Aman a A
HALF YEARLY EXAMINATION-2022-23
A SUBJECT-CHEMISTRY
CLASS-X
Sectioon
them
Time: 3 Hrs. follou Section C,
and
strictly
Section
B,
( e n e r a ln s t r u c t i o n s
instructons S e c t t o n
A,
sectlons
conpulsory
following
fte
p a p e r hare
the are
Aead q u e s t i o n s
All q u e s t i o n s
question
The
paper:
assertion-reason
jl D a n d S e t i o n
In
tne
q u e s t o n
questions
Snort Wsuer/
37
Thern
are
7 to
15
ae
te mark
and
il Q.
No. each ofone
A
-
questions /assertion-reason
eacn.
Section cnoce
mar*
muliple
i one question
28 a r e cnoee
to
carrying
No. 16 multiple
i t S e e t i o n
B -
Q. case
study
based
marks
26 anr each.
tuo
No. 24 to m a r k s carrying
Q four a n s u e r
questtons,
c a r r y i n s
short
are
to 30
queston,
No. 27
markS
three
C -
Q
Section carrying
I) a n s U e r
questtons,
long
each No. 37
to 3 4
are
marks
Section D - Q. carrying
fve
ri answer quew stions,
long
acti. No. 35
to 37
are
Section E -
Q. internal
choce
12i However,
an
each. the question
paper:
marks, 2 questions
no
overall
choce in
l mark, 2 questions of 2 only
one
questions of
is
( u ) There attempt
in 8 o u have to
provided marks.
has been of 5
the 3 questions
and all
3 marks ana
of such questions in with each
section
choces
of the separate
instructions
are given
addition to this,
n
question, whererer necessary
is not permitted.
XUse of calculators 2 o0 3
X Section-A
atomic number
and symbol for element with
What would be the IUPAC name
2
120
2 Define Hund's rule of maximum muliplicity.
Write the electronic configuration of Copper. (atomic number = z
DL 9
What in the masa of I molo of water ? 6
What ia the y of one molecule,of nupgar ? (,,1,,0,,)2,
have directional charaeterintic 7 14921
Which orital does not
What i tho relationship between wavolongth nnd momentum of i partiele
What is the oxidation state of carbon in C , O , ?
9 Amonyg the elements l, Mg, which one hau lowent jonination enthulpy?
Caleuluto the number of moles present in 392 Kruma of cid
10 Hphurie
W r i t e the electronic conliguration of Cr ion. (Atomic number of Cr= 24)
Indicate the number of unpaired electrona in (P). IAtomie number =15|,
13. I'ind out the oxidution number of CI in ion.
(22p,333
CIO
14. Draw the shape of 28 orbital.
15. Caleulate the number of moles present in 11 g of
CO.
o 2 S )
Section-B
16. The oxidation state of oxygen in MnO is
+7 (b) - 1
(c)-2 (d) +2
3
17. The correct order of increasing radii of the elementsi., Na,K and Rb is
(a) Li > Na > K > Rb (i < Na < K< Rb
(c) Na > Li > K> Rb (d) Li< Na < Rb < K
18./ The relative number of atoms of elements (X) and (Y) in a compound is 0.2
and 0.5. The empirical formula of compound is
(a) XY (b) X,Y
(d) X,Y
XY
19/ An aqueous solution of NaQ| is 10% WV. The molarity of this solution is
2t16f
(a) 0.25 M 2 A (G h2.5 M
(c) 0.025 M (d) 2.0 M
O
ml of 5 M solution is diluted to 1500 ml. What will be molarily of
/lf 500 a
resulting solution ?
(a) 1.5 M (b) 1.59 M
(c) 1.66 M (d) 16.6 M
The unit of molarity is
(a) g (mol L
(C) mol mL (d) g ml1
which regularly decreases down the group of periodic table is:
The property
(a Ionisation enthalpy (b) Metallic character
(c) Reducing character (d) Electron gain enthalpy
The size of isoclectronic species 0, Ne, Nat is affected by :
(aPrincipal quantum number (b) Electron-electron repulsion
(c) Nuclear charge (d) None of the above
se Study based
introduced by Ostwald in 1896. This is the Latin word
The term mole was
'moles' meaning heap A mole (mol) is defined as the number
or pile.
atoms
of
atoms in 12 g of carbon-12 has
been
in 12.00 g of carbon-12. The number of
to be 6.023 x 10. This
number is also known a s
found experimentally
Amedco Avogadro (1776-1856).
Avogadro's number named in honour of
atomic
atoms of any element is exactly equal to the
The m a s s of mole one
mass of gram atom)
of that clement. One mole of
atomic
mass in gram (gram
Atomic mass unit is the unit
of atomic m a s s .
22.4 litre at S.T.P.
a gas occupies
1 amu = 1.66 x 10-"g
the following questions:
Read the passage and
answer
in 1 cc at STP ?
of molecules of a gas present
What will be the number
(i)
element will weigh x amu. Calculate the value of x.
i 1 g of an
number of atoms in 16 g O; and 16 g O
Calculate (1x4=4)
atom of in gram ?
the mass of single C
ivWhat will be 218
(atom 3
Case Based
Arvurding to the Bohr model, tne
B eels of a
hydrogen atom can be
making two assumptuo5. U tne eectrons move in a circular orbit
and ti the angular momentum or the electron in the nth energy level
is
quantized to have a value
"2 The levels caleulated witha nuclear
charge
Ze, with a single electron in the orbit, the called
hydrogenic levels. Assume
that the two electron in the
ground state of a helium atom occupy the
(orresponding lowest hydrogenie level.
Read the passage and answer the
following questions
i What is the unit of
angular momentum of electron?
Why the angular momentum of
electron is a shell will be
hydrogen and helium ? same for both
Will the radius of electron orbit for ls electron of H and He'
same? Justify your answer. will be
(iv) What will be the
angular momentum of electron in 5th shell ?
26. The question given below consist of an Assertion (A) and
the following key to cho00Se the correct answer. Reason (R). Use
(a lf both assertion and reason are correct and
reason is the correct
explanation of assertion.
(6) It both assertion and reason are correct but reason is not the the correct
explanation of assertion.
(c) If assertion is
correct but reason is incrrect.
(d) It both assertion and reason are incorrect.
1(A): Each d-block series contains ten elements.
, 29
CR): The maximum
/series
capacity of d-orbitals is of ten electrons as in each
d-orbitals are gradually filled up.
(A): Helium and beryllium have similar outer electronie
ns configuration
(R): Both are
chemically inert 204
44
DL.2
(A):
than
Electron affinity of
oxygen is less than
that of that of iorin
(R): nitrogen.
(
lonisation potentidt-is as follows
N> 0>F
W (A): The irst ionisation
energy of Be is greater than
(R): 2p-orbital is lower in energy than
that o
2s-orbitalk ,
Section-C
Consider the following species 0 > N
N0, Na*, Mg, F, A1 2s,22
What is common in them ? ,1 1
Arrange them in order of increasing ionic radii.
28Would you (2)
expect the second
negative or less negative than
electron
first ?
gain enthalpy of O as
positive, more
Justity your answer.S (2)
29 Would you expect the first
ionisation
tobe same or difterent ? Justiy enthalpy your answer.
of two
isotopes of same element
0. How would you C (2),
explain the fact that the first
is lower than that of ionisation enthalpy of 152sL,3S
magnesium but its second sodium
than that of
magnesium ? ionisation enthalpy is higher
(2)
Section-DD
P +OH PH3 +H,PO2
Balance by
above mentioned equation by oxidation
number method.
S2 Balance the
following ionic equation by ion-electron method
CryOf +SO2 C +So HO -
IS
(in acidic medium)
3)
3 A photon of
wavelength
of the metal
4 x
10 m strike on metal surface, the work funetion
being 2.13 eV. Calculate-
the energy
of the photon (eV)
a) /kinetic ernergy of
emission and
) velocity of
photoelectron (1 eV 1.602 x J0-1 J)
=
DL 29
e 3)
What is the wavelength ol the ight
ernitted wfen the electron in a
atom undergoes transition rom nn energy level withn = 4 to an energy level
hydrogen
with n = 2 ?
(3)
Section-E
35 A gas contains carbon and hydrOgen only. Burning a small sample of it in
oxygen gives 3.38 g CO, 0.690 g of H,o and no other products, A volume of
20.0 L at [Link] of this gas is found to
weigh 11.6 g. Caleulate-
empirical formula O o76 7
of gas
olar mass 2 1 4 3
) molecular formula
36 Calcun carbonate reacts with
O . 1616
[Link] reacts
CaCO+ 2HC CaClaaq Cl2 H,O
What mass
of CaCO, is required to react completely with 25 ml of
0.75 M
HCI ?
(3)
d Chlorine is prepared by treating MnO, with HCI acid.
4HCI MnO, »
2H,0 MnCl Cl,
v How many grams of HCI react with 3.0 g of MnO, ? (Atomic mass of Mn
55 (2)
iThe density of 3 molal solution of
of solution.
NaOH is 1.11 g mI..
Calculate molarity
n (3)
What is the basic difference
beteen molarity and molality (2)
3
*
T/
5
366
6 221
