Astm C989
Astm C989
for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: C989/C989M − 18
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C989/C989M − 18
3. Terminology TABLE 2 Chemical Requirements
Sulfide sulfur (S), max, % 2.5
3.1 Definitions—For definitions of terms used in this
specification, refer to Terminology C125.
Consecutive Samples Sample reference cement more often than every two months. After the
Slag Activity IndexA
28-Day Index, min %
Grade 80 75 70 4
The sole source of commercially available reference portland cement known to
Grade 100 95 90 the committee at this time is CCRL, 4441 Buckeystown Pike, Suite C; Frederick,
Grade 120 115 110 Maryland 21704; www.CCRL.us. If you are aware of alternative suppliers, please
A
7-Day Slag Activity Index shall be determined on Grades 100 and 120, and provide this information to ASTM International Headquarters. Your comments will
reported for informational purposes. receive careful consideration at a meeting of the responsible technical committee,1
which you may attend.
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C989/C989M − 18
TABLE 3 Alkali and Strength Limits of Reference Portland 10.1.6.1 Slag activity index, %,
Cement for Slag Activity Tests 10.1.6.2 Compressive strength at 7 and 28 days, of slag
Total Alkalies (Na2O + 0.658 K2O) min % 0.60 cement-reference cement mortar,
max % 0.90
Compressive Strength, MPa, min, 28 daysA 35 [5000 psi]
10.1.6.3 Compressive strength at 7 and 28 days, of portland
A
The minimum strength limit is based solely on the strength of the Test Method
cement mortar,
C109/C109M mortar cubes, as required in Specification C150/C150M, regardless 10.1.6.4 Total equivalent alkalies of the reference cement
of the strength of the flow-controlled Specification C989 mortar cubes. (Na2O + 0.658 K2O),
10.1.6.5 Reference portland cement type (Type I or Type II).
10.1.7 Precision—The single and multilaboratory state-
initial testing to determine compliance with the compressive ments are based on slag activity index tests using one slag
strength requirement of Table 3, the reference cement shall be cement, in duplicate, at 7 and 28 days after fabrication of
re-qualified at least every six months. samples. The same slag cement and CCRL reference cement
NOTE 7—Different reference cements may produce different Slag
were used at each of 22 laboratories (Note 8).
Activity Index results. Reference portland cement meeting the require- NOTE 8—The precision of this test method was determined from an
ments of 10.1.2 is available from CCRL.5 interlaboratory study (ILS) under the jurisdiction of ASTM Subcommittee
10.1.3 Preparation of Specimens—Prepare mortars in accor- C09.27. The ILS program was conducted in 2015. Practice C670 was
followed for the design and analysis of the data. The details are given in
dance with Test Method C109/C109M, except that sufficient
RR:C09-1048.6
water shall be used in each batch to produce mortar at a flow
of 105 to 115 % as defined in Test Method C1437. The 10.1.7.1 The single-laboratory standard deviation has been
proportions of dry ingredients shall be as follows: found to be 1.65 % at 7 days and 2.62 % at 28 days. Therefore,
Reference Cement Mortar: the slag activity indices of properly conducted tests based on
500 g portland cement single batches of mortar mixed on the same day would not be
1375 g graded standard sand expected to differ by more than 4.6 % at 7 days and 7.3 % at
Slag Cement-Reference Cement Mortar: 28 days in more than one case in 20.
250 g portland cement 10.1.7.2 The multilaboratory standard deviation has been
250 g slag cement found to be 6.88 % at 7 days and 4.78 % at 28 days Therefore,
1375 g graded standard sand the slag activity indices of properly conducted tests of single
10.1.3.1 Mix a reference cement batch each day that a slag batches by different laboratories would not be expected to
cement-reference cement batch is mixed until at least five differ by more than 19.3 % at 7 days and 13.4 % at 28 days in
batches have been mixed with the reference cement. more than one case in 20.
Thereafter, reference cement batches need not be mixed more 10.2 Slag Cement Density and Specific Gravity—Determine
often than once a week whenever slag cement is being in accordance with Test Method C188.
produced or shipped. 10.3 Amount of Slag Cement Retained on a 45-µm (No. 325)
10.1.4 Test Ages—Determine the compressive strength of Sieve—Determine in accordance with Test Method C430.
mortar specimens at 7 and 28 days age in accordance with Test
Method C109/C109M. 10.4 Slag Cement Fineness by Air Permeability—Determine
10.1.5 Calculation—Calculate the slag activity index to the in accordance with Test Methods C204.
nearest percent for both 7 days and 28 days as follows: NOTE 9—In Test Methods C204, the applicable b is 0.9.
Slag activity index, % 5 ~ SP/P ! 3 100 (1) 10.5 Sulfate Ion in Slag Cement Reported as SO3—
where: Determine as sulfur trioxide in accordance with Test Methods
C114, except the sample need not be completely decomposed
SP = average compressive strength of slag cement-reference
by acid.
cement mortar cubes at designated ages, MPa [psi], and
P = average compressive strength of reference cement 10.6 Sulfide Sulfur in Slag Cement—Determine in accor-
mortar cubes at designated age, MPa [psi]. dance with Test Methods C114.
The reference cement-mortar strength used to calculate a 10.7 Calcium Sulfate Expansion of Mortar—If calcium
slag activity index shall, when a reference cement mortar is sulfate is added to slag cement measure in accordance with
mixed on the same day as a slag cement-reference cement Test Method C1038/C1038M.
mortar, be the result for that batch. Otherwise, the average of 10.8 Chloride Content of Slag Cement—Determine in ac-
tests of the five most recent reference cement-mortar batches cordance with Test Methods C114.
shall be used.
10.9 Air Content of Slag Cement Mortar—Determine in
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C989/C989M − 18
10.10 Aluminum Oxide Content of Slag Cement—Determine NOTE 11—Guidance on preparing the manufacturer’s report is provided
in accordance with Test Methods C114. in Appendix X4.
APPENDIXES
(Nonmandatory Information)
X1.1 When slag cement is used in concrete with portland the particular cement used. The results of the slag activity test
cement, the levels and rate of strength development will do not provide quantitative predictions of strength performance
depend importantly on the properties of the slag cement, the in concrete. Performance in concrete will depend on a large
properties of the portland cement, the relative and total number of factors including the properties and proportions of
amounts of slag cement and portland cement, and the concrete the slag cement, the portland cement, and other concrete
curing temperatures. ingredients, concrete temperatures, and curing conditions; and
other conditions.
X1.2 The reference cement used to test slag activity in this
specification must have a minimum 28-day strength of 35 MPa X1.3 Concrete strengths at 1, 3, and even 7 days may tend
[5000 psi] and an alkali equivalent between 0.6 and 0.9 %. to be lower using slag cement-portland cement combinations,
Performance of the slag cement with other portland cements particularly at low temperatures or at high slag cement per-
may be significantly different. The slag-activity test also can be centages. Concrete proportions will need to be established
used to evaluate relative hydraulic activity of different slag considering the importance of early strengths, the curing
cements with a specific cement or of different shipments of the temperatures involved and the properties of the slag cement,
same slag cement. Such comparisons will be improved if all the portland cement, and other concrete materials. Generally a
tests are made with a single sample of cement. To properly higher numerical grade of slag cement can be used in larger
classify a slag cement, the reference portland cement must amounts and will provide improved early strength perfor-
conform to the limits on strength and alkali content. Even mance; however, tests must be made using job materials under
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within these limits, performance will depend to some extent on job conditions.
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X2.1 General—Concrete manufactured with high percent- ages. Data from studies of laboratory exposure of mortars to
ages of slag cement is generally considered to have greater sodium and magnesium sulfate solutions provide the following
resistance to attack by sulfates than do portland cements, based general conclusions.
largely upon comparisons of these mixtures with similar X2.3.1 The combinations of slag cement and portland
mixtures containing ordinary (Type I) portlands. These high cement, in which the slag cement content was greater than 60
volume slag cement mixtures (containing 60 % or more slag) to 65 %, had high sulfate resistance, always better than the
are widely used for sulfate and sea-water resistant concretes portland cement alone, irrespective of the Al2O3 content of the
throughout the world. slag cement. The improvement in sulfate resistance was
X2.2 Sulfate Resistance of Portland Cements—The sulfate greatest for the portland cements with the higher C3A contents.
resistance of concrete is dependent upon a number of factors, X2.3.2 The low alumina (11 %) slag cement tested in-
including mortar permeability and the type and concentration creased the sulfate resistance independently of the C3A content
of the sulfate solutions involved. Others, directly related to the of the portland cement. To obtain adequate sulfate resistance,
cement characteristics, include calcium hydroxide concentra- higher slag cement percentages were necessary with the higher
tion and the tricalcium aluminate (C3A) content. Specification C3A portland cements.
C150/C150M provides limits on the C3A for sulfate-resistant X2.3.3 The high alumina (18 %) slag cement tested, ad-
cements. Specification C150/C150M Type V requirements versely affected the sulfate resistance of portland cements
provide for a limit on the tetracalcium aluminoferrite (C4AF) when blended in low percentages (50 % or less). Some tests
plus twice the C3A. The Specification C150/C150M table of indicated rapid decreases in resistance for cements in the 8 and
Optional Physical Requirements includes a maximum limit on 11 % C3A ranges with slag cement percentages as low as 20 %
expansion of Type V cement in mortar bars when tested by Test or less in the blends.
Method C452. When this option is selected, the standard limits
on tricalcium aluminate and on tetracalcium aluminoferrite X2.3.4 Tests on slag cement (7 to 8 % alumina) in Ontario
plus twice the tricalcium aluminate do not apply. Test Method (3) have shown that a 50:50 combination by mass with Type I
C1012/C1012M can be used to measure the effects of exposure portland cement (having up to about 12 % C3A) is equivalent
to external sulfate environments on mortar or concrete. in sulfate resistance to the Type V cement used in that study.
X2.3 Effect of Slag Cement on Sulfate Resistance—The use X2.4 Tests for Sulfate Resistance—When the relative sulfate
of slag cement will decrease the C3A content of the cementing resistance of a specific portland cement-slag cement combina-
materials and decrease the permeability and calcium hydroxide tion is desired, tests should be conducted in accordance with
content of the mortar or concrete. Tests have shown that the Test Method C1012/C1012M (4). Studies by Subcommittee
alumina content of the slag cement also influences sulfate C01.29 on sulfate resistance using Test Method C1012/
resistance (1, 2),7 and that high alumina content can have a C1012M, as reported by Patzias (5), recommended the follow-
detrimental influence at low slag cement-replacement percent- ing limits for expansion of portland cement and slag cement
combinations at six months of exposure:
7
The boldface numbers in parentheses refer to a list of references at the end of Moderate sulfate resistance — 0.10 % max
this standard. High sulfate resistance — 0.05 % max
X3. EFFECTIVENESS OF SLAG CEMENT IN PREVENTING EXCESSIVE EXPANSION OF CONCRETE DUE TO ALKALI
SILICA REACTION
X3.1 General—If properly proportioned in concrete X3.3 Mitigating ASR with Slag Cement—Slag cement miti-
mixtures, slag cement has been shown to prevent excessive gates ASR by reducing the total alkalies in the system and by
expansion due to alkali-silica reaction. consuming alkalies in the hydration reaction, making them
unavailable for the alkali silica reaction. The percentage of slag
X3.2 ASR in Concrete—Alkali silica reaction occurs in
cement required to mitigate alkali silica reaction is dependent
concrete if certain siliceous aggregates are placed in a highly
on the reactivity of the aggregate and the alkali loading of the
alkaline environment and, in the presence of water, form an
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C989/C989M − 18
X4.1 To provide uniformity for reporting the results of tests X4.2 The identity information given should unambiguously
performed on slag cements under this specification, as required identify the cement production represented by the Mill Test
by Section 12 of Specification C989/C989M entitled Report and may vary depending upon the manufacturer’s
“Certification,” an example Mill Test Report is shown in Fig. designation and purchaser’s requirements.
X4.1.
Plant: Example Slag Cement ASTM C989/C989M Grade 100 December 7, 2017
CHEMICAL
A
Sulfate Sulfur (as SO3), % 2.7
A
Aluminum Oxide (as Al2O3) 10.5
A
Chloride (Cl), % 0.011
A
Equivalent alkalies (Na2O + 0.658 K2O), % 0.52
PHYSICAL
Compressive StrengthB
A
7 Day (psi) 3669
A
28 Day (psi) 5695
Fineness
Blaine (m2/kg) 495 A
We certify that the above described slag cement, at the time of shipment, meets the chemical and physical requirements
of ASTM C989 – 09 or (other) _______ specification.
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C989/C989M − 18
X4.3 The Manufacturer’s Certification statement may vary mally performed on slag cements meeting Specification C989/
depending upon the manufacturer’s procurement order, or legal C989M. Purchaser reporting requirements should govern if
requirements, but should certify that the slag cement shipped is different from normal reporting by the manufacturer or from
represented by the certificate and that the cement conforms to those recommended here.
applicable requirements of the specification at the time it was
tested (or retested) or shipped. X4.5 Slag cements may be shipped prior to later-age test
data being available. In such cases, the test value may be left
X4.4 The sample Mill Test Report has been developed to blank. Alternatively, the manufacturer can generally provide
reflect the chemical and physical requirements of this specifi- estimates based on historical production data. The report
cation and recommends reporting all analyses and tests nor- should indicate if such estimates are provided.
REFERENCES
(1) Locher, F. W., “The Problems of the Sulfate Resistance of Slag (4) Hooton, R. D., and Emery, J. J., “Sulfate Resistance of a Canadian
Cements,” Zement-Kalk-Gips, No. 9, September, 1966. Slag Cement,” ACI Materials Journal, Vol 87, No. 6, November–De-
(2) Van Aardt, J. H. P., and Visser, S., “The Behavior of Mixtures of cember 1990.
Milled Granulated Blast-Furnace Slag and Portland Cement in Sulfate (5) Patzias, T., “The Development of ASTM Method C1012/C1012M
Solutions,” Bulletin 47, National Building Research Institute, South with Recommended Acceptance Limits for Sulfate Resistance of
Africa, 1967. Hydraulic Cements,” Cement, Concrete, and Aggregates, Vol 13, No.
(3) Chojnacki, B., “Sulfate Resistance of Blended (Slag) Cement,” Report 1, ASTM, 1991.
EM-52, Ministry of Transport and Communications, Ontario, Canada
1981.
SUMMARY OF CHANGES
Committee C09 has identified the location of selected changes to this standard since the last issue
(C989/C989M – 17) that may impact the use of this standard. (Approved March 15, 2018.)
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Alumina content in slag cement influences sulfate resistance, with low alumina content enhancing resistance independently of the C3A content in the portland cement. High alumina content can adversely affect resistance when present in low slag cement percentages. Therefore, for high sulfate resistance, low alumina slag should be used, particularly in blends with high C3A portland cements .
Test methods such as C188 for density, C430 for fineness, C204 for air permeability, and C114 for sulfate and chloride content are used to evaluate slag cement properties. These evaluations are crucial for determining the cement's suitability for specific applications, ensuring compliance with standards, and predicting performance in concrete .
The slag activity index is determined by calculating the ratio of the average compressive strength of slag cement-portland cement mortar to that of portland cement mortar, expressed as a percentage. This index is calculated for 7-day and 28-day test ages. It is important because it provides a quantitative measure of slag cement’s contribution to mortar strength, helping assess the quality and performance of slag cement in various concrete applications .
Equivalent alkalies, calculated as the total sodium oxide and potassium oxide content in slag cement, are vital as they influence the potential for alkali-silica reaction (ASR) in concrete. High levels can exacerbate ASR, leading to damaging expansion. Therefore, monitoring and controlling equivalent alkalies are critical to preventing ASR and ensuring the durability of concrete .
Re-qualification of reference cement is necessary every six months to ensure consistency and accuracy in testing, as different reference cements can produce varied results for the Slag Activity Index. Failure to re-qualify could lead to inaccurate assessments of slag cement performance, potentially compromising the quality and reliability of construction projects using these materials .
Slag cement mitigates alkali-silica reaction (ASR) in concrete by lowering the total alkalies in the mix and consuming alkalies during hydration, thus reducing their availability for reaction with siliceous aggregates. This process helps prevent the formation of the expansive gel associated with ASR. The effectiveness of ASR mitigation depends on the reactivity of aggregates and the concrete's alkali loading .
The single-laboratory precision limits are 1.65% at 7 days and 2.62% at 28 days, while the multilaboratory limits are 6.88% at 7 days and 4.78% at 28 days. These limits suggest that results are generally reliable within laboratories, but variability increases across different labs due to procedural discrepancies, emphasizing the need for standardized conditions .
Manufacturers prefer high percentage slag cement mixtures for sulfate and sea-water resistance because they offer superior resistance to chemical attack, specifically by reducing permeability and calcium hydroxide content, as well as lowering C3A levels. Such mixtures outperform portland cement alone, providing high durability in aggressive environments .
The early compressive strength of concrete using slag cement-portland cement blends is influenced by the concrete proportions, slag cement replacement percentage, curing temperature, and specific properties of the slag cement and portland cement used. High slag cement percentages and low temperatures tend to lower early strengths. Using a higher numerical grade of slag cement may improve early strength, but these proportions must be tested with job materials under actual conditions .
Slag cement contributes to sulfate resistance by reducing the C3A content and permeability of the cementitious material, thereby decreasing the calcium hydroxide content within the mortar or concrete. High slag cement content (60% or more) provides better sulfate resistance than portland cement alone, and this effect is more pronounced in cements with high C3A. The alumina content of the slag cement also plays a role, where low alumina slag cement improves sulfate resistance independently of portland cement’s C3A content .