CEDAR COLLEGE EXAMINATIONS

CANDIDATE
NAME

STUDENT COURSE A 2 - C H M -
ID
e.g. A2-ACC-8

A2 Chemistry 9701
Tests: February 2021

Teacher: Mr. Bilal Hameed

Additional Material: Total Time: 1 hour

Data Booklet

Total Marks: 50

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Special Instructions

This document consists of 12 printed pages

 Do not write
2 Marks for this test: 50] outside the
box

Answer all the questions

Answer all questions in the spaces provided.
Write your answer in the space provided.

1 (a)
0 1 This question is about lattice enthalpies.

0 1 . 1 Figure 1 shows a Born–Haber cycle for the formation of magnesium oxide.

Complete Figure 1 by writing the missing symbols on the appropriate energy levels.
[3 marks]
Figure 1

.



 Do not write
3 outside the
box

0 1 .(b)2 Table 1 contains some thermodynamic data.

Table 1
Enthalpy change
/ kJ mol–1
Enthalpy of formation for magnesium oxide –602
Enthalpy of atomisation for magnesium +150
First ionisation energy for magnesium +736
Second ionisation energy for magnesium +1450
Bond dissociation enthalpy for oxygen +496
First electron affinity for oxygen –142
Second electron affinity for oxygen +844

Calculatethe
Calculate a value
valuefor
of the
the enthalpy of latticeofformation
lattice enthalpy magnesiumfor magnesium
oxide.
oxide.
[3
[3 marks]
marks]

Enthalpy of lattice formation kJ mol–1 6

Turn over for the next question

Lattice enthalpy of magnesium oxide _____________________ kJ mol—1

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−15
0 3 2 The ionic product of water, Kw = 2.93 × 10−15 mol222 dm−6
−6
at 10 °C
00 33 The
Theionic
ionicproduct
productof
ofwater, 2.93××10
water,KKww==2.93 10−15 mol
−15
mol 2
dm
dm −6at 10 °C
−6
at 10 °C
0 3 The ionic product of water, Kw = 2.93 × 10 mol dm at 10 °C
0 3 . 1 Which is the correct expression for Kw?
00 33 .. 11 Which
Which
Tick ( is the
thecorrect
)isisone correctexpression
box. expressionfor
forKKww??
0 3 . (a)
1 Which
Tick ( ) onethe
Tick ( ) one box. correct
box. expression for Kw?
Tick ( ) one box. [1 mark]
[1
[1mark]
mark]
[1 mark]

[H O]
A KKw = [H 2
O]
+[H22 O]−
=
AA Kww = [H++[H
][OH −−]
2 O]
A Kw =[H [H ][OH
+
][OH ]−]
[H ][OH ]
B +
BB Kw = [H++][H2O]
KKww==[H
[H +][H
][H22O]
O]
B Kw = [H ][H2O]
C + −
CC Kw = [H++][OH−−]
KKww==[H
[H + ][OH
][OH ]−]
C Kw = [H+ ][OH − ]
[H++][OH−−]
D Kw = [H [H ][OH
][OH ]−]
DD KKww== [H [H+ 2][OH
O] ]
D Kw = [H [H22O]O]
[H2O]

0 3 . 2 Calculate the pH of pure water at 10 °C

00 33 .. 2(b)
2 Calculate
Calculate the
thepH
pHof
of pure
pure water
waterat 10
10°C
atplaces.
°C
0 3 . 2 Give your answer
Calculate the pH to
of two decimal
pure water at 10 °C
Give your answer to two decimal places.
Give your answer to two decimal places.
Give your answer to two decimal places. [2 marks]
[2
[2marks]
marks]
[2 marks]

pH of water
pH
pHof
ofwater
water
pH of water
0 3 . 3(c) Suggest why this pure water at 10 °C is not alkaline.
00 33 .. 33 Suggest
Suggestwhy
whythis
thispure
purewater
waterat
at10
10°C°Cisisnot
notalkaline.
alkaline.
0 3 . 3 Suggest why this pure water at 10 °C is not alkaline. [1 mark]
[1
[1mark]
mark]
[1 mark]

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−3
0 3 . 4 Calculate the pH of a 0.0131 mol dm solution of calcium hydroxide at 10 °C
0 3 . (d)
4 Calculate
Give the pH of
your answer to atwo
0.0131 dm−3 solution of calcium hydroxide at 10 °C
molplaces.
decimal
Give your answer to two decimal places. [3 marks]
[3 marks]

pH of solution
pH of solution

0 3 . 5(e) The 0.0131 mol dm−3 calcium hydroxide solution at 10 °C was a saturated
0 3 . 5 The 0.0131 mol dm−3 calcium hydroxide solution at 10 °C was a saturated
solution.
solution.
A student added 0.0131 mol of magnesium hydroxide to 1.00 dm3 of water at
A student
10 °C and added
stirred 0.0131 mol of
the mixture magnesium
until hydroxide
no more solid to 1.00 dm3 of water at
dissolved.
10 °C and stirred the mixture until no more solid dissolved.
Predict whether the pH of the magnesium hydroxide solution formed at 10 °C is
Predictthan,
larger whether the than
smaller pH oforthe
themagnesium
same as thehydroxide
pH of thesolution
calciumformed at 10 °C is
hydroxide
larger than,
solution at 10smaller
°C than or the same as the pH of the calcium hydroxide
solution at 10 °C
Explain your answer.
Explain your answer. [2 marks]
[2 marks]
pH of magnesium hydroxide compared to calcium hydroxide
pH of magnesium hydroxide compared to calcium hydroxide

Explanation
Explanation

9
9

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3 Titanium(IV)
0
0 5
5 Titanium(IV) chloride
chloride cancan bebe made
made fromfrom titanium(IV)
titanium(IV) oxide
oxide as
as shown
shown in
in the
the
equation.
equation. chloride can be made from titanium(IV) oxide as shown in the
0 5 Titanium(IV)
equation. o −1
TiO (s) +
TiO22(s) 2C(s) +
+ 2C(s) + 2Cl (g) →
2Cl22 (g) 2CO(g) +
→ 2CO(g) + TiCl
TiCl44(l)
(l) ΔHo =
ΔH = −60.0
−60.0 kJ
kJ mol
mol−1

TiO2(s) + 2C(s) + 2Cl2 (g) → 2CO(g) 3 + TiCl4(l) ΔHo = −60.0 kJ mol−1 Do not write
0
0 5
5 .. 1
1 Some entropy data are shown
Some entropy data are shown in Table 3. in Table 3. outside the
box
0 5 . 1 Some entropy data are shown in Table 3.
Table 3
0 2 This question is about sodium fluorideTable (NaF).3
Table 3 Cl2(g) TiCl
Substance
Substance TiO22(s)
TiO (s) C(s)
C(s) Cl2(g) CO(g)
CO(g) TiCl44(l)
(l)
Some o toothpastes
−1 −1 contain sodium fluoride.
Cl223
Substance
S // J
JK K−1 mol
Soconcentration TiO
mol−1 of sodium 2(s)
50.2
50.2 C(s)
5.70
5.70 2(g)
223 CO(g)
198 TiCl
198per million 4(l)
253
253
The fluoride can be expressed in parts (ppm).
So / Jrepresents
1 ppm K−1 mol−1 a concentration
50.2 of 1 mg in every
5.70 2231 kg of toothpaste.
198 253
Use the equation and the data in Table 3 to calculate the
Use the equation and the data in Table 3 to calculate the Gibbs free-energy Gibbs free-energy
0 2 . 1 change
AUse
1.00the
change for
for this
g sample reaction
this of at 989
toothpaste
reaction was°C found to contain 2.88 x 10–5 mol of
equation and theatdata
989 in°CTable 3 to calculate the Gibbs free-energy
Give
sodium
Give your answer
fluoride.
your answer to
to the
the appropriate
appropriate number
number of
of significant
significant figures.
figures.
change for this reaction at 989 °C
Give your answer to the appropriate number of significant figures.
Use
Use your
Calculate answer
yourthe to
to explain
explainofwhether
concentration
answer sodium this
whether reaction
fluoride,
this is
is feasible.
in ppm,
reaction for the sample of toothpaste.
feasible.
[6

Give your answer to 3 significant figures.

Use your answer to explain whether this reaction is feasible. [6 marks]
marks]
[4 marks]
[6 marks]

−1
Gibbs
Gibbs free-energy
free-energy change
change kJ
kJ mol
mol−1
Gibbs free-energy change kJ mol−1
Explanation
Explanation
Explanation

6
6
6

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Concentration of sodium fluoridee pppm

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1 0 Table 4 shows some electrode half-equations and their standard electrode

1 0 4 Table 4 shows some electrode half-equations and their standard electrode
1 0 Table 4 shows some electrode half-equations and their standard electrode
potentials.
potentials.
potentials. Table 4
Table 4
Table 4
Electrode half-equation Eο / V
Electrode half-equation Eο ο/ V
Electrode half-equation E /V
Cl (g) + 2e− → 2Cl−− (aq)
Cl22(g) + 2e− → 2Cl (aq)
Cl2(g) + 2e− → 2Cl− (aq)
+++
1.36
1.36
1.36
NO −(aq) + 4H++(aq) + 3e−− → NO(aq) + 2H2O(aq)
NO33−(aq) + 4H (aq) + 3e → NO(aq) + 2H2O(aq)
NO3−(aq) + 4H+(aq) + 3e− → NO(aq) + 2H
+++
0.96
0.96
2O(aq) 0.96
3+ − 3+
Fe (aq) + e− → Fe3+ (aq)
Fe3+3+(aq) + e → Fe (aq)
Fe (aq) + e−→ Fe3+(aq)
+++
0.77
0.77
0.77
Cu (aq) + 2e−− → Cu(s)
2+
Cu2+2+(aq) + 2e → Cu(s)
Cu (aq) + 2e− → Cu(s)
+++
0.34
0.34
0.34
SO 2−(aq) + 4H++(aq) + 2e−− → SO2(g) + 2H2O(aq) +0.17
SO442−2−
(aq) + 4H (aq) + 2e → SO2(g) + 2H2O(aq) ++0.17
SO4 (aq) + 4H+(aq) + 2e− → SO 2(g) + 2H2O(aq) 0.17
+ −
2H (aq) + 2e− → H2(g) 0.00
2H+(aq) + 2e → H2(g) 0.00
2H+(aq) + 2e− → H 2(g) 0.00
Fe2+ (aq) + 2e−− → Fe(s)
2+
– 0.44
Fe 2+ (aq) + 2e → Fe(s) –0.44
Fe (aq) + 2e− → Fe(s) –0.44

1 0 . (a)
1 Deduce the oxidation state of nitrogen in NO − and in NO
1 0 . 1 Deduce the oxidation state of nitrogen in NO33− and in NO
1 0 . 1 Deduce the oxidation state of nitrogen in NO3− and in NO [2 marks]
[2 marks]
[2 marks]
Nitrogen in NO −
Nitrogen in NO33− −
Nitrogen in NO3
Nitrogen in NO
Nitrogen in NO
Nitrogen in NO
(b)
1 0 . 2 State the weakest reducing agent in Table 4.
1 0 . 2 State the weakest reducing agent in Table 4.
1 0 . 2 State the weakest reducing agent in Table 4. [1 mark]
[1 mark]
[1 mark]

1 0 . 3 Write the conventional representation of the cell that has an EMF of +0.43 V
1 0 . 3 Write the conventional representation of the cell that has an EMF of +0.43 V
1 0 . 3 Write the conventional representation of the cell that has an EMF of +
[20.43 V
marks]
[2 marks]
[2 marks]

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1 0 . (c)
4 Use data from Table 4 to identify an acid that will oxidise copper.

Explain your choice of acid.

Use these data to suggest a possible equation for the reaction.

Calculate the EMF of the cell that has the same overall reaction.
[4 marks]

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0 2 This question is about acidic solutions.

0 2 5 This question is about acidic solutions.

0 2 . 1 The acid dissociation constant, Ka, for ethanoic acid is given by the expression
0 2 . 1 The acid dissociation constant, Ka, for ethanoic acid is given by the expression
[CH COO − ] [H+ ]
Ka = [CH33COO − ] [H+ ]
Ka = [CH3 COOH]
[CH3 COOH]

The value of Ka for ethanoic acid is 1.74 × 10−5 mol dm−3 at 25 °C

The value of Ka for ethanoic acid is 1.74 × 10 mol dm−3 at 25 °C
−5

A buffer solution with a pH of 3.87 was prepared using ethanoic acid and
A bufferethanoate.
sodium solution with
In athe
pHbuffer
of 3.87 was prepared
solution, using ethanoic
the concentration acid andions
of ethanoate
sodium ethanoate.
was 0.136 mol dm −3−3 In the buffer solution, the concentration of ethanoate ions

was 0.136 mol dm

Calculate the concentration of the ethanoic acid in the buffer solution.
Calculate
Give the concentration
your answer of the ethanoic
to three significant figures.acid in the buffer solution.
Give your answer to three significant figures. [3 marks]
[3 marks]

Concentration of acid mol dm−3

Concentration of acid mol dm−3

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76 (a)

(i) For this reaction name the type of reaction and identify the reagent and conditions needed.

type of reaction ...................................................................................................................

reagent and conditions .......................................................................................................

[2]

(ii)

Explain your answers.

.............................................................................................................................................

.............................................................................................................................................

.............................................................................................................................................
[2]

(b) 3

benzenesulfonic acid

+ SO3

SO3H

H2SO4 is used in an initial step to generate the SO3H+ electrophile as shown.

SO3 + H2SO4 SO3H+ + HSO4–

(i) 3 H+ ions. Include all necessary

curly arrows and charges.

benzenesulfonic acid

SO3H+
SO3H
[3]

(ii) Write an equation to show how the H2SO4 catalyst is reformed.

....................................................................................................................................... [1]

© UCLES 2019 9701/43/M/J/19 [Turn over

 22
7 This question is about redox, electrode potentials and feasibility.
22
22

Table 22.1 shows standard electrode potentials for four redox systems.
You need to use this information to answer the questions below.

Redox system Equation Eө 

E ө //V
V
1 Zn2+(aq) + 2e– Zn(s) –0.76
–0.76
2 SO42–(aq) + 2H+(aq) + 2e– SO32–(aq) + H22O(l) +0.17
+0.17
3 Fe3+(aq) + e– Fe2+(aq) +0.77
+0.77
4 MnO4–(aq) + 8H+(aq) + 5e– Mn2+(aq) + 4H22O(l) +1.51
+1.51

Table 22.1

(a) A standard cell is set up in the laboratory based on redox systems 1 and 3 and
and the
the standard
standard
cell potential is measured.

(i) Draw a labelled diagram to show how this cell could be set up to measure
measure its
its standard
standard
cell potential.
cell potential.

Include details
Include details of
of the
the apparatus,
apparatus, solutions
solutions and
and the
the standard
standard conditions
conditions required
required to
to
measure this standard cell potential.
measure this standard cell potential.

Standard conditions
Standard conditions ..........................................................................................................
..........................................................................................................

...........................................................................................................................................
...........................................................................................................................................

...................................................................................................................................... [4]
...................................................................................................................................... [4]
(ii) Predict
(ii) Predict the
the standard
standard cell
cell potential
potential of
of this
this cell.
cell.

standard cell
standard cell potential
potential =
= ......................................................
...................................................... V
V [1]
[1]

© OCR 2017
© OCR 2017
 23
(b) In Table 22.1, what is the strongest reducing agent and the strongest oxidising agent?

Strongest reducing agent ..........................................................................................................

Strongest oxidising agent ..........................................................................................................

[2]

(c) Electrode potentials can be used to predict the feasibility of reactions.

Construct an overall equation for the predicted reaction between the species in redox
systems 2 and 4.

..............................................................................................................................................
7 [2]

(d)(b) Aluminium is extracted from Al 2O3 by electrolysis. Al 2O3 is dissolved in cryolite in this process.

(i) The half-equation for the reaction at the anode is shown.

O2– + C → CO + 2e–

Use this half-equation to write the ionic equation for the electrolysis of Al 2O3.

....................................................................................................................................... [1]

(ii) Aluminium oxide is electrolysed for 3.0 hours using carbon electrodes and a current of
3.5 × 105 A.

Calculate the mass of aluminium that is formed.

mass of aluminium = .............................. g [3]

(iii) Cryolite can be made from SiF4.

© OCR 2017 Turn over
4 with H2O, forming H2SiF6 and SiO2.

Write an equation for this reaction.

....................................................................................................................................... [1]

[Total: 11]