·~

Laws of Chemical Combination, Dalton's Theory, Various Jy~

of Masses ~
\~f

I Subjective Type
8. In an ionic compound moles§ : of cation to anion is

are 138 and

masset:F,~
1 : 2. If atomic
19, then ~ rrect
non-metal respectively
statement is •
1. The following data are obtained when dinitrogen and
dioxygen react together to form different compounds: (a) molecular mass of CQ91Pound is 176
(b) formula mass-:t>-(.compound is 176
Mass of dinitrogen Mass of dioxygen (c) formull m~sp fftmpound is 157
(i) . 14 g 16 g
(d) moly.S~ft mas#of compound is 157
(ii) 14g 32g
9. Two su&stance~ I and II of carbon and oxygen have
(iii) 28 g 32 g 1 .73% and 47.06% oxygen. Hence, they
respecti~
00 ~g Wg
follo1~
2. Phosphorus and chlorine form two compounds. The first (aK!~'<>f multiple proportion
compound contains 22.54% by mass of phosphorus and 6)-,..Ia« of reciprocal proportion
77.46% by mass of chlorine. In the second compound
~~w definite proportion
of
the percentages are 14.88 for phosphorus and 85.12 for r Nd) law of conservation of mass
~ .), 2S contains 97 .11 % sulphur; SO 2 contains 50% oxygen
chlorine. Show that these data are consistent with the law
~ nd H2O contains 11 .11% hydrogen. Thus,
of multiple proportions.
(a) law of multiple proportion is followed
3. Two oxides of a metal contain 27.6% and 30% of o~&_~
(b) law of reciprocal proportion is followed
respectively. If the formula of the first compound is ~
(c) law of consei:vation of mass is followed
find the formula of the second compound.
y (d) all the above
of
4. The average mass of one gold atom in a sample
occurring gold is 3.257 x 10-22 g. Use this to ate the . 11. CO, CO2 , C 20 3 follow
(a) law of definite proportion
molar mass of gold.
(b) law of multiple proportion
(c) law of conservation of mass
.S,ingle Correct Answer -Tri'.'..
:'-~ (d) all of the above
5. There are two common oxi S bur, one of which 12. Two oxides of a metal contain 50% and 40% metal M
contains 50% 0 2 by weight, the almost exactly 60%. respectively. If the formula of the first oxide is MO2' the
The weights of sulphur ·ch combine with 1 g of 0 2 formula of the second oxide will be
(fixed) are in th_e ratio o . (a? MO? . (b) MO 3 (c) M2 0 (d) M 20 5
of C 12 and C 14 is 98.0% and 2.0%
(a) 1 : 1 2: 1 13. If 1sotop1c distribution
(c) 2: 3 d) 3 : 2 respectively, then the number of C 14 atoms in 12 g of carbon
. 6. st oxide 56 gram. Iron is found is
ram oxygen and in second oxide (a) 1.032 X 1022 (b) 1.20 X 1022
ound to be combined with 48 gram (c) 5.88 X 10 3 2
(d) 6.02 x 1023
satisfy the law of
of mass ~ - . Multiple Correct Answers Type ]
ca proportion
14. One of the statements of Dalton's atomic theory is given
iple proportion
mbining volume below:
"Compounds are formed when atoms of different elements
n 10 mL of propane (gas) is combusted completely,
lume of CO2(g) obtained in similar condition is combine in a fixed ratio"
(b) 20 mL
Which of the following laws is/are not related to this
(a) 10 mL
(~) 30 mL (d) 40 mL statement?
(a) Law of conservation of mass
1.4 Physical Chem istry

(b) Law of definite proportions

(c) Law of multiple proportions
(d) Avogadro' s hypothesis
L Matching Column Type
20. Matc h the following:
15. Whic h of the statements are true'?
(a) Law of constant composition is true for a\\ Column I
comp ound s.
types of .~ ~ ~- - - - - t ~Colu
~mn U
a. On deco mpos ition 50% incre ase
(b) Mola r volum e of a gas at stand ard cond
ition s is in volum e at the press ure
22.4 L
(c) Vapour density of a gas is twice of its molecular b. On deco mpos ition 100% incre ase
mass in volum e at same temp er· ·c
(d) Atom ic mass es of most elements are fractional.
16. Whic h of the following statements are corre and press ure
ct?
(a) Fren ch chemist A. Lavoisier is calle d the c. On deco mpos it'
father of
chemistry and propo sed the law of conservatio
n of at
volum e the · ·-~r-~~ il
mass. and press ure
(b) Fren ch chem ist Josep h Proust propo sed the
law of d. Gase s hig s. COC l
definite proportions.
(c) Dalto n propo sed the law of multiple proportions t. HCl
.
(d) Rich ter propo sed the law of reciprocal propo A
rtions.
17. Whic h of the statements are true about the
comb inatio n?
law of chemical "
21. If 6.1 g ~
..Inte ger Type )i i
(a) Potas sium comb ines with two isotopes of C0 3 are adde d to 14.9 g of CH C?O H
chlorine · ~ o l u~?e 3
( 35 Cl and 37 Cl) to form two samp t ' ·sidue is foun d to weig h 16.0 g. Wha t ts the
les of KCl. Their
formation follows the law of definite compositio
n. 2 relea sed in the react ion?
(b) Different proportions of oxygen in the vario 22. e of chlor ine has only two isoto pes, Cl35 and Cl37
us oxides
of sulphur prove the law of multiple proportions and s average atom ic weig ht is 35.82 . The
. percentage
(c) H 2O and H S contain 11.11% hydrogen and bund ance of isoto pe Cl37 in the given samp le
2 5.88% is x x I0 1
hydrogen, respectively, whereas SO contains
2 50%
sulphur. The above data prove the law of reci
p~
proportions. Comprehension Type F-='
....."1111111
(d) In the decomposition ofNH , (2NH ~ ~ a
3 3 .,..~ Thre e isotopes of Mg is avail able in natur e.
the i:atio of volumes of NH , N and H is · They are f1Mg,
3 2 2 · . 2sM
12 g, 26M
12 g
The above data proves the Gay Lussac la
18. Whic h of the following pair of com pou The relative abun danc e of the isoto pes are as
n~ te the follo ws:
law of multiple proportions? Isoto pes
(a) SO2 and SO3 Relative abundance
(b) NO2 ~., .l 24Mg
(c) MgO and Mg(OH)2 (d) NO ~~ 12 80%
19. On amu scale, atomic w e i g ~ s 40.5 nMg 5%
If one u is
redefined, which of the followi d be correct? 26Mg
I 12 15%
(a) Atomic weight of Ca is 20 if o e u is defined
as 116th
of weig ht of an ato ~~ 2 23. Whic h isotope has maxi mum numb er of
atom s per gram

l (b) Atomi·c w e io
of weight of an
(c) Ato mic w7& e·
g~ htf-o n e u is defined as 1/15th
C-12
0ifon euisd efine das l/2P1
of each?
(a) f1Mg
(c) f~Mg
(b) nMg
(d) equa l
of weig ht f C-12 24. Num ber of neutr ons are highe st in
(d) At om iz fCai s80i fone uisd efine das (a) fiMg
l/301h 26 (b) 2sMg
by w~ n atom of C-12 ()
c 12Mg 12
(d) equa l

~
25. Average atomic mass of Mg is appro xima
tely equa l to
(a) 25.0 (b) 24.3 (c) 25.2 (d) 25.8

~~: :
Answers Key
Sing le Corr ect Answ er Type
V 1.66 or 3 : 5 (approx.) 5. (d)
10. (b)
6. (c) 7. (c)
8. (b) 9. (a)
3. MP3 11. (b) 12. (b)
4. Mola r mass = NA x 3.257 x 10- 22 g 13. (b)
Mult iple Corre ct Answ ers Type
14. (a, d)
15. (d)
 16. (a, b, c, d) 17. (b, C, d) Integ er Type
18. (a, b, d) 19. (a, c)
►
21. (5) 22. (6)
Match .ing Colum n Type Comp rehen sion Type
20. (a ➔ r), (b ➔ p, s), (c ➔ q, t), (d ➔ p, q, s, t)
23. (a) 24. (c) 25. (b)
Mo le Concept, Empirical Formula and Mo lec ula r For ~
mu ~

. . Ji
Sub'}ect,ve ype
_ _]
l 11. Unde r the same condi tion-- ~ gases have the same
number of molecules~ S )
1. A drug marijuana owes its activity to terahydro cannabinol,
(a) be noble gases
which contains 70% as many as carbon atoms as hydrogen
(b) have equal volume
atoms and 15 times as many hydrogen atoms as oxygen (c) have a volu ?#t> 22.4 dm3 each
atoms . The numb er of moles in a gram of terahydro
(d) have a n ~ er of atoms ·
cannabinol is 0.00318. Determine its molecular formula. that of a gas
12. The vap~ ·r a gas A is twice B. If
2. From 200 mg of CO , 1021 molecules are removed. How the molec ·1 ht of B is M, the molec ular weight of
2
many g and mole of CO are left?
2 A will b
3. The density of 0 2 at NTP is 1.429 g/L. Calculate the
standard molar volume of gas.
(a) ~ (b) 2 M (c) 3M (d) ~
~
4. A gaseous alkane is exploded with oxygen. The volume of
13. weight of two eleme nts A and B are 40 and 80
0 2 for complete combustion to CO formed is in the ratio ~
2 resp ctively. If x g of A conta ins y atoms, how many atoms
of 7 : 4. Deduce molecular formula of alkane .
· e present in 2x g of B?
5. A crysta lline s~lt on. heatin g becom es anhydro~~ an_d
· , · y y
loses 45.6% of its weight. Its percentage composition i~
. ) (b) (c) y (d) 2y
Al-10 .50% , K-15 .1%, S-24.96%, and 0-4 9.~~., .. 2 4
What is the formula of the anhydrous and crystallin~ ~ ~ Er+?~ ·.
__,J c ~
-....-.-- -,,,-:
Ii~
:.,
Single Corre ct Answ er Type
-- . .
Multiple Correct Answ ers Type
-
.1
14. Whic h is/are correc t statem ents about 1.7 g of NH3?
6. Insulin contains 3.4% sulphur. What will bt?ii{ ~ m (a) It contains 0.3 mol H-ato m
molecular weight of insulin?
(a) 94.176
V"':, (b) It contains 2.408 x 1023 atoms
(b) 1884' 9~ . (c) Mass % of hydro gen is 17.65 %
(c) 941.176 (d) 976 V., (d) Vapour density of NH is 17
7. The volume occupied by 7 .23W ,:3. lecules of carbon 3
15. ~ich of the following has same perce ntage of carbon as
dioxide and 3.01 x 1023 molec. .Argon at 0°C and 10 ethane?
1 atm pressure is
(a) 2-Butene (b) Cyclo hexan e
(a) 38 mL & 3.80 L (c) Cyclohexene
(c) 3.8 x 104 mL V 3.8 x 103 mL 16.
(d) 2-Me thyl but-2-ene
2.0 g of a tri-atomic gaseous eleme nt was found to occupy
8. A given sample of pound contains 9.81 g of Zn, a volume of 448 mL at 76 cm of Hg and 273 K. The mass
1.8 x 1023 atom m, and 0.60 m0l of oxygen of its atom is

(a) ZoCrs,j
atoms. What is

(c) ZnC
st formula?
(b) ZnCr2O4
(d) ZnCr 06 17.
(a) 33.3 amu
(c) 33.3 g
You have given 4.25 g NH (g).
(b) 5.53 x 10-23 g
(d) 5.53 amu
9. Asam __,_ nium has a mass of 54.0 g. What is the Given: at. wt. of N-14 ; H ~l
mas ame number of magnesium atoms? Which of the following is/are correct regarding above NI-½:
( (b) 24 g (c) 48 g (d) 96 g (a) It contains 0.25 mole of NH
-:- 1 litre flasks are separately filled with the gases (b) It contains 0.75 mole of H-aio m
, e, 0 2 and 0 3 at the same temperature and pressure.
(c) It contains total of 1.0 mole of N and H atoms.
e ratio of total number of atoms of these gases present
(d) It contains approximately 1.5 x 1023 molecules of NI{
different flask would be: 18.
(a) 1 : 1 : 1 : 1 Whic h of the follow ing conta ins same numb er ol
(b) 1 : 2: 2: 3 molecules?
(c) 2: 1 : 2 : 3 (d) 3 : 2 : 2 : 1 (a) l g of 0 , 2 g of so
2 2
(b) 1 g of CC\, 1 g ofN
2
o
 Some Basic Concepts, Mole Concept and Stoichiometry 1.7

(c) 112 mL of 0 2 at S.T.P, 224 mL of He at 0 .5 atm and 23. If a protein has 0.07% Fe (M = 56) by weight as the only
273 K metal, its molar mass would be at least M x 104 • Here
(d) 1 g of oxygen, 1 g of ozone Mis. .. . ♦
19. For 3 mole of ammonia (g), which of the following is true?
(a) It contains 12 NA atoms
(b) Volume at S.T.P. is 67.2 litre E Comprehension Type
(c) No. of molecules is 1.80 x 1024 Passage 1:
(d) Total no. of electrons is 1.80 x 1025 A crystalline hydrated salt on being rendered rous loses
45.6% of its weight.
Matching Column Type.. The percentage composition of anl~m♦lt is: Al= 10.5%,
---,. .j - K = 15.1 %, S = 24.8% and oxyge. & ~
20. The recommended daily dose is 17 .6 milligrams of vitamin [Molar mass =27, K =39, S =32).
C (ascorbic acid) having formula C H O . 24. What is the empirica~
6 8 6 a the salt?
Match the following. Given: NA= 6 x 1023 (a) KiAlS 2O 7 (b) KiA12 S2O7
Column I Column II (c) KA1S 2O8 d) ~AlS2O 12
a. O-atoms present 10-4 mole 25. What is the em · ormula of the hydrated salt?
p.
(a) (b) KiA12 S2O 7 .16H2O .
b. Moles of vitamin C in q. 5.68 X 10- 3
1 g of vitamin C (c) 2
0 (d) KA1S 2O 8.12H2 O

C. Moles of vitamin C r. 3.6 X 1020

should be consumed daily n\C•1trst used by Ostwald in 1896 refers for the ratio
of ~~-s_y stance in g and its molecular weight. 1 mole of a
. * · ·---,-: · ~~ ga~=~~~gi"f,ound occupies 22.4 litre at NTP and contains 6.23
---~
- -'-"-"'-'-.__,._ir,_ -
Integer Type ·\ .·
·- ·
· · fii.
0 23
mofecules of gas.
e vapour density of a mixture containing NO and N O
2 2 4
21. The hydrated salt N¾SO4 · nH2O undergoes 50.3% loss 1·~n 38.3 at 27°C. The moles of NO2 in 100 mole mixture is
weightonheat ingandbecom eanhydrous.T hevalueof'' (a) 33.48 (b) 53.52 (c) 38.3 (d) 76.6
will be _ _. ♦..... '11111111 27. The maximum number of atoms present are in ·
22. HowmanyNA electronsispr esentin5.lgN H3~ ~ (a) 4gHe (b) 4gO2 (c) 4gO 3 (d) 4gH2O 2

-------------~
l ~swers Key
Subjective Type ~- 16. (a, b) 17. (a, b, c, d)
1. C21 H 30O 2
3. 22.39 litre mo1- 1
5. K ·Al· S 2O 8 · 12H2O
HVV
2. 2.88 x
4. C2
10-'9~ 18. (a, b, c)
Matching Column Type
20. (a ➔
19. (a, b, c, d)

r), (b ➔ q), (c ➔ p)
Single Correct Answer Type

s.a~
§.r.V
Integer Type
6. (c) 7. (c) 9. (c) 10. (c)
11. (b)
21. (8) 22. (3) 23. (8)
12. (b)
Multiple Correct Answ Comprehensio n Type

14. (a, b, c) (Ii- . (a, b, d) 24. (c) 25. (d) 26. (a) 27. (a)
 Stoi chio met ry and Limiting Rea ctan t
V
Subjective Type 8. In a certain oper-ation 358 TiC1 4 is reacted with
96 g of Mg. Calculateq o if 32 g of Ti is actually
1. A compo und which contains one atom of X and two atoms 4
obtained [At. wt. = 4 =2 l
ofY for each three atoms of Z is made by mixing 5.00 g
(a) 35.38% · ) 66 -6 %
of X, 1.15 x 1023 atoms ofY and 0.03 mole of z atoms.
Given that only 4.40 g of compo und results. Calculate the
(c) 100% (d) 60 %
9. NX is r allowin g step of reactions
atomic weight ofY if the atomic weight of X and Z are 60
and 80 a.m.u. respectively. 2
· 3 M 3X 8
2. Calcul ate the mass of FeO prqduc ed from 2 g VO and
0 3 ~ NX +CO2 + Mp4
5.75 g of Fe2O 3. Also report the limiting.reagent.
M (metal) is consum ed to produc e 206 g of
VO+ Fe2O3 ~ FeO + V2Os
eat. wt. ofM = 56, N = 23, X = 80)
3. Carbon disulph ide, cs ·, can be made from by-product of
2 14 7
SO2. The overall reactio n is ~ ( ) 2g (b) 56 g ( ) ( d)
c 3 g 4 g
SC + 2SO2 ~ cs2 + 4CO
e f o11owmg
· process h as been used to o b tam · 10
· di ne f rom
How much CS 2 can be produc ed from 440 kg of waste SO~
with 60 kg of coke if the SO2 conversion is 80%? ~s~
4. What weight of zinc would be required to produce eno
hydrog en to reduce comple tely 8.5 g of copper ~
. .-
11-field brines in California.
Nal + AgNO ~ Agl + NaNO
2
3 3
Agl + F e ~ Fel2 + 2Ag
copper ? ~ 2Fel2 + 3Cl2 ~ 2FeC13 + 21 2
5. 200 mL of any gas at N.T.P was heated with Ti got How many grams of AgNO 3 are require d in the first step
conver ted into stanno us sulphide and hy~ s left. · for every 254 kg 12 produc ed in the third step?
Thishy drogen whenp assedo verhot CuO, 0.162g (a) 340x 104 (b) 340x 103
• of ffiO. If the vapour density of
formul a.
th~l 7, find its (c) 34 x 10 3
(d) 34 x 105
..,. 11. If20.0 g ofCaC O3 is treated with 20.0 g ofHCl , how many

Ii: .
- - ........_
Single Correct Answe~
A ....
Tfe!' mn ·

6. Calcul ate the amoun t o f ~ e d in the Mond' s process

grams of CO2 can be produc ed accord ing to the reaction:
CaCO ls) + 2HCl(aq) ~ CaCli( aq) + H 2O(1) + CO/g)
(a) 8.80 g (b) 7.70 g (c) 8.00 g (d) 7.20 g

given below. ~
Ni +4CO
If CO used in t ·
•.,
)4 ·
. obtai~ed through a process,
~ tiple Correct Answers Type
¾
II
12. 2.4 g of pure Mg (at. mass 24) is droppe d in 100 mL

+9£
of
in which 6 g o 1 mixed with 44 g CO2 . lN HCL What is true?
(a) 1.122 L of hydrog en is produc ed at S.T.P.
Ni Ni(C0 )4
(b) 0.01 mol of magne sium is behind
(a) ~ 4 . 9g (c) 58 g (d) 28 g
7. Equ (c) 0.1 mol of Mg+ ions are formed in solution
X' (At. wt.= 36) and 'Y' (At. wt.= 24)
(d) HCl is the limitin g reagent

~
to fo~ the compo und X 2Y 3 • Then:
13. A+ B ➔ A3B (unbalanced)
s the limitm g reagen t 2

a
A 3B2 + C ➔ A3B 2C (unbalanced)
is the limitin g reagen t 2
Above two reactions are carried out by taking 3 moles each
No reactan t is left over and mass of X 2Y 3 formed is
of A and B and one mole of C. Then which option is/are
double the mass of ' X' taken correct?
(d) None of these (a) 1 mole of A 3B 2C is formed
2
 Some Basic Concepts, Mole Concept and Stoichiometry 1.9

(b) 1/2 mole of A3B 2C 2 is formed b. N 2 + 3H 2 ➔ 2NH 3 q. 1.333 g

(c) 1/2 mole of A3B2 is formed lg lg

(d) 1/2 mole of A3B2 is left finally r.

C. CaCO 3 ➔ CaO + CO 2
14. If 27 g of carbon is- mixed with 88 g of oxygen and is lg
allowed to burn to produce CO 2, then:
(a) Oxygen is the limiting reagent
(b) Volume of CO 2 gas produced at NTP is 50.41 L
d. 2H 2 ➔ C + CH 4
lg lg
s. r-7<:,J
(c) C and O combine in mass ratio 3 : 8
(d) Volume of unreacted 0 2 at STP is 11.2 L •
15. Which of the following statements is/are correct?
A mixture containing 64.0 g H 2 and 64.0 g 0 2 is igni,t ed
E a. -

Integer Type . _
so that water is formed as follows: 18. 10 g of hydrogen and~ ,f ~ en were filled in a steel
2H 2 + 0 2 ~ 2H2O vess~l and_ exploded . , m" nt of water produced in this
reaction will be . . . . · ~·,
(a) H 2 is the limiting reagent
19. If 5 g H2 is mixed with I~ of nitrogen for the following
(b) 0 2 is the limiting reagent
(c) The reaction mixture contains 72.0 g of H 2O and
56.0 g of unreacted H2.
reacti:: ~~
3
(d) the reaction mixture contains 56.0 g of H 2O and
At the e~ f H2 left unreacted is ... ·- ~ - - -
72.0 g unreacted H 2.
16. Which of the following is/are correct?
, C~mprehension Type
The following reaction occurs:
Na2CO 3 + 2HC1 ~ 2NaCl +CO2+ H2O Cis p ~ afl anticancer agent used for the treatment of solid
106.0 g of N~CO3 reacts with 109.5 g of HCI. tumors, Tu.prepared by the reaction of ammonia with potassium
(a) The HCl is in excess .~ oroplatinate.
(b) 117.0 g of NaCl is formed . PtCl + 2NH ➔ [Pt(NH ) Cl ] 2KC1
3 2 2
(c) The volume of CO2 produced at 1 bar and 273 K ~s 4 3
22.7 L. ~ Cis-platin
(d) The volume of CO2 produced at 1 bar and 298 Assume that 10 g of KiPtC14 and 10 gm of NH3 are allowed
24.7 L. to react. (K = 39, Pt= 195, Cl= 35.5)
20. Number of moles of K2PtCl4 consumed
Matching Column Type.' (a) 0.048 (b) 0.024 (c) 0.012 (d) 0.096
21. Number of moles of NH3 consumed
17. Match the following: (a) 0.048 (b) 0.024 (c) 0.096 (d) 0.192
Column I Coluninll · 22. Number of moles of excess reactant which remains
' : og of CaO unreacted is
a. 2H 2 + 0 2 ➔ 2H2O (a) 0.024 (b) 0.34 (c) 0.54 (d) 0.56
lg lg

Answers Key
Subjective Type ~ . 14. (b, C, d) 15. (b, c)
~ 6kg 16. (a, b, c, d)
1. 70amu 2. E
4. (i) 0.214 .. g Matching Column Type
5. H2
17. (a ➔ r), (b ➔ s), (c ➔ p), (d ➔ q)
Single Co•~f0-i,:J.'7t:fill.l_.,. Type
Integer Type
6. (a) 8. (a) 9. (a) 10. (b)
18. (4) 19. (2)
11.
Comprehen sion Type
,,,ti orrect Answers Type
21. (a) 22. (c)
w,i, d) 13. (b, d)
20. (b)
Mole Concep t in Solution s

of positiYe ion is -l0<7'c lesser ,i...~(\,

~ ncentration of negative
Subjectri1e Type
ion. Assuming total vcj~ ~1tion I 000 ml.
1. (a) How much Ca(NO ):! in mg must be present in 50 mL (a) 400 mL NaCL 60Q.'bd/CaCI,
3
of a solution with 2.35 ppm of Ca? (d = 1 glee) (b) 600 mL NaCL -lOO 1n¢caCI;
(b) What is the molarity of NaCl solution haYing 1.52 ppm (c) 800 mL Nar&>
C m L CaC\ 2
of Na and the solution density is l.O g/cm3? (d) None o~ th~
· 2. Calculate the ionic strength (in g/litre)of a solution ~ ~
containing 0.2 M NaCl and 0.1 M N~SO .
4
·
3. What volume of water should be added to 50 mL of HNO,
_ _• Multiple Correct Answers Type
l""-.J1"'
-==:J
having density 1.5 g mL-1 and 63.09c by weight to hav: 12. 100 ~'f-0.-8 M NaOH are used to neutralised 100 ml.
one molar solution. ~ ~ ~ a i ned by passing 2. 70 g SO 2C1 2 in water. Select
4. 5 g of KiSO4 was dissolved in 250 mL of solution. How ~ct statement:
many mL of this solution should be used so that 2.33 g of e solution of SOFl2 has 0.2 M H 2SO4 and 0.4 M
BaSO4 may be precipitated from BaCl2 solution. ~ HCl
The volume ratio of NaOH used for H SO and HCI
K 2S0 4 + BaCl 2 ~ BaSO 4 + 2KCl ~ is 1 : 2
2 4

5. In a solution, the concentration of CaCli is 5 M an~~~..., (c) The volume ratio of NaOH used for H~SO 4 and HCI
of MgC12 is 5 m. The specific gravity of solution is 1.~ ~ is 1 : 1 -
Cfalmcu1aant~tyth.e concentration of c1- in the solutiot ~ (d) Molarity of S02C!2 solution is 0.1 M
0 01 ~ 'v 13. Which one are correct about the solution that contains 3.42
_ _ ...,.,..,...-. ppmAl/SO4\ and 1.42 ppm N~ SO ?
llf: , Single Correct Answer Type
✓
. (a) [Al3+] = [Na+]
4

6. The mole fraction of a given sample pfj;1f e H 6 6

is 0.2. (b) [So!-] = [Na+] = [Al3+]
. The molality of 1i in C 6 H 6 is: ~ (c) [so!-]= [Na+]+ [A\3+]
(a) 0.32 (b) 3.2 (c)(O-~½ (d) 0.48
7. 125 mL of 10% NaOH (wN) ~~~to 125 mL of 10% (d) [So!-]= [Na+]
HCl (wN). The resultant solution becomes 14. Which of the following graphs correctly represents the
(a) alkaline ~..,.strongly ~kaline variations~ ·
(c) acidic ~ · ~ neutral .
8. The molarity oft ·on ·containing 2.8% (mass/
volume) solution : (Given atomic mass of K =
39) is:
(a) 0.1 M M (c) 0.2 M (d) 1 M
9. If 500 m solution of glucose is mixed with
500 ution of glucose. The final molarity of
Temperature Temperature
0.5 M (c) 2 M (d) 1.5 M
lality of a sulphuric acid solution is 0.2. calculate
1 weight of the solution having 1000 g of solvent.
1000g (b) 1098.6g
c) 980.4 g (d) 1019.6 g
11. What volumes should you mix of 0.2 M NaCl and O. l M
CaCii solution so that in resulting solution the concentration
Dilution
Dilution
 15. Which of the following concentratio n are correct for d. IO mL of 0.5 M AgNO 3 was required s. 0.1 M
13 mass percent of sulphuric acid (densit y: 1.09 g mL- 1)? lo react exactly with I 00 mL solution
(a) 1.443 M (b) 1.625 M ofNaCN.
(c) 1.625 mol kg- 1 (d) 1.525 mol kg- 1
Ag®+ 2CN° -➔ Ag(CN)r
16. I mole BaF, + l mole H 2SO4 ---+
- Resulting mixture What is the molarity of NaCN?
will be neutralized by
(a) 2 mol of KOH (b) l mo! of Ca(OH) 2
(c) 4 mo! of KOH (d) 2 mole of NaOH f Integer Type
l ~ . r" .,
Matching Column Type 18. How many mL of a solutiorr'tif c~ centration I 00 mg
Co 2+ per mL is needed to~ep'are IO mL a solution of
17. Match the reactions given in Column I with molarities concentration 20 mg ~ fer frl?
given in Column II: 19. HCl gas is passed int~~rtr, yielding a solution of density
1.095 g mL- 1 and containf~30% HCI by weight. Calculate
Column I Column II
the molarity of 9.lution.
a. What molar concentration of p. 0.25M 20. How many ·tr H 3AsO4 require to prepare 4 litre
K 4 [Fe(CN) 6] should be used so of l M
that 40 mL · of a solution titrates
196.2 mg Zn (dissolved) by forming Comprehension Type
KzZn3[Fe(CN\]z. (Atomic weight Zn
= 65.4.g mol-1) HN~ ud ~ ):agent has specific gravity of 1.42 g mL- 1 and
b. 40.0 mL ofN3iSO4 solution is treated q. 0 .05 M cont?r~'iQo/) by strength HN03. .
with an excess of BaC12 • If the mass 1. N~ ality of acid is: •
of the precipitated BaSO4 is 2.33 g, (a) 16.78 (b) 15.78
the molarity of the N32SO4 solution is ~ ) 14.78
1
(d) 17.78
(Mw ofBaSO4 = 233 g mol- 1) • Volume of acid that contains 63 g pure acid is
BaC12 + N32SO4 --+ ~aSO4 + 2NaCl (a) 100 mL (b) 40.24 rnL
(c) 63.38 mL (d) 70.68 mL
c. A sample of solution containing r.
23. Volume of water required to make 1 N solution from 2 mL
116 mg of Th+ requires 50.0 mL of
cone. HN03 is
H 2C 2O 4 to precipitate Th(C2 O4 ) 2 .
(a) 29.5q mL (b) 30.56 mL
Th4+ + 2C2 O~---+ Th(C2 O4 ) 2 (c) 28.56 mL (d) 31.56 mL
What is the molarity of H 2 C G . .
(Atomic weight of Th= 232 g)l ~· w--lL__.J___ _

Answers Key
Subjective Type 16. (a, b, d)
1. (a) 0.48 mg Matching Column Type
2. 9.6 g/L
17. (a ➔ q), (b ➔ p), (c ➔ r), (d ➔ s)
4. 87 mL .36 in 1 litre solution
Integer Type

10. (d) 18. (2) 19. (9) 20. (2)

6. (b) 8. (b) 9. (a)
11. (d) Comprehension Type

e
Multiple

12.
c Answers Type

13. (a, c) 14. (a, b, c) 15. (a, d)

21. (b) 22. (c) 23. (a)

C)