C184-E037D

Gas Chromatograph Series Columns

GC Columns Guidebook
Contents
Fused Silica Specific Use
SH-I-1MS P. 7 Acidic Compounds Analysis
SH-I-1HT P. 9 SH-PolarD P.39
SH-I-5MS P. 8
SH-I-5Sil MS P.10 Basic Compounds Analysis
SH-I-5HT P. 9 SH-5 Amine P.38
SH-I-17 P.12 SH-35 Amine P.38
SH-I-17Sil MS P.13 SH-Volatil Amin P.35
SH-I-35Sil MS P.12 SH-PolarX P.40
SH-I-624Sil MS P.14
SH-I-1301Sil MS P.15 Blood Alcohol Analysis
SH-I-PAH P.13 SH-BAC Plus1 P.37
SH-I-XLB P.11 SH-BAC Plus2 P.37
SH-1 P.16
SH-1 PONA P.16 Pesticides Analysis
SH-5/5MS P.17-18 SH-OPP2 P.32
SH-20 P.19 SH-CLP P.33
SH-35 P.20 SH-CLP II P.33
SH-35 MS P.20
SH-50 P.21 PCBs Analysis
SH-65 P.21 SH-PCB P.35
SH-65TG P.22
SH-200/200MS P.25 Volatile organic pollutants Analysis
SH-225 P.27 SH-VRX P.35
SH-440 P.27 SH-VMS P.34
SH-502.2 P.27
SH-624 P.23 Guard Column
SH-1301 P.22 Integrated Guard Columns P.49
SH-1614 P.31 SH-I Guard / Retention Gap Columns P.47
SH-1701 P.24 SH-IP Guard Columns P.48
SH-2330 P.28 SH Guard Column Polar Deactivated P.48
SH-2560 P.28 SH Guard Column Base Deactivated P.48
SH-Wax P.29 SH-MetalX-Siltek Guard Column P.49
SH-FAME P.36
SH-PolarWax P.30
SH-PolarWAX MS P.41

Fused Silica PLOT

SH-Alumina BOND/KCl P.42
SH-Alumina BOND/Na2SO4 P.42
SH-Msieve 5A P.43
SH-Q-BOND P.44
SH-U-BOND P.44
SH-Particle Trap P.47

Stainless Steel (Siltek)

SH-MetalX-1 P.45
SH-MetalX-1HT SimDist P.45
SH-MetalX-5 P.45
SH-MetalX-1701 P.46
SH-MetalX-WAX P.46
SH-MetalX Biodiesel TG P.46
Capillary Columns
Column Selection Guide

Check the structure of the target components

Investigate the structure (functional group), boiling point, nature, stability, and other properties of the target component.

Select the stationary phase

Selecting a stationary phase of chemical properties close to those of the target component helps
increase retention force and prevent drops in separation caused by defective peak shape.

** % cyanopropylphenyl
Stationary 100% dimethyl ** % diphenyl / ** % Trifluoropropyl methyl
/ ** % dimethyl Polyethylene glycol
Phase polysiloxane dimethyl polysiloxane polysiloxane
polysiloxane
Polarity Non-polar Low to Medium Medium Medium to High High
Aromatic compounds are Effective for separation of Uniquely retains
Separation Elution in boiling Strong retention of polar
retained by phenyl group oxygenated compounds, compounds containing
Properties point order compounds
content isomers, etc. halogens
Flavors, environmental Halogenated compounds,
Gasoline and Pesticides, PCBs, Polar compounds,
Applications related, aromatic polar compounds,
solvent related oxygenated compounds solvents, Flavors, FAME
compounds solvents
SH-I-5MS
SH-I-5HT
SH-I-17
SH-I-1MS SH-5
SH-1301
SH-I-1HT SH-5MS SH-200 SH-Wax
Columns SH-624
SH-1 SH-20 SH-200MS SH-PolarWax
SH-1701
SH-MetalX SH-35
SH-35MS
SH-65
SH-MetalX-5

Determine the column size

Determine the column size according to the sample amount to inject while referring to the following table.

Has extremely high resolution but its sample load is small.

0.18 mm • Samples having a complex mixed system
• Suited to split injection
Has high resolution and a moderate sample load
0.25 mm
• Supports samples having a complex mixed system
Inner Diameter 0.32 mm
• Suited to split/splitless injection
Has satisfactory resolution and a large sample load
• Suited to purity measurement and analysis of trace components
0.53 mm
• Used in direct injection, on-column injection, and large-volume injection
• Can be easily replaced from packed column
• Good separation of high-concentration components
Thick Film
• Suited to purity analysis
Film Thickness • Fast elution of high boiling point compounds
Thin Film • Suited to the analysis of medium to high boiling
point compounds
When twice as long (for fixed-temperature analysis)
Length • The analysis time will be twice
• The degree of separation will be 1.4 times
 Capillary Columns
Cross-Reference

Similar Phases
Shimadzu Stationary Phase USP Page
Agilent Supelco SGE Phenomenex Quadrex Alltech

High-Performance Columns

HP-1ms UI,
HP-1ms,
G1, G2, DB-1ms UI, SPB-1, ZB-1,
SH-I-1MS 100% dimethyl polysiloxane BP-1 007-1 AT-1ms 7
G38 DB-1ms, Equity-1 ZB-1ms
Ultra-1,
VF-1ms

HP-5ms UI,
HP-5ms,
5% diphenyl / HP-5msSV, SPB-5, ZB-5,
SH-I-5MS G27, G36 BP-5ms 007-5 AT-5ms 8
95% dimethyl polysiloxane DB-5, Equity-5 ZB-5msi
Ultra-2,
CP Sil 8 CB

SH-I-1HT 100% dimethyl polysiloxane − DB-1HT − − ZB-1HTinferno − AT-1ht 9

5% diphenyl / DB-5HT,
SH-I-5HT − − HT-5 ZB-5HTinferno − − 9
95% dimethyl polysiloxane VF-5HT

DB-5ms UI, ZB-5MS,

1,4-bis(dimethylsiloxy)phenylene
SH-I-5Sil MS G27, G36 DB-5ms, SLB-5ms BPX-5 ZB-Semi-Volatiles, 007-5MS − 10
dimethyl polysiloxane
VF-5ms ZM-5MS plus

DB-XLB, ZB-MR1,
SH-I-XLB proprietary phase − − − − − 11
VF-Xms ZB-XLB

HP-17,
50% diphenyl / DB-17,
SH-I-17 G3 SPB-17 − ZB-50 − − 12
50% dimethyl polysiloxane DB-17HT,
DB-608

DB-35ms,
BPX35,
SH-I-35Sil MS proprietary phase G42 DB-35ms UI, − ZB-MR2 − − 12
BPX608
VF-35ms

DB-17ms,
SH-I-17Sil MS proprietary phase G17 − BPX-50 − − − 13
VF-17ms

SH-I-PAH proprietary phase G51 − − − − − − 13

DB-624,
SH-I-624Sil MS proprietary phase G43 VF-624ms, − BP-624 − − − 14
CP-Select 624 CB

SH-I-1301Sil MS silarylene-based cyano G43 VF-1301ms − − − − − 15

General Purpose Columns

HP-1,
G1, G2, AT-1,
SH-1 100% dimethyl polysiloxane DB-1, SPB-1 BP-1 ZB-1 007-1 16
G38 EC-1
CP Sil 5 CB

HP-5,
5% diphenyl / AT-5,
SH-5 G27, G36 DB-5, SPB-5 BP-5 ZB-5 007-5 17
95% dimethyl polysiloxane EC-5
CP Sil 8 CB

HP-5,
5% diphenyl / AT-5,
SH-5MS G27, G36 DB-5, SPB-5 BP-5 ZB-5 007-5 18
95% dimethyl polysiloxane EC-5
CP Sil 8 CB

20% diphenyl / AT-20,

SH-20 G32 − SPB-20 − − 007-20 19
80% dimethyl polysiloxane EC-20

SH-35/ 35% diphenyl / HP-35, SPB-35, BPX-35, AT-35,

G42 ZB-35 007-35 20
SH-35MS 65% dimethyl polysiloxane DB-35 SPB-608 BPX-608 AT-35ms

HP-50+,
SH-50 100% methyl phenyl polysiloxane G3 SPB-50 − − 007-17 AT-50 21
CP-Sil 24 CB

4
 Similar Phases
Shimadzu Stationary Phase USP Page
Agilent Supelco SGE Phenomenex Quadrex Alltech

65% diphenyl /
SH-65 − − − − − 007-65HT − 21
35% dimethyl polysiloxane

65% diphenyl /
SH-65TG − CP-TAP-CB − − − 007-65HT − 22
35% dimethyl polysiloxane

DB-1301,
6% cyanopropylphenyl /
SH-1301 G43 CP-1301, − − − 007-1301 AT-1301 22
94% dimethyl polysiloxane
VF-1301ms

HP-624,
6% cyanopropylphenyl / DB-624,
SH-624 G43 SPB-624 BP-624 ZB-624 007-624 AT-624 23
94% dimethyl polysiloxane DB-624 UI,
VF-624ms

DB-1701P,
DB-1701,
14% cyanopropylphenyl / ZB-1701,
SH-1701 G46 CP Sil 19 CB, SPB-1701 BP-10 007-1701 AT-1701 24
86% dimethyl polysiloxane ZB-1701P
VF-1701ms,
VF-1701 Pesticides

DB-210,
SH-200/
Trifluoropropylmethyl polysiloxane G6 DB-200, − − − − AT-210 25
SH-200MS
VF-200ms

50% cyanopropylmethyl / DB-225,

SH-225 G7, G19 SPB-225 BP-225 − 007-225 AT-225 27
50% phenylmethyl polysiloxane CP-Sil 43 CB

modifiedpolysiloxane
SH-440 − − − − − − − 27
(uniquephase)

SH-502.2 diphenyl / dimethyl polysiloxane − DB-502.2 − − − − − 27

90% biscyanopropyl /
SP-2330,
10% cyanopropylphenyl G5,G8,
SH-2330 VF-23ms SP-2331, BPX-70 − 007-23 AT-Silar90 28
polysiloxane G48
SP-2380
(Non-bonded)

SH-2560 biscyanopropyl / polysiloxane G5 HP-88, CP-Sil88 SP-2560 − − − − 28

G16, G20, AT-WAXms,

SH-Wax Polyethylene glycol DB-Wax − BP-20 ZB-Wax 007-CW 29
G39 EC-WAX

HP-INNOWax,
G16, G20, AT-WAX,
SH-PolarWax Polyethylene glycol CP-Wax 52 CB, Supelcowax-10 − ZB-Wax Plus − 30
G39 EC-WAX
VF-WAX MS

Dedicated Columns

SH-1614 Ideal for analysis of PBDE − − − − − − − 31

Ideal for analysis of

SH-OPP2 − − − − − − − 32
organophosphorus pesticides

SH-CLP/ Ideal for analysis of organochlorine DB-CLP1 /

− − − − − − 33
SH-CLP II pesticides DB-CLP2

Ideal for analysis of volatile

SH-VMS − − − − − − − 34
organic pollutants

SH-Volatil Amin Ideal for analysis of volatile amines − CP-Volamine − − − − − 35

SH-PCB Dedicated to PCBs analysis − − − − − − − 35

Ideal for analysis of volatile organic

SH-VRX − − − − − − − 35
pollutants

5
 Similar Phases
Shimadzu Stationary Phase USP Page
Agilent Supelco SGE Phenomenex Quadrex Alltech

AT-
SH-FAME Ideal for analysis of FAMEs G16 Select FAME Omegawax − − − AquaWax, 36
AT-FAME

SH-BAC Plus 1/ Ideal for analysis of alcohol DB-ALC1 / ZB-BAC-1 /

− − − − − 37
SH-BAC Plus 2 compounds in blood DB-ALC2 ZB-BAC-2

SH-5 Amine/
Ideal for analysis of amines − − − − − − − 38
SH-35 Amine

HP-FFAP, AT-
DB-FFAP, AquaWax-
SH-PolarD Ideal for analysis of free acid G25, G35 VF-DA, Nukol BP-21 ZB-FFAP − DA, 39
CP-Wax 58 CB, AT-1000,
CP-FFAP CB EC-1000

CAM, Carbowax
SH-PolarX Ideal for analysis of amines − − − − AT-CAM 40
CP-Wax 51 for Amines Amine

Ideal for analyses of food, flavor,

SH-PolarWAX
fragrance, industrial chemical and − − − − − − AT-WAXms 41
MS
solvent

PLOT Columns

SH-Alumina Aluminum oxide with Na2SO4 GS-ALUMINA, Alumina

− − − − AT-Alumina 42
BOND/Na2SO4 deactivation CP-Al2O3/Na2SO4 sulfate PLOT

GS-Alumina KCl,
SH-Alumina Aluminum oxide with KCl Alumina
− HP-PLOT Al2O3 KCl, − − − − 42
BOND/KCl deactivation chloride PLOT
CP-Al2O3/KCl

HP-PLOT Molesieve, Mol Sieve 5A

SH-Msieve 5A Molecular Sieve 5A − − − PLT-5A AT-Mole Sieve 43
CP-Molsieve 5A PLOT

HP-PLOT Q,
100% divinylbenzene porous
SH-Q-BOND − CP-PoraPLOT Q, Supel-Q PLOT − − − AT-Q 44
polymer
CP-PoraBOND Q

HP-PLOT U,
Divinylbenzene ethylene glycol /
SH-U-BOND − CP-PoraPLOT U, − − − − − 44
dimethylacrylate porous polymer
CP-PoraBOND U

Metal Columns

HP-1,
G1, G2, AT-1,
SH-MetalX-1 100% dimethyl polysiloxane DB-1, SPB-1 BP-1 ZB-1 007-1 45
G38 EC-1
CP-Sil 5 CB

SH-MetalX-1HT CP-SimDist UltiMetal,

100% dimethyl polysiloxane − − − ZB-1X SimDist − − 45
SimDist DB-HT SimDis ProSteel

HP-5,
5% diphenyl / 95% dimethyl EC-5,
SH-MetalX-5 G27, G36 DB-5, SPB-5 BP-5 ZB-5 007-5 45
polysiloxane AT-5
CP-Sil 8 CB

DB-1701P,
DB-1701,
ZB-1701,
SH-MetalX-1701 non-disclosure G46 CP-Sil 19 CB, Equity-1701 BP-10 007-1701 AT-1701 46
ZB-1701P
VF-1701ms,
VF-1701 Pesticides

HP-INNOWax,
G16, G20,
SH-MetalX-WAX polyethylene glycol CP-Wax 52 CB, Supelcowax-10 − ZB-WAXplus − AT-WAX 46
G39
VF-WAX MS

SH-MetalX
non-disclosure − − MET-Biodiesel − − − − 46
Biodiesel TG

6
Capillary Columns
High-Performance Columns

SH-I-1MS

• Non-polar phase: Crossbond™ 100% dimethyl polysiloxane ■ SH-I-1MS Structure

• Tested and guaranteed for ultra-low bleed; improved signal-to-noise ratio for better
CH 3
sensitivity and mass spectral integrity.
• General-purpose columns for arson accelerants, essential oils, hydrocarbons, pesticides,
Si O
PCB congeners (e.g., Aroclor mixes), sulfur compounds, amines, solvent impurities,
simulated distillation, oxygenates, gasoline range organics (GRO), refinery gases. CH 3
• Equivalent to USP G2 phase.
100%
• Similar phases: HP-1ms UI, HP-1ms, DB-1ms UI, DB-1ms, Ultra-1, VF-1ms, SPB-1, Equity-1

ID df Temp. Range 20 m 25 m 50 m
0.15 µm -60 to 330/350 °C 227-36001-01 − −
0.15 mm
2.00 µm -60 to 330/350 °C 227-36002-01 − −
0.18 µm -60 to 330/350 °C 221-75921-20 − −
0.18 mm
0.36 µm -60 to 330/350 °C 227-36003-01 − −
0.20 mm 0.33 µm -60 to 330/350 °C − 227-36004-01 227-36004-02
ID df Temp. Range 15 m 30 m 60 m
0.25 µm -60 to 330/350 °C 227-36005-01 221-75923-30 227-36005-02
0.25 mm 0.50 µm -60 to 330/350 °C 227-36006-01 227-36006-02 221-75924-60
1.00 µm -60 to 330/350 °C 227-36007-01 227-36007-02 227-36007-03
0.25 µm -60 to 330/350 °C 227-36008-01 221-75926-30 227-36008-02
0.50 µm -60 to 330/350 °C 227-36009-01 227-36009-02 227-36009-03
0.32 mm
1.00 µm -60 to 330/350 °C − 227-36010-01 221-75928-60
4.00 µm -60 to 330/350 °C − 227-36011-01 −
0.50 µm -60 to 330/350 °C 227-36012-01 227-36012-02 −
0.53 mm 1.00 µm -60 to 330/350 °C 227-36013-01 227-36013-02 −
1.50 µm -60 to 330/350 °C 227-36014-01 227-36014-02 227-36014-03

Petroleum Hydrocarbons (TPH)

Peaks
1. C8 Conditions
2. C10 Instrument: GC-2010
3. C12 Column: SH-I-1MS, 20 m,
4. C14 0.18 mm ID, 0.18 μm
5. C16 (P/N: 221-75921-20)
6. C18 Sample: Florida TRPH
7. C20 Standard, 500 μg/mL
8. C22 each component in
9. C24 hexane
10. C26 Inj. Vol.: 0.5 μL, split (split ratio
11. C28 20:1)
12. C30 Inj. Temp: 275 °C
13. C32 Carrier Gas: Hydrogen, constant
14. C34 linear velocity mode,
15. C36 55 cm/sec.
16. C38 Oven Temp: 40 °C (hold 1 min) to
17. C40 330 °C at 20 °C/min
(hold 10 min)
Detector: FID, 350 °C

7
 Capillary Columns
High-Performance Columns

SH-I-5MS

• Low-polarity phase: Crossbond™ 5% diphenyl / 95% dimethyl polysiloxane ■ SH-I-5MS Structure

• Tested and guaranteed for ultra-low bleed; improved signal-to-noise ratio for
CH 3
better sensitivity and mass spectral integrity.
• General-purpose columns for semi-volatiles, phenols, amines, residual solvents,
Si O Si O
drugs of abuse, pesticides, PCB congeners (e.g., Aroclor mixes), solvent impurities.
• Equivalent to USP G27 and G36 phases. CH 3
• Similar phases: HP-5ms UI, HP-5ms, DB-5, Ultra-2, CP Sil 8 CB, SPB-5, Equity-5
5% 95%

ID df Temp. Range 10 m 15 m 20 m 25 m 30 m 50 m 60 m
0.10 mm 0.10 µm -60 to 330/350 °C 227-36342-01 − − − − − −
0.18 µm -60 to 330/350 °C − − 227-36015-01 − − − −
0.18 mm 0.30 µm -60 to 330/350 °C − − 227-36016-01 − − − −
0.36 µm -60 to 330/350 °C − − 227-36017-01 − − − −
0.20 mm 0.33 µm -60 to 330/350 °C − − − 227-36018-01 − 227-36018-02
0.25 µm -60 to 330/350 °C − 221-75940-15 − − 221-75940-30 − 227-36019-01
0.40 µm -60 to 330/350 °C − − − − 227-36020-01 − −
0.25 mm
0.50 µm -60 to 330/350 °C − 227-36021-01 − − 221-75941-30 − 221-75942-60
1.00 µm -60 to 330/350 °C − 227-36022-01 − − 227-36022-02 − 227-36022-03
0.25 µm -60 to 330/350 °C − 227-36023-01 − − 221-75943-30 − 227-36023-02
0.32 mm 0.50 µm -60 to 330/350 °C − 227-36024-01 − − 221-75944-30 − 227-36024-02
1.00 µm -60 to 330/350 °C − 227-36025-01 − − 227-36025-02 − 227-36025-03
0.25 µm -60 to 330/350 °C − 227-36026-01 − − 227-36026-02 − −
0.50 µm -60 to 330/350 °C − 227-36027-01 − − 227-36027-02 − −
0.53 mm
1.00 µm -60 to 330/350 °C − 227-36028-01 − − 227-36028-02 − −
1.50 µm -60 to 330/350 °C − 227-36029-01 − − 227-36029-02 − −

GC Multiresidue Pesticide
Peaks
1. Chloroneb 21. cis-Chlordane
2. Pentachlorobenzene 22. trans-Nonachlor
3. alpha-BHC 23. Chlorfenson (Ovex)
4. Hexachlorobenzene 24. 4,4'-DDE
5. Pentachloroanisole 25. Dieldrin
6. beta-BHC 26. 2,4'-DDD
7. gamma-BHC (Lindane) 27. Endrin
8. delta-BHC 28. Ethylan (Perthane)
9. Endosulfan ether 29. Endosulfan II
10. Heptachlor 30. 4,4'-DDD
11. Pentachlorothioanisole 31. 2,4'-DDT
12. Aldrin 32. cis-Nonachlor
13. 4,4'-Dichlorobenzophenone 33. Endrin aldehyde
14. Fenson 34. 4,4'-Methoxychlor olefin
15. Isodrin 35. Endosulfan sulfate
16. Heptachlor epoxide (Isomer B) 36. 4,4'-DDT
17. Chlorbenside 37. 2,4'-Methoxychlor
18. trans-Chlordane 38. Endrin ketone
19. 2,4'-DDE 39. Tetradifon
20. Endosulfan I 40. Mirex

Conditions
Column: SH-I-5MS, 30 m, 0.25 mm ID, 0.25 μm
(P/N: 221-75940-30)
Inj. Vol.: 1 μL split (split ratio 50:1)
Inj. Temp: 250 °C
Oven Temp: 90 °C (hold 1 min) to 330 °C at
8.5 °C/min (hold 5 min)
Carrier Gas: He, constant flow rate 1.4 mL/min
Detector: MS-QP
Transfer Line Temp: 290 °C
Source Temp: 325 °C
Solvent Delay Time: 5 min
Ionization: EI

8
SH-I-1HT

• Non-polar phase: Crossbond™ 100% dimethyl polysiloxane ■ SH-I-1HT Structure

• 40% longer lifetime from specially designed fused silica tubing.
CH 3
• Columns processed for high-temperature applications, such as high molecular
weight hydrocarbons.
Si O
• Similar phases: DB-1HT, AT-1ht
CH 3
100%

ID df Temp. Range 15 m 30 m
0.10 µm -60 to 400 °C 227-36087-01 227-36087-02
0.25 mm
0.25 µm -60 to 400 °C − 227-36088-01
0.10 µm -60 to 400 °C 227-36089-01 227-36089-02
0.32 mm
0.25 µm -60 to 400 °C − 227-36090-01

SH-I-5HT

• Low-polarity phase: Crossbond™ 5% diphenyl / 95% dimethyl polysiloxane ■ SH-I-5HT Structure

• 40% longer lifetime from specially designed fused silica tubing.
CH 3
• Columns processed for high-temperature applications, such as mineral oil.
• Similar phases: DB-5HT, VF-5HT
Si O Si O

CH 3
5% 95%

ID df Temp. Range 15 m 30 m
0.10 µm -60 to 400 °C 221-75933-15 227-36091-01
0.25 mm
0.25 µm -60 to 400 °C 227-36092-01 221-75934-30
0.10 µm -60 to 400 °C 227-36093-01 227-36093-02
0.32 mm
0.25 µm -60 to 400 °C − 227-36094-01
0.53 mm 0.15 µm -60 to 380/400 °C − 227-36095-01

9
 Capillary Columns
High-Performance Columns

SH-I-5Sil MS

• Low-polarity phase: Crossbond ™ silarylene phase 1,4-bis(dimethylsiloxy) ■ SH-I-5Sil MS Structure

phenylene dimethyl polysiloxane
• Engineered to be a low-bleed GCMS column. CH 3 CH 3 CH 3
• Excellent inertness for active compounds.
• General-purpose columns—ideal for GCMS analysis of semi-volatiles, Si Si O Si O
polycyclic aromatic compounds, chlorinated hydrocarbons, phthalates,
phenols, amines, organochlorine pesticides, organophosphorus pesticides, CH 3 CH 3 CH 3
drugs, solvent impurities, and hydrocarbons. x y
• Similar phases: DB-5ms UI, DB-5ms, VF-5ms, SLB-5ms

For SH-I-5Sil MS columns with Integrated Guard column, please refer to page 49.
ID df Temp. Range 10 m 15 m 20 m 30 m 40 m 60 m
0.10 mm 0.10 µm -60 to 320/350 °C 227-36317-01 − − − − −
0.15 µm -60 to 320/350 °C − − 227-36030-01 − − −
0.15 mm
2.00 µm -60 to 320/350 °C − − 227-36031-01 − − −
0.10 µm -60 to 320/350 °C − − − − − 227-36032-01
0.18 mm 0.18 µm -60 to 320/350 °C − − 227-36033-01 − 227-36033-02 −
0.36 µm -60 to 320/350 °C − − 227-36034-01 − − −
0.10 µm -60 to 320/350 °C − 227-36035-01 − 227-36035-02 − −
0.25 µm -60 to 320/350 °C − 227-36036-01 − 221-75954-30 − 227-36036-02
0.25 mm
0.50 µm -60 to 320/350 °C − 227-36037-01 − 227-36037-02 − −
1.00 µm -60 to 320/350 °C − 227-36038-01 − 221-75956-30 − 227-36038-02
0.25 µm -60 to 320/350 °C − 227-36039-01 − 227-36039-02 − −
0.32 mm 0.50 µm -60 to 320/350 °C − − − 227-36040-01 − −
1.00 µm -60 to 320/350 °C − − − 227-36041-01 − −
0.53 mm 1.50 µm -60 to 320/350 °C − − − 227-36032-02 − −

Benzodiazepines
Peaks Conditions
1. Oxazepam Instrument: GCMS-QP2010
2. Lorazepam Column: SH-I-5Sil MS, 30 m, 0.25 mm ID,
3. Diazepam 0.25 μm (P/N: 221-75954-30)
4. Flunitrazepam Sample: Diluent: Butyl chloride
5. Prazepam Conc.: 15 μg/mL
6. Clonazepam Inj. Vol.: 1 μL splitless (hold 1 min)
7. Alprazolam Inj. Temp: 280 °C
Purge Flow: 32.2 mL/min (20:1 split)
Oven Temp: 200 °C to 330 °C at 15 °C/min
(hold 3 min)
Carrier Gas: He, constant linear velocity mode,
50 cm/sec.
Detector: MS-QP
Transfer Line Temp: 280 °C
Source Temp: 200 °C
Solvent Delay Time: 4 min
Tune: PFTBA
Ionization: EI
Scan Range: 50-350

10
SH-I-XLB

• Low-polarity proprietary phase

• General-purpose columns exhibiting extremely low bleed. Ideal for many GCMS applications, including pesticides,
PCB congeners (e.g., Aroclor mixes), PAHs.
• Unique selectivity.
• Similar phases: DB-XLB, VF-Xms

ID df Temp. Range 20 m 30 m 60 m
0.18 mm 0.18 µm 30 to 340/360 °C 227-36309-01 − −
0.10 µm 30 to 340/360 °C − 227-36042-01 −
0.25 µm 30 to 340/360 °C − 227-36043-01 227-36043-02
0.25 mm
0.50 µm 30 to 340/360 °C − 227-36044-01 −
1.00 µm 30 to 340/360 °C − 227-36045-01 −
0.25 µm 30 to 340/360 °C − 227-36046-01 227-36046-02
0.32 mm 0.50 µm 30 to 340/360 °C − 227-36047-01 −
1.00 µm 30 to 340/360 °C − 227-36048-01 −
0.50 µm 30 to 320/360 °C − 227-36049-01 −
0.53 mm
1.50 µm 30 to 320/360 °C − 227-36050-01 −
* Maximum temperatures listed are for shorter length columns. Longer columns may have a different maximum temperature.

EU PCB Congeners

Peaks
1. PCB 31
2. PCB 28
3. PCB 52
4. PCB 101
5. PCB 118
6. PCB 153
7. PCB 138
8. PCB 180
9. PCB 194

Conditions
Column: SH-I-XLB, 30 m, 0.25 mm ID, 0.25 μm Oven Temp: 40 °C (hold 2 min) to 240 °C at 30 °C/min
(P/N: 227-36043-01) (hold 2 min) to 340 °C at 10 °C/min (hold 5 min)
Sample: PCB congener standard Carrier Gas: He, constant flow rate 1 mL/min
Diluent: Dichloromethane Detector: MS-QP
Conc.: 3.5 ppm Transfer Line Temp: 300 °C
Inj. Vol.: 0.5 μL splitless (hold 1.75 min) Source Temp: 280 °C
Inj. Temp: 300 °C Ionization: EI
Purge Flow: 50 mL/min Scan Range: 45-550

11
 Capillary Columns
High-Performance Columns

SH-I-17

• Mid-polarity phase: Crossbond™ 50% diphenyl / 50% dimethyl polysiloxane ■ SH-I-17 Structure
• General-purpose columns for pesticides, herbicides, rosin acids, phthalate
CH 3
esters, triglycerides, sterols.
• Similar phases: HP-17, DB-17, DB-17HT, DB-608, SPB-17
Si O Si O

CH 3
50% 50%

ID df Temp. Range 20 m 30 m
0.18 mm 0.18 µm 40 to 280/320 °C 227-36061-01 −
0.25 µm 40 to 280/320 °C − 221-75907-30
0.25 mm 0.50 µm 40 to 280/320 °C − 227-36062-01
1.00 µm 40 to 280/320 °C − 227-36063-01
0.25 µm 40 to 280/320 °C − 227-36064-01
0.32 mm 0.50 µm 40 to 280/320 °C − 227-36065-01
1.00 µm 40 to 280/320 °C − 227-36066-01
0.25 µm 40 to 280/320 °C − 227-36067-01
0.50 µm 40 to 280/320 °C − 227-36068-01
0.53 mm 0.83 µm 40 to 280/320 °C − 227-36069-01
1.00 µm 40 to 280/320 °C − 221-76193-30
1.50 µm 40 to 280/320 °C − 227-36070-01

SH-I-35Sil MS

• Mid-polarity: Crossbond™ phase (similar to 35% phenyl methyl polysiloxane) ■ SH-I-35Sil MS Structure
• Very low-bleed phase for GCMS analysis.
CH 3 CH 3 CH 3
• Special selectivity and excellent inertness for substituted polar compounds,
such as drugs, pesticides, herbicides, PCBs, phenols, etc. Si O Si R Si O Si O

• Provides superior separation for cannabinoids.

CH 3 CH 3 CH 3
• Similar phases: DB-35ms, DB-35ms UI, VF-35ms x y z

ID df Temp. Range 15 m 30 m
0.25 µm 50 to 340/360 °C 227-36051-01 227-36051-02
0.25 mm 0.50 µm 50 to 340/360 °C 227-36052-01 227-36052-02
1.00 µm 50 to 340/360 °C 227-36053-01 227-36053-02
0.25 µm 50 to 340/360 °C 227-36054-01 227-36054-02
0.32 mm 0.50 µm 50 to 340/360 °C 227-36055-01 227-36055-02
1.00 µm 50 to 340/360 °C 227-36056-01 227-36056-02
0.50 µm 50 to 340/360 °C 227-36057-01 227-36057-02
1.00 µm 50 to 320/340 °C 227-36058-01 227-36058-02
0.53 mm
1.50 µm 50 to 310/330 °C 227-36059-01 227-36059-02
3.00 µm 50 to 280/300 °C 227-36060-01 227-36060-02

12
SH-I-17Sil MS

• Mid-polarity Crossbond™ phase (similar to 50% phenyl methyl polysiloxane) ■ SH-I-17Sil MS Structure
• Low bleed for use with sensitive detectors, such as MS.
CH 3 CH 3 CH 3
• Excellent inertness and selectivity for active environmental compounds,
such as PAHs. Si O Si R Si O Si O

• Equivalent to USP G3 phase.

CH 3 CH 3 CH 3
• Similar phases: DB-17ms, HP-17, DB-17, VF-17ms, CP-Sil 24 CB x y z

ID df Temp. Range 30 m 60 m
0.25 mm 0.25 µm 40 to 340/360 °C 221-75916-30 227-36071-01
0.32 mm 0.25 µm 40 to 340/360 °C 227-36072-01 −
* Maximum temperatures listed are for shorter length columns. Longer columns may have a different maximum temperature.

Polycyclic Aromatic Hydrocarbons (US EPA Method 8100)

Peaks
1. Naphthalene
2. 2-Methylnaphthalene
3. 1-Methylnaphthalene
4. Acenaphthylene
5. Acenaphthene
6. Fluorene
7. Phenanthrene
8. Anthracene
9. Fluoranthene
10. Pyrene
11. Benz[a]anthracene
12. Chrysene
13. Triphenylene
14. Benzo[b]fluoranthene
15. Benzo[k]fluoranthene
16. Benzo(j)fluoranthene
17. Benzo[a]pyrene
18. 3-Methylcholanthrene
19. Dibenz(a,h)acridine
20. Dibenz[a,j]acridine
21. Indeno[1,2,3-cd]pyrene
22. Dibenz[a,h]anthracene
23. Benzo[ghi]perylene
24. 7H-Dibenzo[c,g]carbazole
25. Dibenzo[a,e]pyrene
26. Dibenzo(a,i)pyrene
27. Dibenzo(a,h)pyrene

Conditions
Column: SH-I-17Sil MS, 30 m, 0.25 mm ID, 0.25 μm Oven Temp: 65 °C (hold 0.5 min) to 220 °C at 15 °C/min to 330 °C
(P/N: 221-75916-30) at 4 °C/min (hold 15 min)
Inj. Vol.: 0.5 μL splitless (hold 1.75 min) Carrier Gas: He, constant flow rate 2.0 mL/min
Inj. Temp: 320 °C Detector: FID, 320 °C
Purge Flow: 75 mL/min

SH-I-PAH

• Mid-polarity proprietary phase

• Ideal for EFSA PAH4 analysis—separates all priority compounds: benz[a]anthracene, chrysene, benzo[b]
fluoranthene and benzo[a]pyrene.
• Best resolution of chrysene from interfering PAHs, triphenylene, and cyclopenta[cd]pyrene.
• Complete separation of benzo [b], [k], [j], and [a] fluoranthenes.

ID df Temp. Range 30 m 40 m 60 m
0.18 mm 0.07 µm to 350/360 °C − 227-36073-01 −
0.25 mm 0.10 µm to 350/360 °C 227-36074-01 − 227-36074-02

13
 Capillary Columns
High-Performance Columns

SH-I-624Sil MS

• Mid-polarity Crossbond™ silarylene phase (similar to 6% cyanopropylphenyl ■ SH-I-624Sil MS Structure

/ 94% dimethyl polysiloxane)
• Low-bleed, high-thermal stability column—maximum temperatures up to
300–320 °C.
• Inert—excellent peak shape for a wide range of compounds.
• Selective—G43 phase highly selective for volatile organics and residual
solvents, great choice for USP<467>.
• Manufactured for column-to-column reproducibility—well-suited for
validated methods.
• Similar phases: HP-624, DB-624, VF-624ms, CP-Select 624 CB

ID df Temp. Range 20 m 30 m 60 m 75 m 105 m

0.18 mm 1.00 µm -20 to 300/320 °C 227-36075-01 − − − −
0.25 mm 1.40 µm -20 to 300/320 °C − 221-75962-30 227-36076-01 − −
0.32 mm 1.80 µm -20 to 300/320 °C − 227-36077-01 221-75963-60 − −
0.53 mm 3.00 µm -20 to 280/300 °C − 227-36078-01 227-36078-02 227-36078-03 227-36078-04

Ultra-Fast Analysis of Volatile Organic Compounds in

Water
Peaks
1. Vinyl chloride-d3 (ISTD) 9. 1,1,1-trichloroethane 17. 1,4-dioxane 25. m-,p-xylene
2. Vinyl chloride 10. Carbon tetrachloride 18. Bromodichloromethane 26. o-xylene
3. 1,1-dichloroethylene 11. 1,2-dichloroethane 19. Cis-1,3-dichloropropene 27. Bromoform
4. Dichloromethane 12. Benzene 20. Toluene 28. 4-bromofluorobenzene
5. Methyl-t-butyl ether (MTBE) 13. Fluorobenzene (ISTD) 21. Trans-1,3-dichloropropene 29. 1,4-dichlorobenzene
6. Trans-1,2-dichloroethylene 14. Trichloroethylene 22. 1,1,2-trichloroethane
7. Cis-1,2-dichloroethylene 15. 1,4-dioxane-d8 (ISTD) 23. Tetrachloroethylene
8. Trichloromethane 16. 1,2-dichloropropane 24. Dibromochloromethane

Conditions
Instrument: GCMS-TQ8030 + HS-20 Loop Inj.: Split (split ratio 30:1)
Column: SH-I-624Sil MS, 20 m, 0.18 mm ID, Oven Temp: 70 °C, 40 °C/min to 220 °C (hold 0.5 min)
1.00 μm (P/N: 227-36075-01) Carrier Gas: He, constant linear velocity mode, 50 cm/sec
Headspace-Loop: Loop volume: 1 mL Detector: MS: SIM
Sample Equilibration: 70 °C for 30 min MS/MS: MRM
Vial pressurization: 0.5 min, 50 kPa, Event (loop) time: 0.15 sec
equilibration 0.05 min Source Temp: 200 °C
Needle Flush: 2 min Interface Temp: 230 °C
Sample Pathway Temp: 200 °C
Transfer Line Temp: 200 °C

14
SH-I-1301Sil MS

• Mid-polarity Crossbond™ silarylene phase (similar to 6% cyanopropylphenyl ■ SH-I-1301Sil MS Structure

/ 94% dimethyl polysiloxane) CN
• Highest thermal stability in the industry ensures dependable, accurate MS (CH 2 ) 3 CH 3 CH 3 CH 3
results and increased uptime.
Si O Si Si O Si O
• Stabilized cyano phase selectivity improves the performance of existing
CH3 CH 3 CH 3 CH 3
methods. Ideal for solvents, glycols, and other polar compounds. x y z
• Rigorous QC testing ensures inertness and accurate, reliable data for
multiple compound classes.
• Similar phase: VF-1301ms

ID df Temp. Range 15 m 30 m 60 m
0.25 µm -60 to 320 °C − 227-36079-01 227-36079-02
0.25 mm
1.00 µm -60 to 320 °C − 227-36080-01 227-36080-02
0.25 µm -60 to 320 °C − 227-36081-01 −
0.32 mm 1.00 µm -60 to 320 °C − 227-36082-01 227-36082-02
1.50 µm -60 to 320 °C − 227-36083-01 227-36083-02
1.00 µm -60 to 320 °C 227-36084-01 227-36084-02 −
0.53 mm 1.50 µm -60 to 320 °C − 227-36085-01 −
3.00 µm -60 to 280/320 °C − 227-36086-01 227-36086-02

Guard columns for SH-I are also available. Please refer to page 47.

15
 Capillary Columns
General-Purpose Columns

SH-1

• Non-polar phase: Crossbond™ 100% dimethyl polysiloxane ■ SH-1 Structure

• General-purpose columns for solvent impurities, PCB congeners (e.g., Aroclor mixes),
CH 3
simulated distillation, arson accelerants, gases, natural gas odorants, sulfur compounds,
essential oils, hydrocarbons, semi-volatiles, pesticides, oxygenates.
Si O
• Equivalent to USP G1, G2, G38 phases.
• Similar phases: HP-1, DB-1, CP Sil 5 CB, SPB-1 CH 3
100%

For SH-1 columns with Integrated Guard column, please refer to page 49.
ID df Temp. Range 10 m 15 m 20 m 25 m 30 m 60 m 105 m
0.10 mm 0.40 µm -60 to 330/350 °C − − 227-36330-01 − − − −
0.10 µm -60 to 330/350 °C − 221-75718-15 − − 221-75718-30 227-36096-01 −
0.25 µm -60 to 330/350 °C 221-75719-10 − − 221-75719-25 221-75719-30 221-75719-60 −
0.25 mm
0.50 µm -60 to 330/350 °C − − − − 227-36097-01 227-36097-02 −
1.00 µm -60 to 320/340 °C − − − − 227-36098-01 227-36098-02 221-75721-05
0.10 µm -60 to 330/350 °C − − − − 227-36099-01 227-36099-02 −
0.25 µm -60 to 330/350 °C − − − − 221-75723-30 221-75723-60 −
0.50 µm -60 to 330/350 °C − − − − 221-75724-30 227-36100-01 −
1.00 µm -60 to 320/340 °C − − − − 221-75725-30 221-75725-60 −
0.32 mm
1.50 µm -60 to 310/330 °C − − − − 227-36101-01 227-36101-02 −
3.00 µm -60 to 280/300 °C − − − − 227-36102-01 227-36102-02 −
4.00 µm -60 to 280/300 °C − − − − 227-36103-01 − −
5.00 µm -60 to 260/280 °C − − − − 221-75728-30 221-75728-60 −
0.10 µm -60 to 320/340 °C − − − − 227-36104-01 − −
0.25 µm -60 to 320/340 °C − − − − 221-75729-30 227-36105-01 −
0.50 µm -60 to 310/330 °C − 221-75730-15 − − 221-75730-30 227-36106-01 −
1.00 µm -60 to 310/330 °C − 221-75731-15 − − 221-75731-30 221-75731-60 −
0.53 mm
1.50 µm -60 to 310/330 °C − 221-75732-15 − − 221-75732-30 227-36107-01 −
3.00 µm -60 to 270/290 °C − − − − 221-75733-30 221-75733-60 −
5.00 µm -60 to 270/290 °C − − − − 221-75734-30 221-75734-60 −
7.00 µm -60 to 240/260 °C − − − − 227-36108-01 227-36108-02 −
* Maximum temperatures listed are for shorter length columns. Longer columns may have a different maximum temperature.

SH-1 PONA

Compatible with ASTM and CGSB for hydrocarbon analysis.

ID df Temp. Range 100 m

0.25 mm 0.50 µm -60 to 300/340 °C 221-76196-00

16
SH-5

• Low-polarity phase: Crossbond™ 5% diphenyl / 95% dimethyl polysiloxane ■ SH-5 Structure

• General-purpose columns for drugs, solvent impurities, pesticides,
CH 3
hydrocarbons, PCB congeners (e.g., Aroclor mixes), essential oils, semi-volatiles.
• Equivalent to USP G27 and G36 phases.
Si O Si O
• Similar phases: HP-5, DB-5, CP Sil 8 CB, SPB-5
CH 3
5% 95%
For SH-5 columns with Integrated Guard column, please refer to page 49.
ID df Temp. Range 15 m 25 m 30 m 60 m
0.10 µm -60 to 330/350 °C 221-75700-15 − 221-75700-30 227-36109-01
0.25 µm -60 to 330/350 °C 227-36313-01 − 221-75701-30 227-36110-01
0.25 mm
0.50 µm -60 to 330/350 °C − 221-76178-25 221-76178-30 227-36111-01
1.00 µm -60 to 320/340 °C − − 221-75702-30 227-36112-01
0.10 µm -60 to 330/350 °C 227-36312-01 − 227-36113-01 −
0.25 µm -60 to 330/350 °C 221-75703-15 − 221-75703-30 221-75703-60
0.50 µm -60 to 330/350 °C − − 221-75704-30 227-36114-01
0.32 mm
1.00 µm -60 to 320/350 °C − − 221-75705-30 221-75705-60
1.50 µm -60 to 310/330 °C − − 221-76181-30 227-36115-01
3.00 µm -60 to 280/300 °C − − 227-36116-01 227-36116-02
0.10 µm -60 to 320/340 °C − − 227-36117-01 −
0.25 µm -60 to 320/340 °C 227-36314-01 − 221-75708-30 227-36118-01
0.50 µm -60 to 320/330 °C − − 221-75709-30 227-36119-01
0.53 mm 1.00 µm -60 to 320/330 °C 221-75710-15 − 221-75710-30 221-75710-60
1.50 µm -60 to 310/330 °C 221-75711-15 − 221-75711-30 227-36120-01
3.00 µm -60 to 270/290 °C − − 221-75712-30 227-36121-01
5.00 µm -60 to 270/290 °C − − 221-75713-30 221-75713-60
* Maximum temperatures listed are for shorter length columns. Longer columns may have a different maximum temperature.

Metal columns are also available. Please refer to page 45.

17
 Capillary Columns
General-Purpose Columns

SH-5MS

• Low-polarity phase: Crossbond™ 5% diphenyl / 95% dimethyl polysiloxane ■ SH-5MS Structure

• Column specifically tested for low-bleed performance.
CH 3
• General-purpose columns for drugs, solvent impurities, pesticides,
hydrocarbons, PCB congeners (e.g., Aroclor mixes), essential oils, semi-volatiles.
Si O Si O
• Equivalent to USP G27 and G36 phases.
• Similar phases: HP-5, DB-5, CP Sil 8 CB, SPB-5 CH 3
5% 95%

For SH-5MS columns with Integrated Guard column, please refer to page 49.
ID df Temp. Range 15 m 30 m 60 m
0.10 µm -60 to 330/350 °C 221-75854-15 221-75854-30 227-36122-01
0.25 µm -60 to 330/350 °C 221-75855-15 221-75855-30 227-36123-01
0.25 mm
0.50 µm -60 to 330/350 °C − 227-36124-01 227-36124-02
1.00 µm -60 to 325/350 °C − 221-75857-30 −
0.10 µm -60 to 330/350 °C − 227-36125-01 227-36125-02
0.25 µm -60 to 330/350 °C − 221-75858-30 221-75858-60
0.32 mm
0.50 µm -60 to 330/350 °C − 227-36126-01 227-36126-02
1.00 µm -60 to 325/350 °C − 227-36127-01 −
0.50 µm -60 to 320/340 °C − 221-76191-30 −
0.53 mm 1.00 µm -60 to 320/340 °C − 227-36128-01 −
1.50 µm -60 to 310/330 °C − 227-36129-01 −
* Maximum temperatures listed are for shorter length columns. Longer columns may have a different maximum temperature.

Endocrine Disruptors: Alkyl Phenols

Peaks
1. tert-butyl phenol
2. n-pentyl phenol
3. n-hexyl phenol
4. n-heptyl phenol
5. tert-octyl phenol
6. n-octyl phenol
7. n-nonyl phenol
8. bisphenol A

Conditions
Column: SH-5MS, 30 m, 0.25 mm ID, 0.25 μm (P/N: 221-75855-30).
Conc.: 5–10 ng on-column
Inj.: Splitless, purge on at 1 min
Inj. Temp.: 275 °C
Oven Temp: 35 °C (hold 1 min) to 300 °C at 10 °C/min (hold 15 min)
Carrier Gas: He
Det. Temp: 310 °C

18
SH-20

• Mid-polarity phase: Crossbond™ 20% diphenyl / 80% dimethyl polysiloxane ■ SH-20 Structure
• General-purpose columns for volatile compounds, flavor compounds, alcoholic
CH 3
beverages.
• Equivalent to USP G28 and G32 phases.
Si O Si O
• Similar phases: SPB-20, 007-20, AT-20, EC-20
CH 3
20% 80%

ID df Temp. Range 30 m 60 m
0.10 µm -20 to 300/320 °C 227-36130-01 227-36130-02
0.25 µm -20 to 300/320 °C 227-36131-01 227-36131-02
0.25 mm
0.50 µm -20 to 290/310 °C 227-36132-01 227-36132-02
1.00 µm -20 to 280/300 °C 227-36133-01 227-36133-02
0.10 µm -20 to 300/320 °C 227-36134-01 227-36134-02
0.25 µm -20 to 300/320 °C 227-36135-01 227-36135-02
0.50 µm -20 to 290/310 °C 227-36136-01 227-36136-02
0.32 mm
1.00 µm -20 to 280/300 °C 227-36137-01 227-36137-02
1.50 µm -20 to 270/290 °C 227-36138-01 227-36138-02
3.00 µm -20 to 250/270 °C 227-36139-01 227-36139-02
0.10 µm -20 to 260/280 °C 227-36140-01 227-36140-02
0.25 µm -20 to 260/280 °C − 227-36141-01
0.50 µm -20 to 260/280 °C 227-36142-01 −
0.53 mm
1.00 µm -20 to 260/280 °C 227-36143-01 227-36143-02
1.50 µm -20 to 250/270 °C 227-36144-01 −
3.00 µm -20 to 240/260 °C 227-36145-01 227-36145-02

Tocopherols and Tocotrienols

Peaks Conditions
1. δ-tocopherol Column: SH-20, 30 m, 0.53 mm ID,
2. β-tocopherol 0.50 μm (P/N: 227-36142-01)
3. γ-tocopherol Sample: 1 mg/mL each component in
4. dl-δ-tocotrienol isooctane
5. α-tocopherol Inj. Vol.: 1 μL split (split ratio 20:1)
6. dl-β-tocotrienol Inj. Temp: 320 °C
7. dl-γ-tocotrienol Carrier Gas: Hydrogen, constant flow rate
8. hexadecyl hexadecanoate 5.2 mL/min
9. dl-α-tocotrienol Oven Temp: 270 °C to 290 °C at 2 °C/min
290 °C to 320 °C at 10 °C/min
(hold 1 min)
Detector: FID, 320 °C

19
 Capillary Columns
General-Purpose Columns

SH-35 / SH-35MS

• Mid-polarity phase: Crossbond™ 35% diphenyl / 65% dimethyl polysiloxane ■ SH-35 / SH-35MS Structure
• General-purpose columns for organochlorine pesticides, PCB congeners (e.g.,
CH 3
Aroclor mixes), herbicides, pharmaceuticals, sterols, rosin acids, phthalate
esters.
Si O Si O
• Equivalent to USP G42 phase.
• Similar phases: HP-35, DB-35, SPB-35, SPB-608 CH 3
35% 65%

SH-35
ID df Temp. Range 30 m 60 m
0.10 µm 40 to 320 °C 227-36146-01 227-36146-02
0.25 µm 40 to 320 °C 227-36147-01 227-36147-02
0.25 mm
0.50 µm 40 to 310 °C 227-36148-01 227-36148-02
1.00 µm 40 to 290 °C 227-36149-01 227-36149-02
0.10 µm 40 to 320 °C 227-36150-01 227-36150-02
0.25 µm 40 to 320 °C 227-36151-01 227-36151-02
0.50 µm 40 to 310 °C 227-36152-01 227-36152-02
0.32 mm
1.00 µm 40 to 290 °C 227-36153-01 227-36153-02
1.50 µm 40 to 270/290 °C 227-36154-01 −
3.00 µm 40 to 250/270 °C 227-36155-01 227-36155-02
0.10 µm 40 to 260/280 °C − 227-36156-01
0.25 µm 40 to 260/280 °C − 227-36157-01
0.50 µm 40 to 300 °C 227-36158-01 227-36158-02
0.53 mm
1.00 µm 40 to 290 °C 227-36159-01 227-36159-02
1.50 µm 40 to 280 °C 227-36160-01 227-36160-02
3.00 µm 40 to 240/260 °C 227-36161-01 227-36161-02

SH-35MS (Low-bleed phase for GCMS analysis)

ID df Temp. Range 30 m

0.25 mm 0.25 µm 40 to 320 °C 221-75835-30

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20
SH-50

• Mid-polarity phase: Crossbond™ 100% methyl phenyl polysiloxane ■ SH-50 Structure

• General-purpose columns for pesticides, herbicides, rosin acids, phthalate
esters, sterols.
• Equivalent to USP G3 phase.
• Similar phases: HP-50+, CP-Sil 24 CB, SPB-50 Si O

CH 3
100%

ID df Temp. Range 30 m 60 m
0.25 µm 40 to 300/320 °C 227-36162-01 227-36162-02
0.25 mm 0.50 µm 40 to 290/310 °C 227-36163-01 227-36163-02
1.00 µm 40 to 280/300 °C 227-36164-01 227-36164-02
0.25 µm 40 to 300/320 °C 221-76182-30 227-36165-01
0.32 mm 0.50 µm 40 to 290/310 °C 227-36166-01 227-36166-02
1.00 µm 40 to 280/300 °C 227-36167-01 227-36167-02
0.50 µm 40 to 270/290 °C 227-36168-01 227-36168-02
0.83 µm 40 to 270/290 °C 227-36169-01 −
0.53 mm
1.00 µm 40 to 260/280 °C 227-36170-01 227-36170-02
1.50 µm 40 to 250/270 °C 227-36171-01 227-36171-02

SH-65

• Mid-polarity phase: Crossbond™ 65% diphenyl / 35% dimethyl polysiloxane ■ SH-65 Structure
• General-purpose columns for phenols, fatty acids, triglycerides.
CH 3
• Equivalent to USP G17 phase.

Si O Si O

CH 3
65% 35%

ID df Temp. Range 30 m
0.25 µm 50 to 300 °C 227-36172-01
0.25 mm 0.50 µm 50 to 280/300 °C 227-36173-01
1.00 µm 50 to 260/280 °C 227-36174-01
0.25 µm 50 to 300 °C 227-36175-01
0.32 mm 0.50 µm 50 to 280/300 °C 227-36176-01
1.00 µm 50 to 260/280 °C 227-36177-01
0.53 mm 1.00 µm 50 to 250/270 °C 227-36178-01

21
 Capillary Columns
General-Purpose Columns

SH-65TG

• Application-specific columns, specially tested for triglycerides. ■ SH-65TG Structure

The SH-65TG phase resolves triglycerides by degree of unsaturation as well as

by carbon number.

ID df Temp. Range 15 m 30 m
0.25 mm 0.10 µm 40 to 370 °C 227-36325-01 227-36325-02

SH-1301

• Mid-polarity phase: Crossbond ™ 6% cyanopropylphenyl / 94% dimethyl ■ SH-1301 Structure

polysiloxane
• General-purpose columns for residual solvents, alcohols, oxygenates, and
volatile organic compounds.
• Equivalent to USP G43 phase.
• Similar phases: DB-1301, CP-1301, SPB-1301

For SH-1301 columns with Integrated Guard column, please refer to page 49.
ID df Temp. Range 30 m 60 m
0.25 µm -20 to 280 °C 221-76194-30 221-76194-60
0.50 µm -20 to 270 °C 227-36203-01 −
0.25 mm
1.00 µm -20 to 260 °C 227-36204-01 227-36204-02
1.40 µm -20 to 240 °C − 227-36205-01
0.25 µm -20 to 280 °C 227-36206-01 227-36206-02
0.50 µm -20 to 270 °C 227-36207-01 227-36207-02
0.32 mm 1.00 µm -20 to 260 °C 227-36208-01 227-36208-02
1.50 µm -20 to 250 °C 227-36209-01 227-36209-02
1.80 µm -20 to 240 °C 227-36210-01 227-36210-02
0.25 µm -20 to 280 °C 227-36211-01 −
0.50 µm -20 to 270 °C 227-36212-01 227-36212-02
0.53 mm 1.00 µm -20 to 260 °C 227-36213-01 227-36213-02
1.50 µm -20 to 250 °C 227-36214-01 −
3.00 µm -20 to 240 °C 221-75776-30 221-75776-60
* Maximum temperatures listed are for shorter length columns. Longer columns may have a different maximum temperature.

22
SH-624

• Mid-polarity phase: Crossbond ™ 6% cyanopropylphenyl / 94% dimethyl ■ SH-624 Structure

polysiloxane
• Application-specific columns for volatile organic pollutants. Recommended in
U.S. EPA methods for volatile organic pollutants.
• Equivalent to USP G43 phase.
• Similar phases: HP-624, DB-624, DB-624 UI, VF-624ms, SPB-1301

For SH-624 columns with Integrated Guard column, please refer to page 49.
ID df Temp. Range 20 m 30 m 60 m 75 m
0.10 mm 0.50 µm -20 to 240 °C 227-36332-01 − − −
0.18 mm 1.00 µm -20 to 240 °C 227-36259-01 − − −
0.25 mm 1.40 µm -20 to 240 °C − 221-75863-30 227-36215-01 −
0.32 mm 1.80 µm -20 to 240 °C − 221-75864-30 221-75864-60 −
0.53 mm 3.00 µm -20 to 240 °C − 221-75865-30 221-75865-60 221-75865-75
* Maximum temperatures listed are for shorter length columns. Longer columns may have a different maximum temperature.

23
 SH-1701

• Mid-polarity phase: Crossbond ™ 14% cyanopropylphenyl / 86% dimethyl ■ SH-1701 Structure

polysiloxane
• General-purpose columns for alcohols, oxygenates, PCB congeners (e.g.,
Aroclor mixes), pesticides, and fragrance compounds.
• Equivalent to USP G46 phase.
• Similar phases: DB-1701P, DB-1701, CP Sil 19 CB, VF-1701ms, VF-1701
Pesticides, SPB-1701

For SH-1701 columns with Integrated Guard column, please refer to page 49.

ID df Temp. Range 15 m 30 m 60 m
0.10 µm -20 to 280 °C − 227-36216-01 227-36216-02
0.25 µm -20 to 280 °C − 221-75777-30 227-36217-01
0.25 mm
0.50 µm -20 to 270/280 °C − 221-75778-30 227-36218-01
1.00 µm -20 to 260/280 °C − 221-75779-30 227-36219-01
0.10 µm -20 to 280 °C − 221-76184-30 227-36220-01
0.25 µm -20 to 280 °C 221-75780-15 221-75780-30 221-75780-60
0.32 mm 0.50 µm -20 to 270/280 °C − 221-75781-30 227-36221-01
1.00 µm -20 to 260/280 °C − 221-75782-30 221-75782-60
1.50 µm -20 to 240/260 °C − 227-36222-01 227-36222-02
0.10 µm -20 to 270/280 °C − 227-36223-01 227-36223-02
0.25 µm -20 to 270/280 °C − 227-36224-01 −
0.50 µm -20 to 260/270 °C − 227-36225-01 −
0.53 mm
1.00 µm -20 to 250/270 °C − 221-75785-30 227-36226-01
1.50 µm -20 to 240/260 °C − 227-36227-01 227-36227-02
3.00 µm -20 to 230/250 °C − 227-36228-01 227-36228-02
* Maximum temperatures listed are for shorter length columns. Longer columns may have a different maximum temperature.

Analysis of Ethylene Glycol and Diethylene Glycol

Conditions
in Propylene Glycol Instrument: GC-2010 Plus AF/AOC-20i
Column: SH-1701, 30 m, 0.32 mm ID, 1.00 μm
(P/N: 221-75782-30)
Sample: 50 mg each in methanol
Inj. Vol.: 1 μL split (split ratio 20:1)
Inj. Temp: 220 °C
Carrier Gas: He, 38 cm/sec
Oven Temp: 100 °C to 220 °C at 7.5 °C/min (hold 4 min)
Detector: FID, 250 °C

24
Capillary Columns
General-Purpose Columns

SH-200 / SH-200MS

• Mid-polarity phase: Crossbond™ trifluoropropyl methyl polysiloxane ■ SH-200 / SH-200MS Structure

• General-purpose columns for solvents, Freon® fluorocarbons, alcohols, ketones,
silanes, glycols, and drugs of abuse. CF 3
• Equivalent to USP G6 phase.
(CH 2)2
• Similar phases: DB-210, DB-200, VF-200ms

Si O

CH 3

SH-200
ID df Temp. Range 30 m 60 m 105 m
0.10 µm -20 to 320/340 °C 227-36179-01 − −
0.25 µm -20 to 320/340 °C 227-36180-01 227-36180-02 −
0.25 mm
0.50 µm -20 to 310/330 °C 227-36181-01 227-36181-02 −
1.00 µm -20 to 290/310 °C 221-75800-30 227-36182-01 −
0.10 µm -20 to 320/340 °C 227-36183-01 227-36183-02 −
0.25 µm -20 to 320/340 °C 227-36184-01 227-36184-02 −
0.32 mm 0.50 µm -20 to 310/330 °C 227-36185-01 227-36185-02 −
1.00 µm -20 to 290/310 °C 227-36186-01 227-36186-02 −
1.50 µm -20 to 280/300 °C 227-36187-01 227-36187-02 221-75804-15
0.10 µm -20 to 310/330 °C 227-36188-01 227-36188-02 −
0.25 µm -20 to 310/330 °C 227-36189-01 227-36189-02 −
0.50 µm -20 to 300/320 °C 227-36190-01 227-36190-02 −
0.53 mm
1.00 µm -20 to 290/310 °C 227-36191-01 227-36191-02 −
1.50 µm -20 to 280/300 °C 227-36192-01 227-36192-02 −
3.00 µm -20 to 260/280 °C 227-36193-01 227-36193-02 −
* Maximum temperatures listed are for shorter length columns. Longer columns may have a different maximum temperature.

SH-200MS (Low-bleed phase for GCMS analysis)

ID df Temp. Range 30 m
0.10 µm -20 to 320/340 °C 227-36194-01
0.25 µm -20 to 320/340 °C 221-75811-30
0.25 mm
0.50 µm -20 to 310/330 °C 227-36195-01
1.00 µm -20 to 290/310 °C 227-36196-01
0.10 µm -20 to 320/340 °C 227-36197-01
0.25 µm -20 to 320/340 °C 221-75814-30
0.32 mm
0.50 µm -20 to 310/330 °C 227-36198-01
1.00 µm -20 to 290/310 °C 227-36199-01
0.50 µm -20 to 300/320 °C 227-36200-01
0.53 mm 1.00 µm -20 to 290/310 °C 227-36201-01
1.50 µm -20 to 280/300 °C 227-36202-01

25
 Analysis of Organic Solvents
22
21
57
6
37
3 23
15 47 69
16 18 43
9
8
2 11 20 19 33,34
40,41 64 66
17 46 56
45
7
10 25 30 32 52 53
63
73
24 35 45 50 59 62
1 14 26 71
12 27 36 38 42 44 49 58
72 75
55 60 70
28 67 68
39 65 74
29 31 61
51 54
13 48

Peaks
1. Methanol 27. 1,2-Dimethoxyethane 52. Methyl Butyl Ketone
2. Ethanol 28. Ethylene Glycol Monomethyl Ether 53. Cyclohexanol
3. Acetaldehyde + Ethyl Ether 29. Ethylenechlorohydrin 54. 1,1,2,2-Tetrachloroethane
4. 1,1-Dichloroethylene 30. Methyl Ethyl Ketone 55. Isoamyl Acetate
5. Isopropanol 31. Nitromethane 56. Butyl Acrylate
6. Dichloromethane + Hexane 32. Propylene Glycol Monomethyl Ether + 57. Ethylene Glycol Monobutyl Ether
7. trans-1,2-Dichloroethylene Isopropyl Acetate 58. Anisole + Propylene Glycol Monomethyl
8. tert.-Butanol 33. Ethyl Acrylate Ether Acetate
9. tert.-Butyl Methyl Ether 34. Isoamyl Alcohol 59. n-Amyl Acetate
10. Isopropyl Ether 35. Methyl Methacrylate 60. Ethylene Glycol Monoethyl Ether Acetate
11. n-Propanol 36. Ethylene Glycol Monoethyl Ether 61. N,N-Dimethylformamide
12. Ethyl Formate 37. Toluene 62. Isooctanol
13. Chloroform 38. 1,4-Dioxane 63. Cyclohexanone
14. Methyl Acetate 39. tetrachloroethylene 64. o-Dichlorobenzene
15. Cyclohexane 40. n-Propyl Acetate 65. Diethylene Glycol Monoethyl Ether
16. Tetrachloromethane + sec.-Butanol 41. n-Amyl Alcohol 66. Benzyl Alcohol
17. Isooctane 42. Epichlorohydrin 67. N,N-Dimethylacetamide
18. Isobutanol + 1,1,1-Trichloroethane 43. Pyridine 68. Dimethyl Sulfoxide
19. Acetonitrile 44. Ethylene Glycol Monoisopropyl Ether 69. Tetralin
20. Acrylonitrile 45. Isobutyl Acetate 70. Diethylene Glycol Monobutyl Ether
21. Benzene 46. Methyl Isobutyl Ketone + Ethylbenzene 71. 2-Ethylhexyl Acrylate
22. Tetrahydrofuran + methylcyclohexane 47. Chlorobenzene 72. N-Methylpyrrolidone
23. Methyl Acrylate + 1,2-Dichloroethane 48. p-Xylene 73. Isophorone
24. Trichloroethylene 49. m-Xylene 74. 1,3-Dimethyl-2-Imidazolidinone
25. n-Butanol 50. n-Butyl Acetate 75. Sulfolane
26. Ethyl Acetate 51. o-Xylene

Conditions
Instrument: GC-2010
Column: SH-200, 60 m, 0.32 mm ID, 1.00 μm (P/N: 227-36186-02)
Injection: Split (split ratio: 50:1)
Inj. Temp: 250 °C
Carrier Gas: He, constant linear velocity mode, 25 cm/sec
Oven Temp: 40 °C (0 min) to 310 °C at 4 °C/min
Detector: FID, 330 °C

For information on connection parts for capillary columns,

please refer to page 50.

26
Capillary Columns
General-Purpose Columns

SH-225

• Polar phase: Crossbond ™ 50% cyanopropylmethyl / 50% phenylmethyl ■ SH-225 Structure

polysiloxane
C N
• G e n e r a l - p u r p o s e c o l u m n s f o r FA M E s , c a r b o h y d r a t e s , s t e r o l s , f l a v o r
compounds. (CH 2)3
• Equivalent to USP G7 and G19 phases.
• Similar phases: DB-225, DB-225MS, CP-Sil 43 CB, SPB-225 Si O Si O

CH 3 CH 3
50% 50%

ID df Temp. Range 30 m 60 m
0.25 µm 40 to 220/240 °C 227-36229-01 227-36229-02
0.25 mm
0.50 µm 40 to 220/240 °C 227-36230-01 −
0.10 µm 40 to 220/240 °C 227-36231-01 −
0.25 µm 40 to 220/240 °C 227-36232-01 −
0.32 mm
0.50 µm 40 to 220/240 °C 227-36233-01 −
1.00 µm 40 to 200/220 °C 227-36234-01 227-36234-02
0.25 µm 40 to 200/220 °C 227-36235-01 −
0.53 mm 0.50 µm 40 to 200/220 °C 227-36236-01 −
1.00 µm 40 to 200/220 °C 227-36237-01 −
* Maximum temperatures listed are for shorter length columns. Longer columns may have a different maximum temperature.

SH-440

• General-purpose columns with unique selectivity for pesticides, PAHs, or other semivolatiles. Ideal for low/trace-level
analyses.
• Low-bleed, high-resolution columns with unique selectivity.

ID df Temp. Range 30 m
0.25 mm 0.25 µm 20 to 320/340 °C 227-36340-01

SH-502.2

• Application-specific columns with unique selectivity for volatile organic pollutants. The SH-502.2 column is cited in U.S.
EPA Method 502.2 and in many gasoline range organics (GRO) methods for monitoring underground storage tanks.
• Excellent separation of trihalomethanes; ideal polarity for light hydrocarbons and aromatics.
• Similar phase: DB-502.2

The SH-502.2 column will enable you to quantify all compounds listed in U.S. EPA methods 502.2 or 524.2, whether you
use a mass spectrometer or a PID in tandem with an ELCD. The diphenyl/dimethyl polysiloxane based SH-502.2 stationary
phase provides low bleed and thermal stability to 270 °C. A 105-meter column can separate the light gases specified in
EPA methods without subambient cooling. Narrow bore columns can interface directly in GC/MS systems.

ID df Temp. Range 30 m 105 m

0.32 mm 1.80 µm -20 to 250/270 °C 227-36341-01 227-36341-02

27
 Capillary Columns
General-Purpose Columns

SH-2330

• Highly polar phase: Crossbond™ 90% biscyanopropyl / 10% cyanopropylphenyl ■ SH-2330 Structure
polysiloxane (Non-bonded)
• General-purpose columns for cis/trans FAMEs, dioxin isomers.
• Equivalent to USP G8 and G48 phase.
• Similar phases: DB-23, VF-23ms, SP-2330, SP-2331, SP-2380

ID df Temp. Range 30 m 60 m
0.10 µm 0 to 260/275 °C 227-36238-01 227-36238-02
0.25 mm
0.20 µm 0 to 260/275 °C 227-36239-01 227-36239-02
0.10 µm 0 to 260/275 °C 227-36240-01 227-36240-02
0.32 mm
0.20 µm 0 to 260/275 °C 227-36241-01 227-36241-02
0.10 µm 0 to 260/275 °C − 227-36242-01
0.53 mm
0.20 µm 0 to 260/275 °C 227-36243-01 227-36243-02
* Maximum temperatures listed are for shorter length columns. Longer columns may have a different maximum temperature.

SH-2560

• Highly polar phase; biscyanopropyl polysiloxane—not bonded

• Stationary phase selectivity optimized for isomer separation to ensure accurate quantification of critical cis/trans
FAMEs.
• Application-specific QC test guarantees consistent, reliable performance for AOAC 996.06 and AOCS Ce 1j-07
methods.
• Excellent sample capacity; no peak distortion means easy, accurate peak integration.
• Similar phases: HP-88, CP Sil 88, SBP-2560

ID df Temp. Range 100 m

0.25 mm 0.20 µm 20 to 250 °C 227-36311-01

28
SH-Wax

• Polar phase: Crossbond™ polyethylene glycol ■ SH-Wax Structure

• Best polyethylene glycol (PEG) phase for alkenols, glycols, and aldehydes.
• Equivalent to USP G14, G15, G16, G20, G39 phases. H H
• Similar phases: DB-Wax, CP-Wax 52 CB
C C O

H H

ID df Temp. Range 15 m 20 m 30 m 50 m 60 m
0.10 µm 20 to 250 °C − − 221-76186-30 − −
0.25 mm 0.25 µm 20 to 250 °C − − 221-75893-30 221-75893-50 221-75893-60
0.50 µm 20 to 250 °C − − 221-75894-30 − 221-75894-60
0.25 µm 20 to 250 °C − 221-75895-20 221-75895-30 − 221-75895-60
0.32 mm 0.50 µm 20 to 250 °C − − 221-75896-30 221-75896-50 221-75896-60
1.00 µm 20 to 240/250 °C − − 221-75897-30 − 221-75897-60
0.25 µm 20 to 250 °C − − 227-36244-01 − −
0.53 mm 0.50 µm 20 to 250 °C − − 221-76188-30 − 227-36245-01
1.00 µm 20 to 240/250 °C 221-75899-15 − 221-75899-30 − 221-75899-60
* Maximum temperatures listed are for shorter length columns. Longer columns may have a different maximum temperature.

Aldehydes Peaks
1. ethanal
2. propanal
3. butenal
4. pentanal
5. hexanal
6. heptanal
7. octanal
8. nonanal
9. decanal
10. undecanal

Conditions
Column: SH-Wax, 30 m, 0.2 5mm ID,
0.50 μm (P/N: 221-75894-30)
Samples: C2-C11 aldehydes mixture
On-column conc.: 250 ng
Injection: Split (split ratio: 100:1)
Inj. Temp: 200 °C
Carrier Gas: Hydrogen, linear velocity 35
cm/sec. set at 40 °C
Oven Temp: 40 °C (hold 5 min) to 200 °C at
10 °C/min
Detector: FID, 200 °C

29
 Capillary Columns
General-Purpose Columns

SH-PolarWax

• Polar phase: Crossbond™ polyethylene glycol ■ SH-PolarWax Structure

• Low-bleed PEG column ensures long column lifetimes.
• Rugged enough to withstand repeated water injections. H H
• Equivalent to USP G14, G15, G16, G20, and G39 phases.
• Similar phases: Innowax, CP-Wax 52 CB, VF-WAX MS, Supelcowax-10 C C O

H H

ID df Temp. Range 10 m 20 m 30 m 50 m 60 m
0.10 mm 0.10 µm 40 to 250/260 °C 227-36343-01 − − − −
0.18 mm 0.18 µm 40 to 250 °C − 227-36357-01 − − −
0.10 µm 40 to 250/260 °C − − 227-36246-01 − 227-36246-02
0.25 mm 0.25 µm 40 to 250/260 °C − − 227-36305-02 227-36247-01 227-36247-02
0.50 µm 40 to 250/260 °C − − 227-36248-01 − 227-36248-02
0.10 µm 40 to 250 °C − − 227-36249-01 − 227-36249-02
0.25 µm 40 to 250/260 °C − − 221-75972-30 − 227-36250-01
0.32 mm
0.50 µm 40 to 250/260 °C − − 227-36251-01 − 221-75975-60
1.00 µm 40 to 240/260 °C − − 227-36252-01 − 227-36252-02
0.10 µm 40 to 250 °C − − 227-36253-01 − −
0.25 µm 40 to 250/260 °C − − 227-36254-01 − 227-36254-02
0.50 µm 40 to 250/260 °C − − 227-36255-01 − 227-36255-02
0.53 mm
1.00 µm 40 to 240/250 °C − − 221-75979-30 − 227-36256-01
1.50 µm 40 to 230/240 °C − − 227-36257-01 − 227-36257-02
2.00 µm 40 to 220/230 °C − − 227-36258-01 − −
* Maximum temperatures listed are for shorter length columns. Longer columns may have a different maximum temperature.

FAMEs in Biodiesel Oils

Soy FAMEs Rapeseed FAMEs

Tallow FAMEs Yellow Grease FAMEs

Conditions
Column: SH-PolarWax, 30 m, 0.32 mm ID, 0.25 μm (P/N: 221-75972-30)
Inj. Vol.: 1 μL split (split ratio 100:1)
Inj. Temp: 250 °C
Carrier Gas: Hydrogen, constant flow rate 3mL/min, linear velocity 60 cm/sec.
Oven Temp: 210 °C (hold 5 min) to 230 °C at 20 °C/min (hold 5 min)
Det.: FID, 250 °C

30
Capillary Columns
Dedicated Columns

SH-1614

• 5% diphenyl / 95% dimethyl polysiloxane

• Optimized for PBDE analysis by EPA Method 1614.
• Short column option resolves BDE-209 three times faster, with less thermal breakdown.
• Unique deactivation gives higher BDE-209 response than competitor columns, for greater analytical sensitivity.
• Exceeds EPA Method 1614 resolution criteria for BDE-49 and BDE-71.

ID df Temp. Range 15 m 30 m
0.25 mm 0.10 µm -60 to 330/360 °C 227-36265-01 227-36265-02

Brominated Flame Retardants

Peaks
1. BDE-10 15. BDE-37 29. BDE-126
2. BDE-7 16. BDE-75 30. BDE-154
3. BDE-8 17. BDE-49 31. BDE-153
4. BDE-11 18. BDE-71 32. BDE-138
5. BDE-12 19. BDE-47 33. BDE-166
6. BDE-13 20. BDE-66 34. BDE-183
7. BDE-15 21. BDE-77 35. BDE-181
8. BDE-30 22. BDE-100 36. BDE-190
9. BDE-32 23. BDE-119 37. BDE-208
10. BDE-17 24. BDE-99 38. BDE-207
11. BDE-25 25. BDE-116 39. BDE-206
12. BDE-28 26. BDE-118 40. BDE-209
13. BDE-33 27. BDE-85
14. BDE-35 28. BDE-155

Conditions
Column: SH-1614, 15 m, 0.25 mm ID, 0.10 μm (P/N: 227-36265-01)
Sample: 100-300 ppb PBDE PAR Solution
500 ppb decabromodiphenyl ether
Inj. Vol.: 1 μL splitless (hold 1 min),
Inj. Temp: 340 °C
Carrier Gas: He, constant flow, linear velocity 60 cm/sec., 120 °C
Oven Temp: 120 °C (hold 1 min) to 275 °C at 15 °C/min to 300 °C at 5 °C/min (hold 5 min)
Detector: μ-ECD, 345 °C

31
 Capillary Columns
Dedicated Columns

SH-OPP2

• Dedicated column for organophosphorus pesticides; best column combination for US EPA Method 8141.
• Low bleed - ideal for GC-FPD, GC-NPD, or GCMS analyses.

ID df Temp. Range 30 m
0.32 mm 0.32 µm -20 to 310/330 °C 221-75887-30

Organophosphorus Pesticides (U.S. EPA Method 8141A)

Peaks
1. Dichlorvos 8. Thionazin 15. Demeton-S 22. Phosphamidon isomer (breakdown product)
2. Hexamethylphosphoramide 9. Ethoprop 16. Terbufos 23. Dichlorofenthion
3. Mevinphos 10. Naled 17. Dimethoate 24. Phosphamidon
4. Trichlorfon 11. Sulfotepp 18. Diazinon 25. Chlorpyrifos methyl
5. TEPP 12. Phorate 19. Dioxathion 26. Methyl parathion
6. Demeton-O 13. Dicrotophos 20. Fonophos 27. Ronnel
7. Tributyl phosphate (SS) 14. Monocrotophos 21. Disulfoton 28. Aspon
29. Fenitrothion
30. Malathion
31. Chlorpyrifos
32. Trichloronate
33. Parathion-ethyl
34. Fenthion
35. Merphos
36. Chlorfenvinphos
37. Crotoxyphos
38. Stirofos
39. Prothiofos
40. Merphos oxone (breakdown product)
41. Ethion
42. Fensulfothion
43. Sulprofos
44. Carbophenothion
45. Famphur
46. Triphenyl phosphate (SS)
47. EPN
48. Phosmet
49. Leptophos
50. Tri-o-cresyl phosphate
51. Azinphos-methyl
52. Azinphos-ethyl
53. Coumaphos

Conditions
Columns: SH-OPP2, 30 m, 0.32 mm ID, 0.32 μm (P/N: 221-75887-30) Carrier Gas: He
Inj. Vol.: 1 μL splitless (hold 1 min) Dead Time: 1.03 min at 80 °C
Inj. Temp: 200 °C Detector: FPD, 250 °C
Oven Temp: 80 °C (hold 0.5 min) to 280 °C at 12 °C/min (hold 10 min) Notes: Constant pressure

32
SH-CLP / SH-CLP II

• Dedicated columns for organochlorine pesticides and herbicides.

• Low bleed - ideal for high-sensitivity GC-ECD or GCMS analyses.
• Baseline separations in less than 10 minutes.
• Analyze EPA Method 8081B, 8082A, 8151A, 504.1, 515, 508.1, and 552.2 compounds without time-consuming column
changes.
• Similar phases: DB-CLP1 / DB-CLP2

SH-CLP
ID df Temp. Range 30 m
0.32 µm -60 to 320/340 °C 227-36266-01
0.32 mm
0.50 µm -60 to 320/340 °C 221-75879-30

SH-CLP II
ID df Temp. Range 30 m
0.32 mm 0.25 µm -60 to 320/340 °C 227-36267-01

Organochlorine Pesticides (US EPA Method 8081)

Peaks 5. δ-BHC (δ-HCH) 11. 4,4'-DDE 17. 4,4'-DDT
1. 2,4,5,6-tetrachloro- 6. heptachlor 12. endosulfan I 18. endrin aldehyde
m-xylene 7. aldrin 13. dieldrin 19. methoxychlor
2. α-BHC (α-HCH) 8. heptachlor epoxide 14. endrin 20. endosulfan sulfate
3. γ-BHC (lindane) 9. γ-chlordane 15. 4,4'-DDD 21. endrin ketone
4. β-BHC (β-HCH) 10. α-chlordane 16. endosulfan II 22. decachlorobiphenyl

Conditions
Column: SH-CLP, 30 m, 0.32 mm ID, 0.50 μm SH-CLP II, 30 m, 0.32 mm ID, 0.25 μm
(P/N: 221-75879-30) (P/N: 227-36267-01)
Oven Temp: 120 °C (hold 1 min) to 300 °C (hold 10 min)
at 9 °C/min
Inj.: Direct
Inj. Temp: 200 °C
Detector: ECD, 300 °C with anode purge
Dead time: 1.9 min
Head pressure: 8.7 psi (constant)
Flow rate: 1.3 mL/min at 120 °C, He

33
 Capillary Columns
Dedicated Columns

SH-VMS

• Dedicated columns for analyzing volatile organic pollutants by GCMS including methods TO-15, TMS, and EPA 8260.
• Complete separation of U.S. EPA Method 8260 compounds in less than 10 minutes.

ID df Temp. Range 20 m 30 m 60 m
0.18 mm 1.00 µm -40 to 240/260 °C 227-36412-01 − −
0.25 mm 1.40 µm -40 to 240/260 °C − 227-36268-01 227-36268-02
0.32 mm 1.80 µm -40 to 240/260 °C − 227-36269-01 227-36269-02
0.45 mm 2.55 µm -40 to 240/260 °C − − 227-36348-01
0.53 mm 3.00 µm -40 to 240/260 °C − 227-36353-01 −

Volatile Organics (US EPA CLP 04.1) Peaks

1. dichlorodifluoromethane
2. chloromethane
3. vinyl chloride
4. bromomethane
5. chloroethane
6. trichlorofluoromethane
7. 1,1-dichloroethene
8. carbon disulfide
9. 1,1,2-trichloro-1,2,2-
trifluoroethane
10. methylene chloride
11. acetone
12. trans-1,2-dichloroethene
13. methyl acetate
14. methyl tert-butyl ether
15. 1,1-dichloroethane
16. cis-1,2-dichoroethane
17. cyclohexane
18. bromochloromethane (IS)
19. chloroform
20. carbon tetrachloride
21. 1,1,1-trichloroethane
22. 2-butanone
23. benzene
24. 1,2-dichloroethane-d4 (SS)
25. 1,2-dichloroethane
26. methylcyclohexane
27. trichloroethene
28. 1,4-difluorobenzene (IS)
29. 1,2-dichloropropane
30. bromodichloromethane
31. cis-1,3-dichloropropene
32. toluene d8 (SS)
33. toluene
34. tetrachloroethane
35. 4-methyl-2-pentanone
36. trans-1,3-dichloropropane
37. 1,1,2-trichloroethane
38. dibromochloromethane
39. 1,2-dibromoethane
Inj.: Split (split ratio: 35:1) 40. 2-hexanone
Conditions
41. chlorobenzene d5 (IS)
Column: SH-VMS, 30 m, 0.25 mmID, Inj. Temp: 200 °C
42. chlorobenzene
1.40 μm Carrier Gas: He, linear velocity 34 cm/sec.,
43. ethylbenzene
(P/N: 227-36268-01) 40 °C, constant flow
44. m-xylene
Purge and Trap: Trap: #10 (TenaxR/silica gel/ Oven Temp: 40 °C (hold 4 min) to 90 °C at 16 °C/min
45. p-xylene
carbon molecular sieve) to 220 °C at 32 °C/min (hold 5 min)
46. o-xylene
Sample Temp: ambient Detector: MS 47. styrene
Purge: 11 min at 40 mL/min Transfer Line Temp: 150 °C 48. bromoform
Desorb preheat: 185 °C Scan Range: 35-300 amu. 49. isopropylbenzene
Desorb: 0.5 min at 190 °C Ionization: EI 50. 4-bromofluorobenzene (SS)
Desorb flow rate: 35.0 mL/min 51. 1,1,2,2-tetrachloroethane
Bake: 8 min at 210 °C 52. 1,3-dichlorobenzene
Interface: split injector 53. 1,4-dichlorobenzene
Transfer Line Temp: 150 °C 54. 1,2-dichlorobenzene
55. 1,2-dibromo-3-chloropropane
56. 1,2,4-trichlorobenzene

34
SH-Volatil Amin

• Unique selectivity for baseline resolution of all volatile amines.

• Excellent inertness assures accuracy and sensitivity for volatile amines, including free ammonia.
• Highly robust phase withstands repeated water injections, resulting in longer column lifetime.
• High temperature stability (290 °C) ensures elution of amines up to C16 and allows contaminants to be removed by
"baking out" the column.
• Similar phase: CP-Volamine

The SH-Volatile Amine column was designed specifically for analyzing volatile amines in difficult matrices, such as water.
The unique base deactivation creates an exceptionally inert surface for these sensitive compounds, resulting in highly
symmetrical peaks, which allow low detection limits. The stable bonded phase yields a column that is not only retentive
and highly selective for these compounds but is also very robust and able to withstand repeated water injections.

ID df Temp. Range 30 m 60 m
0.32 mm 5.00 µm -60 to 270/290 °C 227-36326-01 227-36326-02

SH-PCB

• Unique polymer for PCBs analysis by GC-ECD or GC-MS.

• Good results for other semivolatiles.
• Low polarity; inert to active compounds.

ID df Temp. Range 60 m
0.25 mm 0.25 µm 30 to 320/340 °C 227-36310-01

SH-VRX

• Application-specific columns for volatile organic pollutants.

• Excellent for U.S. EPA Method 8021 compounds.

The SH-VRX stationary phase and optimized column dimensions provide low bleed, excellent resolution, and fast analysis
times for volatile compounds.

ID df Temp. Range 25 m 30 m
0.10 mm 0.50 µm -40 to 240/260 °C 227-36331-01 −
0.25 mm 1.40 µm -40 to 240/260 °C − 227-36355-01

35
 Capillary Columns
Dedicated Columns

SH-FAME

• Dedicated column for FAMEs, specially tested with a FAME mixture.

• Equivalent to USP G16 phase.
• Similar phases: Select FAME, Omegawax

ID df Temp. Range 30 m
0.25 mm 0.25 µm 20 to 240/250 °C 227-36324-01
0.32 mm 0.25 µm 20 to 240/250 °C 227-36270-01

FAMEs (Marine Oil Standard)

Peak List Conc. (μg/mL)
1. C14:0 600
2. C14:1 100
3. C16:0 1600
4. C16:1 500
5. C18:0 800
6. C18:1 (oleate) 1300
7. C18:1 (vaccenate) 400
8. C18:2 200
9. C18:3 200
10. C20:0 100
11. C20:1 900
12. C20:2 100
13. C20:4 300
14. C20:3 100
15. C20:5 1000
16. C22:0 100
17. C22:1 300
18. C24:0 100
19. C22:6 1200
20. C24:1 100

Conditions
Column: SH-FAME, 30 m, 0.32 mm ID, 0.25 μm (P/N: 227-36270-01)
Inj. Vol.: 1 μL split (split ratio: 100:1)
Conc.: 10,000 μg/mL in isooctane (total FAMEOs)
Inj. Temp: 250 °C
Carrier Gas: Hydrogen, constant flow rate 3 mL/min
Oven Temp: 195 - 240 °C at 5 °C/min (hold 1 min)
Detector Temp: 275 °C

36
SH-BAC Plus 1 / SH-BAC Plus 2

• Optimized column selectivities guarantee resolution of ethanol, internal standards, and frequently encountered
interferences.
• Robust and reproducible column chemistry ensures longer column lifetime and consistent results.

SH-BAC Plus 1
ID df Temp. Range 30 m
0.32 mm 1.80 µm -20 to 240/260 °C 227-36260-01
0.53 mm 3.00 µm -20 to 240/260 °C 227-36261-01

SH-BAC Plus 2
ID df Temp. Range 30 m
0.32 mm 0.60 µm -20 to 240/260 °C 227-36263-01
0.53 mm 1.00 µm -20 to 240/260 °C 227-36264-01

Analysis of Alcohol Compounds in Blood

SH-BAC Plus 2

Peaks
1 Acetaldehyde
2 Methanol
3 Ethanol
4 Acetone
5 Isopropanol
6 t-Butanol
7 1-Propanol

SH-BAC Plus 1

Peaks
1 Acetaldehyde
2 Methanol
3 Ethanol
4 Acetone
5 Isopropanol
6 t-Butanol
7 1-Propanol

Conditions
Instrument: GC-2010 Plus AF + HS-20 Column: SH-BAC Plus 2, 30 m, 0.32 mm ID, 0.60 μm (P/N: 227-36263-01)
Headspace: Oven Temp.: 85 °C SH-BAC Plus 1, 30 m, 0.32 mm ID, 1.80 μm (P/N: 227-36260-01)
Vial Warming Time: 15 min Column Temp: 40 °C
Vial Pressurization Time: 1 min Inj.: Split (split ratio: 20:1)
Injection Time: 0.5 min Carrier Gas: He, 100 kPa
Sample Line Temp: 150 °C Detector: FID, 250 °C
Vial Volume: 20 mL Makeup Gas: He, 30 mL/min
Vial Agitation: Off Hydrogen: 40 mL/min
Vial Pressurization: 100 kPa Air: 400 mL/min
Load Time: 0.5 min
Needle Flash Time: 0.5 min
Transfer Line Temp: 150 °C

37
 Capillary Columns
Dedicated Columns

SH-5 Amine / SH-35 Amine

• Dedicated columns for amines and other basic compounds, including alkylamines, diamines, triamines, ethanolamines,
and nitrogen-containing heterocyclics.

SH-5 Amine (Low-polarity phase: Crossbond™ 5% diphenyl / 95% dimethyl polysiloxane)

ID df Temp. Range 15 m 30 m
0.25 µm -60 to 315 °C − 227-36282-01
0.25 mm 0.50 µm -60 to 300/315 °C 227-36323-01 227-36283-01
1.00 µm -60 to 300/315 °C 227-36323-02 227-36284-01
1.00 µm -60 to 300/315 °C − 227-36332-02
0.32 mm
1.50 µm -60 to 290/305 °C − 227-36285-01
1.00 µm -60 to 290/305 °C − 227-36286-01
0.53 mm
3.00 µm -60 to 280/295 °C − 227-36287-01

SH-35 Amine (Mid-polarity phase: Crossbond™ 35% diphenyl / 65% dimethyl polysiloxane)
ID df Temp. Range 30 m
0.50 µm 0 to 220 °C 227-36288-01
0.25 mm
1.00 µm 0 to 220 °C 227-36289-01
1.00 µm 0 to 220 °C 227-36290-01
0.32 mm
1.50 µm 0 to 220 °C 227-36291-01
1.00 µm 0 to 220 °C 227-36292-01
0.53 mm
3.00 µm 0 to 220 °C 227-36293-01

Peaks
Amines & Phenols 1. diethylamine
2. pyridine
3. morpholine
4. phenol
5. aniline
6. 2-chlorophenol
7. diethylenetriamine
9 8. octylamine
4
9. 1-methyl-2-pyrrolidinone
10. 2-nitrophenol
11. 2,6-dimethylaniline
12. nicotine
5 13. 2-nitroaniline
3
1 2
13 Conditions
Column: SH-5 Amine, 30 m, 0.32 mm
11 ID, 1.00 μm (P/N: 227-36290-01)
8
Inj. Vol.: 1 μL split injection of miscellaneous
amines and phenols in water (split
6 10
ratio: 25:1)
On-column conc.: 22 ng
Inj. Temp: 305 °C
7 Oven Temp: 120 °C to 220 °C at 10 °C/min
12
Carrier Gas: Hydrogen, linear velocity
38cm/sec. set at 120 °C
Det. Temp: 305 °C
FID sensitivity: 6.4 × 10-11 AFS

min. 2 4 6 8 10

38
SH-PolarD

• Polar phase: Crossbond™ acid-deactivated Carbowax™ polyethylene glycol

• Dedicated columns for free (underivatized) acids, some inorganic acids.
• Resistant to oxidative damage.
• Equivalent to USP G25 and G35 phases.
• Similar phases: HP-FFAP, DB-FFAP, VF-DA, CP-Wax 58 CB, CP-FFAP CB, Nukol

ID df Temp. Range 30 m 50 m 60 m
0.10 µm 40 to 250/260 °C 227-36271-01 − −
0.25 mm 0.25 µm 40 to 250/260 °C 221-75981-30 − 227-36272-01
0.50 µm 40 to 250/260 °C 227-36273-01 − 227-36273-02
0.10 µm 40 to 250/260 °C 227-36274-01 − −
0.25 µm 40 to 250/260 °C 227-36321-02 − 227-36275-01
0.32 mm
0.50 µm 40 to 250/260 °C 227-36322-02 − 227-36276-01
1.00 µm 40 to 240/250 °C 227-36277-01 227-36277-03 227-36277-02
0.25 µm 40 to 250/260 °C 227-36278-01 − 227-36278-02
0.50 µm 40 to 250/260 °C 227-36279-01 − 227-36279-02
0.53 mm
1.00 µm 40 to 240/250 °C 227-36280-01 − 227-36280-02
1.50 µm 40 to 230/240 °C 227-36281-01 − 227-36281-02

Organic Acids (Free Fatty Acids) Peaks

1. acetic acid
2. propionic acid
3. isobutyric acid
8 4. n-butyric acid
5. isovaleric acid
6. n-valeric acid
7. isocaproic acid
8. caproic acid
9. heptanoic acid
10. caprylic acid
11. capric acid
9
12. lauric acid
13. myristic acid
7 14. palmitic acid
11
15. stearic acid
13 16. arachidic acid
6 17. behenic acid
5 10
14 16
12
17 Conditions
15
Column: SH-PolarD, 30 m, 0.53 mm ID,
4
3 0.25 μm (P/N: 227-36278-01)
Sample: free acid standard
2
Conc.: 25 ng/μL.
Inj. Vol.: 0.3 μL direct
1 Inj. Temp: 280 °C
Oven Temp: 100 °C (hold 2 min) to 280 °C at
8 °C/min, (hold 10 min)
Carrier Gas: Hydrogen, flow rate 10 cc/min, linear
min. 4 8 12 16 20 24 28 velocity 80 cm/sec.
Detector: FID, 280 °C

39
 Capillary Columns
Dedicated Columns

SH-PolarX

• Polar phase: Crossbond™ base-deactivated Carbowax™ polyethylene glycol

• Dedicated columns for underivatized amines and other basic compounds, including alkylamines, diamines, triamines,
nitrogen-containing heterocyclics. No need for column priming.
• Similar phases: CAM, CP-Wax 51 for Amines, Carbowax Amine

ID df Temp. Range 15 m 30 m 60 m
0.25 µm 40 to 210/220 °C 227-36359-01 227-36294-01 −
0.25 mm
0.50 µm 40 to 210/220 °C − 227-36295-01 −
0.25 µm 40 to 210/220 °C − 227-36296-01 227-36296-02
0.32 mm 0.50 µm 40 to 210/220 °C − 227-36297-01 −
1.00 µm 40 to 210/220 °C − 227-36298-01 227-36298-02
0.50 µm 40 to 210/220 °C − 227-36299-01 −
0.53 mm
1.00 µm 40 to 210/220 °C − 227-36300-01 227-36300-02

Amines (low MW)

4 Peaks
1. trimethylamine
2. dimethylamine
3. ethylamine
4. methylamine
5. isopropylamine
6. n-propylamine
7. tert-butylamine
2 8. diethylamine
9. sec-butylamine

Conditions
5
3 Column: SH-PolarX, 30 m, 0.53 mm ID, 1.00 μm
(P/N: 227-36300-01)
Inj. Vol.: 1 μL direct injection of amines in water
Inj. Temp: 250 °C
6 Carrier Gas: Hydrogen, flow rate 5 cc/min, linear velocity
40 cm/sec.
Oven temp.: 45 °C
7 Detector: FID, 250 °C
8
1 9

min. 1 2 3

40
SH-PolarWAX MS

• High-polarity, stable polyethylene glycol (PEG) stationary phase. ■ SH-PolarWAX MS Structure

• Low bleed and rugged enough to withstand repeated temperature cycles without
retention time shifting.
• Ideal for food, flavor, fragrance, and industrial chemical and solvent analysis.
• Temperature range: 40 °C to 250/260 °C.
• Equivalent to USP G14, G15, G16, G20, and G39 phases.
• Similar phases: VF-WAXms, TR-WaxMS

The SH-PolarWax MS column ensures reproducible retention times from run to run,
even with temperature cycling. When methods require trace analysis, this highly
polar, low-bleed stationary phase produces excellent signal-to-noise levels! Ideal
for food and flavor analysis (e.g., essential oils), fragrance and allergen analysis, as
well as industrial solvent and chemical analysis.

ID df Temp. Range 30 m
0.25 mm 0.25 µm 40 to 250/260 °C 227-36322-01
0.32 mm 0.25 µm 40 to 250/260 °C 227-36322-03

41
 Capillary Columns
PLOT Columns

SH-Alumina BOND

• The reactivity of the aluminum oxide stationary phase is minimized to improve column response for polar unsaturates,
such as dienes, and the column's sensitivity (or response) ensures linear and quantitative chromatographic analysis for
these compounds.
• Highly selective for C1–C5 hydrocarbons
• Separate all saturated and unsaturated hydrocarbon isomers above ambient temperatures.

SH-Alumina BOND/Na2SO4
• Na2SO4 deactivation
• Acetylene and propadiene elute after butanes.
• Best separation for butene isomers (impurities in butene streams).
• Methyl acetylene elutes after 1,3-butadiene.
• Cyclopropane (impurity in propylene) elutes well before propylene.
• Similar phases: GS-ALUMINA, CP-Al2O3/Na2SO4, Alumina sulfate PLOT
ID df Temp. Range 30 m 50 m
0.32 mm 5 µm -60 to 200 °C 227-36328-01 −
0.53 mm 10 µm -60 to 200 °C 227-36316-01 227-36301-01

SH-Alumina BOND/KCl
• KCl deactivation
• Lowest polarity alumina column in Shimadzu PLOT columns.
• Low moisture sensitivity reduces the need for frequent regeneration.
• Acetylene elutes before n-butane.
• Methyl acetylene (impurity in 1,3-butadiene) elutes before 1,3-butadiene.
• Similar phases: GS-Alumina KCl, HP-PLOT Al2O3 KCl, CP-Al2O3/KCl, Alumina chloride PLOT
ID df Temp. Range 50 m
0.53 mm 10 µm -60 to 200 °C 221-76139-50

Refinery Gas
2 3 4 6
Peaks
1
1. methane 12. isobutylene
2. ethane 13. cis-2-butene
3. ethylene 14. isopentane
4. propane 15. n-pentane
5
7,8 5. propylene 16. 1,3-butadiene
6. isobutane 17. trans-2-pentene
7. n-butane 18. 2-methyl-2-butene
8. propadiene 19. 1-pentene
9. acetylene 20. cis-2-pentene
10. trans-2-butene 21. hexanes
11. 1-butene

10
Conditions
16 Column: SH-Alumina BOND/KCl, 50 m, 0.53 mm ID,
11
10 μm (P/N: 221-76139-50)
13 Sample: Refinery gas
9 Inj. Vol.: 10 μL split (split vent flow 80mL/min)
12 Inj. Temp: 200 °C
14 Oven Temp: 45 °C (hold 1 min) to 200 °C at 10 °C/min (hold 3.5 min)
Carrier Gas: Hydrogen, constant pressure, 8.0 psi, linear
15
velocity 74 cm/sec. at 45 °C
19 Detector: FID, 200 °C
18
17 20 21

0 2 4 6 8 10 12 14 16 18
Time (min)

42
SH-Msieve 5A

• Stationary phase: Molecular sieve 5A

• Easily separate permanent gases at temperatures above ambient.
• Improve accuracy with sharp, symmetrical peaks for argon, oxygen, and carbon monoxide.
• Similar phases: HP-PLOT Molesieve, CP-Molsieve 5A, Mol Sieve 5A PLOT

ID df Temp. Range 30 m
0.32 mm 30 µm -100 to 300 °C 227-36611-02
0.53 mm 50 µm -100 to 300 °C 221-75763-30

Analysis of Inorganic Gas

Ar（m/z 40） O2（m/z 32） N2（m/z 28）

1.50 1.75 2.00 2.25 1.50 1.75 2.00 2.25 3.00 3.25 3.50 3.75

CH4（m/z 16） CO（m/z 28）

Peaks
1. Ar 5.65 ppm
2. CO 5.44 ppm
3. O2 5.54 ppm
4. N2 5.40 ppm
5. CH4 5.71 ppm

3.75 4.00 4.25 4.50 7.00 7.25 7.50 7.75

Conditions
Instrument: GCMS-QP2010 Ultra
Column: SH-Msieve 5A, 30 m,
0.32 mm ID,
30 μm (P/N: 227-36611-02)
Sample injection: Gas sampler (1 mL loop
Ar volume)
(P/N: 223-57653-91)
O2 N2 CH4 Inj. Mode: Split (split ratio: 50:1)
Inj. Temp: 200 °C
Control Mode: Pressure (100 kPa)
Carrier Gas: Helium
CO
Oven Temp: 35 °C (hold 2 min) to 150
°C at 10 °C/min
(hold 5 min)
Detector: MS
Interface Temp: 200 °C
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 Ion Source Temp: 200 °C
Measurement Mode: Scan
(m/z 10 to100)
Event Time: 0.5 sec
Ionization Method: EI
Emission Current:150 μA

43
 Capillary Columns
PLOT Columns

SH-Q-BOND

• Non-polar PLOT column incorporating 100% divinylbenzene.

• Excellent for analysis of C1 to C3 hydrocarbons as well as isomers and alkanes up to C12.
• High retention for CO2 simplifies gas analysis; CO2 and methane separated from O2/N2/CO. (Note: O2/N2/CO
not separated at ambient temperature.)
• Use for analysis of oxygenated compounds and solvents.
• Similar phases: HP-PLOT Q, CP-PoraPLOT Q, CP-PoraBOND Q, Supel-Q PLOT

ID df Temp. Range 30 m
0.32 mm 10 μm -60 to 280/300 °C 221-75764-30
0.53 mm 20 µm -60 to 280/300 °C 221-75765-30

SH-U-BOND

• Polar PLOT column, incorporating divinylbenzene ethylene glycol / dimethylacrylate.

• Highest polarity porous polymer column in Shimadzu PLOT columns.
• Highly inert for the analysis of polar and nonpolar compounds.
• Ideal for trace H2S, COS, and mercaptans in hydrocarbon streams.
• Similar phases: HP-PLOT U, CP-PoraPLOT U, CP-PoraBOND U

ID df Temp. Range 30 m
0.32 mm 10 µm -60 to 190 °C 227-36327-01
0.53 mm 20 µm -60 to 190 °C 227-36302-01

Peaks Ret. Time

Water and Ethanol in Acetone Methane 1.935
Water 2.063
Methanol 2.215
Ethanol 2.527
Acetone 2.723

Conditions
Column: SH-Q-BOND, 30 m, 0.53 mm ID,
20 μm (P/N: 221-75765-30)
Sample: 0.5% water and ethanol in
acetone
2.527
Inj. Vol.: 3 μL split (split ratio 11:1)
Inj. Temp: 250 °C
Carrier Gas: He, constant flow, linear velocity
28.7 cm/sec. @ 200 °C
Oven Temp: 200 °C, isothermal
Detector: TCD, 260 °C

1.935 2.215 2.723

min. 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 3.2 3.4

Trap columns for adhering dislodged particles from PLOT columns are also available.
Please refer to page 47.

44
Capillary Columns
Metal Columns

SH-MetalX-1

• Non-polar phase: Crossbond™ 100% dimethyl polysiloxane ■ SH-MetalX-1 Structure

• General-purpose columns for solvent impurities, PCB congeners (e.g.,
Aroclor mixes), gases, natural gas odorants, sulfur compounds, essential oils, CH 3
hydrocarbons, semivolatiles, pesticides, and oxygenates.
Si O
• Equivalent to USP G1, G2, G38 phases.
• 4.5" standard coil diameter.
CH 3
• Similar phases: DB-PS1, UAC-1
100%

ID df Temp. Range 15 m
0.25 mm 0.10 µm -60 to 360/430 °C 227-36318-01
0.28 mm 0.10 µm -60 to 360/430 °C 221-75734-15

SH-MetalX-1HT SimDist

• Nonpolar phase
• Lowest bleed for longest column lifetime.
• Reliably meets all ASTM D2887, D6352, D7169, D7213, and D7500 specifications.
• 100% dimethyl polysiloxane phase allows easy comparisons to historical data.
• Individually tested for guaranteed performance.
• 7" coil diameter.
• Similar phases: DB-HT SimDis ProSteel, CP-SimDist, UltiMetal, ZB-1X SimDist

ID df Temp. Range 5m
0.53 mm 0.10 µm -60 to 430/450 °C 227-36344-01

SH-MetalX-5

• Low-polarity phase: Crossbond™ 5% diphenyl / 95% dimethyl polysiloxane ■ SH-MetalX-5 Structure

• General-purpose columns for drugs, solvent impurities, pesticides,
hydrocarbons, PCB congeners (e.g., Aroclor mixes), essential oils, and CH 3
semivolatiles.
Si O Si O
• Equivalent to USP G27 and G36 phases.
• 4.5" standard coil diameter.
CH 3
• Similar phases: DB-PS5, VF-5ht UltiMetal
5% 95%

ID df Temp. Range 30 m
0.25 mm 0.25 µm -60 to 430 °C 221-75743-30

45
 Capillary Columns
Metal Columns

SH-MetalX-1701

• Midpolarity Crossbond™ phase ■ SH-MetalX-1701 Structure

• General-purpose columns for alcohols, oxygenates, PCB congeners (e.g., Aroclor
mixes), and pesticides.
• Equivalent to USP G46 phase.
• 4.5" standard coil diameter.
• Similar phase: DB-PS1701

ID df Temp. Range 15 m
0.53 mm 1.00 µm -20 to 260 °C 227-36336-01

SH-MetalX-WAX

• Polar phase; Crossbond ™ Carbowax polyethylene glycol—provides oxidation ■ SH-MetalX-WAX Structure

resistance
• General-purpose columns for FAMEs, flavor compounds, essential oils, amines,
solvents, xylene isomers, and U.S. EPA Method 603 (acrolein/acrylonitrile).
• Equivalent to USP G14, G15, G16, G20, and G39 phases.
• 4.5" standard coil diameter.

ID df Temp. Range 15 m
0.53 mm 1.00 µm 40 to 240/250 °C 227-36337-01

SH-MetalX Biodiesel TG

• Fast analysis times and sharp mono-, di-, and triglyceride peaks.
• Stable at 430 °C for reliable, consistent performance.
• Similar phase: MET-Biodiesel

ID df Temp. Range 14 m
0.53 mm 0.16 µm -60 to 380/430 °C 227-36315-01

Download more application data of GC/GCMS from

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46
Capillary Columns
Guard Columns

SH-I Guard / Retention Gap Columns

• Extend column lifetime.

• Excellent inertness—obtain lower detection limits for active compounds.
• Sharper chromatographic peaks by utilizing retention gap technology.
• Maximum temperature: 360 °C.

ID 5m 10 m
0.25 mm 227-36303-01 227-36304-01
0.32 mm 227-36305-01 227-36306-01
0.53 mm 227-36307-01 227-36308-01

SH-Particle Trap (for PLOT columns)

• Includes two Press-Tight® connectors and a 2.5 m column.

• Protects detector and valves; connects between column and detector or valve.
• Eliminates detector spikes and scratches in valve rotors.

* For information about Press-Tight® connectors, please refer to page 46.

Description P/N
SH-Particle Trap for 0.32 mmID PLOT Columns 227-36800-01
SH-Particle Trap for 0.53 mmID PLOT Columns 227-36800-02

47
 Capillary Columns
Guard Columns

SH-IP Guard Columns

• Tested with a comprehensive test mix to ensure high inertness.

• Useful for a wide range of applications.
• Use with most common solvents.
• Maximum temperature: 360 °C.

Description ID 5m 10 m
0.25 mm 227-36320-01 227-36321-03
SH-IP Guard Column 0.32 mm 227-36320-02 227-36321-04
0.53 mm 227-36320-03 227-36321-01

SH Guard Columns Polar Deactivation

• Polar polyethylene glycol deactivation

• Tested with a comprehensive test mix to ensure high inertness.
• Polyethylene glycol deactivation layer provides optimum wettability for polar compounds.
• Minimize peak splitting when using polar solvents such as methanol or water.
• Compatible with SH-PolarWax, SH-225 and SH-2330 capillary columns.
• Maximum temperature: 280 °C.

Description ID 5m
0.25 mm 227-36335-01
SH Guard Column Polar Deactivation 0.32 mm 227-36335-02
0.53 mm 227-36335-03

SH Guard Columns Base Deactivated

• Tested with a basic amine test mix.

• Excellent inertness for basic compounds.
• Recommended for use with SH-5 Amine, SH-35 Amine, SH-Volatile Amine, and SH-PolarX capillary columns.
• Batch test chromatogram included.
• Maximum temperature: 315 °C.

Chemists using guard columns in the analyses of basic compounds frequently observe peak tailing and low recovery. This
happens because conventionally deactivated tubing surfaces can be adsorptive to basic compounds. Shimadzu offers base-
deactivated guard columns, as well as base-deactivated inlet liners, for completely inert sample pathways.

Description ID 5m
0.25 mm 227-36334-01
SH Guard Column Base Deactivated 0.32 mm 227-36334-02
0.53 mm 227-36334-03

48
SH-MetalX-Siltek Guard Column

• Tested with a comprehensive test mix, to ensure high inertness.

• Revolutionary deactivation process for superior inertness.
• Analyze active samples accurately; ideal for chlorinated pesticide analysis (reduces endrin breakdown to less than 1%).
• Maximum temperature: 380 °C.

Description ID 10 m
SH-MetalX-Siltek Guard 0.53 mm 227-36319-01

Integrated Guard Columns

• No leaks for a more robust method.

• No column connections for easier, faster maintenance.
• No peak distortions due to connector dead volume and thermal capacity.

Integrated Analytical/
Guard Column

Continuous Tubing

Integrated Guard Liquid Phase

String indicates where the

analytical column begins

Column ID df Length With 2m Integrated Guard With 5m Integrated Guard With 10m Integrated Guard
SH-I-5Sil MS 0.25 mm 0.25 µm 30 m − 221-76161-30 221-76162-30
0.25 mm 0.25 µm 30 m − 221-75719-31 −
0.53 mm 1.00 µm 30 m − 221-75731-31 −
SH-I-1
0.53 mm 1.50 µm 30 m − 227-36333-01 −
0.53 mm 5.00 µm 30 m − 221-75734-31 −
0.25 mm 0.25 µm 30 m − 221-76153-05 221-76153-30
0.25 mm 1.00 µm 30 m − 221-76179-30 −
0.32 mm 0.25 µm 30 m − 221-76177-30 −
SH-5
0.32 mm 0.25 µm 60 m − 221-76177-60 −
0.32 mm 1.00 µm 30 m − 221-76180-30 −
0.53 mm 5.00 µm 30 m − 221-76154-35 −
0.25 mm 0.10 µm 30 m − 221-76189-30 −
0.25 mm 0.25 µm 15 m − 221-75861-15 −
SH-5MS
0.25 mm 0.25 µm 30 m − 221-75861-05 221-75861-10
0.32 mm 0.25 µm 30 m − 221-76190-30 −
SH-1301 0.53 mm 3.00 µm 30 m − 221-76164-35 −
0.25 mm 1.40 µm 30 m − 221-76183-30 −
SH-624 0.32 mm 1.80 µm 30 m − 221-76157-35 −
0.53 mm 3.00 µm 30 m − 221-76158-30 −
SH-1701 0.25 mm 0.25 µm 30 m − 221-76185-30 −
SH-1MS 0.25 mm 0.10 µm 15 m 227-36346-01 − −

49
 Capillary Columns
Accessories and Supplies

Connection Parts for Capillary Columns

Nuts and Ferrules

1 2 3 4

Diag. # Description Specification P/N

1 Nut with slit (5 pcs) Detector side of GC-2010/2010 Plus/2014/2025 221-32705-84
2 Nut without slit (10 pcs) Injection unit side of GC-2010/2010 Plus/2014/2025 221-16325-81
Nut without slit (5 pcs) For GCMS 670-11009
Graphite Ferrule 0.5 (10 pcs) For 0.1 - 0.32 mmID columns 221-32126-05
Graphite Ferrule 0.8 (10 pcs) For 0.53 mmID columns 221-32126-08
Graphite Vespel® Ferrule (10 pcs) For 0.1 - 0.25 mmID columns 670-15003-03
3 Graphite Vespel® Ferrule (10 pcs) For 0.32 mmID columns 670-15003-04
Graphite Vespel® Ferrule (10 pcs) For 0.53 mmID columns 670-15003-07
SilTite™ Metal Ferrule (10 pcs) For 0.1 - 0.25 mmID columns 221-72563-04
SilTite™ Metal Ferrule (10 pcs) For 0.32 mmID columns 221-72563-05
SilTite™ Metal Ferrule (10 pcs) For 0.53 mmID columns 221-72563-08
SilTite™ Metal Ferrule (10 pcs) For 1/32” ID columns 221-75200-04
4 SilTite™ Kit (10 pcs ferrules, 2 pcs nuts) For 0.1 - 0.25 mmID columns 221-75200
SilTite™ Kit (10 pcs ferrules, 2 pcs nuts) For 0.32 mmID columns 221-75200-01
SilTite™ Kit (10 pcs ferrules, 2 pcs nuts) For 0.53 mmID columns 221-75200-02
SilTite™ Kit (10 pcs ferrules, 2 pcs nuts) For 1/32” ID columns 221-75200-03
SilTite™ Nut (5 pcs) - 221-75186

Glass-Lined Stainless Steel Joint

This is a compact joint to connect capillary columns. The glass

lining minimizes the adsorption of sample components.
To ensure a positive connection, it is necessary to cut the ends
of capillary columns properly to match each other.

Applicable
Description Capillary OD P/N
(mm) Glass Lining
0.4 670-11424-11
Mini-union
0.5 670-11424-12
(with 5 pcs graphite ferrules)
0.8 670-11424-13
0.4 - 0.5 670-11424-21
Graphite Ferrule (10 pcs)
0.8 670-11424-22

50
Connection Parts for Capillary Columns
Press-Tight ™ Connectors

This connector is used to connect capillary columns easily by inserting

the columns into the connector from both ends. When the columns are
coated with polyimide resin, the connection will remain tight almost
permanently and will be completely free of leakage.
Applicable to 0.35 mm to 0.8 mmOD capillary columns.

Description P/N
Press-Tight™ Connector (5 pcs) 221-38102-91
Press-Tight™ Connector (5 pcs with 5 g polyimide resin) 221-38102-92

Main use of Press-Tight ™ connectors

• Connection of broken capillary columns
The connectors are unobtrusive.
• On-column sample injection
Any capillary columns can be used in on-column injection mode by connecting a short wide-bore capillary
columns to the inlet of the column.
• Retention gap method
An about 2 meters long capillary tube with no stationary phase, which is connected to the head of analytical
capillary column, prevents peaks from being split.
• Column conditioning
A short capillary tube, which is connected to the outlet of the column, prevents air (oxygen) from diffusing into
the column, thus preventing the deterioration of liquid phase which is kept at a high temperature.
• Stable storing of capillary columns
Deterioration by air and contamination can be prevented by connecting the both ends with a capillary tube.

51
 GC Columns Guidebook
Capillary Columns
Accessories and Supplies

Capillary Column Accessory Set

This set contains tools and supplies which are used to ensure high analytical productivity in capillary gas chromatography.

P/N 221-38652-91

The set includes:

• Graphite ferrules • Compact vise
• Nuts • Adapter Socket (MM-C)
• Soap film flow meter • Magnet grips
• Capillary tube cutter
• Spanner
• Tweezers
• Magnifying lens
• Ruler (stainless steel, 150mm)
• Accessory Box
• Pin vise
• Drill
• Press-Tight® connectors
• Polyimide resin

Capillary Tube Cutters

To cut a fused silica capillary tube, score the desired part with the above cutters, which have a ceramic blade, and snap at
the position.
The figure on the right shows an easy-to-use pen type. A spare blade is included.

Diag. # Description P/N

1

Capillary Tube Cutter (pen type with 1

1 221-50595-91
pc spare blade)
Capillary Tube Ceramic Cutter (3 pcs) 221-75181

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© Shimadzu Corporation, 2023 / First Edition: February 2016, 3655-12207-PDFIT, C184-E037D