FIITJEE INTERNAL TEST

IIT – JEE 2018

PHASE – VIII_PAPER – I_SET – A
Time: 3 hours Maximum Marks: 183

INSTRUCTIONS:
A. General
1. This booklet is your Question Paper containing 54 questions.
2. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and
electronic gadgets in any form are not allowed to be carried inside the examination hall.
3. Fill in the boxes provided for Name and Enrolment No.
4. The answer sheet, a machine-readable Objective Response (ORS), is provided separately.
5. DO NOT TAMPER WITH / MULTILATE THE ORS OR THE BOOKLET.
B. Filling in the OMR:
6. The instructions for the OMR sheet are given on the OMR itself.
C. Question paper format & Marking Scheme
21. Each part has three sections as detailed in the following table:
Section Question Number of Category wise Marks Each Question Maximum
Type Questions Full Marks Partial Marks Zero Marks Negative marks of
Marks the
section
One or +4 +1 0 –2 28
1 more 7 If only the For darkening a If none of the In all
correct bubble(s) bubble bubbles is other
option (s) corresponding to corresponding darkened cases
all the correct to each correct
option(s) is(are) option,
darkened provided NO
incorrect option
is darkened
Single +3 ––– 0 ––– 15
2 digit 5 If only the bubble In all other
integer corresponding to cases
(0–9) the correct
answer is
darkened.
Single +3 ––– 0 –1 18
3 correct 6 If only the bubble If none of the In all
option corresponding to bubbles is other
the correct option darkened cases
is darkened

Don’t write / mark your answers in this question booklet.

If you mark the answers in question booklet, you will not be allowed to continue the exam.

NAME:

ENROLLMENT NO.:

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PH-VIII-2018-PCM-2

PAPER–I
PART I: PHYSICS
SECTION 1 (Maximum Marks: 28)
 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options
is(are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4
marks; darkening only (A) and (D) will get +2 marks; and darkening (A) and (B) will get –2 marks, as a
wrong option is also darkened.

are 1, 2 and 3 respectively. Then

208 206 204
1. The wavelength of K X-rays for lead isotopes Pb , Pb , Pb
relation among 1, 2 and 3 can be
(A) 1 = 2 = 3 (B) 1 > 2 > 3 (C) 1 < 2 <3 (D) 2 = 12

2. An electron in a hydrogen atom makes a transition n1n2 where n1 and n2 are principal quantum
numbers of the two states. Assume the Bohr model to be valid. The time period of the electron in the
initial state is eight times that in the final state. The possible values of n1 and n2 are :
(A) n1=4, n2=2 (B) n1=8, n2=4 (C) n1=8, n2=1 (D) n1=6, n2=3

3. Which of the following transitions in He ion will give rise to a spectral line which has the same
wavelength as some spectral line in the hydrogen atom?
(A) n = 4 to n = 2 (B) n = 6 to n = 2 (C) n = 6 to n = 3 (D) n = 8 to n=4

4. For which of the pairs of u and f for a mirror image is smaller in size
(A) u = - 10 cm, f = 20 cm (B) u = - 20 cm, f = - 30cm
(C) u = - 45 cm, f = - 10 cm (D) u = - 60 cm, f = 30cm

5. Refractive index of an equilateral prism is 2

(A) minimum deviation from this prism can be 30°
(B) minimum deviation from this prism can be 45°
(C) at angle of incidence = 45°, deviation is minimum
(D) at angle of incidence = 60°, deviation is minimum

Space for rough work

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 PH-VIII-2018-PCM-3

6. A converging lens is used to form an image on a screen. When the upper half of the lens is covered
by an opaque screen
(A) complete image will not be formed
(B) complete image will be formed
(C) intensity of the image will not change
(D) intensity of the image will change

7. In YDSE  = 6000 Å, d = 6 mm and D = 2m.

(A) fringe width is 0.2 mm
rd
(B) position of 3 maxima (from central maxima) is 0.6 mm
nd
(C) position of 2 minima is 0.3 mm
(D) fringe width is 0.3 mm

SECTION 2 (Maximum Marks: 15)

 This section contains FIVE questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
 For each question, darken the bubble corresponding to the correct integer the ORS.

8. The work function of a substance is 4.0 eV. The longest wavelength of light that can cause
photoelectron emission from this substance is approximately is n  107 m . Find n.

r
9. The electric potential between a proton and an electron is given by V = V0 In , where r0 is a
r0
constant. Assuming Bohr’s model to be applicable, the variation of r n with n is rn nk where n being
principal quantum number then find k.

10. The energy of a photon is equal to the kinetic energy of a proton. The energy of the photon is E. Let
1
1 be the de-Broglie wavelength of the proton and 2 be the wavelength of the photon. The ratio
2
1
is proportional to E n . Find n
0
11. A ray of light undergoes deviation of 30 . when incident on an equilateral prism of refractive index
2 . The angle made by the ray inside the prism with the base of the prism is k 150  . Find k.

Space for rough work

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PH-VIII-2018-PCM-4

12. The maximum intensity in Young's double slit experiment is I0. Distance between the slits is d = 5 , where
 is the wavelength of monochromatic light used in the experiment. The intensity of light in front of one of
I
the slits on a screen at a distance D  10 d is 0 , then N is?
N

SECTION 3 (Maximum Marks: 18)

 This section contains SIX questions of matching type.
 This section contains TWO tables (each having 3 columns and 4 rows)
 Based on the table, there are THREE questions
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.

In Bohr’s atomic model for hydrogen like atoms

Column – 1 Column –2 Column –3

I If electron jumps from n = i speed of electron will p angular momentum of
4 to n = 2 become 2 times electron will become 2
times
II If electron jumps from n = ii speed of electron will q angular momentum of
6 to n = 2 become 3 times electron will become 3
times
III If electron jumps from n = iii speed of electron will r angular momentum of
3 to n = 1 become 1/2 times electron will become 1/2
times
IV If electron jumps from n = iv speed of electron will s angular momentum of
6 to n = 3 become 1/3 times electron will become 1/3
times
Answer the Following Questions

16
13. For wave length of emitted radiation is  
3R
(A) I,iii,p (B) II,iii,p (C) I,i,r (D) II,i,r
36
14. For wave length of emitted radiation is  
8R
(A) II,iv,q (B) I, ii,s (C) II,ii,s (D) I,iv,q
9
15. For wave length of emitted radiation is  
8R
(A) III,iv,q (B) II, iv,q (C) III,ii,s (D) II,ii,s

Space for rough work

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 PH-VIII-2018-PCM-5

A lens is made up of a material of

refractive index 2 and is placed in
1 2
medium of refractive index 1. Radii of
curvature of lens are R1 and R2 for the R1
R2
surfaces shown in figure.

Column – 1 Column –2 Column –3

I 2= 1.5 i 1= 1.3 p R1 = +20 cm
II 2= 1.3 ii 1= 1.3 q R1 = –20 cm
III 2= 2 iii 1= 1.3 r R1 = + 
IV 2= 1 iv 1= 1.3 s R1 = – 
Answer the Following Questions

16. For R2 = +  , the combination will be diverging for

(A) I,i,p (B) II, i,r (C) III,i,r (D) IV,i,p

17. For R2 = +20 cm, the combination will be diverging for

(A) I,i,p (B) II, ii,q (C) III,iii,r (D) IV,iv,p

18. For R2 = +  , the combination will be converging for

(A) I,i,p (B) II, ii,q (C) III,iii,r (D) IV,iv,s

PART II: CHEMISTRY

SECTION 1 (Maximum Marks: 28)
 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options
is(are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4
marks; darkening only (A) and (D) will get +2 marks; and darkening (A) and (B) will get –2 marks, as a
wrong option is also darkened.

19. For a process to be spontaneous:


(A) Gsystem T,P  0 (B) Ssystem  Ssurrounding  0

(C) Ssystem  Ssurrounding  0 

(D) Gsystem T,P  0
Space for rough work

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PH-VIII-2018-PCM-6

20. Which of the following pairs of solutions is isotonic ?

(A) 6% (w/v) urea and 6% (w/v) glucose (B) 18% (w/v) fructose and 18% (w/v) glucose
(C) 6% (w/v) urea and 18% (w/v) fructose (D) 34.2% (w/v) sucrose and 60%(w/v) glucose

21. Which of the following statement(s) is/are correct?

(A) Boiling point order: NH3  SbH3  AsH3  PH3
(B) Dipole moment order: NH3  SbH3  AsH3  PH3
(C) SbF5  XeF4  A. The hybridization and shape of the anionic part of A are
3 2
sp d and octahedral respectively.
 
(D) SbF5 reacts with XeF6 to form an adduct.  XeF5   SbF6 

22. The cell reaction of an electrolyte cell is given as:

Fe  2Fe3   3Fe2 with E0  0.404V & G0  2.424J
If the cell reaction is to be written as:
2Fe  4Fe3   6Fe2 ,
then which of the following statements will be correct for the above reaction? [A, B, D]
(A) E 0 can be given by 0.404 V (B) G 0 can be given by – 4.848 V
(C) E and G 0 are 0.404 V – 2.424 J respectively
0

(D) Then value of ‘n’ changes from 6 to 12

23. In electrolytic concentration cell:

(A) the electrode material and the solution in both half-cells are composed of the same substances
(B) only the concentrations of solutions of the same substances is different
(C) Eocell  0
 0.0591 
(D) the Nernst equation reduces to Ecell    logQ at 25C
 n 

air oxygen
24. A (Sulphide ore) + NaCN B (complex) + Na2S Na2SO4 then B is
(A) Paramagnetic (B) diamagnetic
(C) Linear complex (D) co ordination number of central atom is 4

Space for rough work

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 PH-VIII-2018-PCM-7

25. 2.08g of BaCl2 is dissolved in 500 ml of aq. Solution. The specific conductance of the solution is 0.02
–1
Mho.cm then, (equivalent conductance =  ; molar conductance = m)
(A) m = 500 Mho. cm / mol (B)  = 500 Mho.cm / gr. eq.
2 2

(C) m = 1000 Mho. cm / mol. (D)  = 1000 Mho. cm / gr. eq

2 2

SECTION 2 (Maximum Marks: 15)

 This section contains FIVE questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
 For each question, darken the bubble corresponding to the correct integer the ORS.

 wt 
26. The vapour pressure of a 5%   aqueous solution of a non–volatile organic substance at 373 K is
 wt 
745 mm. The molecular mass of the solute is ‘8x’. then ‘x’ is (vapour pressure of pure water at 373
K is 760 mm)

n
27. How many geometrical isomers are possible for square planar complex Mabcd ?

28. The difference of the effective atomic number and the number of unpaired electrons of Fe in
x
K 4 Fe  CN6   x . Find the value of .
  4

The equilibrium constant for the reaction Fe2  Ce4 Fe3  Ce3 is 1 x 10 . at 298 K. The
y
29.

value of ‘y’ is [Given : E0  1.44V; E0  0.909V , R = 8.314 J/K.mol)

Ce4  / Ce3  Fe3  / Fe2

30. Find the current in amperes required to deposit 2.977 g of Pd by the electrolysis of an aqueous
solution of Pd4 salt per 1 hour (At. Wt. of Pd = 106.4)

Space for rough work

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PH-VIII-2018-PCM-8

SECTION 3 (Maximum Marks: 18)

 This section contains SIX questions of matching type.
 This section contains TWO tables (each having 3 columns and 4 rows)
 Based on the table, there are THREE questions
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.

Answer Q.31, Q.32 and Q.33 by appropriately matching the information given in the three columns of
the following table

Column – I Column – II Column – III

(I) Kohlrausch Law  m / m
0 Increase with increase in
the distance between
(i) (P)
parallel plates
(Electrodes)
(II) m 1
(ii)  (Q) Decrease with dilution
R A
(III) K m0
Ca3 PO4 2 
(iii) (R) Increase with dilution
30Ca2  20PO34
(IV)  1000
(iv) K (S)   anion  cation
M

31. The correct combination is

(A) I, iii, S (B) I, ii, S (C) I, iii, R (D) I, iv, S

32. The correct combination is

(A) III, ii, R (B) III, ii, Q (C) III, iv, Q, P (D) III, ii, S

33. The correct combination is

(A) II, iv, R (B) II, iv, Q (C) II, iv, P, R (D) II, ii, S

Space for rough work

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 PH-VIII-2018-PCM-9

Answer Q.34, Q.35 and Q.36 by appropriately matching the information given in the three columns of
the following table

Column – I Column – II Column – III

(I) n–Hexane + n–Heptane (i) Non–ideal solution (P) PA  PA0 XA ; PB  PB0 XB
(II) CCl4 + CHCl3 (ii) Ideal solution (Q) PA  PA0 XA ; PB  PB0 XB
(III) Water + CH3OH Positive deviation from
(iii) (R) PA  PA0 XA ; PB  PB0 XB
Raoult’s law
(IV) CH3OH + CH3COOH Negative deviation from Hmix  0; Vmix  0
(iv) (S)
Raoult’s law

34. The correct combination is

(A) IV, i, iv, R, S (B) IV, II, P (C) IV, i, P (D) IV, i, iii, R, S

35. The correct combination is

(A) III, ii, Q (B) III, ii, P, S (C) III, i, iii, Q (D) III, i, iii, R, S

36. The correct combination is

(A) I, i, Q, S (B) I, i, R, S (C) I, ii, P (D) I, i, P

PART III: MATHEMATICS

SECTION 1 (Maximum Marks: 28)
 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options
is(are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4
marks; darkening only (A) and (D) will get +2 marks; and darkening (A) and (B) will get –2 marks, as a
wrong option is also darkened.

37. Sanjay has 10 friends among whom two are marred to each other. She wishes to invite 5 of the them
for a party. If the married couple refuse to attend separately, then the number of different ways in
which can invite five friends is
(B) 2  C3 (C) C5 – 2  C4
8 8 10 8
(A) C5 (D) none of these

Space for rough work

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PH-VIII-2018-PCM-10

38. The number of ways to select 2 numbers from {0, 1, 2, 3, 4} such that the sum of the squares of the
selected numbers is divisible by 5 are (repetition of digits is allowed)
9 9
(A) C1 (B) C8 (C) 9 (D) 7

39. In a class tournament when the participants were to play one game with another, two class players
fell ill, having played 3 games each. If the total number of games played is 84, the number of
participants at the beginning was
6
(A) 15 (B) 30 (C) C2 (D) 48

40. A class has 30 students. The following prizes are to be awarded to the students of this class, first and
second in Mathematics, first and second in Physics; first in Chemistry and first in Biology. If N denote
the number of ways in which this can be done, then
(A) 400 | N (B) 600 | N
(C) 8100 | N (D) N is divisible by four distinct prime numbers

41. A card is selected at random from cards numbered as 00, 01, 02, ......, 99. An event is said to have
occurred. If product of digits of the card number is 16. If card is selected 5 times with replacement
each time, then the probability that the even occurs exactly three times is
2 3 3 2 3 3
 3   97   3   97   03   97  3 2
(A) 5 C3     (B) 5 C3     (C) 5 C3     (D) 10 (0.03) ) (0.97)
 100   100   100   100   100   100 

42. The probabilities that a student in Mathematics, Physics and Chemistry are ,  and  respectively. Of
these subjects, a student has a 75% chance of passing in atleast one, a 50% chance of passing in
atleast two and a 40% chance of passing in exactly two subjects. Which of the following relations are
true ?
19 27 1 1
(A)  +  +  = (B)  +  +  = (C)  = (D)  =
20 20 10 4

43. A student appears for tests I, II and III. The student is successful if he passes either in tests I and II or
1
tests I and III. The probabilities of the student passing in tests I, II, III are p, q, and respectively. If
2
1
the probability that the student is successful is , then
2
2 1
(A) p = 1, q = 0 (B) p = , q =
3 2
3 2
(C) p = , q = (D) there are infinitely many values of p and q
5 3

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 PH-VIII-2018-PCM-11

SECTION 2 (Maximum Marks: 15)

 This section contains FIVE questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
 For each question, darken the bubble corresponding to the correct integer the ORS.
2 2
44. The number of positive integral solutions of x + y = 352706 is

45. There are four balls of different colours and four boxes of colours, same as those of the balls. The
number of ways in which the balls, one each in a box, could be placed such that a ball does not go to
a box of its own colour is

46. The tens digit of 1! + 2! + 3! + ...... + 97! is

47. There are three piles of identical red, blue and green balls and each pile contains at least 10 balls.
The number of ways of selecting 10 balls if twice as many red balls as green balls are to be selected
is


C2
48. The maximum value of 1
=
C4

SECTION 3 (Maximum Marks: 18)

 This section contains SIX questions of matching type.
 This section contains TWO tables (each having 3 columns and 4 rows)
 Based on the table, there are THREE questions
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.

By appropriately matching the information given in the three columns of the following table.
Column 1 – Equation of Hyperbola, Column 2 – Eccentricity may lie in interval, Column 3 – length of latus
rectum.

Column 1 Column 2 Column 3

 
2 2
(I) 9x – 4y = 36 (i) 2, 3 8 2
(P)
3

(II)
 x  1y
2

1 
2 (ii)  3,2  (Q)
3
6 8 2
2 2
(III) 3x – 6x – 4y + 16y – 14 = 0 (iii) (2, 3) (R) 9

(IV)
x2 y2
 1
(iv) 1, 2   (S) 3
9 6

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PH-VIII-2018-PCM-12

49. Which of the following options is the only CORRECT combination ?

(A) (I) (i) (S) (B) (I) (ii) (R) (C) (II) (ii) (S) (D) (iII) (ii) (R)

50. Which of the following options is the only CORRECT combination ?

(A) (II) (i) (R) (B) (II) (i) (P) (C) (III) (i) (P) (D) (IV) (iii) (R)

51. Which of the following options is the only CORRECT combination ?

(A) (III) (iv) (Q) (B) (III) (iii) (Q) (C) (II) (iv) (Q) (D) (IV) (iii) (P)

By observing column 1, column 2, column 3 establish the relation and answer to the questions below:

Column 1 Column 2 Column 3

3 2 1 (i) P(A  B) 1
(I) P(A) = , P(B) = , P(A  B) = (P)
4 5 4 8
1 1 5 (ii) P(A  B) 9
(II) P(A) = ; P(B) = ; P(A  B) = (Q)
4 2 8 20
1 1
(III) P(A) = ; P(B) ; P(A  B) =
1 
(iii) P A  B  (R)
21
4 2 5 20
3
(IV) P(A  B) = ; P(A  B) =
1  
(iv) P A  P B   (S)
9
4 5 10

52. Which of the following options is CORRECT

(A) (I) (ii) (S) (B) (I) (iv) (R) (C) (I) (iii) (P) (D) (I) (ii) (P)

53. Which of the following options is CORRECT

(A) (II) (i) (P) (B) (II) (ii) (Q) (C) (III) (iii) (R) (D) (I) (ii) (Q)

54. Which of the following options is CORRECT

(A) (III) (iii) (Q) (B) (II) (ii) (Q) (C) (I) (iv) (R) (D) (I) (ii) (P)

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 PH-VIII-2018-PCM-13

FIITJEE INTERNAL TEST

IIT – JEE 2018
PHASE – VIII_PAPER – I_SET-A
ANSWERS
PHYSICS
1. A,D 2. A,B,D 3. A,B,D 4. A,C,D
5. A,C 6. B,D 7. A,B,C 8. 3
9. 1 10. 2 11. 0 12. 2
13. C 14. C 15. C 16. D
17. C 18. A

CHEMISTRY
19. B, D 20. B, C 21. A, B, C, D 22. B, D
23. A, B, C 24. B, C 25. B, C 26. 6
27. 3 28. 9 29. 9 30. 3
31. A 32. B 33. A 34. A
35. C 36. D

MATHEMATICS
37. BC 38. ABC 39. AC 40. ABCD
41. BD 42. BC 43. ABCD 44. 0
45. 9 46. 1 47. 4 48. 3
49. B 50. B 51. A 52. A
53. A 54. A

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PH-VIII-2018-PCM-14

FIITJEE INTERNAL TEST

IIT – JEE 2018
PHASE – VIII_PAPER – II_SET – A
Time: 3 hours Maximum Marks: 183

INSTRUCTIONS:
A. General
1. This booklet is your Question Paper containing 54 questions.
6. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and
electronic gadgets in any form are not allowed to be carried inside the examination hall.
7. Fill in the boxes provided for Name and Enrolment No.
8. The answer sheet, a machine-readable Objective Response (ORS), is provided separately.
9. DO NOT TAMPER WITH / MULTILATE THE ORS OR THE BOOKLET.
B. Filling in the OMR:
6. The instructions for the OMR sheet are given on the OMR itself.
C. Question paper format & Marking Scheme
21. Each part has three sections as detailed in the following table:
Section Question Number of Category wise Marks Each Question Maximum
Type Questions Full Marks Partial Marks Zero Negative marks of
Marks Marks the
section
1 Single +3 ––– 0 –1 21
Correct 7 If only the bubble If none of In all
Option corresponding to the other
the correct option bubbles is cases
is darkened darkened
2 One or +4 +1 0 –2 28
more 7 If only the For darkening a If none of In all
correct bubble(s) bubble the other
option(s) corresponding to corresponding bubbles is case.
all the correct to each correct darkened.
option(s) is (are) option,
darkened. provided NO
incorrect option
is darkened.
3 Compreh +3 ––– 0 ––– 12
ension 4 If only the bubble In all other
corresponding to case.
the correct option
is darkened

Don’t write / mark your answers in this question booklet.

If you mark the answers in question booklet, you will not be allowed to continue the exam.

NAME:

ENROLLMENT NO.:

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 PH-VIII-2018-PCM-15

PAPER–I
PART I: PHYSICS
SECTION 1 (Maximum Marks: 28)
 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to all the correct option in the ORS.

1. AB and CD are surfaces of two slabs as shown in the figure. The medium 1  2
Q
A B
between the slabs has refractive index 2. Refractive index of the slab

above AB is 2 and below CD is 3 . The minimum angle of incidence 2  2
at Q so that the ray is totally reflected by both the slabs is C D
3  3
0 0 0 0
(A) 30 (B) 48 (C) 60 (D) 90

2. A plane mirror is made of a glass slab (g = 1.5) 2.5 cm thick and silvered on its back. A point object is
placed 5 cm in front of the unsilvered face of the mirror. If the position of the final image seen by a
person standing in front of the mirror is ____ from unsilvered face
25 16
(A) cm (B) 25 cm (C) cm (D) 22 cm
3 3

 3
3. A plano-convex glass lens  g   of radius of curvature R = 10
 2
cm is placed at a distance of ‘b’ from a concave lens of focal
length 20 cm. If was observed that if an object ‘O’ is placed at
distance ‘a’ as shown then the position of final image is
independent of ‘b’. The value of a is
(A) 15 cm (B) 20 cm (C) 25 cm (D) 30 cm

4. As shown in the figure, light is incident normally on one face of

a prism. A liquid of refractive index  is placed on the
3
horizontal face AC. The refractive index of the prism is . If
2
total internal reflection taking place on the face AC,  should be
less than

2 3 3 3 3 5 1
(A) (B) (C) (D)
5 4 4 2

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PH-VIII-2018-PCM-16

5. A monochromatic beam of light of 6000 Å is used in YDSE setup. The

two slits are covered with two thin films of equal thickness t but of
different refractive indices as shown in the figure. considering the
intensity of the incident beam on the slits to be I0, find the point on the
–4
screen (in x 10 m) at which intensity is I0 and is just above the
central maxima. (Assume that there is no change in intensity of the
light after passing through the films)

(A) 2.2 (B) 4.3 (C) 3 (D) 5

6. The wavefront of a light beam is given by the equation x + 2y + 3x = c (where c is arbitrary constant),
 X  Y
then the angle made by the direction of light with the y–axis is given as cos1   , then find  
 Y  X
(A) 4 (B) 7 (C) 6 (D) 5

7. A retro–reflector is an optical device which reflects light coming

from infinity back directly recently “scotehlite” sphere have been
invented which behave as a retro reflector (figure). The index of
refraction for such sphere is

1
(A) 2 (B) 3 (C) (D) 2
2

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 PH-VIII-2018-PCM-17

SECTION 2 (Maximum Marks: 15)

 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options
is(are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4
marks; darkening only (A) and (D) will get +2 marks; and darkening (A) and (B) will get –2 marks, as a
wrong option is also darkened.
–7
8. A two–slit interference experiment uses coherent light of wavelength 5 x 10 m. Intensity in the
interference pattern for the following points are I1, I2, I3 and I4, respectively.
–7
(1) a point that is close to one slit than the other by 5 x 10 m
4
(2) a point where the light waves received from the two slits are out of phase by rad
3
–7
(3) a point that is closer to one slit than the other by 7.5 x 10 m

(4) a point where the light waves received by the two slits are out of phase by rad
2
Then, which of following statements is/are correct?
(A) I1 > I4 > I2 > I3 (B) I1 < I4 < I2 < I3 (C) 3 I2 = I4 (D) I3 = 0

9. When barium is irradiated by a light of  = 4000 Å, all the photoelectrons emitted are bent in a circle of
–6
radius 50 cm by a magnetic field of flux density 5.26 x 10 T. Then,
(A) the kinetic energy of fastest photoelectron is 0.6 eV
(B) work function of the metal is 2.5 eV
6 –1
(C) the maximum velocity of photoelectron is 0.46 x 10 ms
(D) the stopping potential for photoelectric effect is 0.6 V

10. The graph shows the variation of potential energy  of a proton 

with its distance ‘r’ from a fixed sodium nucleus, as it approaches
the nucleus placed at origin O. Then the portion B
(A) AB indicates nuclear attraction
(B) AB indicates nuclear repulsion A
(C) BC indicates nuclear attraction
(D) BC represents electrostatic interaction O C r

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PH-VIII-2018-PCM-18

11. The figure shows the variation of photocurrent with anode

potential for a photosensitive surface for three different
radiations. Let Ia, Ib and Ic be the intensities and fa, fb, and fc be
the frequencies for the curves a, b and c respectively:
(A) fa = fb and Ia  Ib (B) fa = fc and Ia = Ic
(C) fa = fb and Ia = Ib (D) fb  fc and Ib = Ic

are 1, 2 and 3 respectively. Then:

208 206 204
12. The wavelength of K X-rays for lead isotopes Pb , Pb , Pb
(A) 1 = 2 = 3 (B) 1 > 2 > 3 (C) 1 < 2 <3 (D) 2 = 12

13. Two point monochromatic and coherent sources of light of wavelength  are placed on the dotted
line in front of an infinite screen. The source emit waves in phase with each other. The distance
between S1 and S 2 is ‘d’ while their distance form the screen is much larger. Then:
(A) If d  7 / 2, O will be a minima
(B) If d  4.3 , there will be a total of 8 minima on screen
(C) If d  7 , O will be a maxima
(D) If d   , there will be only one maxima on the screen

5 cm/s

14. An object is moving with a velocity of 5 cm/s at an angle of y

0
60 with respect to the optic axis of a concave mirror. The
60
object is at a distance of 50 cm from the mirror. The velocity x
of image at the given instant is found to be 10iˆ  K 3 ˆj
cm/sec (K is a positive integer)
50 cm

(A) the focal length of the mirror is 100 cm

(B) the value of K is 5
(C) the image must be real
(D) the image must be virtual

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 PH-VIII-2018-PCM-19

SECTION 3 (Maximum Marks: 18)

 This section contains TWO paragraphs.
 Based on each paragraph, there are TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.

Paragraph–1
–7
In YDSE, the source is red light of wavelength 7 x 10 m. When a thin glass plate of refractive index 1.5 is put
–3
in the path of one of the interfering beams, the central bright fringe shifts by 10 m to the position previously
occupied by the 5th bright fringe.

15. What is the thickness of the plate?

(A) 5 m (B) 0.005 m (C) 7 m (D) 0.007 m

–7
16. If the source is now changed to green light of wavelength 5 x 10 m, the central fringe shifts to a
position initially occupied by the 6th bright fringe due to red light. What will be refractive index of glass
plate for the 2nd light for changed source of light?
(A) 2.6 (B) 1.6 (C) 1.2 (D) 2.2

Paragraph–2
An electron is orbiting in a circular orbit of radius r under the influence of a constant magnetic field B.
Assuming that Bohr’s postulate regarding the quantisation of angular momentum holds good for this electron
[ii = Planck’s constant, e = charge on electron and m = mass of electron]

17. Radius of nth orbit of the electron will be:

2nh 2nh neh 2n e h
(A) (B) (C) (D)
 Be 2 Be 2 Be  Be

18. Kinetic energy of the electron in nth orbit will be:

nhBe nhBe nhB nhB
(A) (B) (C) (D)
4 m 2 m 2 em 4 em

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PH-VIII-2018-PCM-20

PART II: CHEMISTRY

SECTION 1 (Maximum Marks: 28)
 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to all the correct option in the ORS.

–1 2 –
19. At 25C the equivalent conductance at infinite dilution for HCl solution is 4250 ohm cm equivalent
1 –1 –1
, while its specific conductance is 3.825 ohm cm . If the apparent degree of dissociation is 90%,
the normality of the solution is
(A) 0.90 N (B) 1.0 N (C) 1.1 N (D) 1.2 N

20. Buna-S is a
(A) condensation polymer formed by styrene and 1,3-butadiene
(B) addition polymer formed by styrene and 1,3-butadiene
(C) condensation polymer of hexamethylene diamine and adipic acid
(D) addition polymer of hexamethylene diamine and adipic acid

21. Identify the tetrahedral complex

2 2 2 2
(A) Ni  CN4  (B) Cu NH3   (C) PtCl4  (D) Co  SCN4 
   4  
20
22. An ion is reduced to the element when it absorbs 6 x 10 electrons. The no. of equivalents of the ion
is
(A) 0.1 (B) 0.01 (C) 0.001 (D) 0.0001

23. For Button cell, the emf vs time graph is:

 
emf emf
(A) (B)

t t

 
emf emf
(C) (D)

t t

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 PH-VIII-2018-PCM-21

24. A given mass of gas expands from the state A to the state B by three paths
1,2 and 3 as shown in the figure. If w1,w 2 and w 3 respectively be the
work done by the gas along three paths then:

(A) w1  w 2  w3 (B) w1  w 2  w3 (C) w1  w 2  w3 (D) w 2  w3  w1

25. When H2S gas is passed through ammonical sodium nitroprusside solution, then
(A) The complex compound Na4[Fe(CN)5NOS] is formed
2
(B) The complex Fe  CN3 NOS is formed
4
(C) The complex Fe  CN5 NOS is formed (D) None of them is produced

SECTION 2 (Maximum Marks: 15)

 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options
is(are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4
marks; darkening only (A) and (D) will get +2 marks; and darkening (A) and (B) will get –2 marks, as a
wrong option is also darkened.

26. Consider 0.1 M solutions of two solutes X & Y. the solute X behaves as an univalent electrolyte while
the solute Y undergoes dimerization in solution. Select the correct statement(s) regarding these
solutions:
(A) The boiling point of the solution “X” will be higher than that of “Y”
(B) The osmotic pressure of the solution “X” will be higher than that of “Y”
(C) The freezing point of the solution “X” will be lower than that of “Y”
(D) The relative lowering of vapour pressure of both the solutions will be the same

27. When a lead storage battery is discharged

(A) SO2 is evolved (B) lead sulphate is produced at both electrodes
(C) sulphuric acid is consumed (D) water is formed

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PH-VIII-2018-PCM-22

28. In which of the following pair(s) the minerals are converted into metals by self–reduction process ?
(A) Cu2S, PbS (B) PbS, HgS (C) PbS, ZnS (D) Ag2S, Cu2S

29. Which of the following is a correct statement ?

(A) Cassiterite is the ore of tin (B) Galena is the ore of lead
(C) Calamine is the ore of zinc (D) Cryolite is the ore of aluminium


30. Identify the correct statement(s) after observing the following four structures of Co  en 2 Cl2 
 
complex cation:
en en Cl en
Cl Cl Cl

en en
Co 3 Co 3 Co 3 Co 3

Cl Cl Cl
en
en en
Cl

(a) (b) (c) (d)

(A) a and c are identical structures (B) b and d are identical structures
(C) b and d are enantiomers (D) b and c are diastereomers

31. The azeotropic solution of two miscible liquids:

(A) Can be separated by simple distillation
(B) May show positive or negative deviation from Raoult’s Law
(C) Behaves as a supersaturated solution
(D) Behaves like a single component and boils at a constant temperature at a given pressure.

32. For the cell Zn  s  Zn2  aq Cu2  aq Cu  s  . The cell potential Ecell can be increased

(A) by increasing Cu2  (B) by increasing  Zn2 

   
(C) by decreasing Cu 2 
(D) by decreasing Zn 2 
   

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 PH-VIII-2018-PCM-23

SECTION 3 (Maximum Marks: 18)

 This section contains TWO paragraphs.
 Based on each paragraph, there are TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.

Paragraph–1

A bluish green coloured compound ‘A’ on heating gives two products solid residue ‘B’ and gas ‘C’. A metal ‘D’
is deposited on passing H2 through heated ‘B’. The compo und ‘A’ and ‘B’ are insoluble in water. ‘B’ is black
in colour, dissolves in HCl and on treatment with K4[Fe(CN)6] gives a chocolate brown ppt of compound ‘E’. ‘C’
is colourless, odoulress gas and turns lime water milky.

33. Compound ‘A’ is

(A) CuSO4 (B) CuCO3 (C) FeSO4 (D) CrCl3

34. The compounds ‘B’ and ‘C’ are respectively

(A) CuS, SO2 (B) CuO, CO2 (C) FeO, H2S (D) Cr2O3, CO

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PH-VIII-2018-PCM-24

Paragraph–2

The Ellingham diagram for zinc, magnesium and carbon converting into corresponding oxides is
shown below

35. At what temperature, zinc and carbon have equal affinity of oxygen?
(A) 1000C (B) 1500C (C) 500C (D) 1200C

36. At 1100C , which reaction is spontaneous to a maximum extent?

(A) MgO  C  Mg  CO (B) ZnO  C  Zn  CO
(C) MgO  Zn  Mg  ZnO (D) ZnO  Mg  MgO  Zn

SECTION 1 (Maximum Marks: 28)

 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to all the correct option in the ORS.

37. Two small squares on a chess board are chosen at random. Probability that they have a common
side is
1 1 1 5
(A) (B) (C) (D)
3 9 18 18

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 PH-VIII-2018-PCM-25

PART III: MATHEMATICS

The coefficients of a quadratic equation ax + bx + c = 0 (a  b  c) are chosen from first three prime
2
38.
numbers, the probability that roots of the equation are real is
1 2 1 3
(A) (B) (C) (D)
3 3 4 4

1
39. A boy is throwing stones at a target. The probability of hitting the target at any trial is . The
2
th th
probability of hitting the target 5 time at the 10 throw is
10 10
5 63 C C4
(A) 10 (B) 9 (C) 105 (D)
2 2 2 210

40. A dice is thrown (2n + 1) times. The probability that faces with even numbers appear odd number of
times is
2n  1 n 1 n
(A) (B) (C) (D) none of these
2n  3 2n  1 2n  1

41. A natural number x is chosen at random from the first 100 natural numbers. The probability that
100
x+ > 50 is
x
1 11 1
(A) (B) (C) (D) none of these
10 50 20

42. A wire of length  is cut into three pieces. What is the probability that the three pieces form a triangle ?
1 1 2
(A) (B) (C) (D) none of these
2 4 3

43. Suppose X is a binomial variate B(5, p) and P(X = 2) = P(X – 3), then p is equal to
1 1 1 1
(A) (B) (C) (D)
2 3 4 5

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PH-VIII-2018-PCM-26

SECTION 2 (Maximum Marks: 15)

 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options
is(are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4
marks; darkening only (A) and (D) will get +2 marks; and darkening (A) and (B) will get –2 marks, as a
wrong option is also darkened.

44. The number of ways in which 10 candidates A1, A2, ......, A10 can be ranked, so that A1 is always
above A2 is
10!
(B) 8!  C2
10 10 10
(A) (C) P2 (D) C2
2

45. The number of ways of arranging seven persons (having A, B, C and D among them) in a row so that
A, B, C and D are always in order A–B–C–D (not necessarily together) is
(C) 6  C4
7 7
(A) 210 (B) 5040 (D) P3

46. Triplet (x, y, z) is chosen from the set {1, 2, 3, ......, n}, such that x  y < z. The number of such that
triplets is
2 n+1 n n n
(A) n (B) C3 (C) C2 (D) C2 + C3

1
47. Let A and B are two independent events. The probability that both A and B happen is and the
12
1
probability that neither A nor B happens is , then
2
1 1 1 1
(A) P(A) = , P(B) = (B) P(A) = , P(B) =
3 4 2 6
1 1 1 1
(C) P(A) = , P(B) = (D) P(A) = , P(B) =
6 2 4 3

48. The letters of the word PROBABILITY are written down at random in a row. Let E 1 denotes the event
that two I’s are together and E2 denotes the event that two B’s are together, then
2 2 18 1
(A) P(E1) = P(E2) = (B) P(E1  E2) = (C) P(E1  E2) = (D) P(E1 / E2) =
11 55 55 5

49. Let X be a set containing n elements. If two subsets A and B of X are picked at random, the
probability that A and B have the same number of elements is
2n
C 1 1 3  5      2n  1 3n
(A) 2nn (B) 2n (C) (D) n
2 Cn 2  n!
n
4

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 PH-VIII-2018-PCM-27

50. Two numbers b and c are chosen at random (with replacement from the numbers 1, 2, 3, 4, 5, 6, 7, 8
and 9). The probability that x + bx + c > 0 for all x  R is
2

17 32 82 45
(A) (B) (C) (D)
123 81 125 143

SECTION 3 (Maximum Marks: 18)

 This section contains TWO paragraphs.
 Based on each paragraph, there are TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.

Paragraph–1

Different words are being formed by arranging the letters of the word “SUCCESS”. All the words obtained by
written in the form of a dictionary.

51. The number of words in which the two C are together but no two S are together is
(A) 120 (B) 96 (C) 24 (D) 420

52. The number of words in which the consonants appear in alphabetic order is
(A) 42 (B) 40 (C) 420 (D) 280

Paragraph–2

If a particular experiment be given n (a finite) independent trials.

If the probability of success in one trial (say) p
We get probability of failure, q = (1 – p)
n r n–r
The probability of r success in n trials = Crp q .

1
53. The probability of a man hitting a target in one fire is . Atleast n times he must fire at the target that
4
2
the chances of hitting the target at least once will exceed , then n is
3
(A) 2 (B) 4 (C) 6 (D) 8

54. A coin is tossed 4 times whose faces are marked with the numbers 5 and 3. The odds in favour of
getting a sum less than 15 is
5 5 16 11
(A) (B) (C) (D)
16 11 5 5

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PH-VIII-2018-PCM-28

FIITJEE INTERNAL TEST

IIT – JEE 2018
PHASE – VIII_PAPER – II_SET - A
ANSWERS
PHYSICS
1. C 2. A 3. B 4. B

5. C 6. B 7. D 8. A

9. ABCD 10. BC 11. A,D 12. A,D

13. ABCD 14. ABD 15. C 16. B

17. B 18. A

CHEMISTRY
19. B 20. B 21. D 22. C

23. C 24. B 25. A 26. A,B,C

27. B, C, D 28. A, B 29. A, B, C, D 30. A, C, D

31. B, D 32. A, D 33. B 34. B

35. A 36. D

MATHEMATICS
37. C 38. A 39. B 40. D

41. D 42. B 43. A 44. AB

45. ACD 46. BD 47. AD 48. ABCD

49. AC 50. B 51. C 52. A

53. B 54. B

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 PH-VIII-2018-PCM-29

FIITJEE INTERNAL TEST

IIT – JEE 2018
PHASE – VIII_PAPER – I_SET – B
Time: 3 hours Maximum Marks: 183

INSTRUCTIONS:
A. General
1. This booklet is your Question Paper containing 54 questions.
10. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and
electronic gadgets in any form are not allowed to be carried inside the examination hall.
11. Fill in the boxes provided for Name and Enrolment No.
12. The answer sheet, a machine-readable Objective Response (ORS), is provided separately.
13. DO NOT TAMPER WITH / MULTILATE THE ORS OR THE BOOKLET.
B. Filling in the OMR:
6. The instructions for the OMR sheet are given on the OMR itself.
C. Question paper format & Marking Scheme
21. Each part has three sections as detailed in the following table:
Section Question Number of Category wise Marks Each Question Maximum
Type Questions Full Marks Partial Marks Zero Marks Negative marks of
Marks the
section
One or +4 +1 0 –2 28
1 more 7 If only the For darkening a If none of the In all
correct bubble(s) bubble bubbles is other
option (s) corresponding to corresponding darkened cases
all the correct to each correct
option(s) is(are) option,
darkened provided NO
incorrect option
is darkened
Single +3 ––– 0 ––– 15
2 digit 5 If only the bubble In all other
integer corresponding to cases
(0–9) the correct
answer is
darkened.
Single +3 ––– 0 –1 18
3 correct 6 If only the bubble If none of the In all
option corresponding to bubbles is other
the correct option darkened cases
is darkened

Don’t write / mark your answers in this question booklet.

If you mark the answers in question booklet, you will not be allowed to continue the exam.

NAME:

ENROLLMENT NO.:

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PH-VIII-2018-PCM-30

PAPER–I
PART I: PHYSICS
SECTION 1 (Maximum Marks: 28)
 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options
is(are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4
marks; darkening only (A) and (D) will get +2 marks; and darkening (A) and (B) will get –2 marks, as a
wrong option is also darkened.

1. A converging lens is used to form an image on a screen. When the upper half of the lens is covered
by an opaque screen
(A) complete image will not be formed
(B) complete image will be formed
(C) intensity of the image will not change
(D) intensity of the image will change

2. In YDSE  = 6000 Å, d = 6 mm and D = 2m.

(A) fringe width is 0.2 mm
rd
(B) position of 3 maxima (from central maxima) is 0.6 mm
nd
(C) position of 2 minima is 0.3 mm
(D) fringe width is 0.3 mm

3. For which of the pairs of u and f for a mirror image is smaller in size
(A) u = - 10 cm, f = 20 cm (B) u = - 20 cm, f = - 30cm
(C) u = - 45 cm, f = - 10 cm (D) u = - 60 cm, f = 30cm

4. Refractive index of an equilateral prism is 2

(A) minimum deviation from this prism can be 30°
(B) minimum deviation from this prism can be 45°
(C) at angle of incidence = 45°, deviation is minimum
(D) at angle of incidence = 60°, deviation is minimum

5. Which of the following transitions in He ion will give rise to a spectral line which has the same
wavelength as some spectral line in the hydrogen atom?
(A) n = 4 to n = 2 (B) n = 6 to n = 2 (C) n = 6 to n = 3 (D) n = 8 to n=4

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 PH-VIII-2018-PCM-31

are 1, 2 and 3 respectively. Then

208 206 204
6. The wavelength of K X-rays for lead isotopes Pb , Pb , Pb
relation among 1, 2 and 3 can be
(A) 1 = 2 = 3 (B) 1 > 2 > 3 (C) 1 < 2 <3 (D) 2 = 12

7. An electron in a hydrogen atom makes a transition n1n2 where n1 and n2 are principal quantum
numbers of the two states. Assume the Bohr model to be valid. The time period of the electron in the
initial state is eight times that in the final state. The possible values of n 1 and n2 are :
(A) n1=4, n2=2 (B) n1=8, n2=4 (C) n1=8, n2=1 (D) n1=6, n2=3

SECTION 2 (Maximum Marks: 15)

 This section contains FIVE questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
 For each question, darken the bubble corresponding to the correct integer the ORS.
0
8. A ray of light undergoes deviation of 30 . when incident on an equilateral prism of refractive index
2 . The angle made by the ray inside the prism with the base of the prism is k 150  . Find k.

9. The maximum intensity in Young's double slit experiment is I0. Distance between the slits is d = 5 , where
 is the wavelength of monochromatic light used in the experiment. The intensity of light in front of one of
I
the slits on a screen at a distance D  10 d is 0 , then N is?
N

r
10. The electric potential between a proton and an electron is given by V = V 0 In , where r0 is a
r0
constant. Assuming Bohr’s model to be applicable, the variation of r n with n is rn nk where n being
principal quantum number then find k.

11. The energy of a photon is equal to the kinetic energy of a proton. The energy of the photon is E. Let
1
1 be the de-Broglie wavelength of the proton and 2 be the wavelength of the photon. The ratio
2
1
is proportional to E n . Find n

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12 The work function of a substance is 4.0 eV. The longest wavelength of light that can cause
photoelectron emission from this substance is approximately is n  107 m . Find n.

SECTION 3 (Maximum Marks: 18)

 This section contains SIX questions of matching type.
 This section contains TWO tables (each having 3 columns and 4 rows)
 Based on the table, there are THREE questions
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.

A lens is made up of a material of

refractive index 2 and is placed in
1 2
medium of refractive index 1. Radii of
curvature of lens are R1 and R2 for the R1
R2
surfaces shown in figure.

Column – 1 Column –2 Column –3

I 2= 1.5 i 1= 1.3 p R1 = +20 cm
II 2= 1.3 ii 1= 1.3 q R1 = –20 cm
III 2= 2 iii 1= 1.3 r R1 = + 
IV 2= 1 iv 1= 1.3 s R1 = – 
Answer the Following Questions

13. For R2 = +  , the combination will be diverging for

(A) I,i,p (B) II, i,r (C) III,i,r (D) IV,i,p

14. For R2 = +20 cm, the combination will be diverging for

(A) I,i,p (B) II, ii,q (C) III,iii,r (D) IV,iv,p

15. For R2 = +  , the combination will be converging for

(A) I,i,p (B) II, ii,q (C) III,iii,r (D) IV,iv,s

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In Bohr’s atomic model for hydrogen like atoms

Column – 1 Column –2 Column –3

I If electron jumps from n = i speed of electron will p angular momentum of
4 to n = 2 become 2 times electron will become 2
times
II If electron jumps from n = ii speed of electron will q angular momentum of
6 to n = 2 become 3 times electron will become 3
times
III If electron jumps from n = iii speed of electron will r angular momentum of
3 to n = 1 become 1/2 times electron will become 1/2
times
IV If electron jumps from n = iv speed of electron will s angular momentum of
6 to n = 3 become 1/3 times electron will become 1/3
times
Answer the Following Questions

16
16. For wave length of emitted radiation is  
3R
(A) I,iii,p (B) II,iii,p (C) I,i,r (D) II,i,r
36
17. For wave length of emitted radiation is  
8R
(A) II,iv,q (B) I, ii,s (C) II,ii,s (D) I,iv,q
9
18. For wave length of emitted radiation is  
8R
(A) III,iv,q (B) II, iv,q (C) III,ii,s (D) II,ii,s

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PH-VIII-2018-PCM-34

PART II: CHEMISTRY

SECTION 1 (Maximum Marks: 28)
 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options
is(are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4
marks; darkening only (A) and (D) will get +2 marks; and darkening (A) and (B) will get –2 marks, as a
wrong option is also darkened.

air oxygen
19. A (Sulphide ore) + NaCN B (complex) + Na2S Na2SO4 then B is
(A) Paramagnetic (B) diamagnetic
(C) Linear complex (D) co ordination number of central atom is 4

20. 2.08g of BaCl2 is dissolved in 500 ml of aq. Solution. The specific conductance of the solution is 0.02
–1
Mho.cm then, (equivalent conductance =  ; molar conductance = m)
(A) m = 500 Mho. cm / mol (B)  = 500 Mho.cm / gr. eq.
2 2

(C) m = 1000 Mho. cm / mol. (D)  = 1000 Mho. cm / gr. eq

2 2

21. The cell reaction of an electrolyte cell is given as:

Fe  2Fe3   3Fe2 with E0  0.404V & G0  2.424J
If the cell reaction is to be written as:
2Fe  4Fe3   6Fe2 ,
then which of the following statements will be correct for the above reaction? [A, B, D]
(A) E 0 can be given by 0.404 V (B) G 0 can be given by – 4.848 V
(C) E and G 0 are 0.404 V – 2.424 J respectively
0

(D) Then value of ‘n’ changes from 6 to 12

22. In electrolytic concentration cell:

(A) the electrode material and the solution in both half-cells are composed of the same substances
(B) only the concentrations of solutions of the same substances is different
(C) Eocell  0
 0.0591 
(D) the Nernst equation reduces to Ecell    logQ at 25C
 n 

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 PH-VIII-2018-PCM-35

23. Which of the following statement(s) is/are correct?

(A) Boiling point order: NH3  SbH3  AsH3  PH3
(B) Dipole moment order: NH3  SbH3  AsH3  PH3
(C) SbF5  XeF4  A. The hybridization and shape of the anionic part of A are
sp3d 2 and octahedral respectively.
 
(D) SbF5 reacts with XeF6 to form an adduct.  XeF5   SbF6 

24. For a process to be spontaneous:


(A) Gsystem
T,P
0 (B) Ssystem  Ssurrounding  0

(C) Ssystem  Ssurrounding  0 

(D) Gsystem
T,P
0

25. Which of the following pairs of solutions is isotonic ?

(A) 6% (w/v) urea and 6% (w/v) glucose (B) 18% (w/v) fructose and 18% (w/v) glucose
(C) 6% (w/v) urea and 18% (w/v) fructose (D) 34.2% (w/v) sucrose and 60%(w/v) glucose

SECTION 2 (Maximum Marks: 15)

 This section contains FIVE questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
 For each question, darken the bubble corresponding to the correct integer the ORS.

The equilibrium constant for the reaction Fe2  Ce4 Fe3  Ce3 is 1 x 10 . at 298 K. The
y
26.

value of ‘y’ is [Given : E0  1.44V; E0  0.909V , R = 8.314 J/K.mol)

Ce4  / Ce3  Fe3  / Fe2

27. Find the current in amperes required to deposit 2.977 g of Pd by the electrolysis of an aqueous
solution of Pd4 salt per 1 hour (At. Wt. of Pd = 106.4)

n
28. How many geometrical isomers are possible for square planar complex Mabcd ?

29. The difference of the effective atomic number and the number of unpaired electrons of Fe in
x
K 4 Fe  CN6   x . Find the value of .
  4

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 wt 
30. The vapour pressure of a 5%   aqueous solution of a non–volatile organic substance at 373 K is
 wt 
745 mm. The molecular mass of the solute is ‘8x’. then ‘x’ is (vapour pressure of pure water at 373
K is 760 mm)

SECTION 3 (Maximum Marks: 18)

 This section contains SIX questions of matching type.
 This section contains TWO tables (each having 3 columns and 4 rows)
 Based on the table, there are THREE questions
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.

Answer Q.34, Q.35 and Q.36 by appropriately matching the information given in the three columns of
the following table

Column – I Column – II Column – III

(I) n–Hexane + n–Heptane (i) Non–ideal solution (P) PA  PA0 XA ; PB
 PB0 XB
(II) CCl4 + CHCl3 (ii) Ideal solution (Q) PA  PA0 XA ; PB  PB0 XB
(III) Water + CH3OH Positive deviation from
(iii) (R) PA  PA0 XA ; PB  PB0 XB
Raoult’s law
(IV) CH3OH + CH3COOH Negative deviation from Hmix  0; Vmix  0
(iv) (S)
Raoult’s law

31. The correct combination is

(A) IV, i, iv, R, S (B) IV, II, P (C) IV, i, P (D) IV, i, iii, R, S

32. The correct combination is

(A) III, ii, Q (B) III, ii, P, S (C) III, i, iii, Q (D) III, i, iii, R, S

33. The correct combination is

(A) I, i, Q, S (B) I, i, R, S (C) I, ii, P (D) I, i, P

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 PH-VIII-2018-PCM-37

Answer Q.31, Q.32 and Q.33 by appropriately matching the information given in the three columns of
the following table

Column – I Column – II Column – III

(I) Kohlrausch Law  m / m
0 Increase with increase in
the distance between
(i) (P)
parallel plates
(Electrodes)
(II) m 1
(ii)  (Q) Decrease with dilution
R A
(III) K m0
Ca3 PO4 2 
(iii) (R) Increase with dilution
30Ca2  20PO34
(IV)  1000
(iv) K (S)   anion  cation
M

34. The correct combination is

(A) I, iii, S (B) I, ii, S (C) I, iii, R (D) I, iv, S

35. The correct combination is

(A) III, ii, R (B) III, ii, Q (C) III, iv, Q, P (D) III, ii, S

36. The correct combination is

(A) II, iv, R (B) II, iv, Q (C) II, iv, P, R (D) II, ii, S

PART III: MATHEMATICS

SECTION 1 (Maximum Marks: 28)
 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options
is(are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4
marks; darkening only (A) and (D) will get +2 marks; and darkening (A) and (B) will get –2 marks, as a
wrong option is also darkened.

37. The probabilities that a student in Mathematics, Physics and Chemistry are ,  and  respectively. Of
these subjects, a student has a 75% chance of passing in atleast one, a 50% chance of passing in
atleast two and a 40% chance of passing in exactly two subjects. Which of the following relations are
true ?
19 27 1 1
(A)  +  +  = (B)  +  +  = (C)  = (D)  =
20 20 10 4

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38. A student appears for tests I, II and III. The student is successful if he passes either in tests I and II or
1
tests I and III. The probabilities of the student passing in tests I, II, III are p, q, and respectively. If
2
1
the probability that the student is successful is , then
2
2 1
(A) p = 1, q = 0 (B) p = , q =
3 2
3 2
(C) p = , q = (D) there are infinitely many values of p and q
5 3

39. A class has 30 students. The following prizes are to be awarded to the students of this class, first and
second in Mathematics, first and second in Physics; first in Chemistry and first in Biology. If N denote
the number of ways in which this can be done, then
(A) 400 | N (B) 600 | N
(C) 8100 | N (D) N is divisible by four distinct prime numbers

40. A card is selected at random from cards numbered as 00, 01, 02, ......, 99. An event is said to have
occurred. If product of digits of the card number is 16. If card is selected 5 times with replacement
each time, then the probability that the even occurs exactly three times is
2 3 3 2 3 3
 3   97   3   97   03   97  3 2
(A) 5 C3     (B) 5 C3     (C) 5 C3     (D) 10 (0.03) ) (0.97)
 100   100   100   100   100   100 

41. In a class tournament when the participants were to play one game with another, two class players
fell ill, having played 3 games each. If the total number of games played is 84, the number of
participants at the beginning was
6
(A) 15 (B) 30 (C) C2 (D) 48

42. Sanjay has 10 friends among whom two are marred to each other. She wishes to invite 5 of the them
for a party. If the married couple refuse to attend separately, then the number of different ways in
which can invite five friends is
(B) 2  C3 (C) C5 – 2  C4
8 8 10 8
(A) C5 (D) none of these

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43. The number of ways to select 2 numbers from {0, 1, 2, 3, 4} such that the sum of the squares of the
selected numbers is divisible by 5 are (repetition of digits is allowed)
9 9
(A) C1 (B) C8 (C) 9 (D) 7

SECTION 2 (Maximum Marks: 15)

 This section contains FIVE questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
 For each question, darken the bubble corresponding to the correct integer the ORS.

44. There are three piles of identical red, blue and green balls and each pile contains at least 10 balls.
The number of ways of selecting 10 balls if twice as many red balls as green balls are to be selected
is


C2
45. The maximum value of 1
=
C4

46. There are four balls of different colours and four boxes of colours, same as those of the balls. The
number of ways in which the balls, one each in a box, could be placed such that a ball does not go to
a box of its own colour is

47. The tens digit of 1! + 2! + 3! + ...... + 97! is

2 2
48. The number of positive integral solutions of x + y = 352706 is

SECTION 3 (Maximum Marks: 18)

 This section contains SIX questions of matching type.
 This section contains TWO tables (each having 3 columns and 4 rows)
 Based on the table, there are THREE questions
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.

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By observing column 1, column 2, column 3 establish the relation and answer to the questions below:

Column 1 Column 2 Column 3

3 2 1 (i) P(A  B) 1
(I) P(A) = , P(B) = , P(A  B) = (P)
4 5 4 8
1 1 5 (ii) P(A  B) 9
(II) P(A) = ; P(B) = ; P(A  B) = (Q)
4 2 8 20
1 1
(III) P(A) = ; P(B) ; P(A  B) =
1 (iii) P A  B  (R)
21
4 2 5 20
3
(IV) P(A  B) = ; P(A  B) =
1  
(iv) P A  P B   (S)
9
4 5 10

49. Which of the following options is CORRECT

(A) (I) (ii) (S) (B) (I) (iv) (R) (C) (I) (iii) (P) (D) (I) (ii) (P)

50. Which of the following options is CORRECT

(A) (II) (i) (P) (B) (II) (ii) (Q) (C) (III) (iii) (R) (D) (I) (ii) (Q)

51. Which of the following options is CORRECT

(A) (III) (iii) (Q) (B) (II) (ii) (Q) (C) (I) (iv) (R) (D) (I) (ii) (P)

By appropriately matching the information given in the three columns of the following table.
Column 1 – Equation of Hyperbola, Column 2 – Eccentricity may lie in interval, Column 3 – length of latus
rectum.

Column 1 Column 2 Column 3

 
2 2
(I) 9x – 4y = 36 (i) 2, 3 8 2
(P)
3

(II)
 x  1 y
2

1
2 (ii)  3,2  (Q)
3
6 8 2
2 2
(III) 3x – 6x – 4y + 16y – 14 = 0 (iii) (2, 3) (R) 9

(IV)
x 2

y 2
1
(iv) 1, 2   (S) 3
9 6

52. Which of the following options is the only CORRECT combination ?

(A) (I) (i) (S) (B) (I) (ii) (R) (C) (II) (ii) (S) (D) (iII) (ii) (R)

53. Which of the following options is the only CORRECT combination ?

(A) (II) (i) (R) (B) (II) (i) (P) (C) (III) (i) (P) (D) (IV) (iii) (R)

54. Which of the following options is the only CORRECT combination ?

(A) (III) (iv) (Q) (B) (III) (iii) (Q) (C) (II) (iv) (Q) (D) (IV) (iii) (P)

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FIITJEE INTERNAL TEST

IIT – JEE 2018
PHASE – VIII_PAPER – I_SET-B
ANSWERS
PHYSICS
1. B,D 2. A,B,C 3. A,C,D 4. A,C
5. A,B,D 6. A,D 7. A,B,D 8. 0
9. 2 10 1 11. 2 12 3
13. D 14. C 15. A 16. C
17. C 18. C

CHEMISTRY
19. B, C 20. B, C 21. B, D 22. A, B, C
23. A, B, C, D 24. B, D 25. B, C 26. 9
27. 3 28. 3 29. 9 30. 6
31. A 32. C 33. D 34. A
35. B 36. A

MATHEMATICS
37. BC 38. ABCD 39. ABCD 40. BD
41. AC 42. BC 43. ABC 44. 4
45. 3 46. 9 47. 1 48. 0
49. A 50. A 51. A 52. B
53. B 54. A

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FIITJEE INTERNAL TEST

IIT – JEE 2018
PHASE – VIII_PAPER – II_SET – B
Time: 3 hours Maximum Marks: 183

INSTRUCTIONS:
A. General
1. This booklet is your Question Paper containing 54 questions.
14. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and
electronic gadgets in any form are not allowed to be carried inside the examination hall.
15. Fill in the boxes provided for Name and Enrolment No.
16. The answer sheet, a machine-readable Objective Response (ORS), is provided separately.
17. DO NOT TAMPER WITH / MULTILATE THE ORS OR THE BOOKLET.
B. Filling in the OMR:
6. The instructions for the OMR sheet are given on the OMR itself.
C. Question paper format & Marking Scheme
21. Each part has three sections as detailed in the following table:
Section Question Number of Category wise Marks Each Question Maximum
Type Questions Full Marks Partial Marks Zero Negative marks of
Marks Marks the
section
1 Single +3 ––– 0 –1 21
Correct 7 If only the bubble If none of In all
Option corresponding to the other
the correct option bubbles is cases
is darkened darkened
2 One or +4 +1 0 –2 28
more 7 If only the For darkening a If none of In all
correct bubble(s) bubble the other
option(s) corresponding to corresponding bubbles is case.
all the correct to each correct darkened.
option(s) is (are) option,
darkened. provided NO
incorrect option
is darkened.
3 Compreh +3 ––– 0 ––– 12
ension 4 If only the bubble In all other
corresponding to case.
the correct option
is darkened

Don’t write / mark your answers in this question booklet.

If you mark the answers in question booklet, you will not be allowed to continue the exam.

NAME:

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PAPER–I
PART I: PHYSICS
SECTION 1 (Maximum Marks: 28)
 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to all the correct option in the ORS.

1. The wavefront of a light beam is given by the equation x + 2y + 3x = c (where c is arbitrary constant),
 X  Y
then the angle made by the direction of light with the y–axis is given as cos1   , then find  
 Y  X
(A) 4 (B) 7 (C) 6 (D) 5

2. A retro–reflector is an optical device which reflects light coming

from infinity back directly recently “scotehlite” sphere have been
invented which behave as a retro reflector (figure). The index of
refraction for such sphere is

1
(A) 2 (B) 3 (C) (D) 2
2

3. As shown in the figure, light is incident normally on one face of

a prism. A liquid of refractive index  is placed on the
3
horizontal face AC. The refractive index of the prism is . If
2
total internal reflection taking place on the face AC,  should be
less than

2 3 3 3 3 5 1
(A) (B) (C) (D)
5 4 4 2

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4. A monochromatic beam of light of 6000 Å is used in YDSE setup. The

two slits are covered with two thin films of equal thickness t but of
different refractive indices as shown in the figure. considering the
intensity of the incident beam on the slits to be I0, find the point on the
–4
screen (in x 10 m) at which intensity is I0 and is just above the
central maxima. (Assume that there is no change in intensity of the
light after passing through the films)

(A) 2.2 (B) 4.3 (C) 3 (D) 5

 3
5. A plano-convex glass lens  g   of radius of curvature R = 10
 2
cm is placed at a distance of ‘b’ from a concave lens of focal
length 20 cm. If was observed that if an object ‘O’ is placed at
distance ‘a’ as shown then the position of final image is
independent of ‘b’. The value of a is
(A) 15 cm (B) 20 cm (C) 25 cm (D) 30 cm

6. AB and CD are surfaces of two slabs as shown in the figure. The medium 1  2
Q
A B
between the slabs has refractive index 2. Refractive index of the slab

above AB is 2 and below CD is 3 . The minimum angle of incidence 2  2
at Q so that the ray is totally reflected by both the slabs is C D
3  3
0 0 0 0
(A) 30 (B) 48 (C) 60 (D) 90

7. A plane mirror is made of a glass slab (g = 1.5) 2.5 cm thick and silvered on its back. A point object is
placed 5 cm in front of the unsilvered face of the mirror. If the position of the final image seen by a
person standing in front of the mirror is ____ from unsilvered face
25 16
(A) cm (B) 25 cm (C) cm (D) 22 cm
3 3

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SECTION 2 (Maximum Marks: 15)

 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options
is(are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4
marks; darkening only (A) and (D) will get +2 marks; and darkening (A) and (B) will get –2 marks, as a
wrong option is also darkened.

8. Two point monochromatic and coherent sources of light of wavelength  are placed on the dotted
line in front of an infinite screen. The source emit waves in phase with each other. The distance
between S1 and S 2 is ‘d’ while their distance form the screen is much larger. Then:
(A) If d  7 / 2, O will be a minima
(B) If d  4.3 , there will be a total of 8 minima on screen
(C) If d  7 , O will be a maxima
(D) If d   , there will be only one maxima on the screen

5 cm/s

9. An object is moving with a velocity of 5 cm/s at an angle of y

0
60 with respect to the optic axis of a concave mirror. The
60
object is at a distance of 50 cm from the mirror. The velocity x
of image at the given instant is found to be 10iˆ  K 3 ˆj
cm/sec (K is a positive integer)
50 cm

(A) the focal length of the mirror is 100 cm

(B) the value of K is 5
(C) the image must be real
(D) the image must be virtual

10. The figure shows the variation of photocurrent with anode

potential for a photosensitive surface for three different
radiations. Let Ia, Ib and Ic be the intensities and fa, fb, and fc be
the frequencies for the curves a, b and c respectively:
(A) fa = fb and Ia  Ib (B) fa = fc and Ia = Ic
(C) fa = fb and Ia = Ib (D) fb  fc and Ib = Ic

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PH-VIII-2018-PCM-46

are 1, 2 and 3 respectively. Then:

208 206 204
11. The wavelength of K X-rays for lead isotopes Pb , Pb , Pb
(A) 1 = 2 = 3 (B) 1 > 2 > 3 (C) 1 < 2 <3 (D) 2 = 12

12. The graph shows the variation of potential energy  of a proton 

with its distance ‘r’ from a fixed sodium nucleus, as it approaches
the nucleus placed at origin O. Then the portion B
(A) AB indicates nuclear attraction
(B) AB indicates nuclear repulsion A
(C) BC indicates nuclear attraction
(D) BC represents electrostatic interaction O C r

–7
13 A two–slit interference experiment uses coherent light of wavelength 5 x 10 m. Intensity in the
interference pattern for the following points are I1, I2, I3 and I4, respectively.
–7
(1) a point that is close to one slit than the other by 5 x 10 m
4
(2) a point where the light waves received from the two slits are out of phase by rad
3
–7
(3) a point that is closer to one slit than the other by 7.5 x 10 m

(4) a point where the light waves received by the two slits are out of phase by rad
2
Then, which of following statements is/are correct?
(A) I1 > I4 > I2 > I3 (B) I1 < I4 < I2 < I3 (C) 3 I2 = I4 (D) I3 = 0

14 When barium is irradiated by a light of  = 4000 Å, all the photoelectrons emitted are bent in a circle of
–6
radius 50 cm by a magnetic field of flux density 5.26 x 10 T. Then,
(A) the kinetic energy of fastest photoelectron is 0.6 eV
(B) work function of the metal is 2.5 eV
6 –1
(C) the maximum velocity of photoelectron is 0.46 x 10 ms
(D) the stopping potential for photoelectric effect is 0.6 V

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 PH-VIII-2018-PCM-47

SECTION 3 (Maximum Marks: 18)

 This section contains TWO paragraphs.
 Based on each paragraph, there are TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.

Paragraph–1
An electron is orbiting in a circular orbit of radius r under the influence of a constant magnetic field B.
Assuming that Bohr’s postulate regarding the quantisation of angular momentum holds good for this electron
[ii = Planck’s constant, e = charge on electron and m = mass of electron]

15. Radius of nth orbit of the electron will be:

2nh 2nh neh 2n e h
(A) (B) (C) (D)
 Be 2 Be 2 Be  Be

16. Kinetic energy of the electron in nth orbit will be:

nhBe nhBe nhB nhB
(A) (B) (C) (D)
4 m 2 m 2 em 4 em

Paragraph–2
–7
In YDSE, the source is red light of wavelength 7 x 10 m. When a thin glass plate of refractive index 1.5 is put
–3
in the path of one of the interfering beams, the central bright fringe shifts by 10 m to the position previously
occupied by the 5th bright fringe.

17. What is the thickness of the plate?

(A) 5 m (B) 0.005 m (C) 7 m (D) 0.007 m
–7
18. If the source is now changed to green light of wavelength 5 x 10 m, the central fringe shifts to a
position initially occupied by the 6th bright fringe due to red light. What will be refractive index of glass
plate for the 2nd light for changed source of light?
(A) 2.6 (B) 1.6 (C) 1.2 (D) 2.2

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PH-VIII-2018-PCM-48

PART II: CHEMISTRY

SECTION 1 (Maximum Marks: 28)
 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to all the correct option in the ORS.

19. A given mass of gas expands from the state A to the state B by three paths
1,2 and 3 as shown in the figure. If w1,w 2 and w 3 respectively be the
work done by the gas along three paths then:

(A) w1  w 2  w3 (B) w1  w 2  w3 (C) w1  w 2  w3 (D) w 2  w3  w1

20. When H2S gas is passed through ammonical sodium nitroprusside solution, then
(A) The complex compound Na4[Fe(CN)5NOS] is formed
2
(B) The complex Fe  CN3 NOS is formed
4
(C) The complex Fe  CN5 NOS is formed (D) None of them is produced

20
21. An ion is reduced to the element when it absorbs 6 x 10 electrons. The no. of equivalents of the ion
is
(A) 0.1 (B) 0.01 (C) 0.001 (D) 0.0001

22. For Button cell, the emf vs time graph is:

 
emf emf
(A) (B)

t t

 
emf emf
(C) (D)

t t

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 PH-VIII-2018-PCM-49

23. Identify the tetrahedral complex

2 2 2 2
(A) Ni  CN4  (B) Cu NH3   (C) PtCl4  (D) Co  SCN4 
   4  
–1 2 –
24. At 25C the equivalent conductance at infinite dilution for HCl solution is 4250 ohm cm equivalent
1 –1 –1
, while its specific conductance is 3.825 ohm cm . If the apparent degree of dissociation is 90%,
the normality of the solution is
(A) 0.90 N (B) 1.0 N (C) 1.1 N (D) 1.2 N

25. Buna-S is a
(A) condensation polymer formed by styrene and 1,3-butadiene
(B) addition polymer formed by styrene and 1,3-butadiene
(C) condensation polymer of hexamethylene diamine and adipic acid
(D) addition polymer of hexamethylene diamine and adipic acid

SECTION 2 (Maximum Marks: 15)

 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options
is(are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4
marks; darkening only (A) and (D) will get +2 marks; and darkening (A) and (B) will get –2 marks, as a
wrong option is also darkened.

26. The azeotropic solution of two miscible liquids:

(A) Can be separated by simple distillation
(B) May show positive or negative deviation from Raoult’s Law
(C) Behaves as a supersaturated solution
(D) Behaves like a single component and boils at a constant temperature at a given pressure.

27. For the cell Zn  s  Zn2  aq Cu2  aq Cu  s  . The cell potential Ecell can be increased

(A) by increasing Cu2  (B) by increasing  Zn2 

   
(C) by decreasing Cu 
2
(D) by decreasing  Zn 
2
   

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PH-VIII-2018-PCM-50

28. Which of the following is a correct statement ?

(A) Cassiterite is the ore of tin (B) Galena is the ore of lead
(C) Calamine is the ore of zinc (D) Cryolite is the ore of aluminium


29. Identify the correct statement(s) after observing the following four structures of Co  en 2 Cl2 
 
complex cation:
en en Cl en
Cl Cl Cl

en en
Co 3 Co 3 Co 3 Co 3

Cl Cl Cl
en
en en
Cl

(a) (b) (c) (d)

(A) a and c are identical structures (B) b and d are identical structures
(C) b and d are enantiomers (D) b and c are diastereomers

30. In which of the following pair(s) the minerals are converted into metals by self–reduction process ?
(A) Cu2S, PbS (B) PbS, HgS (C) PbS, ZnS (D) Ag2S, Cu2S

31. Consider 0.1 M solutions of two solutes X & Y. the solute X behaves as an univalent electrolyte while
the solute Y undergoes dimerization in solution. Select the correct statement(s) regarding these
solutions:
(A) The boiling point of the solution “X” will be higher than that of “Y”
(B) The osmotic pressure of the solution “X” will be higher than that of “Y”
(C) The freezing point of the solution “X” will be lower than that of “Y”
(D) The relative lowering of vapour pressure of both the solutions will be the same

32. When a lead storage battery is discharged

(A) SO2 is evolved (B) lead sulphate is produced at both electrodes
(C) sulphuric acid is consumed (D) water is formed

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 PH-VIII-2018-PCM-51

SECTION 3 (Maximum Marks: 18)

 This section contains TWO paragraphs.
 Based on each paragraph, there are TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.

Paragraph–1

The Ellingham diagram for zinc, magnesium and carbon converting into corresponding oxides is
shown below

33. At what temperature, zinc and carbon have equal affinity of oxygen?
(A) 1000C (B) 1500C (C) 500C (D) 1200C

34. At 1100C , which reaction is spontaneous to a maximum extent?

(A) MgO  C  Mg  CO (B) ZnO  C  Zn  CO
(C) MgO  Zn  Mg  ZnO (D) ZnO  Mg  MgO  Zn

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PH-VIII-2018-PCM-52

Paragraph–2

A bluish green coloured compound ‘A’ on heating gives two products solid residue ‘B’ and gas ‘C’. A metal ‘D’
is deposited on passing H2 through heated ‘B’. The compo und ‘A’ and ‘B’ are insoluble in water. ‘B’ is black
in colour, dissolves in HCl and on treatment with K4[Fe(CN)6] gives a chocolate brown ppt of compound ‘E’. ‘C’
is colourless, odoulress gas and turns lime water milky.

35. Compound ‘A’ is

(A) CuSO4 (B) CuCO3 (C) FeSO4 (D) CrCl3

36. The compounds ‘B’ and ‘C’ are respectively

(A) CuS, SO2 (B) CuO, CO2 (C) FeO, H2S (D) Cr2O3, CO

PART III: MATHEMATICS

SECTION 1 (Maximum Marks: 28)
 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to all the correct option in the ORS.

37. A wire of length  is cut into three pieces. What is the probability that the three pieces form a triangle ?
1 1 2
(A) (B) (C) (D) none of these
2 4 3

38. Suppose X is a binomial variate B(5, p) and P(X = 2) = P(X – 3), then p is equal to
1 1 1 1
(A) (B) (C) (D)
2 3 4 5

39. A dice is thrown (2n + 1) times. The probability that faces with even numbers appear odd number of
times is
2n  1 n 1 n
(A) (B) (C) (D) none of these
2n  3 2n  1 2n  1

40. A natural number x is chosen at random from the first 100 natural numbers. The probability that
100
x+ > 50 is
x
1 11 1
(A) (B) (C) (D) none of these
10 50 20

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 PH-VIII-2018-PCM-53

1
41. A boy is throwing stones at a target. The probability of hitting the target at any trial is . The
2
th th
probability of hitting the target 5 time at the 10 throw is
10 10
5 63 C C4
(A) 10 (B) 9 (C) 105 (D)
2 2 2 210

42. Two small squares on a chess board are chosen at random. Probability that they have a common
side is
1 1 1 5
(A) (B) (C) (D)
3 9 18 18

The coefficients of a quadratic equation ax + bx + c = 0 (a  b  c) are chosen from first three prime
2
43.
numbers, the probability that roots of the equation are real is
1 2 1 3
(A) (B) (C) (D)
3 3 4 4

SECTION 2 (Maximum Marks: 15)

 This section contains SEVEN questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options
is(are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4
marks; darkening only (A) and (D) will get +2 marks; and darkening (A) and (B) will get –2 marks, as a
wrong option is also darkened.

44. Let X be a set containing n elements. If two subsets A and B of X are picked at random, the
probability that A and B have the same number of elements is
2n
C 1 1 3  5      2n  1 3n
(A) 2nn (B) 2n (C) (D)
2 Cn 2n  n! 4n

45. Two numbers b and c are chosen at random (with replacement from the numbers 1, 2, 3, 4, 5, 6, 7, 8
and 9). The probability that x + bx + c > 0 for all x  R is
2

17 32 82 45
(A) (B) (C) (D)
123 81 125 143

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PH-VIII-2018-PCM-54

1
46. Let A and B are two independent events. The probability that both A and B happen is and the
12
1
probability that neither A nor B happens is , then
2
1 1 1 1
(A) P(A) = , P(B) = (B) P(A) = , P(B) =
3 4 2 6
1 1 1 1
(C) P(A) = , P(B) = (D) P(A) = , P(B) =
6 2 4 3

47. The letters of the word PROBABILITY are written down at random in a row. Let E1 denotes the event
that two I’s are together and E2 denotes the event that two B’s are together, then
2 2 18 1
(A) P(E1) = P(E2) = (B) P(E1  E2) = (C) P(E1  E2) = (D) P(E1 / E2) =
11 55 55 5

48. Triplet (x, y, z) is chosen from the set {1, 2, 3, ......, n}, such that x  y < z. The number of such that
triplets is
2 n+1 n n n
(A) n (B) C3 (C) C2 (D) C2 + C3

49. The number of ways in which 10 candidates A1, A2, ......, A10 can be ranked, so that A1 is always
above A2 is
10!
(B) 8!  C2
10 10 10
(A) (C) P2 (D) C2
2

50. The number of ways of arranging seven persons (having A, B, C and D among them) in a row so that
A, B, C and D are always in order A–B–C–D (not necessarily together) is
(C) 6  C4
7 7
(A) 210 (B) 5040 (D) P3

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 PH-VIII-2018-PCM-55

SECTION 3 (Maximum Marks: 18)

 This section contains TWO paragraphs.
 Based on each paragraph, there are TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.

Paragraph–1

If a particular experiment be given n (a finite) independent trials.

If the probability of success in one trial (say) p
We get probability of failure, q = (1 – p)
n r n–r
The probability of r success in n trials = Crp q .

1
51. The probability of a man hitting a target in one fire is . Atleast n times he must fire at the target that
4
2
the chances of hitting the target at least once will exceed , then n is
3
(A) 2 (B) 4 (C) 6 (D) 8

52. A coin is tossed 4 times whose faces are marked with the numbers 5 and 3. The odds in favour of
getting a sum less than 15 is
5 5 16 11
(A) (B) (C) (D)
16 11 5 5

Paragraph–2

Different words are being formed by arranging the letters of the word “SUCCESS”. All the words obtained by
written in the form of a dictionary.

53. The number of words in which the two C are together but no two S are together is
(A) 120 (B) 96 (C) 24 (D) 420

54. The number of words in which the consonants appear in alphabetic order is
(A) 42 (B) 40 (C) 420 (D) 280

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PH-VIII-2018-PCM-56

FIITJEE INTERNAL TEST

IIT – JEE 2018
PHASE – VIII_PAPER – II_SET - B
ANSWERS
PHYSICS
1. B 2. D 3. B 4. C
5. B 6. C 7. A 8. ABCD
9. ABD 10 A,D 11. A,D 12. BC
13 A 14 ABCD 15. B 16. A
17. C 18. B

CHEMISTRY
19. B 20. A 21. C 22. C
23. D 24. B 25. B 26. B, D
27. A, D 28. A, B, C, D 29. A, C, D 30. A, B
31. A,B,C 32. B, C, D 33. A 34. D
35. B 36. B

MATHEMATICS
37. B 38. A 39. D 40. D
41. B 42. C 43. A 44. AC
45. B 46. AD 47. ABCD 48. BD
50. ACD 49. AB 51. B 52. B
53. C 54. A

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