KURDISTAN REGION -IRAQ IN THE NAME OF GOD Name…………………

HIGH COMMITTEE OF GENERAL EXAMINATIONS

Preliminary Examinations for Preparatory Stage
m Subject: Chemistry
(Scientific) (2020-2021) Time: 2 Hours
14. Intermolecular forces of attraction in alkanes are :-
A. Strong interface forces B. Hydrogen bonds
C. London dispersion forces D. Both (B + C ) are correct
Answer the following questions : ( two marks for each right choice )
1. One of the following equations does not represent redox reaction.
o 15. Hydrofloric acid (HF) is a weak electrolytes because :-
A. The bond between H,F is strong and can not easily be broken .
A. 2KNO3
C. H2 + Cl2
2KNO2 + O2
2HCl
B. H2 + CuO
D. NaOH + HCl e Cu + H2O
NaCl + H2O
B. It is completely ionized
C. The bond between H,F is very weak and can easily be broken .
2. Which of the following solutions with the same concentration has the lowest PH ? D. It conducts electrical current well.
A. HCl B. CH3COOH C. NaOH g D. NH3 16. Calculate the equilibrium constant ( K ) for the following gaseous reaction: 2SO2 + O2 2SO3 at 900 K
when you know that the equilibrium system contains 0.4 mol of each O2 , SO2 and SO3 in a 2.0 L vessel
3. The Tyndall effect is used to distinguish between:-
A. Solvents and solutes
C. Sugar solution and milk
r
B. Liquids and gases
D. Sand and water
A. 0.2 B. 5
17. Which one of the following pairs is a conjugate pair ?
C. 8 D. 4

[Link]- , H+ B. NH2- , NH4+ C. H2SO4 ,HSO3- D. HCl , Cl-

4. The following reaction ( CH2 = CH2 + H2
A. substitution B. addition C. eliminationo
CH3 – CH3 ) is a kind of …………….. reaction.
D. condensation 18. One of the following is an important plant hormone, induction of flowering and fruit ripening.
5. What is the expected change in the freezing point of water in a solution of 125 g of barium nitrate ,Ba (NO 3)2 in A. Ethane B. Ethene C. Acetylene D. Ethelene glycol

A. 2.66 Co B. -2.66 Co C. -0.88 Co

u
1 kg of water? (molar mass of Ba (NO3)2 = 261.35 g / mol , Kf water = -1.86 C0 / m )
D. 0.88 Co
19. 35 g of a material is heated from 293 K to 313 K and absorbed 48 J of energy, how much energy will the
sample gain when it is heated from 313 K to 343 K ?

p
6. Calculate the solubility product constant, ( Ksp ) of lead chloride ( PbCl2 ) which has a solubility of 0.036M at 25C0
.
A. 72.45J B. 0.069J C. 74.25 J D. 7.245 J
20. The change in concentration of reactants per unit time as a reaction proceeds is called:-
-8 -10 -11 -4
A. 1.86X10 B. 4.66X10 C. 3.2X10 D. 1.86X10 A. Specific Rate Constant B. Equilibrium Constant
i
7. Which one of the following is used as an antacid to relieve discomfort caused by excess hydrochloric acid in the C. Reaction Rate D. Chemical Equilibrium
stomach ? 21. Which of the following is considered as one of the strongest reducing agent ?
A. Ba(OH)2 B. Ca(OH)2 C. Mg(OH)2
d
8. Which one of the following compounds is considered as saturated hydrocarbon compound ?
D. NaOH A. Li B. F2 C. Pb
22. Determine the concentration of Ca(OH)2 solution if [H3O+]=2X10-11M
D. Li+

A. C3H8 B. C6H6 C. C2H4 D. C5H8 A. 5X10-4M B. 2.5X10-4M C.1X10-4M D. 5X10-3M

9. Which one of the following processes has negative ∆S ? 23. Which of the following effects the solubility of solids in liquids ?
A. Evaporating one mole of a liquid A. Agitation of solution B. Increasing the surface area of the solute
B. raising the temperature of 1 L of water from 295 K to 350 K C. Temperature D. All of them are correct
C. freezing of one mole of a liquid
24. The organic compounds in which two hydrocarbon groups are bonded to the same atom of oxygen are called :
D. fizzing process .
A. Alcohols B. Ethers C. Carboxylic acids D. Esters
10. A particular reaction is found to have the following rate law : R=K[A][B] when the concentration of B is
2
25. How many moles of anions are produced by the dissociation of 1.4 mol Aluminum sulfate Al2(SO4)3 ?
cut to half and the concentration of A quadruples , the rate of reaction will ……………
A. 2.8mol B. 4.2mol C. 7mol D. 5mol
A. be twice B. be 16 times C. be 64 times D. remain as it is
26. If the pressure on the equilibrium gaseous system ( A + 3B 2C ) is increased
11. This half reaction 2MnO2 + H2O + 2e Mn2O3 has lack of :-
- A. The reaction is shifted to the right . B. The reaction is shifted to the left
A. electrons B. OH ions C. Mn+2 ions D. O-2 ions
C. The equilibrium state does not change D. The value of K is increased .
12. Which of the following solutions is not considered a basic solution ?
27. Whose acid definition is broadest ?
A. [H3O+]=5X10-11M B. [H3O+]=5X10-5M C. [OH-]=5X10-5M D. [OH-]=10-6M
A. Arhenius B. Bronsted-Lowry C. Lewis D. Le Chatelier
13. What mass of NaOH in 1 L of its solution with a concentration 0.01 M . When molar mass of NaOH =40 g /mol
A. 1g B. 40g C. 0.4g D. 4g
 42. In an aqueous solution of salt of strong acid and weak base , which of the following is correct ?
28. What is the name of this compound ( ) according to the IUPAC system ?
A. The anion undergoes a hydrolysis reaction. B. The pH value does not change .
A. methyl benzene B. ethyl benzene C. methyl cyclo hexane D. 1- methyl cyclo hexane
C. The pH value increases. D. The cation undergoes a hydrolysis reaction
29. Calculate the enthalpy of formation of CO gas . By using the balanced thermo chemical equations .
43. Ions that do not take part in chemical reactions and are found in a solution both before and after reaction are:-
1- C(s) + O2(g) CO2(g) ∆Hfo=-393.5 kJ/mol
A. poly atomic ions B. common ions C. Spectator ions D. Mono atomic ions
2- CO(g) +½ O2(g) CO2(g) ∆Hco=-283kJ/mol
A. -110.5kJ/mol B. 110.5kJ/mol C.-676.5 kJ/mol D. 676.5 kJ/mol 44. The aqueous solution of KF has one of the following properties: -
A. Acidic B. Basic C. Neutral D. Amphoteric
30. Changing the temperature affects the rate of reaction because it affects:
A. The energy of the activated complex B. The properties of the reactants 45. The net ionic equation for the reaction of Zn with HCl is :-
C. The enthalpy of the reaction. D. The number of effective collisions. A. Zn(s)+ HCl(aq) ZnCl2(aq) + H2(g) B. Zn(s) + H3O+(aq) Zn+2(aq) + H2O(l) + H2(g)
+
C. Zn(s) + 2H3O (aq) Zn+2(aq) + 2H2O(l) + H2(g) D. Zn(s) + 2H3O+(aq) Zn(s) + 2H2O(l) + H2(g)
31. Determine the number of moles of H2SO4 that would be chemically equivalent amount of the 1.4 mole of NaOH
A. 0.7mol B. 1.4mol C. 1mol D. 2mol 46. Which of the following compounds are often formed during the breakdown of proteins in animal cells , their foul
odors? A. Alcohols B. Carboxylic acids C. Aldehydes D. Amines
32. The enthalpy of solution for AgNO3 is +22.8KJ/mol as, AgNO3 dissolves .What change occurs in the
temperature of the solution? 47. The enthalpy of formation of the products in a reaction is - 600KJ / mol and the enthalpy of formation of the
A. the temperature of the solution decreases. B. the temperature of the solution does not change. reactants is – 550 KJ / mol Which of the following is correct?
C. the temperature of the solution rises slightly. D. the temperature of the solution rises a lot. A. ∆H0 = 50KJ B. ∆H0 = - 50KJ
C. the products are more stable D. Both (B+C) are correct
33. Which formula indicates the number and type of atoms present in molecule and also shows the bonding
arrangement of the atoms? 48. If the slowest – rate step for a reaction : (NO2 + NO2 NO3 + NO) which of the options is the rate law of
A. molecular formula B. structural formula C. empirical formula D. ionic formula the reaction?
A. R=K[NO2] B. R=K[NO2]2 C. R=K[NO3] D. R=K[NO2][NO3]
34. Which one of the following is an ionic compound that dissociated in water?
A. NaCl B. HCl C. CH3OH D. NH3 49. If a base is added to a solution of a weak acid and its salt :-
A. more of the nonionized weak acid forms B. more of the nonionized weak acid ionizes
35. This reaction: AgNO3(aq) + KCl(aq) AgCl(s) + KNO3(aq) tends to run to completion by :
C. precipitation occurs D. the hydronium ion concentration increases
A. formation of gas B. formation of a slightly ionized product
C. formation of precipitate D. None of them is correct 50. This organic compound is called:

36. Which of the following is species is the conjugate acid of another species in the list?
A. propanal B. propane C. 2-propanone D. propanol
A. PO43- B. H3PO4 C.H2PO4- D. H2O
37. Which of the following can not have geometric isomer?
A. C4H10 B. C3H6 C. 1- butene D. All of them not have
38. If you know that the heat of combustion for one mole of toluene equals -3910 KJ/mol, one gallon of toluene has
mass of 1.748Kg. What is the heat combustion for one gallon of toluene.(toluene molar mass=92 g/mol )
A. 74290 kJ B. -74290 kJ C. -72490KJ D. 72490KJ
39. Which one of the statements is false about specific rate constant (K):
A. The value of (K) is determined at the given temperature .
B. The value of (K) changes ( becomes larger ) if a catalyst is present .
C. The units of (K) depend on the overall order of the reaction .
D. The value of (K) is increased by pressure increasing.
40. The oxidation number of oxygen in H2O2 is :
A. -1 B. +1 C. -2 D. Zero
41. Which of the following mixture is homogeneous?
A. sugar and water B. soil and water C. the air D. Both (A + C) are correct