SAFETY DATA SHEET
Issue date 29-Apr-2016 Revision Date 02-May-2016 Version 1
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
1.1. Product identifier
Product name DMA-748
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use Oilfield Chemical
Uses advised against No information available
1.3. Details of the supplier of the safety data sheet
Supplier
Flotek Chemistry, LLC
1004 S. Plainsman Road
Marlow, OK 73055
Phone +1 (580) 658-6608
Fax +1 (580) 658-3223
CESI Chemical, Holland Branch
Waanderweg 64
7812 HZ, Emmen
The Netherlands
Phone +31 (0) 591-677550
For further information, please contact:
E-mail address information@[Link]
1.4. Emergency telephone number
Emergency telephone +1 405-282-8510
2. HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Regulation (EC) No 1272/2008
Serious eye damage/eye irritation Category 2
Specific target organ toxicity (single exposure) Category 3
Physical hazards Flammable liquids Category 3
2.2. Label Elements
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Signal Word
Warning
Hazard Statements
H319 - Causes serious eye irritation
H336 - May cause drowsiness or dizziness
H226 - Flammable liquid and vapor
Precautionary Statements - EU (§28, 1272/2008)
P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction
P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking
2.3. Other information
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
Chemical Name EC-No CAS-No Weight-% Classification (Reg. REACH Registration
1272/2008) No.
Isopropyl alcohol Present 67-63-0 10-30 Flam. Liq. 2 (H225) 01-2119457558-25
STOT SE 3 (H336)
Eye Irrit. 2 (H319)
EGMBE Present 111-76-2 1-5 Acute Tox. 4 (H302) No data available
Acute Tox. 4 (H312)
Skin Irrit. 2 (H315)
Acute Tox. 4 (H332)
Eye Irrit. 2 (H319)
4. FIRST AID MEASURES
4.1. Description of first aid measures
General advice
Show this material safety data sheet to the doctor in attendance. If symptoms persist, call a physician.
Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Keep eye wide open while rinsing.
Skin contact
Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists,
call a physician.
Ingestion
Call a physician or poison control center immediately. Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Drink plenty of water.
Inhalation
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If symptoms persist, call a
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physician.
Self-Protection of the First Aider
Remove all sources of ignition. Use personal protective equipment as required.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed.
Notes to physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
5.1. Extinguishing media
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use CO2, dry chemical,
or foam.
Extinguishing media which must not be used for safety reasons
No information available.
5.2. Special hazards arising from the substance or mixture
Special Hazard
None in particular.
5.3. Advice for firefighters
Special protective equipment for fire-fighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Remove all sources of ignition. Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas. Ensure
adequate ventilation. Use personal protective equipment as required. If spilled, take caution, as material can cause surfaces to
become very slippery.
See section 12 for additional ecological information.
6.2. Environmental precautions
Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary
sewer system.
6.3. Methods and material for containment and cleaning up
Dike to collect large liquid spills. Prevent further leakage or spillage if safe to do so.
Soak up with inert absorbent material. Clean up promptly by sweeping or vacuum. Sweep up and shovel into suitable containers for
disposal. Keep in suitable, closed containers for disposal.
7. HANDLING AND STORAGE
7.1. Precautions for safe handling
Ensure adequate ventilation. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures
against static discharges. Avoid contact with skin, eyes or clothing. When using do not eat, drink or smoke. Wear personal
protective equipment/face protection. Do not breathe vapors or spray mist. Never pierce, drill, grind, cut, saw or weld any empty
container.
7.2. Conditions for safe storage, including any incompatibilities
Keep tightly closed in a dry and cool place. Keep in properly labeled containers. Keep from freezing.
7.3. Specific end use(s)
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Isopropyl alcohol STEL: 400 ppm TWA: 400 ppm IDLH: 2000 ppm
67-63-0 TWA: 200 ppm TWA: 980 mg/m3 TWA: 400 ppm
TWA: 980 mg/m3
STEL: 500 ppm
STEL: 1225 mg/m3
EGMBE TWA: 20 ppm TWA: 50 ppm IDLH: 700 ppm
111-76-2 TWA: 240 mg/m3 TWA: 5 ppm
S* TWA: 24 mg/m3
NIOSH IDLH: Immediately Dangerous to Life or Health
Exposure limits
Chemical Name European Union United Kingdom France Spain Germany
Isopropyl alcohol Not available STEL: 500 ppm STEL: 400 ppm Not available TWA: 200 ppm
67-63-0 STEL: 1250 mg/m3 STEL: 980 mg/m3 TWA: 500 mg/m3
TWA: 400 ppm Ceiling / Peak: 400
TWA: 999 mg/m3 ppm
Ceiling / Peak: 1000
mg/m3
EGMBE Not available STEL: 50 ppm TWA: 10 ppm Not available TWA: 10 ppm
111-76-2 STEL: 246 mg/m3 TWA: 49 mg/m3 TWA: 49 mg/m3
TWA: 25 ppm STEL: 50 ppm Ceiling / Peak: 20 ppm
TWA: 123 mg/m3 STEL: 246 mg/m3 Ceiling / Peak: 98
mg/m3
Component Italy Portugal Netherlands Finland Denmark
Isopropyl alcohol Not available Not available TWA: 200 ppm 8hr, Not available TWA: 200 ppm TWA:
67-63-0 ( 10-30 ) 500 mg/m3 8hr 490 mg/m3
EGMBE Not available Not available Not available Not available TWA: 20 ppm TWA:
111-76-2 ( 1-5 ) 98 mg/m3
Skin
Chemical Name Austria Switzerland Poland Norway Ireland
Isopropyl alcohol STEL 800 ppm STEL STEL: 400 ppm Not available Not available Not available
67-63-0 2000 mg/m3 STEL: 1000 mg/m3
MAK: 200 ppm MAK:
500 mg/m3
EGMBE Skin STEL: 20 ppm Not available Not available Not available
111-76-2 STEL 40 ppm STEL STEL: 98 mg/m3
200 mg/m3
MAK: 20 ppm MAK: 98
mg/m3
Derived No Effect Level (DNEL) No information available
Predicted No Effect Concentration (PNEC) No information available
8.2. Exposure controls
Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations
and safety showers are close to the workstation location. Where reasonably practicable this
should be achieved by the use of local exhaust ventilation and good general extraction.
Personal protective equipment
Eye Protection Safety glasses with side-shields. Goggles.
Hand Protection Impervious gloves. Nitrile rubber.
Skin and body protection Wear suitable protective clothing.
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Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn.
Hygiene measures When using do not eat, drink or smoke. Provide regular cleaning of equipment, work area
and clothing.
Environmental Exposure Controls Do not allow material to contaminate ground water system.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Physical State Liquid Appearance slight haze
Odor Alcohol Color light brown
Property Values Remarks/ Method
pH 8.19
Freezing Point -18.89 °C / -2 °F
Boiling point / boiling range No data available
Flash Point 31.3 °C / 88.34 °F CC (closed cup)
Evaporation rate No data available
Flammability (solid, gas) No data available
Flammability Limit in Air No data available
Upper flammability limit
Lower flammability limit
Vapor pressure No data available
Vapor density No data available
Relative density 0.942-1.00
Water solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Explosive properties No data available
Oxidizing Properties No data available
Softening point
Molecular Weight
VOC content No data available
Density Bulk Density 7.85-8.35 lbs/gal
10. STABILITY AND REACTIVITY
10.1. Reactivity
No data available.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Hazardous polymerization does not occur.
10.4. Conditions to Avoid
Heat, flames and sparks.
10.5. Incompatible Materials
Strong oxidizing agents. Incompatible with strong acids and bases.
10.6. Hazardous Decomposition Products
Carbon oxides.
11. TOXICOLOGICAL INFORMATION
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11.1. Information on toxicological effects
Acute toxicity
Product Information
Inhalation Inhalation of vapors is irritating to the respiratory system, may cause throat pain and cough.
Eye contact Avoid contact with eyes. Severely irritating to eyes. May cause irreversible damage to eyes.
Skin contact Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis.
Ingestion Harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhea. May be fatal or cause blindness if swallowed. May cause drowsiness or dizziness.
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
Isopropyl alcohol = 1870 mg/kg ( Rat ) 12800 mg/kg ( Rat ) = 72600 mg/m3 ( Rat ) 4 h
12870 mg/kg ( Rabbit )
8.00 mL/kg, 6280 mg/kg ( Rabbit )
EGMBE = 470 mg/kg ( Rat ) = 400 mg/kg ( Rabbit ) = 450 ppm ( Rat ) 4 h
= 2270 mg/kg ( Rat )
Chronic toxicity
Carcinogenicity Contains no ingredient listed as a carcinogen >0.1%
- California - Proposition 65 - Carcinogens List
Sensitization No information available
Neurological effects No information available
Reproductive toxicity No information available
Mutagenic effects No information available
Developmental Toxicity No information available
Teratogenicity No information available
Target Organ Effects No information available.
12. ECOLOGICAL INFORMATION
12.1. Toxicity
Ecotoxicity .
Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to daphnia and
Microorganisms other aquatic invertebrates
Isopropyl alcohol 1000: 72 h Desmodesmus 9640: 96 h Pimephales - -
subspicatus mg/L EC50 promelas mg/L LC50
1000: 96 h Desmodesmus flow-through 11130: 96 h
subspicatus mg/L EC50 Pimephales promelas mg/L
LC50 static 1400000: 96 h
Lepomis macrochirus µg/L
LC50
EGMBE - 1490: 96 h Lepomis - -
macrochirus mg/L LC50
static 2950: 96 h Lepomis
macrochirus mg/L LC50
12.2. Persistence and degradability
No information available.
12.3. Bioaccumulative potential
No information available.
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12.4. Mobility in soil
No information available.
12.5. Results of PBT and vPvB assessment
No information available
12.6. Other adverse effects
13. DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste from Residues/Unused Products Dispose of in accordance with local regulations.
Contaminated packaging Do not reuse empty containers. Empty containers should be
taken to an approved waste handling site for recycling or
disposal.
EWC Waste Disposal No According to the European Waste Catalog, Waste Codes are not
product specific, but application specific Waste codes should be
assigned by the user based on the application for which the
product was used
14. TRANSPORT INFORMATION
DOT
Proper shipping name UN1993, Flammable liquids, n.o.s., (contains Isopropanol and EGMBE), 3, PG III
Hazard class 3
UN/ID no. UN1993
Packing Group PG III
IMDG/IMO
Proper shipping name UN1993, Flammable liquids, n.o.s., (contains Isopropanol and EGMBE), 3, PG III
Hazard class 3
UN/ID no. UN1993
Packing Group PG III
ADR/RID
Proper shipping name UN1993, Flammable liquids, n.o.s., (contains Isopropanol and EGMBE), 3, PG III
Hazard class 3
UN/ID no. UN1993
Packing Group PG III
ICAO/IATA
UN/ID no. UN1993
Proper shipping name UN1993, Flammable liquids, n.o.s., (contains Isopropanol and EGMBE), 3, PG III
Hazard class 3
Packing Group PG III
15. REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
International Inventories
TSCA Complies
EINECS/ELINCS -
DSL/NDSL Complies
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PICCS -
ENCS -
IECSC -
AICS -
KECL -
Legend
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
PICCS - Philippines Inventory of Chemicals and Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
AICS - Australian Inventory of Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
15.2. Chemical Safety Assessment
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name CAS-No Weight-% SARA 313 - Threshold
Values %
Isopropyl alcohol 67-63-0 10-30 1.0
SARA 311/312 Hazard Categories
Acute Health Hazard Yes
Chronic Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR.
Chemical Name WHMIS Hazard Class
Isopropyl alcohol 1%
B2,D2B
EGMBE 1%
B3,D1A,D2B
Chemical Name NPRI
Isopropyl alcohol X
Legend
NPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
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NFPA Health Hazard 2 Flammability 3 Stability 0 Physical and chemical
hazards -
HMIS Health Hazard 2 Flammability 3 Physical Hazard 0 Personal protection -.
Full text of H-Statements referred to under sections 2 and 3
H302 - Harmful if swallowed
H312 - Harmful in contact with skin
H315 - Causes skin irritation
H332 - Harmful if inhaled
H319 - Causes serious eye irritation
H225 - Highly flammable liquid and vapor
H336 - May cause drowsiness or dizziness
H319 - Causes serious eye irritation
H336 - May cause drowsiness or dizziness
H226 - Flammable liquid and vapor
Prepared By HSE Department
Issue date 29-Apr-2016
Revision Date 02-May-2016
Revision Note Not applicable.
This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
US Only: This safety data sheet complies with the requirements of the OSHA Hazard Communication Standard 29 CFR
1910.1200.
Disclaimer
While the information and data contained herein are presented in good faith and believed to be reliable, nothing herein
shall be deemed to constitute a warranty, express or implied, that the information or data is reliable, accurate, or
complete or that the products described herein are merchantable or fit for a particular purpose or that said information,
data, or products can be used without infringing the intellectual property rights of third parties. Individuals who receive
the products or the information or data relating to the products described herein, must use their own judgment in
determining fitness for a particular purpose. Unless otherwise stated, the information or data contained herein relates to
the products when not used in conjunction with any other products or materials. Flotek Industries, Inc. and its affiliates
(“Flotek”)di scl
aim al lexpressandi mpl i
edwar rant i
esofmer chant abi
lity,fitnessf orapar ticularpur pose,and
non-infringement. Flotek shall not be liable for any loss or damage that may occur from the use of the products
described herein, including the use of the products in conjunction with other products or materials, or reliance on the
data or information described herein.
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