SAFETY DATA SHEET

Sulfur Dioxide

Section 1. Identification
GHS product identifier : Sulfur Dioxide
Chemical name : sulphur dioxide
Other means of : Sulfur dioxide; Sulfur oxide; Sulfurous oxide; Sulfurous acid anhydride; E 220;
identification sulphurous acid anhydride; Sulfur superoxide; Sulfurous anhydride; Sulfur dioxide,
anhydrous; Dioxide of sulfur; Sulphure dioxide; SULFUR DIOXIDE, LIQUID
Product type : Gas.
Product use : Synthetic/Analytical chemistry.
Synonym : Sulfur dioxide; Sulfur oxide; Sulfurous oxide; Sulfurous acid anhydride; E 220;
sulphurous acid anhydride; Sulfur superoxide; Sulfurous anhydride; Sulfur dioxide,
anhydrous; Dioxide of sulfur; Sulphure dioxide; SULFUR DIOXIDE, LIQUID
SDS # : 001047
Supplier's details : Airgas USA, LLC and its affiliates
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253

24-hour telephone : 1-866-734-3438

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : GASES UNDER PRESSURE - Liquefied gas
substance or mixture ACUTE TOXICITY (inhalation) - Category 3
SKIN CORROSION - Category 1
SERIOUS EYE DAMAGE - Category 1

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : Contains gas under pressure; may explode if heated.
Causes severe skin burns and eye damage.
Toxic if inhaled.
Precautionary statements
General : Read and follow all Safety Data Sheets (SDS’S) before use. Read label before use.
Keep out of reach of children. If medical advice is needed, have product container or
label at hand. Close valve after each use and when empty. Use equipment rated for
cylinder pressure. Do not open valve until connected to equipment prepared for use.
Use a back flow preventative device in the piping. Use only equipment of compatible
materials of construction. Always keep container in upright position.
Prevention : Wear protective gloves. Wear protective clothing. Wear eye or face protection. Use
only outdoors or in a well-ventilated area. Avoid breathing gas.
Response : Immediately call a POISON CENTER or doctor. IF INHALED: Remove person to fresh
air and keep comfortable for breathing. IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
Storage : Store locked up. Protect from sunlight. Store in a well-ventilated place.

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Section 2. Hazards identification

Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients

Substance/mixture : Substance
Chemical name : sulphur dioxide
Other means of : Sulfur dioxide; Sulfur oxide; Sulfurous oxide; Sulfurous acid anhydride; E 220;
identification sulphurous acid anhydride; Sulfur superoxide; Sulfurous anhydride; Sulfur dioxide,
anhydrous; Dioxide of sulfur; Sulphure dioxide; SULFUR DIOXIDE, LIQUID
Product code : 001047

CAS number/other identifiers

CAS number : 7446-09-5
Ingredient name % CAS number
sulphur dioxide 100 7446-09-5
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush
eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and
remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns
must be treated promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician. Remove victim to
fresh air and keep at rest in a position comfortable for breathing. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained
breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. If
unconscious, place in recovery position and get medical attention immediately. Maintain
an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Get medical attention immediately. Call a poison center or physician. Flush
contaminated skin with plenty of water. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a
physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : As this product is a gas, refer to the inhalation section.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Toxic if inhaled.
Skin contact : Causes severe burns.
Frostbite : Try to warm up the frozen tissues and seek medical attention.
Ingestion : As this product is a gas, refer to the inhalation section.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:, pain, watering, redness

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Section 4. First aid measures

Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:, pain or irritation, redness, blistering may
occur
Ingestion : Adverse symptoms may include the following:, stomach pains

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Contains gas under pressure. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst or explode.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products sulfur oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Contact supplier immediately for specialist advice. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers
cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not breathe gas. Provide adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Put on appropriate personal protective
equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Ensure emergency procedures to deal with accidental gas releases are in place to avoid
contamination of the environment. Inform the relevant authorities if the product has
caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Immediately contact emergency personnel. Stop leak if without risk.

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Section 6. Accidental release measures

Large spill : Immediately contact emergency personnel. Stop leak if without risk. Note: see Section
1 for emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Contains gas under
pressure. Do not get in eyes or on skin or clothing. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Do not puncture or
incinerate container. Use equipment rated for cylinder pressure. Close valve after each
use and when empty. Protect cylinders from physical damage; do not drag, roll, slide, or
drop. Use a suitable hand truck for cylinder movement.
Empty containers retain product residue and can be hazardous. Do not breathe gas.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store away from direct sunlight in a dry, cool and well-ventilated area, away from
incompatibilities incompatible materials (see Section 10). Cylinders should be stored upright, with valve
protection cap in place, and firmly secured to prevent falling or being knocked over.
Cylinder temperatures should not exceed 52 °C (125 °F). Store locked up. Keep
container tightly closed and sealed until ready for use. See Section 10 for incompatible
materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
sulphur dioxide California PEL for Chemical Contaminants (
Table AC-1) (United States).
PEL: 2 ppm 8 hours.
STEL: 5 ppm 15 minutes.
ACGIH TLV (United States, 3/2019).
STEL: 0.25 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 2 ppm 8 hours.
TWA: 5 mg/m³ 8 hours.
STEL: 5 ppm 15 minutes.
STEL: 10 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2016).
TWA: 2 ppm 10 hours.
TWA: 5 mg/m³ 10 hours.
STEL: 5 ppm 15 minutes.
STEL: 13 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 5 ppm 8 hours.
TWA: 13 mg/m³ 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

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Section 8. Exposure controls/personal protection

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles and/
or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use. Respirator selection must be based on known or anticipated exposure
levels, the hazards of the product and the safe working limits of the selected respirator.

Section 9. Physical and chemical properties

Appearance
Physical state : Gas. {NOTE: A LIQUID BELOW 14 F. SHIPPED AS A LIQUEFIED COMPRESSED
GAS.}
Color : Colorless.
Odor : Pungent.
Odor threshold : Not available.
pH : Not available.
Melting point : -72°C (-97.6°F)
Boiling point : -10°C (14°F)
Critical temperature : 156.85°C (314.3°F)
Flash point : [Product does not sustain combustion.]
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : 34 (psig)
Vapor density : 2.25 (Air = 1)
Specific Volume (ft 3/lb) : 5.9172
Gas Density (lb/ft ) 3
: 0.169
Relative density : Not applicable.
Solubility : Not available.
Solubility in water : Not available.
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Section 9. Physical and chemical properties

Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not applicable.
Flow time (ISO 2431) : Not available.
Molecular weight : 64.06 g/mole

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : No specific data.

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
sulphur dioxide LC50 Inhalation Gas. Rat 2520 ppm 1 hours
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
sulphur dioxide Eyes - Mild irritant Rabbit - 768 hours 6 -
ppm
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
sulphur dioxide - 3 -
Reproductive toxicity
Not available.

Teratogenicity
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Section 11. Toxicological information

Not available.

Specific target organ toxicity (single exposure)

Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Toxic if inhaled.
Skin contact : Causes severe burns.
Ingestion : As this product is a gas, refer to the inhalation section.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:, pain, watering, redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:, pain or irritation, redness, blistering may
occur
Ingestion : Adverse symptoms may include the following:, stomach pains

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Inhalation (gases) 1260 ppm

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Section 12. Ecological information

Toxicity
Not available.

Persistence and degradability

Not available.

Bioaccumulative potential
Not available.

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is
not feasible. This material and its container must be disposed of in a safe way. Empty
containers or liners may retain some product residues. Do not puncture or incinerate
container.

Section 14. Transport information

DOT TDG Mexico IMDG IATA
UN number UN1079 UN1079 UN1079 UN1079 UN1079

UN proper SULFUR DIOXIDE SULFUR SULFUR DIOXIDE SULPHUR SULPHUR

shipping name DIOXIDE; OR DIOXIDE DIOXIDE
SULPHUR
DIOXIDE
Transport 2.3 (8) 2.3 (8) 2.3 (8) 2.3 (8) 2.3 (8)
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards
“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.”

Additional information
DOT Classification : Toxic - Inhalation hazard Zone C
Limited quantity Yes.
Quantity limitation Passenger aircraft/rail: Forbidden. Cargo aircraft: Forbidden.
Special provisions 3, B14, T50, TP19

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Section 14. Transport information

TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.13-2.17 (Class 2), 2.40-2.42 (Class 8).
Explosive Limit and Limited Quantity Index 0
ERAP Index 500
Passenger Carrying Vessel Index Forbidden
Passenger Carrying Road or Rail Index Forbidden
IATA : Quantity limitation Passenger and Cargo Aircraft: Forbidden. Cargo Aircraft Only:
Forbidden.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.

to IMO instruments

Section 15. Regulatory information

U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined

Clean Air Act (CAA) 112 regulated toxic substances: sulphur dioxide
Clean Air Act Section 112 : Not listed
(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients
SARA 302 TPQ SARA 304 RQ
Name % EHS (lbs) (gallons) (lbs) (gallons)
sulphur dioxide 100 Yes. 500 - 500 -
SARA 304 RQ : 500 lbs / 227 kg
SARA 311/312
Classification : Refer to Section 2: Hazards Identification of this SDS for classification of substance.

State regulations
Massachusetts : This material is listed.
New York : This material is listed.
New Jersey : This material is listed.
Pennsylvania : This material is listed.
California Prop. 65
WARNING: This product can expose you to sulfur dioxide, which is known to the State of California to cause birth
defects or other reproductive harm. For more information go to [Link].

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Section 15. Regulatory information

Ingredient name No significant risk Maximum
level acceptable dosage
level
sulfur dioxide - Yes.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.

Inventory list
Australia : This material is listed or exempted.
Canada : This material is listed or exempted.
China : This material is listed or exempted.
Europe : This material is listed or exempted.
Japan : Japan inventory (ENCS): This material is listed or exempted.
Japan inventory (ISHL): Not determined.
New Zealand : This material is listed or exempted.
Philippines : This material is listed or exempted.
Republic of Korea : This material is listed or exempted.
Taiwan : This material is listed or exempted.
Thailand : Not determined.
Turkey : Not determined.
United States : This material is active or exempted.
Viet Nam : This material is listed or exempted.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health / 3
Flammability 0
Physical hazards 3

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)

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Section 16. Other information

0 Flammability
Health 3 0 Instability/Reactivity
Special

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
GASES UNDER PRESSURE - Liquefied gas Expert judgment
ACUTE TOXICITY (inhalation) - Category 3 On basis of test data
SKIN CORROSION - Category 1 Expert judgment
SERIOUS EYE DAMAGE - Category 1 Expert judgment
History
Date of printing : 9/29/2021
Date of issue/Date of : 9/29/2021
revision
Date of previous issue : 2/1/2018
Version : 1.02
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

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