SAFETY DATA SHEET

Sika MultiPrimer Marine

Version Revision Date: SDS Number: Date of last issue: 2021/08/09

5.0 2022/05/24 000000035557 Date of first issue: 2017/11/15

Section 1: Identification

Product name : Sika MultiPrimer Marine

Product code : 000000035557

Manufacturer or supplier's details
Company : Sika (NZ) Ltd.
85-91 Patiki Road
Avondale
Auckland AKL 1026
Telephone : +64 9 820 2900
Emergency telephone num- : 0800 734 607
ber
Telefax : +64 9 828 4091
E-mail address : info@[Link]
Recommended use of the chemical and restrictions on use
Product use : Pretreatment agent

Section 2: Hazard identification

GHS Classification
Flammable Liquids : 3.1B

Acute toxicity (Oral) : 6.1E

Acute toxicity (Inhalation) : 6.1E

Skin irritation : 6.3B

Eye irritation : 6.4A

Skin sensitisation : 6.5B

Toxic to Reproduction : 6.8A

Specific Target Organ Toxicity : 6.9B

(Inhalation)

Aquatic toxicity (Acute or : 9.1C

Chronic)

GHS label elements

Hazard pictograms :

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SAFETY DATA SHEET

Sika MultiPrimer Marine

Version Revision Date: SDS Number: Date of last issue: 2021/08/09

5.0 2022/05/24 000000035557 Date of first issue: 2017/11/15

Signal word : Danger

Hazard statements : H225 Highly flammable liquid and vapour.

H303 May be harmful if swallowed.
H316 Causes mild skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H333 May be harmful if inhaled.
H360FD May damage fertility. May damage the unborn child.
H371 May cause damage to organs if inhaled.
H373 May cause damage to organs through prolonged or re-
peated exposure if inhaled.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements :
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/ sparks/ open flames/ hot surfaces.
No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting equip-
ment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe mist or vapours.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P304 + P312 IF INHALED: Call a POISON CENTER or doctor/
physician if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P309 + P311 IF exposed or if you feel unwell: Call a POISON
CENTER or doctor/ physician.
P321 Specific treatment (see supplemental first aid instructions
on this label).
P333 + P313 If skin irritation or rash occurs: Get medical ad-
vice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ at-

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SAFETY DATA SHEET

Sika MultiPrimer Marine

Version Revision Date: SDS Number: Date of last issue: 2021/08/09

5.0 2022/05/24 000000035557 Date of first issue: 2017/11/15

tention.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam for extinction.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification

None known.

Section 3: Composition/information on ingredients

Substance / Mixture : Mixture

Components
Chemical name CAS-No. Concentration (% w/w)
ethyl acetate 141-78-6 >= 50 -< 70
xylene 1330-20-7 >= 2.5 -< 10
dibutyltin dilaurate 77-58-7 >= 0.25 -< 1

Section 4: First-aid measures

General advice : Move out of dangerous area.

Consult a physician.
Show this safety data sheet to the doctor in attendance.

If inhaled : Move to fresh air.

Consult a physician after significant exposure.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.

In case of eye contact : Immediately flush eye(s) with plenty of water.

Remove contact lenses.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.

Most important symptoms : irritant effects

and effects, both acute and Excessive lachrymation
delayed Loss of balance
Vertigo
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SAFETY DATA SHEET

Sika MultiPrimer Marine

Version Revision Date: SDS Number: Date of last issue: 2021/08/09

5.0 2022/05/24 000000035557 Date of first issue: 2017/11/15

See Section 11 for more detailed information on health effects

and symptoms.
May be harmful if swallowed or if inhaled.
Causes mild skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
May damage fertility. May damage the unborn child.
May cause damage to organs if inhaled.
May cause damage to organs through prolonged or repeated
exposure if inhaled.

Notes to physician : Treat symptomatically.

Section 5: Fire-fighting measures

Suitable extinguishing media : Alcohol-resistant foam

Carbon dioxide (CO2)
Dry chemical

Unsuitable extinguishing : Water

media High volume water jet

Specific hazards during fire- : Do not use a solid water stream as it may scatter and spread
fighting fire.

Hazardous combustion prod- : No hazardous combustion products are known

ucts

Specific extinguishing meth- : Use water spray to cool unopened containers.

ods

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

Hazchem Code : 3YE

Section 6: Accidental release measures

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Remove all sources of ignition.
gency procedures Deny access to unprotected persons.

Environmental precautions : Prevent product from entering drains.

If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for : Contain spillage, and then collect with non-combustible ab-
containment and cleaning up sorbent material, (e.g. sand, earth, diatomaceous earth, ver-
miculite) and place in container for disposal according to local
/ national regulations (see section 13).

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SAFETY DATA SHEET

Sika MultiPrimer Marine

Version Revision Date: SDS Number: Date of last issue: 2021/08/09

5.0 2022/05/24 000000035557 Date of first issue: 2017/11/15

Section 7: Handling and storage

Advice on protection against : Use explosion-proof equipment.

fire and explosion Keep away from heat/ sparks/ open flames/ hot surfaces. No
smoking.
Take precautionary measures against electrostatic discharg-
es.

Advice on safe handling : Do not breathe vapours or spray mist.

Avoid exceeding the given occupational exposure limits (see
section 8).
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Take precautionary measures against static discharge.
Open drum carefully as content may be under pressure.
Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapours).
Follow standard hygiene measures when handling chemical
products

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

Conditions for safe storage : Store in original container.

Store in cool place.
Keep in a well-ventilated place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Store in accordance with local regulations.

Section 8: Exposure controls/personal protection

Components with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
ethyl acetate 141-78-6 WES-TWA 200 ppm NZ OEL
720 mg/m3
xylene 1330-20-7 WES-TWA 50 ppm NZ OEL
217 mg/m3
Biological occupational exposure limits
Components CAS-No. Control Biological Sampling Permissible Basis
parameters specimen time concentration
xylene 1330-20-7 Methylhip- Urine End of 1.5 g/l NZ BEI
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SAFETY DATA SHEET

Sika MultiPrimer Marine

Version Revision Date: SDS Number: Date of last issue: 2021/08/09

5.0 2022/05/24 000000035557 Date of first issue: 2017/11/15

puric acid shift

Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
The filter class for the respirator must be suitable for the max-
imum expected contaminant concentration
(gas/vapour/aerosol/particulates) that may arise when han-
dling the product. If this concentration is exceeded, self-
contained breathing apparatus must be used.

Hand protection : Chemical-resistant, impervious gloves complying with an

approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is nec-
essary.

Eye protection : Safety eyewear complying with an approved standard should

be used when a risk assessment indicates this is necessary.

Skin and body protection : Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.

Section 9: Physical and chemical properties

Appearance : liquid

Colour : colourless

Odour : hydrocarbon-like

Odour Threshold : No data available

pH : Not applicable substance/mixture is non-soluble (in water)

Melting point/range / Freezing : No data available

point
Boiling point/boiling range : > 70 °C (158 °F)

Flash point : ca. -4 °C (25 °F)

(Method: closed cup)

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Flammability (liquids) : Not applicable

Upper explosion limit / Upper : 7 %(V)

flammability limit

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SAFETY DATA SHEET

Sika MultiPrimer Marine

Version Revision Date: SDS Number: Date of last issue: 2021/08/09

5.0 2022/05/24 000000035557 Date of first issue: 2017/11/15

Lower explosion limit / Lower : 1 %(V)

flammability limit

Vapour pressure : 99.9915 hPa

Relative vapour density : No data available

Density : ca. 0.98 g/cm3 (20 °C (68 °F))

Solubility(ies)
Water solubility : insoluble

Solubility in other solvents : No data available

Partition coefficient: n- : No data available

octanol/water
Auto-ignition temperature : 427 °C

427 °C

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : ca. 10 - 20 mPa.s (20 °C (68 °F))

Viscosity, kinematic : < 20.5 mm2/s ( 40 °C (104 °F))

Explosive properties : No data available

Oxidizing properties : No data available

Volatile organic compounds : Directive 2010/75/EU of 24 November 2010 on industrial

emissions (integrated pollution prevention and control)
Volatile organic compounds (VOC) content: 66.61% w/w

Section 10: Stability and reactivity

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : The product is chemically stable.

Possibility of hazardous reac- : Stable under recommended storage conditions.

tions Vapours may form explosive mixture with air.

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : Peroxides

Strong acids and oxidizing agents
Bases

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SAFETY DATA SHEET

Sika MultiPrimer Marine

Version Revision Date: SDS Number: Date of last issue: 2021/08/09

5.0 2022/05/24 000000035557 Date of first issue: 2017/11/15

Section 11: Toxicological information

Acute toxicity
May be harmful if swallowed or if inhaled.
Components:
ethyl acetate:
Acute oral toxicity : LD50 Oral (Rat): > 5,000 mg/kg

Acute inhalation toxicity : LC50 (Rat): ca. 1,600 mg/l

Exposure time: 4 h
Test atmosphere: vapour

Acute dermal toxicity : LD50 Dermal (Rabbit): > 5,000 mg/kg

xylene:
Acute oral toxicity : LD50 Oral (Rat): 3,523 mg/kg

Acute dermal toxicity : LD50 Dermal (Rabbit): 1,700 mg/kg

dibutyltin dilaurate:
Acute oral toxicity : LD50 Oral (Rat): 2,071 mg/kg

Skin corrosion/irritation
Causes mild skin irritation.
Serious eye damage/eye irritation
Causes serious eye irritation.
Respiratory or skin sensitisation

Skin sensitisation
May cause an allergic skin reaction.
Respiratory sensitisation
Not classified based on available information.

Chronic toxicity

Germ cell mutagenicity

Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
May damage fertility. May damage the unborn child.
STOT - single exposure
May cause damage to organs if inhaled.

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SAFETY DATA SHEET

Sika MultiPrimer Marine

Version Revision Date: SDS Number: Date of last issue: 2021/08/09

5.0 2022/05/24 000000035557 Date of first issue: 2017/11/15

STOT - repeated exposure

May cause damage to organs through prolonged or repeated exposure if inhaled.
Aspiration toxicity
Not classified based on available information.

Section 12: Ecological information

Ecotoxicity

Components:
xylene:
Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (green algae)): 2.2
plants mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

Toxicity to fish (Chronic tox- : NOEC (Oncorhynchus mykiss (rainbow trout)): > 1.3 mg/l
icity) Exposure time: 56 d

Toxicity to daphnia and other : NOEC (Daphnia (water flea)): 1.17 mg/l
aquatic invertebrates (Chron- Exposure time: 7 d
ic toxicity)
dibutyltin dilaurate:
Toxicity to fish : LC50 (Fish): 3.1 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia (water flea)): 1 mg/l

aquatic invertebrates Exposure time: 48 h

Toxicity to algae/aquatic : EC50 (Selenastrum capricornutum (green algae)): 1 - 10 mg/l

plants Exposure time: 72 h

M-Factor (Acute aquatic tox- : 1

icity)
M-Factor (Chronic aquatic : 1
toxicity)
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : An environmental hazard cannot be excluded in the event of
mation unprofessional handling or disposal.
Harmful to aquatic life with long lasting effects.

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SAFETY DATA SHEET

Sika MultiPrimer Marine

Version Revision Date: SDS Number: Date of last issue: 2021/08/09

5.0 2022/05/24 000000035557 Date of first issue: 2017/11/15

Section 13: Disposal considerations

Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with chemi-
cal or used container.
Send to a licensed waste management company.

Contaminated packaging : Empty remaining contents.

Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

Section 14: Transport information

International Regulations

IATA-DGR
UN/ID No. : UN 1866
Proper shipping name : Resin solution
Class : 3
Packing group : II
Labels : Flammable Liquids
Packing instruction (cargo : 364
aircraft)
Packing instruction (passen- : 353
ger aircraft)
IMDG-Code
UN number : UN 1866
Proper shipping name : RESIN SOLUTION
Class : 3
Packing group : II
Labels : 3
EmS Code : F-E, S-E
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations

NZS 5433
UN number : UN 1866
Proper shipping name : RESIN SOLUTION
Class : 3
Packing group : II
Labels : 3

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SAFETY DATA SHEET

Sika MultiPrimer Marine

Version Revision Date: SDS Number: Date of last issue: 2021/08/09

5.0 2022/05/24 000000035557 Date of first issue: 2017/11/15

Hazchem Code : 3YE

Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely based
upon the properties of the unpackaged material as it is described within this Safety Data Sheet.
Transportation classifications may vary by mode of transportation, package sizes, and variations in
regional or country regulations.

Section 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture
International Chemical Weapons Convention (CWC) : Not applicable
Schedules of Toxic Chemicals and Precursors
HSNO Approval Number
HSR002662
HSW Controls
Certified handler certificate not required.
Tracking hazardous substance not required.
Refer to the Health and Safety at Work (Hazardous Substances) Regulations 2017, for further infor-
mation.

The components of this product are reported in the following inventories:

NZIoC : On the inventory, or in compliance with the inventory

Section 16: Other information

Full text of other abbreviations

NZ BEI : New Zealand. Biological Exposure Indices
NZ OEL : New Zealand. Workplace Exposure Standards for Atmospher-
ic Contaminants
NZ OEL / WES-TWA : Workplace Exposure Standard - Time Weighted average
ADG : Australian Dangerous Goods Code.
ADR : European Agreement concerning the International Carriage of
Dangerous Goods by Road
CAS : Chemical Abstracts Service
DNEL : Derived no-effect level
EC50 : Half maximal effective concentration
GHS : Globally Harmonized System
IATA : International Air Transport Association
IMDG : International Maritime Code for Dangerous Goods
LD50 : Median lethal dosis (the amount of a material, given all at
once, which causes the death of 50% (one half) of a group of
test animals)
LC50 : Median lethal concentration (concentrations of the chemical in
air that kills 50% of the test animals during the observation
period)
MARPOL : International Convention for the Prevention of Pollution from
Ships, 1973 as modified by the Protocol of 1978

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SAFETY DATA SHEET

Sika MultiPrimer Marine

Version Revision Date: SDS Number: Date of last issue: 2021/08/09

5.0 2022/05/24 000000035557 Date of first issue: 2017/11/15

OEL : Occupational Exposure Limit

PBT : Persistent, bioaccumulative and toxic
PNEC : Predicted no effect concentration
REACH : Regulation (EC) No 1907/2006 of the European Parliament
and of the Council of 18 December 2006 concerning the Reg-
istration, Evaluation, Authorisation and Restriction of Chemi-
cals (REACH), establishing a European Chemicals Agency
SVHC : Substances of Very High Concern
vPvB : Very persistent and very bioaccumulative

The information contained in this Safety Data Sheet corresponds to our level of knowledge at the
time of publication. All warranties are excluded. Our most current General Sales Conditions shall
apply. Please consult the product data sheet prior to any use and processing.

Changes as compared to previous version !

NZ / EN

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