ASAHI YUKIZAI CORPORATION
No.D-015e-00
High Impact poly vinyl chloride pipes for water supply(HI-PVC) page：1/5
Preparation date: Nov 22, 2017
: Shavings (JIS K 6742, AS20) Safety Data Sheet Revision Date: -
1. Products and Company information
Product name High Impact poly vinyl chloride pipes for water supply (HI-PVC)
: Shavings (JIS K 6742, AS20)
Supplier name Asahi Yukizai Corporation
Address 2-5955, Nakanose-cho Nobeoka-city Miyazaki-pref. Japan 882-8688
Section Valve & Piping Systems Administration CS & Quality Assurance Group
Phone +81-982-35-9380
Facsimile +81-982-35-9358
Recommended use and restrictions for use Pipes for transfer of waterworks.
2. Hazard identification
GHS classification
Physical and Chemica hazards Not classifiable
Health hazards Not classifiable
GHS label elements
Symbol Not classifiable
Signal word Not classifiable
Hazard statements No information
Precautionary statements (Shavings)
Safety measures P260：Do not breathe dust.
P264：Wash hand thoroughly after handling.
P270：Do not eat, drink or smoke when using this product.
P273：Avoid release to the environment.
P281：Use personal protective equipment as required.
Emergency measures P304+P340：If inhaled, remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P308+P313：If exposed or concerned, get medical advice/attention.
Storage P401：Store not to leak of the Shavings.
Disposal P501：Dispose of contents/container should be outsourced to a dedicated
waste disposal company licensed by the municipal governor.
3. Composition / information on ingredients
Single or Mixture Solid mixture
Product name Unplasticized poly vinyl chloride pipes for water supply
Reference Number in Gazetted
Concentration or List in Japan
Component concentration Chemical formula CAS No.
range CSCL Labor Safety
and Health Act
Polyvinyl chloride (PVC) 90-95% (CH2CHCl)n (6)-66 Che(6)-66 9002-86-2
MBS polymers 5-10% (C8H8.C5H8O2.C4H6.C3H3N)x - - 9010-94-0
Other organic/inorganic
＜5% Non-disclosure Non-disclosure Non-disclosure Non-disclosure
compounds
Industrial Safety and Health Act Not applied
4. First-aid measures
If inhaled (shavings) Move to a place of fresh air and get rest in an easily breathing posture.
Call a doctor if you feel unwell.
If on skin (shavings) Promptly remove the shavings.
If you feel unusual, contact a doctor.
High Impact poly vinyl chloride pipes for water supply(HI-PVC) ASAHI YUKIZAI CORPORATION
: Shavings (JIS K 6742, AS20) No.D-015e-00
page：2/5
Preparation date: Nov 22, 2017
Safety Data Sheet Revision Date: -
If in eyes (shavings) Carefully wash with water for a few minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
If you feel unusual, contact a doctor.
If swallowed (shavings) Rinse mouth. Do not induce vomiting.
If you feel unusual, contact a doctor.
5. Fire-fighting measures
Extinguishing media Water, spray water, fire-extinguishing powder, general fire-extinguishing
foam, carbon dioxide, sand
Special hazards It is self-extinguishing and puts out once it is taken out of flame but produces
stimulant gas if it burns. (Key ingredients of gas are HCl, CO, and CO2)
[Sourced from] Japan PVC Pipe and Fittings Association,
Vinyl Environmental Council
Special fire-extinguishing method Separate the product from the source of fire, if possible and extinguish fire
from the windward.
Advice for fire-fighters Wear appropriate protective clothing (heat resistance) while
extinguishing fire.
6. Accidental release measures
Personal precautions The worker should wear appropriate protective equipment to avoid contact
with the eye and skin or inhalation if dust evolves by cutting the pipe.
Environmental precautions Cautions should be exerted not to affect the environment resulting from
release to rivers etc. Never discharge to the environment.
Collection If pipe cutting produces dust, rake and collect dust in an empty container and
dispose of it later.
Prevention of secondary hazards If pipe cutting produces dust and if dust remains on the floor, there is a
danger of slipping: frequent sweeping is required.
7. Handling and storage
Handling (Shavings)
Engineering measures Implement equipment measures as described in "8. Exposure
controls/personal protection" and wear protective equipment.
Local / general ventilation Implement local / general ventilation as described in "8. Exposure
controls/personal protection."
Precautions for safe handling Do not inhale or swallow the product (shavings).
Wash hands well after handling.
Provide ventilation for emission to keep the airborne concentration below
the exposure limit. (If pipe cutting produces dust)
Use the product only outdoor or in an area with good ventilation.
Avoid release to the environment (if pipe cutting produces dust).
Contact avoidance See "10. Stability and reactivity."
Storage (Shavings)
Engineering measures Avoid fire.
Storage condition No specific technical countermeasures are required.
High Impact poly vinyl chloride pipes for water supply(HI-PVC) ASAHI YUKIZAI CORPORATION
: Shavings (JIS K 6742, AS20) No.D-015e-00
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Preparation date: Nov 22, 2017
Safety Data Sheet Revision Date: -
8. Exposure controls/personal protection
Control parameters
Control Allowable concentration Allowable concentration
Component
concentration (Japan Society for Occupational Health) (ACGIH)
- - - -
Equipment measures Handling shall be conducted where a general ventilator is installed.
(If cutting produces dust)
Protective equipment
Respiratory protection Use personal respiratory protective equipment where necessary.
Hand protection Use personal hand protective equipment where necessary.
Eye protection Use personal eye protective equipment where necessary.
Skin protection Use personal protective clothing and protective face mask where necessary.
Sanitary measures Wash hands thoroughly after handling.
9. Physical and chemical properties
Physical state
Appearance Solid (Pipe)
Color Gray
Odor Almost odorless
pH No data available
Flash point 454ºC [Sourced from] "Plastic Data Handbook" edited by Kimimasa Ito,
Kogyo Chosakai Publishing Co., Ltd. (1980)
Specific gravity Approx. 1.4g/cm3 (20 ºC)
Combustion quality Self-extinguishing
Solubility Not soluble in water but soluble in ketone and THF.
10. Stability and reactivity
Chemical stability Stable under normal condition.
Possibility of hazardous reactions No information
Conditions to avoid No information
Incompatible materials No information
Hazardous decomposition products If it burns, it evolves hazardous gas (key ingredients of gas are HCl, CO and
CO2).
11. Toxicological information
Under a general environment it is a solid pipe showing no hazardous cases.
However, the following items may apply to shavings and fragments that may
occur during pipe installation.
Acute toxicity
Oral Not classifiable due to the lack of data
Dermal Not classifiable due to the lack of data
Inhalation Not classifiable due to the lack of data
Skin corrosion / irritation Not classifiable due to the lack of data
Serious eye damage / eye irritation Not classifiable due to the lack of data
Respiratory sensitization or skin sensitization Not classifiable due to the lack of data
Germ cell mutagenicity Not classifiable due to the lack of data
Carcinogenicity Not classifiable due to the lack of data
High Impact poly vinyl chloride pipes for water supply(HI-PVC) ASAHI YUKIZAI CORPORATION
: Shavings (JIS K 6742, AS20) No.D-015e-00
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Preparation date: Nov 22, 2017
Safety Data Sheet Revision Date: -
Reproductive toxicity Not classifiable due to the lack of data
Specific target organ toxicity (single exposure) Not classifiable due to the lack of data
Specific target organ toxicity (repeated exposure) Not classifiable due to the lack of data
Aspiration hazard Not classifiable due to the lack of data
12. Ecological information
Environmental hazards
Hazardous to the aquatic environment Not classifiable due to the lack of data
(Acute)
Hazardous to the aquatic environment Not classifiable due to the lack of data
(Long-term hazard)
Ecotoxicity No information
Residual/decomposition property Not easily decomposed under a general environment.
Biological concentration No information
Mobility in soil No information
Other Follow "13. Disposal considerations" when disposing of the product.
13. Disposal considerations
Waste from residues Follow the related laws and regulations as well as the local government’s
standards for disposal.
Outsource disposal to an industrial waste vendor licensed by the prefectural
governor or the local government if it disposes of waste.
When outsourcing waste disposal, the waste vendor must be fully informed
of its hazards and harmful effects before outsourcing.
This product is classified as waste plastics (stable industrial waste).
Reference: It is incinerated at a furnace with exhaust gas treatment device or
buried as non-hazardous waste. [Sourced from] Vinyl Environmental
Council "Safety Information on PVC Resin")
Contaminated container and package (shavings) Not applicable
14. Transport information
International regulations
Marine regulation information No restrictions
Aviation regulation information No restrictions
Domestic regulations
Land regulation information No restrictions
Marine regulation information No restrictions
Aviation regulation information No restrictions
Special safety measures Follow "7. Handling and storage."
15. Regulatory information (in Japan)
Industrial Safety and Health Act Not applied
Waste Management and Public Cleansing Act Industrial waste (classification when it is disposed of as waste)
Poisonous and Deleterious Substances Control Act Not applied
Fire Service Act Not applicable or non-hazardous material
Foreign Exchange and Foreign Trade Act Not applied
High Impact poly vinyl chloride pipes for water supply(HI-PVC) ASAHI YUKIZAI CORPORATION
: Shavings (JIS K 6742, AS20) No.D-015e-00
page：5/5
Preparation date: Nov 22, 2017
Safety Data Sheet Revision Date: -
Ship Safety Act Not applied
Civil Aeronautics Act Not applied
Act on Port Regulations Not applied
16. Other information
Contact information Specified in "[Link] and Company information."
References JIS Z 7250-2010 Material Safety Data Sheet (MSDS)
Japan PVC Pipe and Fittings Association website "Product Summary"
Vinyl Environmental Council website "PVC safety information"
"Plastic Data Handbook" edited by Kimimasa Ito, Kogyo Chosakai
Publishing Co., Ltd. (1980)
Others Unplasticized poly vinyl chloride pipes for water supply is a molded product
and is therefore not applicable to GHS classification but GHS classification
was conducted assuming micro-powder dust that may be produced when it is
being handled or cut.
The content described on the Safety Data Sheet for this product is based on
the materials and information available at this point in time but we are
unable to provide any sort of warranty with respect to hazards, physical and
chemical properties.
Precautions and considerations are based on normal handling. If you handle
the product in a special manner, full safety measures shall be taken to meet
its intended use and usage method.
Please discard the previous material safety data sheet of the product, if any.
Please confirm whether your SDS is the latest version if the date of
preparation / revision is more than two years ago since SDS will be revised
according to revision of the laws or improvement of the product.
SDS delivery route: Safety Data Sheet (SDS) is delivered to end users on the
following route.
If you have no SDS or any inquiry about the latest version, please contact
us through the distribution route.
[Manufacturer → Distributor → User]
