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M156 White Offset Ink - SDS5075 - US

This safety data sheet provides information on the composition and hazards of M156 White Offset Ink. It contains titanium dioxide, isophorone, cyclohexanone, polyvinyl chloride resin, benzotriazole UV stabilizer, and butyltin heat stabilizer. The product is classified as flammable and harmful if swallowed, with additional health hazards. Appropriate personal protective equipment should be worn when handling. In the event of exposure, get medical attention and show them this safety data sheet.

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0% found this document useful (0 votes)
959 views16 pages

M156 White Offset Ink - SDS5075 - US

This safety data sheet provides information on the composition and hazards of M156 White Offset Ink. It contains titanium dioxide, isophorone, cyclohexanone, polyvinyl chloride resin, benzotriazole UV stabilizer, and butyltin heat stabilizer. The product is classified as flammable and harmful if swallowed, with additional health hazards. Appropriate personal protective equipment should be worn when handling. In the event of exposure, get medical attention and show them this safety data sheet.

Uploaded by

gg131077
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Revision date: 2/20/2020 Revision: 4 Supersedes date: 3/14/2019

SAFETY DATA SHEET


M156 White Offset Ink

1. Identification

Product identifier
Product name M156 White Offset Ink

Product number 71002790

Container size 6 x 1 Liter

Recommended use of the chemical and restrictions on use


Application Printing ink.

Uses advised against Use only for intended applications.

Details of the supplier of the safety data sheet


Supplier Matthews Marking Systems
3159 Unionville Road, Suite 500
Cranberry Township, PA 16066
412.665.2500
412.828.4545
[email protected]

Manufacturer Matthews Marking Systems


Zona Franca La Lima
Multitenant #8
Cartago, Costa Rica 30106
(506) 4000-1103

Emergency telephone number


Emergency telephone Chemtrec US : 1-800-424-9300 Chemtrec World: 1-703-527-3887

2. Hazard(s) identification

Classification of the substance or mixture


OSHA Regulatory Status This Product is Hazardous under the OSHA Hazard Communication Standard.

Physical hazards Flam. Liq. 4 - H227

Health hazards Acute Tox. 4 - H302 Eye Irrit. 2A - H319 Skin Sens. 1 - H317 STOT SE 3 - H335 STOT RE 2 -
H373

Environmental hazards Aquatic Chronic 3 - H412

Label elements

Hazard symbols

Signal word Warning

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Hazard statements H227 Combustible liquid.


H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements P210 Keep away from heat, sparks, open flames and hot surfaces. No smoking.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P308+P313 If exposed or concerned: Get medical advice/ attention.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/ container in accordance with national regulations.

Contains Isophorone, Polyvinyl Chloride Resin, Butyltin Heat Stabilizer

3. Composition/information on ingredients

Mixtures

Titanium Dioxide 30-<50%


CAS number: 13463-67-7

Classification
Carc. 2 - H351

Isophorone 30-<50%
CAS number: 78-59-1

Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Eye Irrit. 2A - H319
Carc. 2 - H351
STOT SE 3 - H335

Cyclohexanone 5-<10%
CAS number: 108-94-1

Classification
Flam. Liq. 3 - H226
Acute Tox. 4 - H332

Polyvinyl Chloride Resin 5-<10%


CAS number: Proprietary

Classification
STOT RE 2 - H373

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Benzotriazole UV Stabilizer <1%


CAS number: Proprietary
M factor (Chronic) = 1

Classification
Combustible Dust - USH01
Skin Sens. 1B - H317
Aquatic Chronic 1 - H410

Butyltin Heat Stabilizer <1%


CAS number: Proprietary

Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Skin Irrit. 2 - H315
Eye Irrit. 2A - H319
Skin Sens. 1 - H317
Muta. 2 - H341
STOT SE 1 - H370

The full text for all hazard statements is displayed in Section 16.
Composition comments This material does contain Hazardous Air Pollutants (HAPS) as defined by the Clean Air Act
under the US Environmental Protection Agency (EPA). See Sections 9 and 15 for further
details.

Ingredient notes The exact percentage/concentration is withheld as a trade secret in accordance with 29 CFR
1910.1200. The exact identity is withheld as a trade secret in accordance with 29 CFR
1910.1200.

4. First-aid measures

Description of first aid measures


General information Consult a physician for specific advice. If medical advice is needed, have product container or
label at hand. If in doubt, get medical attention promptly. Show this Safety Data Sheet to the
medical personnel.

Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. If breathing stops, provide artificial respiration. Consult a physician for specific
advice.

Ingestion Get medical attention immediately. Rinse mouth thoroughly with water. Never give anything
by mouth to an unconscious person. Do not induce vomiting unless under the direction of
medical personnel.

Skin Contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical
attention if irritation persists after washing. Wash clothing and clean shoes thoroughly before
reuse.

Eye contact Rinse immediately with plenty of water. Continue to rinse for at least 15 minutes and get
medical attention.

Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue.

Most important symptoms and effects, both acute and delayed

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General information The product is considered to be a low hazard under normal conditions of use. The severity of
the symptoms described will vary dependent on the concentration and the length of exposure.
See Section 11 for additional information on health hazards.

Inhalation May be harmful if inhaled. May cause eye and respiratory system irritation. Vapors in high
concentrations are anesthetic. Overexposure to organic solvents may depress the central
nervous system, causing dizziness and intoxication and, at very high concentrations,
unconsciousness and death.

Ingestion Harmful if swallowed. May cause nausea, headache, dizziness and intoxication. May cause
stomach pain or vomiting.

Skin contact Causes skin irritation. Prolonged or repeated contact with skin may cause irritation, redness
and dermatitis.

Eye contact This product is strongly irritating. Prolonged contact causes serious eye and tissue damage.

Indication of immediate medical attention and special treatment needed


Notes for the doctor Treat symptomatically.

5. Fire-fighting measures

Extinguishing media
Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.

Unsuitable extinguishing Water spray.


media

Special hazards arising from the substance or mixture


Flammability Class 3.0 Combustible Liquid II

Specific hazards Combustible liquid. Vapors are heavier than air and may spread near ground and travel a
considerable distance to a source of ignition and flash back.

Hazardous combustion Thermal decomposition or combustion products may include the following substances:
products Carbon dioxide (CO2). Carbon monoxide (CO).

Advice for firefighters


Protective actions during Evacuate area. Stop leak if safe to do so. Use water to keep fire exposed containers cool and
firefighting disperse vapors. Use water spray to reduce vapors.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures


Personal precautions No smoking, sparks, flames or other sources of ignition near spillage. Avoid contact with skin,
eyes and clothing. Avoid inhalation of vapors. Wash thoroughly after dealing with a spillage.
Ensure procedures and training for emergency decontamination and disposal are in place.

Environmental precautions
Environmental precautions Avoid release to the environment. Do not discharge into drains or watercourses or onto the
ground. Use appropriate containment to avoid environmental contamination. Spillages or
uncontrolled discharges into watercourses must be reported immediately to the Environmental
Agency or other appropriate regulatory body.

Methods and material for containment and cleaning up

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Methods for cleaning up Eliminate all sources of ignition. Stop leak if safe to do so. Do not touch or walk into spilled
material. Take care as floors and other surfaces may become slippery. Contain and absorb
spillage with sand, earth or other non-combustible material. Collect and place in suitable
waste disposal containers and seal securely. When handling waste, the safety precautions
applying to handling of the product should be considered. Dispose of waste to licensed waste
disposal site in accordance with the requirements of the local Waste Disposal Authority.

Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health
hazards. See Section 12 for additional information on ecological hazards. For waste disposal,
see Section 13.

7. Handling and storage

Precautions for safe handling


Usage precautions Wear protective clothing as described in Section 8 of this safety data sheet.

Advice on general Do not eat, drink or smoke when using this product. Provide eyewash station and safety
occupational hygiene shower. Good personal hygiene procedures should be implemented. Wash skin thoroughly
after handling. Wash contaminated clothing before reuse.

Conditions for safe storage, including any incompatibilities


Storage precautions Store at temperatures between 4.4°C/40°F and 32.2°C/90°F. Keep only in the original
container in a cool, well-ventilated place. Protect from freezing and direct sunlight. Container
must be kept tightly closed when not in use. Keep containers upright. Keep away from heat,
hot surfaces, sparks, open flames and other ignition sources. No smoking. Store in
accordance with national regulations.

Storage class Flammable liquid storage.

Specific end uses(s)


Specific end use(s) The identified uses for this product are detailed in Section 1.

8. Exposure controls/Personal protection

Control parameters
Occupational exposure limits
Isophorone
Long-term exposure limit (8-hour TWA): OSHA 25 ppm 140 mg/m³
Ceiling exposure limit: ACGIH 5 ppm 28 mg/m³
A3
Cyclohexanone
Long-term exposure limit (8-hour TWA): OSHA 50 ppm 200 mg/m³
Long-term exposure limit (8-hour TWA): ACGIH 20 ppm
Short-term exposure limit (15-minute): ACGIH 50 ppm
A3, Sk
Polyvinyl Chloride Resin
Long-term exposure limit (8-hour TWA): ACGIH 1 mg/m³ respirable fraction
A4
Butyltin Heat Stabilizer
Short-term exposure limit (15-minute): ACGIH 0.2 mg/m³
Long-term exposure limit (8-hour TWA): ACGIH 0.1 mg/m³
Long-term exposure limit (8-hour TWA): OSHA 0.1 mg/m³

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OSHA = Occupational Safety and Health Administration.


ACGIH = American Conference of Governmental Industrial Hygienists.
A4 = Not Classifiable as a Human Carcinogen.
A3 = Confirmed Animal Carcinogen with Unknown Relevance to Humans.
Sk = Danger of cutaneous absorption.

Ingredient comments Data based on literature. Product not tested.

Isophorone (CAS: 78-59-1)

Immediate danger to life 200 ppm


and health

Cyclohexanone (CAS: 108-94-1)

Immediate danger to life 700 ppm


and health

Exposure controls

Protective equipment

Appropriate engineering As this product contains ingredients with exposure limits, process enclosures, local exhaust
controls ventilation or other engineering controls should be used to keep worker exposure below any
statutory or recommended limits, if use generates dust, fumes, gas, vapor or mist. Use
explosion-proof ventilating equipment.

Eye/face protection Wear tight-fitting, chemical splash goggles or face shield.

Hand protection It is recommended that chemical-resistant, impervious gloves are worn. The most suitable
glove should be chosen in consultation with the glove supplier/manufacturer, who can provide
information about the breakthrough time of the glove material. It is recommended that gloves
are made of the following material: Butyl rubber. Nitrile rubber. Rubber (natural, latex).
Frequent changes are recommended.

Other skin and body Avoid contact with skin. Wear appropriate clothing to prevent repeated or prolonged skin
protection contact.

Hygiene measures Wash contaminated skin thoroughly after handling. Provide eyewash station and safety
shower.

Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn. Wear a respirator
fitted with the following cartridge: Organic vapor filter.

Thermal hazards If there is a risk of contact with hot product, all protective equipment worn should be suitable
for use with high temperatures.

Environmental exposure Keep container tightly sealed when not in use.


controls

9. Physical and chemical properties

Information on basic physical and chemical properties


Appearance Colored liquid.

Color White.

Odor Ketonic.

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Melting point -8°C/18°F

Initial boiling point and range 155°C/311°F @ 760 mm Hg

Flash point 44°C/111°F Closed cup.

Evaporation rate 0.01 (butyl acetate = 1)

Upper/lower flammability or Upper flammable/explosive limit: 9.4 % vol Lower flammable/explosive limit: 0.8 % vol
explosive limits

Vapor pressure 0.2 mm Hg @ 20°C/68°F

Vapor density 3.39

Relative density 1.39715 g/cc 1397.15 g/l 11.64 lbs/gal

Solubility(ies) Soluble in the following materials: Ketones. Insoluble in water.

Partition coefficient log Pow: 0.81

Auto-ignition temperature 420°C/788°F

Decomposition Temperature Not applicable.

Viscosity <15000 cP @ 25°C/77°F

Explosive properties Not applicable.

Oxidizing properties Not applicable.

Comments Information given is applicable to the product as supplied. Information declared as "Not
available" or "Not applicable" is not considered to be relevant to the implementation of the
proper control measures.

Volatile organic compound This product contains a maximum VOC content of 728 g/l. This product contains a maximum
VOC content of 6.06 lbs/gal.

HAPS Content 40.78%

10. Stability and reactivity

Reactivity There are no known reactivity hazards associated with this product.

Stability Stable at normal ambient temperatures and when used as recommended.

Conditions to avoid Avoid the following conditions: Heat, sparks, flames.

Materials to avoid Avoid contact with the following materials: Strong oxidizing agents.

Hazardous decomposition Heating may generate the following products: Carbon dioxide (CO2). Carbon monoxide (CO).
products

11. Toxicological information

Information on toxicological effects


Toxicological effects Information given is based on data of the components and of similar products.

Acute toxicity - oral


ATE oral (mg/kg) 1,226.09

Acute toxicity - dermal


ATE dermal (mg/kg) 2,697.4

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Acute toxicity - inhalation


ATE inhalation (vapours mg/l) 128.21

Specific target organ toxicity - single exposure


Target organs Eyes Gastro-intestinal tract Respiratory system, lungs Skin

Specific target organ toxicity - repeated exposure


Target organs Central nervous system Gastro-intestinal tract Reproductive organs Respiratory system, lungs

Aspiration hazard
Aspiration hazard Not relevant.

Toxicological information on ingredients.

Isophorone

Acute toxicity - oral

ATE oral (mg/kg) 500.0

Acute toxicity - dermal

ATE dermal (mg/kg) 1,100.0

Acute toxicity - inhalation

Acute toxicity inhalation 7.0


(LC₅₀ dust/mist mg/l)

ATE inhalation 7.0


(dusts/mists mg/l)

Serious eye damage/irritation

Serious eye Causes serious eye irritation.


damage/irritation

Carcinogenicity

Carcinogenicity Known carcinogen based on animal evidence.

Specific target organ toxicity - single exposure

Target organs Respiratory tract

Specific target organ toxicity - repeated exposure

Target organs Kidneys

Aspiration hazard

Aspiration hazard Entry into the lungs following ingestion or vomiting may cause chemical
pneumonitis.

Cyclohexanone

Acute toxicity - inhalation

Acute toxicity inhalation 15.0


(LC₅₀ vapours mg/l)

ATE inhalation (vapours 15.0


mg/l)

Skin corrosion/irritation

Skin corrosion/irritation Irritating to skin.

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Serious eye damage/irritation

Serious eye Causes serious eye damage.


damage/irritation

Carcinogenicity

IARC carcinogenicity IARC Group 3 Not classifiable as to its carcinogenicity to humans.

Polyvinyl Chloride Resin

Carcinogenicity

IARC carcinogenicity IARC Group 3 Not classifiable as to its carcinogenicity to humans.

Specific target organ toxicity - repeated exposure

STOT - repeated exposure Prolonged or repeated exposure may cause the following adverse effects: Chronic
inflammation of nose, throat and bronchial tubes.

Benzotriazole UV Stabilizer

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 10,000.0


mg/kg)

Species Rat

ATE oral (mg/kg) 10,000.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 2,000.1


mg/kg)

Species Rat

ATE dermal (mg/kg) 2,000.1

Acute toxicity - inhalation

Acute toxicity inhalation 7.59


(LC₅₀ dust/mist mg/l)

Species Rat

ATE inhalation 7.59


(dusts/mists mg/l)

Skin sensitization

Skin sensitization Guinea pig maximization test (GPMT) - Guinea pig: Sensitizing.

Butyltin Heat Stabilizer

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 510.0


mg/kg)

Species Rat

ATE oral (mg/kg) 510.0

Acute toxicity - dermal

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Acute toxicity dermal (LD₅₀ 1,516.0


mg/kg)

Species Rat

ATE dermal (mg/kg) 1,516.0

Skin corrosion/irritation

Skin corrosion/irritation Severe skin irritation.

Serious eye damage/irritation

Serious eye Causes serious eye irritation.


damage/irritation

Skin sensitization

Skin sensitization May cause sensitization or allergic reactions in sensitive individuals.

Germ cell mutagenicity

Genotoxicity - in vitro May induce heritable mutations in the germ cells of humans.

Reproductive toxicity

Reproductive toxicity - Suspected of damaging fertility.


fertility

Specific target organ toxicity - single exposure

Target organs Thymus

Specific target organ toxicity - repeated exposure

Target organs Blood, thymus

12. Ecological information

Ecological information on ingredients.

Isophorone

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 145 mg/l, Pimephales promelas (Fat-head Minnow)

Acute toxicity - aquatic EC₅₀, 48 hours: 120 mg/l, Daphnia magna


invertebrates

Acute toxicity - aquatic EC₅₀, 96 hours: 126 mg/l, Pseudokirchneriella subcapitata


plants

Acute toxicity - IC₅₀, 16 hours: 500-1000 mg/l, Activated sludge


microorganisms

Cyclohexanone

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: >100 mg/l, Pimephales promelas (Fat-head Minnow)

Acute toxicity - aquatic EC₅₀, 48 hours: >100 mg/l, Daphnia magna


invertebrates

Acute toxicity - aquatic EC₅₀, 72 hours: >100 mg/l, Desmodesmus subspicatus


plants

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Acute toxicity - EC₅₀, 30 minutes: >1000 mg/l, Activated sludge


microorganisms

Benzotriazole UV Stabilizer

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: >0.17 mg/l, Oncorhynchus mykiss (Rainbow trout)

Acute toxicity - aquatic EC₅₀, 24 hours: > 1000 mg/l, Daphnia magna
invertebrates

Chronic aquatic toxicity

M factor (Chronic) 1

Chronic toxicity - aquatic NOEC, 21 days: 0.013 mg/l, Daphnia magna


invertebrates

Butyltin Heat Stabilizer

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 11.7 mg/l, Brachydanio rerio (Zebra Fish)

Acute toxicity - aquatic EC₅₀, 48 hours: 0.035 mg/l, Daphnia magna


invertebrates

Acute toxicity - aquatic EC₅₀, 72 hours: 0.56 mg/l, Scenedesmus subspicatus


plants

Chronic aquatic toxicity

Chronic toxicity - aquatic EC₅₀, 21 days: 0.640 mg/l, Daphnia magna


invertebrates

Persistence and degradability


Ecological information on ingredients.

Isophorone

Persistence and The product is readily biodegradable.


degradability

Biodegradation Soil - Degradation 95%: 28 days

Biological oxygen demand 2.78 g O₂/g substance

Cyclohexanone

Biodegradation Soil - Degradation 90 - 100: 28 days

Bioaccumulative potential
Partition coefficient log Pow: 0.81

Ecological information on ingredients.

Isophorone

Bio-Accumulative Potential BCF: 7, Fish

Partition coefficient log Pow: 1.67-1.70

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Cyclohexanone

Partition coefficient log Pow: 0.81

Benzotriazole UV Stabilizer

Bio-Accumulative Potential BCF: 44-220, Cyprinus carpio (Common carp)

Mobility in soil
Mobility No data available.

Other adverse effects


Other adverse effects Not applicable.

13. Disposal considerations

Waste treatment methods


General information The generation of waste should be minimized or avoided wherever possible. When handling
waste, the safety precautions applying to handling of the product should be considered.
Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. Dispose of waste product or used containers in accordance
with local regulations Disposal of this product, process solutions, residues and by-products
should at all times comply with the requirements of environmental protection and waste
disposal legislation and any local authority requirements.

Disposal methods Dispose of contents/container in accordance with national regulations. Dispose of waste to
licensed waste disposal site in accordance with the requirements of the local Waste Disposal
Authority. When handling waste, the safety precautions applying to handling of the product
should be considered.

14. Transport information

UN Number
UN No. (TDG) 1210

UN No. (IMDG) 1210

UN No. (ICAO) 1210

UN No. (DOT) 1210

UN proper shipping name


Proper shipping name (TDG) PRINTING INK

Proper shipping name (IMDG) PRINTING INK

Proper shipping name (ICAO) PRINTING INK

Proper shipping name (DOT) PRINTING INK

Transport hazard class(es)


TDG class 3

TDG label(s) 3

IMDG Class 3

ICAO class/division 3

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Transport labels

Packing group
TDG Packing Group III

IMDG packing group III

ICAO packing group III

DOT packing group III

Environmental hazards

Environmentally Hazardous Substance


No.

Special precautions for user


EmS F-E, S-D

15. Regulatory information

Regulatory References OSHA Hazard Communication Standard, 29 CFR 1910.1200

Hazardous Air Pollutants Contains - Isophorone


Content

US Federal Regulations
CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA)

Isophorone
Cyclohexanone
Polyvinyl Chloride Resin

SARA 313 Emission Reporting

Polyvinyl Chloride Resin

SARA (311/312) Hazard Categories

Isophorone
Acute
Chronic
Fire
Cyclohexanone
Fire
Acute
Chronic
Polyvinyl Chloride Resin
Chronic
Benzotriazole UV Stabilizer
Fire
Acute

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Butyltin Heat Stabilizer


Acute
Chronic

US State Regulations
California Air Toxics "Hot Spots" (A-I)

Isophorone

California Directors List of Hazardous Substances


The following ingredients are listed:
Isophorone
Cyclohexanone

Massachusetts "Right To Know" List


The following ingredients are listed:
Isophorone
Cyclohexanone
Polyvinyl Chloride Resin
Butyltin Heat Stabilizer

Rhode Island "Right To Know" List


The following ingredients are listed:
Isophorone
Cyclohexanone

Minnesota "Right To Know" List


The following ingredients are listed:
Isophorone
Cyclohexanone

New Jersey "Right To Know" List


The following ingredients are listed:
Isophorone
Cyclohexanone
Polyvinyl Chloride Resin

Pennsylvania "Right To Know" List


The following ingredients are listed:
Isophorone
Cyclohexanone
Polyvinyl Chloride Resin
Butyltin Heat Stabilizer

Inventories
EU - EINECS/ELINCS
All the ingredients are listed or exempt.

Canada - DSL/NDSL
All the ingredients are listed or exempt.

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US - TSCA
All the ingredients are listed or exempt.

Australia - AICS

Isophorone
Cyclohexanone
Butyltin Heat Stabilizer

Japan - ENCS

Isophorone
Cyclohexanone
Butyltin Heat Stabilizer

Korea - KECI

Isophorone
Cyclohexanone
Butyltin Heat Stabilizer

China - IECSC

Isophorone
Cyclohexanone
Butyltin Heat Stabilizer

Philippines - PICCS
The following ingredients are listed:
Isophorone
Cyclohexanone
Butyltin Heat Stabilizer

New Zealand - NZIOC

Isophorone
Cyclohexanone
Butyltin Heat Stabilizer

Taiwan - TCSI
The following ingredients are listed:
Isophorone
Cyclohexanone
Butyltin Heat Stabilizer

16. Other information

Issued by Matthews Marking Systems - Chemical Services Department

Revision date 2/20/2020

Revision 4

Supersedes date 3/14/2019

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SDS No. 5075

SDS status Approved.

Hazard statements in full H226 Flammable liquid and vapor.


H227 Combustible liquid.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H351 Suspected of causing cancer.
H351 Suspected of causing cancer by inhalation.
H370 Causes damage to organs (Blood, thymus).
H373 May cause damage to organs (Respiratory system, lungs) through prolonged or
repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
USH01 May form combustible dust concentrations in air.

NFPA - health hazard Temporary incapacitation, injury. (2)

NFPA - flammability hazard Burns only if heated moderately. (2)

NFPA - instability hazard Normally stable. (0)

ACA HMIS Health rating. Moderate hazard. (2) Chronic hazard. (*)

ACA HMIS Flammability Burns only if heated moderately. (2)


rating.

ACA HMIS Physical hazard Normally stable. (0)


rating.

ACA HMIS Personal C


protection rating.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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