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SAFETY DATA SHEET
according to SS 586
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SDS # : 082936
HBF 3
Issuing date: 2015-06-30 Revision Date: 2016-11-01 Version 2
____________________________________________________________________________________________
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name HBF 3
Number 466
Substance/mixture Mixture
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Brake fluid.
1.3. Details of the supplier of the safety data sheet
Supplier TOTAL OIL ASIA PACIFIC PTE LTD
331 North Bridge Road
#23-01 Odeon Towers
Singapore 188720
Tel: +65 6879 2200
Fax: +65 6879 2203
For further information, please contact:
Contact Point HSE
E-mail Address
[email protected] 1.4. Emergency telephone number
CHEMTREC Singapore: 800-101-2201 (toll-free in country) or +65 3158 1349
International: CHEMTREC +1 703 527 3887 (collect calls accepted)
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
This product is not classified as hazardous according to Singapore Standard SS 586 on the Hazard Communication for Hazardous
Chemicals and Dangerous Goods
Label elements
This product is not classified as hazardous according to Singapore Standard SS 586 on the Hazard Communication for Hazardous
Chemicals and Dangerous Goods
Version SGPE
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SAFETY DATA SHEET
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SDS # : 082936
HBF 3
Issuing date: 2015-06-30 Revision Date: 2016-11-01 Version 2
____________________________________________________________________________________________
Other hazards which do not result in classification
Physical-Chemical Properties Contaminated surfaces will be extremely slippery.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No EC-No Weight %
ethanol, 2-butoxy-, manufacture of, 161907-77-3 310-287-7 10-<20
by-products from
2,2'-oxydiethanol 111-46-6 203-872-2 5-<10
Diethylene glycol monomethyl ether 111-77-3 203-906-6 1-<3
4. FIRST AID MEASURES
4.1. Description of first-aid measures
General advice IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR
EMERGENCY MEDICAL CARE.
Eye contact Rinse thoroughly with plenty of water, also under the eyelids.
Skin contact Remove contaminated clothing and shoes. Wash off with soap and water. Wash
contaminated clothing before reuse.
Inhalation Move to fresh air.
Ingestion Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a
physician or Poison Control Center immediately.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact Not classified.
Eye contact Not classified.
Inhalation Not classified. Inhalation of vapors in high concentration may cause irritation of respiratory
system.
Ingestion Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhea.
4.3. Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician Treat symptomatically.
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SAFETY DATA SHEET
according to SS 586
____________________________________________________________________________________________
SDS # : 082936
HBF 3
Issuing date: 2015-06-30 Revision Date: 2016-11-01 Version 2
____________________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
5.1. Extinguishing media
Suitable Extinguishing Media Carbon dioxide (CO 2). ABC powder. Foam. Water spray or fog.
Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire.
5.2. Special hazards arising from the substance or mixture
Special Hazard Incomplete combustion and thermolysis may produce gases of varying toxicity such as
carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may
be highly dangerous if inhaled in confined spaces or at high concentration.
5.3. Advice for fire-fighters
Special protective equipment for Wear self-contained breathing apparatus and protective suit.
fire-fighters
Other information Cool containers / tanks with water spray. Fire residues and contaminated fire extinguishing
water must be disposed of in accordance with local regulations.
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
General Information Do not touch or walk through spilled material. Contaminated surfaces will be extremely
slippery. Use personal protective equipment. Ensure adequate ventilation. Remove all
sources of ignition.
6.2. Environmental precautions
General Information Do not allow material to contaminate ground water system. Try to prevent the material from
entering drains or water courses. Local authorities should be advised if significant spillages
cannot be contained.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Dam up. Contain spillage, and then collect with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according
to local / national regulations (see section 13). Keep in suitable, closed containers for
disposal.
6.4. Reference to other sections
Personal Protective Equipment See Section 8 for more detail.
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SAFETY DATA SHEET
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SDS # : 082936
HBF 3
Issuing date: 2015-06-30 Revision Date: 2016-11-01 Version 2
____________________________________________________________________________________________
Waste treatment See section 13.
Other information Not applicable.
7. HANDLING AND STORAGE
7.1. Precautions for safe handling
Advice on safe handling When using, do not eat, drink or smoke. For personal protection see section 8. Use only in
well-ventilated areas. Do not breathe vapors or spray mist. Avoid contact with skin, eyes
and clothing.
Prevention of fire and explosion Take precautionary measures against static discharges: Ground/bond containers, tanks
and transfer/receiving equipment.
Hygiene measures Ensure the application of strict rules of hygiene by the personnel exposed to the risk of
contact with the product. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and at the end of workday. Do not use
abrasives, solvents or fuels. Do not dry hands with rags that have been contaminated with
product. Do not put product contaminated rags into workwear pockets.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures/Storage Keep away from food, drink and animal feedingstuffs. Keep in a bunded area. Keep
conditions container tightly closed. Keep preferably in the original container. Otherwise reproduce all
indication of the regulation label on the new container. Do not remove the hazard labels of
the containers (even if they are empty). Design the installations in order to avoid accidental
emissions of product (due to seal breakage, for example) onto hot casings or electrical
contacts. Protect from frost, heat and sunlight. Protect from moisture.
Materials to Avoid Strong oxidizing agents. Strong acids. Strong bases.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Exposure limits Contains no substances with occupational exposure limit values.
Legend See section 16
8.2. Exposure controls
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SAFETY DATA SHEET
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SDS # : 082936
HBF 3
Issuing date: 2015-06-30 Revision Date: 2016-11-01 Version 2
____________________________________________________________________________________________
Occupational Exposure Controls
Engineering Measures Apply technical measures to comply with the occupational exposure limits. When working in
confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for
breathing and wear the recommended equipment.
Personal Protective Equipment
General Information If the product is used in mixtures, it is recommended that you contact the appropriate
protective equipment suppliers. These recommendations apply to the product as supplied.
Respiratory protection None under normal use conditions. When workers are facing concentrations above the
exposure limit they must use appropriate certified respirators. Respirator with combination
filter for vapour/particulate (EN 14387). The use of breathing apparatus must comply strictly
with the manufacturer's instructions and the regulations governing their choices and uses.
Eye Protection If splashes are likely to occur, wear:. Safety glasses with side-shields.
Skin and body protection Wear suitable protective clothing. Protective shoes or boots. Long sleeved clothing.
Hand Protection Impervious gloves: Nitrile rubber, Neoprene gloves. Polyvinylchloride. Please observe the
instructions regarding permeability and breakthrough time which are provided by the
supplier of the gloves. Also take into consideration the specific local conditions under which
the product is used, such as the danger of cuts, abrasion, and the contact time. If used in
solution, or mixed with other substances, and under conditions which differ from EN 374,
contact the supplier of the EC approved gloves.
Environmental exposure controls
General Information The product should not be allowed to enter drains, water courses or the soil.
9. PHYSICAL AND CHEMICAL PROPERTIES
General Information
Color light yellow
Physical State @20°C liquid
Odor Characteristic
Odor Threshold No information available
Important health safety and environmental information
Property Values Remarks Method
pH 7.5 - 10 @ 20 °C FMVSS 116
Melting point/range No information available
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SAFETY DATA SHEET
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SDS # : 082936
HBF 3
Issuing date: 2015-06-30 Revision Date: 2016-11-01 Version 2
____________________________________________________________________________________________
Boiling point/boiling range > 245 °C @ 0.001033 bar FMVSS 116
> 473 °F FMVSS 116
Flash point >= 130 °C ASTM D7094
>= 266 °F ASTM D7094.
Evaporation rate No information available
Flammability Limits in Air No information available
Vapor Pressure < 10 mbar @ 20 °C
Vapor density No information available
Relative density 1.04 - 1.07 @ 20 °C DIN 51757
Density 1040 - 1070 kg/m3 @ 20 °C DIN 51757
Water solubility soluble
Solubility in other solvents Fats
logPow No information available
Autoignition temperature No information available
Decomposition temperature No information available
Viscosity, kinematic 14.5 - 17 mm2/s @ 20 °C FMVSS 116
Explosive properties Not explosive
Oxidizing Properties Not applicable
Possibility of hazardous reactions None under normal processing
Other information
Freezing Point No information available
10. STABILITY AND REACTIVITY
10.1. Reactivity
General Information No dangerous reaction known under conditions of normal use.
10.2. Chemical stability
Stability Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous Reactions None under normal processing.
10.4. Conditions to Avoid
Conditions to Avoid Heat (temperatures above flash point), sparks, ignition points, flames, static electricity.
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SAFETY DATA SHEET
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SDS # : 082936
HBF 3
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____________________________________________________________________________________________
10.5. Incompatible materials
Materials to Avoid Strong oxidizing agents. Strong acids. Strong bases.
10.6. Hazardous Decomposition Products
Hazardous Decomposition Products Incomplete combustion and thermolysis may produce gases of varying toxicity such as
carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot.
11. TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Information on likely routes of exposure
Skin contact Not classified.
Eye contact Not classified.
Inhalation Not classified. Inhalation of vapors in high concentration may cause irritation of respiratory
system.
Ingestion Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhea.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Acute toxicity - Product Information
Oral Not classified.
ATEmix (oral) > 2000 mg/kg
Dermal Not classified.
ATEmix (dermal) 12,787.00 mg/kg
Inhalation Not classified.
ATEmix (inhalation-dust/mist) 25.60 mg/l
ATEmix (inhalation-vapor) 88.10 mg/l
Acute toxicity - Component Information
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
ethanol, 2-butoxy-, manufacture of, LD50 2630 mg/kg bw (rat-OECD LD50 3540 mg/kg bw (rabbit -
by-products from 401) OECD 402)
161907-77-3
2,2'-oxydiethanol LD50 13300 mg/kg bw (rabbit) LC50 (4h) > 4.6 mg/l (rat - aerosol)
111-46-6
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SDS # : 082936
HBF 3
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Diethylene glycol monomethyl ether = 4 mL/kg ( Rat ) = 2500 µL/kg ( Rabbit )
111-77-3
Skin corrosion/irritation Not classified.
Serious eye damage/eye irritation Not classified. The supplier of some components contained within this formulation has
indicated that the classification as irritant is not required.
Sensitization Not classified as a sensitizer.
Germ Cell Mutagenicity This product is not classified as mutagenic.
Carcinogenicity This product is not classified carcinogenic.
Reproductive toxicity Not classified. Contains a known or suspected reproductive toxin.
Chemical Name European Union
Diethylene glycol monomethyl ether Repr. 2 (H361d)
111-77-3
STOT-single exposure Not classified.
STOT - repeated exposure Not classified.
Aspiration Hazard Not classified.
Other adverse effects Characteristic skin lesions (pimples) may develop following prolonged and repeated
exposures (contact with contaminated clothing).
12. ECOLOGICAL INFORMATION
12.1. Toxicity
Not Classified.
Acute aquatic toxicity - Product Information
No information available.
Acute aquatic toxicity - Component Information
Chemical Name Toxicity to algae Toxicity to daphnia and Toxicity to fish Toxicity to
other aquatic invertebrates microorganisms
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SAFETY DATA SHEET
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SDS # : 082936
HBF 3
Issuing date: 2015-06-30 Revision Date: 2016-11-01 Version 2
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ethanol, 2-butoxy-, EC50 (48h) > 1054 mg/l EC50 (24h) > 3200 mg/l LC0 (24h) > 1800 mg/l
manufacture of, by-products (Scenedesmus (Daphnia magna - OECD (Scophthalmus maximus -
from capricornutum - OECD 201) 202) OECD 203)
161907-77-3 EC50 (48h) 1686 mg/l EC50 (48h) > 3200 mg/l LC50 (48h) > 1800 mg/l
(Scenedesmus (Daphnia magna - OECD (Scophthalmus maximus -
capricornutum - OECD 201) 202) OECD 203)
EC50 (72h) 1075 mg/l LC50 (72h) > 1800 mg/l
(Scenedesmus (Scophthalmus maximus -
capricornutum - OECD 201) OECD 203)
EC50 (72h) 2490 mg/l LC50 (96h) > 1800 mg/l
(Scenedesmus (Scophthalmus maximus -
capricornutum - OECD 201) OECD 203)
LC0 (96h) > 1000 mg/l
(Scophthalmus maximus -
OECD 203)
2,2'-oxydiethanol EC50 (96h) 9362 mg/l EC100 (24h) >10000 mg/l LC50 (96h) 75200 mg/l
111-46-6 (green algae) (Daphnia magna) (Pimephales promelas)
EC50 (24h) >10000 mg/l
(Daphnia magna)
Diethylene glycol EC50 (72h) > 500 mg/L EC50 (48h) > 500 mg/L LC50 (96h) = 7500 mg/L EC50 > 10000 mg/L 17 h
monomethyl ether Desmodesmus subspicatus Daphnia magna Lepomis macrochirus (static)
111-77-3 LC50 (96h) = 7500 mg/L
Lepomis macrochirus ()
LC50 (96h) = 5741 mg/L
Pimephales promelas ()
Chronic aquatic toxicity - Product Information
No information available.
Chronic aquatic toxicity - Component Information
.
Chemical Name Toxicity to algae Toxicity to daphnia and Toxicity to fish Toxicity to
other aquatic invertebrates microorganisms
ethanol, 2-butoxy-, NOEC (48h) > 1800 mg/l
manufacture of, by-products (Daphnia magna - OECD
from 202)
161907-77-3
Effects on terrestrial organisms
No information available.
12.2. Persistence and degradability
General Information Readily biodegradable ( >90 % after 5 days).
12.3. Bioaccumulative potential
Product Information No information available.
logPow No information available
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SAFETY DATA SHEET
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SDS # : 082936
HBF 3
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____________________________________________________________________________________________
Component Information .
Chemical Name log Pow
Diethylene glycol monomethyl ether - 111-77-3 0
12.4. Mobility in soil
Soil No information available.
Water Will likely be mobile in the environment due to its water solubilty.
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment No information available.
12.6. Other adverse effects
General Information No information available.
13. DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Methods Should not be released into the environment. Do not empty into drains. Dispose of in
accordance with all applicable national environmental laws and regulations.
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Disposal Precautions Refer to section 8 for safety and protective measures for disposal personnel.
14. TRANSPORT INFORMATION
ADR/RID Not regulated
IMDG/IMO Not regulated
ICAO/IATA Not regulated
15. REGULATORY INFORMATION
National regulatory information
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SDS # : 082936
HBF 3
Issuing date: 2015-06-30 Revision Date: 2016-11-01 Version 2
____________________________________________________________________________________________
Singapore
Applicable National Regulation:
Workplace Safety and Health (General Provision) Regulations
16. OTHER INFORMATION
Abbreviations, acronyms
ACGIH = American Conference of Governmental Industrial Hygienists
bw = body weight
bw/day = body weight/day
EC x = Effect Concentration associated with x% response
GLP = Good Laboratory Practice
IARC = International Agency for Research of Cancer
LC50 = 50% Lethal concentration - Concentration of a chemical in air or a chemical in water which causes the death of 50% (one
half) of a group of test animals
LD50 = 50% Lethal Dose - Chemical amount, given at once, which causes the death of 50% (one half) of a group of test animals
LL = Lethal Loading
NIOSH = National Institute of Occupational Safety and Health
NOAEL = No Observed Adverse Effect Level
NOEC = No Observed Effect Concentration
NOEL = No Observed Effect Level
OECD = Organization for Economic Co-operation and Development
OSHA = Occupational Safety and Health Administration
UVCB = Substance of unknown or Variable composition, Complex reaction products or Biological material
Legend Section 8
TWA: Time Weight Average
STEL: Short Time Exposure Limit
PEL: Permissible exposure limit
REL: Recommended exposure limit
TLV: Threshold Limit Values
+ Sensitizer * Skin designation
** Hazard Designation C: Carcinogen
M: Mutagen R: Toxic to reproduction
Revision Date: 2016-11-01
Revision Note *** Indicates updated section.
____________________________________________________________________________________________
This safety data sheet serves to complete but not to replace the technical product sheets. The information contained
herein is given in good faith and is accurate to the best of knowledge at the date indicated above.It is understood by the
user that any use of the product for purposes other than those for which it was designed entails potential risk.The
information given herein in no way dispenses the user from knowing and applying all provisions regulating his
activity.The user bears sole liability for the precautions required when using the product.The regulatory texts indicated
herein are intended to aid the user to fulfil his obligations. This list is not to be considered complete and exhaustive.It is
the user's responsibility to ensure that he is subject to no other obligations than those mentioned.
End of the Safety Data Sheet
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