mi nubiola SAFETY DATA SHEET Nubifer Iron Oxide Red Identification of the substance/mixture and of the company/undertaking Product identifier ‘Trade name Nubifer R-2800, R-2501, R-2512, R-2513, R-2621, R-2620, R-2641, R288. Nubifer R-4511, R-4520, R-4521, R-4530, R-4540, R-5501, R-6510, R-S511 Nubifer R-8520, R-5530, R-5531, R-6540, R-6580 Chemical description Ditron trioxide REACH nr. 01-2119457614-35 1.2. Relevant identified uses of the substance or mixture and uses advised against Use Colouring agents, pigments. 1.3, Detalls of the supplier ofthe safety data sheet Company identification NUBIOLA GROUP Gran Via Corts Catalanes 648 05010 Barcelona SPAIN Tel, - 0034 - 93 - 343 57 50 [Link]@[Link] 1.4, Emergency telephone number Phone nr UK National Poisons Emergency + 44 0870 600 6286 2. Hazards identification clas: n of: substan: ixture Classification [Regulation (EC) No 1272/2008 (CLP/GHS, Not classified Classification [67/548/EEC or 1999/45/EC) Not classified Labelling [Regulation (EC) No 1272/2008 (CLP/GHS) Not classified Labelling [67/548/EEC or 1999/45/EC) Not classified 2.3. Other hazards Revised edition no:2 Page: 1/7 Date sri22011 Supersedes : 13/5/2011mi nubiola ur passion your colors SAFETY DATA SHEET Nubifer Iron Oxide Red 2. Hazards identification (continued) Other hazards None under normal conditions 3. Composition/information on ingredients Substance / Mixture Substance, Diiron trioxide, Pigment Red 101, C1 77491 ‘CAS No :001308-37-1 EC No :218-168-2 Index No REACH Ref. :01-2119457614-95, Hazardous components) This product is not hazardous. Composition Fe203 Substance name Contents __CASNo eco hnderlo__ REACH l._classfication Plament Rea 01, 177481, Woteassited (GS) Contains no other components or impurities which will Influence the classification of the product 4, First aid measures 4.4, Description of first ald measures Inhalation ‘Assure fresh alr breathing, Allow the victim to rest, Skin contact Remove atfected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Eye contact Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist Ingestion Do not induce vomiting. Obtain emergency medical attention, 4.2. Most important symptoms and effects, both acute and delayed, ‘Symptoms relating to use Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment nesded General information Never give anything by mouth to an unconscious person. If you feel unwell, sesk ‘medical advice (shaw the label where possible). 5. Fire-fighting measures 5.1, Extinguishing media Suitable extinguishing media Foam. Water spray. Dry powder. Carbon dioxide. Sand, Unsuitable extinguishing media Do net use a heavy water stream. Surrounding fires Use water spray or fog for cooling exposed containers, ‘Special hazards arising from the substance or mixtu Revised edition no:2 Page 2/7 Date : 5712/2011 Supersedes : 13/5/2011mi nubiola SAFETY DATA SHEET Nubifer Iron Oxide Red 5. Fire-fighting measures (continued) Hazardous combustion products Under fre conditions, hazardous fumes will be Advice for fire-fighters Protection against fire Do not enter fre area without proper protective equipment, including respiratory protection, Special procedures Exercise caution when fighting any chemical fire. Avoid (reject fre-ighting water to center environment, 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures. For amergency responders Ventiate area, Equip cleanup crew with proper protection ‘Special precautions Recover the cleaning water for later disposal For non-emergency personnel Evacuate unnecessary personnel 6.2. Environmental precautions Environmental precautions Prevent entry to sewers and publ ‘sewers or public waters, vaters, Notty authorities if product enters 6.3. Methods and material for containment and cleaning up, Clean up methods \Ventilate area. On land, sweep or shovel into suitable containers. Minimize generation of dust Reference to other sections See section 8, Exposure controls/personal protection 7. Handling and storage ‘A. Precautions for safe handling Handling Wash hands and other exposed areas with mild soap and water before eat. drink or ‘smoke and when leaving work. Technical protective measures Provide adequate ventlation to minimize dust and/or vapour concentrations, ‘L.2. Conditions for safe storage, including any incompatibilities Storage Keep only in the original container in a cool, dry, well-ventilated place. container closed when not in use ‘Storage - away from Strong acids. Strong bases 13, Specific end use(s) ‘Specific end use(s) No data available Revised edition no:2 Page 3/7 Date : 5712/2011 Supersedes : 13/5/2011mi nubiola our passion your colors SAFETY DATA SHEET Nubifer Iron Oxide Red 8. Exposure controls / personal protection 8.1, Control parameters Occupational Exposure Limits 8.2. Exposure controls, Personal protection TWA: 10 mg Feim3 (8 hours, Inhalable Dust) TWA: 3 mg Feim3 (8 hours, Respirable Dust) ‘Avoid all unnecessary exposure. + Respiratory protection Where excessive dust may result, weer approved mask. FFP2 (EN149) + Hand protection In case of repeated or prolonged contact wear gloves. + Bye protection ‘Chemical goggles or safety classes. + Others Do not eat, drink or smoke when using this product. 9. Physical and chemical properties Information on basic physical and chemical properti Physical state at 20°C Colour Odour Odour threshold pH Melting point [C] Critical temperature [’C] [Link] temperature [°C] Flammability (solid, gas) Flash point [°C] Boiling point [C] Evaporation rate ‘Vapour density Density at 20°C [g/em3] Solubility in water Log Pow octanol / water at 20°C Viscosity at 40°C [mmzis] ‘Other information Explosive properties Explosion limits - upper [%) Explosion limits - lower [4] Oxidising properties Revised edition no:2 Date : 5712/2011 Power. Red Osouriess. No data available 36 (10% wi) [ASTM D-1208-78] > 1000°C Not applicable. Not applicable, Not flammable. [UN Test 1] Not applicable, Not applicable, (Sola) Not applicable, Not applicable, 4.0 -5.0 giem3 [ASTM D-183-4] Insoluble. No data available Not applicable. (Solid) Not explosive. Not applicable, Not applicable, Not oxidizing, Page 4/7 Supersedes : 13/5/2011mi nubiola SAFETY DATA SHEET Nubifer Iron Oxide Red 40. Stability and reactivity 10.4. Reactivity Reactivity 10.2. Chemical stability Chemical stability 1 i rs Hazardous reactions 10.4, Conditions to avoid Conditions to avoid 1 i t Materials to avoid ‘Stable under normal conditions, ‘Stable under normal conditions, ‘Stable under recommended storage conaitons. Decomposes at temperatures above 1000 °C. ‘Strong acids, Strong bases 10.8. Hazardous decomposition products Hazardous decomposition products None under normal conditions 11. Toxicological information 11.4, Information on toxicological effects Acute toxicity = LD50 Oral (rat) {mg/kg] = LC50 Rat inhalation (mgim"/6h] Irritation ‘Sensitization Mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (STOT) ~ single exposure Specific target organ toxicity (STOT) ~ repeated exposure Aspiration hazard > 5000 mgikg > 210 mgim3 Non-iritating, No sensitizing potential No experimental or epidemiological evidence exists 'No experimental or epidemiological evidence exists. No experimental or epidemiological evidence exists No experimental or epidemiological evidence exists No experimental or epidemiological evidence exists Not applicable. 12. Ecological information 124, Toxicity Acute toxicity Revised edition no:2 Date : 5712/2011 Page 5/7 Supersedes : 13/5/2011mi nubiola SAFETY DATA SHEET Nubifer Iron Oxide Red 12. Ecological information (continued) + E050 48 h - Daphnia [mg/L] > 100 mg/L = LE50 96 h- Fish [mg/L] > 50000 mg/L (Danio rerio) 12.2. Persistence - degradabilty Persistence - degradability Not applicable 12.3. Bioaccumulative potential Bloaccumulative potential Not applicable 12.4, Mobility in soi Mobility in soil Not applicable 125, Results of PBT and vPvB assessment Results of PBT and vPvB assessment : The substance does not fll the critaria tobe identified as PBT substance or vPVB Substance according to Annex Xill of Regulation REACH, 128, Other adverse effects Environmental precautions Avoid relaese tothe environment WK class (Germany) ° 43. Disposal considerations General ‘Avoid release to the environment. Dispose in a safe manner in accordance with localinational regulations 14, Transport information 14.1. Land transport (ADR-RID) General information Not regulated, 14.2. Sea transport (IMDS) General information Not regulated, 143. Air transport (ICAO4ATA) General information Not regulated, Revised edition no:2 Page 617 Date : 5712/2011 Supersedes : 13/5/2011mi nubiola ur passion your colors SAFETY DATA SHEET Nubifer Iron Oxide Red 45. Regulatory information 15.1. Safety, health and environmental requlations/leaislation specific for the substance or mixture ‘Safety, health and environmental Ensure all nationalilocal regulations are observed. regulationsilegislation spacifie for the substance or mixture REACH Restrictions - Annex XVII None. 15.2. Chemical Safety Assessment Chemical Safety Assessment Ithas been carried out 46. Other information Revision Revision - See :* ‘Sources of key data used REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF ‘THE COUNCIL of 18 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Reguiation (EC) No 1907/2008 Recommended uses and restrictions: See procluct bulletin for detailed information, Further information For professional use only. ‘The contents and format of this safety Gata shest are in accordance with REACH Regulation (EC) No 1907/2006 and Regulation ( EU) No 4532010, DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we belleve are relabla. However, tne Information Is provided without any warranty, express or implied, regarding its correctness, The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsiblity and expressly disclaim lability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and Is to be used only for this product. Ifthe product is used as @ component in another product, this MSDS information may not be applicable. End of document Revised edition no:2 Page :7/7 Date : 5712/2011 Supersedes : 13/5/2011