; R. K. MALIK'S raitramanovs,neorca son, non kar NEWTON CLASSES Enjoys unparalleled reputation for best results in terms of percentage selection www.newtonclasses.net EUDIOMETRY |[R C MUKHERJEE SOLUTIONS] ° l CH3~ “CH +09 (excess) —* 3CO7+3H20 (Acetone) 40 ml (given). From the above balanced chemical equation +L ml of acetone will produce 3 ml of COz 40 ——————_ 40x3 = 120 mlof CO,(g) = 120 inl of CO; (g); Ans Q: Sol: SOQ; + Yo.-——> SOs 210 mi Since 1 ml of SO2 require Jmlof 0; 210 ———— 2 mlofO, If x is the volume of air required, Then xx21% = volume of oxygen (required) Volume of air= x 10 00m Ans Q3: Sol:- CaHlyo (2) + (+ Jo. + 400; (g) + 5HL0 Dit 1" method +. Lit of CsHio will produce 4 lit of CO2 (g) a 2x 4 lit = 8 lit of CO2 (g) Ans 2™ method 1 volume of CuH{o = 4 volume of CO.(g) 4x volume of CuHio = volume of CO (g) Office.: 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0661-2682623, 9635608812, 7546846949 NEWTONCLASSES.NETR. K. MALIK’S NEWTON CLASSES Volume of COs (g) = 4x2 lit=8 lit Ans Sol:- Hy (g)+ Ch(g) —>2HCl(g) Initially = 121it, 11.2 Lit 0 After reac-"(12-11.2)lit 0 2x 11.2 lit 0.8 lit 0 22.4 lit +. Vuicig) = 22.4 lit & VHb (g) = 0.8 lit Ans Qs: Sol:- CsHs (g) + (3+8}o: —> 3C0» + 4H:0 Propane (50:) Mass = 2.2 ¢ 3 Motes = 224 = 1 44g 20 Volume at NIP = a 22.4lit = 1.12 it . volume of C3Hs = 5 volume of O2 xvolume of C3Hs = 5x 1.12 lit =5.6 lit Ans Q6:- Sol:- Let the hydrocarbon gas is CxHy x . CxHy + (« +5, ]Os—>xC0, + Fo OS lit (excess istaken) 2.5lit 3 it 1 volume of C,Hy = volume of CO2 © Volume of CO; = X$volume of C,H, 2.5 lit=x x0.5 xX=5 Also 1 volume of C.Hy Y volume of Hx0 Volume of H,0 = Volumeof C,H, 3lit= Xx o.5tit 2 Y = 12. So hydrocarbon is CsH}. Ans Office.: 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2835608812, 7546845949, NEWTONCLA:EUDIOMETRY [R C MUKHERJEE SOLUTIONS] QT: Sol:- V(Hp + Or) = 0.02 lit H,+3.0,—+H,0 Let volume of Hp (g) in mixtur Op (g) «’. From balanced chemical equation 2H2(g) + O2(g) —> 2H20 (1) Initially x 0.02-x Finally 0 O.02-4)- 32 Y, hoor “ +: Finally only O; remained & if x lit of Hz consumed than ¥/) lit of O; will get cosumed. (0.02 x) - ys = 0.003 0.02 - = 0.003 2 % = 0.020.003 = 0.0171it x= 0.01333 lit cof Hh = oor 100 56.6% Ans % of Or = 43.3 % Ans Qs: Sol:- C,H, + (« +2)0,—sc0, +5H.0 Lami sof <1. volume of O; (required to react with CH,) =(xe3 potter, = (x03 }2-——@ 4 4 After reaction: Volume of 2 + volum’of CO» 2 mi fier passing over KOH, COp is absorbed Then volume of O (remained) = 8 ml -- 606 , 6 Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2662623, 9836608812, 7546846949 NEWTONCLA:R. K. MALIK’S NEWTON CLASSES Q) > {10-122} rxeae 50 — J2K —3y + Jak = 32 50 -3y =32 =~ 232 26 = 50-1 2) 3):- 50 12(x+2) 8 => 50-12x-3y=8 => 50-12x-18=8 = 12x=32-8 24 a5 Hydrocarbon is GH, Ans 2+ Volume of H,0 is not taken because the volume measured is below 100°C. However question doesn't specify it. CxHy + (« + xo, —>xco, +5H.0 ism Zo Volume of O; = 21% of volume of air = 215357=7497m 100 *, A/C to balanced chemical equation. 1s(x+ 4) =75 ext Yi =5 Volume of product(s) = 327 ml (at NTP), Z Volume of air (remained) + Volume of CO; = 327 ml 282-4 xx15=327 15x=45 X=3 + (=> x4 =5 wf 55-3=2 =y=8 ¢ Hydrocarbon is CxHy =CsHs Ans Q10 Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCLA:EUDIOMETRY [R C MUKHERJEE SOLUTIONS] Sol: CxHyOz + («+2 Je. > xCO2 + HO 0.9 gm 224 ml 1 =——moles 100 After the combustion Volume of O2 remained + volume of CO: = 560 yz oe _.& {s24-224(x42-2)] Gast ) Also volume after passing KOH = 112 ml ©. volume of CO> absorbed = 560 -112 = 448 ml 224 x ml = 448 mi x= 224 2 Also, 224-224 (2494-9, esas = 560 224 - 448 - 224 (4-%4)=12 224-224 (4-%)=112 Gu bey-a Also, Mo. Wt of C,H,Oz = 90 12x+Ixy+162=90 24+y+16Z=90 Y+16Z=66 —-—----(3) 27-y=<-(4) (3) + (4) = 18Z=72 g=- Pe 18 =8-6=2 2. Molecular formula = C2H;O, Ans Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 9636608812, 7546846949, NEWTONCLASS6 R. K. MALIK’S NEWTON CLASSES Qi Sol:-Let the gas is N,Oy (since it produces water & Nz with Hs, SO it must contains Nz & oxygen) YH, + N,O,—> ykhO + aN, l volume 1 volume—> 1 volume 1 volume The given volume of product directly implies that Y¥=1 & a1 => x=2 ‘Compound is NxOy = N20 Ans Let the molecular formula is CH, Cally + («+¥%Jo.— 100,44 .0. Sml (excess given = 30 ml) Volume of Or (required reacting with 5 ml of CxH,) = (x03 }sm 4 Aa, ‘Volume of O2 remained + volume of CO; = 25 20-5 (x+Y{)osn-2s 30 -Sx Lasx02s Ay BY _ =4 : =y Also volume of CO absorbed in CO» = 25 ~ 15 ml 5x=10 ml X=2. :. Molecular formula = C,H, = C:H, Ans Q13- Sol:- Let the formula of Ammonia is NH, x y Nally —>3Ns +31, 40 mi ‘Alq, final volume = 40 + 40 = 80 ml Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCLASSES.NETEUDIOMETRY [R C MUKHERJEE SOLUTIONS] x y ¥x40+%%40= 2402 40-80 X+y=4-(1) x N.Hy + £0, —+ EN, (e)+ 5H, 0(8) 40m! 40m Gases remained 40-x40 +40% =30 4 2 40 ~ 10y-+20x=30 ()dy33 ©. Molecular formula of ammonia = NxHy = NH; Ans Qua: Sol:- Let the molecular formula is HxSy Mol. wt = 34 XX1+ 32xy = 34 x+32xy = (1) H,S,(g)+Sn—> 5H, +SnS 20 ml w A/q, volume of H2 obtained = 20 ml 7 20=20 x=2 (1) dy=1 Molecular formula = HS. Qus: Sol: Let molecular formula of Ozone = Ox Let y ml of O> is taken from which zx converted to ozone xO, —> 20, Decrement in volum€= 40 ml (y-xz)+22=y-4 Office.: 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2662623, 9836608812, 7646846949 NEWTONCLASSR. K. MALIK’S NEWTON CLASSES XZ-22=4-(1) Turpentine absorbs O3 “. Volume yéimained = (Y - XZ)=y-4-8 XZ=12 (1) 9 12-22=4 2Z=8 Z=4 J XZ=12=> Xx4=12 >x=3 . Molecular formula O, = O3 Ans Let volume of Ozone = x lit Volume of oxygen = (1-x) lit At 0°C & 1 atm (NTP), molar volume = 22.4 lit Weofl lit= 15g &. Wr of 22.4 lit= 1.5 x22.4=33.6 g -: Mol wt of ozonised oxygen = 33.6 g 100 ml is reduced to 90 ml after passing over turpentine: +. volume of ozone absorbed = 10 mi -. 100 ml contain 10 ml of ozone 1000 ml 100 ml of ozone. 100 it =0.1tt 1000 *. Volume of ozone in 1 lit mix = 0.1 lit = -oxygen =~ 9 lit Mot wt = Mole%of ozone mol. jny +MOI%of 0, xM.Wos «Mol. = —— Ar 100 10K MW ne +9032 109 M.w of ozone = 48 g Ans 33.6= Let the molecular formula of S = Sx mole of Sx in 280 ml at NTP = —284. 22408 28 8 ,. cowt of Sx = WE OES 3003 3ex=3ah 18 Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCLASSEUDIOMETRY [R C MUKHERJEE SOLUTIONS] x= Zag 28 Molecular formula of sulphur=S3 Ans Qis Sol:- V(H.) = 1 lit V(O)= 1 lit 2H; + O)——> 2H,0()) Before react-" Lit 1 lit 0 After reac-" 0 1-Miit Lit Volume of O» remained = Yt Moles of O = =2- = na 48 1 . Weof Or= x 32g=0.7143 oa . Also moles of H2O produced from a molesof H, 1 Weproduced = x18 =0,8036, Pe Da « At 100°C, water becomes gas. +-Total volume of gases = 1+ 4 = 3 it “. Py=nRT I L 1), ooszix (asta) ones 7 on y= 30 mL Let volume of C:H; = x mL Volume of CO = (20-x) mL . 2), Ci b+ (249 0, —42C0, +H,0 4) 0° _- 06 , 6 Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2662623, 9836508812, 7546846949 NEWTONCR. K. MALIK’S NEWTON CLASSES + 30, +2004)+#,0 Sx X mole of CoH requires mLofO, C0+40,—+00, (20-x) mL of CO requires ( z 1" method *. Total no. of moles of O> which reacted with C>H2 & CO = 58, @2=*) (49g yml (30 mL is taken & 8 mL remained, So (30-8) mL. reacted) Sx+20-x=44 2+4x=44 4x =-20+44=24 xX=6 Or 2" method After the reaction, volume of CO, obtained + volume of O» = 34 After passing KOH, CO) get absorbed Alq, volume of CO; absorbed = 34-8 = 26 mL 2x + (20-x)=26 X=26-20=6 mL +. Volume of CH) = 6 mL. Ans Volume of CO=20-6=14 mL. Ans Q20:- V(N2 + NO) = 25 mL Let volume of Nz = x mL Volume of NO = (25 -x) mL Cu+NO—>Cu0 + 5 N.(g) (No is highly uncreative due to very strong triple bond It only (25-x) react with Mg, Li etc) Volume of N2 produced from NO gas = (25%) Volume of N2 present from before = x mL. Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCEUDIOMETRY [R C MUKHERJEE SOLUTIONS] 2x +25-x = 40 X=40-25=15 mL Volume of No =x = 15 mL 2: %ofN: =#2.x100= 60% 25 % of NO = 0 100= 40%. ° 25 Qa Sol:~ V(H2 + CHs + N2) = 40 mL VO» = 10 mL H; + 40, —>H,00) CH,+ (+4Jo, —+c0, +2H,00) Ni—+No reac-" Let volume of Ha =x mL Volume of CH, = y mL Volume of Na = {(40-(x+y)} On cooling the gas remained = COx(g) produced + No(g) + Op (remained) Al, ¥ +(40-(x+y)} + 10- {S423} 36.5 (with x mL of Hs, 9/4 mL of O, reacts & with y mL of CH, 2y mL of O> reacts) 40-x +10 4 -2y=36.5 2 will be absorbed. 110-(% +2y)= 34 10-4=hr2y 50-365 = .2y +4y-(3) Sohing (1) &Q) X=5 an +4y=27 Yu) Or from (2) & (3) X=5 ©. Volume of Hy = $ mL After passing over KOH, x Volume of NH, = 3 mL CO; will be absorbed VelunsdotN, = 32 mb, y=3m0 2) ‘olume of i mi After passing over pyrogallol, 2 Ye of CHy= > x100=7.5% 3x 50-*=2y =36.5 2 06 , 6 Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2662623, 9836508812, 7546846949 NEWTONCR. K. MALIK’S NEWTON CLASSES /jq*100=12.5% woth = F0 =80% Sol: V(H + CHy + CO + C,H, + non-combustible mixture) = 1000 lit Volume % of H = 50% => volume Hz = 500 lit Volume % of CH, = 35% =>volume CH, = 350 lit Volume % of CO => Volume CO = 80 lit Volume % of non-combustible mixture = $%=> volume = 50 lit Hy + Yo,—H.0 500 lit requires 250 lit of O> CH, +20; —>CO, +2H:0 350 lit requires 350%2 = 700 lit of O» co+ Yo,—2c0, 80 lit requires 802 = 160 lit of O» CHa + 30. — 2CO; + 2120 20 lit requires 60 lit of ‘Total volume of O2(required) 250 lit + 700 lit + 160 lit +60 lit =1170 lit +. Ifvolume of air = x lit ‘Then xx21% = 1170 1170x100 “2 =SS7Uit =5.57m’ Ans V(CO +H) = 38 ml Let volume of CO = x ml Volume of Hz = (38- x) mL €0+40,—+C0,(8) X mL of CO requires ¥ 4 mlof 0, & will produce x ml of CO, Hy + yy —H,0(1) 3 2 lq, Total volume after reaction = 29 ml ml of 0; & will produce (38-x) ml of HO (38-x) mL of Hz requires ( Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCEUDIOMETRY [R C MUKHERJEE SOLUTIONS] Volume of CO.(g) + Volume of O» remained = 29 mL {x7 382% S xa3I-fyt si}=29 & X+31-19=29 => X+12=29 =>x=17 :. Volume of CO = 17 mL Volume of Hz = 38 17= 21 ml 17, % of CO = —x100% = 44.7% OB %of H2= 2 croo% «ss 3% | Ans |:- P(CHy + CoH) = 63 mm of Hg PCO; obtained = 69 mm of Hg (in the same volume) (1) CHy + 202 ——+ CO» + 2H2O 2) Cath + (2+34)0,— +200, + H,0 Let moles of CH, =n; & due to this pressure P is exerted. &Moles of CoH. = m & due to this pressure P. is exerted ‘Then P; + P) = 63 mm of Hg — YD From equation (1) & (2) moles of CO; produced from CH. « Pressure exerted = Py moles of CO; produced from Pressure exerted = 2P) ‘Ag,Pi + 1P2 @-a) P;=6 mmof Hg P, =57 mm of Hg Fraction of methane = Sol:~ V(CO + CHy + Nz) = 20 mL. Let x ml of CO & y mL of CH, is present, Then 06 , 6 Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2662623, 9836508812, 7546846949 NEWTONCR. K. MALIK’S NEWTON CLASSES co+ Yo, — co, CH, +20; —> CO; +2H,0 +. Total moles of CO> produced =x + y= 14 () (Because volume reduction after KOH is passed is due to CO) absorption) Volume is reduced by 13 mL IfZ is the volume of O> taken. ‘Then Initial volume = 20 +Z. Final volume = (20 +Z)-13 Final volume = Veox + Vo; remained + VN 20+Z-13 .= tai) +Z-(Ex+2y)+20-(0+9) T=xty ~\x-2y+20-x-y () => x=10mL Volume of CO = x mi = 10 mL. Ans 3x42y=20-7=13 Volume of CHy=y mL =4 mL X+4y=26 -(2) @)-() 3y=12 y=4mL Let x mL is the volume of Hp present in mixture CuO + H+ Cu + H20 X mL — nmoles corresponding to x ml cu + Yo, —>cx0 n— mL moles will react with %, mL of O; under same condition of temp & pressure ~. Volume of O; remained 100 - (x+¥4)=84.5 34-185 > x="! 21033mL 3 ‘Ans Qz7: Sol:- SQ) + 30; —=4 430, given moles : 10 15 0 Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCEUDIOMETRY [R C MUKHERJEE SOLUTIONS] After reaction: 10-x 15-2 Aq, x= 8 moles :. moles of SO2 which doesn’t undergo reaction = 10-x= 10-8 =2 moles moles of 02 which doesn’t undergo reaction. Q28:- Sol:- Volume of O) = x mL. Volume of O3 (100-x) mL Since Os is absorbed by turpentine oil Volume of O3 = (100 —x) = 20 => x = 80 mL If the mixture is heated, O; will be decomposed os 30, gmt = 30 mL. ©. Total volume now, = 80 ml +30mL=110mL Ans Let the compound is CxHy Oz 2 Initially volume 2.5 volume Finally CxHyOz + (e Sa Jo. —>xC0, + Tuo Sothe compound is CxH,O. Ans Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph. 0861-2662623, 9636608812, 7546846949, NEWTONCLASSES.NET16 R. K. MALIK’S NEWTON CLASSES Q30:- Sol: moles of (Hz + O2 + Nz) = 5.22 10% moles Pressure (total) = 67.4 mm of Hg From the given data in the problem, it is clear that Hz is in excess amount than the amount consumed in reaction. Also let pressure due to Hy = X mm of Hg Pressure due to O2 = y mm of Hg Pressure due to No = 67.4 ~ (x+y) H 0, —>H,0() Initially xy ay Finally (x-2y) 0 From question, PHs(excess) + PNo= 14.3 mm ~() When oxygen is added, it consumes Hp, but then OQ) becomes in excess. Po cexcoay + PN, =14.3mm Q) Reaction implies that P(H, excess) = x-2y & PN: =67.4~ (x+y) (1) > x 2y + 67.4~(xty) = 143, 62.4 - 3y = 14.3 i. yea 43 SH =177 mm of Hg Also when 30 mm of Q; is added. H, + $0, —+H,0 Initially (x-2y) 30 Finally 0. 30-4 (x29) (2) PO,(cxcess) + PN2 = 32.9 mm Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCLASSES.NETEUDIOMETRY [R C MUKHERJEE SOLUTIONS] PN, = 67.4-(x+y) 67.4 - (43+ 17.7) = 6.7 mm of Hg mole fraction of Hy = PH: = 3 9.638 Ans 606 , 6 Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2662623, 9836608812, 7546846949