[ome Pace: FILLIKE Heda | Aingle glage ecbjacions | Considot “that _benzore add CCkg 13) 5 extsyacted q210m toluene ( RmS] sec. row wate jcpoloot, the Wo steams axe fed Into Umigy and _-then tt 16 pumped _mto_a_ settler lohich gives 20 Weye} of, Raghinate ane extyjact. | Extsjact ~~) Benxoie Acid + Waten Rapinate —» Toluene _| Model the system +0 find_out what y. of BA has Pessed Into the qgitvent phase. BA t Toluenc+ Waled Nixet 4 epaatoH § Rofiiuete Toluene + SA BA twdy <4 Eatyoct Cexgandc Taye ) (aq Tayer ) (Rakguate ) R mlec tolunas—— > Pntfsec tole C kin? OF Aingle stage. a kglm3_ 6A | ectadtion | Sr /sec wate] KS rife nate 4g ims Br org BE C Eatyjack yoFULLIM || Few assumplions to be taken s 3) | AU the low Rates avje steady state the goloent must be immstble wo 8) |the reed concoxbjation must Re AY] The outstyeoms afer im equililostinm voit each other, Ahenpoie, yom 7 wy | Haws balanee {09 Benaoic acid (@n) 3 ~ | dnpat_= Oulput —— © “Topul of B= RCXI + 6.0 = KC Clee’) —O Output GBA = Rat St Chg lec) —® | put eg D ond @ in ey" @ we .gek RO = R44 G4, —— O (“gem ) | ft RC = Rat Smet 2 A= RC avd ye mec = ~—() | Rams "REM ~ | the dguction 6 BA extjaded ts given by effitency E E= Baeabpete| = 6 BA Fed ra Es SmRC™ =m ~—© (pom @) RE( R405) R45_——| re a0: a FILL) divide both “numenad.o ‘aud denominator, iby ™6S in 6), [Weg E = 3 . [a —6_ 1+ eR lta mS i [here a= Rk ftw a satto of feed to the gooet ™s {ow Rate at equilibsium. ” Lule and divide a" 6 ey 1, E= W-1 —@ a1 Bite! | Compute the 4staction of solute that could be extyacted ‘ma _éimgle stage gowent extyadion ust the numerical values Of S=12R, m= 9 and C= [Link] ao UO > | Griven that, 6-128, mye and C=05| kal 3 He know that,» E= Sy aud = MRE [ : RC " REMS I * We Ye xkx 0.1 = OL = 0.005 LS K+ ygxi2) 8(1+15) “ E= (2840005 = 0.6 = 60% RX 0-1 Hl lof, G= 1 x= R LL Lta msone nue FULLIM xe RF - yx A ples + Gs] > | e- 2, = = 0.6 = 60% 3 atyg Steady-state Tioo-sigge Golvent Eattaction: — | Develop _a_model_and obtain _an expnesion the Leatsjadtion_ BA Im a steady state opetediion with 00 stages. the input data aye game as in the, Previous pridblom. RIT a —> RK a oe | + —_ sa K— $10 fe aaumptions to be made: the teed concntyation Cstemain dconstant— ) the mixer is 60 ebpiced that -the tuo stieouns leaving g etage aie alureats in equilibyiwm ithe each Nothext. The equation yemax_ is still valid fol each Stage seposady gioug. o d= ma —O Yes mdq2 —@ Noss Balance {on the Ba: Input = output —@ot Prat: SS BIEL a t Stage 1 “stage 2 Input of GACkg/sec): RetSy2 RF SO Oulput of BA Cg |sec) Sy) + Ray Reo +54. pulling above values ine @ {or Styget and 2 Respro Wegek, Staged: Ret Sy2= S¥it KX) ——~ A Slage 2% RX = RA2+ 642 ——@) Ho= mato and #) = Aim — put im_eq C1 “fie g and at %) Rot Sma0 = Sait Bu C pene" @ \ = ROFSmMA2 = _ MOAI +RYy ™ @ “My =m (Ret Smee) (ém+R) RY = Rd t Smgo —(2)_ (from eqn(H) \ ™ puttin eqr ) in @s R x mcectsmd2) = Rot omqa. St (emt) R(Rer maa) = 4a Comte) =[= R2c+ Romd2 = 42 [R>+ 25mR + Sune | = fo R24 28mR 4 m2—eKom] = R2C |: qa2= RC —@ | R2t OR + SP? a] purge @in @, [gsm x R2C (ism) RK R2smR +2 | | oy = mRe(RtSm) | RemRot Sm @ [swe kqod, E= 5%) = Sm(Rism) —@ {- RC R24 RgmtSHyd 2 | Taking Sm common in numenatey and $7? Commer [im ddlomumatog in eqn @) [es Plt +1) _ Sf RR + Rt 1 mz sm Zz |. € = ott x al xt K+] X=}| -b% (a- b)(474 b?4ab ) —- E= (2) | —— 0) 3—| | (8-1 = (ant) («241 +«)) Gor we can conclude that 01 N no. % Stages , f fd x42. E= aN-| — aNH_| Comput -the yiactfon of solute that aan be exttsactecl_ im_a wo ~stage counter - aujent eatyeiction usreg he. came numerical values of 6712 1m=Ye and C=0.144 \which were used {07 sWigle stage extjacton aud T Compare tho syesults. | Given thot) S=12R, M=1g, O=0.1 kq/w3 a= mec (R+sm ) ! R2+ mREt ere i = Yer ces {es i2r(Ye) ) Rt 12R*(Ye) + 144 R2x /4)2 = roi Cir 8) (64 +96+144)| | onte | | ome | FILLIN ~~ ee [> e264 = Axo a I RC (RX [Link] 804 a | ES 0.9895 4 Td | _ _ | oy, E€= al w= ek { x3—| ms _ | = w= 4 = 2 Ya x 12.8 . | (4-1 = —0.55S5 | (3)3-] 0. $08} | “ ~ E= 0.3845 & 747, LA greater degsiee of extyaction has thus bec obtained With two Stages (347.) than 7th sues étage (607.) cocythve, alse bela the same- Ex: 4.5 | 160 om] sec a golwent 5(B) 75 used to leat 400 am3}see (ATC) GF 10% by Deight cpolution Cin A. Whew C 18 beng eatiatted pom vie i Countel- awment LLE (25 aye) What 1 the - Composition 2 fual cagydn (#2) aud exMact( 4), and also coldlat. ynaction extjacted m=3 and 34 = 1000 Kgl, Se= Bun kglm?, Sc= 1260 kg) m3 Rerpectio Bo galet , C— golly _aa | ret | ——— - _ — FILLIN” = [Link]/see = |6vI0" m|see = 6 — | or ow Rete gs = val- {ow fate x dewsily 7 = 6 KIO 1x BOD i = 0.128 qlee - Mol {1000 Rote potubioun (arc) = 400 on] eee = 4x10 mse Wh C= % Meee = 1X 1200 ky eee —@ MN A= [yxo—a) mefgcc = (0-4-1000) IyJsceo — | Total mass {lowe Ratt Fr-odlution. (-4++C) =Q+29 A+C = (0-4 +200% ) ks | ee —@ | cone. of cin cpblulion = 0.1 = [2004 kal sec. o.4t2004 — Kefece “0.04 +204 = 1200% B04 = 0.04 —¥ A= O.04 = 3.3898 KIDS m3/sec, 1180 L_@ = Now flow sate Of C = 3.3838K 10° 1200 = 0.0406 kg Jeee —€) avs How Hote EA = 0.4 - 0004 3.38aexi0° (tou @) = 0-4~ 0.0334 = 02366! bglseo_ —@)ate: Pane Al. Yow sale A= ‘(ate)- fF = Ae a So 3. 66 xo m3] sec — Fut gon) CRs) = bal see GC = 0.0406 M3jsee 3-661 10-4 C= 110-8488 kg lms —G | for 2 tage, ao = RC —@ R24 Rory + 677% dacm DP and @, 6= 16x10 m/sec Uy puting im ~ & 3.66) 1104 m/sec, | 94% = U0. 98.992 kg 1m3 and (10) cs a 13.403 x1078 X 110. 84 86 13-403 x 10-8 + IF-SFIBX 10-3 4 23.04x 1078 = 1486. 392} x 1078 S4.0) X107 8 . a= 2t.S1FF kgm 3 Yi = mRo (etme ) = R2+ Ram + 77) 25% = 1214-99 x 104 x 9.461 x10 4 54.01 X 107 8 » M1 = 180.805 kg] m8 N\ | Fyactiaur Extjacted B® gom by, ; | = Func) “| G2 SH = 305.288 KIL = 0.9514 __ | RC 4os 44 L104 —| ees a2 Rowe, w= R cl ms [w= 3.66lxiol = 0.962_ {i 3x16 xX 1074 g E= (0362) 1 = —0.4)82 | (0-762)8 - | = 0-545) | | B= 0.45006 Lit-3 Consided the idealized 44010 system. shaoy_in fig. 4.4 'Coelow) here the ayes have the same meaning — Os 9 the plevious [ Ss f Saal? Sears) RC Staget Lek nN tage 2 te r I x I | 5:0 50 I r 4 "ye assumptions to be takous 1\)_ We aye considera a pure golventne vant FALL) 2) | the mitvor te Go efffereut that the leaving tacams, je alwoonfs Tr _ equililostium 8) The polocnt plow yjale 16 sarae, 17 tut slower, ‘The equation gern 16 still valtd {oa each age, separately \ jt "ys them’) ——-O —— _ goemy2, ——@ Hass Balance foot the BAS Inpul = Ou! age RRS O RE = SH + RAY RA) = SNok R42 "@O Cyen oy‘nt nc FILLIN Vc |e “pak oo 4) ab] min in eq” Oue and alo (0 in fie gets C= Sip Rn i= Rims Tt a ~ 25 mee Go (arom) : fae gC ——@ 7 (Rt $m)® “ The daction Oh BA _entjacted IS ioe ee E= Shrsd2 = sf4irde) ——@ RC putting eg O and @) in @, “G4 e= 5 [| mee. + mR [atm (Resm)2 RO mRo G@onmmen, g (Rts) es S xmee xfr +R 1 KE (atom) OL Rism | = a xf t+ Rms \ [R_ +1 \ Ai+i |) (™s 7 msb= 1 [+ _%_\ = at at! J E = 2a) (any> Compute. the faaction 5 oolute that Can be eéttyoctedl [im a to0-stage cyoss-auent goloent_extyoclion slg the come numetical values & S=6R, m=Vo Lande = 0.1 kg)? which ue used fon ingle stage, eathjacteu j and compare jemults . ~ | a= mke and Y2= mK2c R+MS (Rms)? = Yak(0-) = Hg R2(00 R+ Ygx6R (Rt Yq x6R)* | = 0.1XY = Olx 62 29( +) KAY 4) = 0.004148 Yo = 0.00}03 | a E = S(4it42) RC = 6X (0-022) RX 0+) E= 0.6485 = 64-357,FILL AME) Ok, E= 2atl_ —I CH) a ~ | a= 8 = 41 = i Ioxé 3 — Lg x ER - E = 2x44) = (B+2)xH 3 7 #44) f4ari\* | CS 7 | E= 33 = 0.6485 = 64 a5h 44 T aI wrth -the game conditions the fyastron h_agetute eattjactecl i the count - cuyent sporotion 1 highst than thet We [the cass -cuyent _oporetia. 7 Faction extjacted | eyjoena (commer-cument > «jo -unot ) 7 T Mutttetage Gas Abeouption 134.8 kg mot/oec_ ot a Het gas containing Yur ky mol 4 WA H H | gotute 4 mol_tk wet gas 6 qa into bose“ cL plate, absorption column whew the golule ts to be [Tetuipped qo the gas by absoeption in Lokgmot [sex 5. leon af ahidk To“ped at the top 5h the Colum. The gvutt in the enteung off ts Xo ka mol/kg mot lean oft aud the ¢vlute ir the exit gos 73 Y fg mot | U kg mtl_ek wet sos. the equiltorium constort Km 75 Alen ab km= Yml am ; ohere ge ond ee S( ont pase FILLIW male ¢aadions the galult Inthe gas and quid ‘phoses, olespedively, Shoo that the pufermone 9 the nosonbot hn be expremed in terms 9. tha albsauption_qoctor a = (Lo K Gun) and the numb, |g ideal atages (1) v4 the kKyousn- Bourn equotion, " | (islods gelates she ional pluto, netaver to the absorption actor) + You = Ys = avt-n | Yui = Yo an} Git LoXo t | mM-E | Ym Xm4 at. Ym+1 - A - xm m+ to Pr Coss Yoss4 Lukwa: alone ove ni lage 2 Input = Output” Gur Ymtt + Lokms = Gur Ym+ lLoXm —@ Guul YY) = Lo ( Xm-Xm-1) —@© qn Gre = Yn Gus — @ &mbim = Xmlo — @ | We knod that eq gelation iS) to = Kn ati —@) |_putling. eq G2) ond G) im @), Yo Gu = Km XmLo —~ © Gay Lrg Xm = aut (tas) [Yo fim ]\~v0 | Km tn {eum Stage aa fase Yes 0) putting og and (8) i @, Gn ( Yonti - Yr) eB | La Vm — Lm Ym4 iW Ae (Gm Kn Gina Kent L@FILL Hosurstion. goeter jet plate 1 and mo gives by, Am = Lm — (10 Krliny Art = Lm —= (ii) Kr Grit pit e4% (10) and @ in ®. Yen - Ym = AY — Aria Ym-) Yon (Amel) = Yost t+ Ym Am-) = Ym = You + Yaa Amt — (») Amt) Talorg -the mean value 6} nbsorption {actor bl thw top Und -the bottom g the Columy 0s *, ( Aims =A, Am= ny eq*' becomes’ » Ym = Yt t Yma tk At | » Yai — (Att) Ym + AYm-) = 0 ——('3) x By the method he quite difkenene , | AE= CF + PL — Particular Tutegned | e ~ Comp UI J eee =FILLIN “Hue, PT=0 (Ab Risz0) CF = AE, pubes eq" (into the operational {oum_aud fen nts, [et- (ates ql¥u =o —(H) [e*e-neta] =o [ CECE“) =A (ea) ] Yu =0 & Cel (e-a) Yu=0 — (is VA g Y= Cit Cont — (9 let m=0, Yoo Cit Cok? = Cit Go —(1H) m=. , Y= Cit Con {'8) mene You = G4 GahT Cp Gulostndivg eg @_ yom (19), Yun -Yo = Co(am 1) — @) cust acl eq ('9)_ om @: Yon ~ Yi = Co( 4-4) —@)PULLIN 1 —_ — ~ _ Some experiments axe done on the absaaplion of air “mature 72.60 caustte odd. In one experiment ak Jotmosphente, qlessune, the sjesults obtained ars. 0% fafows I Exi4.10 Gas 4ais_ of the bottom Atha “amet = 0-4 bynes Liquid _sjat. ak the top the toe, = 3. 44 kg) meg B The C2 tthe fnlet_gas fs 31S ppm and ‘in the | eait gas Tk 1 i py: Fund the mole, dadion i | Co2 Bbepebed by Naot. (an=) ) | o= 0 izaixio® way ky mee | l Qvi=disxio® — an=7 Gad = 0-24 ka /m?s A) | Matecuton sought fai = 24 by eas * Gut = 0-34 = 0.01} kml fy26 -~—) 2g > — a eti LN Ho gm Nao pot” Fu_29 N —\100gm Nao ! stiri we have [000s gatution , —— iy = IOOX40 + 00X16 1000 I: M10 nos = 20.2 kg Lkme| Lo = 04234 = 0.145 kmél /m%4 ——@ 20-2 “t & overall modedal Balance. | | Guu ( Yun — Yi) = Lo (An a0) + 0.04 (316 x10 g)x10%) = 0. 145(4w-0) n= 14-04 x 107° © An= 14-04 ppm * | Multiage ODrstillatfon: Trye4|| 4 continuous 010 distaibution_cotumn_1% ded an a bina. mixtun Q Aad [Link] sfelatrve volatili the mitt, & hstank. by @usideina thes oat “above, the tod plate: derive “Hw. dy} co equation that (yjolates the Uquid composition to the plate, number 1 iL<= the overall plate officers ‘16 OD‘. ‘pede the “equotion, -to_alinooy one with vant co of ficients ghow that LAhe aats wanalation mal nes athe port, whetw the equilibsiivn and spenating lings intersect. Lt) tn bo-tho mole jraétion 5, mow volatile, compound Im Ugquid Leavin hae plate 1- | Ao be the mi yadion oF mere volatile compound a [pacduct o withdrawn {or condensys{ | An® be tho mole action oe more vilatile compourel_ ™m the vapeur im equiltosium with the liquid compositios |Yn_be the mole Madam pp mote volatile Compound” loding. the plate 1 5 O be Me constant molon foo Jat. tiquid down the, Column |v be the consteuct maton stow syarte 5 vapoun up the colunm D be the molt flow gate oe the produce pom the | condesey || Compenout Balance over nt plate % | Fuput = Outpue Vyn4 = Oant+ Dao + Vyng = Odn — Dao = 0 —f1) a= dan bang = Kany —a 14 (45 Jaw E 1+ (a-t}an4are ase | FILLIN: | | [patina oe @inQy L Van k = On — DAD = 0 ——-O 14 (4-1) atney =k Van-1 — Oru (14 (4) Mtn) —Dalo( 1+ (ana) =0 2a an —O02tn— 0%n(a-1)%n4 - DAD-DAy (x), i ant =O l : Lf | Divido_eq* (4) with 044), i _NAant_ = ky = Andny — Daly — DAoRny =O Lola!) kA O(«4) 0 EO | ejay ea" (3) with (1), 'OAodns + DAD +t aly +t ay at n+ — Vdaln+ =O l oO O(a4) aA O(a) lotnatnd +. + DAD + [ Daloatn4x (x-]) — yakou-y]=0 a} oles} fo fet) oka l @ ls tnaing tan tan + any] O%old1)— Va] =o a] o(a-t) Coie) J ; Ca lt A= 1, b= Dalo(w-l) -xV C= OX a-l 0(«-1) O(a) 1 Gr@) becomes, Ankns + An + banat C=o —f3)spat dn = anh 6 aed ata = atnysh & * (ature) (dna +$) +4 (ant) + b(anr +b) + CHO atnan) tan B+ anyb + An +46 + batny tbd+C4+6"=p lovin + otm(S40)+ ana (Stb)+ 67 +G+tb)EtC=0 Ll IO. ‘| consider, 624 (atb)d+ C=O 0 get gull diffe, anand + 9n(6ra) + any (6tb) = 0 —Ci) | divide og (7) by stnatn4, i+ (ere) + (646) =0-—) - And ain loth Vn = Yon) Vn = ¥) tn Vn (6b) + Vana l64a) = - 2 — (ss) publ 4" (Fin operational torn [e (ots) + Cats) [vn = 0 —(W “Es =fars) (ots)