SAFETY DATA SHEET
In compliance with EC Regulations No.: 1907/2006 and 453/2010.
Date last modified: 28 January 2015 - version 3.0
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY
1.1 Product Identifier
Product Name: BIOACTIVE LIQUID
Product Code #: 550510 (5 lt)
1.2 Relevant identified uses of the substance or mixture and uses advised against
Intended Use: Industrial applications; Sewage Water Treatment.
Uses advised against: This product is not recommended for any industrial, professional or consumer
use other than the Intended Uses above.
1.3 Details of the supplier of the safety data sheet
Company/undertaking identification
Supplier/Manufacturer:
Marichem Marigases Hellas SA
Sfaktirias 64,
185 45 Piraeus,
Greece
Tel. No.: ++30 210 4148800
Fax No.: ++30 210 4133985
[Link]
e-mail: mail@[Link]
1.4 Emergency telephone number
Tel. No.: ++30 210 4148800 (including working hours)
Emergency Information:
Inside U.S. and Canada: (800)-424-9300 (CHEMTREC)
Outside U.S. and Canada: 1-703-527-3887 (CHEMTREC)
National Emergency Centre (Greece): ++30 210 7793777
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2. HAZARDS IDENTIFICATION
2.1 Classification of the mixture
Classification under EC 1272/2008 regulation - GHS classification.
No need for classification according to GHS criteria for this product.
2.2 Label Elements
Labelling according to Regulation (EC) No. 1272/2008.
The substance is classified and labelled according to the CLP Regulation.
The product does not require a hazard warning label in accordance with GHS criteria.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Product classification and labelling according to Directive 67/548/EEC, European Dangerous
Preparations Directive (1999/45/EC), European Regulation 648/2004 and their amendments.
The preparation is not classified as dangerous according to Directive 1999/45/EC and its
amendments.
No special labeling information required according to EU directives.
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Chemical Composition:
· Chemical characterization: Mixtures
· Description: Mixture: consisting of the following components:
Ingredients CAS Number Proportion Hazard Code(s)*
Calcium Nitrate 4- 13477-34-4 2.5% - 10% H272; H319.
hydrate
Alkyl Ether Sulfate 9004-82-4 <=2.5% H315; H319.
Other ingredients that
do not contribute to the - 82.5% - 95.5% -
classification of the
product
*
See section 16 for the full text of the Hazard Code(s) declared above.
Occupational Exposure Limits, if available, are listed in section 8.
Other components:
55965-84-9 Mix of : 5-chloro-2-méthyl-2H-isothiazol-3-one [No. CE 247-500-7]; 2- methyl-
2Hisothiazol-3-one [No. CE 220-239-6] (3:1)
T, N; R 23/24/25-34-43-50/53
24730-31-2 Surfactin (lipopeptide complex)
2
Biosurfactant: lipoprotein complex nature surfactant, derived from fermentation of non-pathogenic
microorganisms (EFB class 1)
Regulation 648/2004 on Detergents:
anionic surfactants, perfumes < 5%
4. FIRST AID MEASURES
4.1 DESCRIPTION OF FIRST AID MEASURES
General information: No special measures required.
After excessive inhalation: Provide fresh air; consult a doctor in case of medical complaints.
After skin contact: Generally the product does not irritate the skin.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing: If symptoms persist consult a doctor.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
No further relevant information available.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL
TREATMENT NEEDED
No further relevant information available.
5. FIRE-FIGHTING MEASURES
5.1 SUITABLE EXTINGUISHING AGENTS
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE
No further relevant information available.
5.3 ADVICE FOR FIRE-FIGHTERS
Protective equipment: No special measures required.
6. ACCIDENTAL RELEASE MEASURES
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY
PROCEDURES
Not required.
6.2 ENVIRONMENTAL PRECAUTIONS
Dilute with plenty of water.
Do not allow the product to enter sewers/ surface water or ground water.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
6.4 REFERENCE TO OTHER SECTIONS
See Section 7 for information on safe handling.
See Section 8 for information on personal protective equipment.
See Section 13 for disposal information.
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7. HANDLING AND STORAGE
7.1 PRECAUTIONS FOR SAFE HANDLING
No special measures required.
Information about fire - and explosion protection: No special measures required.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: None.
7.3 SPECIFIC END USE(S)
No further relevant information available.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical facilities: No further data; see section 7.
8.1 CONTROL PARAMETERS
Ingredients with limit values that require monitoring at the workplace
The product does not contain any significant quantities of materials with critical values that have to
be monitored at the workplace.
Additional information
The most current valid lists have been used as a basis for the production of this document.
8.2 EXPOSURE CONTROLS
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures are to be adhered to when handling chemicals.
Respiratory protection
Not required.
Protection of hands
No personal protective equipment is required. In case of intensive use, follow the safety measures
and hygiene usual for the use of chemicals.
Gloves material: -
Eye protection
Goggles recommended during refilling.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
9.1.1. Appearance
Physical State: Liquid
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Color: Green
Odor: Characteristic mint-scent
9.1.2. Basic data
Boiling Point: Undetermined
Freezing Point: Undetermined
pH: 5.8 (+/-0.5) at 200 C
Flash Point: Not applicable
Autoignition Temperature: Product is not self-igniting.
Danger of explosion: Product does not present an explosion hazard.
Vapour pressure at 20 °C: 23 hPa
Density at 20°C: 1 gr/cm3
Solubility in / Miscibility with water: Fully miscible.
9.2 Other Information: No further relevant information available.
10. STABILITY AND REACTIVITY
10.1 REACTIVITY
No hazardous reactions if stored and handled as prescribed/indicated.
10.2 CHEMICAL STABILITY
Stable under ordinary conditions of use and storage.
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS
No dangerous reactions known.
10.4 CONDITIONS TO AVOID
No further relevant information available.
10.5 INCOMPATIBLE MATERIALS
No further relevant information available.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS
No dangerous decomposition products known.
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11. TOXICOLOGICAL INFORMATION
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS
Acute toxicity:
Primary irritant effect:
On the skin: No irritant effect.
On the eyes: No irritant effect.
Sensitisation: No sensitising effects known.
Additional toxicological information:
The product is not subject to classification according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version.
When used and handled according to specifications, the product does not have any harmful effects
to our experience and the information provided to us.
12. ECOLOGICAL INFORMATION
12.1 TOXICITY
Aquatic toxicity: No further relevant information available.
12.2 PERSISTENCE AND DEGRADABILITY
No further relevant information available.
12.3 BIOACCUMULATIVE POTENTIAL
No further relevant information available.
12.4 MOBILITY IN SOIL
No further relevant information available.
Additional ecological information:
General notes: Generally not hazardous for water.
12.5 RESULTS OF PBT AND vPvB ASSESSMENT
PBT: Not applicable.
vPvB: Not applicable.
12.6 OTHER ADVERSE EFFECTS
No further relevant information available.
The product is not harmful to the marine environment as per paragraphs 1.7.4 and 1.7.5. of
Resolution MEPC. 219 (63) /Annex 24 - 2012 adoption of IMO’s MARPOL Annex V.
13. DISPOSAL CONSIDERATIONS
13.1 WASTE TREATMENT METHODS
Recommendation: Smaller quantities can be disposed of with household waste.
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
Recommended cleansing agents: Water, if necessary together with cleansing agents.
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14. TRANSPORT INFORMATION
14.1 No special transport information required according to ADR/RID, IMDG, US DOT and
ICAO/IATA codes.
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture.
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.
15.2 Chemical Safety Assessment
A CSA has been carried out for the raw materials in this product, from the raw materials
manufacturers (when needed to be carried out).
16 Other
16. OTHER INFORMATION
16.1 Full text of Hazard Code(s) referred in Section 3
H272: May intensify fire; oxidiser.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
16.2 Abbreviations and acronyms
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European
Agreement concerning the International Carriage of Dangerous Goods by Road).
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de
fer (Regulations Concerning the International Transport of Dangerous Goods by Rail).
IMDG: International Maritime Code for Dangerous Goods.
IATA: International Air Transport Association.
ICAO: International Civil Aviation Organization.
bw: Body weight.
Carc.: Carcinogenicity.
CAS number: Chemical Abstracts Service number.
CLP: Classification Labelling Packaging Regulation.
CSA: Chemical Safety Assessment.
CSR: Chemical Safety Report.
DNEL: Derived No Effect Level.
dw: Dry weight.
EC number: EINECS and ELINCS number.
EC: European Commission.
EC50: Half maximal effective concentration.
EINECS: European Inventory of Existing Commercial Chemical Substances.
ELINCS: European List of Notified Chemical Substances.
EmS: Emergency Schedule.
ERC: Environmental Release Category.
ES: Exposure scenario.
food: oral feed.
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GHS: Globally Harmonized System of Classification and Labelling of Chemicals.
Irrit.: Irritation.
LC50: Lethal concentration, 50 %.
LD50: Median Lethal dose.
LOAEC: Lowest Observed Adverse Effect Concentration.
LOAEL: Lowest Observed Adverse Effect Level.
MK value: Maximum Concentration value.
NCO: An international corporation that provides customer service contracting.
NOAEC: No Observed Adverse Effect Concentration.
NOAEL: No Observed Adverse Effect Level.
NOEC: No Observed Effect Concentration.
OECD: Organisation for Economic Cooperation and Development.
PBT: Persistent, Bioaccumulative and Toxic.
PNEC: Predicted No Effect Concentration.
PROC: Process category.
REACH: The Registration, Evaluation, Authorisation and Restriction of Chemicals.
Resp.: Respiratory.
Sens.: Sensitization.
STEL value: Short Term Exposure Limit value.
STOT RE: Specific target organ toxicity — repeated exposure.
STOT SE: Specific target organ toxicity — single exposure.
STOT: Specific Target Organ Toxicity.
STP: Sewage Treatment Plant.
SU: Sector of use.
Tox.: Toxicity.
TWA value: Time Weighted Average value.
vPvB: Very Persistent and Very Bioaccumulative.
16.3 Notice to reader
All information, instructions and statements contained in this Material Safety Data Sheet are
compiled in accordance with European Directives, corresponding national legislation and on the
basis of information given by our suppliers.
The information disclosed in this Material Safety Data Sheet (which supersedes all previous
versions) is believed to be correct, at the date of issue, to the best of our current knowledge and
experience. It only relates to the specific product designated herein and it may not be valid when said
product is used in combination with any other products or in any processed form, unless specified in
the text. This document aims to provide the necessary health and safety information of the product
and is not to be considered a warranty or quality specification. It is the responsibility of the recipient
of this Material Safety Data Sheet to ensure that information given here is read and understood by all
who use, handle, dispose of or in any way come in contact with the product.
Also, it is the responsibility of the user to comply with local legislation relating to safety, health,
environment and waste management. Data and information provided concerning the product are
informative, exclusively presented to the customer.
