics of


corrosion, methods of prevention to corrosion.

Electrosynthesis – use of electrodes in synthesis of organic compounds

Block-3.15.3 Title: Irreversible thermodynamics and Solid state reactions


Unit-9 Microscopic reversibility and Onsager reciprocity relation, phenomenological
equations, Transformation of generalized fluxes and forces, The cyclic
version of Clausius’ inequality and its integrated form and their
correspondence with time’s arrow and irreversibility.
Unit-10 Clausius’ uncompensated heat. Derivation of the differential form of
Clausius’ inequality, Rate of entropy production and the concept of Chemical
affinity and its application to the cases of chemical reactions, coupled
reactions, electrochemical reactions.
Unit-11 Derivation of Gibbs relation and its DeDonderian version (time rate form) for
spatially uniform chemically reacting closed systems, entropy production in
spatially non-uniform systems like heat flow, Electrokinetic effect – Saxen
relation.
Unit-12 Solid State Reactions: General principle, types of reactions: Additive,
decomposition and phase transition reactions, tarnish reactions, kinetics of
solid state reactions, factors affecting the solid state reactions, photographic
process.

Block-3.15.4 Title: Nuclear chemistry


Unit-13 Radioactive decay- General characteristics, decay kinetics, parent-daughter

44
decay growth relationship, determination of half lives, Nuclear stability-
packing fraction, binding energy.
Unit-14 A review of α, β and γ – decays, Bathe’s notation, types of nuclear reactions –
photonuclear reactions, oppenteimer- Phillips process, spallation reactions,
Definition of Curie & Zilard – Chalmers process, GM Counter.
Unit-15 Radiation chemistry – Introduction of electromagnetic radiation with matter,
G-value, dosimetry, Ficke dosimeter, Radiolysis-Cystein and biphenyl.
Unit-16 Radioisotopes as tracer- structure determination, reaction mechanism and
14
solubility of sparingly soluble substances, C dating and medical
applications, Hazards in radiochemical wars and radiation protection.

45
Course 15: Organic chemistry special [30OS]
Block-3.15.1 Title: Rearrangement reactions
Unit-1 Rearrangement to Electron Deficient Carbon: Wagner-Meerwein
rearrangement, Pinocol-pinocolone rearrangement, Benzidine rearrangement,
Benzylic acid rearrangement, Arndt-Eistert Homologation rearrangement,
Dienophine rearrangements
Unit-2 Rearrangement to Electron Deficient Nitrogen: Hofmann rearrangement,
Curtius rearrangement, Lossen rearrangement, Schmidt rearrangement,
Beckmann rearrangement, Meisenheimer rearrangement and Wolff
Rearrangements
Unit-3 Rearrangement to Electron-Rich Carbon: Cope Rearrangement, Fries
rearrangement, Favorskii rearrangement, Hauser rearrangement, Stevens
Rearrangement,
Unit-4 Sommelet rearrangement, Smiles rearrangement, Neber rearrangement, Japp-
Klingemann rearrangement, allylic rearrangement and Bayer-villeger
rearrangement

Block-3.15.2 Title: Organic named reactions


Unit-5 Condensation and annulations reactions: Aldol, Acyloin, Benzoin, Stobbe,
claisen-Schmidt, Perkin Darzens and Dieckmann condensation reactions,
Robinson, Danheiser and Anionic annulation reactions
Unit-6 Oxidation and Reduction reactions: Clemmensen Reduction, Wolff Kishner
Reduction, Stephen reaction, Rosenmund Reduction, Meerwein-Ponndorf-
Verley Reduction, Carbylamine reaction, Oppenauer Oxidation, Tishchenko
Reaction, Cannizaro, reaction.
Unit-7 Addition reactions: Diels-Alder, Mannich, Reimer-Tieman, Chichibabin,
Knoevenagel addition, Michael addition, Enolate chemistry: Generation:
Kinetic and thermodynamic controls, use of LDA. Aldol reaction, alkylations
and acylation reactions of enolates.
Unit-8 Enamines Preparation (Stork enamine reaction) and synthetic applications,
46
organophosphorus (Wittig reaction) Sulphur ylides and their synthetic
applications

Block-3.15.3 Title: Chemistry of heterocyclic compounds


Unit-9 Azoles: Structural and chemical properties; Synthesis of pyrazole,
imidazoles, oxazoles isoxazole; thiazoles and isothiazole, Nucleophilic and
electrophilic substitutions; Carbonyldiimidazole as coupling agent
Unit-10 Benzofused heterocycles: Synthesis of indole, benzofuran and benzo-
thiophene, quinoline and isoquinoline, Nucleophilic, electrophilic and
radical substitutions; Addition reactions; Indole rings in biology.
Unit-11 Diazines: Structural and chemical properties; Synthesis of pyridazines,
pyrimidines, pyrazines; benzodiazines, Diazi nes containing one nitrogen
atom and an oxygen or sulphur atom, Nucleophilic and electrophilic
substitutions.
Unit-12 Triazines, tertazines, Osotriazoles and triazoles, Oxadiazoles, Syndones,
tetrazole, Nucleophilic and electrophilic substitutions

Block 4.15.4 Title: Synthetic methodology in organic chemistry

Unit-13 Introduction, Chemo selective, regio selective, steroselctive and


stereospecific, reactions, examples of chemo selective and regio selective
reactions.

Unit-14 Stereo selectivity and diasteroselctivity, Stereochemical control in synthesis


of cyclic comounds, Conformational control in the formation of six
membered rings, Synthesizing single diastereomers using stereosecltive
reactions, Prochirality, streoselectivity reversion by chelation.

Unit-15 Chiral auxiliary and Chiral agent assisted organic reactions, Baker’s yeast
assisted reductions, Asymmetric desymetrization method for synthesis of
single enantiomers, Thermo dynamic controlled conjugate addition of
enolates, reactions.

Unit-16 Protection and deprotection of functional groups, Protection of hydroxyl,


thiol amino carbonyl, carboxyl, groups. Orthogonal protection and
Illustration of protection /deprotection in synthesis.
Reference books:
1. Organic reaction mechanisms (II edition), 1995 - V. K. Ahluwalia & R. K.Parasar
2. Organic reaction Mechanism, Singh and Mukherjee, Mc millan 3rd ed, 2000.
47
3. Reaction mechanism and reagents in organic chemistry, 2nded ,1991-Gurdeep R.
Chatwal
4. Organic chemistry (VI edition),2001 - Morrison Boyd.
5. Organic chemistry – I.L. Finar, Vol.1, 3rd edition,1975
6. Organic chemistry - (VII edition), 2008 - Mc Marry)
7. Advanced organic chemistry (IV edition), 2001 – J March
8. Reaction mechanisms and problems in organic chemistry 2nd edition 2001 – P.
Chattopadhyay
9. Reactive intermediates in organic chemistry 1st Edition, 2001 - J. P. Trivedi
10. Principles of reaction mechanism in organic chemistry – Parmar & Chawla, Ed. II,
1978.
11. Organic Photochemistry2nd Edition ,1984 - J. Coxon & B. Halton
12. Advanced organic chemistry Part B – F.A. Carey & R. J. Sundberg Ed II, 1990 .
13. Organic Chemistry - P.Y. Bruice, Pearson Education Pvt. Ltd., New Delhi (2002), Ed
III

48
Fourth Semester
Course 16: Inorganic spectroscopy
Block-4.16.1 Title: Symmetry and Group theory
Unit-1 Definition of groups, sub groups, cyclic groups, conjugates relationships.
Unit-2 Symmetry elements and symmetry operations, point groups (of molecules)
Unit-3 Reducible and irreducible representations, characters of representation.
Unit-4 Character tables and their uses (representations, of Cn, Cnv, Cnh, Dnh etc
groups to be worked out)

Block-4.16.2 Spectroscopic Applications for inorganic compounds


Unit-5 Vibrational spectroscopy- vibrational spectra of diatomic linear and bent
triatomic, AB3, AB4 AB5 and AB6 molecules,
Unit-6 IR Spectra of metal complexes, amines, amido, nitro, nitrito, lattice water,
aquo and hydrido, carbonato, sulphato, cyanato, thiocyanato complexes,
mano and multinuclear carbonyl complexes, Ethylene diamino and
diketonate complexes.
Unit-7 ESR spectroscopy-Spin polarization for atoms and transition metal ions,
spin-orbit coupling and significance of g-tensors, zero/non zero field
splitting , Kramer’s degeneracy, applications to transition metal complexes
(having one to five unpaired electrons) including biological molecules and
free radicals such PF4 F2 and BH3.
Unit-8 NMR spectroscopy- applications of 31P, 19F, 11B NMR spectroscopy in the
structural assessment of inorganic compounds, proton/ hydride interactions
with Rn103, W 183, Pt 185 and Pb207 in metal complexes/organometallic
compounds.

49
Block-4.16.3 Modern spectroscopic techniques-I
Unit-9 Photoelectron Spectroscopy: Introduction, principles, chemical shifts,
photoelectron spectra of simple molecules. X-ray photoelectron and Auger
electron spectroscopyPrinciples and applications.
Unit-10 NQR Spectroscopy: Introduction, Principles, Quadrupolar nuclei, electric
field gradient, nuclear quadrupole coupling constants, energies of
quadrupolar transitions, effect of magnetic field. Applications.
Unit-11 Mössbauer spectroscopy: The Mössbauer effect, chemical isomer shifts,
quadrupole interactions, magnetic splitting, measurement techniques and
spectrum display, application to the study of Fe2+and Fe3+ compounds; iron
in very high oxidation states Fe(V) and Fe(VI) nitride complexes; Sn 2+and
Sn4+compounds, nature of M-L bond, coordination numberand structure,
detection of oxidation states and aninterhalogen compound I2Br2Cl4.
Unit-12 Principles, Instrumentation &applications of the following Thermal
techniques
TG, DTA, DSC, Cyclic Voltametry, Problems based on above techniques
should be solved

Block-4.16.4 Title: Modern spectroscopic techniques-II


Unit-13 General idea about two dimensional NMR spectroscopy, Correlation
spectroscopy (COSY)- Homo COSY (1H-1H), TOCSY, Hetero COSY
(HMQC, HMBC), Homo and Hetero nuclear 2D resolved spectroscopy,
NOESY and 2D-INADEQUATE experiments and their applications.
13
Unit-14 C NMR Spectra: un-decoupled, Proton decoupled, Off resonance, APT,
INEPT, DEPT, chemical shift, Homo nuclear (13C-13C) and Hetero nuclear
(13C-1H) coupling constants.
Unit-15 Flame photometry: Principle, Instrumentation and types of burners, Factors
affecting flame photometric determination. Limitations of flame
photometry, Interferences in flame photometry, Applications, Stripping
Voltammetry: Principle and technique in anodic and cathodic stripping
voltammetry, applications to metal ion analysis, limitations.
Unit-16 Introduction to scanning probe microscopy (SPM), scanning tunneling
microscopy (STM), atomic force microscopy (AFM) and scanning
electrochemical microscopy (SECM), CD and ORD
Reference books
1. Introduction to Spectroscopy – D. L. Pavia, G.M. Lampman, G. S. Kriz, 3rd Ed.
(Harcourt college publishers).
2. Spectrometric identification of organic compounds R. M. Silverstein, F. X. Webster, 6th
Ed. John Wiley and Sons.
3. Spectroscopic methods in organic chemistry - D. H. Williams and I. Flemming Mc Graw
Hill
50
4. Absorption spectroscopy of organic molecules – V. M. Parikh
5. Nuclear Magnetic Resonance – Basic Principles- Atta-Ur-Rehman, Springer-Verlag
(1986).
6. One and Two dimensional NMR Spectroscopy – Atta-Ur-Rehman, Elsevier (1989).
7. Organic structure Analysis- Phillip Crews, Rodriguez, Jaspars, Oxford University Press
(1998)
8. Organic structural Spectroscopy- Joseph B.Lambert, Shurvell, Lightner, Cooks,
PrenticeHall (1998).
9. Organic structures from spectra –Field L.D., Kalman J.R. and Sternhell S. 4th Ed. John
Wiley and sons Ltd.
10. Spectroscopic identification of organic compound- R M Silverstein, G C Bassler and T C
Morril, John Wiley
11. Introduction to NMR spectroscopy-R J Abrahm, J Fisher and P loftus Wiley
12. Organic spectroscopy-William kemp, E L B with McMillan
13. Spectroscopy of organic molecule-PS Kalsi,Wiley, Esterna, New Delhi
14. Organic spectroscopy-RT Morrison and RN Boyd
15. Practical NMR spectroscopy-ML Martin, J J Delpench, and D J Martyin
16. Spectroscopic methods in organic chemistry-D H Willson, I Fleming
17. Spectroscopy in organic chemistry- C N R Rao and J R Ferraro
18. NMR –Basic principle and application-H Guntur
19. Interpretation of NMR spectra-Roy H Bible
20. Mass spectrometry organic chemical applications, J H Banyon.
21. Structural methods in Inorganic Chemistry – E.A.V. Ebsworth, D.W.H. Rankin & S.
Cradock, Blackwell Scientific Publication, 1987.
22. Physical Methods for Chemists-R.S. Drago, (2nd edition, Saunders).
23. Instrumental methods of Chemical Analysis – Chatwal & Anand.
24. Laboratory Techniques in Electro analytical Chemistry edited by P.T. Kissinger and
W.R. Heinman (1984) M. Dekker vinc (USA).
25. Dennis H. Evans, Journal of Chemical Education, vol.60, pp290 (1983).

51
Course 17: Bio-organic chemistry
Block-4.17.1 Title: Proteins and peptides
Unit-1 Amino acids and peptides: Amino acids, structural characteristics, acid base
property, stereochemistry of amino acids, Stecker synthesis, Zwitter ionic
nature isolectric points optical resolution.
Unit-2 Peptide structure and conformations, biological functions, C and N terminal
residue determination, Reaction of polypeptide, structure determination of
polypeptide.
Unit-3 Proteins, Classification of proteins, protein structure; primary, secondary (α-
helix, β-sheet and β-turns), tertiary and quaternary structure.
Unit-4 Factors contributing to the secondary, tertiary and quaternary structure, role of
salt bridge, disulphide bond, denaturation and renaturation of proteins,
Ramachandran plot and its significance.

Block-4.17.2 Title: Nucleic acids and carbohydrates


Unit-5 Nucleic acids: Introduction, nucleosides and nucleotides, numbering method
for sugar unit, base unit, synthesis of nucleobases, Protecting groups used for
amino groups in bases and hydroxyl group in sugar unit for synthesis of DNA
and RNA.
Unit-6 Structures and functions of DNA and RNA, Watson-crick model, types of
DNA, Base paring and stability.
Unit-7 Chelator and interchelator, codons, genetic code, replication of DNA,
biosynthesis of proteins
Unit-8 Carbohydrate: Types of naturally occurring sugars, deoxy sugars, amino
sugars, branched chain sugars, methyl ethers and acid derivatives of sugars,
general methods of structure and ring size determination with reference to
maltose, lactose, sucrose, Anomeric effect and epimerization and
mutarotation,Chemistry of starch and cellulose.
Block-4.17.3 Title: Steroids, Prostaglandins and Terpenoids
Unit-9 Steroids: Occurrence, nomenclature, basic skeleton, Diel’s hydrocarbon and

52
stereochemistry, Isolation, structure determination and synthesis of
Cholesterol and Bile acids, Biosynthesis of steroids (lanosterol) .
Unit-10 Plant Pigments: Occurrence, nomenclature and general methods of structure
determination, isolation and synthesis of Apigenin, Luteolin,
Unit-11 Prostaglandins: Occurrence, nomenclature, classification, biogenesis and
physiological effects. Synthesis of PGE2 and PGF2α
Porphyrins: Structure and synthesis of Haemoglobin and Chlorophyll.
Lipids: Introduction, nomenclature, classification and purifications. waxes,
triacyl glycerol, phospholipids, their biological importance.
Unit-12 Terpenoids: Classification, nomenclature, occurrence, isolation, general
methods of structure determination, isoprene rule. Structure determination,
stereochemistry, and synthesis of the following representative molecules:
Citral, Geraniol, α-terpeneol, Menthol, Farnesol, Zingiberene, Biosynthesis of
the tepenoids (limonene, camphor, α-pinene, β-pinene)

Block-4.17.4 Title: Alkaloids, Vitamins and Enzymes


Unit-13 Alkaloids: Definition, nomenclature and physiological action, occurrence,
isolation, classification based on nitrogen heterocyclic ring, role of alkaloids
in plants Structure,
Unit-14 General methods of structure elucidation, degradation stereochemistry, and
synthesis of the following: Ephedrine, (+)-coniine, Nicotine, Atropine,
Quinine, Reserpine and Morphine,
Unit-15 Vitamins: Introduction, constitution of thiamine, riboflavin, pyridoxine,
biotin, ascorbic acid, vitamin A, E and K groups and synthesis thiamine,
ascorbic acid biosynthesis and biological importance vitamins
Introduction to hormones, antibodies and anti oxidents, their Biological
importance
Unit-16 Enzymes: Introduction, chemical and biological catalysis, remarkable
properties of enzymes like catalytic power, specificity and regulation.
Cofactors as derived from vitamins, coenzymes, prosthetic groups,
apoenzymes. Nomenclature and classification, Fischer’s lock and key and
Koshland’s induced fit hypothesis, concept and identification of active site by

53
the use of inhibitors, affinity labeling and enzyme modification by site-
directed mutagenesis. Baker’s yeast catalyzed reactions

Course 20: Analytical techniques


Block-4.20.1 Title: Extraction and precipitation methods
Unit-1 Solvent extraction: Principle and techniques, Distribution ratio and
distribution coefficient, Factors affecting extraction efficiency, Ion
association complexes, chelation, synergistic extraction,
Unit-2 Role of chelating ligands, crown ethers, calixarenes and cryptands in solvent
extraction, Introduction to Solid phase extraction (SPE) and Microwave
assisted extraction (MAE), Applications.
Unit-3 Gravimetric analysis: General principles, stoichiometry, calculation of results
from gravimetric data, Properties of precipitates, Nucleation and crystal
growth.
Unit-4 Factors influencing completion of precipitation. Co-precipitation and post-
precipitation, purification and washing of precipitates, Precipitation from
homogeneous solution.

Block-4.20.2 Title: Titration methods-1


Unit-5 Principles of titrimetric analysis, titration curves for strong acid-strong base,
weak acid-strong base and weak base-strong acid titrations. Titration of
polyprotic acids, poly equivalent bases,
Unit-6 Detection of end points, Theories of acid base indicators, selection of proper
indicators, Finding the end point by visual indicators, monitoring pH and
temperature.
Unit-7 Acid-base titrations in non-aqueous media: Role of solvent in acid-base
titrations, solvent systems, differentiating ability of a solvent, some selected
solvents, titrants and standards,
Unit-8 Titration curves, effect of water, determining the equivalence point, typical
applications - determination of carboxylic acids, phenols and amines.

Block-4.20.3 Title: Titration methods-2

54
Unit-9 Titration methods employing EDTA-direct, back and displacement titrations,
Selectivity, masking and demasking agents, typical applications of EDTA
titrations-hardness of water, magnesium and aluminium in antacids,
magnesium, manganese and zinc in a mixture, titrations involving unidentate
ligands-titration of chloride with Hg2+ and cyanide with Ag+.
Unit-10 Karl-Fischer titrations: Stoichiometry of the reaction, precipitation of reagent,
titration method, standardization, determination of water in samples.
Application to quantitative analysis of organic compounds- Alcohols,
carboxylic acids, acid anhydrides and carbonyl compounds.
Unit-11 Redox titrations- Principles, Nerst equation, standard and normal potentials,
titration curves, endpoint signals.
Unit-12 Indicators- criteria for the selection of indicators, feasibility of redox titration.
Titration of multicomponent systems. Applications- oxidens such as KMnO4,
K2Cr2O7, Ce(IV), bromates and Iodates

Block-4.20.3 Title: Complexometric titrations


Unit-9 Complex formation reactions, stability of complexes, stepwise formation
constants, chelating agents, EDTA-acidic properties, complexes with metal
ions, equilibrium calculations involving EDTA.
Unit-10 Conditional formation constants, derivation of EDTA titration curves, Effect
of other complexing agents, factors affecting the shape of titration curves-
completeness of reaction, indicators for EDTA titrations.
Unit-11 Inorganic analysis - alkalinity, acidity and free CO2 in water and waste
waters, nitrogen, sulphur ammonium salts, nitrates and nitrites, carbonates
and bicarbonates.
Unit-12 Organic analysis – functional groups like carboxylic acid, sulphonic acid,
amine, ester, hydroxyl and carbonyl.

References
1. Fundamental of Analytical Chemistry, D.A. Skoog, D.M. West, Holler and Crouch,
8th edition, 2005, Saunders College Publishing, New York.
2. Analytical Chemistry, G.D. Christian, 5th edition, 2001, John Wiley & Sons, Inc,

55
India.
3. Quantitative Analysis, R.A. Day and A.L. Underwood, 6th edition, 1993, Prentice
Hall, Inc. New Delhi.
4. Vogel’s Textbook of Quantitative Chemical Analysis, J. Mendham, R.C. Denney, J.D.
Barnes and M.J.K. Thomas, 6th edition, Third Indian Reprint, 2003, Pearson
Education Pvt. Ltd., New Delhi.
5. Quantitative Analysis, R.A. Day and A.L. Underwood, 6th edition, 1993
prenticeHall, Inc. New Delhi.
6. Analytical Chemistry Principles, John H. Kennedy, 2nd edition, Saunders
CollegePublishing, California, 1990.
7. Principles and Practice of Analytical Chemistry, F.W. Fifield and Kealey, 3rd
edition, 2000, Blackwell Sci., Ltd. Malden, USA.
8. Modern Analytical Chemistry, David Harvey, McGraw Hill, New Delhi, 2000.

56
Course 21: Advanced inorganic chemistry [40AI]
Block-4.21.1 Title: Applied inorganic chemistry

Unit-1 Ionic liquids: Molten salt solvent systems, Ionic liquids at ambient
temperature, Reactions in and applications of molten salt/ionic liquid media

Unit-2 Supercritical fluids: Properties of supercritical fluids and their uses as


solvents. Supercritical fluids as media for inorganic chemistry

Unit-3 Symmetry in Chemical bonding: Group theory to Crystal fieldtheory and


Molecular orbital theory (octahedral and tetrahedral complexes).

Unit-4 Symmetry in Vibrational Spectroscopy: Determining the symmetry groups


of normal modes for non-linear molecules (H2O, NH3, CH4, trans-N2F2) and
linear molecules (CO, HCl, HCN and CO2) (Integration method).

Block- 4.21.2 Tile: Modern theories of chemical bonding


Unit-5 Molecular orbital theory, Linear combination of atomic orbitals (LCAO),
Rules for linear combination of atomic orbitals, Formation of σ,  and δ
molecular orbitals, Non-bonding combinations of orbitals.
Unit-6 Molecular orbital energy diagram, bond order and magnetic properties of
hetero nuclear di-atomic molecules (CO, NO, HCl) and linear tri-atomic
molecules involving delocalized π bonding (ex: CO2, NO2).
Unit-7 Molecular geometry, the ligand close packing (LCP) model, comparison of
the VSPER and LCP models.
Unit-8 Reexamination of crystalline solids, intermediate types of bonding in solids,
quantum theory of atoms in molecule.

Block-4.21.3 Title: Synthesis and catalytic applications of organometallics of transition


elements
Unit-9 Synthesis and π-bonding of Pd and Rh metals with olefins and their
applications in C-C bond formations including Wacker process, Heck

57
reaction, Carbonylation, hydroformylation, decarbonylation, olefin
isomerism.
Unit-10 Synthesis and bonding in Ru metal, Grubb’s catalysts, Olefin metathesis
using Grubb’s catalysts, Sonogashira reaction, Stille coupling, Buchwald
reaction and Pauson -Khand reaction.
Unit-11 Synthesis and bonding in Zn, Pt, Ir and metals,
Unit-12 Fluxional organometallic compounds- Fluxionality and dynamic equilibria in
organometallic compounds – (i) Compounds with acyclic alkenes (ii)
Compounds with σ-bonded cyclic alkenes (iii) Compounds with one or more
cyclopolyenes π-bonded or σ and π-bonded to several metal atom.

Block-4.21.4 Title: cluster molecules

Unit-13 Hydrides, Isocyanides and tertiary phosphine complexes- synthesis, structure


and bonding,

Unit-14 Dihydrogen, dioxygens and dinitrogen complexes-Synthesis, structure and


bonding.

Unit-15 Boron hydrides: Classification, nomenclature, structure, bonding and


topology of boranes, 4-digit coding (s, t, y, x) numbers for higher boranes and
their utilities.

Unit-16 Chemistry of diboranes: Study of Metalloboranes, Carboranes and


Metallocarboranes with reference to preparations and structures.

58
Course 21: Advanced physical chemistry [40AP]
Block 4.21.1 Title: Solid state chemistry
Unit-1 Types of imperfections, classification of imperfections, point defects,
schottky defect, Fremkell defects, disordered crystals, line defect, dislocation
types plane defects, small-angle and large angle boundaries. Stacking fanets,
crystal growth and twimming
Unit-2 Semiconductors, Band theory, energy band, intrinsic and extrinsic
semiconductors. Conductivity- electron and holes, temperature dependence on
conductivity, Photovoltamic effect, P-N junctions, transistors.
Unit-3 Supper conductors-Meissner effect, Type-I and Type-II superconductors,
isotope effect, manifestation of energy gap, Josephson devises.
Unit-4 X-ray diffractions: Crystal lattices, Unit cell, identifications of lattice planes-
Miller indices, Bragg equation, elucidation of structure by Lacers and powder
methods

Block-4.21.2 Title: Kinetics of fast reactions


Unit-5 Chain reactions- Kinetics of explosive reactions, explosion limits (H2 and O2
reaction). Autocatalysis and oscillatory chemical reactions, Kinetics and
mechanism of Ru(III) catalyzed oxidation reactions of primary amines by
Chloramine-T in HCl media.
Unit-6 Fast reactions- Study of kinetics by flow technique, equation for contact time,
stopped flow and continuous flow methods, Relaxation method, equation for
relaxation time, temperature jump and pressure jump methods, flash
photolysis, pulse radiolysis and shock tube method
Unit-7 Homogeneous catalysis, Acid-base catalysis, general acid-base catalysis,
specific acid-base catalysis. Acidity functions, Huckel, Hammett and
Bummett hypothesis.
Unit-8 Linear free energy relationship- Taft and Hammette equation, Swain-Scott
equation, Edward equation and their significance.

59
Block-4.21.3 Title: Photochemistry
Unit-9 Consequences of light absorption, Laws of photochemistry-Grothus-Draper
law, Stark-Einstein law, Quantum yield, determination of quantum yield,
actinometers, The Jablask diagram and its significance.
Unit-10 Photochemical reactions: The photochemical rate law, Kinetics of
photochemical reactions, Kinetics of Hydrogen-Chlorine, Hydrogen-Bromine
reactions, Kinetics of decomposition of HI.
Unit-11 Energy transfer in photochemical reaction, Photosensitization and quenching,
Fluorescence and Phosphorescence, Quenching of fluorescence. delayed
fluorescence mechanisms, kinetics of collisional quenching, Stern-Volmer
equation, quenching by added substances charge transfer mechanism, energy
transfer mechanism.
Unit-12 Chemiluminesence, The oscillator strength, The geometry of excited states,
the laser and maser, self-phase modulation, single photon counting,
experimental techniques, flash photolysis, Picosecond and Femtosecond flash
photolysis, applications: Solar energy conversion and storage,

Block 4.21.4 Title: Non-equilibrium Thermodynamics

Unit-13 Conservation of mass and energy in time dependent closed and open systems,
Thermodynamic criteria of irreversibility, rate of entropy production and
entropy exchange in irreversible processes. The generation of the concept of
Chemical Affinity and the extent of advancement of chemical reactions,
Thermodynamic constraints on the signs of chemical affinity and the velocity
of chemical reaction, application to any one coupled reaction, problems.

Unit-14 Colligative properties, Relation between the relative lowering of vapour


pressure of the solvent Osmosis phenomenon, Van’t Hoff theory of dilute
solution, Van’t Hoff relation between osmotic pressure of a solution and
molecular weight, theories of osmosis, Elevation in boiling point, depression
in freezing point, relationship between molecular mass of solute and

60
Elevation in boiling point/ depression in freezing point, Van’t Hoff factors,
Problems.

Unit-15 Phase equilibrium, phase diagrams, lever rule, phase rule, counting
components, Different experimental techniques for determination of transition
point, liquid-solid phase transition, phase diagram of carbon dioxide and
sulphur systems, two component system involving soild-liquid equilibria (
FeCl3-H2O, NaCl-H2O, Na2SO4-H2O), experimental determination of phase
diagram of two component

Unit-16 Liquid-Liquid mixtures, Expressing concentration of solutions, Raoult’s Law,


Henry’s Law, Duhem-Margules equation, completely soluble liquids, vapour
pressure composition diagram for Ideal and non-dial solutions, principle of
distribution of binary miscible liquids, azeotropes, Immiscible liquids,
partially miscible liquids, critical solution temperature, effect of impurities on
critical solution temperature.

61
Course 21: Advanced Organic chemistry [40AO]
Block-4.21.1 Title: Photochemistry of organic molecule
Unit-1 Introduction, types of excitation n−π, π - π∗, Photochemistry of carbonyl
compounds, reactivity of electronically excited ketones, representation of
excited states of ketones, α-cleavage, γ-hydrogen transfer. Norrish Type-1
and Type-2 reactions
Unit-2 Photochemistry of alkenes conjugated alkenes, aromatic compounds with
reference to isomerisation, addition and substitution, pyridinium yields and
p- Benzoquinones. Photochemical isomerisation, addition and substitution.
Unit-3 Photochemical isomerization of cis and trans alkenes, Photo-Fries
rearrangement of ethers and anilides; Barton reaction, Hoffmann-Loefller-
Freytag reaction, Paterno-buchi reaction,
Unit-4 di-π-methane rearrangement; Singlet molecular oxygen reactions; Photo-
cleavages. Greenhouse effect. Photo theory reaction of anilides,
photochemistry of vision, Applications of photochemical methods in
synthesis: Isocomene, Cedrene, Hirsutene

Block-4.21.2 Title: Pericyclic Reactions

Unit-5 Molecular orbital symmetry, Frontier orbitals of ethylene, 1,3-butadiene, 1,


3, 5-hexatriene, allyl system, classification of pericyclic reaction. FMO
approach, Woodward-Hoffman correlation diagram method and Perturbation
of Molecular Orbital (PMO) approach of pericyclic reaction under thermal
and photochemical conditions.
Unit-6 Electrocyclic reactions, conrotatary and disrotatary motion 4n and (4n+2)
systems, Cycloaddition reaction with more emphasis on [2+2] and [4+2],
Cycloaddition of ketones Secondary effects in [4+2] cycloaddition.
Stereochemical effects and effect of substituents on rate of cycloaddition
reaction, Diels-Alder reaction,
Unit-7 Sigmotropic rearrangement, suprafacial, and antarafacial shift involving

62
carbon moieties, retention and inversion of configuration, [3,3] and [3,5]
sigmotropic rearrangements, Claisen, Cope, Sommelet-Hauser
rearrangements, Ene reaction.
Unit-8 1,3-dipolar cycloaddition and chelotropic reactions, Application to synthesis
of heterocyclic compounds.

Block-4.21.3 Title: Modern synthesis concepts

Unit-9 Umpolung concept: Dipole inversion, generation of acyl anion, use of 1,3-
dithiane, ethylmethylthiomethylsulphoxide, bis-phenylthiomethane,
metallated enol ethers, alkylidene dithiane, ketone thioacetals, 2-
propenethiobismethyl thioallyl anion, thiamine hydrochloride based
generation of acyl anion

Unit-10 Organopalladium in organic synthesis-Heck reaction, carbonylation, Wacker


oxidation, coupling reactions: Kumada Reaction, Stille coupling,
Sonogashira, Negishi and Suzuki coupling reactions and their importance,
Applications of Co2(CO)8, Ni(CO)4, Fe(CO)5 in organic synthesis.
Wilkinson catalyst of Ruthenium and Rhodium–synthesis and uses its use in
hydrogenation reactions-deallylation, C-C, C-O, C-N bond cleavages.

Unit-11 Olefin metathesis by 1st and 2nd generation catalyst, reaction mechanism
and application in the synthesis of homo and heterocyclic compounds,

Unit-12 Multicomponet reactions, combinatorial organic synthesis, solid phase


organic synthesis, dominoreactions, microwave assisted organic synthesis.

Block-4.21.4 Title: Advanced synthetic methods

Unit-13 Planning of organic synthesis, Linear and convergent synthesis Illustration


of Total synthesis, Formal synthesis and Cosine synthesis of simple organic
molecules, Planning the synthesis of simmple organic molecule using named
reactions, reagents and arganometallic compounds.

63
Unit-14 Retrosynthetic analysis, An introduction to synthons and synthetic
equivalents, disconnection approach, functional group inter-conversions, the
importance of the order of events in organic synthesis, one group C-X and
two group C-X disconnections,

Unit-15 One Group C-C Disconnections: Alcohols and carbonyl compounds, Two
Group C-C Disconnections: Retro-Diels-Alder reaction 1,3-difunctionalised
compounds, α,β- unsaturated carbonyl compounds,

Unit-16 Chirality transfer, Stereoselective addition of nucleophiles to carbonyl


group: Re-Si face concepts, Cram’s rule, Felkin Anh rule, Houk model,
Cram’s chelate model. Asymmetric synthesis use of chiral auxiliaries,
asymmetric hydrogenation, asymmetric epoxidation and asymmetric
dihydroxylation,

Reference Books

1. Principle of Organic Synthesis R. O. C. Norman and J. M. Coxon


2. Modern Synthetic Reaction. H. O. House and W. A. Benjamin
3. Organic Synthesis: The Disconnection Approach-S. Warren
4. Designing Organic Synthesis-S. Warren
5. Some Modern Methods of Organic Synthesis-W. Carruthers
6. Advance Organic Reaction. Mechanism and Structure-Jerry March
7. Advance Organic Chemistry Part-B-F. A. Caray and R. J. Sundberg Plenum Press
8. Organic Reaction and their Mechanism-P. S. Kalsi
9. Protective Groups in Organic Synthesis-T. W. Greene
10. The Chemistry of Organo Phosphorous-A. J. Kirbi and S. G. Warren
11. Organo Silicon Compound-C. Eabon
12. Organic Synthesis via Boranes-H. C. Brown
13. Organo Borane Chemistry-T. P. Onak
14. Organic Chemistry of Boron-W. Gerrard

64
Third semester
Skill enhancement course-1
Block-1 Title: Data Analysis and chemical handling
Unit-1 The Investigative Approach: Making and Recording Measurements. SI Units and
their Use, different expression of concentrations and their interconcersions,
Unit-2 Buffer solution and calculation of pH, Buffer actions, Calculation of % yield and
overall yield in multistep organic synthesis, Safe working procedure and
protective environment, protective apparel, emergency procedure and first aid,
laboratory ventilation.
Unit-3 Safe storage and use of hazardous chemicals, procedure for working with
substances that pose hazards, flammable or explosive hazards, Handling the
following chemicals: hydrochloric acid, nitric acid, sulphuric acid, caustic soda,
bleaching powder, sodium thiosulphate, hydrogen peroxide
Unit-4 Structure Elucidation of organic compounds on the basis of spectral data (UV,
IR, 1H and 13CNMR and Mass)

Block-2 Title: Green Chemistry


Unit-5 Definition and Objective of Green Chemistry, The twelve principles of Green
Chemistry, atom economy in chemical synthesis,
Unit-6 Important technique employed in practice of Green Chemistry, Application of
microwave irradiation and ultrasound in chemical reactions.
Unit-7 Use of renewable raw materials and biosynthesis, use of safer reagents and green
solvents and green catalysts.
Unit-8 Real Applications of Green Chemistry: Replacement of CFC and hydrocarbon
blowing agents with environmental friendly blowing agent CO2 in the production
of polystyrene. Replacement of Ozone depleating and Smog producing solvents
by surfactant assisted liquid or supercritical carbon dioxide for cleaning in
manufacture of ICs and Computer chips.

65
Fourth semester
Skill enhancement course-2
Block-1 Title: Methods of Scientific Research and Writing Scientific Papers
Unit-1 Sources of information: Primary, secondary, tertiary sources; Journals: Journal
abbreviations, abstracts, current titles, reviews, monographs, dictionaries, text-
books, current.
Unit-2 Introduction to Chemical Abstracts and Beilstein, Subject Index, Substance
Index, Author Index, Formula Index, and other Indices with examples.
Unit-3 Reporting practical and project work, Writing literature surveys and reviews,
Organizing a poster display, Giving an oral presentation.
Unit-4 Writing scientific papers – justification for scientific contributions, bibliography,
description of methods, conclusions, the need for illustration, style, publications
of scientific work, Writing ethics, Avoiding plagiarism.

Block-2 Title: Industrial Application of Chemistry


Unit-5 Chemistry of Cement, Paper and Pulp, and Petroleum
Unit-6 Conducting polymers - Introduction, conduction mechanism, polyacetylene,
polyparaphenylene and polypyrrole, applications of conducting polymers, Ion-
exchange resins and their applications.
Unit-7 Industrial waste identification and classifications, sorting, washing, shredding,
extruding.
Unit-8 Waste Management Nuclear waste management, e-waste management, organic
waste management, recycling of plastic.

66
I SEMESTER
CHEMISTRY PAPER – I

Block-1 Inorganic Chemistry

Unit-1 Rutherford model of atom, Bohr’s theory of Hydrogen atom, line spectra of
atom, Zeeman effect, Quantum theory, Quantum numbers and their
significance, Shapes of s, p and d orbitals, Effective nuclear charge, screening
effect-based on Slater’s rules (problems to be worked out), Pauli’s exclusion
principle.

Unit-2 General energy level diagram of multi electron atom (up to n=4), Aufbau
principle Hund’s rule, (n+1) rule, Electronic configuration of elements (up to
At. No. 40), stability of completely filled and half-filled orbitals based on the
concepts of pairing energy.

Unit-3 Periodic Table and Periodicity: Classification of elements, cause of periodicity,


Detailed discussion of the Atomic, Covalent, ionic, Vanderwaal’s and crystal
radii, Additive nature of covalent radii, Determination of ionic radii by Lande’s
method, Variation of covalent radii in a group and in a period, explanation for
the observed trends, Comparison of the size of the atoms with the
corresponding anions and cations, Variation of ionic radii in isoelectronic ions.

Unit-4 Ionization enthalpy, Successive ionization enthalpy, factors affecting ionization


enthalpy, applications of ionization enthalpy. Variation in a group and in a
period, explanation for the observed trends.

Electron gain enthalpy, Successive electron gain enthalpy variation of electron


gain enthalpy in period and in a group, explanation for the observed trends.

Electronegativity, Variation of electronegativity in a group and in a period,

67
explanation for the observed trends, Factors determining electro negativity
(charge on the atom and hybridization). Pauling, Mulliken and Allred-Rochow
scale of electronegativity.

Block-2 Physical Chemistry

Unit-5 Gases: Maxwell-Boltzmann distribution of molecular velocities, Effect of


temperature on distribution of molecular velocities using distribution curve
(graph). Boltzmann factor (significance and equation), Energy distribution as a
function of temperature, Types of molecular velocities – average (Uav) - root
mean square velocity (Urms) - most probable velocity (Ump) – their definition
and equations, Relation between Uav, Urms and Ump velocities of molecules and
their calculations (based on temperature dependence)

Unit-6 The critical phenomena – Andrew’s experiments on CO2, critical constants –


Tc, Pc and Vc, definitions experimental determination of Critical temperature
and Critical pressure by using Cagniard delaTour’s apparatus, critical volume
by Cailletes and Mathias method – Vander Waal’s equation – relation between
Vander Waal’s Constants ‘a’ and ‘b’ and critical constants Tc, Pc and Vc to be
derived using isotherms of CO2.

Unit-7 Law of corresponding states and reduced equation of state (to be derived)

Liquefaction of gases – Principle underlying liquefaction of gases – Joule


Thomson effect, Joule Thomson experiment – Show that Joule Thomson effect
is an isoenthalphic process (ΔH = 0). Joule Thomson coefficient, Inversion
temperature, definitions and its relation between Vander Waal’s constants (‘a’
and‘b’).

Unit-8 Indicator – Definitions, types (acid-base, redox, adsorption indicators),


examples for each type. Theory of indicators – Oswald’s theory and Quinonoid
theory – indicator constant – action of phenolphthalein and methyl orange in
acid-base solutions – pH titration curves for strong acid vs strong base, weak
acid vs strongbase, weak base vs strong acid, choice of indicators in these types
of titrations – color change and pH range, Universal indicator – definition.

68
Block-1 Organic Chemistry

Unit-9 Definition and importance of organic compounds, classification of organic


compounds, Tetravalency of carbon, sp3, sp2 and sp – hybridization (in brief).
Bond length, bond angle, bond energy, localized and delocalized chemical
bonds – resonance and hyperconjugation effects, isomerism and their different
types

Unit-10 Alkanes: General formula and IUPAC nomenclature, properties, Preparation


by Corey-House reaction, conversion of alkanes to aromatic compounds via
alkenes and alkynes- aromatization and pyrolysis, reactions of alkanes.

Alkenes: General formula, and IUPAC nomenclature, geometrical isomerism


in alkenes, Preparation of alkenes by Witting’s reaction, Hoffmann’s
elimination, reactions of alkenes: electrophillic addition, oxymercuration,
reduction, hydroboration – oxidation and epoxidation reactions and their
mechanisms, oxidation with KMnO4 and OsO4, ozonolysis, industrial
applications of ethane and propene.

Unit-11 Dienes: Types, relative stabilities of dienes, conjugated dienes – 1,3 butadiene-
structure, 1,2 and 1,4- addition reactions with H2 and halogens, Diel’s Alder
reaction with an example.

Alkynes: General formula, and IUPAC nomenclature, acidity of acetylenic


proton, Methods of preparation – dehydrohalogenation from vicinal and
geminal dihalides, reactions of alkynes – Electrophillic additions with HCN,
CH3COOH and H2O, polymerization.

Unit-12 Cycloalkanes: General formula, Definition, synthesis, relative stability Bayer’s


strain theory and its limitations, SachseMohr’s theory of strainless rings, Chair
and boat conformations of cyclohexane and their stability, structure and

69
stability of higher cylcohalkanes (up to ring size 10)

II SEMESTER
CHEMISTRY PAPER – II

Block-2.1 Inorganic Chemistry

Unit-1 Ionic bond- Introduction, Factors that favor the formation of ionic bonds,
Lattice energy, BornLande’s equation (no derivation), Born-Haber cycle,
setting up of Born-Haber cycle for 1:1 ionic solids, Numerical calculations of
LE and EA based on Born-Haber cycle for 1:1 ionic solids, uses of Born-Haber
cycle, Role of lattice energy and hydration energy and their importance in the
context of stability and solubility of ionic solids.

Unit-2 Covalent bond- Introduction, Factors favoring the formation of covalent bond
(ionization energy, electron affinity, electronegativity, nuclear charge, inter
nuclear distance and number of valence electrons). Valence bond approach –
explanation with examples (H2, F2, HF, O2 and N2) to illustrate valence bond
approach. Sigma and Pi bonds – explanation by taking H2, O2 and N2 as
examples.

Unit-3 Fajan’s rules of polarization and their explanation. Bond length, bond order,
bond energy and their significance, polarity of covalent bonds, polar and non-
polar molecules, Dipole moment and polarity of molecules to be explained by
taking HCl, CO2, CCl4 and H2O as examples.

Unit-4 Hybridization-directional property and geometry of sp, sp2 , sp3 , sp3d and
sp3d2 hybrid orbitals taking BeCl2, BF3, SiCl4, PCl5 and SF6 as examples
respectively. VSEPR theory with SO2, NH3, H2O, SF4 and ClF3 as examples.

70
Block-2 Physical Chemistry

Unit-5 Adsorption- Introduction, principle involved, Sorption, absorption and


adsorption (statement, differences and examples) physical and chemical
adsorption – definition and differences, Adsorption of gases on solids – factors
which influence, Adsorption isotherms (definition) – mathematical expression
for Freundlich’s and Langmuir’s adsorption isotherms, Applications of
adsorption.

Unit-6 Liquid mixtures: Classification of binary mixtures – partially miscible,


completely miscible and completely immiscible pairs of liquids (explanation
with examples for each type). Raoult’s law, definition of ideal and non- ideal
solutions based on Raoult’s law.

Partially miscible liquids: Critical solution temperature (CST) – types – phenol-


water system, triethylamine-water system, nicotine-water system (mutual
solubility temperature (MST) vs composition curves to be drawn). Effect of
addition of non-volatile solute on CST. Binary mixtures of completely miscible
liquids.

Unit-7 Vapour pressure – definition, vapor pressure – composition diagrams and


boiling point – composite diagrams. Classification into the types – obeying
Raoult’s law (type I), showing positive deviation from Raoult’s Law (type II)
and showing negative deviation from Raoult’s Law (type III) – examples for
each type.

Principles of fractional distillation: Fractional distillation of type I, type II and


type III liquid mixtures (with examples). Azeotropic mixtures (definition).

Binary mixtures of completely immiscible liquids (with examples), weight


fraction of distillates, principle of distillation, applications (numerical problem
on weight fractions of components).

71
Unit-8 Polyme rs: Introduction, monomer, repeating units, types (linear, branches and
network) with examples, degree of polymerization, classification (arrangement
and shape) with examples, polymerization reaction (addition and
condensation), molar masses of polymers – types (number average and mass
average), determination of molar mass (viscosity and osmotic pressure method)
(Numerical problems).

Block-3 Organic Chemistry

Unit-9 Aromatic hydrocarbons: Nomenclature of benzene derivatives, Resonating


structures of benzene, naphthalene and anthracene. Huckel’s rule with respect
to benzenoids, (benzene, naphthalene, anthracene and phenanthracene)
Aromatic electrophillic substitution – General mechanism, electronic
interpretation of orientating influence of electron donating groups (-CH3, -Cl, -
NH2 and -OH groups) and electron withdrawing groups (-NO2, -CHO, -COOH
and –SO3H groups) on electrophillic substitution reactions.

Unit-10 Non-benzenoid compounds, Huckel’s rule with respect to non-benzenoid


compounds (cyclopentadienyl anion, cycloheptadienyl cation) anti-aromaticity.

Hydrogenation of aromatic compounds: Birch reduction, side chain oxidation


of toluene to benzaldehyde and benzoic acid. Diel’s Alder reactions of
anthracene with maleic anhydride. Biphenyls: Preparation – Ullmann reaction.

Alkenyl Benzenes: Cis and Trans stilbene and their preparation (any one
method).

Unit-11 Alcohols: Definition and classification, IUPAC nomenclature, Monohydric


alcohols: Preparation of alcohols from alkene, carbonyl compounds, and
carboxylic acids, Distinction tests between 1°, 2°, and 3° alcohols by Victor
Meyer oxidation method. Conversion of 1° to 2°, 2° to 3° and 1° to 3° alcohols.
Dehydration of 1°, 2°, 3° alcohols and comparison of their rates, Reactions:
With sodium, HX (Lucas test), esterification, oxidation (with PCC, alk.

72
KMnO4, acidic dichromate, conc. HNO3), Oppeneauer oxidation.

Unit-12 Dihydric alcohols: Glycol – preparation from vicinal dihalides and uses.
Pinacoles – synthesis, mechanism of pinacol-pinacolone rearrangement.

Trihydric alcohols: Glycerol, synthesis from propene, reactions with HNO3,


H2SO4, oxalic acid and HI. Uses of glycerol.

Ethers: IPUAC Nomenclature, synthesis, reactions – cleavage and auto-


oxidation-Ziesel’s method. Epoxides: Synthesis by Darzen’s method. Acid and
base catalyzed opening of epoxides. Crown ethers: Introduction with examples

Phenols: Definition, classification with examples, acidity of phenols, effect of


substituents on acidity of phenols. Mechanism of Reimer-Tiemann reaction and
Kolbe reaction, Houben–Hoesch Condensation, Schotten –Baumann Reaction.

73
III SEMESTER
CHEMISTRY PAPER – III

Block-3.1 Inorganic Chemistry

Unit-1 Molecular Orbital Theory: An elementary account of MOT, linear combination


of atomic orbitals (no mathematical approach). Bonding and antibonding
molecular orbitals, conditions for the combination, energy levels of molecular
orbitals, Molecular orbital structures and bond orders of species like H2, He2,
He2+, N2, O2, HF, LiH, and CO, Prediction of magnetic properties of these
species.

Unit-2 Metallic bond: Definition, factors favouring the formation of metallic bond,
Band theory, explanation of electrical conductance of metals, semiconductors
(n- and p-type), Insulators and Superconductors (explanation and applications
with suitable examples).

Hydrogen bonding: Types of hydrogen bonding, conditions for the formation of


H-bond. Hydrogen bonding in HF, H2O, NH3, alcohols, carboxylic acids and
nitrophenols. Appropriate anomalous properties like physical state, boiling
point and solubility. Structure of ice. Theories (or nature) of hydrogen bond

(electrostatic approach, VBT and MOT treatments)

Unit-3 Noble gases: Isolation from air by Rayleigh’s method, preparation, separation
of Noble gases-Dewar’s method. Preparation, Structure and applications of
compounds of Xenon and Krypton (XeF2, XeOF2, XeO3, KrF2, KrF4, KrO3
XH2O-one method of preparation for each), Clathrates (explanation with
suitable examples, essential conditions for the formation and uses).

Unit-4 s-block elements: alkali and alkaline earth metal, occurrence and abundance,
electronic structure, general physical properties: size of atoms, and ions,

74
density, ionization energy, electronegativity and bond type, melting and boiling
points, flame colour and spectra, structures of the metals, hardness and
cohesive energy, chemical properties, reactions with air, water, dinitrogen,
oxides, hydroxides, peroxides and superoxides, anomalous properties of
Lithium and Beryllium,

Block-3.2 Physical Chemistry

Unit-5 Colligative Properties: Concept of vapour pressure, variation of vapour


pressure with temperature. Definition of boiling point and freezing point, effect
of dissolution of solute on the vapour pressure of the solvent. Lowering of
vapour pressure. Raoult’s law – relation between relative lowering of vapour
pressure and molar mass (to be derived). Determination of relative molar mass
of solute by dynamic method. Elevation of boiling point and its relation to
lowering of vapour pressure and molar mass (to be derived). Ebullioscopic
constant of the solvent and its relation to the boiling point (only equation).
Determination of molar mass of the solute by Walker-Lumsden method.

Unit-6 Depression in freezing point and its relation to lowering of vapour pressure and
molar mass (to be derived). Cryoscopic constant and its relation to the melting
point (equation). Determination of molar mass of a non-volatile solute by
Beckmann’s method (problems to be worked out). Definition of osmosis,
osmotic pressure (mention application), determination of osmotic

pressure by Berkley-Hartley’s method, laws of osmotic pressure analogy with


gas laws, determination of molar mass from osmotic pressure measurements
(relation to be derived), isotonic solutions, Semi permeable membrane – natural
and artificial, preparation of copper ferrocyanide membrane by Morse- Frazer
method, plasmolysis.

Unit-7 Distribution Law: Nernst distribution law in liquid-liquid systems, distribution


coefficient, statement of Nernst distribution law – verification of distribution
law taking distribution of I2 in H2O and CCl4 – limitations of the law,

75
conditions for the validity of distribution law, association of the solute in one of
the solvents, dissociation of the solute in one of the solvents, application of
distribution law with respect to solvent extraction process (numerical problems)

Unit-8 Physical Properties and chemical constitution: Additive and constitutive


properties, properties of liquids– viscosity, definition of coefficient of viscosity,
factors affecting viscosity – temperature, size, weight, shape of molecules,
intermolecular forces, determination of viscosity of liquids by Ostwald’s
method.

Surface tension: Definition, effect of temperature on surface tension, effect of


solute on surface tension, determination of surface tension of liquids using
stalgmometer.

Parachor: Definition – Sugden equation, calculation of parachor and its


application with respect to structural elucidation of benzene and quinone,
numerical problems based on surface tension, viscosity and parachor
applications

Block-3.3 Organic Chemistry

Unit-9 Alkyl Halides: IUPAC Nomenclature, Preparation: from alkenes and alcohols,
Reactions: hydrolysis, nitrite & nitro formation, nitrile & isonitrile formation,
Elimination vs substitution, Reactivity and Relative strength of C-Halogen
bond in alkyl, allyl, benzyl, vinyl and aryl halides,

Aryl Halides: Preparation: (Chloro, bromo and iodo-benzene case): from


phenol, Sandmeyer & Gattermann reactions, Reactions (Chlorobenzene):
Aromatic nucleophilic substitution (replacement by –OH group) and effect of
nitro substituent. Benzyne Mechanism: KNH2/NH3 (or NaNH2/NH3).

Unit-10 Carbonyl Compounds: Distinction between aldehydes and ketones, structure


of carbonyl group, reactivity trend, IUPAC Nomenclature, acidity of α-
hydrogen atom, synthesis of carbonyl compounds by oxidation and reduction

76
method, Reactions of carbonyl compounds:

Addition of alcohols- formation of hemiacetal and acetal, Condensation with


NH2OH and 2,4-DNP. Perkins reaction, Cannizzaro reaction, Claisen
condensation, Knovenagel reaction, Wittig reaction, Benzoin condensation.
Clemensen reduction and Wolff Kishner reduction. Meerwein-Pondorff Verley
reduction.

Unit-11 Reactions of carbonyl compounds: Aldol condensation, Mechanism of aldol


condensation, Synthesis of β-Hydroxy Carbonyls and α,β-Unsaturated
Carbonyls, The Mixed Aldol Reaction and Regiocontrol Involving Enolates,
Enolate Reactions: Synthesis of 1,3-Dicarbonyls, 1,5-Dicarbonyls, and
Cyclohexenones, Synthesis of Aromatic Ketones (Friedel–Crafts

Acylation) Synthesis of Aromatic Aldehydes (Formylation Reactions),


Iodoform reaction, Addition of organomagnessium, organozinc and
arganocopper reagents to carbonylgroup.

Unit-12 Carboxylic acids (aliphatic and aromatic), IUPAC nomenclature, Preparation:


Acidic and Alkaline hydrolysis of esters. Nitrile, amids, oxidation of alcohols
and carbonyl compounds, acidity of carboxylic acid group, Reactions: Hell –
Vohlard - Zelinsky Reaction, Reformatsky Reaction, Perkin condensation, α-
halogenation, decarboxylation,

Derivatives of carboxylic acids: synthesis of Acid chlorides, Anhydrides,


Esters, Lactums and Amides and their reactions.

Hydroxy acids: Synthesis of lactic, citric and tartaric acids. One method each
and their importance. Effect of heat on α, β, γ-hydroxy acids.

77
IV SEMESTER
CHEMISTRY PAPER-IV

Block-4.1 Inorganic Chemistry

Unit-1 Boron: Boron hydrates – diborane, preparation, structure and uses.

Carbon: allotropy of carbon, Fullerenes – production, structure of C60 and C70,


Diamond, graphite – properties and structure.

Silicon: Structure of silica. Silicates – types and structure with one example for
each type.

Nitrogen: Preparation, properties, structure and applications of hydrazine,


hydroxyl amine and nitrogen trichloride.

Unit-2 Sulphur: Preparation, properties, structures and applications of thionyl


chloride, sulphuryl chloride and SF6.

Halogens: Bleaching powder – preparation, properties and structure.

Pseudo halogens: Preparation, properties and structure of cyanogen and


thiocyanogen (any one method of preparation and any three properties to be
discussed).

Unit-3 Chemistry of transition elements: Position in the periodic table, electronic


configuration, general characteristics- atomic and ionic radii, ionization energy,
variable oxidation states, spectral properties, redox potentials, colour and
magnetic properties, catalytic activity, complex formation and interstitial
compounds formation (3d, 4d and 5d series).

Unit-4 Chemistry of inner transition elements: Electronic configuration and position


in the periodic table, oxidation states, spectral properties, colour and magnetic

78
properties, complex formatio n and ionic radii, lanthanide contraction – cause
and its consequences. General survey of actinides – comparison with
lanthanides, transuranic elements.

Block-4.2 Physical Chemistry

Unit-5 Ionic equilibria: Ionic equilibria in aqueous solutions, strong and weak
electrolytes – definition and examples. Ostwald’s dilution law (to be derived)
and its limitations (numerical problems). Activity and activity coefficients –
definition and their relation. Mean ionic activity coefficients – ionic strength –
determination and its calculation. Debye-Huckel theory of strong electrolytes
(relaxation time effect, electrophoretic effect and viscous effect).

Unit-6 Debye-Huckel-Onsagar equation, Debye-Huckel Limiting equation for activity


coefficients, Solvent system concept of acids and bases. Role of solvents in
altering strengths of acids and bases, Hydrolysis of salts – derivation of
hydrolysis constant and degree of hydrolysis of the salt of weak acid and weak
base (ammonium acetate), effect of temperature on degree of hydrolysis.

Unit-7 Thermodynamics: Introduction, First Law of Thermodynamics and its


limitations of– need for II Law of thermodynamics, spontaneous, non-
spontaneous and equilibrium processes (definitions and examples for each),
different ways of stating II Law, heat engine (example) Carnot cycle, efficiency
of Carnot cycle

(derivation), concept of entropy – definition and physical significances of


entropy – criteria of spontaneity in terms of entropy change, statements of II
law in terms of entropy (numerical problems to be worked out on entropy and
efficiency of Carnot engine)

Unit-8 Free energy: Helmholtz and Gibb’s free energy – their definitions and their
relationship, Gibb’s–Helmholtz equation at constant pressure and volume
(derivations), thermodynamic criteria of equilibrium and spontaneity, variation
of free energy with temperature and pressure, Claussius – Clappeyron equation

79
(differential form to be derived), integrated form of Claussius – Clappeyron
equation (to be assumed) and its applications (enthalpy of vapourization,
boiling point and freezing point at different temperatures), (numerical problems
on these applications), Van’t Hoff’s reaction isotherms and isochore equations
(to be derived).

Block-4.3 Organic Chemistry

Unit-9 Amines: Definition, classification with example. Separation of amine mixture


by Hinsberg’s method using toluene sulphonyl chloride. Distinction tests for 1°,
2°, 3° amines (acetylation and Hoffmann’s exhaustive methylation. Action of
nitric acid on different amines. Both aliphatic and aromatic 1°, 2°, 3° amines,
basicity of amines, effect of substituents on basicity of aliphatic and aromatic
amines. Hoffmann-Martius rearrangement.

Diazonium Compounds: preparation, mechanism of preparation and synthetic


applications of benzene diazonium chloride. Conversion to phenol,
halobenzene, phenyl hydrazine and coupling reaction.

Unit-10 Stereochemistry: Introduction, definition, elements of symmetry (plane,


centre, simple axes and alternative axes), asymmetry and dissymmetry,
Chirality, designation of configuration – R-S notation. Optical activity –
explanation – cause of optical activity (non-super impossibility). Enantiomers
and diastereomers optical isomerism in tartaric acid and biphenyls,
racemisation, resolution, methods of resolution (Chemical and biochemical
methods)

Unit-11 Geometrical isomerism: Definition with example, designation of cis-trans and


E-Z notations with examples. Geometrical isomerization of aldoximes and
ketoximes, Beckmann rearrangement, cis-trans conformations in disubstituted
cyclohexanone.

Conformational analysis of acycalic molecule: ethane, propane and butane and

80
bicyclic molecule: Decalins and substituted decalines

Unit-12 Active methylene compounds: Definition, ethyl acetoacetate, preparation and


keto-enol tautomerism in ethyl acetoacetate- its evidence.

Synthetic applications: Acid hydrolysis, ketonic hydrolysis, mono carboxylic


acids, dicarboxylicacids succinicacid, adipicacid, antipyrine, uracil, acetyl
acetone, crotonic acid and cinnamic acid.

81
V SEMESTER
CHEMISTRY PAPER-V

Paper –VA
Block- Inorganic Chemistry
5A.1

Unit-1 Nuclear chemistry: Fundamental particles of nucleus- nucleons, isotopes,


isobars and isotones (definition with suitable examples), Nuclear forces (brief
explanation), nuclear stability-n/p ratio, Mass defect, Binding energy, Inner
structure of nucleus- Liquid drop model, Nuclear fission- (definition with
suitable examples), Calculation of energy release in nuclear fission, modes of
release of fission energy (uncontrolled and controlled), Plutonium as a
fissionable material (Plutonium bomb),

Unit-2 Nuclear fusion and its advantages over nuclear fission reactions, hydrogen
bomb, nuclear transmutation-artificial radioactivity. Detection and
measurement of radioactivity – G. M. counter. Cyclotron, Nuclear reactor,
Breeder reactor, Q values of nuclear reactions. Uses of radio isotopes – tracer
technique, agriculture, medicine, food preservation and dating (explanation).
Separation of uranium isotopes – Laser irradiation method (atomic and
molecular routes).

Unit-3 Fuels: Definition, classification with examples – characteristics, calorific value,


determination of calorific value of a solid or liquid fuel. Applications of
gaseous fuels. Compressed natural gas, water gas, producer gas and LPG –
their production, composition and applications Propellants: Definition,
characteristics, classification and applications.

Unit-4 Abrasives: Definition, classification with examples – hardness, manufacture

82
and applications of carborundum, alundum and tungsten carbide.

Refractories: Definition, properties, classification with examples. Different


steps involved in the manufacture of refractories. Applications of refractories.
Explosives: Definition, classification with examples, characteristics of
explosives. Preparation and uses of dynamite, cordite and RDX.

Block- Physical Chemistry


5A.2

Unit-5 Crystallography: Elements of symmetry – plane, axis and center, elements of


symmetry in cubic crystals, law of rational indices – Weiss and Miller indices,
lattice planes in cubic crystals. Crystal lattice and unit cell, types of Lattice –
Bravais lattices.

Unit-6 X-Ray diffraction and Bragg’s Law (to be derived), determination of crystal
structure of rock salt by rotating crystal method using Bragg’s spectrometer,
application of X-ray studies – distance between lattice planes, density of
crystals, determination of Avogadro Numbe r (numerical problems on
applications).

Unit-7 Liquid Crystals: Definition, classification of thermotropic liquid crystals into


smectic and nematic with examples-molecular arrangement of these and their
uses.

Unit-8 Nanotechnology: Definition, uses and nature of nanotechnology,


Nanomaterials-definition, properties and applications, Carbon nanotubes-
definition, types, methods of preparation (mention), properties and industrial
applications of carbon nanotubes, Nanowires-definition, types, production of
crystalline nanowires by vapour- liquid-solid synthesis method, applications of
nanowires

Block- Organic Chemistry

83
5A.3

Unit-9 Organometallic compounds: Definition with example, organo zinc


compounds – preparation of diethyl zinc and its applications. Organo
magnesium compounds (Grignard reagent)- preparation and applications
Organolithium Compounds- Preparation and synthetic applications.
Organocopper reagents- Preparation and synthetic applications.

Unit-10 Active methylene compounds: Definition, ethyl acetoacetate, preparation and


keto-enol tautomerism in ethyl acetoacetate- its evidence.

Synthetic applications: Acid hydrolysis, ketonic hydrolysis, mono carboxylic


acids, dicarboxylic acidssuccinic acid, adipic acid, antipyrine, uracil, acetyl
acetone, crotonic acid and cinnamic acid.

Unit-11 Amines: Definition, classification with example. Separation of amine mixture


by Hinsberg’s method using toluene sulphonyl chloride. Distinction tests for 1°,
2°, 3° amines (acetylation and Hoffmann’s exhaustive methylation. Action of
nitric acid on different amines. Both aliphatic and aromatic 1°, 2°, 3° amines,
basicity of amines, effect of substituents on basicity of aliphatic and aromatic
amines. Hoffmann-Martius rearrangement.

Unit-12 Diazonium Compounds: preparation, Sandmeyer reaction, mechanism of


preparation and synthetic applications of benzene diazonium chloride.
Conversion to phenol, halobenzene, phenyl hydrazine and coupling reaction,
Nitro and nitraso compounds-preparations and synthetic applications

84
Paper –VB
Block-5B.1 Inorganic Chemistry

Unit-1 Coordination Chemistry: Ligands, classification of ligands and chelation,


nomenclature of co-ordination compounds, physical methods in the study of
complexes – change in conductance, colour and pH. Stability of complexes –
stability constant, a brief outline of thermodynamic stability of metal
complexes, factors affecting the stability of complexes. Polynuclear complexes,
inner metallic complexes.

Unit-2 Isomerism in co-ordination complexes: Stereo-isomerism – Geometrical and


optical isomerism exhibited by co-ordination compounds of co-ordination
number 4 and 6.

Unit-3 Metal-ligand bonding in transition metal complexes:

Valence bond theory: Salient features, formation of octahedral complexes on


the basis of VBT, outer and inner orbital octahedral complexes- [Fe(CN)6]4-,
[Fe(CN)6]3-, [Co(CN)6]3-, [CoF6]3- [Cr(H2O)6]3+ and [Fe(H2O)6]2+. Formation of
tetrahedral and square planner complexes on the basis of VBT – [Ni(CN)4]2-,
[Cu(NH3)]2+, [Zn(NH3)4]2+and [Ni(CO)4], limitations of VBT.

Unit-4 Crystal field theory: Important features of crystal field theory, crystal field
splitting of d-orbitals in tetrahedral, octahedral and square planar complexes,
crystal field stabilization energy (CFSE), factors affecting the magnitude of Δo,
(nature of ligand, oxidation state of the metal ion, size of the orbitals, geometry
of the complex)

high spin (HS) and low spin (LS) complexes, magnetic properties of metal
complexes based on crystal field theory-[Co(NH3)6]3+, [CoF6]3-, [Fe(CN)6]4-,
[Fe(CN)6]3- and [Ni(CN)4]2-. Magnetic susceptibility, measurement of magnetic

85
moment by Gouy’s method. Limitations of CFT.

Block-5B.2 Physical Chemistry

Unit-1 Electrochemistry-I: Introduction, conductance – specific conductance,


equivalent conductance and molar conductance – their definitions and SI units.
Conductance cell and cell constant. Determination of equivalent conductance
by meter – bridge method, ionic mobility, ionic conductance, Kohlrausch’s law
and its significance – determination of equivalent conductance at infinite
dilution for weak electrolyte.

Unit-2 Transport number: Definition and explanation, anomalous transport number


– explanation with examples, relationship between ionic conductance and
transport number (to be derived), determination of transport number by moving
boundary method – transport number of H+ using CdCl2 as supporting
electrolyte (numerical problems on equivalent conductance, transport numbers
and kohlra usch’s law).

Unit-3 Application of conductance measurements – (a) solubility and solubility


product of sparingly soluble salt, (b) ionic product of water, (c) degree of
ionization of weak electrolyte. Numerical problems for the applications of a, b
and c to be worked out. Conductometric titration: strong acid vs strong base,
weak acid vs strong base, strong acid vs weak base, weak acid vs weak base,
with suitable examples for each.

Unit-4 Phase equilibria: Gibb’s phase rule – definition of the terms with examples,
application to one component system (water system), reduced phase rule –
statement, reduced systems, two component system – simple eutectic type KI-
water system, freezing mixtures, Pb-Ag system (desilverization of
argentiferrous lead)

86
Block-5B.3 Organic Chemistry

Unit-5 Hetrocyclic Compounds: Definition, classification with examples, synthesis


of furan, thiophene, pyrrole, pyridine, indole (Fischer method) quinoline
(Skrup’s synthesis with mechanism), isoquinoline, pyrimidine (one method
each), aromaticity and basicity of pyrrole and pyridine. Electrophillic
substitution reactions of pyrrole and pyridine.

Unit-6 Carbohydrates: Definition and importance, classification based on


composition with examples-reducing and non-reducing sugars.

Monosaccharides: Glucose: reactions of glucose (with H2N-OH, HCN,


C6H5NHNH2, Br2 water, Conc. HNO3, reductions with HI/red P , methanols,
(dry HCl), acetic anhydride and reduction reactions.

Structural elucidation of glucose: Open chain structure, configuration,


drawbacks of open chain structure, ring structure.

Unit-7 Fisher and Haworth structure. Determination of ring size by methylation


method. Fischer and Haworth structures of fructose, galactose and mannose.

Conversion reactions – 1. Ascending (Kiliani’s synthesis) 2. Descending


(Wohl’s degradation) 3. Aldose to ketose 4. Ketose to Aldose 5. Epimerisation

Disaccharides: Structural elucidation of sucrose, structural formulae of maltose


and lactose (Haworth tructure).

Polysaccharides: Partial structural formulae of starch, cellulose, glycogen and


their uses.

Unit-8 Alkaloids: Definition, classification based on heterocyclic rings- isolation,


synthesis and structural elucidation of nicotine and morphine, physiological
importance of alkaloids.

Uric acid: Elucidation of structure and synthesis by Fischer’s method,

87
conversion of uric acid to purine and caffeine

Paper –VC
Block- Inorganic Chemistry
5C.1

Unit-1 Non-aqueous solvents: Liquid ammonia-reasons for the solvent properties,


typical reactions- solubility of alkali metals; acid-base, precipitation,
ammonolysis, Ionization of weak acids, advantages and disadvantages.

Liquid SO2-reasons for the solvent properties, typical reactions-acid-base,


solvolysis, precipitation, amphoteric and redox

HSAB: Classification of acids and bases as Hard and Soft. Pearson’s HSAB
concept, acid-base strength, hardness and softness, symbiosis.

Unit-2 Metal carbonyls: Definition, classification with examples, nature of M-CO


bonding in carbonyls. Preparation, properties and structures of mono nuclear
and binuclear metal carbonyls-Ni(CO)4, Cr(CO)6, Fe(CO)5, Mn2(CO)10,
Co2(CO)8. Applications of EAN rule to mononuclear metalcarbonyls.

Unit-3 Metallurgy: Types of metallurgy: Pyrometallurgy: Extraction of Nickel from


sulphide ore – general metallurgy followed by Mond’s process (purification),
manganese from oxide ores – reduction by the Aluminothermite process –
refining by electrolytic process.

Hydrometallurgy: Extraction of gold from native ore by cyanide process and


refining by quartation process.

Unit-4 Nanotechnology: Definition, uses and nature of nanotechnology,


Nanomaterials-definition, properties and applications, Carbon nanotubes-
definition, types, methods of preparation (mention), properties and industrial
applications of carbon nanotubes, Nanowires-definition, types, production of
crystalline nanowires by vapour- liquid-solid synthesis method, applications of

88
nanowires.

Block- Physical Chemistry


5C.1

Unit-5 Electromotive force-I: Electrolytic and electrochemical cells, electrode


reaction of Daniel cell, single electrode potential, sign of electrode potential-
convention (reduction potential to be adopted), convention of representing a
cell, EMF and standard EMF of a cell, cell reaction, reversible and irreversible
cells, Nernst equation (to be derived) and calculation of electrode potential.

Unit-6 Standard hydrogen gas electrode, reference electrodes-calomel and Ag-AgCl


electrode-construction and working. Electrochemical series and its significance,
equilibrium constant and free energy of cell reaction, spontaneity of a cell
reaction, Concentration cells. EMF of concentration cells- Definition,
explanation – with transference and without transference.

Unit-7 Liquid junction potential and salt bridge. (Numerical problems on Nernst
equation and EMF calculations). Fuel cells: Working of H2-O2 fuel cell and its
importance.

Unit-8 Electromotive force-II: Application of EMF measurements: (a) Determination


of pH of a solution using quinhydrone electrode and glass electrode (using dip
type Calomel electrode) – Explanation with principle and procedure. (b)
Potentiometric titration – principle, location of end points in - (1)
Neutralization reactions [NaOH Vs HCl] (2) Oxidation-reduction reactions
[K2Cr2O7 Vs FAS] (3) Precipitation reaction [KCl Vs AgNO3] and (4)
Complexometric reactions (ZnSO4 Vs K3[Fe(CN)6])

Block- Organic Chemistry


5C.3

89
Unit-9 Chromatography: Paper: introduction to ascending, descending and circular,
Rf value and it’s applications

TLC: Introduction and applications

Column Chromatography: Introduction, principle and experimental details


and applications

Gas Chromatography: Introduction, apparatus, programmed temperature gas


chromatography, quantitative analysis of GLC

HPLC: Introduction, schematic diagram of instrumentation and application.

Unit-10 Amino acids: Structure of α-amino acids, peptide bond, protecting groups-Boc,
Z, F-moc groups, use of HOBt and HOAt.

Vitamins: Definition, classification, structural elucidation and synthesis of Vit-


A, Synthesis of Vit-C, structural formulae of Vit B1, B2, B6, calciferol, E and K
and their importance.

Unit-11 Terpenes: Definition, isoprene rule, classification, isolation (solvent extraction


and steam distillation) structural elucidation of citral and its synthesis,
structural formulae of α-terpeniols, camphor and menthol.

Natural Pigments: Introduction to antho cyanines, structural formulae and


their importance of antho cyanins, β-carotene and haemoglobin.

Unit-12 Special techniques in organic synthesis:

a) Polymer supported reagents – introduction, properties of polymer support-


advantages of polymer support reagents, choice of polymers, types and
applications.

b) Phase transfer catalysis – introduction, definition, types, preparation,


mechanism and advantages.

c) Microwave induced organic synthesis – introduction, reaction vessel,


reaction medium, advantages, limitations, precaution and applications.

90
d) Sonochemistry – use of ultra sound in organic synthesis, introduction,
instrumentation, physical aspects, types and applications.

VI SEMESTER
CHEMISTRY PAPER-V
Paper-6A
Block- Inorganic Chemistry
6A.1

Unit-1 Inorganic polymers: Definition – examples, general properties, comparison


with organic polymers, glass transition temperature

Silicones: Definition, nomenclature, preparation (linear, cross- linked and


cyclic). Factors affecting the nature of silicon polymers, properties (chemical
and thermal stabilities, chemical properties) uses of silicon polymers, silicon
fluids/oils – uses, silicon elastomers – rubbers, silicon resins (preparation and
uses)

Unit-2 Phosphazenes: Definition, types, structures, preparation, properties and uses.


Crystalline polymetaphosphates – Maddrell’s and Kuroll’s salts – properties
and uses. Nature of bonding in phosphazenes.

Fluorocarbons: Definition, examples, preparation, properties and uses of


Freon-12, Freon-22, PTFE and poly per fluorovinyl chloride

Unit-3 Paints: Constituents and their functions, manufacture of lithopone and titanium
dioxide.

Fertilizers: Definition and classification, manufacture of nitrogeneous


fertilizers – CAN and urea. Phosphatic fertilizers – calcium dihydrogen
phosphate, NPK type fertilizers.

Unit-4 Fuels: Definition, classification with examples – characteristics, calorific

91
value, determination of calorific value of a solid or liquid fuel. Applications of
gaseous fuels. Compressed natural gas, water gas, producer gas and LPG –
their production, composition and applications.

Propellants: Definition, characteristics, classification and applications.

Block- Physical Chemistry


6A.2

Unit-5 Crystallography: Elements of symmetry – plane, axis and centre, elements of


symmetry in cubic crystals, law of rational indices – Weiss and Miller indices,
lattice planes in cubic crystals. Crystal lattice and unit cell, types of Lattice –
Bravais lattices, X-Ray diffraction and Bragg’s Law (to be derived),
determination of crystal structure of rock salt by rotating crystal method using
Bragg’s spectrometer,

Unit-6 Application of X-ray studies – distance between lattice planes, density of


crystals, determination of Avogadro Number (numerical problems on
applications).

Liquid Crystals: Defination, classification of thermotropic liquid crystals into


smectic and nematic with examples-molecular arrangement of these and their
uses.

Unit-7 Spectrophotometry and photochemistry: Lambert – Beer’s law – statement


and mathematical form (to be derived). Molar extinction coefficient – definition
– spectrophotometer – construction and working, its application.

Laws of photochemistry – Grotthus-Draper law of photochemical activation


and Einstein’s law of photochemical equivalence, quantum efficiency, reasons
for low quantum yield (HBr formation as example) and high quantum yield
(HCl formation as example), actinometry – Uranyl oxalate actinometer.

Unit-8 Photophysical processes: Definition with examples – photosensitization (eg.


photosynthesis in plants), photo inhibition, fluorescence, phosphorescence,

92
chemiluminescence and bioluminescence with examples. Determination of
absorbed intensity – schematic diagram of apparatus used. Detectors –
thermopile,photoelectric cell and actinometer (Uranyl oxalate).

Block- Organic Chemistry


6A.3

Unit-9 UV-visible spectroscopy: Introduction, chromophores and auxo chrome, blue


shift and red shift, graphical representation of spectra of 1,3-butadiene, benzene
and lycopene. Influence of conjugation on UV absorption-comparison of UV
spectra of acetone and methylvinyl ketone

Unit-10 IR-Spectroscopy: Introduction, stretching frequency of –OH (free and H-


bonded), alkyl –C-H, C=C, C=C, C-C, C=O and C-O groups (by taking suitable
examples). Graphical representation of IR spectra of benzoic acid and methyl
benzoate

Unit-11 NMR Spectroscopy: Basic principles of proton magnetic resonance , nuclear


magnetic spin quantum number I, influence of the magnetic field on the spin of
nuclei, spin population, saturation using radio frequency, nuclear magnetic
resonance-chemical shift ( δ value), uses of TMS reference, nuclear shielding
effects, equivalent and non-equivalent protons, spin-spin splitting and coupling.

Unit-12 Applications of NMR spectroscopy to simple organic molecules (like ethyl


alcohol, ethane, propane, ethylene, methylamine, aniline, benzene, toluene,
acetone, acetophenone, methyl cyanide and other simple molecules.

93
Paper-6B

Block-6B.1 Inorganic Chemistry

Unit-1 Gravimetry: Introduction to gravimetric analysis – precipitation methods


(various steps involved to be discussed), advantages of gravimetric analysis,
purity of the precipitates, co-precipitation and post precipitation, conditions of
precipitation, precipitation from homogeneous solution (hydroxides and
sulphates), washing and ignition of precipitate (general discussion only).
Electro-gravimetric analysis estimation of copper. Organic precipitants:
Advantages of organic precipitants over inorganic precipitants, DMG, 8-
hydroxy quinoline (Oxine), 1,10-phenanthroline and EDTA. Structure of Ni2+-
DMG and Mg2+-oxine complexes

Unit-2 Glasses, Ceramics and composite: Glasses, Ceramics Composites and Nano-
materials: Glassy state, glass formers and GlassModifiers. Glasses, Ceramics,
Clay products, Refractories with reference to: preparation, Properties and
applications. Microscopic composites, dispersion, strengtheried and
particlereinforced, fibre reinforced Composites, microscopic composites,
nanocrystaline phase, preparation procedure, special properties and
applications,

Ores: Composition and analysis of the followings ores- Bauxite, Pyrolusite,


Dolomite, Chromite.

Portland cement: Composition, raw material, manufacturing processes,


characteristics, analysis

Unit-3 Analysis of alloys: Definition of alloy, Phase diagrams of Fe-C, Pb-Sn, Pb-Ag
systems and their applications. Types of steel: hypoeutectic, hypereutectic

94
steels, mild steel, and stainless steel. Uses of steel. Composition and uses of
brass, bronze and soldering alloy. Analysis of iron, nickel, chromium and
manganese in steel. Analysis of copper and zinc in brass, lead and tin in
soldering alloy. Industrial applications of alloys.

Unit-4 Analysis of petroleum and petroleum products: Introduction, determination


of flash and fire point, Pensky Marten’s apparatus, cloud and pour point,
aniline point, drop point, viscosity and viscosity index, Redwood and Saybolt
viscometer, API specific gravity, water and sulphur in petroleum products,
carbon residue, corrosion stability, decomposition stability, emulsification,
neutralization and saponification number.

Block-6B.2 Physical Chemistry

Unit-5 Chemical Kinetics: Introduction – differential and integrated rate equations for
second order kinetics, derivation of second order rate equation when a=b and
a≠b, unit of rate constant, half- life period, experimental verification of second
order reactions – study of kinetics of saponificaiton of an ester, determination
of the order of reaction – differential, time for half-change method and isolation
method.

Experimental methods of chemical kinetics, conductometric – example -


saponification of esters.

Unit-6 Potentiometric - example – kinetics of bromination of N,N-di-methyl aniline


and spectrophotometric – example – colorimetric study of kinetics of oxidation
of Indigocarmine by chloramine-T.

Application of kinetic studies: Arriving at the mechanism of urea formation


from ammonium cyanate.

Unit-7 Phase equilibria: Gibb’s phase rule – definition of the terms with examples,
application to one component system (water system), reduced phase rule –
statement, reduced systems, two component system – simple eutectic type KI-
water system, freezing mixtures, Pb-Ag system (desilverization of

95
argentiferrous lead)

Unit-8 Radiation Chemistry: Definition, primary and secondary stages in


radiochemical reactions, ionic yield, energy yield, comparison with
photochemistry, units of radiation – rad, gray and roentgen, Dosimeter – Fricke
dosimeter, theories of radiolysis – Lind’s and EHT theories. Radiolysis of
water vapour, benzene and

acetic acid

Block-6B.3 Organic Chemistry

Unit-9 Substitution reactions: Nucleophilic substitution reaction, SN1 and SN2 with
energy profile diagram. Stereochemistry and mechanism of SN1 and SN2
reaction, Walden inversion, Factors affecting the rate of SN1 and SN2
reactions- nature of alkyl groups, nature of leaving groups, nucleophiles and
solvents.

Unit-10 Elimination reactions: E1 and E2 reactions, mechanisms of E1 and E2


reactions, Stereochemistry of elimination reactions- Anti and Syn, Factors
affecting the rate of E1 and E2 reactions- nature of alkyl groups, nature of
leaving groups, nucleophiles and solvents, Substitution v/s Elimintion
reactions. EICB reactions,

Unit-11 Additions reactions: Additions to Alkenes and Alkynes, Syn Additions, Anti
Additions, Additions to Carbonyls- Diastereoselectivity in Acyclic Systems:
Cram’s Rule, Felkin–Ahn Model, Chelation Control by Neighboring Groups,
Addition to Cyclohexanones, Additions to Enolates- Formation of (E) and (Z)
Enolates.

Unit-12 Synthesis of cyclic compounds: Synthesis of Cyclopropanes, Synthesis of


Cyclobutanes, Synthesis of Five-Membered Rings (Radical Cyclization
Reactions), Baldwin’s Rules, Synthesis of Six-Membered Rings (Diels–Alder
Reaction)- The Dienophile (E+), The Diene (Nu:) Regiochemistry of the Diels–

96
Alder: 1,2-Disubstituted Product Is Preferred Over 1,3, 1,4-Disubstituted
Product Is Preferred Over 1,3. Robinson annulation.

Paper- 6C

Block- Inorganic Chemistry


6C.1

Unit-1 Introduction, Components of Environment, Biosphere, Lithosphere,


Hydrosphere and Atmosphere, Ecological principles- aspects of ecology,
classification, types of ecosystems. Environmental Pollution and
Environmental Pollutants, Some Commonly used terms in Environmental
Pollution, Types of Pollution, Smog, Greenhouse Effect and Global Warming,
Ozone Layer and its Depletion (Stratospheric Pollution), Soil or Land
Pollution, Strategies to Control Environmental Pollution, Green Chemistry as
an Alternative Tool for Reducing Pollution

Unit-2 Water pollution and analysis: Sources of water pollution, composition of


potable water,importance of water analysis, sampling and sample preservation,
physico-chemical analysis ofwater. Mineral analysis (temperature, pH,
conductivity, turbidity, solids, alkalinity, chloride,fluoride, sulphates,
hardness), Demand analysis (DO, BOD, COD, TOC), nutrients (nitrogen-
total,nitrate, nitrite, phosphate) and heavy metals (As, Cd, Cr, Hg and Pb). A
brief idea of coagulation and flocculation. Water treatment plants: Sand filters
and other types of filters.

Unit-3 Air pollution and analysis: Air pollution and analysis-classification of air
pollutants, sources of air pollution and methods of control, sampling of aerosols
and gaseous pollutants and their effects, SO2, NO2, CO, CO2, particulates-SPM,
RSPM, High Volume Sampler, Fabric Filters, Cyclones (direct and Reverse),
ESP,

Thermal pollution—sources, harmful effects and prevention of thermal

97
pollution.

Noise pollution --- sources, effects and control of noise pollution

Unit-4 Bio-inorganic chemistry: Essential and trace elements in biological process,


metalloporphyrins with special reference to haemoglobin and myoglobin,
oxygen uptake, structure and functions of haemoglobin, myoglobin,
Oxygenation and deoxygenation, biological role of alkali and alkaline earth
metal ions with respect to Na+ and Ca2+ ions, Photosynthesis and nitrogen
fixation reactions.

Block- Physical Chemistry


6C.2

Unit-5 Molecular Spectroscopy: Regions of spectra, types of spectra, microwave


spectra – rotational spectra of diatomic molecules, moment of inertia
(expression to be derived). Expression for rotational energy, selection rule and
transition, calculation of bond length, Isotopic effect.

Unit-6 IR Spectra – vibrational spectra of diatomic molecules – forceconstant (no


derivation), expression for vibrational energy, zero point energy.Selection rule
and transitions. Vibrational modes of polyatomic molecules taking H2O and
CO2 molecules as examples. Applications of IR spectroscopy (mention).

Unit-7 Raman Spectra: Concept of polarizability, pure rotation, vibration (qualitative


study) stoke’s and antistoke’s lines, selection rule, applications (mention)

Electronic Spectra: Potential energy curves for bonding and antibonding


molecular orbitals, band theory, electronic transitions, qualitative description of
non-bonding orbitals and transition between them. Selection rule and Franck
Condon principle.

Unit-8 Lattice Defects: Per fect &Imperfect crystals, point defects, Interstitial,
Schottky defect, Frenkel defect, line defect & other entities, thermodynamics of
Schottky & Frankel defects. Dissociation, theory of dislocation, plane defects-
Lineage boundary, grain boundary, stacking fault, 3D defects, Defects & their

98
concentrations, ionic conductivity in solids, Non stoichiometric compounds.

Electronicproperties of Non-stoichiometric oxides.

Block- Organic Chemistry


6C.3

Unit-9 Green Chemistry: Purpose, principles to be followed for green chemistry.


Synthesis of acetamide, ibuprofen, benzoin, benzylic acid and para-bromo
acetanilide.

Natural Pigments: Introduction to antho cyanines, structural formulae and


their importance of antho cyanins, β-carotene and haemoglobin.

Unit-10 Organic Polymers: Monomer and repeating units, Condensation polymers,


addition polymers, natural polymer- rubber, vulcanization of rubber, silk, hair,
synthetic polymer- poly styrene, PVC, PEG, polyethelen, Nylon66, terylene ,
synthesis and their applications, gals transition temperature.

Unit-11 Dyes: Colour and constitution, chromophore - oxochrome theory, classification


of dyes based on applications with examples, synthesis of indigo and malachite
green, structural elucidation of alizarin and its synthesis.

Terpenes: Definition, isoprene rule, classification, isolation (solvent extraction


and steam distillation) structural elucidation of citral and its synthesis,
structural formulae of α-terpeniols, camphor and menthol.

Unit-12 Drugs: Chemotherapy and chemotherapeutic agents, definition of drugs, types


of drugs, antipyretics, analgesics, anesthetics, sedatives, narcotics, antiseptics,
antibacterials, antibiotics, antimalarials and sulpha drugs with examples.
Synthesis of paracetamol, sulphanilamide, sulphaguanidine

99
Chemistry Syllabus for Practical for B.Sc. Course
Note: Students should be trained to use electronic balances
72hr per semester
I Semester: Practical – I
1. Calibration of: (i) Pipette (ii) Burette (iii) Volumetric flask
2. Preparation of 2N solutions of H2SO4, HCl, HNO3, CH3COOH and NH3
3. Preparation of standard sodium carbonate solution and standardization of
hydrochloric acid solution (methyl orange indicator). Estimation of sodium hydroxide
present in the solution using phenolphthalein indicator.
4. Preparation of standard oxalic acid solution and standardization of sodium hydroxide
solution. Estimation of sulphuric acid present in the solution
5. Preparation of standard potassium biphthalate solution and standardization of sodium
hydroxide solution. Estimation of oxalic acid present in the solution.
6. Preparation of standard oxalic acid solution and standardization of potassium
permanganate solution. Estimation of ferrous ammonium sulphate present in the
solution
7. Preparation of standard oxalic acid solution and standardization of potassium
permanganate solution. Estimation of hydrogen peroxide present in the solution.
8. Estimation of sulphuric acid and oxalic acid in a mixture using standard sodium
hydroxide and standard potassium permanganate solutions.
9. Determination of the percentage of available chlorine in the given sample of
bleaching powder.
10. Estimation of ferrous and ferric iron in a given mixture using standard potassium
dichromate solution.
11. Preparation of standard zinc sulphate solution and standardization of EDTA.
Estimation of total hardness of water.
12. Estimation of ammonium chloride using standard sodium hydroxide and standard
hydrochloric acid solutions (back titration).

100
II Semester: Practical – II
Part 1: Qualitative analysis of mono functional organic compounds through functional group
analysis. Determination of physical constant and preparation of suitable derivative of the
following class
1. Acids
2. Alcohols
3. Aldehydes
4. Amides
5. Amines
6. Halogenated hydrocarbons
7. Hydrocarbons
8. Ketones
9. Nitro compounds
10. Phenols
Part 2: Organic preparations: Recrystallization and determination of melting point and its
importance may be mentioned
1. Acetylation: Preparation of acetanilide from aniline
2. Oxidation: Preparation of benzoin acid from benzaldehyde
3. Reduction: Preparation m-nitrobenzylacohol from m-nitrobenzaldehyde
4. Hydrolysis: preparation of benzoic acid from ethyl benzoate

101
III Semester: Practical – III
Systematic semi-micro qualitative analysis of a mixture of two simple salts (with no
interfering radicals) including ionic reactions
The constituent ions in the mixture to be restricted to the following
Anions: HCO3-, CO32-, SO3-, Cl-, Br-, NO3-, BO33-, SO42- and PO43-
Cations: Pb2+, Bi3+, Cd2+, Al3+, Fe3+, Fe2+, Mn2+, Zn2+, Ba2+, Sr2+, Ca2+, Mg2+, K+, Na+ and
NH4+
Note:
1. Mixtures requiring elimination of phosphate and borate should not be given.
2. Combination of anions in 2nd group shall be avoided.
3. Salts that yield double decomposition shall be avoided (like BaSO4).
4. The combination of two cations in the mixture should belong to different groups.
However combinations like Mg2+ and NH4+ and Na+ and NH4+ can be given.

IV Semester: Practical – IV
1. Determination of the density using specific gravity bottle and viscosity of a liquid
using Ostwald’s viscometer.
2. Determination of the density using specific gravity bottle and surface tension of a
liquid using stalagmometer.
3. Determination of molecular mass of a non-volatile solute by Walker-Lumsden
method.
4. Determination of rate constant of the decomposition of hydrogen peroxide catalyzed
by FeCl3.
5. Determination of transition temperature of the salt hydrates.
6. Determination of rate constant of saponification of ethyl acetate titrimetrically.
7. Determination of percentage composition of sodium chloride solution by determining
the miscibility temperature of phenol - water system.
8. Determination of the mass present in the given solution of a strong acid using strong
base by thermometric titration method.

102
9. Determination of molecular weight of a polymer material by viscosity measurements
(cellulose acetate/methyl acrylate).
10. Study of kinetics of reaction between K2S2O8 and KI, second order, determination of
rate constant.
11. Determination of distribution coefficient of iodine in water and carbon tetra chloride.
V Semester: Practical – V and VI
Practical - V:
Gravimetric Estimations:
1. Gravimetric estimation of barium as barium sulphate.
2. Gravimetric estimation of iron as iron (III) oxide.
3. Gravimetric estimation of copper as copper (I) thiocyanate.
4. Gravimetric estimation of nickel as nickel dimethylglyoximate.
5. Gravimetric estimation of magnesium as magnesium -8-hydroxy oxinate.
6. Gravimetric estimation of sulphate as barium sulphate.
7. Gravimetric estimation of aluminum as aluminum oxide.
8. Gravimetric estimation of zinc as zinc oxide.
9. Gravimetric estimation of calcium as calcium oxide.
10. Paper chromatographic separation of Fe3+ and Ni2+ ions.
11. Paper chromatographic separation of Na+ and K+ ions
PRACTICAL - VI:
Ore and Alloy Estimations:
1. Preparation of standard potassium dichromate solution and estimation of iron in the
given sample of hematite by dichromate method.
2. Estimation of percentage of calcium in limestone by oxalate method.
3. Estimation of manganese in the given sample of pyrolusite.
4. Estimation of magnesium in the given sample of dolomite by EDTA method.
5. Estimation of copper in bronze by iodometric method.
6. Estimation of tin in solder using EDTA.
Preparation of Inorganic Complexes
1. Preparation of mercurytetrathiocyanatocobaltate(II).
2. Prparation of potassiumtrisoxalatoferrate(III).
3. Preparation of ferrousoxalate.
4. Preparation of potassiumbisoxalatodiaquachromate(III).
103
5. Preparation of chloropentaminecobalt(III)chloride.
6. Preparation of manganese (III)acetylacetonate.

VI Semester – Practical VII and VIII

Practical VII:
1. Determination of equivalent conductance of the given electrolyte (strong and weak)
by using Meter Bridge.
2. Determination of solubility of sparingly soluble salt (like BaSO4) by conductometric
method.
3. Determination of Ka (dissociation constant of a weak acid) by conductometric
method.
4. Determination of rate constant of saponification of ethyl acetate by conductivity
measurements.
5. Conductometric titration of strong acid and strong base and weak acid and strong
base.
6. Determination of percentage composition of a given mixture containing two miscible
liquids by Abbe’s refractometer.
7. Potentiometric titration of ferrous ammonium sulphate against potassium dichromate.
8. pH titration of strong acid against strong base ( by observing change in pH).
9. Potentiometric titration of mixture of HCl and CH3COOH using NaOH solution.
10. Colorimeteric estimation of Fe3+ ion using ammonium thiocyanate as complexing
agent.
11. Colorimeteric estimation of Cu2+ ion using NH4OH as complexing agent.
12. Colorimeteric study of kinetics of oxidation of indigocarmine by chloramine-T.
Practical-VIII
Organic Estimations:
1. Separation of p- and o- nitroaniline by TLC method (Solvent extraction).
2. Separation of p- and o- nitroaniline by column chromatography.
3. Estimation of glucose by Fehling solution method.
4. Estimation of Phenol by acetylation method.

104
5. Estimation of ascorbic acid by iodometric method.
6. Determination of Iodine value of oils by chloromine-T.
7. Isolation of Caffeine from tea powder.
8. Isolation of Castor oil from Castor seeds.
9. Estimation of neutral amino acids by titrametric method.
10. Estimation of carboxylic acid by titrametric method.
11. Estimation of –NH2 group by acetylation method.
12. Determination of saponification value of oils.

Reference books
Inorganic chemistry
1. A Text book of Inorganic Chemistry; P. L. Soni, Sultan Chand & Sons
2. A Text book of Inorganic Chemistry; B. R. Puri & L. Sharma, Shobhanlal Nagin
Chand Co.
3. Principles of Inorganic Chemistry; Puri, Sharma & Kalia Shobhanlal Nagin, Chand
Co.
4. A Text book of Inorganic Chemistry; Gurudeep Raj, Krishna Prakashan Media (P)
Ltd
5. Concise Inorganic Chemistry; J. D. Lee, Well Science Ltd.
6. A Text book of Inorganic Chemistry; Sathya Prakash & others, S Chand & Co Ltd.
7. Basic concepts of Analytical Chemistry; S. M. Khopkar, New Age International
8. Selected Topics in Inorganic Chemistry; Madan, Malik & Tuli S. Chand & Company
9. A Text book of Inorganic Chemistry; A. K. De, New Age International
10. Comprehensive Inorganic Chemistry; O. P. Agarwal; Disha Publication.
11. Inorganic Chemistry; Kapoor & Chopra, R. Chand & Co
12. Engineering Chemistry; B. K. Sharma, Krishna Prakashan Media P. Ltd.
13. Industrial Chemistry; B. K. Sharma, Krishna Prakashan Media P. Ltd.
14. Engineering Chemistry; Jayaprakash & Venugopal,
15. Engineering Chemistry; Jain and Jain, Dhanpal & Sons, New Delhi
16. Hand book of Industrial Chemistry; Riegel’s James A. Kent B. S. Publishers &
Distributors
17. Instrumental methods of Chemical analysis; B. K. Sharma, Goel Publishing House
105
18. Elements of Nuclear Chemistry R. Gopalan Vikas Publishing House
19. Industrial Chemistry B. N. Chakarbathy Oxford & IBH Publishers
20. Instrumental methods of Chemical analysis; Gurdeep R. Chatwal & Anand Sham,
Himalaya Publishing House
21. A Textbook Quantitative analysis; A. I. Vogel, ELBS
22. A Textbook Quantitative analysis; A. I. Vogel, ELBS
23. Management of Water Resources in Agriculture; V. S. Shreramulu,
24. Inorganic Polymers; C. R. Chatwal, Himalaya Publishing House
25. Theoretical Principles of Inorganic Chemistry; Manku, Tata McGraw Hills
26. Advanced Practical Inorganic Chemistry; Gurudeep Raj, Goel Publishing House
27. Experimental Inorganic/Physical Chemistry; Mounir A. Malati Horward Series in
Chemical science
28. University Chemistry; C. N. R. Rao, Mac Millan Company
29. A Text book of Inorganic Chemistry; Robinson & Heslop, New Age Publications
30. A Text book of Inorganic Chemistry; Emeleus & Anderson, New Age Publications
31. A Text book of Inorganic Chemistry; F. A. Cotton & G. Wilkinson, Wiley
Interscience
32. Analytical Chemistry; Willard, Meritind & Dean, New Age Publications
33. Advanced Chemistry; Philip Mathews, Cambridge University Press
34. Instrumental methods of Chemical analysis; H. H.Willard, L. L. Merrite, K. A. Dean
& F. A. Skettle, CBS Publishers
35. A Text book of Inorganic Chemistry; Emelius H. J., Sharpe A. G., University Book
Stall New Delhi
36. Theoretical Inorganic Chemistry; Dey & Selbin, University Book Stall New Delhi
37. Analytical Chemistry; John. H. Chenady, Saunders College, Publishing New York
38. Introduction to nanoscience & nanotechnology; Chattopadhyay, PHI
39. Nanotechnology fundamentals & applications; Manasi Karkare, IKI NTPC
40. Nanotechnology; Richard Brooker , Earl boyson, Wiley Dream Tech India
41. Advances in nanoscience & nanotechnology; Dr. Shuthosh Sharma & Dr. Bellari,
CSIR Publications

Organic chemistry
1 A Text book of Organic Chemistry; M. K. Jain, S. Chand & Company
106
2 A Text book of Organic Chemistry; Bhal & Bhal., S. Chand & Company
3 A Text book of Organic Chemistry; P. L. Soni., S. Chand & Company
4 Laboratory Manual of Organic Chemistry; Raj K. Bansal., New Age Publications
5 Laboratory Manual of Organic Chemistry; Jayaraman., S. Chand & Company
6 Chemistry of Natural products; Aggarwal., Goel Publishing House Meerut
7 Organic Chemistry; K. K. Sharma., Shobhanlal & Nagan Company
8 Organic Chemistry; Puri & Sharma., Shobhanlal & Nagan Company
9 Medicinal Chemistry; Ashuthosh Kar., Tata Mcgraw Hill Publications
10 Organic Chemistry; Handrickson., Tata Mcgraw Hill Publications
11 Organic Synthesis special techniques V. K. Ahluwalia & Renu Aggarwal Narosa
publishing House
12 Organic Chemistry Vol. I & II I. L. Finar ELBS
13 Stereo Chemistry Eliel John Wiley Eastern Publications
14 Text Book of Qualitative & Quantitative Organic Analysis; Arthur Vogel, ELBS
15 Heterocyclic Chemistry; Raj K. Bansal, Tata Mcgraw Hill,Publications
16 Laboratory Manual of Organic Chemistry; Skoog & West, Prentice-Hall of India Pvt.
India
17 Manual of organic Chemistry; Dey & Seetharaman, Allied Publishers.
18 A text book of practical organic chemistry (Volume-III); A. I. Vogel
19 Practical Organic chemistry; Mann & Saunders,
Physical Chemistry
1 Physical Chemistry; R. P. Verma, Pradeep Publication
2 Kinetics of Chemical Reactions; S. K. Jain, Vishal publications, Jalandhar New Delhi
3 Physical Chemistry; M. Kundan & S. K. Jain, S. Chand & Company
4 Text book of Physical Chemistry; K. K. Sharma & C. K. Sharma, Vani Educational Books
5 Biophysical Chemistry; Upadhyaya & Upadhyaya, Himalaya Publishing Homes
6 Principles of physical chemistry; Puri, Sharma &Pathania
7 Essentials of physical chemistry; B. S. Bahl, Arun Bahl & G. D. Tuli
8 Polymer Science; V. R. Gowriker, N. V. Vishwanathan & J. Sreedhar
9 Quantum Chemistry (2nd edition); A. K. Chandra,
10 Quantum Chemistry; R. K. Prasad,
11 Colloidal Chemistry; D. K. Sharma, Goel Prakashan. Meerut
12 Physical Chemistry; R. L. Madan & G. D. Tuli S., Chand & Company
107
13 Text book of advanced Physical Chemistry; Gurudeep Raj, Goel Prakashan. Meerut
14 Principles and Applications of Catalysis; B. Vishwanath, Narosa Publishing House
15 Engineering Chemistry; Jain & Jain; Dhanpal & Sons, New Delhi
16 Text Book of Physical Chemistry; B. D. Khosla, R. Chand & Publications
17 Fundamentals of Molecular Spectroscopy; Colin N. Banwell & Elleine M. Meeash,
Himalaya Publishing Group
18 Physical Chemistry; Colin N. Banwell, Himalaya Publishing Group
19 Physical Chemistry; Glasstone, ELBS
20 Text book of Chemical Kinetics; Laidier, New Age Publication
21 Text book of Photochemistry; W. Bansal, S. Chand & Company
22 Text book of Thermodynamics; Glasstone, East-West Press Pvt. Ltd.
23 Text book of Electrochemistry; Glasstone, East-West Press Pvt. Ltd.
24 Physical Chemistry; Rakshit,
25 Physical Chemistry; Pathania & Sharma, Vishal Publications Jalandhar &,Delhi

108
Annexure I
INTER- DISCIPLINARY COURSE
(Open Elective) for First Semester
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À gÀÄ, 1992
2. AiÀÄÄUÀzsÀªÄÀ ð ªÀÄvÀÄÛ ¸Á»vÀå zÀ±Àð£À: QÃwð£ÁxÀ PÀÄvÀðPÉÆÃn, ªÀÄ£ÉÆÃºÀgÀ UÀæAxÀ ªÀiÁ¯É, zsÁgÀªÁqÀ,
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3. PÀ£ÀßqÀ ¸Á»vÀå EwºÁ¸À: gÀA.²æÃ. ªÀÄUÀĽ, VÃvÁ §ÄPï ºË¸ï, ªÉÄʸÀÆgÀÄ, 2018
4. PÀ£ÀßqÀ ¸Á»vÀå ¸ÀAUÁw: QÃwð£ÁxÀ PÀÄvÀðPÉÆÃn, PÀ£ÀßqÀ «±Àé«zÁ央AiÀÄ, ºÀA¦, ºÉƸÀ¥ÃÉ mÉ, 1995
5. PÀ£ÀßqÀ ¸Á»vÀå ¸ÀAUÁw: (¥Àæ.¸ÀA) §gÀUÆ
À gÀÄ gÁªÀÄZÀAzÀæ¥Àà, PÀ£ÁðlPÀ ¸Á»vÀå CPÁqÉ«Ä, 2018
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109
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DEPARTMENT - ENGLISH
EL-1.1: INTER- DISCIPLINARY COURSE-I (OPEN ELECTIVE)

INDIAN LITERATURE-I

OBJECTIVES
 To help to understand the contribution of Kalidasa to Sanskrit drama as a
playwright
 To create an awareness of the importance of Shakuntala and Mrichhakatika as
classical Indian texts
 To evaluate Lord Macaulay and Raja Ram Mohan Roy writers of English
Prose.
 To introduce the role of Autobiographies in Indian writing in English
BLOCK –I
Kalidasa: Shakuntala
Shudraka: Mrichhakatika

BLOCK -II

Jawaharlal Nehru: An Autobiography


Ram Mohan Roy: Letter to Lord Amherst
Macaulay: Minutes on Indian Education
Vivekananda: Address to the Parliament of Religions
Suggested Reading:
 M.K.Naik: Critical Essays on Indian Writing in English. Sahitya Akademi, 1969.
 Narasimhaiah. C.D: The Swan and the Eagle. Indian Institute of Advanced Study,
1987.
 Meenakshi Mukherjee: The Twice Born Fiction. Heinemann Educational Publishers,
1972.

110
 Chirantan Kulshrestha. Contemporary Indian English Verse: An Evaluation.
Arnold-Heinemann, 1981.
DEPARTMENT - HINDI
व्यावहारिक हहिंदी एविं व्याकिण

वणण ववचाि

 वर्ण
 स्वर और उसका वर्गीकरर्
 व्यंजन और उसका वर्गीकरर्
 वर्ों का उच्चारर् स्थान
 संधि
 समास

शब्द ववचाि

 शब्द के भेद
 अथण के आिार पर शब्द भेद
 व्यत्ु पत्त्ि के आिार पर शब्द भेद
 रचना के आिार पर शब्द भेद
 प्रयोर्ग के आिार पर शब्द भेद
 ववकारी और अववकारी शब्द भेद
 अव्यय
 संज्ञा और उसके भेद
 वचन- उसके भेद, वचन पररविणन के ननयम
 ल र्ग
ं - उसके भेद, ल र्ग
ं पररविणन के ननयम
 का और उसके भेद
 कारक और ववभत्ति- उसके प्रकार,
 सवणनाम और उसके भेद
 ववशेषर् और उसके भेद
 क्रिया और उसके भेद
 क्रिया ववशेषर् और उसके भेद
 समच्
ु च्य बोिक और उसके भेद

111
 संबि
ं बोिक और उसके भेद
 ववस्मयाददबोिक और उसके भेद
 परसर्गण और उपसर्गण
 वाच्य और उसके प्रकार

वाक्य ववचाि

 वातय का अथण और पररभाषा


 वातय के प्रकार .... आहद

सससससस ससससस

 ससससससस ससससससस सससस– ससससससस सससस सससससससस सससस.


 ससससससस ससससससस– ससससससस सससस सससससससस सससस.
 सससससससससस ससससस सस सससस– ससससस ससससस सससससससस, सससस
ससससससस
 सससससस ससससस ससससससस सस सससस– सस. सससससससससससस सससससस,
ससससस ससस
 ससससससससस ससससस सससस-सससससस सससससससस– ससससससससस
ससससस ससससससस
 ससससस ससससससस- ससससससससससस सससस

DEPARTMENT - TELUGU

E. L. 1.1 Thilak Prathyeka Adhyayanam


Block - 1:Thilak Kavithvam - 1
Unit - 1:Amrutham Kurisina Raathri

Unit - 2:Thilak Padhya Kavithaa Vaibhavam

Unit - 3:Thilak Abhiruchulu - Alavaatlu

Unit - 4: Thapala bantrothu

Block - 2: Thilak Kavithvam


Unit - 1:Thilak Sahithya Parichayam - 1
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Unit - 2: Thilak Sahithya Parichayam - 2

Unit - 3:Thilak vachana kavithaa Vaibhavam - 1

Unit - 4: Thilak Vachana Kavithaa Vaibhavam – 2

DEPARTMENT - HISTORY
ANCIENT WORLD CIVILIZATIONS
(Egypt, Mesopotamia, Greek, Roman, Inca, Chinese)

Objective: The course is aims to understand major world civilizations. It is to provide a


global historical perspective of ancient world which special reference to Egypt,
china, Greek, Roman, Inca civilizations.
Pedagogy: personal contact programmes, audio video programmes, online lectures
Assignments, etc
Credits: 2.
Examination Duration: 11/2 hours and Maximum Marks:40
Course outcomes:

After completing this course the students should be able to


 Discuss the Egyptian and Mesopotamian civilizations.
 Analyse the political socio economic conditions of Greek Roman
civilizations.
 Evaluate the Chinese contributions to ancient world.

Block – I

Unit-1
Egyptian Civilization: Importance of the Nile, Geographical importance, Gift of Nile,
Political conditions.
Unit-2
Social, Economic and religious conditions, Literature and learning, arts and
architecture.
Unit-3
Mesopotamian Civilization, Sumer and Babylonian, Hammurabi’s code, Society and
Culture, Economic conditions, art and literature, Assyrian Empire.
Unit - 4
Greek Civilization, Political Organizations, the city, State, Alexander the Great,
Greek political theory, Religion, Philosophy, art and architecture, Characteristic of
Hellenistic Civilization.

Block – II
Unit - 5

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Roman Civilization, The Land and the people, the Government, Roman Republic,
Roman Empire, Roman Republic, The Empire, The Patricians and Plebeians, Punic
wars.
Unit – 6
Julius Caesar, his wars, fall Augustus Caesar, Social Economic Conditions, Roman art
and architecture.
Unit - 7
Painting, Sculpture, Roman Law, Roman Religion, Philosophy, Roman literature,
Decline of the Roman Empire.
Unit - 8
Inca Civilisation, Socio – economic Political conditions, Chinese Civilisation, Socio –
economic Political conditions.

Suggested readings:
1. Breasted,J.H. : Ancient Times, A History of the early world.
2. Rostovzeff,M.S. : History of Ancient World
3. Schvider.H : The History of Civilization
4. Swain.J.E. : A History of World Civilization
5. Breasted.J.H. : History of Egypt
6. Jastorow.M : The Civilization of Babylonia and Austria
7. Bury.J.E. & OTHERS: The Hellenistic Age
8. Bailey.C : The Legacy of Rome and others
9. Abot.F.F.: Society and Politics of Ancient Rome

DEPARTMENT – ECONOMICS
EL1.1: Economic Policies of India Since 1991.

 Objective: To enable the Students to understand the economic policies of India in the
era of new economic policy.
 Pedagogy: A Combination of Lectures, Group Discussion, Assignments.
 Credits: 2 ; Examination Duration: 1 and Maximum Marks: 50 (Internal
Assessment Marks = 10 and Semester-end Examination =40)

Course Inputs
BLOCK – I: India’s Economic Policies

UNIT : 1 Economic Policies in India Since 1991


Economic reforms in India – Economic Scenario in India during 1990-91 –
Domestic Financial Crisis – Balance of Payment Crisis – Extent of External
debt and debt Trap Problem.
UNIT : 2 Need for Reforms
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Measures Taken – Devaluation – Privatization – Liberalization –
Globalization.
UNIT : 3 Monetary Policy and Fiscal Policy
Narasimhan Committee on Banking and Financial Sector Reforms Since 1998
– Fiscal Reforms: Raja Chellaiah Committee and Tax Reform Policies – Fiscal
Prudence and Policies.
UNIT : 4 Structural Adjustments and External Sector in India
Foreign Trade: Trends in Exports and Imports – Balance of Payment and its
Crisis – Export Import Policy – In Defence of Import Substitution – Foreign
Exchange Policy.

BLOCK : II FDI and the Role of State

UNIT : 5 Foreign Direct Investment (FDI)


Trends in FDI – FDI Policy – Its Impact on the Domestic Economy – Labour
Migration: causes and Consequences on Indian Economy – Information and
Communication Revolution and India.
UNIT : 6 Challenges to Development in India
Poverty – Unemployment – Poverty alleviation Programmes - urban Poverty
and Problems – Income Inequality – Employment Generating Schemes.
UNIT: 7 The Role of State
Parallel Economy in India – Black Money – Corruption – Slams – Redefining
the Role of the State and the Markets – Balance between Economic and Socio
- Political Goals.
UNIT : 8 Administrative Reforms
Rights to Information – Measures Towards Good Governance – NITI Ayoga
and aftermath – Digitalized India – Demonetization – GST – Make in India.
References:
1. Acharya Shankar, (2003) India’s Economy: Some Issues and Answers, Academic
Foundation, New Delhi.
2. Byres J Terence (Ed.,) (1999) The Indian Economy, Major Debates since
Independence, OUP,New Delhi.
3. Datt Ruddar, (2002) Economic Reforms in India - A Critique, S.Chand and Co, New
Delhi.
4. Kapila Uma (Ed) (2015) Indian Economy since Independence, Academic
Foundations, New Delhi.
5. Kapila Uma, (2005) Understanding the Problem of Indian Economy, Academic
Foundation, New Delhi.
6. Misra S.K. & V.K. Puri, (2011) Indian Economy-Its Development Experience,
Himalaya Pub., House, Mumbai.
7. NCAER, Economic and Policy Reforms in India, NCAER, New Delhi.
8. Rangarajan C, (1998) Indian Economy- Essays on Money and Finance, UBSPD, New
Delhi.
9. Sachs D.Jeffrey, A.Varshney & N Bajpai (Ed)(1999) India in the Era of Economic
Reforms,OUP, New Delhi.

115
10. Vaidyanathan A, India’s Economic Reforms and Development, OUP, New Delhi

DEPARTMENT - POLITICAL SCIENCE


(OEL-I) Local Government in India

Block-I
Unit:1 Meaning, Nature and Scope of Local Governments.
Unit:2 Evolution of Panchayat Raj Institution in India.
a) Constitute Assembly and Village Panchayat.
b) Balavanth Roy Mehta Committee Report
c) Ashok Mehta Committee Report.
d) G.V.K. Rao Committee Report.
Unit:3 Constitutional Amendments and Panchayat Raj Institutions:
a) Basis of Constitutional Amendment.
b) 73rd and 74th Constitutional Amendment.
c) Karnataka Panchayat Raj At of 1983.
d) Karnataka Panchayat Raj Act of 1993.
Unit:4 Zilla Panchayat: Structure, Functions and Sources of Revenue.

Block-II
Unit:5 Taluk Panchayat : Structure, Functions, Executive Officer, Powers and
Functions.
Unit:6 Gram Panchayat: Gram Sabha, Ward Sabha: Structure, Functions and Sources
of Revenue.
Unit:7 Panchayat Development Officer and Secretary: Powers and Functions.
Unit:8 Role of Panchayat Raj Institutions in Development (with Reference to
Karnataka)
a) Panchayat Raj in Rural Development.
b) Social Change: Empowerment of the Weaker Sections.
References:
1. Verma B. M, Social justice and Panchayath Raj
2. Mutarib-M.A. and Others, Theory of Local Government,
3. Dr. Arjun darshankar, Panchayath Raj aani Nagari.
4. V. B. Patil, Pancayath Raj.
5. A.N. Kulkarni, Bharatiya Sthanik Swashasan,
6. Shantaram Bhosale, Bharatiya Sthanik Shasan,
7. Kikherji. S, Essays on Rural Development.
8. Balaramu. C. H. Administration of Anty Poverty Programmes.
9. 73rd Constitutional Amendment Act, Government of India, 1993.
10. Karnataka Panchayatraj Acts, 1985, 1995.
116
DEPARTMENT - SOCIOLOGY

Invitation to Sociology
( 02 Credits )

Course Description

This course introduces learners to the basic concepts of sociology. It is particularly


designed to orient the learners from interdisciplinary background about the essence of
sociology and intends to inculcate sociological imagination.

Course Objectives

 To introduce the learner to the basic concepts and processes of sociology


 to comprehend the structural and organizational aspects of society
 to examine the process of social change
Learning Outcomes and Competencies

After successfully completing the course, following outcomes and competencies are possible
among the learners. Learner will have/can

 Conceptual precision and clarity about the basic sociological concepts


 Develop sociological imagination and apply to analyze the contemporary events
 explain major social processes of society
 analytical view about Indian social structure
 explicate major process of social change and can conceptualize the changing
aspects of Indian society
Course Contents

Block-1 Basic Concepts and Processes


Unit-1 Emergence of Sociology-Factors and Early Thinkers-Sociological Imagination
Unit-2 Society, Community- Associations and Institutions- Culture and Socialization
Unit-3 Social System, Structure and Function
Unit-4 Social Processes-Cooperation, Competition, Conflict, Accommodation and
Assimilation

Block-2 Social Organization and Social Change


Unit-5 Caste and Class System-Changes in Caste
Unit-6 Social Mobility and Types
Unit-7 Factors of Social Change
Unit-8 Process of Social Change in India (Sanskritization, Westernization,
117
Modernization and Globalization)

References

1. Berger, Peter L. 1978. An Invitation to Sociology, Allen and Unwin, London. Davis,
Kingsley. Human Society, Macmilan, New Delhi.
2. Dumont, Louis, 1988, Homo Hierarchicus. Oxford University Press. Giddens,
Anthony. 2009. Sociology. Politi Press, Malden.
3. Inkles, Alex. 2002. What is Sociology, Prentice Hall India, New Delhi. Jayaram, N,
1990, Introductory Sociology, Macmilan, New Delhi.
4. Johnson Harry M., 2011: Sociology: A Systematic Introduction: Allied Publishers,
New Delhi.
5. MacIver, R.M and C.H. Page. Society - Introduction to Sociology, Macmilan, New
Delhi
6. Samuel, Koenig. 1957. Sociology: An Introduction to Science of Society, Barnes &
Nobel Books, London.
7. Singh, Yogendra. 1993: Social Change in India: Crisis and Resilience, Har-Anand,
New Delhi.

DEPARTMENT – ANCIENT HISTORY AND


ARCHEOLOGY

AHA World Heritage Sites of India


OE 1.1

Block - 1 Introduction

Unit - 1 Nature - Scope - Criteria for incorporation of World Heritage sites

Unit - 2 Types of World Heritage sites in India

Block - 2 Archaeological and Cave Heritage sites

Unit - 3 Bimbetka - Sanchi- Nalanda – Champaner - Dholavira

Unit – 4 Ajanta – Ellora - Elephant

Block - 3 North Indian World Heritage Sites

Unit – 5 Bodh Gaya –– Kajuraho–Konarak–Rani kivav– Jaipur,

Unit – 6 Agra Fort – Red Fort - FathepurSikri–Taj Mahal – Humayun’s Tomb –

118
Ahamadabad, Qutub Minar

Block - 4 South Indian World Heritages Sites

Unit – 7 Mahabalipuram – Pattadakallu – Chola temples

Unit - 8 Monuments of Hampi – Churches and Convents of Old Goa – Ramappa Temple

References:

1. Marco Canneo, Jasmina: The world heritage sites of


UNESCO – TheTreasure of Art
2. ASI: World Heritage Sites Series
3. Individual guide: Books on respective city Individual

DEPARTMENT - EDUCATION
IDC – 1 FOUNDATIONS OF EDUCATION
BLOCK-1 FOUNDATIONS OF EDUCATION – I
Unit-1 Philosophical Foundations
Unit-2 Basic Concepts of Philosophy
Unit-3 Psychology as a Science
Unit-4 Basic Concept in Psychology related to Education

BLOCK-2 FOUNDATIONS OF LEARNING – II


Unit-5 Sociological bases of Education
Unit-6 Educational Issues in Indian Society
Unit-7 Cultural and Historical Foundations
Unit-8 Political and Economic bases of Education
References:
1. Harison and Myers (1970), Education, Manpower and Economic Growth, McGrothill,
Oxfords, IBH Publishing Co., New Delhi.
2. Kamala Bhatia & Baldev Bhatia, (1974) The Philosophical and Sociological
Foundations of Education, Doaba House, New Delhi.
3. Bhatia B.D, (1974), ‘Theory and Principles of Education, Doaba House, Delhi’.
4. Sorokim .P, (1947) ‘Society, Culture and Personality’, Harper and Brothers
Publishers, New York.

DEPARTMENT – COMMERCE

EL1.1: Personal Financial Planning


119
Objective: To enable the Students to understand about the different Investment
Avenues, Saving Schemes designed by various agencies particularly for
the individuals.
Pedagogy: A Combination of Lectures, Group Discussion, Assignments.
Credits: 2
Examination Duration: 1 and Maximum Marks: 50

(Internal Assessment Marks = 10 and Semester-end Examination =40)

Course Inputs
Block I
 Unit -1: Introduction to Financial Planning: Introduction - The Process
Financial Planning – Client Interactions – Time Value of Money Applications
– Personal Financial Statements – Cash Flow ad Debt Management – Planning
to Finance Education.
 Unit -2: Financial Planning Process: Introduction - Setting Goals – Informal
Budget Preparation – Investment Opportunities – Financial Vs Physical
Investments – Role of a Financial Planner.
 Unit -3: Savings Plans: Introduction - Setting Goals – Savings Instruments –
Savings Plan – Tax Savings Schemes.
 Unit -4: Investment Planning: Introduction - Risk Return Analysis – Mutual
Fund – Derivatives – Asset Allocation – Investment Strategies and Portfolio
Construction and Management.
Block II
 Unit -5: Risk Analysis and Insurance Planning: Introduction - Risk
Management and Insurance Decision in Personal Financial Planning – Various
Insurance Policies and Strategies for General Insurance – Life Insurance –
Motor Insurance – Medical Insurance.
 Unit -6: Retirement Planning and Benefits: Introduction - Retirement Need
Analysis Techniques – Savings and Investment Plans for Retirement –
Employee Provident Fund – Public Provident Fund – Superannuation Fund –
Gratuity – Annuity Plans.
 Unit -7: Tax Planning: Introduction - Income-tax Computation for Individuals
– Companies - Trust and other bodies – Statutory Provisions Pertaining to
Capital Gains and Indexation – House Property – Deduction and Allowances.
 Unit -8:Health Financing: Introduction - Health Financing Models –
Financing of Health in India – National Rural Health Mission – Challenges of

120
Access to Health Care and Service Quality – Health Insurance Mechanism &
Financial Protection.

Books Recommended for Reference


01. Khan M.Y, Financial Services, Tata MacGraw Hill.
02. Singhanar V.K, Students’ Guide to Income Tax, Taxmann.
03. Ranganathan andMadhuamathi, Investment Analysis and Portfolio
Management, Pearson Publications.
04. Gordon and Natarajan, Emerging Scenario of Financial Services, Himalaya
Publishing House.
05. George Rejda, Principles of Risk Management and Insurance, Pearson.

DEPARTMENT - MANAGEMENT
COURSE: OE-1 : Disaster Management - Credit: 2
MBAS 459: DISASTER MANAGEMENT

Objectives : The course aims at familiarizing the students with the concepts of disaster
management, need for disaster management and its relevance.
Pedagogy : Lectures, assignments, Industrial visits and practical exercises,
discussions.

1. Understanding Disasters · Meaning, nature, characteristics and types of Disasters, Causes


and effects, Disaster: A Global View, Disaster Profile of India, The Disaster
Management cycle.
2. Geological and Mountain Area Disasters · Earthquakes · Volcanic Eruption · Landslides
Snow Avalanches, Wind and Water Related Natural Disaster · Floods and Flash Floods ·
Droughts · Cyclones · Tsunamis, Man Made Disasters · Understanding Man-Made
Disasters · Fires and Forest Fires · Nuclear, Biological and Chemical disaster · Road
Accidents
3. Introduction to disaster Preparedness · Disaster Management: Prevention, Preparedness
and Mitigation · Disaster Preparedness: Concept & Nature · Disaster Preparedness Plan ·
Disaster Preparedness for People and Infrastructure · Community based Disaster
Preparedness Plan
4. Roles & Responsibilities of Different Agencies and Govt. · Roll of Information,
Education, Communication & Training · Role and Responsibilities of Central, State,
District and local administration. · Role and Responsibilities of Armed Forces, Police,
Para Military Forces. Role and Responsibilities of International Agencies, NGO’s,
Community Based Org. (CBO’s)
5. Technologies for Disaster Management · Role of IT in Disaster Preparedness · Remote
Sensing, GIS and GPS · Use and Application of Emerging Technologies · Application of
Modern Technologies for the Emergency communication. · Application and use of ICST
for different disasters.
121
6. Disaster Mitigation · Disaster Mitigation: meaning and concept · Disaster Mitigation
Strategies · Emerging Trends in Disaster Mitigation · Mitigation management · Role of
Team and Coordination
7. Disaster Management in India Disaster Profile of India – Mega Disasters of India and
Lessons Learnt Disaster Management Act 2005 – Institutional and Financial Mechanism
National Policy on Disaster Management, National Guidelines and Plans on Disaster
Management; Role of Government (local, state and national),Non-Government and Inter-
Governmental Agencies. National Disaster management Authority.
References
1. Bryant Edwards (2005): Natural Hazards, Cambridge University Press, U.K.
2. Carter, W. Nick, 1991: Disaster Management, Asian Development Bank, Manila.
3. Central Water Commission, 1987, Flood Atlas of India, CWC, New Delhi.
4. Central Water Commission, 1989, Manual of Flood Forecasting, New Delhi.
5. Government of India, 1997, Vulnerability Atlas of India, New Delhi.
6. Sahni, Pardeep et.al. (eds.) 2002, Disaster Mitigation Experiences and Reflections,
Prentice Hall of India, New Delhi.

DEPARTMENT - BIO CHEMISTRY


Basics of Bioinorganic and Biophysical chemistry for Biology graduates.

Bioinorganic chemistry
Coordination Compounds: Transition metals, properties (Colour, Oxidation states,
Magnetic properties) Coordinate bond, double and complex salts– differences with examples.
Postulates of Warner’s theory. Types of ligands: For examples: uni, bi, polydentate
ligands. Coordination number, examples.
Porphyrin nucleus and their classification. Important metallo-porphyrins occurring in
nature. Structure and biological importance of Heme, cytochrome, chlorophyll,Vitamin B12.
Nitrogen, Fixation of atmospheric nitrogen – Symbiotic and non-symbiotic. Nitrogen cycle.
Environmental pollution by nitrogen compounds. Phosphorous: Importance of
Phosphorous compounds in biological system, phosphorous cycle
Oxygen, Formation of ozone in atmosphere. Role of ozone in maintenance of life on
earth. Effect of environmental pollutants on ozone layer.
Sulphur and Selenium, Importance of compounds of Sulphur and Selenium in
biological systems. Effect of sulphur compounds on environmental pollution.

Biophysical chemistry.
Units in chemistry, Avogadro’s number, Mole, Mole fraction, Molarity, Equivalent
weight, Normality, Molality. Colligative Properties, Osmotic pressure and its measurements.
Hypo-, Hyper- and isotonic solutions. Effect of osmotic pressure on living cells.
Donnan membrane equilibrium. Relative lowering of vapour pressure, Raoult’s law.
Elevation of boiling point, depression in freezing point.

122
Adsorption: Freundlich and Langmuir’s adsorption isotherm. Applications of
adsorption.
Viscosity: Definition, determination of viscosity of liquids & solutions by Ostwald’s
viscometer (solutions of gum and protein to be taken as examples).
Distribution law, Distribution law, partition coefficient, application of distribution
law.
Acids, bases and buffers- Lewis concept of acids and bases. Ionic product of water.
pH scale, buffers, Henderson- Hasselbach equation, buffer capacity Choice of buffers.
Theory of acid base indicators. pH titration curve and iso-electric pH of amino acids.

Selected References:
1. Basic Principles of Organic Chemistry, Roberts and Caserio, W. A. Benjamin, Inc. (1964).
2. Organic Chemistry, Morrison and Boyd, Allyn and Bacon Inc (1992).
3. Principles of Inorganic chemistry by Cotton & Wilkinson, Wiley (1999).
4. Textbook of Organic chemistry by Ahluwalia V K & Madhuri G Narosa publications
(2001).
5. Physical chemistry by Castellan G W, Narosa Publications (2004).
6. Physical chemistry by Chakraborthy D K, Narosa Publications (2004).

DEPARTMENT - BIOTECHNOLOGY
MBT EL –I- Biotechnology and its Applications
Introduction to biotechnology. Principles of biotechnology, classification.
Recombinant DNA Technology

Introduction, outline of genetic engineering procedure, restriction endonucleases, cloning &


expression vectors- plasmids, cloning in plasmid, transformation and detection of
transformants- lacZ, genomic and cDNA libraries, gene analysis techniques-hybridization:
Southern, Northern, Western, in situ, Polymerase chain reaction.
Microbial and food and environmental Biotechnology

Basics of fermentation technology: Types of microbial culture- batch, continuous and fed-
batch. Microbial production: Use of microbes in production of vitamins, enzymes, organic
acids, amino acids, polysaccharides, flavors, sweeteners, proteins and antibiotics.
Fermented food products- yogurt, cheese, tempeh, sauerkraut; beverages- wine and beer. Pre-
and Pro-biotics, single cell proteins, Genetically modified foods, designer foods.
Current status of biotechnology in environment. Bioconservation, biofuels, gasohol,
biogas.Bioremediation: Concepts and principles, bioremediation using microbes, in situ and
ex situ bioremediation, biosorption and bioaccumulation of heavy metals.
Plant Biotechnology
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Landmarks in Plant tissue culture. Types of cultures- embryo, organ, callus and cell cultures,
Somatic embryogenesis, Haploid Production, Androgenesis, Protoplast culture and somatic
hybridization. Micropropagation- Methods and stages, applications. Synthetic seeds,
somaclonal variation. Production of secondary metabolites by plant cells, Biotransformation.

Plant transformation techniques: Direct and indirect methods of gene transfer in plants.
Transgenic plants and crop improvement- herbicide tolerance, disease resistance, abiotic
stress tolerance, delayed ripening, improvement of nutritional quality, molecular pharming.
Animal Biotechnology
Basics of animal cell culture techniques, cell lines, physical conditions for culturing animal
cells, equipments required, scale-up of culture methods.
Application of animal cell culture- Hybridomas, production of therapeutic antibodies, stem
cell technology, cell and tissue engineering.

Genetic engineering of animals: Methods for gene transfer in animals, microinjection, nuclear
transplantation, retrovirus-mediated gene transfer, gene knockdown techniques. Transgenic-
animals- sheep, pigs, cattle, chickens; applications of transgenic animals.

DEPARTMENT - CHEMISTRY
Block-1 Title: Periodic Table and chemical Periodicity
Unit-1 Elements, atomic structure, atomic number, atomic mass, quantum numbers,
electronic configuration,
Unit-2 Periodic properties of elements, State of Matter, their resources. Important
periodic properties of the elements, covalent radii, ionic radii, ionization
potential, electron affinity and electronegativity
Unit-3 Concepts of Acids and Bases: Review of acid base concepts. Lux-Flood and
solvent system concepts. Hard-soft acids and bases. Applications.
Unit-4 Solutions: Concentration units, solutions of liquids in liquids, Raoult’s law,
ideal and non-ideal solutions.

Block-2 Title: Bonding and molecular structure


Unit-5 Calcification of matter: (elements, compounds, substance and mixture), The
three states of matter, physical and chemical properties of matter, fundamental
particles of atoms, atomic number, atomic mass, atomic structure of atom
molecular formula, empirical formula, molecular mass.
Unit-6 Ions and ionic compounds, properties of ionic compounds, formation of ionic
compounds, covalent compounds, properties of covalent compounds, properties
124
of covalent compounds
Unit-7 Metals, properties of metals, theory of metallic bond formation, types of metals
conductor, semiconductor and insulators, n-type semiconductors and p-type
semiconductors, alloys and superconducting materials.
Unit-8 Acids and bases, general properties of acid and bases, Acid base reactions,
oxidation reduction reactions, oxidation number, types of redox reactions,
balancing oxidation-reduction equation, exothermic and endothermic reactions
energy change in chemical reactions.

DEPARTMENT : CLINICAL NUTRITION


AND DIETETICS
OEL-1: HEALTHY LIFESTYLES AND NUTRITION 3
Credits

BLOCK 1: INTRODUCTION TO FOOD AND NUTRITION


Unit 1.- Factors affecting food habits, choices and dietary patterns – Definition of
Food, Nutrition, Health, Fitness. Interrelationship between nutrition and
health, concept of a desirable dietfor optimum nutrition, health and fitness.
Unit 2-. A brief review of nutrients in general –
 Energy and macronutrients – Carbohydrates, Protein, Fat - functions,
sources deficiency disorders and recommended intakes.
 Micronutrients: Minerals – calcium, Iron, Iodine, and other elements,
Vitamins – FatSoluble & Water Soluble.
Unit 3: Nutritional assessment- Anthropometric, biochemical, clinical, dietary and
Biochemical assessments
Unit 4: Basic principles of planning diet –, RDA for Indians, Food groups, Dietary
guidesand balanced diets.

BLOCK 2: PLANNING OF DIET


Unit 5: Principles of planning a normal diet: characteristics of a normal diet, meeting
nutrientrequirements of individuals and family. Use of Dietary guidelines for Indians.
Unit 6: Objectives of diet therapy- Regular diet and rationale for modifications in energy
and other nutrients, texture, fluid, soft diets etc.
Unit 7: Role of dietician in hospital- specific functions, team approach in patient care,
psychological consideration, interpersonal relationship with patients. Nutrition and
medicalethics. Hospital dietary- scope and importance, types of food service, quality
125
management.
Unit 8: Nutrition counseling: definition, concept, role of clinical dietician, the recipient
and counseling environment and goals of counseling. An overview of systems approach to
nutritionalcare and its components (planning, implementation and evaluation).

REFERENCES
 Srilakshmi B (2004) Nutrition Science. New Age International (P) Ltd, Publishers.
 Kango M (2005) Normal Nutrition, Curing diseases through diet. First
Edition CBS Publications.Paul S (2003) Text Book of Bio-Nutrition,
Fundamental and Management. RBSA Publishers.
 Williams SR (2000) Nutrition and Diet Therapy. Sixth Edition C.V. Melskey Co.
 Mudambi SR and Rajagopal MV (1997) Fundamentals of Foods and
Nutrition. New AgeInternational (P) Ltd, Publishers.
 Swaminathan M (1999) Essential of Food and Nutrition. Vol I and II,
Bappco publications,Madras.
 Corinne, H. Robinson 2010– “Normal and Therapeutic nutrition”, Oxford and IBH
publishingcompany, Bombay.
 B.
Srilakshmi – 2012“Dietetics”, 4th edition, New age international publisher,Chennai

DEPARTMENT - COMPUTER SCIENCE


ELMCS-01 Mobile App Development: Credit 2
Block – I
Unit-1: Introduction to Mobile Computing: applications, a simplified reference model,
Wireless
Transmission:
Unit-2: Frequencies of radio transmission, signals, antennas, signal propagation,
multiplexing,
modulation, spread spectrum, cellular system.
Unit-3 Media Access Control: motivation for a specialized MAC, SDMA, FDMA, TDMA,
CDMA ,and
Comparisons.
Unit-4: GSM, DECT, Wireless LAN: Infrared vs. radio transmission, Infrastructure and ad-
hoc networks,
IEEE 802.11, HPERLAN, Bluetooth.

Block – II

Unit-5: Mobile Network Layer: mobile IP, dynamic host configuration protocol,
Unit-6: ad-hoc networks. Mobile Transport Layer: Traditional TCP, classical TCP
improvements,
Unit-7: TCP over 2.5/3G wireless networks. File Systems, World Wide Web,
126
Unit-8: Wireless Application Protocol (WAP) and WAP 2.0.

Text book:

1. Jochen H. Schiller, Mobile Communications(2e)

Reference
1. Raj Kamal, Mobile Computing
2. Asoke K. Talukder, Roopa R. Yavagal, Mobile Computing
3. Mazliza Othman,Principles of Mobile Computing and Communications
4. Prasant Kumar Pattnaik, Rajib Mall, Fundamentals of Mobile Computing
5. Ivan Stojmenovic,Handbook of Wireless Networks and Mobile Computer
6. David Taniar, Mobile Computing Concepts, Methodologies, Tools, and Applications

DEPARTMENT - ENVIRONMENTAL SCIENCE


ESOEL-1: Basics of Environmental Science

Block I: Ecology and Environment


Unit 1: Definition, Principles and Scope. Biotic and abiotic factors of environment.
Ecosystems: pond, forest, river, grassland and estuary ecosystems
Unit 2: Ecosystem – trophic structure, energy flow, food chain, food web, Ecological
pyramids.
Unit 3: Population dynamics: Definition, population density, Natality, Mortality, Age
structure, Growth pattern, population dispersion.
Unit 4: Biogeochemical cycle – types, sedimentary and gaseous cycles, N, C, S, P, O cycles.
Rock and hydrological cycles.

Block II: Biodiversity and Conservation


Unit 5: Biodiversity, Definition, Types of Biodiversity, importance and roles.
Unit 6: Needs and benefits of biodiversity, Loss of biodiversity- causes and consequences,
Need for conservation of biodiversity
Unit 7: Conservation strategies, endemic and exotic species, Red Data book, National parks,
wildlife sanctuaries, biosphere reserves, biodiversity hotspots, wildlife protection
act, biodiversity act, wetland conservation and management, Hotspots of
biodiversity.
Unit 8: Project Tiger, Project elephant, Ramsar site and other conservation projects. Experts
Committee Reports on Environmental conservation

DEPARTMENT - GEOGRAPHY
ELMG –01, Introduction to Physical Geography (Credit-2)
Block-1
127
Origin, Shape and Size of the Earth, Movement of the Earth- Rotation and Revolution,
Effects ofthe movement of Earth, Coordinates -Latitude, Longitude and Time; Structure
of the Earth, Rocks - types, significance, Weathering –types; Agents of Denudation -
River, Glacier, Wind and Under Ground water; Structure and Composition of Atmosphere,
Weather and Climate

Block-2
Atmospheric Pressure, Winds and Precipitation; Distribution of Land and Sea, Submarine
Relief of the Ocean, Temperature and Salinity of Sea Water; Ocean Tides and Oceanic
Currents- Atlantic, Pacific and Indian Oceans; Biosphere- Elements, Ecology, Ecosystem,
World’s Biomes, Biodiversity – Importance, Types and Conservation

References
1. B.S. Negi (1993) Physical Geography. S.J. Publication, Meerut
2. D.S.Lal (1998) Climatology.Chaitnya publishing house, Allahabad
3. K. Siddhartha (2001) Atmosphere, Weather and Climate.Kisalaya publication, New Delhi
4. R.N.Tikka (2002) Physical Geography. KedarnathRamnath&co, Meerut
5. Willian D. Thornbury (1997) Principle of Geomorphology. New Age Internatinal
(Pvt Ltd.)New Delhi.

DEPARTMENT -MATHEMATICS
ELMM –01 - FUNDAMENTALS OF MATHEMATICS
(2 Credits)
Block-I: Number Theory: Natural numbers, integers, Real numbers, GCD, LCM, Prime numbers.
Surds, Indices, Logarithms, Progressions, Arithmetic Progression, Geometric Progression, Harmonic
Progression,

Block-II: Set Theory: Operations of Union, Intersection, Complementation. Relations & Functions:
Types of relations One-one, onto, Many-one functions, graphs of functions.
Mathematical Logic: Propositions, logical connectives, Methods of proofs.

Books for Reference:


1. Kolman and Busby: Discrete Mathematics, PHI.
2. S. L. Loney: The Elements of Coordinate Geometry, London Macmillan & Co.
3. B. S. Grewal: Higher Engineering Mathematics, 36th Ed., Khanna Pub.
4. S. Lipschutz and M. Lipson: Theory and Problems of Discrete Mathematics. Schaum
Series. 2nd Ed. Tata McGraw Hill.

DEPARTMENT - MICRO BIOLOGY


128
Microbial World and Microbial Diversity

i. Introduction to microbial world, Physiochemical and biological characteristics;


Characteristics of Acellular microorganisms (Viruses); Baltimore classification,
general structure with special reference to viroids and prions.
ii. Binomial Nomenclature, Whittaker’s five kingdom and Carl Woese’s three kingdom
classification systems and their utility.
iii. Difference between prokaryotic and eukaryotic microorganisms
i. General characteristics of Cellular microorganisms, types - archaebacteria, eubacteria,
wall-less forms - MLO (mycoplasma and spheroplasts) with emphasis on
distribution and occurrence, morphology, mode of reproduction and economic
importance.
ii. Structure, reproduction and economic importance of Mycoplasma.
i. General concept of Phytoplanktons and Zooplanktons. Characteristics, occurrence,
thallus organization and classification of Algae.
ii. Cyanobacteria - occurrence, thallus organization, cell ultra structure, reproduction and
economic importance. Applications of algae in agriculture, industry, environment
and food.
i. Historical developments in the field of Mycology including significant contributions
of eminent mycologists.
ii. General characteristics of fungi including habitat, distribution, nutritional
requirements, fungal cell ultra- structure, thallus organization and aggregation,
mode of reproduction and
iii. Economic importance of fungi with examples in agriculture, environment, Industry,
medicine and food.
i. General characteristics, structure, mode of reproduction and economic importance of
Actinomycetes with special reference to its application in medicine and industry.
ii. General characteristics, occurrence, classification structure, reproduction and
economic importance of Protozoa.

References:
1. Singh,R.P. General Microbiology. Kalyani Publishers, New Delhi (2007).
2. Aneja, K.R. Experiments in Microbiology, Plant pathology and Biotechnology, Fourth
edition, NewAge International publishers.
3. Dubey, R.C. and Maheshwary, D.K. Text book of Microbiology. S.chand and company
(1999).
4. Powar, C.B. and Daginawal, H.F. General Microbiology. Vol-I and Vol- II, Himalaya
Publishing House.
5. Chakraborty P. A Textbook Of Microbiology. New central book Agency (2005).
6. Prescott, M.J., Harley,J.P. and Klein, D.A. Microbiology. 5th Edition WCB Mc Graw Hill,
New York, (2002).
7. Tortora, G.J., Funke, B.R. and Case, C.L. Microbiology: An Introduction. Pearson
Education, Singapore, (2004).
8. Alcomo, I.E. Fundamentals of Microbiology. VI Edition, Jonesand Bartlett Publishers.
Sudbury. Massachusetts, (2001).
129
9. Black J.G. Microbiology-Principles and Explorations. JohnWiley &Sons Inc. New York,
(2002).
10. Pelczar, MJ Chan ECS and Krieg NR, Microbiology McGraw-Hill.
11. Willey, Sherwood, Woolverton. Prescott, Harley, and Klein’s Microbiology McGraw-Hill
publication
12. Tortora, Funke, Case. Microbiology. Pearson Benjamin Cummings.
13. JACQUELYN G. BLACK. Microbiology Principles and explorations. JOHN WILEY &
SONS, INC.
14. Madigan, Martinko, Bender, Buckley, Stahl. Brock Biology of Microorganisms. Pearson
15. Tom Besty, D.C Jim Koegh. Microbiology Demystified Mc GRAW-HILL.

DEPARTMENT -PHYSICS
MP-EL1: Mechanics
BLOCK-A

Unit-1: Laws of Motion: Frames of reference, Newton’s Laws of motion,


Dynamics of a system of particles, Centre of Mass.
Unit-2: Momentum and Energy: Conservation of momentum, Work and energy,
Conservation of energy, Motion of rockets.
Unit-3: Rotational Motion: Angular velocity and angular momentum, Torque,
Conservation of angular momentum.
Unit-4: Gravitation: Kepler’s Laws (statement only), Newton’s Law of gravitation,
motion of a particle in a central force field, satellite in circular orbit and
applications, geosynchronous orbits, weightlessness, basic idea of global
positioning system (GPS).

BLOCK-B:

Unit-5: Oscillations: Simple harmonic motion, differential equation of SHM


and its solutions, kinetic and potential energy, total energy and their
time averages, damped oscillations.
Unit-6: Elasticity-1: Hooke’s law, stress-strain diagram, elastic moduli-relation
between elastic constants, Poisson’s ratio, expression for Poisson’s ratio in
terms of elastic constants, work done in stretching and work done in
twisting a wire.
Unit-7: Elasticity-2: Twisting couple on a cylinder - determination of rigidity
modulus by static torsion, torsional pendulum-determination of rigidity
modulus and moment of inertia - q, by Searles method.
Unit-8: Special Theory of Relativity: constancy of speed of light, postulates of special
theory of relativity, length contraction, time dilation.

130
DEPARTMENT -PSYCHOLOGY
EL-1 Introduction to Psychology 2 Credits

Block 1: Introduction to Psychology-I


Unit 1: Introducing Psychology -Definition, Scope, and goals
Unit 2: Branches of Psychology
Unit 3: Motivation
Unit 4: Emotions

Block 2: Introduction to Psychology-II


Unit 5: Sensation, Attention and Perception
Unit 6: Learning, Memory and Forgetting
Unit 7: Intelligence
Unit 8: Personality

References:
1. Charles G.Morris. Albert A. Maisto Psychology an Introduction , Prentice Hall. New
Jersy.
2. Feldman, A. R.,Understanding Psychology IV th Ed, 1996, McGraw Hill, New Delhi.
3. Morgan, King, Weisz &Schopler, Introduction to Psychology-V11 Ed,1993, Tata
McGraw Hill, New Delhi.
4. Ernest R Hilgard, Richard C Atkinson ,Rita L Atkinson Introduction to Psychology
Oxford Publication, New Delhi.

DEPARTMENT : INFORMATION TECHNOLOGY


ELMIT –01: Green Computing (2 Credits)

Course Objective: Study the concepts related to Green IT, Green devices and hardware
along with software methods, green enterprise activities, managing the green IT and various
laws, standards, protocols along with outlook of green IT.

BLOCK 1: Overview of Green Computing

Unit 1:Green IT Introduction, Overview and issues, Initiatives and standards, Pathways of
Green computing, Benefits of Green IT, Environmental Impacts of IT
Unit 2: Green devices and hardware Environmental issues arising from electronic devices,
life cycle of electronic devices, Hazards and E-waste Ecycling, Going paperless,
Hardware considerations, Greening information systems, Managing Green IT, 3Rs of
Green IT, Thinking About Money-Saving Efforts
131
Unit 3: Green Data Centres and Associated Energy Challenges, Data Centre IT
Infrastructure, Data Centre Facility Infrastructure: Implications for Energy Efficiency,
IT Infrastructure Management, Green Data Storage, Storage Media Power
Characteristics,
Unit 4: Green network and communications, objectives and challenges of green networking,
Enterprise Green IT strategy, Approaching Green IT strategies, Business drivers and
dimensions for Green IT strategies, Steps in Developing a Green IT Strategy, Metrics
and Measurements in Green Strategies

BLOCK 2: Management of Green Computing


Unit 5: Sustainable Information Systems and Green Metrics, Sustainable IT Services,
Sustainable IT Roadmap, Enterprise, Green IT Readiness, Readiness and Capability
Green Enterprises and the Role of IT, Organizational and Enterprise Greening, Information
Systems in Greening Enterprises, Greening the Enterprise: IT Usage and Hardware,
Unit 6: Managing Green IT, Strategizing Green Initiatives, Implementation of Green IT,
Regulating Green IT: Laws, Standards and Protocols,
Unit 7: Green Cloud Computing and Environmental Sustainability, Cloud Computing and
Energy Usage Model: A Typical Example, Features of Clouds Enabling Green Computing,
Green Cloud Architecture
Unit 8: Green IT: An Outlook, Awareness to Implementation, Green IT Trends, Greening by
IT, A Seven-Step Approach to Creating Green IT Strategy
Text Books:
1. Gangadharan, G. R., & Murugesan, S. (2012). Harnessing Green IT: Principles and
practices. Wiley Publication, ISBN: 9788126539680.
2. Smith, B. E. (2013). Green Computing: Tools and Techniques for Saving Energy, Money,
andResources. CRC Press.

DEPARTMENT -BOTANY
Plant-Microbe Interactions
Overview of plant microbes interactions,
Introduction, beneficial microbes, Rhizobium bacterium and nitrogen fixation, mycorrhizal
fungi.
Plant pathogens, Agrobacterium tumefaciens and crown gall disease,
Mechanisms of plant disease mechanism, some bacterial plant diseases,
Plant viruses and mechanism of plant against viruses attacks.
Fungal pathogen- mechanism of plant disease,
Omycete pathogens, Fungal mediated plant.
General concept of plant immunity,
PAMP-triggered immunity (PTI) and effectors-triggered immunity (ETI).
132
Transcription activator like effector and their role in virulence and disease resistance.

References
1. Lautenberg, B. (2015). Principles of Plant-Microbes Interactions: Microbes for
sustainable Agriculture, Springer.
2. Stacey, G. and Keen, N. T. (1997). Plant-Microbes Interactions, Vol 4, . Springer.
3. Ramasamy, K, (2015). Plant Microbes Interactions, New India Publishing Agency.
4. Martin, F. and Kamoun, S. (2014). Effectors in Plant-Microbes Interactions 1st Edition,
Wiley Blackwell.

DEPARTMENT -ZOOLOGY
MZO-IE-1: Parasites, Vectors & Communicable Diseases
Introduction to parasites.

Distribution, types, origin and evolution of parasites. Parasitism.

Types: Ecto-parasites, Endo-parasites and their adaptations.

Pathogenic micro-organisms, brief outline and classification of parasitic protozoan’s:


Entamoeba, Balantidium, Giardia, Trichomonus, Plasmodium, Leishmania and Trypanosoma
and their diseases.

Control measures, diagnosis and therapy.


Pathogenic helminthes and vectors.

Etiology, epidemiology, pathogenesis, diagnosis, prevention and control of disease due to


Trichinella spiralis, Ancylostoma duodenale, Fasciola hepatica, Schistosoma species.

Pathogenic Cestodes: Life cycle, treatment of diseases caused by Echinococcus, Hymenolepis


and Diphyllobothrium. Scope and importance of vectors. Origin and evolution of vectors.
Habitat, life cycle, pathogenicity of fleas, mites, ticks, lice’s and mosquitoes.

Historical perspectives and scientists involved in the discovery of vectors and communicable
Diseases.
Epidemiology, bio-ecology, life cycle of biological and mechanical Vectors. Vector-host-
parasites interactions, Host-pathogen interaction, insects transmitting Bacteria and viruses.
Control and management of vectors and vector borne diseases

Control measures: cultural, chemical, biological, genetic and environmental Methods of


vectors. Management of biological and mechanical vectors during Different seasons.
Integrated Vector Control and Management.

Insecticide resistance in vectors, Drug resistance in pathogens.

133
Importance of education, awareness among public on communicable diseases and community
participation. Covid-19 pandemics. Epidemiology of corona virus and its mutants.
Vaccination against corona virus in India and other parts of the world.

DEPARTMENT –FOOD AND NUTRITION


SCIENCE

ELMFNS- 01 FOOD PSYCHOLOGY


Credits: 2
BLOCK 1: FOOD: PREFERENCES AND CHOICES

Unit 1: Food: Physiological definition and significance, meaning of food, food classification,
Food as statement of self-identity, Social interaction, Cultural identity

Unit 2: The Role of Food and Eating on Personality and Social Development:
Psychology of eating, Food and emotion regulation, Food in daily living, Food
Socialization, Food and control of others

Unit 3: Food Preferences and Fluctuations: Developmental Models, Cognitive Models &
Psychophysiological Models, Physiology of food choice, Likes and Dislikes, acquired
food preferences, Attitudes towards change, Food and sensory stimulus, Factors
influencing eating behavior – (biological, environmental, individual, food
characteristics, culture etc., Effect of eating on food selection and preferences,
Understanding of the body and self – selection of the diet.

Unit 4: Food choices across lifespan and influence of society: The changing role of the
senses in food choice and food intake across lifespan, Food in security and health across
lifespan, Influence of media and advertisements, Digital platform and influence on
food choices

BLOCK 2: EATING DISORDERS AND TREATMENTS

Unit 5: Mood, Emotions, food cravings and addictions: relation with food preferences,
Connection between mood and eating, Biological and physiological aspects of food
cravings, Stress and eating behavior, Food addiction - description, neurobiology of
food addiction

134
Unit 6: Eating disorders and treatment: Anorexia nervosa, Bulimia nervosa and binge eating
Disorder-Definition, Symptoms, believed causes, Classification, Risk factors, Common
myths of eating disorders, Treatment & dietary management

Unit 7: Overeating, Obesity and Weight management: Definition, Prevalence, Classification


of Body Mass Index, Types & patterns, Etiology, Physiological component, Fad diets,
Risk factors, Treatment - Weight management (Behavior & Cognitive), Lifestyle
modifications, Dietary modification - (calorie restricted diet)

Unit 8: You are what you eat- Approaches to change the dietary behavior:
Multidisciplinary approach, Strategies to support healthy dietary behavior: Encouraging
healthy eating, Selection of food, Meal & portion size, developing education
materials, Motivation & economics, Benefits of exercise, Stage classification for
change, Barriers affecting the clinical outcome

REFERENCES:

1. Smith John L. (2002 ), The Psychology of Food and Eating (English, Hardcover, Smith John
, Publisher: Palgrave MacmillanL.), ISBN: 9780333800201, 0333800206.
Alexandra W. LogueOct 2017, The Psychology of Eating and Drinking Fourth Edition.

135
Annexure II
INTER- DISCIPLINARY COURSE
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8. ±ÀvÀªiÀ Á£ÀzÀ PÀ£ÀßqÀ ¸Á»vÀå : ¸ÀA¥ÁzÀPÀgÄÀ , f.J¸ï. £ÁAiÀÄPÀ, PÀ£ÀßqÀ ¸Á»vÀå CPÁqÉ«Ä, ¨ÉAUÀ¼Æ
À gÀÄ
9. PÀ£ÀßqÀ ¸Á»vÀåzÀ EwºÁ¸À : gÀA. ²æÃ. ªÀÄÄUÀ½, PÉÃAzÀæ ¸Á»vÀå CPÁqÉ«Ä, £Àªz
À ɺÀ°, 1963
10. PÀ£ÀßqÀ ¸Á»vÀå ZÀjvÉæ : gÀA.²æÃ. ªÀÄÄUÀ½, GµÁ ¸Á»vÀå ªÀiÁ¯É, ªÉÄʸÀÆgÀÄ, 1971
11. ©A§: ZÀzÀÄgÀAUÀ, ¸ÀAªÀºÀ£À ¥ÀæPÁ±À£À, ªÉÄʸÀÆgÀÄ
12. PÀ£ÀßqÀ ¸Á»vÀå ZÀjvÉæ ¸ÀA¥ÀÄlUÀ¼ÀÄ : PÀĪÉA¥ÀÄ PÀ£ÀßqÀ CzsåÀ AiÀÄ£À ¸ÀA¸ÉÜ, ªÉÄʸÀÆgÀÄ. «±Àé«zÁ央AiÀÄ,
ªÉÄʸÀÆgÀÄ, 1982
13. PÀ£ÀßqÀ ¸Á»vÀåzÀ ¥ÁæaãÀvÉ: ¥ÀæzsÁ£À ¸ÀA¥ÁzÀPÀgÄÀ , J. gÀAUÀ¸Áé«Ä, ¯ÉÃ. JZï.¦. VÃvÁ, d£À¦æAiÀÄ PÀ£ÀßqÀ
ªÀiÁ¯É, PÀ£ÀßqÀ CzsÀåAiÀÄ£À ªÀÄvÀÄÛ ¸ÀA±ÉÆÃzsÀ£Á «¨sÁUÀ, PÀgÁªÀÄÄ«, ªÉÄʸÀÆgÀÄ, 2011
14. ¥ÁæaãÀ PÀ£ÀßqÀ PÁªÀå ¹ÜgÀvÉ ªÀÄvÀÄÛ ZÀ®£À ²Ã®vÉ : ¥ÀæzsÁ£À ¸ÀA¥ÁzÀPÀgÄÀ , J. gÀAUÀ¸Áé«Ä, ¯ÉÃ.
²ªÀgÁªÀÄAiÀÄå, d£À¦æAiÀÄ PÀ£ÀßqÀ ªÀiÁ¯É, PÀ£ÀßqÀ CzsåÀ AiÀÄ£À ªÀÄvÀÄÛ ¸ÀA±ÉÆÃzsÀ£Á «¨sÁUÀ, PÀgÁªÀÄÄ«,
ªÉÄʸÀÆgÀÄ, 2012
15. PÀ£ÀßqÀ PÉʦr: ¸ÀA¥ÀÄl 2, ¥Àæ¸ÁgÀAUÀ, ªÉÄʸÀÆgÀÄ «±Àé«zÁ央AiÀÄ, ªÉÄʸÀÆgÀÄ, 2007

DEPARTMENT - ENGLISH
EL-2.1: INDIAN LITERATURE-II

OBJECTIVES
 To appreciate artistic values in Hayavadana and the use of myth
 To know the importance of Indian English historical plays
 To appreciate Sri Aurobindo as a poet and critic
 To comprehend the different theories of aesthetic experience of art
BLOCK -I
Girish Karnad: Hayavadana
Gurucharan Das: Larin Sahib

BLOCK –II
M. Hiriyanna: Art Experience
Sri Aurobindo: Selections: The Poets of the Dawn and The Poets of the Dawn 3 (The Future
Poetry)
Suggested Reading:
 K.R.Srinivas Iyengar: Indian Writing in English .Macmillan, 1979.
 M.K.Naik: Critical Essays on Indian Writing in English.Sahitya Akademi, 1969.
137
 Narasimhaiah C.D: The Swan and the Eagle. Indian Institute of Advanced Study, 1987.
 Meenakshi Mukherjee: The Twice Born Fiction. Heinemann Educational Publishers, 1972.

DEPARTMENT - HINDI
हहिंदी सिनेमा
 लसनेमा का उद्भव और ववकास
 मक
ू च धचत्र और दादा साहब फाल्के यर्ग

 दस
ू रा पढाव, सवाक च धचत्र अथवा आ मआरा
 रं र्गीन लसनेमा का यर्ग

 सामात्जक लसनेमा एक वववेचन
 िमण एवं सांस्कृनिक लसनेमा एक वववेचन
 राजनैनिक लसनेमा एक वववेचन
 आधथणक लसननमा एक वववेचन
 हास्य एवं व्यंग्य लसनेमा एक वववेचन
 बा लसनेमा
 लसनेमा एवं संवेदना
 लसनेमा एव भाषा-लशल्प लसनेमा एवं र्गायन
 लसनेमा एवं पात्र संयोजना
 लसनेमा एवं नैनिक मल्
ू य
 अनदू दि लसनेमा
 लसनेमा का िु नात्मक अध्ययन
 क्रफल्म समीक्षा......आहद

सससससस ससससस
 लसनेमा सादहत्य और समाज- प्रह् ाद अग्रवा , अनालमका प्रकाशन, नई ददल् ी
 कथाकार कम ेश्वर और दहंदी लसनेमा- उज्जज्जव अग्रवा , राजकम प्रकाशन, नई ददल् ी
 बॉल वड
ु पाठ ववमशण के संदभण- ल ि जोशी, वार्ी प्रकाशन, नई ददल् ी
 फ् श
ै बैक, प्रभन
ु ाथ आज़मी, लशल्पायन, नई ददल् ी
 नाटक के सौ बरस, हररश्चंद्र अग्रवा और अत्जि पष्ु क , लशल्पायन, नई ददल् ी

DEPARTMENT - TELUGU
E. L. 2.1 TELUGU SAMSKRUTHI - SAMAJAM

138
Block - 1: ANDHRULA CHARITHRA - SAMSKRUTHI
Unit - 1:Samskruthi Vaisistyam
Unit - 2:Andhrula Charithra - Samskruthi Paraspara Prabhavam
Unit - 3:Andhrula kalalu
Unit - 4: Andhrula basha - samajam

Block - 2: ANDHRULA AACHARALU -SAMPRADHAYALU


Unit - 1:Andhrula Pandugalu
Unit - 2: Sthrela Nomulu - Vrathalu
Unit - 3: Andhrula Sangikaacharalu
Unit - 4: Andhrula Sampradhayalu

DEPARTMENT - HISTORY
OEL2.1 Social Reform Movements in Modern India
Objective: The course is aims to trace the causes for the division of society in various
sections and need for reformation. Further it explains age old social evils which
crippled Indian society.
Pedagogy: personal contact programmes, audio video programmes, online lectures
Assignments, etc
Credits: 2. Examination Duration: 1 1/2 hours and Maximum Marks: 40
Course outcomes

After completing this course the students should be able to


 Understanding the contributions of the Raja ram Mohan Roy Dayananda Sarawathi
towards the Indian modernity
 Analyse the Jyothibai pule Savithribai Pule Ambedkar’s contributions to Indian social
reform movements
 Evalute the works of Sahu Maharaj and Krishna raja wadiyar IV patronage to social
Justice.

Block-I
Unit : 1
Colonial Discovery of India : Orientalism, Anglicism, Evangelism-Understanding
Indian Society, Meaning of Social Reform. The Concept of Modernity : Western
Impact – Indian Response.
Unit : 2
Rajaram Mohan Roy and Brahmo Samaj, Dayananda Sarawathi and Arya Samaj-
Nationalism and Society – Prarthana Samaj.
Unit : 3
Jyothi Ba- Phle and Savithri Ba Pule, Social and education reforms.
Unit : 4
Communalism, Eradication of Communalism, Muslim League, Wahhabi and Pan
Islamism-Syed Ahmed and Aligarh Movement.
Block-II
139
Unit : 5
The debate over the interpretation of Shastras – Ishwar Chandra Vidya Sagar -
B.M.Malabari – Vivekananda –M.G. Ranade—Bal Gangadhar Tilak.
Unit :6
Dr. B.R.Ambedkar-, His views on Society, A caste and its annihilation, Religion and
Economy, M.K.Gandhi- E.V.Ramswamy Periyar and Sri.Narayanguru, Ayyan kali.
Unit :7
The reformers – Kandukuri Veereshalingam – Pandit Shivanatha Shastry – Gopal
Ganesh Agarkar-K.T.Telang-Maharma.
Unit :8
D.K.Karve, Maharaj Saiyyaji Rao Gaekwad of Baroda – Chatrapathi Shahu Maharaj
of Kolhapur and Maharaja Krishnaraja Wodeyar IV of Mysore.

Suggested readings:

1. Nararajan : A Century of Social Reform in Indian.


2. Seetharam Singh : Nationalism and Social Reform in India
3. Dhananjaya Keer : Ambedkar, Life and Mission
4. Dhananjaya Keer :Mahatma Jyoti Rao Phule : Father of Social Revolution in India
5. Charless Heimsath R : Indian Nationalism and Hindu social Reform
6. A.S.Altekar : Position of Women In Hindu Civilization.
7. Gail Omvedt : Cultural Revolt in a Colonial Society – The Non – Brahmin Movements
in Western India.
8. Gail Omvedt : Dalits and Democratic Revolution.
9. Ravindrakumar : Selected Documents of B.G.Tilak.
10. S. Ramkrishna : Social Reform Movements in Andhra
11. M.K.Gandhi : Women and Social Injustice.
«dAiÀÄ ¥ÉÆtZÀÄÑ vÀA§AqÀ (¸ÀA), ¨sÁgÀvÀ G¥ÀRAqÀzÀ DzsÀĤPÀ ¥ÀƪÀð ZÀjvÉæ ««zsÀ DAiÀiÁªÀÄUÀ¼ÄÀ
- ¸ÀA¥ÀÄl-03, ¥Àæ¸ÁgÁAUÀ, PÀ£ÀßqÀ «±Àé«zÁ央AiÀÄ, ºÀA¦.

DEPARTMENT - ECONOMICS
EL2.1: Institutions for International Development

 Objective: To enable the Students to understand the need and importance of


various International Institutions.
 Pedagogy: A Combination of Lectures, Group Discussion, Assignments.
 Credits: 2 ; Examination Duration: 1 and Maximum Marks: 50 (Internal Assessment
Marks = 10 and Semester-end Examination =40)

Course Inputs

140
Block – I Economic Issues at Global and National Level

Unit – 1 Globalisation
Globalisation – Forces Driving Globalisation – Income Inequality – National
Integrity – Impact on Labour – Multinational corporations – Global Business
Environment – National Business Environment.
Unit – 2 Legal Issues of Business at Global and National Level
Political Risks – Legal System – Business Ethics – Centrally Planned
Economy – Mixed Economy – Market Economy – Human Development
Unit – 3 International Trade
Importance – Volume – Direction – Composition – Trends – Theories of
Trade - Mercantilism – Absolute Advantage – Comparative Advantage –
International Product Life Cycle – Political, Economic and Cultural Motives
behind Government Intervention.
Unit – 4 GATT and WTO
Importance – objectives – Functions - GATT and W.T.O – India and WTO.
Block – II Economic Integration and International Business Issues

Unit – 5 Regional Economic Integration


Meaning – Effects – Integration in Europe: European Union – Integration in
Americans : North American Free Trade Agreement (NAFTA) – Latin
American Integration Association (LAIA) – Free Trade Area of Americans
(FTAA) and Transatlantic Economic Partnership.
Unit – 6 Integration in Asia
Association of Southern East Asian Nations (ASEAN) - Asia Pacific
Economic Cooperation (APEC) – Integration in middle East : Gulf
Cooperation Council (GCC) – BRICS – SAARC.
Unit – 7 International Financial Markets
International capital markets – Foreign Exchange markets – Currency
Convertibility – International Monetary System.
Unit – 8 Issues in International Business
Trade War – Balance of Payment – Terrorism – Oil Crisis – Smuggling –
Dumping – Environmental Degradation – Exhibit of Nuclear power – Covid
19 and other pandemics.
References:

141
01. Apte A.N. (2011) International Financial Management, Tata McGraw Hill Pub., Co.
Ltd., New Delhi.
02. Bhambari C.P, (1980) The World Bank and India, Vikas Publishing House, New
Delhi.
03. International Development Association, Annual Reports.
04. International Finance Corporation, Annual Reports.
05. International Monetary Fund, Annual Reports.
06. World Bank, (1995) The Evolving Role of the World Bank in the First Half Century,
Washington D.C.
07. World Bank, World Bank in India, Washington, D.C. USA
08. World Bank, World Development Reports, and Annual Reports.
Palle Krishna Rao, (2005) WTO, Text and Cases, PSG Excel Series, New Delhi.

DEPARTMENT - POLITICAL SCIENCE


(OEL-I) Indian Constitution
Block-I
Unit:1 Framing of the Indian Constitution.
Unit:2 Preamble and Salient Features of the Indian Constitution.
Unit:3 Fundamental Rights and Duties.
Unit:4 Directive Principles of the State Policy.
Block-II
Unit:5 Union Legislature : Composition, Powers and Functions.
Unit:6 Union Executive : President and Vice-President - Election, Powers and
Functions, Prime ministers and Council of Minister - Powers and
Functions.
Unit:7 State Legislature : Composition, Powers and Functions, State
Executive -Governor and Chief Minister.
Unit:8 The Judiciary : Supreme Court and High Court - Composition,
Jurisdiction and Functions.

References:
1. Andre Beteille, 1965. Caste,class, and Power. Berkley: University of California Press.
2. Appadorai, A 1968. india: Studies In Social And Political Development 1947-1967.
New Delhi: Aisa Publishing House.
3. Desai, A R. 2016. Social Background of Indian Nationalism. Los Angeles: Papular
Prakashan.
4. Granville Austin, 2000. The Indian Constitution: Cornerstone of a Nation. Melbourne:
Oxford University Press.
5. Hanson and Douglas, 1972. India`s Democracy. New York city: W W Norton & Co
Inc.
6. Johari J C 1974. Indian Government and Politics. New Delhi: Vishal Publications.
7. Karunakaran, K.P 1964. Continuity and Change in Indian Politics. New Delhi:
People`s Pub. House.
8. Kochanek. A. 1968. The Congress Party of India: the Dynamics of a One-Party
Democracy. New Jersey: Princeton University Press.
142
9. Morris Jones, 1967. The Government and Politics of India. London: Hutchinson
University Library.
10. Myron Weiner, 1957. Party Politics in India. New Jersey: Princeton University Press.
11. Myron Weiner, 1967. Party Building in New Nation. Chicago: University of Chicago
Press.
12. Palmer, N D 1971. The Indian Political System. Boston: Houghton Mifflin.
13. Partha Chatterjee, 1998. State and Politics in India. University of Michigan: Oxford
University Press.
14. Pylee, M V 1960. Constitutional government in India. Bombay: Asia Pub. House.
15. Rajni Kothari, 1970. Politics in india. The University Of Michigan: Little Brown
16. Rajni Kothari, 1995. Caste in Indian Politics. Telangana: Orient Blackswan.
17. Venkatarangaiya: M Shiviah, 1975. Indian Federalism. New Delhi: Arnold-
heinemann Publishers.
18. Zoya Hasan, 2000. The State in Indian Politics. Landon: Sage publication.
19. DEPARTMENT – PUBLIC
ADMINISTRATION
20. INDIAN POLITY – I

21. BLOCK – 1
22. UNIT – 1 Indian Constitution. .
23.
24.UNIT – 2 Preamble - Meaning and Importance.
25.
26. UNIT – 3 Fundamental Rights and Duties.
27.
28.UNIT – 4 Directive Principles of State Policy and Relation with
Fundamental Rights.
29.
30. BLOCK – 2
31.
32. UNIT – 5 Indian Federalism and Parliamentary system of Government.
33.
34.UNIT – 6 Centre - State Relations. Legislative Administrative and
Financial
35.
36. UNIT – 7 Union Executive - President Elections, Powers and
Positions. .
37.
38. UNIT – 8 Council of Ministers and Prime Ministers - Powers and
Functions

DEPARTMENT - SOCIOLOGY
Study of Indian Society -02 Credits
143
Course Description
Every science has its own classical theories, which stand as eternal in their explanatory power
and prowess to transcend the time and region. This course intends to introduce the learners to
the classical period of sociology which is not just a bundle of theories but a consistent
tradition and formative period, even contemporary theories cannot eschew from being
inspired. After studying this course, following learning outcomes can be expected.

Course Objectives
1. To appreciate the organizational framework of Indian society
2. To appreciate the aspects unity and diversity of Indian society
3. Examine the social issues in contemporary India

Learning Outcomes
Following outcomes are expected from the learners after successfully completing the course.
Learner can/has
LOC-1: sociological insights about the social structural and organizational aspects of Indian
society
LOC-2: present the changes in institutional framework of Indian society
LOC-3: recognize the causes for major social issues and present realistic remedies
Course Content
Block-1 Social Organizations
Unit-1 Unity and Diversity-Problem of Integration
Unit-2 Caste-Characteristics and Recent Changes
Unit-3 Marginalization-SC, ST, OBC and Minorities
Unit-4 Changes in Family and Concerns of the Aged
Block-2 Social Issues in Contemporary India
Unit-5 Environmental Sanitation and Ecological Degradation
Unit-6 Educated Unemployment and Employability
Unit-7 Social Unrest-Terrorism, Naxalism, Communalism and Corruption
Unit-8 Child Rights and Right to Education (RTE)
References
 Ahuja, Ram. 2002. Study of Social Problems. Jaipur & New Delhi: Rawat Publications
 Atal, Yogesh. 1979. The Changing Frontiers of Caste. National Publishing House: Delhi
 Beteille, Andre. 1971. Caste, Class and power. Berkeley: University of California.
 Betteille, Andre. 1974. Social Inequality, New Delhi: Oxford University Press.
 Betteille, Andre. 1992. Backward Classes in Contemporary India. New Delhi:
Oxford University Press.
 Berreman, G.D. 1979. Caste and Other Inequalities: Essays in Inequality. Meerut:
Folklore Institute.
 Dube, Leela. 1997. Women and Kinship, Comparative Perspectives on Gender
 Southern South Asia.
 Das, Veena. 2006. Oxford Handbook of Indian Sociology. New Delhi: Sage
 Dube, S C. 1990. Study of Indian Society. New Delhi: National Book Trust
 Jha, Hetukar. 2015. Sanitation in India. Delhi: Gyan Books.

144
 Karve, Iravathi. 1990. Kinship Organization in India.
 Pais, Richard. 2015. Sociology of Sanitation. Delhi: Kalpaz Publications.
 Pathak, Bindeshwar. 2015. Sociology of Sanitation. Delhi: Kalpaz Publications.
 Singer, Milton & Cohen, Bernards. 1996. Structure and change in Indian Society. Jaipur:
Rawat
 Singh, Yogendra, Modernization of Indian Tradition. Jaipur & New Delhi: Rawat
 Srinivas, M N. 1995. Social Change in Modern India: Orient Blackswan
 Srinivas, M. N. 1962. Caste in Modern India and Other Essays. Asia Publishing House: Delhi

DEPARTMENT – ANCIENT HISTORY AND


ARCHEOLOGY

AHA Cultural History of Hoysalas (OE)


OE 2.1

Block - 1 Early Kings


Unit - 1 Archeological and Literary Sources
Unit - 2 Theories of Origin of Hoysalas – Sala – Nripakama – Ereyanga
Block - 2 Important Rulers
Unit - 3 Vishnuvardhana - VeeraNarasimha – I
Unit - 4 Ballala – II - Narasimha – II - Narasimha III and Ballala – III
Block - 3 Cultural Contributions
Unit - 5 Hoysala polity - Economy
Unit –6 Hoysala Society – Religion – Education - literature
Block - 4 Art and Architecture
Unit - 7 Hoysala Architecture
Unit – 8 Hoysala Art

References:

1. Epigraphia Carnatica: Relevant Volumes


2. Derrett Duncan, M.J: The Hoysalas, 1957
3. Dhakey M.A: Encyclopedia of Indian Temple Architecture
4. Desai P.B: History of Karnataka
5. Foekema Gerard: A Complete Guide to Hoysala Temples

145
6. Gopinatha Rao T.A: Elements of Hindu Iconography,Vols
7. Kelleson Collyer: The Hoysala Artists – Their Identity Style
8. Krishna Murthy M.S: The Hoysala Art, Kuppam, 2007
9. Padmnabha K: Hoysala Sculptures : A cultural Study
10.Sheik Ali B (Ed): The Hoysala Dynasty , 1972 11.William Cohelo: The
HoysalaVamsha, 1950
12.Annual Reports of the Department of Archaeology, Mysore 1939 – 46
13.Settar S: Hoysala Temples
14. Marg: In Praise of Hoysala Art
15. Narasimhachar R; Lakshmidevi Temple at Doddagaddhavalli
16. Shastri KAN: The Cholas, 17.Shastri KAN: History of South India

DEPARTMENT - EDUCATION
IDC - 2 HIGHER EDUCATION
BLOCK - 1 HIGHER EDUCATION – ORGANIZATION AND TEACHING –
LEARNING
Unit-1 Higher Education
Unit-2 Teaching Learning in Higher Education – I
Unit-3 Teaching-Learning in Higher Education – II
Unit-4 Problems and Innovations in Higher Education
BLOCK - 2 HIGHER EDUCATION – SOCIO-PSYCHOLOGICAL AND MANAGEMENT
DIMENSIONS
Unit-5 Socio-Psychological Background of College Students
Unit-6 Problems of College Students
Unit-7 Higher Education – Management Dimensions
Unit-8 Higher Education Teacher
References:
1. Shills Edward (1989) ‘The modern university Liberal Democracy’.
2. Abraham, Abu (1988) The Penguin, Book of Indian cartoons, New Delhi.
3. Chandra, Bipan (1984) Communalism Modern India, New Delhi.
4. Chauhan S.S (1989) Innovations in Teaching Learning Process, New Delhi, Vikas.
5. Srivastva A.B and Sharma K.K (1985) Elementary Statistics in Psychology and
Education, New Delhi, Sterling Publishers Pvt. Ltd.,

DEPARTMENT - COMMERCE
Elective Course – EL2.1: Entrepreneurship Development
 Objective: To enable the Students to understand about the different aspects of
Entrepreneurship Development.
 Pedagogy: A Combination of Lectures, Group Discussion, Assignments.
146
 Credits: 2 ; Examination Duration: 1 and Maximum Marks: 50 (Internal
Assessment Marks = 10 and Semester-end Examination =40)
Course Inputs
Block I

 Unit -1: Entrepreneur and Entrepreneurship: Introduction - Evolution –


Characteristics – Distinction between Entrepreneur and Manager – Functions – Types
– Entrepreneur - Concept of Entrepreneurship – Growth of Entrepreneurship in India
– Role of Entrepreneurship in Economic Development
 Unit – 2: Women Entrepreneurship: Introduction - Concept – Statistical Evidence –
New Age Women – Functions – Growth - Problems – Recent trends in Development
of Women Entrepreneurship.
 Unit -3: Rural Entrepreneurship: Introduction - Meaning – Need – Rural
Industrialisation in Retrospect – Problems – Development of Rural Entrepreneurship
– NGOs and Rural Entrepreneurship.
 Unit -4: Conceptual Models of Entrepreneurship: Introduction - Models of John
Kao – Udai Pareek and Nadakarni– NISIET.

Block II
 Unit – 5: Factors Affecting Entrepreneurial Growth And Competencies:
Introduction - Economic Factors – Non-Economic Factor – Government Actions -
Entrepreneurial Competencies: Meaning – Major Entrepreneurial Competencies –
Developing Competencies.
 Unit -6: Entrepreneurial Motivation and Mobility: Introduction - Motivation –
Motivation Theories – Motivating Factors – Achievement Motivation – Factors
Influencing Mobility – Occupational Mobility – Locational Mobility.
 Unit – 7: Entrepreneurship Development Programes: Introduction - Need for
EDPs - Objectives of EDPs – Course Contents and Curriculum of EDPs – Phases of
EDPs – Evaluation of EDPs.
 Unit -8: Institutional Support System for Entrepreneurship: Introduction - DICs –
SISIs – SIDCOs – NISIET – EDIT – NIESBU – TCOs- A Broad Overview of Central
and State Level Financing Institutions.
Books Recommended for Reference
a. Vasanth Desai, The Dynamics of Entrepreneurial Development and Management,
Himalaya Publishing House.
b. A. N Desai, Entrepreneurship Management, Ashish Publishing House.
c. Chandra Prasanna, Project Preparation, Appraisal and Implementation, Tata
McGraw Hill.
d. Khanka, S.S, Entrepreneurial Development, S. Chand Publications.
e. Prasanna Chandra, Projects: Planning, Analysis, Selection, Implementation and
Review, Tata McGraw Hill.

DEPARTMENT - MANAGEMENT
E-COMMERCE
147
Credits: 2

Module 1: E-commerce and its Technological Aspects:


Overview of developments in Information Technology and Defining E-Commerce: The scope
of E commerce, Electronic Market, Electronic Data Interchange, Internet Commerce,
Benefits and limitations of E-Commerce, Produce a generic framework for E-Commerce,
Architectural framework of Electronic Commerce, Web based E Commerce Architecture.
Module 2: Electronic Data Interchange: Benefits of EDI, EDI technology, EDI standards,
EDI communications, EDI Implementation, EDI Agreements, EDI Security. Electronic
Payment Systems, Need of Electronic Payment System: Study and examine the use of
Electronic Payment system and the protocols used, Study Electronic Fund Transfer and
secure electronic transaction protocol for credit card payment. Digital economy: Identify the
methods of payments on the net – Electronic Cash, cheques and credit cards on the Internet.

References:
1. Elias. M. Awad, " Electronic Commerce", Prentice-Hall of India Pvt Ltd.
2. Ravi Kalakota, Andrew B. Whinston, "Electronic Commerce-A Manager's guide",
Addison-Wesley.
3. Efraim Turban, Jae Lee, David King, H.Michael Chung, “Electronic Commerce–A
Managerial Perspective", Addison-Wesley.
4. Elias M Award, “Electronic Commerce from Vision to Fulfilment”, 3rd Edition, PHI, Judy
Strauss, Adel El-Ansary, Raymond Frost, “E-Marketing”, 3RDEdition, Pearson Education

DEPARTMENT - BIO CHEMISTRY


Basics of Bioorganic chemistry for Biology graduates.

Introduction to Organic chemistry: Classification of organic compounds, unique


characteristics, IUPAC nomenclature of organic compounds (including bifunctional).
Reaction mechanisms: Classification of organic reactions: substitution, addition, elimination
and rearrangement with one example for each. Concepts of the following – carbon
anions, carbon cations, free radicals, carbenes, nucleophiles and electrophiles.
Cycloalkanes: Reactivities and relative stability, Bayer’s strain theory. Sachse-Mohr theory.
Boat and chair form of cycloalkanes. Axial and equatorial bonds.
Arenes: Structue of Benzene–resonance and molecular orbital theories. Aromaticity.
Mechanism of Nitration and Friedel-Craft’s reaction. Electronic interpretation of the
orienting influence of substituents in the electrophilic substitution of Toluene,
Chlorobenzene, Nitrobenzene and Phenol. Polynuclear hydrocarbons–Resonance
structures of Naphthalene, Anthracene and phenanthrene.
SN1 and SN2 reactions, mechanism with an example for each. Concept of elimination
reactions. Example –n-butyl chloride.

Alcohols: Classification, monohydric, alcohols-distinguishing reactions for primary,


secondary and tertiary alcohols.
Trihydric alcohols: Glycerol, Properties, (KHSO4, HNO3, Oxalic acid and HI)

148
Phenols: Acidity of phenols, Effect of substitution on acidity
Stereochemistry: Stereoisomerism, types, Fischer-projection formulae, asymmetric carbon
atom, molecular dissymmetry, chirality, optical isomerism: ex. Glyceraldehyde, Lactic
acid, Tartaric acid. Nomenclature of enantiomers. D- and L- system, Recemisation and
resolution.
Heterogeneous and Homogenous hydrogenation of oils.

Selected References:
1. Basic Principles of Organic Chemistry, Roberts and Caserio, W. A. Benjamin, Inc. (1964).
2. Organic Chemistry, Morrison and Boyd, Allyn and Bacon Inc (1992).
3. Principles of Inorganic chemistry by Cotton & Wilkinson, Wiley (1999).
4. Textbook of Organic chemistry by Ahluwalia V K & Madhuri G Narosa publications
(2001).
5. Physical chemistry by Castellan G W, Narosa Publications (2004).
6. Physical chemistry by Chakraborthy D K, Narosa Publications (2004).

DEPARTMENT - BIOTECHNOLOGY
MBT EL-2 FUNDAMENTAL OF BIOTECHNOLOGY

Scope and Introduction to Biotechnology History & Introduction to Biotechnology What is


Biotechnology? Definition of Biotechnology, Traditional and Modern Biotechnology,
Branches of Biotechnology

Plant, Animal Biotechnology, Marine Biotechnology, Agriculture, Healthcare, Industrial


Biotechnology, Pharmaceutical Biotechnology, Environmental Biotechnology.

Applications Biotechnology Applications of Biotechnology in Agriculture : GM Food, GM


Papaya, GM Tomato, Fungal and Insect Resistant Plants BT Crops, BT Cotton and BT
Brinjal Pros and Cons Biotechnological applications in Crop and Livestock Improvements
Modifications in Plant Quality Golden Rice, Molecular Pharming, Plant Based Vaccines
Ethics in Biotechnology and IPR 15 lectures

Food and Fermentation Biotechnology Food Biotechnology Biotechnological applications in


enhancement of Food Quality Unit Operation in Food Processing Quality Factors in Pre
processed Food Deterioration and its Control Rheology of Food Products Microbial role in
food products Yeast, Bacterial and other Microorganisms based process and products
Fermentation Technology Definition, Applications of Fermentation Technology Microbial
Fermentations Overview of Industrial Production of Chemicals (Acetic Acid, Citric Acid and
Ethanol), Antibiotics, Enzymes and Beverages

149
Molecular Biology - Replication DNA Replication in Prokaryotes and Eukaryotes Semi-
conservative DNA replication, DNA Polymerases and its role, E.coli Chromosome
Replication, Bidirectional Replication of Circular DNA molecules. Rolling Circle
Replication, DNA Replication in Eukaryotes DNA Recombination – Holliday Model for
Recombination Transformation

Mutation and DNA Repair Definition and Types of Mutations. Mutagenesis and Mutagens.
( Examples of Physical, Chemical and Biological Mutagens) Types of Point Mutations, DNA
REPAIR Photo reversal, Base Excision Repair, Nucleotide Excision Repair, Mismatch
Repair, SOS Repair and Recombination Repair.

Genetic Engineering Experimental evidences for DNA and RNA as Genetic Material.
Genetic Engineering in Ecoli and other Prokaryotes, Yeast, Fungi and Mammalian Cells
Cloning Vectors-Plasmids ( pBR 322, pUC) Vectors for Plant and Animal Cells, Shuttle
Vectors, YAC Vectors, Expression Vectors Enzymes- DNA Polymerases, Restriction
Endonucleases, Ligases, Reverse Transcriptase’s, Nucleases, Terminal Transferees,
Phosphatases Isolation and Purification of DNA (Genomic, Plasmid) and RNA,,
Identification of Recombinant Clones

DEPARTMENT - CHEMISTRY
Block-1 Title: Physical parameters of molecules
Unit-1 Thermodynamics: First and second laws of thermodynamics. Concept of
entropy and free energy, entropy as a measure of unavailable energy. Entropy
and free energy changes and spontaneity of process.
Unit-2 Chemical kinetics: Rate and order of reaction. Factor affecting the rate of
reaction. And determination Order of reaction. Energy of activation and its
determination. Brief account of collision and activated complex theories.
Unit-3 Ionic equilibria: pH scale, buffer solutions, calculation of pH of buffer
solutions, buffer capacity and buffer index, buffer mixtures.
Unit-4 Electrochemistry: Electrolytic conductance, specific, equivalent and molar
conductance, ionic mobility and transference number, factors affecting the
electrolytic conductance, Arrhenius theory of strong and weak electrolytes,
assumptions of DebyeHuckel theory of strong electrolytes.
Block-2 Title: Organic molecules
Unit-5 Introduction to organic chemistry, atomic orbitals, sigma and pi bond
formation-molecular orbital (MO) method, sp, sp2 and sp3
hybridization, bond length, bond dissociation energies and bond angles
Unit-6 Electronegativity and polarity of the bonds. Classifications and
reactions of organic compounds (with examples).

150
Unit-7 Biological importance of natural products: Amino acids, proteins,
carbohydrates (cellulose, starch, glycogen), lipids (fats and oils, phospholipids),
nucleic acids, steroids, alkaloids, vitamins, flavonoids.
Unit-8 Applications of synthetic products: Dyes, drugs, polymers (plastics), soaps and
detergents, pesticides and pheromones.

DEPARTMENT – CLINICAL NUTRITION AND


DIETETICS
OEL - 2: NUTRACEUTICALS AND HEALTH FOODS 2 Credits

BLOCK 1. NUTRACEUTICALS:

Unit - 1: Introduction to Nutraceutical


Unit - 2: Use of Nutraceuticals in Traditional Health Sciences

Unit – 3: Functional Foods


Unit – 4: Development of Nutraceutical and Functional Foods

BLOCK 2: FUNCTIONAL FOODS AND NUTRACEUTICALS OF PLANT,


ANIMAL AND MIRCIBIAL ORIGIN
Unit - 5: Prebiotics and Probiotics
Unit - 6: Bio Active Peptides and Phyto- Chemicals

Unit - 7: Fats and Oils- Omega 3 Fatty Acids:


Unit - 8: Sugar Substitutes / Sweeteners

REFERENCES:
 Tai Hu Guan, (2018), text book of Nutraceuticals and Health, Scitus Academics
Publisher, Wilmington DE 19804, United States of America.
 Wildman REC, (2016), Handbook of Nutraceuticals and Functional Foods, 2nd
edition, CRC Press publishers, Boca Raton, Florida (USA).
 Athapol Noomhorm, Imran Ahmad, Anil Kumar Anal (2014), Functional Foods and
Dietary Supplements Processing, Effects and Health Benefits, first edition, published
by John Wiley & Sons, Ltd. UK 111 River Street, Hoboken, NJ 07030-5774, USA
 Wildman REC, (2001) Handbook of Nutraceutical and Functional Foods, CRC Press,

151
USA.Ghosh D et al, (2012) Innovations in Healthy and Functional Foods, CRC Press,
USA. Pathak YV (2011) Handbook of nutraceuticals Volume 2, CRC Press, USA.

DEPARTMENT - COMPUTER SCIENCE


ELMCS- 02: E -Commerce
BLOCK-1

UNIT-1: Overview of developments in Information Technology and Defining E-Commerce: The


scope of E commerce, Electronic Market, Electronic Data Interchange, Internet Commerce, Benefits
and limitations of E-Commerce, Produce a generic framework for E-Commerce,

UNIT-2: Architectural framework of Electronic Commerce, Web based E Commerce Architecture.


Consumer Oriented E Commerce E-Retailing: Traditional retailing and e retailing, Benefits of e
retailing,

UNIT-3: Key success factors, Models of e retailing, Features of e retailing. E services: Categories of
e-services, Web-enabled services, matchmaking services,

UNIT-4: Information-selling on the web, e entertainment, Auctions and other specialized services.
Business to Business Electronic Commerce

BLOCK-2

UNIT-5: Electronic Data Interchange: Benefits of EDI, EDI technology, EDI standards, EDI
communications, EDI Implementation, EDI Agreements, EDI Security. Electronic Payment Systems,
Need of Electronic Payment System:

UNIT-6: Study and examine the use of Electronic Payment system and the protocols used, Study
Electronic Fund Transfer and secure electronic transaction protocol for credit card payment. Digital
economy: Identify the methods of payments on the net – Electronic Cash, cheques and credit cards on
the Internet.

UNIT-7: Security in E Commerce Threats in Computer Systems: Virus, Cyber Crime Network
Security: Encryption, Protecting Web server with a Firewall, Firewall and the Security Policy,
Network Firewalls and Application Firewalls, Proxy Server. Issues in E Commerce Understanding
Ethical,

UNIT-8: Social and Political issues in E-Commerce: A model for Organizing the issues, Basic
Ethical Concepts, Analyzing Ethical Dilemmas, Candidate Ethical Principles Privacy and Information
Rights: Information collected at E-Commerce Websites, The Concept of Privacy, Legal protections
Intellectual Property Rights: Types of Intellectual Property protection, Governance.

References:

1. Elias. M. Awad, " Electronic Commerce", Prentice-Hall of India Pvt Ltd.


2. RaviKalakota, Andrew B. Whinston, "Electronic Commerce-A Manager's guide", Addison-Wesley.
3. Efraim Turban, Jae Lee, David King, H.Michael Chung, “Electronic Commerce–A
ManagerialPerspective", Addison-Wesley.
152
4. Elias M Award, “Electronic Commerce from Vision to Fulfilment”, 3rd Edition, PHI, Judy
Strauss, Adel
5. El-Ansary, Raymond Frost, “E-Marketing”, 3RDEdition, Pearson Education.

DEPARTMENT - GEOGRAPHY
ELMG –02 Regional Geography of Karnataka (Credits – 2)

Block-1

Physical setting - Location, Administrative divisions, Geology, Physiographic divisions of


the Karnataka; Climate and Rivers; Soils and Vegetation; Irrigation in Karnataka, Major
Multipurpose River Valley Projects, Major water problems and Issues - Yetthinahole,
Linganamakki, Mekedatu, Krishna-Cauvery valley-linking Rivers.

Block-2
Agriculture - Major of Crops: Rice, Jowar, Ragi, Wheat, Oil seeds, Sugarcane, Cotton,
Tobacco and Coffee; Minerals Resources - Iron ore, Manganese, Bauxite, Copper, Gold;
Major Power Projects - Hydel, Thermal and Atomic Energy power plants; Industries -
Cotton Textile, Silk Textile, Sugar, Iron and Steel, Cement and Paper industries, Industrial
Regions of Karnataka; Transportation - Roads, Railway, Water way, Ports/Harbors and
Airways; Population - growth, distribution and density

References:
1. Directorate of Information and Tourism,
Government of KarnatakaKarnataka State
Gazetteer
2. Mallappa, P., (2014) Geography of Karnataka, Chethana book publishers, Mysuru
3. N.B.K Reddy & G.S. Murthy, (1967) Regional Geography of Mysore State
4. R.P. Misra, (1973) Geography of Mysore
5. Ranganath, (2018) Geography of Karnataka, Mysore Book House, Mysuru

DEPARTMENT - MATHEMATICES
Combinatorics and Graph Theory (ELMM –02) 2 Credits

Block-I: Permutations and Combinations, Pigeon-hole principle, Principle of inclusion and exclusion.

153
Block-II: Graphs, Vertices of graphs, Walks and connectedness, Degrees, Operations on graphs,
Blocks – Cutpoints, bridges, Block graphs and Cutpoint graphs. Trees - Elementary properties of
trees,

Books for Reference:


1. C. L. Liu – Elements of Discrete Mathematics, McGraw-Hill, 1986.
2. Kenneth H. Rosen – Discrete Mathematics and its Applications, McGraw-Hill, 2002.
3. F. Harary – Graph Theory, Addition Wesley Reading Mass, 1969.
4. N. Deo – Graph Theory With Applications to Engineering and Computer Science, Prentice
Hall of India, 1987.
5. K. R. Parthasarathy – Basic Graph Theory, Tata McGraw-Hill, New Delhi, 1994.
6. G. Chartand and L. Lesniak – Graphs and Diagraphs, wadsworth and Brooks, 2nd Ed.,
7. Clark and D. A. Holton – A First Look at Graph Theory, Allied publishers.
8. D. B. West – Introduction to Graph Theory, Pearson Education Inc.,2001, 2nd Ed.,
9. J. A. Bondy and U. S. R. Murthy – Graph Theory with applications, Elsevier, 1976.

DEPARTMENT - MICROBIOLOGY
Microbes in Sustainable Agriculture and Development

i. Soil Microbiology: Soil as Microbial Habitat, Soil profile and properties,


ii. Soil formation, Diversity and distribution of microorganisms in soil.
iii. Microbial Activity in Soil and Green House Gases- Carbon dioxide, methane, nitrous
oxide, nitric oxide – production and control
i. Mineralization of Organic & Inorganic Matter in Soil: Mineralization of cellulose,
hemicelluloses, lignocelluloses, lignin and humus, phosphate, nitrate, silica,
potassium .
ii. Microbial Control of Soil Borne Plant Pathogens: Biocontrol mechanisms and ways,
Microorganisms used as biocontrol agents against Microbial plant pathogens,
Insects, Weeds.
iii. Biofertilization, Phytostimulation,
iv. Bioinsecticides: Plant growth promoting bateria, biofertilizers – symbiotic
(Bradyrhizobium, Rhizobium, Frankia),
v. Non Symbiotic (Azospirillum, Azotobacter, Mycorrhizae, MHBs,
Phosphatesolubilizers,algae),
vi. Novel combination of microbes as biofertilizers, PGPRs
i. Secondary Agriculture Biotechnology: Biotech feed, Silage, Biomanure, biogas,
biofuels – advantages and processing parameters.
ii. GM crops: Advantages, social and environmental aspects, Bt crops, golden rice,
transgenic animals.
References:
1. EldorA.Paul. SoilMicrobiology. EcologyandBiochemistry.VIEdition:Academic Press,
(2007).
2. EugeneL. Madsen. Environmental Microbiology:FromGenomestoBiogeochemistry.
IEdition,Wiley-BlackwellPublishing. (2008).
154
3. Agrios, G.N. Plant pathology. Harcourt Asia Pvt. Ltd. (2000).
4. Buchanan. B.B., Gruissem, W. and Jones, R.L Biochemistry and Molecular Biology of
Plants. I.K. International Pvt. Ltd. (2000).
5. Mehrotra R S and Ashok Agrawal. Plant Pathology. Tata Mc Graw Hill ,6th reprint
(2006).
6. K. S. Bilgrami, H. C. Dube. A textbook of modern pathology. 6th Edition, Vani
Educational Books, a division of Vikas, (1984).
7. K.R. Aneja .Experiments in Microbiology, Plant Pathology and Biotechnology . New Age

Publications.2017

DEPARTMENT - PHYSICS
MP-EL2: Waves and Optics
BLOCK-A:

Unit-1: Superposition of Two Collinear Harmonic oscillations: linearity &


superposition principle. (i) Oscillations having equal frequencies and (ii)
oscillations having different frequencies (Beats).

Unit-2: Waves Motion- General: Transverse waves on a string, travelling


and standing waves on a string, normal modes of a string, group
velocity, phase velocity, plane waves, Spherical waves, wave intensity.
Unit-3: Fluids: Surface tension: synclastic and anticlastic surface - excess of
pressure - application to spherical and cylindrical drops and bubbles.
viscosity - rate flow of liquid in a capillary tube - Poiseuille’s formula
- determination of coefficient of viscosity of a liquid.
Unit-4: Sound: Simple harmonic motion - forced vibrations and resonance
intensity and loudness of sound, intensity levels, musical notes,
musical scale, acoustics of buildings: reverberation and time of
reverberation, absorption coefficient, Sabine’s formula - measurement
of reverberation time.
BLOCK-B:

Unit-5: Wave Optics: electromagnetic nature of light, definition and


properties of wave front, Huygen’s Principle.
Unit-6: Interference: Interference: division of amplitude and division of
wavefront. Young’s double slit experiment, interference in thin films:
parallel and wedge-shaped films, Newton’s Rings: measurement of
wavelength and refractive index.
Unit-7: Diffraction: Fraunhofer diffraction- single slit and double Slit,
multiple slits and diffraction grating, Fresnel diffraction: half-period
zones, zone plate, Fresnel diffraction pattern of a straight edge, a slit
and a wire using half-period zone analysis.
Unit-8: Polarization: Transverse nature of light waves, plane polarized light –
production and analysis, circular and elliptical polarization.

155
DEPARTMENT -PSYCHOLOGY
EL-2 Psychology in Everyday Life 2 Credits
Block 1: Applications of Psychology-I
Unit 1: Psychology as a Profession
Unit 2: Memory Improving Techinques
Unit 3: Stress and Emotional Management
Unit 4: Personality Development
Block 2: Applications of Psychology-II
Unit 5: Psychology in Educational Settings
Unit 6: Psychology in Health Setting
Unit 7: Psychology in Organizational Setting
Unit 8: Adjustment to Family and Work Place
References:
1. Charles G.Morris. Albert A. Maisto Psychology an Introduction , Prentice Hall. New Jersy.
2. Feldman, A. R.,Understanding Psychology IV th Ed, 1996, McGraw Hill, New Delhi.
3. Morgan, King, Weisz &Schopler, Introduction to Psychology-V11 Ed,1993, Tata McGraw
Hill, New Delhi.
4. Ernest R Hilgard, Richard C Atkinson ,Rita L Atkinson Introduction to Psychology Oxford
Publication, New Delhi.

DEPARTMENT -INFORMATION TECHNOLOGY


ELMIT –02 E-Commerce (2 Credits)
Block 1:Fundamentals of E-commerce
Unit 1 : Introduction to E-commerce
What Is E-commerce? The Difference Between E-commerce and E-business, Technological
Building Blocks Underlying E-commerce: the Internet, Web, and Mobile Platform, Major
Trends in E-commerce, Unique Features of E-commerce Technology
Unit 2 : Types of E-commerce:
Business-to-Consumer (B2C) E-commerce, Business-to-Business (B2B) E-commerce.
Consumer-to-Consumer (C2C) E-commerce, Mobile E-commerce (M-commerce), Social E-
commerce, Local E-commerce E-commerce: A Brief History, Understanding E-commerce:
Organizing Themes, Academic Disciplines Concerned with E-commerce
Unit 3 : E-Commerce Infrastructure
The Internet, Technology Background , Internet – Key Technology concepts, TCP/IP, IP
addresses, Domain names, DNS and URLs, Client Server Computing, Cloud computing
model, Mobile platform
Unit 4 : Internet and Web

156
Hypertext, HTML, XML, Web servers and clients, Web browsers, Communication tools – E
mail, messaging apps, online message boards, Internet Telephony
Block 2: Construction of E-commerce presence
Unit 5: E-commerce presence – Building an e-commerce idea, Systematic approach,
Choosing software and hardware, E-commerce site tools
Unit 6: E-commerce security E-commerce System environment, Security threats,
Technology solutions
Unit 7: E-commerce payment systems : Management policies, E-commerce payment
systems, Electronic billing presentment and payment
Unit 8: E-commerce Business Strategies : E-commerce business models, Major B2C
Business models, B2B Business models,
References:
1. Laudon, Kenneth C., and Carol Guercio Traver. E-Commerce 2020-2021. Pearson,
2020.
2. Laudon, Kenneth C., and Carol Guercio Traver. E-commerce Essentials. Pearson,
2014

DEPARTMENT - BOTANY
Plant Diversity and Human Welfare
Plant Diversity and its Scope Levels of biodiversity: Genetic, Species and Ecosystem;
Agrobiodiversity and cultivated plant taxa and related wild taxa.
Values and uses of Biodiversity, Methodologies for valuation, Ethical and aesthetic
values, Uses of plants; Ecosystem services.
Loss of Biodiversity Loss of biodiversity- causes and implications, Hot spots of biodiversity,
extinction of species, projected scenario for biodiversity loss.
Management of Plant Biodiversity Organizations associated with biodiversity management,
IUCN, UNEP, WWF, UNESCO, NBPGR; Methodology for execution;
Biodiversity legislation; Information management and communication.
Conservation of Biodiversity, Role of Plants in Relation to Human Welfare
Conservation of genetic, species and ecosystem diversity,
In situ and ex situ conservation strategies, India’s biodiversity and its conservation Social
approaches to conservation,
Biodiversity awareness programmes, Sustainable development.
Importance of forestry their utilization and commercial aspects; Avenue trees; Ornamental
plants of India; Alcoholic beverages; Fruits and nuts; Wood and its uses; their commercial
importance.

References
157
1. Krishnamurthy, K.V. (2004). An Advanced Text Book of Biodiversity - Principles and
Practices.Oxford and IBH Publications Co. Pvt. Ltd. New Delhi
2. Singh, J.S., Singh, S.P. and Gupta, S. (2006). Ecology Environment and Resource
Conservation. Anamaya Publications, New Delhi, India.
3. Reddy, K.V. and Veeraiah, S. (2010). Biodiversity and Plant Resources. Aavishkar
publication, New Delhi.
4. Heywood, V. H. and Watson, R. T. (1995). Global biodiversity and Assessment.
Cambridge University Press.

DEPARTMENT –FOOD AND NUTRITION


SCIENCE
OEL-2: NUTRITIONAL MANAGEMENT IN DISASTER CONDITIONS
BLOCK- I: NATURAL / MANMADE DISASTERS

Unit-1: Emergency Situations-Famine, Drought, Flood, Earthquake, Cyclone, War, Civil and
Political Emergencies.

Unit-2: Nutrition in Emergencies, Nutritional Problems and Communicable Diseases.

Unit-3: Feeding Programs during Emergencies.


Unit-4: Assessment and monitoring of Nutritional Status and relief measures during
emergencies.

BLOCK- I: NUTRITIONAL RELIEF AND REHABILITATION

Unit-5: Assessment of Food needs in emergency situations, Food Distribution Strategy, Local
food rehabilitation.

Unit-6: Special Foods/ Rations for Nutritional Relief, Organizations for Mass Feeding/ Food
Distribution, and Supplementary Feeding.

Unit-7: Transportation, Storage, Feeding Centres, Sanitation, Hygiene and Identifying


Reaching the Vulnerable Group.

Unit-8: Public Nutrition Approach to Tackle Nutritional and Health Problems in


Emergencies, food security.

REFERENCES:

Jaspars, S. & Young, H. (1996), General Food Distribution in Emergencies: from Nutritional
Needs to Political Priorities. Good Practice Review 3. 1996. Relief and
Rehabilitation Network, Overseas Development Institute. London.

158
Young H., Jaspars S., Brown R., Frize J. & Khogali H (2001), Food Security and
Assessments in Emergencies: A Livelihoods Approach. Humanitarian Practice Network,
Overseas Development Institute. London

159

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