SAFETY DATA SHEET

Road Marking Paint

Section 1. Identification
Product name : Road Marking Paint
Product code : 4272
Product description : Paint.
Product type : Liquid.
Other means of : Not available.
identification

Supplier's details : Jotun UAE Ltd. L.L.C.

P.O.Box 3671, Dubai, U.A.E.
Tel: 009714 3395000
Fax:009714 3380666

Jotun Abu Dhabi L.L.C.

P.O.box-3714
Abu Dhabi U.A.E.
Tel: 00971 2 5510300
Fax:00971 2 5510232

[email protected]

Emergency telephone : SHE Dept. Jotun AS, Norway

number +47 33 45 70 00

4272 5 4272
^(ValidationDate) 1

Section 2. Hazards identification

Classification of the : FLAMMABLE LIQUIDS - Category 3
substance or mixture ACUTE TOXICITY (dermal) - Category 5
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE - Category 2
LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 3

GHS label elements

Hazard pictograms :

Signal word : Warning.

Hazard statements : H226 - Flammable liquid and vapour.
H313 - May be harmful in contact with skin.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H335 - May cause respiratory irritation.
H373 - May cause damage to organs through prolonged or repeated exposure.
(hearing organs)
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements

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Section 2. Hazards identification

Prevention : P280 - Wear protective gloves. Wear eye or face protection.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P273 - Avoid release to the environment.
P260 - Do not breathe vapour or spray.
Response : P314 - Get medical advice/attention if you feel unwell.
P304 + P312 - IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
P362 + P364 - Take off contaminated clothing and wash it before reuse.
P302 + P312, P352 - IF ON SKIN: Call a POISON CENTER or doctor if you feel
unwell. Wash with plenty of water.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice or attention.
Storage : P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional,
national and international regulations.

Other hazards which do not : None known.

result in classification

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers

CAS number : Not applicable.
EC number : Mixture.
Product code : 4272
Ingredient name % CAS number
xylene ≥25 - ≤50 1330-20-7
ethylbenzene ≥10 - ≤24 100-41-4
hydrocarbons, C9, aromatics ≤3 64742-95-6
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If it is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. If not breathing, if breathing is irregular
or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel. It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. Get medical attention. If necessary, call a poison center or physician.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.

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Road Marking Paint

Section 4. First aid measures

Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or
wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. If
necessary, call a poison center or physician. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air
and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention following exposure or if feeling unwell. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a
collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : May cause respiratory irritation.
Skin contact : May be harmful in contact with skin. Causes skin irritation.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Firefighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

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Section 5. Firefighting measures

Specific hazards arising : Flammable liquid and vapour. Runoff to sewer may create fire or explosion hazard.
from the chemical In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion. This material is harmful to aquatic life with long
lasting effects. Fire water contaminated with this material must be contained and
prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities.

Methods and material for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach the release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilt product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

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Road Marking Paint

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not breathe
vapour or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid
release to the environment. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use.
Store and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment.
Use only non-sparking tools. Take precautionary measures against electrostatic
discharges. Empty containers retain product residue and can be hazardous. Do not
reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved
including any area. Store in original container protected from direct sunlight in a dry, cool and well-
incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and
drink. Store locked up. Eliminate all ignition sources. Separate from oxidising
materials. Keep container tightly closed and sealed until ready for use. Containers
that have been opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabelled containers. Use appropriate containment to
avoid environmental contamination. See Section 10 for incompatible materials
before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
xylene ACGIH TLV (United States, 1/2021).
STEL: 651 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 434 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
ethylbenzene ACGIH TLV (United States, 1/2021).
Notes: K
TWA: 20 ppm 8 hours. Form:

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapour or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.

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Section 8. Exposure controls/personal protection

Eye/face protection : Safety eyewear complying to EN 166 should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or
dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : There is no one glove material or combination of materials that will give unlimited
resistance to any individual or combination of chemicals.
The breakthrough time must be greater than the end use time of the product.
The instructions and information provided by the glove manufacturer on use,
storage, maintenance and replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove
material.
Always ensure that gloves are free from defects and that they are stored and used
correctly.
The performance or effectiveness of the glove may be reduced by physical/chemical
damage and poor maintenance.
Barrier creams may help to protect the exposed areas of the skin but should not be
applied once exposure has occurred.
Wear suitable gloves tested to EN374.
May be used, gloves(breakthrough time) 4 - 8 hours: neoprene
Not recommended, gloves(breakthrough time) < 1 hour: butyl rubber, PVC
Recommended, gloves(breakthrough time) > 8 hours: nitrile rubber, 4H, Teflon,
polyvinyl alcohol (PVA)

Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : If workers are exposed to concentrations above the exposure limit, they must use a
respirator according to EN 140. Use respiratory mask with charcoal and dust filter
when spraying this product, according to EN 14387(as filter combination A2-P2). In
confined spaces, use compressed-air or fresh-air respiratory equipment. When use
of roller or brush, consider use of charcoalfilter.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Colour : White., Black, Red, Yellow.
Odour : Characteristic.
Odour threshold : Not applicable.
pH : Not applicable.
Melting point : Not applicable.
Boiling point : Lowest known value: 136.1°C (277°F) (ethylbenzene). Weighted average: 138.36°C
(281°F)
Flash point : Closed cup: 25°C (77°F)
Evaporation rate : Highest known value: 0.84 (ethylbenzene) Weighted average: 0.79compared with
butyl acetate
Flammability (solid, gas) : Not applicable.
Lower and upper explosive : 0.8 - 7.6%
(flammable) limits
Vapour pressure : Highest known value: 1.2 kPa (9.3 mm Hg) (at 20°C) (ethylbenzene). Weighted
average: 0.98 kPa (7.35 mm Hg) (at 20°C)
Vapour density : Highest known value: 3.7 (Air = 1) (xylene). Weighted average: 3.7 (Air = 1)

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Section 9. Physical and chemical properties

Density : 0.99 to 1.25 g/cm³
Solubility : Insoluble in the following materials: cold water and hot water.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Lowest known value: 280 to 470°C (536 to 878°F) (hydrocarbons, C9, aromatics).
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C): >0.205 cm2/s (>20.5 cSt)

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Incompatible materials : Reactive or incompatible with the following materials:
oxidising materials
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
xylene LC50 Inhalation Vapour Rat 20 mg/l 4 hours
LD50 Oral Rat 4300 mg/kg -
TDLo Dermal Rabbit 4300 mg/kg -
ethylbenzene LC50 Inhalation Vapour Rat - Male 17.8 mg/l 4 hours
LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
xylene Eyes - Mild irritant Rabbit - 87 milligrams -
Skin - Mild irritant Rat - 8 hours 60 -
microliters
Sensitisation
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)

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Section 11. Toxicological information

Name Category Route of Target organs
exposure
xylene Category 3 - Respiratory tract
irritation
hydrocarbons, C9, aromatics Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
ethylbenzene Category 2 - hearing organs
Aspiration hazard
Name Result
xylene ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
hydrocarbons, C9, aromatics ASPIRATION HAZARD - Category 1

Information on likely routes : Not available.

of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : May cause respiratory irritation.
Skin contact : May be harmful in contact with skin. Causes skin irritation.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity : No known significant effects or critical hazards.

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Section 11. Toxicological information

Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Dermal 3626.55 mg/kg
Inhalation (vapours) 47.97 mg/l

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
xylene Acute LC50 8500 μg/l Marine water Crustaceans - Palaemonetes 48 hours
pugio
Acute LC50 13400 μg/l Fresh water Fish - Pimephales promelas 96 hours
ethylbenzene Acute EC50 7700 μg/l Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 2.93 mg/l Daphnia 48 hours
Acute LC50 4.2 mg/l Fish 96 hours
hydrocarbons, C9, aromatics Acute EC50 <10 mg/l Daphnia 48 hours
Acute IC50 <10 mg/l Algae 72 hours
Acute LC50 <10 mg/l Fish 96 hours

Persistence and degradability

Product/ingredient name Aquatic half-life Photolysis Biodegradability
xylene - - Readily
ethylbenzene - - Readily
hydrocarbons, C9, aromatics - - Not readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
xylene 3.12 8.1 to 25.9 low
ethylbenzene 3.6 - low
hydrocarbons, C9, aromatics - 10 to 2500 high

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or

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Section 13. Disposal considerations

landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Vapour from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.

Section 14. Transport information

ADR/RID IMDG IATA
UN number UN1263 UN1263 UN1263

UN proper Paint Paint Paint

shipping name
Transport hazard 3 3 3
class(es)

Packing group III III III

Environmental No. No. No.
hazards
Additional - Emergency schedules F-E, -
information S-E

Additional information
ADR/RID : ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to
receptacles < 450 litre capacity).
Hazard identification number 30
Tunnel code (D/E)
IMDG : IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5
(applicable to receptacles < 450 litre capacity).
Emergency schedules F-E, S-E
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not available.

to IMO instruments

Section 15. Regulatory information

Safety, health and : No known specific national and/or regional regulations applicable to this product
environmental regulations (including its ingredients).
specific for the product
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants

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Section 15. Regulatory information

Not listed.

UNECE Aarhus Protocol on POPs and Heavy Metals

Not listed.

Section 16. Other information

History
Date of printing : 13.12.2021
Date of issue/Date of : 13.12.2021
revision
Date of previous issue : 13.12.2021
Version : 1.01
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
The information in this document is given to the best of Jotun's knowledge, based on laboratory testing and
practical experience. Jotun's products are considered as semi-finished goods and as such, products are
often used under conditions beyond Jotun's control. Jotun cannot guarantee anything but the quality of the
product itself. Minor product variations may be implemented in order to comply with local requirements.
Jotun reserves the right to change the given data without further notice.

Users should always consult Jotun for specific guidance on the general suitability of this product for their
needs and specific application practices.

If there is any inconsistency between different language issues of this document, the English (United
Kingdom) version will prevail.

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