Chomety (Bscjo Dor 1
asrt-A
Onuldatlovn Number 01
Mn in HnO4
h e 0udaten umbn oHn be
b + and O -2
Onidation Nunber e
H ) + +
4(-2) -0
+ l -8 0
- =0 =
Onudahien number Mn istt
2) The tempratun at whi ch realo non- ldoal gal thaue as an
ldaal gas otds Yanga pVaisw calld Boyle's
vel a
LeMpehadure Ts)
ca) Tmpeat intensive Rpe
6) olum i angfonaive propU a t dopends upo mass.
Cc) Dend an
thtendiu pvepy
3 b) Vo-lunne
Veuwn a n ectenslu prepiy aL it
drpandi upon mass
So it daPLndi on h
si o amOnt 0mattur in
dh gysam.
ha isomanis m Lohith ompoLLnes hao is
t e eishnc
wo 6 m e CompbuRds ahat a s Capabu 6 laial
ntlconuUs{m, byhe intuAConueng hey sil stay un
uill 9 ubrium
ELampli ketona- tnol, enanne Imun -
Chemistry (8SC/o2) N.-2
Kero -Rndl
R bH
CRg C=
H
ukerd Pno
Th amn (NH) qmeup in ani oho and pa& dvaag
o u p ooude thoy Can relase dactY end fowasdi ring
ous to ha Sonandc and ot Hh sam ime thy wlthdrau tha
alactv ons tDu d s Aamtelou hom ahomcic ietpeiunds Yng du
to ect whesAs, s amidus au lus aclivalng bcase
oCAuiee hey m struechuts that pal the uctren
rsonant
uctron dunsil aayhom hi hng 3o the aL ma
di've tk
MsomLic ec nduchiu sc
Induchua let is an uchrenic
1 Matomuic a t isaMesult
in pola moleculs vions
Subshtuens tundnOml ect
CLR fo ha po LarisaHen dr bond
n an thrmical tompound
qreupA
u The ualdative nuthod descvibing hman Caui hu
th lectrmagatiudrnt
h e Ltren-
Ah e t
Lothdrawing o releating greup oetween the atovme a t i h e r
Pnd othe bonod
PTepeis he ubst tuun,
bated tn relayart esoranc
STruttwns
Ea-0-H and C- bondo
prepunal
hemi s Fry ocC lo 2) No,3
The hybvide'gakien PCts u spsd
7
Shape tvigenal bipymamidal
0ygn ipaAAa paama nagnne because h a twe
npaunad luetmen n its lasFmelecula b i tal. Hs Sudh,
npauld
un
when Hwa a berpe npaiineol eleetrems hey spn
a giaaler maquatic iala e e
the Scm direetaon gneratung
Chanaatanuaue
Qnd qwuo it a paamagnatie
9peetrescopie mthod aduanegeous v e classial
0wethed becauus taulews the meagwRment e bethn
CTYs ia i n and anmerpes gubs taunces DFalleuws analyso
e e e n S g e hairo e pautelusD can bpa mad
wnden implo Cendhene Which de met h o o n e vattttt
va CuuM PAedueon e centrot fRl reaHe humuidua,
haaUung ceetng
0)Moleulo spertrescopy is used as a teel o shudgiung
he sTuctuwes o tvpr atems and moleoules. Tho
avelengh emitted lau
lasge
laee
Lmbar e
Systms makos passibu. to m vestgatz thai struch
ihn d a t a l inolurdung h ootren cenkGunatiew
eund And vauous e t t Rcitnd sfatus thuegh
mouenar sptctvoscepP
Chanistyy (BSC 102) No.41
au
1 Cp
CP Mota ha aapaci ly at Congfant pretsuwe
y Molar heat Capac at constant volum
oletn. han a gas ig hoated at a censtant-veum the woi
the 9as incnaLes th inteAnal pnangy o
Systm AtconLlant pyessun, whom a 20s haotnd , the
we dov (S done to eAceme 1ep p [Link] anol hee
Ppanei b w the uelume with an inchase m the
inteanal A y tha syt Theuton, it ic gaid
Cp aluoay eater han Cy o a qas
12)
Pdbiabsic Tsothannal pnupo n
Cinpraulan
P-V ouagam
Cahnat
Ardbn loodie pens van
Tsothanal
Carnpu slbvu C
Velum
The Cedition undu whuieh he incy
eueAbll Canot engune can be mad on iu only
A T = Ok hais only t o the cold rreseredu
a t abs oute ze d
a No.- 5
Chemsty CBSC|02)
14 The Sallotien Rulu that É Case ploctrewe
transtH ons
AS0 The Spin Rut
i)
u) AL t/-1, Th RDrb ial RulL ( lapoie)
Ralanah bn o Rudes canee 0Cw thaeug h'
Spu 0rbik teuplrg This iues mise to baeak SpLn
nbldden bands.
u) Vibrenic teuplung hm cotahedral Cemplen may be havee
allosedl uibratiow whwne he MOulla u
asymmatvic
osor pen bghtat hat mement io then poasible
u) Miung TT-ACCep and - deno ligando can uiou
with d- Onbitals go fyonstftbns a ne
lenges pk
p Pudy d-d.
15 n Dhdun to a
oompeund on Selutien to erhibit tolaun, the
Contyal attn o t h cempeund sheuld hawe atkanst
Cun pacvrtd unpaiud eleetron d esetren in it. Thio
w absAAb gtt and hon re - emt i a particular
Se
wwavelengtn tnsqwng a celaun. utA in case Z 2 ion
t has a l Sub-shell, 3dl°, wwich olses net allsw
et elocrenie, tronsitiewa which adcen a the colown
tronsitien,tompeunds Jn aELS a4 aqUROs solution
euma t h ceteunless shablu hydnatad ine Comple
T2n lH,O.1 c a u Gmet hovng
any wpaud
eloctrono in d- Stub Shall , P tuo complan io cetounles.
Chamust (8se 102) Pa No.-6.
16) AUy and [Link] halidss undAgo rnucluophilic atfaok vey
Raslybecaua hey fom steble Carbocahien du to
[Link] onanC daloca usoa H on )behween T - bnd and 4he
eaNen toAmedl and ginc S SN, Yackion inu-o-ls onet
oAnah oY Carboca ion AS intumadi att thoy ar
igh
Yea tive fokuasds Yucluophitic attatk . n bon ) [Link] ion,
posihue dhaa ALLoCaed on ha benene ving uwidh mesonmanec
o ich mals m p R skab And aluo allykc eel
Canboca A on, Changi u detoenct dulocalined via d e u b l
oond wwich makes i meiu Stabl Thus , fhey wdugo
welLopnlic attach vapdb and easily
17) The Mett Cemmer r s t gemeatuen ancti - Cane oouug u
Cisplatin
Sunthess eisplatn is
2k p
2 2
2K P C7
excs 2k P P +2T
NM
N, 72
C H LN7
Pt
kCu
cess K
.cs P NO 2AaT
KNO
KNO, +
H0 NH
C NH
Cisplain
Pa No.-7
Chamisty(BSC/o2)
fant-C
19k nea chevH-tt) ols
Hu spentenieuspysical and chenical changs fekes
pdr place m the olivaction 6{ a dseaaat m u
evogyHopetonLes reactien may invele an
incicaoe ey
docheaae in thalpy, i may m s inelue an 1Mehaae
[Link] im imdm entrep but it wl alloays,
nvewt a doelease n e mngy thot is AGT to be
H,oC) +4lk Hol)
Here he DH posihu but thus Cannu be a
techo to decidL thot th readev IS SpemBanee-us oA net.
whon fhe wot enapehatas the asectat om w a b
meluenlos yaplaced ay ndividual wal vapew meleoulu,
oung Aandapant indupendanty im vevapo-u phase wn th
muwch nioherinete enngy Thusthe trangi Hon b
e Syetew e m an odored aa alangemant pentelo
o Kos ohdhd anangimet Had u t a
Teaeton, S s positiue, and d huus
entrep
entropy n
Anteasts duirng the prouks, because wata vapeu
naR mere nrep ale.
han So,as
OC H -TAS TAS AH, 9o, t DGn bicemos
mLcgative and the Taacuon ic SpendanuBus heugh
Enegeicay nfavehed
Chemis tmy Psc (02) g No.- 8
20) I l o SHW Im oCaCO, aquivaluut
S0ml SH
SOml S 2 0 mo EDTA eoluto
2 0 ml EDTA S0 ma d e Caco eq
Ion EDTA 50
ng CaCD, 1
So ml watu Samp 3 0 ml £DTA siorm
500 m o wate sample ODD X 230
50
6 0 0 ml o EpTP Soluti om
But, Iml DTA 25 CaCO3 292
CaCO3
RSx 6o S6 mg CaCO
q4 EDTA
=
600 m
Tetal hordnosg ( wat S oo mgL
500 PPm
Chemis try (BC 102 a No.-9
21)s R FeCHa0)
Fe sd
3dand Ft,0 a eak ald igend so
PauY Mot take place AR and leetres mt to
ta and 2co ahetrreo
CFSE Gbital
CFSE -0:4 4Ao + 0:6 x 2A6 -04 A
Sustaun
)TnFelCN) iren has 3d 1s in GTound
ha
shet
Quu in 9heund stou LE loses tuwe lestrens m
emaK en I6s atrensem Hs , so fhud
Onol tuwe
Co-bot gus 3de Conigwratim,. N i i s qleus
du to CN So all
igand ,30 all
spin cempler
lecres g o to tag obitals ,andO slsctrens u l
Bein a bik
SE L-0-4A 0L06) 6-04
t o(o-6)A
-24 B. v )
Prntibend ing o
33 m7 Pntibordurg T
Non-bondng n
Er T
ording T7
Londing
Molorulo elertrenit tronai Hevs tu plaA whan
lortrow in a melel anl pNelidem one enng
to hgher tnegy len luel. The Rnegy
a
hong
thang
[Link] &CC1o2)
AStociadad with thuo tvanai fion P70u-aleo dnfoAmaio
datAmuns u
ern tha 9ruetuna o a malatul and
relscuan propakes guah as olow
23
23 Kachan em
Strp n ravose otdh, Tha hydronu do ion dapyohnals
ha aldihdu
CH, CHO t 0
H CHO
Stap Rou Enolate im, odas to tha unaaefad-arldokN
-H CH, CH
PL,-CH-Ch,CHO
ibn u pYotonated atnA
Step lou du
O
H,C-CH- Ch, CHo "o H CH-CH,CHO
Stap 1 ASmal ambundt
jon.
alda s Lonuuted into moloti
Aop by hydyo uids
,c-CM-CHCHo oH > H,CCH-cHCHOo
hawisty (BSC 102)
Step 5
Me n l a t i en oses hdro ud ion
:O
, (-Ch-CHCHO CH CH =
CHCH 0+
DH
By-produrla-
O era lacatevte FT em i n c e p t i Condonakend
[Link] Diaceto alcohl (-h drouy
muthylpntan -2- ev ) amd mesityl oid a-KaRp
mhaP -on e v -mthgant--an-2om
tetovu ihsetoound
From ha aldai Condengaion
hyduhdva Han uB-hydve htna
