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Copolyester Safety Guidelines

This safety data sheet provides information on Eastman Cristal 400 Copolyester pellets. It lists the product identifiers and supplier contact information. The product is not classified as hazardous according to regulation (EC) No. 1272/2008. When handling the product, appropriate personal protective equipment should be worn.

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0% found this document useful (0 votes)
130 views9 pages

Copolyester Safety Guidelines

This safety data sheet provides information on Eastman Cristal 400 Copolyester pellets. It lists the product identifiers and supplier contact information. The product is not classified as hazardous according to regulation (EC) No. 1272/2008. When handling the product, appropriate personal protective equipment should be worn.

Uploaded by

sri
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Eastman Cristal(TM) 400 Copolyester

Version Revision Date: SDS Number: Date of last issue: 31.10.2014


2.3 18.10.2017 150000093472 Date of first issue: 21.01.2013
PRD SDSEU / EN / 0001

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1 Product identifier
Trade name : Eastman Cristal(TM) 400 Copolyester

Product code : 400, P33394FR, 50140497, 50126658, 50126677,


50126678, 50126669, E3339402
Substance name : not applicable

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub- : Polymer
stance/Mixture

Recommended restrictions : None known.


on use

1.3 Details of the supplier of the safety data sheet


Company : Eastman Chemical Company
200 South Wilcox Drive
37660-5280 Kingsport

Telephone : +14232292000

E-mail address of person : Visit our website at [Link] or email


responsible for the SDS emnmsds@[Link]

1.4 Emergency telephone number


Emergency telephone number : NCEC +44 (0)1235 239 670:

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)


Not a hazardous substance or mixture.
2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)


Not a hazardous substance or mixture.

2.3 Other hazards


This substance/mixture contains no components considered to be either persistent, bioaccumul a-
tive and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or
higher.

SECTION 3: Composition/information on ingredients


3.2 Mixtures

Components

1/9
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Eastman Cristal(TM) 400 Copolyester

Version Revision Date: SDS Number: Date of last issue: 31.10.2014


2.3 18.10.2017 150000093472 Date of first issue: 21.01.2013
PRD SDSEU / EN / 0001

Chemical name CAS-No. Classification Concentration


EC-No. (% w/w)
Registration number
copolyester proprietary 100

For explanation of abbreviations see section 16.

SECTION 4: First aid measures


4.1 Description of first aid measures
If inhaled : Move to fresh air.
Treat symptomatically.
If symptoms persist, call a physician.

In case of skin contact : Wash off with soap and water.


If symptoms persist, call a physician.
Cool skin rapidly with cold water after contact with molten
material.
Do not peel solidified product off the skin.
Burns must be treated by a physician.

In case of eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.

If swallowed : Seek medical advice.

4.2 Most important symptoms and effects, both acute and delayed
Risks : The molten product can cause serious burns.

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.

SECTION 5: Firefighting measures


5.1 Extinguishing media
Suitable extinguishing media : Water spray
Dry chemical
Carbon dioxide (CO2)

Unsuitable extinguishing : Do not use a solid water stream as it may scatter and spread
media fire.

5.2 Special hazards arising from the substance or mixture


Specific hazards during fire- : Avoid generating dust; fine dust dispersed in air in sufficient
fighting concentrations, and in the presence of an ignition source is a
potential dust explosion hazard.

Hazardous combustion prod- : No hazardous combustion products are known


ucts

2/9
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Eastman Cristal(TM) 400 Copolyester

Version Revision Date: SDS Number: Date of last issue: 31.10.2014


2.3 18.10.2017 150000093472 Date of first issue: 21.01.2013
PRD SDSEU / EN / 0001

5.3 Advice for firefighters


Special protective equipment : Wear an approved positive pressure self-contained breathing
for firefighters apparatus in addition to standard fire fighting gear.

Further information : Minimize dust generation and accumulation.

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions : Wear appropriate personal protective equipment.
Local authorities should be advised if significant spillages
cannot be contained.

6.2 Environmental precautions


Environmental precautions : Avoid release to the environment.

6.3 Methods and material for containment and cleaning up


Methods for cleaning up : Sweep up and shovel into suitable containers for disposal.

6.4 Reference to other sections


For personal protection see section 8.

SECTION 7: Handling and storage


7.1 Precautions for safe handling
Advice on safe handling : Wash thoroughly after handling.
Use only in area provided with appropriate exhaust ventilation.
Minimize dust generation and accumulation.

Advice on protection against : Minimize dust generation and accumulation.


fire and explosion

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.

7.2 Conditions for safe storage, including any incompatibilities


Requirements for storage : Keep tightly closed.
areas and containers

7.3 Specific end use(s)


Specific use(s) : Polymer

SECTION 8: Exposure controls/personal protection


8.1 Control parameters

8.2 Exposure controls

3/9
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Eastman Cristal(TM) 400 Copolyester

Version Revision Date: SDS Number: Date of last issue: 31.10.2014


2.3 18.10.2017 150000093472 Date of first issue: 21.01.2013
PRD SDSEU / EN / 0001

Engineering measures
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Personal protective equipment
Eye protection : Safety glasses
Wear a face shield when working with molten material.

Hand protection
Remarks : Wear suitable gloves. When handling hot material, use heat
resistant gloves.

Skin and body protection : Wear suitable protective clothing.

Respiratory protection : Use respiratory protection unless adequate local exhaust ven-
tilation is provided or exposure assessment demonstrates that
exposures are within recommended exposure guidelines.
Wear respiratory protection when its use is identified for cer-
tain contributing scenario.

Protective measures : Ensure that eye flushing systems and safety showers are
located close to the working place.

SECTION 9: Physical and chemical properties


9.1 Information on basic physical and chemical properties
Appearance : pellets

Colour : colourless

Odour : odourless

Odour Threshold : not determined

pH : not determined

Softening point : 80 °C

Flash point : not applicable, combustible solid

Evaporation rate : not determined

Upper explosion limit : not determined

Lower explosion limit : not determined

Vapour pressure : not determined

Relative vapour density : not determined

4/9
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Eastman Cristal(TM) 400 Copolyester

Version Revision Date: SDS Number: Date of last issue: 31.10.2014


2.3 18.10.2017 150000093472 Date of first issue: 21.01.2013
PRD SDSEU / EN / 0001

Relative density : >1


(estimated)

Solubility(ies)
Water solubility : negligible

Partition coefficient: n- : No data available


octanol/water

Auto-ignition temperature : not determined

Decomposition temperature : Thermal stability not tested. Low stability hazard expected at
normal operating temperatures.

Viscosity
Viscosity, dynamic : not determined

Viscosity, kinematic : not determined

Explosive properties : No data available

Oxidizing properties : No data available

9.2 Other information

No data available

SECTION 10: Stability and reactivity


10.1 Reactivity
None reasonably foreseeable.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : Stable

10.4 Conditions to avoid


Conditions to avoid : Minimize dust generation and accumulation.

10.5 Incompatible materials


Materials to avoid : Strong oxidizing agents

10.6 Hazardous decomposition products


Carbon monoxide, Carbon dioxide (CO2)

SECTION 11: Toxicological information

5/9
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Eastman Cristal(TM) 400 Copolyester

Version Revision Date: SDS Number: Date of last issue: 31.10.2014


2.3 18.10.2017 150000093472 Date of first issue: 21.01.2013
PRD SDSEU / EN / 0001

11.1 Information on toxicological effects

Acute toxicity
Not classified based on available information.
Skin corrosion/irritation
Not classified based on available information.
Serious eye damage/eye irritation
Not classified based on available information.
Respiratory or skin sensitisation
Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
Experience with human exposure

Product:
Inhalation : Remarks: None known.

Skin contact : Remarks: The molten product can cause serious burns.

Eye contact : Remarks: The molten product can cause serious burns.

Ingestion : Remarks: None known.

SECTION 12: Ecological information


12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available

6/9
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Eastman Cristal(TM) 400 Copolyester

Version Revision Date: SDS Number: Date of last issue: 31.10.2014


2.3 18.10.2017 150000093472 Date of first issue: 21.01.2013
PRD SDSEU / EN / 0001

12.4 Mobility in soil


No data available
12.5 Results of PBT and vPvB assessment

Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher..

12.6 Other adverse effects


No data available

SECTION 13: Disposal considerations


13.1 Waste treatment methods
Product : Dispose of in accordance with local regulations.

SECTION 14: Transport information


14.1 UN number
Not regulated as a dangerous good
14.2 UN proper shipping name
Not regulated as a dangerous good
14.3 Transport hazard class(es)
Not regulated as a dangerous good
14.4 Packing group
Not regulated as a dangerous good
14.5 Environmental hazards
Not regulated as a dangerous good
14.6 Special precautions for user
Not applicable
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mi x-
ture
REACH - Candidate List of Substances of Very High : Not applicable
Concern for Authorisation (Article 59).

Regulation (EC) No 1005/2009 on substances that de- : Not applicable


plete the ozone layer

Regulation (EC) No 850/2004 on persistent organic pol- : Not applicable


lutants

7/9
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Eastman Cristal(TM) 400 Copolyester

Version Revision Date: SDS Number: Date of last issue: 31.10.2014


2.3 18.10.2017 150000093472 Date of first issue: 21.01.2013
PRD SDSEU / EN / 0001

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of
major-accident hazards involving dangerous substances.
Not applicable

The components of this product are reported in the following inventories:


DSL : All components of this product are on the Canadian DSL

AICS : On the inventory, or in compliance with the inventory

ENCS : On the inventory, or in compliance with the inventory

KECI : On the inventory, or in compliance with the inventory

PICCS : On the inventory, or in compliance with the inventory

IECSC : On the inventory, or in compliance with the inventory

TCSI : On the inventory, or in compliance with the inventory

TSCA : On the inventory, or in compliance with the inventory

15.2 Chemical safety assessment


None.

SECTION 16: Other information


Full text of other abbreviations

ADN - E uropean Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - European Agreement concerning the International Carriage of Dangerous
Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society
for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regula-
tion; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN
- Standard of the German Institute for Standardisation; DS L - Domestic Substances List (Cana-
da); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx -
Conc entration associated with x% response; ELx - Loading rate associated with x% response;
EmS - Emergency Schedule; ENCS - Existing and New Chemical Substanc es (Japan); ErCx -
Conc entration associated with x% growt h rate response; GHS - Globally Harmonized System;
GLP - Good Laboratory Practice; IARC - Int ernational Agency for Research on Cancer; IA TA - In-
ternational Air Transport Association; IBC - International Code for the Construction and Equip-
ment of Ships carrying Dangerous Chemic als in Bulk; IC50 - Half maximal inhibit ory concentra-
tion; ICAO - International Civil A viation Organization; IECSC - Inventory of Existing Chemical
Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Mari-
time Organization; IS HL - Industrial Safety and Health Law (Japan); ISO - International Organisa-
tion for Standardization; KECI - K orea Existing Chemicals Inventory; LC50 - Lethal Concentration
to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal
Dose); MARPOL - International Convention for the Prevention of Pollution from S hips; n. o.s. - Not
Otherwise S pecified; NO(A )EC - No Observed (Adverse) E ffect Concentration; NO(A)E L - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rat e; NZIoC - New
Zealand Invent ory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-

8/9
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Eastman Cristal(TM) 400 Copolyester

Version Revision Date: SDS Number: Date of last issue: 31.10.2014


2.3 18.10.2017 150000093472 Date of first issue: 21.01.2013
PRD SDSEU / EN / 0001

lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REA CH - Regulation (E C) No
1907/2006 of the E uropean P arliament and of the Council concerning the Registration, E val ua-
tion, Authorisation and Restriction of Chemicals; RID - Regulations concerning the Int ernational
Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Dec omposition Temperature;
SDS - Safety Data Sheet; TCS I - Taiwan Chemical Substance Inventory; TRGS - Technical Rule
for Hazardous Substances; TSCA - Toxic Substances Control Act (United States); UN - United
Nations; vPvB - Very Persistent and Very Bioaccumulative

Further information

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a gui d-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The in formation relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

ZW / EN

9/9

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