Problem set # 12 ‘Chemistry 200 Thermodynamics Name: 1, Automobile airbags solid azide, NaNs, that reacts to produce nitrogen 2NaNa(s) — 2Na(s) + 3No(g) Calculate the value of work, w, for the following system if 39.1 g of NaNs reacts completely at 1.20 atm and 24°C. W=- RSV V met wan B94 Mans x coed = 0.6 02 mel Van, 0+ 602 mel Nang x —S eve Deel wow PVEMRT my 120 tmx Vy, = 0-903mel x 082 SERE y 297K = Vvzigl = 0-903 med Mr . 3235 ee 2-1 a HUG atm Lb x ONE? 5.918855 2-2190 We ~%, AV = -)2eate x (18-04) = nana 3 y 2. 25.1 g sample of methanol, CH3OH, was combusted in the presence of excess oxygen in a ‘bomb calorimeter conaining 3600 g of water. The temperature of the water increased from 25°C to 65°C. The heat capacity of the calorimeter was 2657 J/°C. The specific heat of water is 4.184 Wg°C. Calculate the intemal energy change (AU) for the reaction in kI/mol. Heat gainesl by Water = MxCpxAT= B6ooyx 4.184 x (652-252) 2 C0245 3 se = boo Ky Heat gaineh by calenimeter = Cx OT = 265Fy x (656-252) = 062807 enous Total heat evelved = books + Noks eFloky 25.14 CHyon x peseicew = 0.784 aos ao Hees, = tees 906 Mt Aue = woe HS, oa 3. Calculate the molar heat capacity of copper given that 204.75 J of energy raises the temperature of 15g of copper from 25° t0 60°C. VS 5 cor ye NSH = 0.24 mel Cu BE RCH Fan KAT a> 204.755 = 124 mol x Cp x (60 b= 25e) = a ee as Dr. Behrang Madani Chem 200 We4. A piston confines 0.36 mol Na(g) in 2.3L at 25°C. Two experiments are performed. (a) The gas is allowed to expand through an additional 2.3L against a constant pressure of 0.960 atm. (b) The gas allowed to expand reversibly and isothermally to the same final volume. Which process does more work? fe 4013235 A) We - Pe AV =-O:960atm x (MGL~ 2-3 LIE ~E Patel x Goa = Lr0F Sy 298Kx Ln (HE bY we-na4ddn Vie a5 w= 0-36 mol x 8314 a ay we - 685 = -820T The veversidle proccess cloer move werk than Constant Pre ssure 5, Calculate the heat that must be supplied to a 600.g ice at -10.0°C to raise its temperature to the boiling point of water, 100.0°C (the molar heat capacity of liquid water is 75 J.K"'mol" the molar heat capacity of ice is 37.6 J.K'' mol, and enthalpy of fusion of ice is 6.0 [Link]". ‘The melting point of ice is 0.00°C. 1 6004 Ho x Wre = 33.3 mal Hio (ice) BSt0 x\o0 =\28005 \ G@) Best sol. ¢ eme cy x AT © 35.3 mol x 97-6 5 ee oe &OKT . yooos _ 5 @) Fusion : 33.3 me\ tho x Tan ige * “Ege = Reoonle S @ Hest Wail ten eg AT =33.3meln ¥5 Toy * lioo'e 0°) = 2:50 x8 J H total = Mest ad+ By y+ Heat CSolict) = 2.50 (e854 2 oextfSe125005 BAS KIS T 6. Calculate the heat that must be supplied to a 18.0g of liquid mercury (Hg) at 26°C to raise its temperature to 390°C. (the molar heat capacity of liquid mercury is 28.0 J.K"|mol the molar heat capacity of vapor mercury is 81 J.K"!.mot", and enthalpy of vaporization of liquid mercury is 59.1 [Link]'. The boiling point of bromine is 356°C. Amt HS x 0.0897 mel H too. Hy O° 5 @ Heat lig ¢ GenxCea x OT 1805 Hy x £0089 Fmely 23-0 x (3860 -260) = 8305 e Z) Vap, & cc BIFmal Nyx ZAK , Weed . [Link] ® ver, a Shy * Tey 3 CD) Wrest Yap 2 4 enn Cyn AT 2d $20.06 9Fmolx BS y (3902-3560) 2 LAFF mobi Hy cea Meat (lig.) + SH + Mene(vap) = 8305 + [Link]' Se UF = 63807 De. Behrang Madani Chem200 vc7. For the following reaction: CHa(g) + 202(g}> CO2(g) + 2H20(g) 1f 650 kJ of heat energy is released per mole of methane (CHa): 8) What is the enthalpy of this reaction if 342 g of methane reacts? Amel CHy - 650 KS Amel Sxl KT | QHs —blewie ky 16 § chy A mmel CY, Buds CMY x ‘b) Find the enthalpy of reaction when sufficient methane is bumed to produce 0.56 mole of water vapor? Amel Cty — — 650 KS x = (oly AW = So KS Del yo 1 mel CHy 0-56 mel Ho x 8. Calculate AH? for the reaction: Naz0(s) + SOs(g) > NaxSO«(g) given the following information: AH® (1) Na(s) + H:0(0) > NaOH(s) + 1/2 Fh(g) “146 kd (2) Na2SO.(s) + H20()) > 2NaOH(s) + SOs(g) +418 kd (3) 2Na.O(s) + 2Ha(g) ~> 4Na(s) + 2H2O() +259 KT step 1: we clivide veaction(3> by 2: asks @ ~a206s) «Wy > ewalsd © HeM) — OH SRBES Le IB0 KT Step 2: Reverse veaction(@) : e 2 4S @ rnaowls) + Sos(s) > Marsoqcsr# Hre0) ABE a a Po Q Ane 4 BonKts = 288 Ae —AWazols) + trl) + Waotl(s) + Sony) —> rWals) 4 NagS04(5} # ZHLOC1) Step 3% to cancel UnWantesl VACH, He, Va, and Heo, muleiply readin 1 Bee vals) ZrO Cl) > LvaoW(s) + Hs) As 2x L-WGp— 292 Wy 49 = e =292KS 2 - $80 STER4 2 Combine CAD => Ans 28845 Sgr $805 Dr. Betrang Madani9. Calculate the standard heat of formation, AH, for FeS2(s) given the following information: 2FeS2(s) + 5O2(g) >2FeO(s) + 4S02(g) AHP nxn = -1370 kJ AH? for SOx(g) = -297 ki/mol OH/ foro, = 0-0 KAZ) AH? for FeO(s) = -268 kJ/mol AW = EN Aue” (predects) — Endy,” (reactants) f AW on = [CR mel) (iy Fe) 4 (amet) e (engso,)}- [C0 (ony FeS2) + (Smet) (ony? on) | H\BFoks = [Com)x (- 2 63Ky) + Camel) * cuir )]- [camry x (AME Fe) + (Seayx(o-o¥sy,) | (BFo Kye HIRE KT - ( 2moleDHy Fese) B54 IT = Lele AW Fesy => AL Fes, = +1FF by Dr. Bebrang Madani ‘Chem 200 ve