Organic Chemistry Worksheet 1
Name: Orane Cassanova
Answer the following questions:
1. Why is carbon able to form a huge number of different organic compounds?
Carbon has a valency of four and normally forms covalent bonds. As a result of carbon having four
valence electrons, carbon atoms can join with each other in an almost unlimited way to form the
following:
1. Straight (unbranched) or branched chains of different lengths
2. Rings of different sizes
3. Single, double or triple bonds
2. What is a homologous series?
A homologous series is a group of organic compounds which all possesses the same functional group
and can be represented by the same general formula.
3. List four characteristics of a homologous series
1. All members contain the same functional group.
2. All members have the same general formula.
3. Each member differs in molecular formula from the next by CH2, or in relative molecular mass
by 14.
4. All members show similar chemical properties. Reactivity decreases as number of carbon atoms
per molecule (molecular mass) increases.
4. Complete the table
Name of Homologous General Fully display structural Molecular
compound series formula formula formula of
of compound compound
Propane Alkanes CnH2n+2 H H H C3H8
H–C–C–C–H
H H H
Butene Alkenes CnH2n H H H H C4H8
C=C–C–C–H
H H H
Propanoic Carboxylic Acids Cn H(2n+1) COOH H H C2H5COOH
acid O
H–C–C–C
O–H
H H
Butanol Alcohols -OH H H H H C4H9OH
H–C–C–C–C–O–H
H H H H
2-hexene Alkenes CnH2n H H H H H H C6H12
H–C–C–C–C=C–C–H
H H H H
5. For each of the following give the name and homologous series the compound belong to
a) C3H7COOH- Butanoic acid, Carboxylic acids
b) C5H12- Pentane, Alkanes
c) C4H8- Butene, Alkenes
d) CH3CH2OH- Alcohols, Ethanol
6. Define structural isomerism
Structural isomerism is the occurrence of two or more organic compounds with the same molecular
formula but different structural formulae. The compounds are called isomers.
7. Explain why structural isomers of members of the same homologous series have very
similar chemical properties but different physical properties.
They have very similar chemical properties because they have the same functional group and differ in
physical properties because they have different structural formulas.
8. Hexane has five structural isomers. Draw and name any TWO of these.
H H
H–C–H H–C–H
H H H H H H H
H–C–C–C–C–H H–C–C–C–C–C–H
H H H H H H H H
H–C–H 2- Methylpentane
2,2- Dimethylbutane
9. Name two natural sources of hydrocarbon
Natural gas and Petroleum (crude oil)
10. List the main uses of three of the fractions obtained from fractional distillation of
petroleum.
1. Kerosene (paraffin)- Fuel for jet engines, kerosene lamps, paraffin-oil cooking stoves. Cracked
into smaller hydrocarbons.
2. Bitumen (asphalt)- Road surfacing, roofing.
3. Petrol (gasoline)- Fuel for internal combustion engines, e.g. cars, light aircraft.
11. Describe what is meant by ‘cracking’ and distinguish between thermal and catalytic
cracking of alkanes.
This involves breaking up larger hydrocarbon molecules into smaller ones. Thermal cracking uses heat
while catalytic cracking uses heat plus a catalyst. The cracking of alkanes always results in the formation
of at least one alkene and therefore, is a major source of alkenes.
12. Give the formulae and names of two products which could be obtained by cracking
pentane(C5H12)
Propane C3H8 Ethene C2H4
H H H H H
H–C–C–C–H C=C
H H H H H