PERODIC PROPERTICS Page # 35
Exercise - II (One or more than one option correct)
Question No. 1 and 2 are based on the following
information. statement alone is sufficient.
Four elements, P,Q,R & S have ground state electronic (D) Statement (1) & (2) together are not sufficient.
configuration as : In following questions a statement S and an explanation
P 1s2 2s2 2p6 3s2 3p3 E is given. Choose the correct answers from the codes
Q 1s2 2s2 2p6 3s2 3p1
A, B, C, D given for given questions.
R 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p3
S 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p1 (A) S is correct but E is wrong
(B) S is wrong but E is correct.
1.Comment which of the following option represent
the correct order of true (T) & false (F) statement. (C) Both S and E are correct and E is correct
I. size of P < size of Q explanantion of S.
II. size of R < size of S (D) Both S and E are correct but E is not correct
III. size of P < size of R (appreciable difference) explanation of S.
IV. size of Q < size of S (appreciable difference)
(A) TTTT (B) TTTF (C) FFTT (D) TTFF
5.S : Lithium is a better reducting agent than Cs.
2.Order of IE1 values among the following is E : Sublimation energy and Ionisation energy of lithium
(A) P > R > S > Q (B) P < R < S < Q is less than that of Cs.
(C) R > S > P > Q (D) P > S > R > Q
6.S : The first ionization energy of Be is greater than
3.Match the various sequences with the appropriate
orders : that of B.
Sequences Orders E : 2p orbital is lower in energy than 2s.
(I) Na+ Mg+2 Al+3 (a) increasing size of ion
in gaseous state 7.Bond distance C – F in (CF4) & Si–F in (SiF4) are
(II) I– S2– N3– (b) decreasing size of
respective 1.33 Å & 1.54 Å. C–Si bond is 1.87 Å.
ion in gaseous state
(III) O O– O–2 (c) increasing size of ions Calculation the covalent radius of F atom ignoring the
aqueous state. electronegativity differences.
(IV) N F O (IE2) (d) decreasing size of ions
aqueous state. 133
. 154
. 18
. 154
.
(A) 0.64 Å (B) Å (C) 0.5 Å (D) Å
(e) increasing order of IE2 3 2
(f) decreasing order of
electron affinity 8.Two elements A & B are such that B. E of A – A, B –
(A) I-(b), II-(c), III-(e), IV-(f) B & A – B are respectively 81 Kcal/mole, 64 Kcal/mole,
(B) I-(c), II-(b), III-(a), IV-(f) 76 Kcal/ mole & if electronegativity of B is 2.4. then
(C) I-(b), II-(c), III-(f), IV-(e) the electronegativity of A may be approxiamtely
(D) I-(b), II-(c), III-(a), IV-(e)
(A) 2.81 (B) 1.8 (C) 1.99 (D) 3.0
4. Is a data sufficiency problem in which it is to
9.Using the concept of Zeff (from Stater's rule). Explain
be decided on the basis of given statements whether
the given questions can be answered or not. (No the following :
matter whether the answer is yes or no) "In obtaining the electronic configuration of V+ from
If HSolution < 0 then compound acts as ionic in aqueous that of V, an e– is removed from 4s and not from 3d."
solution. Is AlCl3(s) ionic in aqueous solution.
STATE 1 : L.E. of AlCl3 is 5137 kJ/mol 10. From the following information
STATE 2 : HHE of Al+3 ion is –4665 kJ/mol–1 & HHE A–(g) A+2 (g) + 3e– H1 = 1400 kJ
of Cl is –381 kJ/mol–1
– A(g) A+2 (aq) + 2e–\ H2 = 700 kJ
+
(A) Statements (1) alone is sufficient but statement HEG[A (g)] = –350 kJ/mol
(2) is not sufficient. (IE1 + IE2) for A(g) = 950 kJ/mol
(B) Statements (2) alone is sufficient but statement Find
(1) is not sufficient. (A) IE1 of A (B) IE2 of A
(C) Both Statement together are sufficient but neither (C) HEG of A (D) HHE of A2+ (g)
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11. For ionic compound A2+B22– & C22+D2
(a)A4(s) + B2(g) A B2(s) Hf = –500
Find the lattice energy of AB2
(b)Find Hf for according D3(g) + C(s) C2D (s)
Given on sublimation of above metal (A4) it dissociates
into individual atom.
Given : Sublimation energy of A4 is 1600 ;
Sublimation energy of C is 100
Dissociation energy of B2 is 200 ;
Dissociation energy of D3 is 90
A(g) A (g) ; H = 50
A (g) A 2 (g) ; H = 150
B – (g) B(g) ; H = 260
B – (g) B 2 – (g) ; H = 250
D(g) D – (g) ; H = –50
D – (g) D 2 – (g) ; H = 100
C (g) C(g) ; H = – 150
+ 2–
C2D(s) 2C (g) + D (g) ; H = 1000
All the values are in kJ/mol
12. If each orbital can hold a maximum of three
electrons, the number of elements in 9th period of
periodic table (long form) are
(A) 48 (B) 162 (C) 50 (D) 75
13. The Zeff for
3d electron of Cr
4s electron of Cr
3d electron of Cr3+
3s electron of Cr3+ are in the order respectively.
(A) 4.6, 2.95, 4.95, 8.05 (B) 4.95, 2.95, 4.6, 8.05
(C) 4.6, 2.95, 5.3, 12.75 (D) none of these
14. (a) If internuclear distance between Cl atoms in
Cl2 is 10Å & between H atoms in H2 is 2Å, then calculate
internuclear distance between H & Cl (Electronegativity
of H = 2.1 & Cl = 3.0)
(b)Compare the following giving reasons
Acidic nature of oxides : CaO, CO, CO2, N2O5, SO3
15. With the help of EN values [ENA = 1.8, ENB = 2.6,
ENC = 1.6, END = 2.8] answer the following questions
for the compounds
HAO, HBO, HCO, HDO
(a)Compounds whose aqueous solution is acidic and
order of their acidic strength
(b)Compounds whose aqeous solution is basic and order
of their basic strength
(c)Comment on the chances of being coloured on the
basis of percent ionic character for the compounds
CD & AB
16.
140
Al+3(g) + 3Cl–(g)
130
120
Al+2(g) + 3Cl–(g)
110
100
ACl3(s)
Energy (kJ)
90
Al+3(g) + 3Cl–(aq)
80
70
60
50
Al+3(aq) + 3Cl–(aq)
40
30
1
20 Na(g) Cl2 (g)
2
10
0
1 3
Na(s) Cl2 (g) Al(s) Cl2 (g)
2 2
With the help of above information answer the following questions.
(1)HL.E. of NaAlCl4 will be _______________________
(2)HH.E. of Al+3 (g) ion will be _____________________
(3)Hf of NaCl(s) will be ________________________
(4) BECl2 Heg [Cl(g)] will be ____________________
3
(5) Heg1 of [ Al ( g)] will be ______________________.
