Major Test - 1 : Chemistry (Paper - 2)
PART (B) : CHEMISTRY
SECTION – I : SINGLE CORRECT ANSWER TYPE
(Maximum Marks : 30)
This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out of which ONLY ONE is correct.
Marking Scheme : +3 for correct answer, 0 if not attempted and -1 in all other cases.
21. The ionisation energy of Zn is :-
(A) More than Cu and Ga
(B) Less than Cu and Ga
(C) More than Ga and less than Cu
(D) More than Cu and less than Ga
22. If YZ plane contain all the atoms of formaldehyde (H2CO), find the nodal plane of -bond in
formaldehyde.
(A) XY
(B) YZ
(C) XZ
(D) Not predictable
23. Naturally occurring thallium consists of two stable isotopes, Tl-203 and Tl-205 (atomic mass = 203.0
and 205.0, respectively) and has an average atomic mass of 204.4. What is percentage of Tl – 205?
(A) 14.0 %
(B) 30.0 %
(C) 50.0 %
(D) 70.0 %
24. A solution containing 12.0 % NaOH by mass has a density of 1.131 g/mL. What volume of this
solution contains 5.00 mol of NaOH?
(A) 0.0240 L
(B) 1.67 L
(C) 1.47 L
(D) 1.00 L
25. The antacid “Milk of Magnesia” is an aqueous slurry of magnesium hydroxide containing about
80 mg Mg(OH)2 per mL. What volume of gastric juice which is about 0.17 mol/L HCl can be
neutralized by 1 table spoon (15 mL) of Milk of Magnesia?
(A) 0.242 L
(B) 0.00122 L
(C) 0.0611 L
(D) 0.122 L
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Major Test - 1 : Chemistry (Paper - 2)
26. What possibly can the ratio be of the de Broglie wavelengths for two electrons having the same
initial energy and accelerated through 50 volts and 200 volts?
(A) 3 : 10
(B) 10 : 3
(C) 1 : 2
(D) 2 : 1
27. Which electronic configuration represents a violation of Hund’s rulel and Pauli’s rule both for an
atom in its ground state?
(A)
(B)
(C)
(D)
28. An electron cannot have the quantum numbers n = ……, l = ……, ml …….. .
(A) 1, 1, 1
(B) 2, 0, 0
(C) 3, 2, 1
(D) 2, 1, –1
29. Assuming Heisenberg Uncertainity Principle to be true what could be the minimum uncertainity in
de-Broglie wavelength of a moving electron accelerated from rest by Potential Difference of 6 V
7
whose uncertainty in position is nm.
22
(A) 6.25 Å
(B) 6 Å
(C) 0.625 Å
(D) 0.3125Å
30. Total no. of lines in Lyman series of H spectrum will be _____ if de-excitation occurs from nth orbit
(A) n
(B) n – 1
(C) n – 2
(D) n (n + 1)
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Major Test - 1 : Chemistry (Paper - 2)
SECTION – II : MULTIPLE CORRECT ANSWER TYPE
(Maximum Marks : 20)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE than ONE option can be correct.
Marking Scheme : +4 for correct answer, +1 Partial Mark, 0 if not attempted and -1 in all other
cases.
31. As per Valence Bond Theory (V.B.T.), which of the following overlapping is/are possible?
(A)
(B)
(C)
(D)
32. Select correct option regarding Uuh (atomic number 116)
(A) It belongs to 7th period element
(B) It belongs to group 16 element
(C) It is p-block element
(D) It is an inert gas
33. Select correct statements.
(A) Bond length of NO NO
(B) Bond order of NO NO
(C) Bond energy of NO NO
(D) NO is paramagnetic but NO is diamagnetic
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Major Test - 1 : Chemistry (Paper - 2)
34. Correct order of acidic strength :-
(A) HNO2 > HNO3
(B) H2SO4 > H2SO3
(C) HClO3 > HBrO3 > HIO3
(D) H3PO2 > H3PO4 > H3PO3
35. Which of the following molecule(s) does not have existence?
(A) IBr7
(B) PH5
(C) SH6
(D) BI3
SECTION – III : INTEGER ANSWER TYPE
(Maximum Marks : 10)
This section contains 5 questions. The answer to each question is a SINGLE DIGIT INTEGER ranging
from 0 to 9, BOTH INCLUSIVE.
Marking scheme: +2 for correct answer, 0 if not attempted and 0 in all other cases.
36. Write the total number of elements (upto atomic number = 10), which have positive electron gain
enthalpy (EGE1).
37. Choose the number of correct statement(s) from the following:
(a) Ist ionisation potential of ‘B’ is higher than that of ‘Be’.
(b) Electron affinity of ‘O’ is higher than that of ‘S’.
(c) [Ar] 4s2 3d3 is the electronic configuration of Mn2+.
(d) IInd ionisation potential of Na > Ist ionisation potential of Na.
(e) Ist ionisation potential of N > IInd ionisation potential of N.
(f) Eletronagativity of Cl > Electronegativity of F.
(g) C C2+ change is called IInd ionisation potential of carbon.
(h) Energy is required to convert He He–.
(i) Conversion of O O2– is exothermic.
38. Sum of p d bonds in SO2(g) and SO3(g) is :
39. Number of lone pair – bond pair repulsion at 90o are (P) in I 3 .
Number of lone pair – bond pair repulsion at 90o are (Q) in ICl4 .
Find difference of (P) and (Q).
40. Total number of faces in SF5 ion polyhedron is :
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